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Chng 3

AMIN- AMINO AXIT PROTIN (Ban KHTN)

Bi 11: AMIN
I. NH NGHA, PHN LOI, DANH PHP V NG PHN 1. nh ngha Amin l nhng hp cht hu c c to ra khi thay th mt hoc nhiu nguyn t hiro trong phn t NH3 bng mt hoc nhiu gc hirocacbon. Th d: CH3-N-CH3 NH3 ; C6H5NH2 ; CH3NH2 ; | CH3-NH-CH3 CH3 2 . Phan loai Amin c phan loai theo 2 cach thong dung nhat : a. Theo ac iem cau tao cua goc hirocacbon Amin thm (anilin C6H5NH2), amin beo (etylamin ), amin d vong (piroliin NH ) b. Theo bac cua amin Bac cua amin c tnh bang so nguyen t H trong phan t NH3 c thay the bang goc hyro cacbon. R R-NH2 R-NH-R R-N-R amin bac I amin bac II amin bac III 3. Danh php Cch gi tn theo danh php gc-chc : Ankan + v tr + yl + amin Cch gi tn theo danh php thay th : Ankan+ v tr + amin Tn thng thng Ch p dng cho mt s amin nh : C6H5NH2 Anilin ; C6H5-NH-CH3 N-Metylanilin Hp cht CH3NH2 C2H5NH2 CH3CH2CH2NH2 CH3CH(NH2)CH3 C6H5NH2 C6H5 -NH-CH3 Tn gc chc Metylamin Etylamin Prop-1-ylamin (n-propylamin) Prop-2-ylamin (isopropylamin) Phenylamin Metylphenylamin Tn thay th Metanamin Etanamin Propan-1-amin Propan-2-amin Benzenamin NMetylbenzenamin

4. ng phn Amin c cc loi ng phn: - ng phn v mch cacbon.; - ng phn v tr nhm chc; - ng phn v bc ca amin. II- TNH CHAT VAT L - Metylamin, imetylamin, trietylamin va etylamin la nhng chat kh, mui khai kho chu, oc, de tan trong nc.Cac amin ong ang cao hn la nhng chat long hoac ran, o tan trong nc giam dan theo chieu tang cua phan t khoi. - Anilin la chat long, soi 1840C, khong mau, oc, t tan trong nc, tan trong etanol, benzen. e lau trong khong kh, anilin chuyen sang mau nau en v b oxi hoa bi oxi khong kh. III- CAU TAO PHAN T VA TNH CHAT HOA HOC - CTCT amin cac bac va anilin:
N H R H

R R

N H

R R

N R
N

H H

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- Do phan t amin co nguyen t N con oi e cha lien ket nen amin co tnh baz. - Nguyen t N trong phan t amin co so oxi hoa -3 nen amin thng de b oxi hoa. - Cac amin thm, th du nh anilin, con de dang tham gia phan ng the vao nhan thm do anh hng cua oi electron cha lien ket nguyen t nit. 1. Tnh cht ca nhm -NH2 a) Tnh baz * CH3NH2 + HCl [CH3NH3]+ClMetylamin Metylaminclorua * Tc dng vi qu hoc phenolphtalein Metylamin Anilin Qu tm Xanh Khng i mu Phenolphtalein Hng Khng i mu * So snh tnh baz : CH3-NH2 >NH3 > C6H5NH2 b) Phn ng vi axit nitr *Ankylamin bc 1 + HNO2 Ancol + N2 + H2O : C2H5NH2 + HO NO C2H5OH + N2 + H2O * Amin thm bc 1 + HONO (to thp) mui iazoni : C6H5NH2+ HONO + HCl C6H5N2+Cl+ 2H2O Phenyl i azoni clorua c) Phn ng ankyl ho thay th nguyn t hiro ca nhm -NH2 C6H5N H2 + CH3 I C6H5-NHCH3 + HI Anilin Metyl ioua N-metylanilin 2. Phn ng th nhn thm ca anilin: Phn ng vi nc brom Do nh hng ca nhm -NH2 nguyn t Br d dng thay th cc nguyn t H v tr 2, 4, 6 trong nhn thm ca phn t anilin.

:NH2
+ 3Br2

Br

NH2

Br

Br
+ CH3I -HI + CH3I -HI

+ 3HBr

IV. NG DNG V IU CH a) Ankylamin c iu ch t amonic v ankyl halogenua

+ CH3I

NH3 CH3NH2

(CH3)2NH (CH3)3N
-HI

b) Anilin thng c iu ch bng cch kh nitro benzen bi hiro mi sinh (Fe + HCl)
Fe + HCl

C6H5 NO2 + 6H

t0

C6H5 NH2 + 2 H2O

Bi 12: AMINO AXIT

INH NGHA, CU TO PHN T V DANH PHP 1. nh ngha Amino axit l loi HCHC tp chc m phn t cha ng thi nhm amino (NH2) v nhm cacboxyl (COOH). VD: H2N CH2 COOH CH3 CH[NH2] COOH 2. Cu to phn t V nhom COOH co tnh axit, nhom NH2 co tnh baz nen trang thai ket tinh amino axit ton tai dang ion lng cc. Trong dung dch, dang ion lng cc chuyen mot phan nho thanh dang phan t : R CH COOR CH COOH NH3 dang ion lng cc
+

NH2 dang phan t

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3. Danh php Tn thay th: axit + (v tr nhm NH2 : 1, 2,) + amino + tn axit cacboxylic tng ng. Tn bn h thng: axit + (v tr nhm NH2: , , , ..) + amino + tn thng thng axit cacboxylic tng ng. Ten thay the Ten ban he Ten K Cong thc thong thng hieu
CH2 -COOH NH2 CH3 - CH - COOH NH2 CH3 - CH CH -COOH CH3 NH2

Axit aminoetanoic Axit 2 - aminopropanoic Axit - 2 amino -3 metylbutanoic Axit - 2 - amino -3(4 hiroxiphenyl)propano ic Axit 2 - aminopentanioic Axit 2,6 - iaminohexanoic

Axit aminoaxetic Axit - aminopropanoic Axit aminoisovaleric Axit -amino - (p hiroxiphenyl) propionic Axit - aminoglutamic Axit , - iaminocaproic

Glyxin Alanin Valin Tyrosin Axit glutamic Lysin

Gly Ala Val Tyr Glu Lys

HO

CH2 CH COOH NH2

HOOC(CH2)2CH - COOH NH2 H2N - (CH2)4 - CH - COOH NH2

II- TNH CHT VT L Cc amin axit l cc cht rn khng mu, v hi ngt, nhit nng chy cao, d tan trong nc. III- TNH CHT HA HC 1. Tnh cht axit baz ca dd amino axit a) Moi trrng dd aminoaxit. Xet vi aminoaxit (H2N)xR(COOH)y: - Khi x=y: dd gan nh trung tnh pH =7 - Khi x<y: dd co moi trng axit pH < 7 - Khi x>y: dd co moi trng baz pH > 7 b) Amino axit c tnh lng tnh + Amino axit tc dng vi axit v c mnh -> mui : HOOC CH2 NH2 + HCl -> HOOC CH2 NH3Cl + Amino axit tc dng vi baz mnh -> mui v nc : NH2 CH2 COOH + NaOH -> NH2 CH2 COONa +H2O 2. Phn ng este ha nhm COOH khiHCl NH2 CH2 COOH + C2H5OH NH2 CH2 COOC2H5 + H2O 3. Phn ng ca nhm NH2 vi HNO2 NH2 CH2 COOH + HNO2 > HOCH2COOH + N2+H2O 4. Phn ng trng ngng ... +H - NH -[CH2]5CO- OH +H - NH[CH2]5CO - OH +H - NH - [CH2]5CO -OH + Hay vet gon la : nH NH [CH2]5CO OH > (- NH [CH2]5CO -)n + nH2O IV- NG DUNG - Aminoaxit thien nhien (hau het la - aminoaxit) la c s e kien tao nen cac loai protein cua c the song. - Mot so amino axit c dung pho bien trong i song nh muoi mononatri cua axit glutamic dung lam gia v thc an (goi la m chnh hay bot ngot); axit glutamic la thuoc ho tr than kinh, methionin la thuoc bo gan. - Axit 6 - aminohexanoic va axit 6 - aminoheptanoic la nguyen lieu dung san xuat nilon -6 va nilon - 7.

T . . . - NH - [CH2]5CO - NH - [CH2]5CO - ...

+ nH2O

Bi 13: PEPTIT V PROTEIN

I- KHAI NIEM VA PHAN LOAI

A - PEPTIT
L thuyt v bi tp AMIN AMINO AXIT3

PROTEIN

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1. Khai niem
- Lien ket cua nhom CO vi nhom NH gia hai n v - amino axit c goi la lien ket peptit. - Peptit la nhng hp chat cha t 2 en 50 goc - amino axit lien ket vi nhau bang cac lien ket peptit. 2 . Phan loai Cac peptit c chia lam 2 loai : a. Oligopeptit gom cac peptit co t 2 en 10 goc - amino axit va c goi tng ng la ipeptit, tripeptit,... ecapeptit. b. Polipeptit gom cac peptit co t 11 en 50 goc - amino axit. Popipeptit la c s tao nen protein II. CAU TAO, ONG PHAN VA DANH PHAP 1. Cau tao - Phan t peptit hp thanh t cac goc - amino axit noi vi nhau bi lien ket peptit theo mot trat t nhat nh : amino axit au N con nhom NH2, amino axit au C cua nhom COOH. H2NCH CONHCHCONHCHCO....NHCHCOOH R1 R2 R3 Rn au N Lien ket peptit au C 2. ong phan, danh phap - Moi phan t peptit gom mot so xac nh cac goc - amino axit lien ket vi nhau theo mot trat t nghiem nghat. Viec thay oi trat t o se dan ti cac peptit ong phan. Th du : H2NCH2 CONHCHCOOH ; H2NCHCONHCH2 COOH CH3 CH3 - Neu phan t peptit cha n goc - amino axit khac nhau th so ong phan loai peptit se la n ! - Ten cua cac peptit c hnh thanh bang cach ghep ten goc axyl cua cac amino axit bat au t au N, roi ket thuc bang ten cua axit au C (c gi nguyen) III- TNH CHAT 1. Tnh chat vat l : Cac peptit thng the ran, co nhiet o nong chay cao va de tan trong nc. 2. Tnh chat hoa hoc : Do peptit co cha cac lien ket peptit nen no co hai phan ng ien hnh la phan ng thuy phan va phan ng mau biure. a. Phan ng mau biure : Dd peptit hoa tan Cu(OH)2 tao ra dd phc chat co mau tm ac trng. ipeptit ch co mot lien ket peptit nen khong co phan ng nay. b. Phan ng thuy phan Peptit a b thuy phan thanh hon hp cac - amino axit khi un nong dung dch peptit vi axit hoac kiem H2NCH CONHCHCONHCHCO....NHCHCOOH R1 R2 R3 Rn + 0 H ,t + nH2O H2NCHCOOH +H2NCHCOOH R1 R2 + H2NCHCOOH+.... + H2N CH COOH R3 Rn

B- PROTEIN
I- KHAI NIEM VA PHAN LOAI Protein la nhng polipeptit. cao phan t co phan t khoi t vai chuc nghn en

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vai trieu. Protein co vai tro la nen tang ve cau truc va chc mang cua moi c the song. Protein c phan thanh 2 loai : - Protein n gian la nhng protein c tao thanh ch t cac goc - amino axit.

- Protein phc tap la nhng protein c tao thanh t protein n gian cong vi thanh phan phi protein, nh axit nucleic, lipit, cacbohirat,... II- S LC VE CAU TRUC PHAN T PROTEIN
-PT protein c cau tao t mot hay nhieu chuoi polipeptit ket hp vi nhau hoac vi cac thanh phan phi protein khac. - Cac phan t protein khac nhau ve ban chat cac mat xch - amino axit, so lng va trat t sap xep cua chung, nen trong cac sinh vat t khoang tren 20 - amino axit thien nhien a tao ra mot lng rat ln cac protein khac nhau. - ac tnh sinh l cua protein phu thuoc vao cau truc cua chung. Co bon bac cau truc cua phan t protein : cau truc bac I, bac II, bac III va bac IV. III. TNH CHT CA PROTEIN 1. Tnh cht vt l ca protein Dng tn ti: protein tn ti 2 dng chnh l dng si v dng hnh cu. Tnh tan ca protein khc nhau: protein hnh si khng tan trong nc, protein hnh cu tan trong nc. - S ng t : khi un nng, hoc cho axit, baz, mt s mui vo dung dch protein, protein s ng t li, tch ra khi dung dch. 2. Tnh cht ho hc ca protein a) Phn ng thu phn Trong mi trng axit hoc baz, protein b thu phn thnh cc aminoaxit.
H2N CH CO NH CH CO NH CH CO .... NH CH COOH + (n 1) H2O R1 R2 R3 Rn H2N CH COOH + H2N CH COOH + H2N CH COOH + .... + H2N CH COOH R1 R2 R3 Rn
hay enzim

b) Phn ng mu Khi tc dng vi axit nitric, protein to ra kt ta mu vng :

NO2 OH + 2HNO3 OH NO2

+ 2H2O

Khi tc dng vi Cu(OH)2, protein to mu tm c trng (Phan ng mau biure). BI TP TRC NGHIM AMIN- AMINO AXIT- PROTEIN CU HI 1/ Hp chat CH 3 N(CH 3 ) CH 2CH 3 co ten la: A Trimetylmetanamin Bimetyletanamin C. N-imetyletanamin D. N,Nimetyletanamin 2/ ng vi cong thc C3H9N co so ong phan amin la : A. 3 B . 4 C. 5 D. 6 3/ ng vi cong thc C4H11N co so ong phan amin bac 2 la : A. 3 B. 4 C. 5 D. 6 4/ ng vi cong thc C5H13N co so ong phan amin bac 3 la : A. 3 B. 4 C. 5 D. 6 5/ ng vi cong thc C7H9N co so ong phan amin cha vong benzen la : A. 3 B. 4 C. 5 D. 6 6/ Anilin (C6H5NH2) v phenol (C6H5OH) u c phn ng vi : A dd HCl B dd NaOH C nc Br2 D dd NaCl 7/ Aminoaxit nao sau ay co hai nhom amino.

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A Axit Glutamit B Lysin C Alanin D Valin 8/ Mot amino axit co cong thc phan t la C4H9NO2. So ong phan amino axit la A 3 B 4 C 5 D 9/ Hp chat A co cong thc phan t CH6N2O3. A tac dung c vi KOH tao ra mot baz va cac chat vo c. Cong thc cau tao cua A la: + A H2N COO NH3OH B CH3NH 3 NO 3 . C.HONHCOONH4. D.H2N CHOH 2 NO 10/ Peptit co cong thc cau tao nh sau: H 2 N CH CO NH CH 2 CO NH CH COOH

CH3 CH(CH3 )2 Ten goi ung cua peptit tren la: A Ala Ala Val B Ala Gly Val C.Gly Ala Gly D. Gly Val Ala 11/ Cong thc nao sau ay cua pentapeptit (A) thoa ieu kien sau: + Thuy phan hoan toan 1 mol A th thu c cac - amino axit la: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin. + Thuy phan khong hoan toan A, ngoai thu c cac amino axit th con thu c 2 i peptit: Ala-Gly; Gly- Ala va 1 tripeptit Gly-Gly-Val. A Ala-Gly-Gly-Gly-Val B. Gly-Gly-Ala-Gly-Val C. Gly-Ala-Gly-Gly-Val D.Gly-Ala-Gly-ValGly 12/ Thuy phan khong hoan toan tetra peptit (X), ngoai cac -amino axit con thu c cac i petit: Gly-Ala; Phe-Va; Ala-Phe. Cau tao nao la ung cua X. A Val-Phe-Gly-Ala B Ala-Val-Phe-Gly C Gly-Ala-Val-Phe D. Gly-Ala-Phe-Val 13/ Bradikinin co tac dung lam giam huyet ap, o la mot nonapeptit co cong thc la: Arg-Pro-Pro-Gly-Phe-Ser-Pro-Phe-Arg Khi thuy phan khong hoan toan peptit nay co the thu c bao nhieu tri peptit ma thanh phan co cha phenyl alanin (phe). A.3 B.4 C.5 D. 6 14/ Cho cac chat sau ay: (1) Metyl axetat. (2) Amoni axetat.(3) Glyxin. (4) Metyl amoni fomiat. (5) Metyl amoni nitrat (6) Axit Glutamic. Co bao nhieu chat lng tnh trong cac chat cho tren: A.3 B. 4 C.5 D.2 15/Alanin co the phan ng c vi bao nhieu chat trong cac chat cho sau ay: Ba(OH)2; CH3OH; H2N CH2 COOH; HCl, Cu, CH3NH2, C2H5OH, Na2SO4, H2SO4. A 7 B 4 C 5 D 6 + NaOH + HCl 16/Cho s o bien hoa sau: Alanin X Y Chat Y la chat nao sau ay: A. CH3-CH(NH2)-COONa B. H2N-CH2-CH2-COOH C. CH3-CH(NH3Cl)COOH D. CH3-H(NH3Cl)COONa 17/Mt - amino axit X ch cha 1 nhm amino v 1 nhm cacboxyl. Cho 10,68 gam X tc dng vi HCl d thu c 15,06 gam mui. X c th l : A axit glutamic B valin C glixin D alanin 18/1 mol -aminoaxit X tac dung va het vi 1 mol HCl tao ra muoi Y co ham lng clo la 28,287%. Cong thc cau tao cua X la A CH3 CH(NH2) COOH B H2N CH2 CH2 COOH C NH2 CH2 COOH D H2N CH2 CH(NH2) COOH 19/ Khi trung ngng 13,1g axit -aminocaproic vi hieu suat 80%, ngoai aminoaxit con d ngi ta thu c m gam polime va 1,44g nc. Gia tr m la A 10,41g B 9,04g C 11,02g D 8,43g 20/ ot chay hoan toan mot amin no n chc thu c V H2O = 1,5V CO2 . Cong thc phan t cua amin la : A C2H7N B C3H9N C C4H11N D C5H13N 21/ Cho 3,04g hon hp A gom 2 amin no n chc tac dung va u vi 400ml dd HCl 0,2M c 5,96g muoi. Tm the tch N2 (ktc) sinh ra khi ot het hon hp A tren ?

L thuyt v bi tp AMIN AMINO AXITPROTEIN

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A 0,224 lt B 0,448 lt C 0,672 lt D 0,896 lt 22/ Cho 17,7g mot ankylamin tac dung vi dung dch FeCl3 d thu c 10,7g ket tua. Cong thc phan t cua ankylamin la : A. C2H7N B. C3H9N C. C4H11N D. CH5N 23/ Cho 10 gam hn hp gm 3 amin n chc, ng ng k tip nhau tc dng va vi dung dch HCl 1M, ri c cn dung dch th thu c 15,84 gam hn hp mui. Nu trn 3 amin trn theo t l mol 1 : 10 : 5 theo th t phn t khi tng dn th cng thc phn t ca 3 amin l p n no sau y? A CH5N, C2H7N, C3H7NH2 B. C2H7N, C3H9N, C4H11N C C3H9N, C4H11N, C5H11N D. C3H7N, C4H9N, C5H11N 24/ t chy hon ton 6,2 gam mt amin no, n chc phi dng ht 10,08 lt kh oxi (ktc). Cng thc ca amin l cng thc no sau y? A C2H5NH2 B. CH3NH2 C.C4H9NH2 D. C3H7NH2 25/ t chy hon ton 100ml hn hp gm imetylamin v hai hirocacbon ng ng k tip thu c 140ml CO2 v 250ml hi nc (cc th tch o cng iu kin). Cng thc phn t ca hai hirocacbon l p n no? A C2H4 v C3H6 B.C2H2 v C3H4 C. CH4 v C2H6 D. C2H6 v C3H8 26/ t chy hon ton hn hp hai amin no n chc ng ng lin tip, ta thu c hn hp sn phm kh vi t l th tch nCO2: nH2O = 8 : 17. Cng thc ca hai amin l p n no? A. C2H5NH2, C3H7NH2 B. C3H7NH2, C4H9NH2 C. CH3NH2, C2H5NH2 D. C4H9NH2, C5H11NH2 27/Cho 1,52 gam hn hp hai amin no n chc (c s mol bng nhau) tc dng va vi 200ml dung dch HCl, thu c 2,98g mui. Kt lun no sau y khng chnh xc. A Nng mol ca dung dch HCl bng 0,2M B S mol ca mi cht l 0,02mol C Cng thc thc ca hai amin l CH5N v C2H7N D Tn gi hai amin l metylamin v etylamin 28/ Ngi ta iu ch anilin bng cch nitro ha 500g benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on 78% ? A 346,7g B 362,7g C 463,4g D 358,7g 29/Este X c iu ch t aminoaxit v ru etylic. T khi hi ca X so vi hiro 5,15 . t chy hon ton 10,3 gam X thu c 17,6gam kh CO2 v 8,1gam nc v 1,12 lt nit (ktc). Cng thc cu to thu gn ca X l cng thc no sau y? A H2N (CH2)2 COO C2H5 B. H2N CH(CH3) COOC2H5 C H2N CH2 CH(CH3) COOH D. H2N CH2 COO CH3 30/ Cht A c % khi lng cc nguyn t C, H, O, N ln lt l 32%, 6,67% 42,66%, 18,67%. T khi hi ca A so vi khng kh nh hn 3. A va tc dng NaOH va tc dng dd HCl, A c cng thc cu to nh th no? A CH3 CH(NH2) COOH B H2N (CH2)2 COOH C H2N CH2 COOH D H2N (CH2)3 COOH 31/ Cht A c thnh phn % cc nguyn t C, H, N ln lt l 40,45%, 7,86%, 15,73% cn li l oxi. Khi lng mol phn t ca A <100 g/mol. A tc dng c vi NaOH v vi HCl, c ngun gc t thin nhin, A c CTCT nh th no. A. CH3 CH(NH2) COOH B . H2N (CH2)2 COOH C. H2N CH2 COOH D. H2N (CH2)3 COOH 32/ Dung dch X gom HCl va H2SO4 co pH = 2. e trung hoa hoan toan 0,58g hon hp 2 amin no n chc bac 1 (co so ngt C nho hn hoac bang 4) phai dung 1 lt dd X. Cong thc cua 2 amin co the la A CH3NH2 va C4H9NH2 B. C2H5NH2 va C4H9NH2 C. C3H7NH2 va C4H9NH2 D. Ca A va B 33/ ot chay hoan toan a mol aminoaxit A thu c 2a mol CO2 va a/2 mol N2. Aminoaxit A la : A . H2NCH2COOH B. H2N[CH2]2COOH C. H2N[CH2]3COOH D. H2NCH(COOH)2 34/Nguyn nhn gy nn tnh baz ca amin l: A Do amin tan nhiu trong H2O B Do phn t amin b phn cc mnh C Do nguyn t N c m in ln nn cp electron chung ca nguyn t N v H b ht v pha N D Do nguyn t N cn cp eletron t do nn phn t amin c th nhn proton 35/ Mt peptit c cng thc:

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Tn ca peptit trn l H 2 N CH CO NH CH 2 CO NH CH COOH

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CH3 CH(CH3 )2 A glyxinalaninvalin B glyxylalanylvalyl C. glyxylalanylvalin D. glyxylalanyllysin 36/ t chy hon ton hn hp X gm 2 amin no n chc k tip nhau trong dy ng ng, thu c 22 g CO 2 v 14,4 g H2O. Cng thc phn t ca hai amin l : A CH3NH2 v C2H7N B C2H7N v C3H9N C .C3H9N v C4H11N D.C4H11N v C5H13 N 37/ Mt hp cht hu c X c cng thc phn t C 3H9O2N. Cho X phn ng vi dung dch NaOH, un nh thu c mui Y v kh Z lm giy qu tm nc ho xanh. Cht rn Y tc dng vi NaOH rn (CaO, t0 cao) thu c CH4. X c cng tc cu to : A CH3 COO NH4 B C2H5 COO NH4 C. CH3 COO H3NCH3 D. A v C u ng 38/ Mt hn hp gm 2 amin no n chc k tip nhau trong dy ng ng. Ly 21,4 gam hn hp cho vo dung dch FeCl3 c d thu c mt kt ta c khi lng bng khi lng ca hn hp trn. Cng thc phn t ca hai amin l: A C3H7NH2 v C4H9NH2 B. CH3NH2 v C2H5NH2 C C2H5NH2 v C3H7NH2 D. C4H9NH2 v C5H11NH2 39/ t chy hon ton m gam mt amin X bng lng khng kh va thu c 17,6 gam CO 2, 12,6 gam H2O v 69,44 lt N2. Bit trong khng kh ch cha N2 v O2 (80%). Cc th tch kh o ktc. Amin X c Cng thc phn t: A C3H7NH2 B CH3NH2 C. C4H9NH2 D. C2H5NH2 40/Hp cht hu c X mch h, thnh phn phn t gm C, H, N. Trong %N chim 23,7% (theo khi lng), X tc dng vi HCl theo t l mol 1:1. X c Cng thc phn t: A C3H7NH2 B. CH3NH2 C.C4H9NH2 D.C2H5NH2 41/ t chy hon ton mt amin thm X thu c 3,29 gam CO 2, 0,99 gam H2O v 336ml N2 (ktc). trung ho 0,1 mol X cn 600ml dung dch HCl 0,5M. Cng thc phn t ca X: A C7H11N B.C7H7NH2 C.C7H11N3 D. C7H9N2 42/ C hai amin bc mt: A (ng ng ca anilin) v B (ng ng ca metylamin). t chy hon ton 3,21g amin A sinh ra 336ml kh N2 (ktc). Khi t chy hon ton amin B cho n H2 O : n CO2 = 3 : 2 . Cng thc phn t ca hai amin l: A. CH3C6H4NH2 v CH3CH2CH2NH2 B. C2H5C6H4NH2 v CH3CH2CH2NH2 C. CH3C6H4NH2 v CH3CH2CH2CH2NH2 D.C2H5C6H4NH2 v CH3CH2CH2CH2NH2 43/ Hn hp X gm hai amin no bc mt X v Y. X cha 2 nhm axit v mt nhm amino, Y cha mt nhm axit v mt nhm amino. t chy hon ton 1 mol X hoc 1 mol Y th thu c s mol CO 2 < 6. Bit t l khi lng phn t MX = 1,96 .CTCT ca 2 amino axit l: MY A H2NCH2CH(COOH)CH2COOH v H2NCH2COOH B. H2NCH2CH(COOH)CH2COOH v H2N(CH2)2COOH C H2NCH(COOH)CH2COOH v H2N(CH2)2COOH D. H2NCH(COOH)CH2COOH v H2NCH2COOH 44/ tch ring hn hp gm ba cht lng: C6H6, C6H5OH v C6H5NH2 ngi ta c th tin hnh theo trnh t sau: A Dng dung dch HCl, lc, chit, sc kh CO2 B Dng dung dch NaOH, lc nh, chit, dung dung dch HCl, chit, dng dung dch NaOH C Dng dung dch NaOH, lc nh, chit, sc kh CO2. D Dng dung dch brom, lc nh, chit, dng dung dch NaOH, kh CO2 45/ Mt hp cht hu c X c Cng thc phn t C3H7O2N. X phn ng vi dung dch brom, X tc dng vi dung dch HCl v dung dch NaOH. Cht hu c X c cng thc cu to: A H2N CH = CHCOOH B CH2 = CH COONH4 C. H2N CH2 CH2COOH D. A v B ng 46/ un nng 100ml dung dch mt aminoaxit 0,2 M tc dng va vi 80ml dung dch NaOH 0,25M. Sau phn ng ngi ta c cn dung dch thu c 2,5 g mui khan. Mt khc, ly 100g dung dch aminoaxit trn c nng 20,6 % phn ng va vi 400ml dung dch HCl 0,5 M. Cng thc phn t ca aminoaxit l: A H2NCH2COOH B.CH3CH(NH2)COOH C. CH3CH2CH(NH2)COOH D. CH3COONH4 47/ Aminoaxit X cha mt nhm amin bc mt trong phn t. t chy hon ton mt lng X thu c CO 2 v N2 t l th tch l 4:1 . X c cng thc cu to l: A H2NCH2COOH B CH3CH(NH2)COOH C. NH2CH2CH2COOH D. CH3CH2CH(NH2)COOH 48/ Vi hn hp gm hai axit amin l glixin (glycine, Gly) v alanin (alanine, Ala), c th thu c ti a bao nhiu tripeptit khi cho chng kt hp vi nhau? (Bit rng trong mi tripeptit u c cha hai aminoaxit ny) A. 4 B. 6 C. 8 D. nhiu hn 49/ Mt hemoglobin (hng cu ca mu) cha 0,4% Fe (mi phn t hemoglobin ch cha 1 nguyn t Fe). Phn t

L thuyt v bi tp AMIN AMINO AXITPROTEIN

Gv : Phan Trung B

Trng THPT L Thng Kit

khi gn ng ca hemoglobin trn l : A. 12000 B. 14000 C. 15000 D. 18000 50/ Aminoaxit X c 1 nhm amino v 1 nhm cacboxyl trong phn trm khi lng ca oxi l 31,068%. C bao nhiu aminoaxit ph hp vi X? A.3 B. 4 C. 5 D. 6 51/t chy hon ton 5,9g mt hp cht hu c n chc X thu c 6,72 lt CO2, 1,12 lt N2 (ktc) v 8,1g H2O. Cng thc ca X l : A. C3H6O B. C3H5NO3 C. C3H9N D.C3H7NO2 52/ Khi cho metylamin v anilin ln lt tc dng vi HBr v dung dch FeCl2 s thu c kt qu no di y? A. C metylamin v anilin u tc dng vi c HBr v FeCl2. B. Metylamin ch tc dng vi HBr cn anilin tc dng c vi c HBr v FeCl2. C. Metylamin tc dng c vi c HBr v FeCl2 cn anilin ch tc dng vi HBr. D. C metylamin v anilin u ch tc dng vi HBr m khng tc dng vi FeCl2 53/ Mt amin A thuc cng dy ng ng vi metylamin c hm lng cacbon trong phn t bng 68,97%. Cng thc phn t ca A l... A. C2H7N. B. C3H9N. C. C4H11N. D. C5H13N. - aminocaproic vi hiu sut 80%, ngoi amino axit cn d, ngi ta thu c m 54/ Khi trng ngng 13,1 g axit gam polime v 1,44 g nc. Gi tr ca m l ? A. 10,41. B. 9,04. C. 11,02. D. 8,43. 55/ Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH, un nng c dung dch Y v 4,48 lt (ktc) hn hp Z gm 2 kh ( u lm xanh giy qu tm m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l : A. 16,5g B. 14,3g. C. 8,9g. D. 15,7g. 56/Hp cht X cha 2 loi nhm chc amino v cacboxyl. Cho 100ml dd X 0,3M phn ng va vi 48ml dd NaOH 1,25M. Sau em c cn dd th thu c 5,31g mui khan. Bit X c mch cacbon khng phn nhnh v c mt nhm amino v tr . Cng thc cu to ca X l: A. CH3-CH(NH2)-COOH. B. CH3-CH(NH2)-(COOH)2. C. HOOC-CH2-CH(NH2)-COOH. D. H2N-CH2-COOH. 57/ Trong cc cht sau: Cu, HCl, C2H5OH, HNO2, KOH, Na2CO3, CH3OH/kh HCl. Glyxin tc dng c vi nhng cht no ? A.HCl, HNO2, KOH, Na2CO3, CH3OH/HCl. B. C2H5OH, HNO2, KOH, Na2CO3, CH3OH/kh HCl , Cu. C. Cu, KOH, Na2CO3,HCl, HNO2, CH3OH/kh HCl. D. Tt c cc cht. 58/ Este X c iu ch t Aminoaxit Y v ancol etylic. T khi hi ca X so vi hidro bng 51,5. t chy hon ton 10,3g X thu c 17,6g kh CO2, 8,1g nc v 1,12 lt N2(ktc). Cng thc cu to thu gn ca X l cng thc no sau y ? A. H2N-(CH2)2-COO-C2H5. B.H2N-CH2-COO-C2H5. C. H2N-CH(CH3)-COOH. D. H2N-CH(CH3)-COO-C2H5. 59/ Thy phn n cng mt protein, ta thu c cc cht no? A. cc axit amin. B. Cc peptit. C. chui peptit. D. hn hp cc aminoaxit. 60/Cho 0,02 mol cht X (X l mt -aminoaxit) phn ng va ht vi 160ml dd HCl 0,152M th to ra 3,67g mui. Mt khc, 4,41g X khi tc dng vi mt lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l : A. HOOC-CH(NH2)-CH(NH2)-COOH. B.HOOC-CH2-CH2-CH(NH2)-COOH. C. CH3-CH2-CH(NH2)-COOH. D. CH3-CH2-CH2-CH(NH2)-COOH 61/ cho 7,12g mt aminoaxit X l ng ng ca axit aminoaxetic vo 300ml dung dch HCl 0,4M. tc dng hon ton vi cc cht c trong dung dch sau phn ng, phi dng 0,2mol KOH. Cng thc cu to thu gn ca X l : A. C2H5-CH(NH2)-COOH. C. CH3-CH(NH2)-COOH. B. H2N-CH2-COOH. D. H2N-CH2-CH2-CH2-COOH. 62/ t chy hon ton 5,15g mt cht X th cn va 5,88 lt oxi thu c 4,05g H2O v 5,04 lt hn hp gm CO2 v N2. Bit X l mt aminoaxit c mt nhmNH2 trong phn t.Cng thc phn t ca X l (kh o ktc). A. C3H7O2N. B. C4H9O2N. C. C2H5O2N. D. C5H9O2N. 63/t chy hon ton 6,2 g mt amin no, n chc, mch h phi dng ht 10,08 lt kh oxy (ktc). TCPT ca amin l: A. C3H7NH2 B. C2H5NH2 C. C4H9NH2 D. CH3NH2 64/ Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng c vi dung dch NaOH v u tc dng c vi dung dch HCl l A. X, Y, Z, T. B. X, Y, T. C. X, Y, Z. D. Y, Z, T. 65/ Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l

L thuyt v bi tp AMIN AMINO AXITPROTEIN

Gv : Phan Trung B

Trng THPT L Thng Kit

A. 0,1 mol v 0,4 mol. B. 0,1 mol v 0,2 mol. C. 0,1 mol v 0,1 mol. D. 0,1 mol v 0,3 mol. 66/ C cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), H2N-CH2-CH2CH(NH2)-COOH, ClH3N-CH2-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l : A. 2. B. 5. C. 4. D. 3. 67/ Cho cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 85. B. 68. C. 45. D. 46. 68/Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t X, thnh phn phn trm khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865% v 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l : A. H2NCH2COO-CH3. B. CH2=CHCOONH4. C. H2NCOO-CH2CH3. D. H2NC2H4COOH 69/ Cho X l NH3, Y l CH3NH2, Z l (CH3)2NH, T l C6H5NH2 v U l (C6H5)2NH. Trt t tng dn tnh baz l: A. U < Z< T < Y < X B. U < T < Z < Y < X C. X < Y < Z < T < U D. U < T < X < Y < Z 70/ trung ha 50 gam dung dch ca mt amin n chc X nng 12,4% cn dng 200ml dung dch HCl 1M. Cng thc phn t ca X l : A. C2H7N. B. C3H5N. C. CH5N. D. C3H7N 71/ t chy hon ton amin X bng lng khng kh va thu c 17,6 gam CO2 ,12,6 gam H2O v 69,44 lt N2 .Gi thit khng kh gm N2 v O2 ,trong O2 chim 80% khng kh v th tch. Cc th tch o trong cng ktc .Cng thc ca amin l : A. C3H7NH2 B. C2H5NH2 C. C4H9NH2. D. CH3NH2 72/Cho hp cht hu c A c cng thc phn t C2H8N2O3. Bit 0,15 mol A tc dng vi dung dch cha 12 gam NaOH un nng thu c cht kh A1 lm xanh qu tm m v dung dch A2. C cn dung dch A2 c p gam cht rn khan. Gi tr ng ca p l : A.18,75 gam B.15 gam C.12,5 gam D.20,625 gam 73/ Tin hnh trng ngng hn hp glyxin v alanin. Hi c th thu c ti a bao nhiu ipeptit ? A. 2 B. 3 C. 4 D. 5 74/ Hn hp X gm benzen,anilin v phenol. m gam X tc dng vi nc brom d thu c 82,6 gam kt ta. m gam X tc dng va vi 100 ml dung dch KOH 1M. t chy hon ton m gam X thu c 47,04 lt CO2(ktc). m c gi tr l : A. 31,15 B.35,25 C. 26,25 D. 35,55 75/ Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng vi vi 0,075 mol Br2 to kt ta. Lng cc cht NH3, C6H5NH3 v C6H5OH ln lt bng bao nhiu? A. 0,01 mol; 0,005mol v 0,02mol B. 0,05 mol; 0,005mol v 0,02mol C. 0,05 mol; 0,002mol v 0,05mol. D. 0,01 mol; 0,005mol v 0,02mol 76/A l mt aminoaxit. Cho bit 1 mol A phn ng va vi 1 mol HCl, hm lng clo trong mui thu c l 19,346%. Cng thc ca A l : A. HOOCCH2CH2CH(NH2)COOH B. HOOCCH2CH2 CH2CH(NH2)COOH C. CH3CH2CH(NH2)COOH D. CH3CH(NH2)COOH 77/ Cho 11,25 gam C2H5NH2 tc dng vi 200 ml dung dch HCl x(M). Sau khi phn ng xong thu c dung dch c cha 22,2 gam cht tan. Xc nh x : A. 1,3M B. 1,25M C. 1,36M D. 1,5M 78/Hp cht hu c X c cng thc tng qut CxHyOzNt. Thnh phn % khi lng ca N v O trong X ln lt l 15,730% v 35,955%. Khi X tc dng vi HCl ch to ra mui R(Oz)NH3Cl (R l gc hirocacbon). Bit X c trong thin nhin v tham gia phn ng trng ngng. Cng thc cu to ca X l. A. CH2 = CHCOONH4 B. H2NCH(CH3)COOH. C. H2NCH2CH2COOH. D. H2NCH2COOCH3. 79/ Cht X tc dng vi dung dch NaOH to ra cht Y. t chy hon ton 11,1 gam cht Y c 0,3 mol hn hp CO2 v N2 c t khi so vi H2 bng 20,667, ngoi ra cn 0,3 mol H2O v 0,05 mol Na2CO3. Bit X c tnh lng tnh v Y ch cha 1 nguyn t N. Cng thc cu to ca Y l. A. H2NCH = CHCOOONa. B. CH3CH(NH2)COOONa. C. H2NCH2COONa. D. CH2 = CHCOONH4. 80/28,1 gam hn hp propylamin, axit aminoaxetic v etylaxetat c th phn ng vi 6,72 lt hiroclorua ( ktc). Cng mt lng hn hp trn c th phn ng vi 100 ml dung dch KOH 1M (cc phn ng va ). % khi lng ca aminoaxit trong hn hp l : A. 23,3%. B. 26,69%. C. 54,7%. D. 22%. 81/ Khi thy phn mt protein (X) thu c hn hp gm 2 aminoaxit no k tip nhau trong dy ng ng. Bit mi cht u cha mt nhm - NH2 v mt nhm - COOH. t chy hon ton 0,2 mol hn hp 2 aminoaxit ri cho sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng 32,8 gam. Cng thc cu to ca 2 aminoaxit l. : A. H2NCH2COOH, H2NCH(CH3)COOH. B. H2NCH(CH3)COOH, H2N(CH2)3COOH.

L thuyt v bi tp AMIN AMINO AXITPROTEIN

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Gv : Phan Trung B

Trng THPT L Thng Kit

C. H2NCH2COOH, H2NCH2CH2COOH. D. H2NCH(CH3)COOH, C2H5CH(NH2)COOH. 82/ Khi thy phn hon ton mt polipeptit ta thu c cc aminoaxit X, Y, Z, E, F. Cn khi thu phn tng phn th thu c cc i- v tripeptit XE, ZY, EZ, YF, EZY. Trnh t cc aminoaxit trong polipeptit trn l. A. X - Z - Y - F - E. B. X - E - Z - Y - F. C. X - Z - Y - E - F. D. X - E - Y - Z - F. 83/ Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l : A. C2H7N. B. C4H9N. C. C3H7N. D. C3H9N. 84/ Cho s chuyn ho sau:
(1)

Benzen

Clobenzen

(2)

X Y

(3)

Phe nol Anilin

.

Nitrobenzen (5) (4)

(6)

X, Y ln lt l. A. C6H5NH3Cl, C6H5ONa. B. C6H5Br, C6H5CH2NH3Cl. C. C6H5ONa, C6H5CH2NH3Cl. D. C6H5ONa, C6H5NH3Cl 85/ t chy hon ton 0,02 mol mt amin bc 1 (X) vi lng O2 va , cho ton b sn phm chy qua bnh cha Ca(OH)2 d thy khi lng bnh tng 3,02 gam v cn li 0,224 lt ( ktc) mt cht kh khng b hp th. Khi lc dung dch thu c 4 gam kt ta. Cng thc cu to ca X l. : A. (CH2)2(NH2)2. B. CH3CH(NH2)2. C. CH2 = CHNH2. D. CH3CH2NH2. 86/ Cho s sau:

C6H6 X C 6H 5NH 2 Y Z C 6 5 2 . X, Y, Z ln lt l. H NH
A. C6H5NO2, C6H5Br, C6H5NH3Cl. B. C6H5Cl, C6H5NO2, C6H5NH3Cl. C. C6H5CH3, C6H5NO2, (C6H5NH3)2SO4. D. C6H5NO2, C6H5NH3Cl, C6H5NH3NO3. 87/Chn phng php tt nht phn bit dung dch cc cht: Glixerol, glucoz, anilin, alanin, anbumin. A. Dng ln lt cc dung dch AgNO3/NH3, CuSO4, NaOH. B. Dng ln lt cc dung dch CuSO4, H2SO4, I2. C. Dng Cu(OH)2 ri un nng nh, sau dng dung dch Br2. D. Dng ln lt cc dung dch HNO3, NaOH, H2SO4.
CuO 3 2 88/ Cho s phn ng: NH3 X Y Z . Bit Z c kh nng tham gia phn ng trng gng. (1:1) t0 CH I HNO

Hai cht Y v Z ln lt l. A. CH3OH, HCHO. B. C2H5OH, HCHO. C. CH3OH, HCOOH. D. C2H5OH, CH3CHO 89/ Cho 0,1 mol hp cht X tc dng va vi 80 ml dung dch HCl 1,25M, sau c cn dung dch thu c 18,75 gam mui. Mt khc, cho 0,1 mol X tc dng vi NaOH va ri c cn th c 17,3 gam mui. Bit X l mt aminoaxit v c kh nng phn ng vi Br2/Fe cho hp cht C8H9O2NBr. Cng thc cu to ca X l. A. C6H5CH(NH2)COOH. B. H2NCH2C6H4COOH. C. H2NC6H4CH2COOH. D. H2NC6H4COOH. 90/ Dung dch X cha HCl v H2SO4 c pH = 2. trung ha hon ton 0,59 gam hn hp hai amin no, n chc, bc 1 (c s nguyn t C nh hn hoc bng 4 v cc cht c cng s mol) phi dng 1 lt dung dch X. Cng thc phn t ca 2 amin ln lt l. A. CH3NH2 v C4H9NH2. B. C2H5NH2 v C4H9NH2. C. C3H7NH2 v C4H9NH2. D. CH3CH2CH2NH2 v CH3CH(CH3)NH2. 91/ trung ho 25 gam dung dch ca 1 amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l : A. C2H7N. B. CH5N. C. C3H7N. D. C3H5N.

BI TP T LUN V AMIN- AMINOAXIT- PROTEIN

BI TP 1/ Mot hon hp gom benzen, phenol va anilin. Cho kh HCl d vao 10 gam hon hp nay th thu c 1,305 gam muoi. e trung hoa 10 gam hon hp nay th can dung 3,35 ml dung dch NaOH 20% (d=1,2g/ml). Tnh so mol moi chat ban au. 2/ ot chay hoan toan 4,45 gam A can dung 4,2 lt O2 (ktc) thu c 3,15 gam H2O va 3,92 lt hon hp gom CO2 va N2 (ktc). Cho d A H = 44,5 . Xac nh cong thc phan t
2

cua A. Xac nh cong thc cau tao cua A biet A la este cua ru metylic 3/ Hp chat A la 1 -amino axit. Cho 0,01 mol A tac dung va u vi 80ml dung dch HCl 0,15M, co can th thu c 1,835g muoi. 11 L thuyt v bi tp AMIN AMINO AXIT-

PROTEIN

Gv : Phan Trung B

Trng THPT L Thng Kit

a)Tnh khoi lng phan t cua A. b)Trung hoa 2,94g A bang 1 lng va u dung dch NaOH, co can c 3,82g muoi. Viet CTCT cua A, biet A co mach Cacbon khong phan nhanh. Cho biet ng dung cua A. 4/ Cho 1,52 g hon hp 2 amin n chc no mach h bac I tac dung va u vi 200ml dd HCl thu c 2,98g muoi. a)Tnh tong so mol cua 2 amin trong hon hp va CM dd HCl. b)Tnh th tch N2 va CO2 thu c ieu kien chuan neu ot chay hoan toan 1,52g hon hp 2 amin tren. c)Xac nh CTCT cua 2 amin, biet hon hp 2 amin c tron theo so mol bang nhau. 5/ X l mt aminoaxt . Khi cho 200ml dung dch X 0,1 M tc dng vi HCl th cn ht 80 ml dung dch HCl 0,25 M. Cn khi cho 500ml dd X trn tc dng vi 100ml dd HCl 0,6 M th thu c dung dch A. tc dng ht vi cc cht trong dung dch A cn dng 6,4 g NaOH , sau phn ng thu c 12,36 gam mui. Tm CTCT ca X. 6/ Cho 200ml dd Amino Axit X. Co 1 nhom amin tac dung va u vi 80ml dd HCl 0,5M, ta c dung dch A. e tac dung het vi dung dch can 60ml Ba(OH)2 1M. Neu lay 250ml dd X trung hoa vi KOH c 111,5g muoi khan. a/ Tnh nong o mol/l cua dung dch X. b/ Tm CTPT cua X. Viet CTCT mach thang. 7/ ot chay hoan toan m gam mot Amin c 7,84 lt CO2 (kc) va 4,05g H2O. Mat khac e trung hoa m gam A can 50ml dung dch HCl 1M va thu c 7,175g muoi. a/ Tm CTN cua A. b/ Suy ra CTPT, CTCT va goi ten A, biet A la ong ang cua Anilin. 8/ Este A c ieu che t aminoaxit B va ancol metylic. T khoi hi cua A so vi hiro la 44,5. ot chay hoan toan 8,9 gam este A thu c 13,2 gam kh CO2, 6,3 gam H2O va 1,12 lit N2 (o ktc). Viet cong thc phan t va cong thc cau tao cua cac chat A va B. 9/ A la mot amino axit. Lay 0,02 mol A phan ng u vi 160ml dung dch HCl 0,125M thu c 3,67 gam muoi. Mat khac 4,41 gam A phan ng het bi NaOH thu c 5,73 gam muoi. a) Xac nh cong thc phan t cua A. b) Viet cong thc cau tao cua A biet A co mach cacbon khong co nhanh va nhom amino v tr . 10/ Hp chat hu c (A) co cong thc tng qut CXHYNO khoi lng phan t cua (A) bang 113 .v.C. A co mach cacbon khong phan nhanh, khong lam mat mau dung dch Br2, nhng b thuy phan trong dung dch NaOH va co kha nang phan ng trung hp. a/ nh cong thc phan t, cong thc cau tao va goi ten A. b/ Viet phng trnh thoa man vi tnh chat tren. 11/ ot chay 5,15 gam chat A can va u 5,88 lt O2 thu c 4,05 gam H2O va 5,04 lt kh hon hp gom CO2 va N2. Tm cong thc phan t cua A biet rang ty khoi hi cua A so vi H2 la 51,5, cac the tch kh o ktc . 12/ ot hoan toan 8,7 gam aminoaxit A (axit n chc) th thu c 0,3 mol CO2 ; 0,25mol H2O va 1,12 lt (ktc) cua mot kh tr. a/ Xac nh cong thc cau tao cua A. b/ Viet phan ng tao polyme cua A

L thuyt v bi tp AMIN AMINO AXITPROTEIN

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