ANEHIT-XETON-AXIT CACBOXYLIC

Copyright Mr.Caoduan

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ANEHIT-XETON-AXIT CACBOXYLIC

Copyright Mr.Caoduan

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ANEHIT-XETON-AXIT CACBOXYLIC

Copyright Mr.Caoduan

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Copyright Mr.Caoduan

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Copyright Mr.Caoduan

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ANEHIT-XETON-AXIT CACBOXYLIC

ANEHIT-XETON-AXIT CACBOXYLIC Cu 1: Mt anehit c cng thc tng qut l CnH2n + 2 2a m (CHO)m. Cc gi tr n, a, m ln lt c xc nh l A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 2: Co bao nhiu ng phn cu tao C5H10O co kha nng tham gia phan ng trang gng ? A. 2. B. 3. C. 4. D. 5. Cu 3: Co bao nhiu xeton co cng thc phn t l C5H10O ? A. 1. B. 2. C. 3. D. 4. Cu 4: Co bao nhiu ng phn cu tao C6H12O tham gia phan ng trang gng ? A. 6. B. 7. C. 8. D. 9. Cu 5: Co bao nhiu ancol C5H12O khi tac dung vi CuO un nong cho ra anehit ? A. 1. B. 2. C. 3. D. 4. Cu 6: CTGN ca 1 anehit no, a chc, mch h l C2H3O. CTPT ca n l A. C8H12O4. B. C4H6O. C. C12H18O6. D. C4H6O2. Cu 7: CTGN ca anehit no, a chc, mch h l C2H3O. Anehit c s ng phn l Copyright Mr.Caoduan Trang 6

ANEHIT-XETON-AXIT CACBOXYLIC

A. 2. B. 4. C. 1. D. 3. Cu 8: (CH3)2CHCHO c tn l A. isobutyranehit. B. anehit isobutyric. C. 2-metyl propanal. D. A, B, C u ng. Cu 9: CTPT ca ankanal c 10,345% H theo khi lng l A. HCHO. B. CH3CHO. C. C2H5CHO. D. C3H7CHO. Cu 10: Anehit A (ch cha mt loi nhm chc) co %C va %H (theo khi lng) ln lt la 55,81 va 6,97. Chi ra phat biu sai A. A la anehit hai chc. B. A con co ng phn la cac axit cacboxylic. C. A la anehit no. D. Trong phan ng trang gng, mt phn t A chi cho 2 electron. Cu 11: Trong cung iu kin nhit va ap sut, 1 lit hi anehit A co khi lng bng khi lng 1 lit CO2. A la A. anehit fomic. B. anehit axetic. C. anehit acrylic. D. anehit benzoic. Cu 12: t chay hoan toan p mol anehit X c q mol CO2 va t mol H2O. Bit p = q - t. Mt khac 1 mol X trang gng c 4 mol Ag. X thuc day ng ng anehit A. n chc, no, mch h. C. hai chc cha no (1 ni i C=C). B. hai chc, no, mch h. D. nhi chc cha no (1 ni ba CC). Cu 13: Anehit a chc A chay hoan toan cho mol CO2 - mol H2O = mol A. A la A. anehit no, mch h. B. anehit cha no. C. anehit thm. D. anehit no, mch vong. Cu 14: t chay anehit A c mol CO2 = mol H2O. A la A. anehit no, mch h, n chc. B. anehit n chc, no, mch vong. C. anehit n chc co 1 ni i, mch h. D. anehit no 2 chc, mch h. Cu 15: un nng V lt hi anehit X vi 3V lt kh H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c mt hn hp kh Y c th tch 2V lt (cc th tch kh o cng iu kin nhit , p sut). Ngng t Y thu c cht Z ; cho Z tc dng vi Na sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. no, hai chc. B. khng no (cha mt ni i C=C), hai chc. C. no, n chc. D. khng no (cha mt ni i C=C), n chc. Cu 16: Cho cac cht : HCN, H2, dung dich KMnO4, dung dich Br2/H2O, dung dich Br2/CH3COOH a. S cht phan ng c vi (CH3)2CO iu kin thch hp la A. 2. B. 3. C. 4. D. 5. b. S cht phan ng c vi CH3CH2CHO iu kin thch hp la A. 4. B. 2. C. 3. D. 5. Cu 17: CH3CHO c th to thnh trc tip t A. CH3COOCH=CH2. B. C2H2. C. C2H5OH. D. Tt c u ng. Cu 18: Qu trnh no sau y khng to ra anehit axetic ? A. CH2=CH2+ H2O (to, xc tc HgSO4). B. CH2=CH2 + O2 (to, xc tc). C. CH3COOCH=CH2 + dung dch NaOH (to). D. CH3CH2OH + CuO (t0). Cu 19: Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l A. C2H5OH, C2H2, CH3COOC2H5. B. HCOOC2H3, C2H2, CH3COOH. C. C2H5OH, C2H4, C2H2. D. CH3COOH, C2H2, C2H4. Cu 20: Mt axit cacboxylic c cng thc tng qut l CnH2n + 2 2a m (COOH)m. Cc gi tr n, a, m ln lt c xc nh l Copyright Mr.Caoduan Trang 7

A. n > 0, a 0, m 1. B. n 0, a 0, m 1. C. n > 0, a > 0, m > 1. D. n 0, a > 0, m 1. Cu 21: A la axit no h, cng thc CxHyOz. Chi ra mi lin h ung A. y = 2x-z +2. B. y = 2x + z-2. C. y = 2x. D. y = 2x-z. Cu 22: A la axit cacboxylic mach h, cha no (1 ni i C=C), cng thc CxHyOz. Chi ra mi lin h ung A. y = 2x. B. y = 2x + 2-z. C. y = 2x-z. D. y = 2x + z-2. Cu 23: Axit khng no, n chc c mt lin kt i trong gc hirocacbon c cng thc ph hp l A. CnH2n+1-2kCOOH ( n 2). B. RCOOH. C. CnH2n-1COOH ( n 2). D. CnH2n+1COOH ( n 1). Cu 24: Axit cacboxylic A co cng thc n gian nht la C3H4O3. A co cng thc phn t l A. C3H4O3. B. C6H8O6. C. C18H24O18. D. C12H16O12. Cu 25: CTGN ca mt axit hu c X l CHO. t chy 1 mol X thu c di 6 mol CO2. CTCT ca X l A. CH3COOH. B. CH2=CHCOOH. C. HOOCCH=CHCOOH. D.Kt qu khc. Cu 26: Mt axit no A c CTGN l C2H3O2. CTPT ca axit A l A. C6H9O6. B. C2H3O2. C. C4H6O4. D. C8H12O8. Cu 27: C4H6O2 c s ng phn mch h thuc chc axit l A. 4. B. 3. C. 5. D. tt c u sai. Cu 28: Axit cacboxylic n chc mach h phn nhanh (A) co % O (theo khi lng) la 37,2. Chi ra phat biu sai A. A lam mt mau dung dich brom. B. A la nguyn liu iu ch thuy tinh hu c. C. A co ng phn hinh hoc. D. A co hai lin trong phn t. Cu 29: Axit hu c A c thnh phn nguyn t gm 40,68% C ; 54,24% O. trung ha 0,05 mol A cn 100ml dung dch NaOH 1M. CTCT ca A l A. HOOCCH2CH2COOH. B. HOOCCH(CH3)CH2COOH. C. HOOCCH2COOH. D. HOOCCOOH. Cu 30: Hp cht CH3CH2(CH3)CH2CH2CH(C2H5)COOH c tn quc t l A. axit 2-etyl-5-metyl hexanoic. B. axit 2-etyl-5-metyl nonanoic. C. axit 5-etyl-2-metyl hexanoic. D. tn gi khc. Cu 31: Gim n la dung dich axit axetic co nng la A. 2% 5%. B. 59%. C. 912%. D. 1215%. Cu 32: Axit axetic tc dng c vi dung dch no ? A. natri etylat. B. amoni cacbonat. C. natri phenolat. D. C A, B, C. Cu 33: Trong dy ng ng ca cc axit n chc no, HCOOH l axit c mnh trung bnh, cn li l axit yu (in li khng hon ton). Dung dch axit axetic c nng 0,001 mol/l c pH l A. 3 < pH < 7. B. < 3. C. 3. D. 10-3 Cu 34: in li ca 3 dung dch CH3COOH 0,1M ; CH3COOH 0,01M v HCl c sp xp theo th t tng dn l A. CH3COOH 0,01M < HCl < CH3COOH 0,1M. B. CH3COOH 0,01M < CH3COOH 0,1M < HCl. C. HCl < CH3COOH 0,1M < CH3COOH 0,01M. D. CH3COOH 0,1M < CH3COOH 0,01M < HCl. Copyright Mr.Caoduan Trang 8

ANEHIT-XETON-AXIT CACBOXYLIC

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 35: Th t sp xp theo s tng dn tnh axit ca CH3COOH ; C2H5OH ; CO2 v C6H5OH l A. C6H5OH < CO2 < CH3COOH < C2H5OH. B. CH3COOH < C6H5OH < CO2 < C2H5OH. C. C2H5OH < C6H5OH < CO2 < CH3COOH. D. C2H5OH < CH3COOH < C6H5OH < CO2. Cu 36: Cho 3 axit ClCH2COOH , BrCH2COOH, ICH2COOH, dy sp xp theo th t tng dn tnh axit l A. ClCH2COOH < ICH2COOH < BrCH2COOH. B. ClCH2COOH < BrCH2COOH < ICH2COOH. C. ICH2COOH < BrCH2COOH < ClCH2COOH. D. BrCH2COOH < ClCH2COOH < ICH2COOH. Cu 37: Gi tr pH ca cc axit CH3COOH, HCl, H2SO4 c sp xp theo th t tng dn l A. H2SO4, CH3COOH, HCl. B. CH3COOH, HCl , H2SO4. C. H2SO4, HCl, CH3COOH. D. HCl, CH3COOH, H2SO4. Cu 38: Trong cc phn ng este ha gia ancol v axit hu c th cn bng s chuyn dch theo chiu thun khi ta A. dng cht ho nc tch nc. B. chng ct ngay tch este ra. C. cho ancol d hoc axit d. D. tt c u ng. Cu 39: t chay hoan toan hn hp X gm 2 axit cacboxylic c mol CO2 = mol H2O. X gm A. 1 axit n chc, 1 axit a chc. B. 1 axit no, 1 axit cha no. C. 2 axit n chc no mach vong D. 2 axit no, mch h n chc. Cu 40: trung hoa 0,2 mol hn hp X gm 2 axit cacboxylic cn 0,3 mol NaOH. X gm co A. 2 axit cung day ng ng. B. 1 axit n chc, 1 axit hai chc. C. 2 axit a chc. D. 1 axit n chc, 1 axit a chc. Cu 41: t chay hoan toan axit cacboxylic A bng lng va u oxi c hn hp (khi va hi) co ti khi so vi H2 la 15,5. A la axit A. n chc no, mch h B. n chc co 1 ni i (C = C), mch h. C. a chc no, mch h. D. axit no,mch h, hai chc, Cu 42: t chy ht 1 th tch hi axit A thu c 2 th tch CO2 o cng iu kin, A l A. HCOOH. B. HOOCCOOH. C. CH3COOH. D. B v C ng. Cu 43: C th iu ch CH3COOH t A. CH3CHO. B. C2H5OH. C. CH3CCl3. D. Tt c u ng. Cu 44: Cho cc cht : CaC2 (I), CH3CHO (II), CH3COOH (III), C2H2 (IV). S chuyn ha ng iu ch axit axetic l A. I IV II III. B. IV I II III. C. I II IV III. D. II I IV III. Cu 45: Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. Cu 46: Cho s chuyn ha : CH3CH2Cl + KCN X (1); X + H3O+ (un nng) Y(2) Cng thc cu to ca X, Y ln lt l A. CH3CH2NH2, CH3CH2COOH. B. CH3CH2CN, CH3CH2CHO. Copyright Mr.Caoduan Trang 9

ANEHIT-XETON-AXIT CACBOXYLIC

C. CH3CH2CN, CH3CH2COOH. D. CH3CH2CN, CH3CH2COONH4. Cu 47: Cht c nhit si cao nht l A. CH3CHO. B. C2H5OH. C. CH3COOH. D. C2H6. Cu 48: Nhit si ca mi cht tng ng trong dy cc cht sau y, dy no hp l nht ? C2H5OH HCOOH CH3COOH A. 118,2oC 78,3oC 100,5oC B. 118,2oC 100,5oC 78,3oC C. 100,5oC 78,3oC 118,2oC D. 78,3oC 100,5oC 118,2oC Cu 49: Chi ra th t tng dn nhit si ca cc cht ? A. CH3CHO; C2H5OH ; CH3COOH. C. C2H5OH ; CH3COOH ; CH3CHO. B. CH3CHO ;CH3COOH ; C2H5OH. D. CH3COOH ; C2H5OH ; CH3CHO. Cu 50: Nhit si ca cc cht c sp xp theo th t tng dn l A. CH3OH < CH3CH2COOH < NH3 < HCl. B. C2H5Cl < CH3COOH < C2H5OH. C. C2H5Cl < CH3COOCH3 < C2H5OH < CH3COOH. D. HCOOH < CH3OH < CH3COOH < C2H5F. Cu 51: Cho cac cht CH3CH2COOH (X) ; CH3COOH ( Y) ; C2H5OH ( Z) ; CH3OCH3 (T). Day gm cac cht c sp xp tng dn theo nhit si la A. T, X, Y, Z. B. T, Z, Y, X. C. Z, T, Y, X. D. Y, T, Z, X. Cu 52: Nhit si ca ancol etylic (I), anehit axetic (II), axit axetic (III) v axit propionic (IV) sp xp theo th t gim dn l A. IV > I > III > II. B. IV > III > I > II. C. II > III > I > IV. D. I > II > III > IV. Cu 53: A la ancol n chc no h, B la axit cacboxylic no h n chc. Bit MA=MB. Phat biu ung l A. A, B la ng phn B. A, B co cung s cacbon trong phn t. C. A hn B mt nguyn t cacbon. D. B hn A mt nguyn t cacbon. Cu 54: Hai hp cht hu c X v Y c cng CTPT C3H4O2. X tc dng vi CaCO3 to ra CO2. Y tc dng vi dung dch AgNO3/NH3 to Ag. CTCT thu gn ph hp ca X, Y ln lt l A. HCOOCH=CH2, CH3COOCH3. B. CH3CH2COOH, HCOOCH2CH3. C. HCOOCH=CH2, CH3 CH2COOH. D. CH2=CHCOOH, HOCCH2CHO. OH Cu 55: Cho chui phn ng : C2H6O X axit axetic + CH 3 Y. CTCT ca X, Y ln lt l A. CH3CHO, CH3CH2COOH. C. CH3CHO, CH2(OH)CH2CHO. Cu 56: Cho s phn ng sau : B. CH3CHO, CH3COOCH3. D. CH3CHO, HCOOCH2CH3.
H2 -O Z

, CH CH 2HCHO butin-1,4-iol H 2 Y xt

Y v Z ln lt l A. HOCH2CH2CH2CH3 ; CH2=CHCH=CH2. B. HOCH2CH2CH2CH2OH ; CH2=CHCH2CH3. C. HOCH2CH2CH2CH2OH ; CH2=CHCH = CH2. D. HOCH2CH2CH2CH2OH ; CH3CH2CH2CH3. Copyright Mr.Caoduan Trang 10

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 57: Cho s chuyn ha sau:

, Hirocacbon A Br2 B NaOH C CuO as D O 2 , Mn HOOCCH2COOH. Vy A l
2+

CH2 - CH 2

A. CH2 B. C3H8. Cu 58: Cho chui phn ng sau

, C3H6 H 2 B1 Ni

C. CH2=CHCH3.
-

D. CH2=CHCOOH. B4 . Vy B4 l

Cl 2 , as

2 B2 (spc) OH O /H

B3

O 2 , Cu

A. CH3COCH3. B. A v C ng. Cu 59: Xt cc chui bin ha sau: a.

, A H 2 B Ni
- H 2O, - H 2 , xt

C. CH3CH2CHO.

D. CH3CHOHCH3.

C cao su Buna. C. OHC(CH2)2CH2OH. D. A, B, C u ng.

CTCT ca A l A. OHCCH2CH2CHO. B. CH3CHO. b.

, A H 2 B Ni

C cao su Buna.

CTCT ca A l A. OHCCH2CH2CHO. B. CH3CHO. Cu 60: Cho s chuyn ha sau : C2H6

, 2 Br2 A OH O B as /H
-

C. HOC(CH2)2CH2OH. D. A, B, C u ng.
O 2 , C Cu

O 2 , Mn D. Vy D l D. CH3COOH.

2+

A. CH3CH2OH. B. CH3CHO. Cu 61: Cho s chuyn ha sau Chn cu tr li sai A. A5 c CTCT l HOOCCOOH. C. A2 l mt iol. Cu 62: Cho chui bin ha sau :
C2H5OH

C. CH3COCH3.

Br2 C2H4 A1 NaOH A2 CuO A3 Cu(OH) 2 A4 H 2SO 4 A5. , NaOH

B. A4 l mtianehit. D. A5 l mt iaxit.
A C2H5OH

C2H5OH

a. Cht A c th l A. natri etylat. B. anehit axetic. C. etyl axetat. D. A, B, C u ng. b. Cht B c th l A. etilen. B. tinh bt. C. glucoz. D. A, B, C u sai. c. Cht C c th l A. etanal. B. axetilen. C. etylbromua.D. A, C u ng. Cu 63: Mt hp cht c thnh phn l 40% C ; 6,7% H v 53,3% O. Hp cht c CTGN l A. C6H8O. B. C2H4O. C. CH2O. D. C3H6O. Cu 64: Pht biu ng l A. Axit cha no khi chy lun cho s mol CO2 ln hn s mol H2O. B. anehit tc dng vi H2 (xc tc Ni) lun to ancol bc nht. C. anehit va c tnh kh va c tnh oxi ha. D. A, B, C u ng. Copyright Mr.Caoduan Trang 11

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Cu 65: Cho cc cht sau : (1) CH2=CHCH2OH ; (2) CH3CH2CHO ; (3) CH3COCH3. Pht biu ng l A. 1, 2, 3 l cc ng phn. B. 3 tc dng vi H2 (xc tc Ni) to 1 ancol bc 2. C. 1, 2 tc dng vi H2 (xc tc Ni) u to ra 1 ancol. D. A, B, C u ng. Cu 66: Cho 4 hp cht c CTPT l M : C3H6O ; N : C3H6O2 ; P : C3H4O ; Q : C3H4O2. Bit : M v P cho phn ng trng gng ; N v Q phn ng c vi dung dch NaOH ; Q phn ng vi H2 to thnh N ; oxi ha P thu c Q. a. M v P theo th t l A. C2H5COOH ; CH2=CHCOOH. B. C2H5CHO ; CH2=CHCHO. C. CH2=CHCOOH ; C2H5COOH . D. CH2=CHCHO ; C2H5CHO. b. N v Q theo th t l A. C2H5COOH ; CH2 = CHCOOH. B. CH2=CHCOOH ; C2H5COOH. C. C2H5CHO ; CH2=CHCHO. D. CH2=CHCHO ; C2H5CHO. Cu 67: Cho cc cht sau: (1) CH2=CHCH2OH ; (2) HOCCH2CHO ; (3) HCOOCH=CH2. Pht biu ng l A. 1, 2, 3 tc dng c vi Na. B. Trong A, B, C c 2 cht cho phn ng trng gng. C. 1, 2, 3 l cc ng phn. D. 1, 2, 3 chy u cho s mol H2O b hn s mol CO2. Cu 68: Hai hp cht hu c X, Y c cng cng thc phn t C 3H6O2. C X v Y u tc dng vi Na ; X tc dng c vi NaHCO3 cn Y c kh nng tham gia phn ng trng bc. Cng thc cu to ca X v Y ln lt l A. C2H5COOH v HCOOC2H5. B. HCOOC2H5 v HOCH2OCH3. C. HCOOC2H5 v HOCH2CH2CHO. D. C2H5COOH v CH3CH(OH)CHO. Cu 69: Cho dy cc cht : HCHO, CH3COOH, HCOONa, HCOOH, C2H5OH, HCOOCH3. S cht trong dy tham gia phn ng trng gng l A. 3. B. 6. C. 4. D. 5. Cu 70: Cho cc cht sau : phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 4. B. 3. C. 2. D. 1. Cu 71: Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi: Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng Na. Cng thc cu to ca X1, X2 ln lt l A. CH3COOH, CH3COOCH3. B. (CH3)2CHOH, HCOOCH3. C. HCOOCH3, CH3COOH. D. CH3COOH, HCOOCH3. Cu 72: Cho tt c cc ng phn mch h, c cng cng thc phn t C2H4O2 ln lt tc dng vi : Na, NaOH, NaHCO3. S phn ng xy ra l A. 2. B. 5. C. 4. D. 3. Cu 73: Cho cc cht sau : CH3CH2CHO (1) ; CH2=CHCHO (2) ; CHCCHO (3) ; CH2=CHCH2OH (4) ; (CH3)2CHOH (5). Nhng cht phn ng hon ton vi lng d H2 (Ni, to) cng to ra mt sn phm l A. (2), (3), (4), (5). B. (1), (2), (4), (5). C. (1), (2), (3). D. (1), (2), (3), (4). Copyright Mr.Caoduan Trang 12

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 74: Cho cc hp cht hu c : C2H4 ; C2H2 ; CH2O ; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. a. S cht tc dng c vi dung dch AgNO3/NH3 to ra Ag l A. 2. B. 4. C. 3. D. 5. b. S cht tc dng c vi dung dch AgNO3/NH3 to ra kt ta l A. 2. B. 4. C. 3. D. 5. Cu 75: Co th phn bit 3 lo mt nhan cha: HCOOH ; CH3COOH ; C2H5OH vi hoa cht nao di y ? A. dd AgNO3/NH3. B. NaOH. C. Na. D. Cu(OH)2/OH-. Cu 76: Chi dung thuc th nao di y co th phn bit 4 lo mt nhan cha : fomon ; axit fomic ; axit axetic ; ancol etylic ? A. dd AgNO3/NH3. B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 77: Chi dung thuc th nao di y co th phn bit 4 lo mt nhan cha : etylen glicol ; axit fomic ; fomon ; ancol etylic ? A. dd AgNO3/NH3 B. CuO. C. Cu(OH)2/OH-. D. NaOH. Cu 78: Chi dung quy tim va nc brom co th phn bit c nhng cht no sau y ? A. axit fomic ; axit axetic ; axit acrylic ; axit propionic. B. Axit axetic; axit acrylic; anilin; toluen; axit fomic. C. Ancol etylic; ancol metylic; axit axetic; axit propionic. D. Ancol etylic; ancol metylic ; phenol ; anilin. Cu 79: phn bit 3 mu ha cht ring bit : phenol, axit acrylic, axit axetic bng mt thuc th, ngi ta dng thuc th A. dung dch Na2CO3. B. CaCO3. C. dung dch Br2. D. dung dch AgNO3/NH3. Cu 80: phn bit axit propionic v axit acrylic ta dng A. dung dch Na2CO3. B. dung dch Br2. C. dung dch C2H5OH. D. dung dch NaOH. Cu 81: C th phn bit CH3CHO v C2H5OH bng phn ng vi A. Na. B. Cu(OH)2/NaOH. C. AgNO3/NH3. D. Tt c u ng. Cu 82: phn bit 3 dung dch ring bit : axit axetic, axit acrylic, axit fomic ngi ta dng theo th t cc thuc th sau A. dung dch Br2/CCl4. B. dung dch Br2/H2O. C. dung dch Na2CO3. D. dung dch AgNO3/NH3 d. Cu 83: phn bit HCOOH v CH3COOH ta dng A. Na. B. AgNO3/NH3. C. CaCO3. D. NaOH. Cu 84: Trng gng hon ton hp cht hu c X bng AgNO3/NH3 thu c hn hp sn phm ch gm cc cht v c. X c cu to A. HCHO. B. HCOONH4. C. HCOOH. D. Tt c u ng. Cu 85: C th phn bit HCOOCH3 v CH3COOH bng A. AgNO3/NH3 B. CaCO3. C. Na. D. Tt c u ng. Cu 86: Cht to c kt ta gch khi un nng vi Cu(OH)2 l A. HCHO. B. HCOOCH3. C. HCOOH. D. Tt c u ng. Cu 87: Ch dng 1 ha cht no sau y phn bit cc dung dch : ancol etylic, glixerol, fomalin ? A. Cu(OH)2 , toC. B. Na. C. AgNO3 / NH3. D. A, B, C u ng. Copyright Mr.Caoduan Trang 13

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 88: Hiro hoa hoan toan 2,9 gam mt anehit A c 3,1 gam ancol. A co cng thc phn t la A. CH2O. B. C2H4O. C. C3H6O. D. C2H2O2. o Cu 89: Th tch H2 (0 C v 2 atm) va tc dng vi 11,2 gam anehit acrylic l A. 4,48 lt. B. 2,24 lt. C. 0,448 lt. D. 0,336 lt. Cu 90: Cho 14,6 gam hn hp 2 anehit n chc, no lin tip tc dng ht vi H2 to 15,2 gam hn hp 2 ancol. a. Tng s mol 2 ancol l A. 0,2 mol. B. 0,4 mol. C. 0,3 mol. D. 0,5 mol. b. Khi lng anehit c KLPT ln hn l A. 6 gam. B. 10,44 gam. C. 5,8 gam. D. 8,8 gam. Cu 91: Cho 7 gam cht A c CTPT C4H6O tc dng vi H2 d c xc tc to thnh 5,92 gam ancol isobutylic. a. Tn ca A l A. 2-metyl propenal. B. 2-metylpropanal. C. but-2-en-1-ol. D. but-2-en-1-al. b. Hiu sut ca phn ng l A. 85%. B. 75%. C. 60%. D. 80%. Cu 92: Oxi ha 1,76 gam mt anehit n chc c 2,4 gam mt axit tng ng. Anehit l A. anehit acrylic. B. anehit axetic. C. anehit propionic. D. anehit fomic. Cu 93: Oxi hoa 17,4 gam mt anehit n chc c 16,65 gam axit tng ng (H = 75%). Anehit co cng thc phn t la A. CH2O. B. C2H4O. C. C3H6O. D. C3H4O. Cu 94: t chy a mol mt anehit A thu c a mol CO2. Anehit ny c th l A. CH3CHO. B. HCHO. C. C2H5CHO. D. A, B, C u ng. Cu 95: t chy hon ton 1,46 gam hn hp 2 anehit no, n chc ng ng k tip thu c 1,568 lt CO2 (ktc). a. CTPT ca 2 anehit l A. CH3CHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H5CHO v C3H7CHO. D. Kt qu khc. b. Khi lng gam ca mi anehit l A. 0,539 v 0,921. B. 0,88 v 0,58. C. 0,44 v 1,01. D. 0,66 v 0,8. Cu 96: t chay hoan toan mt anehit n chc no, mch h A cn 17,92 lit O2 (ktc). Hp thu ht san phm chay vao nc vi trong c 40 gam kt tua va dung dich X. un nong dung dich X lai co 10 gam kt tua na. Cng thc phn t A la A. CH2O. B. C2H4O. C. C3H6O. D. C4H8O. Cu 97: X, Y, Z, T la 4 anehit no h n chc ng ng lin tip, trong o MT = 2,4MX. t chay hoan toan 0,1 mol Z ri hp thu ht san phm chay vao binh ng dung dich Ca(OH)2 d thy khi lng dung dich tng hay giam bao nhiu gam? A. tng 18,6 gam. B. tng 13,2 gam. C. Giam 11,4 gam. D. Giam 30 gam. Cu 98: t chay hoan toan mt lng aehit A cn va u 2,52 lit O2 (ktc), c 4,4 gam CO2 va 1,35 gam H2O. A co cng thc phn t la A. C3H4O. B. C4H6O. C. C4H6O2. D. C8H12O. Copyright Mr.Caoduan Trang 14

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 99: t chy hon ton 1 anehit A mch h, no thu c CO2 v H2O theo t l
n A : n C O2 : n H2O = 1 : 3 : 2 . Vy A l

A. CH3CH2CHO. B. OHCCH2CHO. C. HOCCH2CH2CHO. D. CH3CH2CH2CH2CHO. Cu 100: Cho 1,97 gam dung dch fomalin tc dng vi dung dch AgNO3/NH3 d thu c 10,8 gam Ag. Nng % ca anehit fomic trong fomalin l A. 49%. B. 40%. C. 50%. D. 38,07%. Cu 101: Hp cht A cha 1 loi nhm chc v phn t ch cha cc nguyn t C, H, O trong oxi chim 37,21% v khi lng, 1 mol A trng gng hon ton cho 4 mol Ag. Vy A l A. C2H4(CHO)2. B. HCHO. C. HOCCH2CHO. D. CH3CHO. Cu 102: Cho 10,4 gam hn hp gm metanal v etanal tc dng vi mt lng va d AgNO 3/NH3 thu c 108 gam Ag. Khi lng metanal trong hn hp l A. 4,4 gam. B. 3 gam. C. 6 gam. D. 8,8 gam. Cu 103: Cho bay hi ht 5,8 gam mt hp cht hu c X thu c 4,48 lt hi X 109,2 oC v 0,7 atm. Mt khc khi cho 5,8 gam X phn ng ca AgNO3/NH3 d to 43,2 gam Ag. CTPT ca X l A. C2H2O2. B. C3H4O2. C. CH2O. D. C2H4O2. Cu 104: Cho 5,8 gam anehit A tc dng ht vi mt lng d AgNO3/NH3 thu c 43,2 gam Ag. Tm CTPT ca A A. CH3CHO. B. CH2=CHCHO. C. OHCCHO. D. HCHO. Cu 105: Cho 8,7 gam anehit X tac dung hoan toan vi lng dung dich AgNO3/NH3 (d) c 64,8 gam Ag. X co cng thc phn t la A. CH2O. B. C2H4O. C. C2H2O2. D. C3H4O. Cu 106: 8,6 gam anehit mach khng nhanh A tac dung vi lng (d) dung dich AgNO3/NH3 tao 43,2 gam Ag. A co cng thc phn t la A. CH2O. B. C3H4O. C. C4H8O. D.C4H6O2. Cu 107: X la hn hp gm 2 anehit ng ng lin tip. Cho 0,1 mol X tac dung vi lng d dung dich AgNO3/NH3 c 25,92 gam bac. % s mol anehit co s cacbon nho hn trong X la A. 20%. B. 40%. C. 60%. D. 75%. Cu 108: Cho 0,1 mol mt anehit X tac dung ht vi dung dich AgNO3/NH3 (d) c 43,2 gam Ag. Hiro hoa hoan toan X c Y. Bit 0,1 mol Y tac dung va u vi Na va u c 12 gam rn. X co cng thc phn t la A. CH2O. B. C2H2O2. C. C4H6O. D. C3H4O2. Cu 109: X la hn hp 2 anehit n chc. Chia 0,12 mol X thanh hai phn bng nhau : - t chay ht phn 1 c 6,16 gam CO2 va 1,8 gam H2O. - Cho phn 2 tac dung vi lng d dung dich AgNO3/NH3 c 17,28 gam bac. X gm 2 anehit co cng thc phn t la A. CH2O va C2H4O. B. CH2O va C3H6O. C. CH2O va C3H4O. D. CH2O va C4H6O. Cu 110: Oxi ha 48 gam ancol etylic bng K2Cr2O7 trong H2SO4 c, tch ly sn phm hu c ra ngay khi mi trng v dn vo dung dch AgNO3/NH3 d thy c 123,8 gam Ag. Hiu sut ca phn ng oxi ha l A. 72,46 %. B. 54,93 %. C. 56,32 %. D. Kt qu khc. Copyright Mr.Caoduan Trang 15

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 111: Dn m gam hi ancol etylic qua ng ng CuO d un nong. Ngng tu phn hi thoat ra c hn hp X gm anehit, ancol etylic va H2O. Bit lng X tac dung vi Na (d) giai phong 3,36 lit H2 ( ktc), con 1/2 lng X con lai tac dung vi d dung dich AgNO3/NH3 tao c 25,92 gam Ag. a. Gia tri m la A. 13,8 gam B. 27,6 gam C. 16,1 gam D. 6,9 gam b. Hiu sut phn ng oxi ho ancol etylic l A. 20%. B. 40%. C. 60%. D. 75%. Cu 112: Cho m gam ancol n chc no (h) X qua ng ng CuO (d) nung nong. Sau khi phan ng hoan toan thy khi lng cht rn trong ng giam 0,32 gam. Hn hp hi thu c (gm hi anehit va hi nc) co ti khi so vi H2 la 19. Gia tri m la A. 1,2 gam. B. 1,16 gam. C. 0,92 gam. D.0,64 gam. Cu 113: X la hn hp 2 ancol n chc ng ng lin tip. Cho 0,3 mol X tac dung hoan toan vi CuO un nong c hn hp Y gm 2 anehit. Cho Y tac dung vi lng dung dich AgNO3/NH3 c 86,4 gam Ag. X gm A. CH3OH va C2H5OH. B. C3H7OH va C4H9OH. C. C2H5OH v C3H7OH. D. C3H5OH va C4H7OH. Cu 114: Dn 4 gam hi ancol n chc A qua ng ng CuO, nung nong. Ngng tu phn hi thoat ra c hn hp X. Cho X tac dung vi lng d dung dich AgNO3/NH3 c 43,2 gam bac. A la A. ancol metylic. B. ancol etylic.C. ancol anlylic. D. ancol benzylic. Cu 115: X la hn hp gm mt ancol n chc no, mch h A va mt anehit no, mch h n chc B (A va B co cung s cacbon). t chay hoan toan 13,4 gam X c 0,6 mol CO2 va 0,7 mol H2O. S nguyn t C trong A, B u la A. 1. B. 2. C. 3. D. 4. Cu 116: Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, un nng. Sau khi cc phn ng xy ra hon ton, khi lng Ag to thnh l A. 43,2 gam. B. 10,8 gam. C. 64,8 gam. D. 21,6 gam. Cu 117: Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. Cu 118: Hiro ho hon ton hn hp M gm hai anehit X v Y no, n chc, mch h, k tip nhau trong dy ng ng (MX < My), thu c hn hp hai ancol c khi lng ln hn khi lng M l 1 gam. t chy hon ton M thu c 30,8 gam CO2. Cng thc v phn trm khi lng ca X ln lt l A. HCHO v 50,56%. B. CH3CHO v 67,16%. C. CH3CHO v 49,44%. D. HCHO v 32,44%. Cu 119: Cho 0,1 mol anehit X tc dng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO. B. OHCCHO. C. CH3CHO. D. CH3CH(OH)CHO.

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Cu 120: Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HOCH2CHO v HOCH2CH2CHO. B. HOCH2CH2CHO v HOCH2CH2CH2CHO. C. HCOOCH3 v HCOOCH2CH3. D. HOCH(CH3)CHO v HOOCCH2CHO. Cu 121: Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. HCOOC2H5. B. CH3COOCH3. C. HOOCCHO. D. OHCCH2CH2OH. Cu 122: Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 10,5. B. 8,8. C. 24,8. D. 17,8. Cu 123: Cho m gam hn hp X gm hai ru (ancol) no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c mt hn hp rn Z v mt hn hp hi Y (c t khi hi so vi H2 l 13,75). Cho ton b Y phn ng vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8. B. 8,8. C. 7,4. D. 9,2. Cu 124: Cho 3,6 gam anehit n chc X phn ng hon ton vi mt lng d Ag2O (hoc AgNO3) trong dung dch NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lt NO2 (sn phm kh duy nht, ktc). Cng thc ca X l A. C3H7CHO. B. HCHO. C. C4H9CHO. D. C2H5CHO. Cu 125: Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d Ag2O (hoc AgNO3) trong dung dch NH3, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 76,6%. B. 80,0%. C. 65,5%. D. 70,4%. Cu 126: Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n-3CHO (n 2). B. CnH2n-1CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n(CHO)2 (n 0). Cu 127: Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H 2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 35,00%. B. 65,00%. C. 53,85%. D. 46,15%. Cu 128: Hn hp X gm hai ancol no, n chc, mch h, k tip nhau trong dy ng ng. Oxi ho hon ton 0,2 mol hn hp X c khi lng m gam bng CuO nhit thch hp, thu c hn hp sn phm hu c Y. Cho Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Gi tr ca m l A. 13,5. B. 8,1. C. 8,5. D. 15,3. Copyright Mr.Caoduan Trang 17

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 129: 1,72 gam hn hp anehit acrylic v anehit axetic tham gia phn ng cng va 1,12 lt H 2 (ktc). Cho thm 0,696 gam anehit B l ng ng ca anehit fomic vo 1,72 gam hn hp 2 anehit trn ri cho hn hp thu c tham gia phn ng trng bc hon ton c 10,152 gam Ag. Cng thc cu to ca B l A. CH3CH2CHO. B. C4H9CHO. C. CH3CH(CH3)CHO. D. CH3CH2CH2CHO. Cu 130*: 17,7 gam hn hp X gm 2 anehit n chc phn ng hon ton vi dung dch AgNO 3 trong NH3 (dng d) c 1,95 mol Ag v dung dch Y. Ton b Y tc dng vi dung dch HCl d c 0,45 mol CO2. Cc cht trong hn hp X l A. C2H3CHO v HCHO. B. C2H5CHO v HCHO. C. CH3CHO v HCHO. D. C2H5CHO v CH3CHO. Cu 131: A la axit cacboxylic n chc cha no (1 ni i C=C). A tac dung vi brom cho san phm cha 65,04% brom (theo khi lng). Vy A co cng thc phn t la A. C3H4O2. B. C4H6O2. C. C5H8O2. D. C5H6O2. Cu 132: Mun trung ha 6,72 gam mt axit hu c A cn dng 200 gam dung dch NaOH 2,24%. A l A. CH3COOH. B. CH3CH2COOH. C. HCOOH. D. CH2=CHCOOH. Cu 133: trung hoa 40 ml gim n cn 25 ml dung dich NaOH 1M. Bit khi lng ring cua gim la 1 g/ml. Vy mu gim n nay co nng la A. 3,5%. B. 3,75%. C. 4%. D. 5%. Cu 134: Trung hoa 9 gam axit cacbonxylic A bng NaOH va u c can dung dich c 13,4 gam mui khan. A co cng thc phn t la A. C2H4O2. B. C2H2O4. C. C3H4O2. D. C4H6O4. Cu 135: Trung hoa 2,7 gam axit cacboxylic A cn va u 60 ml dung dich NaOH 1M. A co cng thc phn t la A. C2H4O2. B. C3H4O2. C. C4H6O4. D. C2H2O4. Cu 136: Trung ha hon ton 1,8 gam mt axit hu c n chc bng dung dch NaOH va ri c cn dung dch sau phn ng c 2,46 gam mui khan. Axit l A. HCOOH. B. CH2=CHCOOH. C. CH3CH2COOH. D. CH3COOH. Cu 137: Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn khan. Cng thc phn t ca X l A. C2H5COOH. B. CH3COOH. C. HCOOH. D. C3H7COOH. Cu 138: A v B l 2 axit cacboxylic n chc. Trn 1,2 gam A vi 5,18 gam B c hn hp X. trung ha ht X cn 90 ml dung dch NaOH 1M. A, B ln lt l A. Axit propionic, axit axetic. B. axit axetic, axit propionic. C. Axit acrylic, axit propionic. D. Axit axetic, axit acrylic. Cu 139: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 400 ml dung dch NaOH 1M. Tng khi lng mui thu c sau phn ng l A. 3,54 gam. B. 4,46 gam. C. 5,32 gam. D. 11,26 gam. Cu 140: Cho 5,76 gam axit hu c X n chc, mch h tc dng ht vi CaCO3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH2=CHCOOH. B. CH3COOH. C. HCCCOOH. D. CH3CH2COOH. Copyright Mr.Caoduan Trang 18

ANEHIT-XETON-AXIT CACBOXYLIC

Cu 141: Cho 0,1 mol axit hu c X tc dng vi 11,5 gam hn hp Na v K thu c 21,7 gam cht rn v thy thot ra 2,24 lt kh H2 (ktc). Cng thc cu to ca X l A. (COOH)2. B. CH3COOH. C. CH2(COOH)2. D. CH2=CHCOOH. Cu 142: Cho 16,6 gam hn hp gm HCOOH, CH3COOH tc dng ht vi Mg thu c 3,36 lt H2 (ktc). Khi lng CH3COOH l A. 12 gam. B. 9 gam. C. 6 gam. D. 4,6 gam. Cu 143: X la hn hp gm HCOOH va CH3COOH (ti l mol 1:1). Ly 21,2 gam X tac dung vi 23 gam C2H5OH (xuc tac H2SO4 c, un nong) thu c m gam hn hp este (hiu sut este hoa u at 80%). Gia tri m la A. 40,48 gam. B. 23,4 gam. C. 48,8 gam. D. 25,92 gam. Cu 144: un nong 6 gam CH3COOH vi 9,2 gam C2H5OH (co H2SO4 c lam xuc tac) n khi phan ng at ti trang thai cn cn bng thi c 5,5 gam este. Hiu sut phan ng este hoa la A. 55%. B. 62,5%. C. 75%. D. 80%. Cu 145: Cho 0,3 mol axit X n chc trn vi 0,25 mol ancol etylic em thc hin phn ng este ha thu c thu c 18 gam este. Tch ly lng ancol v axit d cho tc dng vi Na thy thot ra 2,128 lt H2. Vy cng thc ca axit v hiu sut phn ng este ha l A. CH3COOH, H% = 68%. B. CH2=CHCOOH, H%= 78%. C. CH2=CHCOOH, H% = 72%. D. CH3COOH, H% = 72%. Cu 146: Oxi ho anehit OHCCH2CH2CHO trong iu kin thch hp thu c hp cht hu c X. un nng hn hp gm 1 mol X v 1 mol ancol metylic vi xc tc H 2SO4 c thu c 2 este Z v Q (MZ < MQ) vi t l khi lng mZ : mQ = 1,81. Bit ch c 72% ancol chuyn thnh este. S mol Z v Q ln lt l A. 0,36 v 0,18. B. 0,48 v 0,12. C. 0,24 v 0,24. D. 0,12 v 0,24. Cu 147: t chy hon ton 2,22 gam mt axit hu c no A thu c 1,62 gam H2O. A l A. C3H7COOH. B. C2H5COOH. C. HCOOH. D. CH3COOH. Cu 148: t chay hoan toan 0,1 mol axit n chc cn V lit O2 ktc, thu c 0,3 mol CO2 va 0,2 mol H2O. Gia tri V la A. 6,72 lit. B. 8,96 lit. C. 4,48 lit. D. 5,6 lit. Cu 149: t chay hoan toan mt axit A thu c 0,2 mol CO2 va 0,15 mol H2O. A co cng thc phn t la A. C3H4O4. B. C4H8O2. C. C4H6O4. D. C5H8O4. Cu 150: t chy hon ton 4,38 gam mt axit E no, mch thng thu c 4,032 lt CO 2 (kc) v 2,7 gam H2O. CTCT ca E l A. CH3COOH. B. C17H35COOH. C. HOOC(CH2)4COOH. D. CH2=C(CH3)COOH. Cu 151: t chay hoan toan 0,1 mol axit cacboxylic A thu c cha n 8 gam hn hp CO2 va H2O. A la A. axit fomic. B. axit axetic. C. axit acrylic. D. axit oxalic. Cu 152: Z l mt axit hu c. t chy 0,1 mol Z cn 6,72 lt O2 (ktc). CTCT ca Z l A. CH3COOH. B. CH2=CHCOOH. C. HCOOH. D. Kt qu khc. Cu 153: t chy ht 1 th tch hi axit hu c A c 3 th tch hn hp CO2 v hi nc khi o cng iu kin. CTPT ca A l A. HCOOH. B. CH3COOH. C. HOOCCOOH. D. HOOCCH2COOH.

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ANEHIT-XETON-AXIT CACBOXYLIC

Cu 154: t chy hon ton 0,44 gam mt axit hu c, sn phm chy cho hp th hon ton vo bnh 1 ng P2O5, bnh 2 ng dung dch KOH. Sau th nghim thy khi lng bnh 1 tng 0,36 gam v bnh 2 tng 0,88 gam. CTPT ca axit l A. C4H8O2. B. C5H10O2. C. C2H6O2. D. C2H4O2. Cu 155: t chy ht 10ml th tch hi mt hp cht hu c A cn dng 30 ml O2, sn phm thu c ch gm CO2 v H2O c th tch bng nhau v u bng th tch O2 phn ng. CTPT ca A l A. C2H4O2. B. C3H6O3. C. C3H6O2. D. C4H8O2. Cu 156: X la hn hp 2 axit cacboxylic no, h, phn t mi axit cha khng qua 2 nhom -COOH. t chay hoan toan 9,8 gam X c 11 gam CO2 va 3,6 gam H2O. X gm A. HCOOH va CH3COOH. B. HCOOH va HOOCCH2COOH. C. HCOOH va HOOCCOOH. D. CH3COOH va HOOCCH2COOH. Cu 157: Cc sn phm thu c khi t chy hon ton 3 gam axit hu c X c dn ln lt qua bnh 1 ng H2SO4 c v bnh 2 ng dung dch NaOH. Sau th nghim thy khi lng bnh 1 tng 1,8 gam v khi lng bnh 2 tng 4,4 gam. CTCT ca A l A. HCOOH. B. C2H5COOH. C. CH3COOH. D. A hoc B hoc C. Cu 158: Oxi hoa 0,125 mol ancol n chc A bng 0,05 mol O2 (xt, to) c 5,6 gam hn hp X gm axit cacboxylic ; anehit ; ancol d va nc. A co cng thc phn t la A. CH4O. B. C2H6O. C. C3H6O. D. C3H8O. Cu 159: Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOCCOOH v 42,86%. B. HOOCCOOH v 60,00%. C. HOOCCH2COOH v 70,87%. D. HOOCCH2COOH v 54,88%. Cu 160: Cht A c ngun gc t thc vt v thng gp trong i sng (cha C, H, O), mch h. Ly cng s mol ca A cho phn ng ht vi Na2CO3 hay vi Na th thu c s mol CO2 bng 3/4 s mol H2. Cht A l A. axit malic : HOOCCH(OH)CH2COOH. B. axit xitric : HOOCCH2C(OH)(COOH)CH2COOH. C. axit lauric : CH3(CH2)10COOH. D. axit tactaric : HOOCCH(OH)CH(OH)COOH. Cu 161: Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO 3 th u sinh ra a mol kh. Cht X l A. ancol o-hiroxibenzylic. B. axit aipic. C. axit 3-hiroxipropanoic. D. etylen glicol. Cu 162: Chia 0,3 mol axit cacobxylic A thanh hai phn bng nhau. - t chay phn 1 c 19,8 gam CO2. - Cho phn 2 tac dung hoan toan vi 0,2 mol NaOH, thy sau phan ng khng con NaOH. Vy A co cng thc phn t la A. C3H6O2. B. C3H4O2. C. C3H4O4. D. C6H8O4. Cu 163: Cho 10 gam hn hp X gm HCHO va HCOOH tac dung vi lng (d) dung dich AgNO3/NH3 c 99,36 gam bac. % khi lng HCHO trong hn hp X la A. 54%. B. 69%. C. 64,28%. D. 46%.

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ANEHIT-XETON-AXIT CACBOXYLIC

Cu 164: trung hoa a mol axit cacboxylic A cn 2a mol NaOH. t chay hoan toan a mol A thu c 3a mol CO2. A co cng thc phn t la A. C3H4O2. B. C3H6O2. C. C6H10O4. D. C3H4O4. Cu 165: t chay hoan toan 3,12 gam axit cacboxylic A c 3,96 gam CO2. Trung hoa cung lng axit nay cn 30 ml dung dich NaOH 2M. A co cng thc phn t la A. C2H4O2. B. C4H6O2. C. C3H4O2. D. C3H4O4. Cu 166: Hn hp X gm 2 axit no A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt CO2 (kc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. CTCT ca 2 axit l A. HCOOH v C2H5COOH. B. CH3COOH v C2H5COOH. C. HCOOH v HOOCCOOH. D. CH3COOH v HOOCCH2COOH. Cu 167: Trung ha a mol axit hu c A cn 2a mol NaOH. t chy ht a mol A c 2a mol CO2. A l A. CH3COOH. B. HOOCCOOH. C. axit n chc no. D. axit n chc khng no. Cu 168: Hp cht hu c E mch h c CTPT C3H6O3 c nhiu trong sa chua. E c th tc dng vi Na v Na2CO3, cn khi tc dng vi CuO nung nng th to ra hp cht hu c khng tham gia phn ng trng gng. CTCT ca E l A. CH3COOCH2OH. B. CH3CH(OH)COOH. C. HOCH2COOCH3. D. HOCH2CH2COOH. Cu 169: t chy hon ton 0,1 mol cht X l mui Na ca mt axit hu c thu c 0,15 mol CO2, hi H2O v Na2CO3. CTCT ca X l A. C3H7COONa.B. CH3COONa. C. CH3COONa. D. HCOONa. Cu 170: Hn hp X gm 0,01 mol HCOONa v a mol mui natri ca hai axit no n chc mch h l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO 2, hi nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2 tng nhiu hn bnh mt l 3,51 gam. Phn cht rn Y cn li sau khi t l Na2CO3 cn nng 2,65 gam. Cng thc phn t ca hai mui natri l A. C2H5COONa v C3H7COONa. B. C3H7COONa v C4H9COONa. C. CH3COONa v C2H5COONa. D. CH3COONa v C3H7COONa. Cu 171: Khi lng axit axetic thu c khi ln men 1 lit ancol etylic 8o la bao nhiu ? Cho d = 0,8 g/ml va hiu sut phan ng at 92%. A. 76,8 gam. B. 90,8 gam. C. 73,6 gam. D. 58,88 gam. Cu 172: Thc hin phn ng oxi ha m gam ancol etylic nguyn cht thnh axit axetic (hiu sut phn ng t 25%) thu c hn hp Y, cho Y tc dng vi Na d thu c 5,6 lt H2 (ktc). Gi tr ca m l A. 18,4 gam. B. 9,2 gam. C. 23 gam. D. 4,6 gam. Cu 173: Cho s phn ng sau: + HCN + H3O+, to + H2SO4 , to xt, to, p CH3CH=O A B C3H4O2 C C3H4O2 c tn l A. axit axetic. B. axit metacrylic. C. axit acrylic. D. anehit acrylic.
,ete Cu 174: Cho s sau : C2H5Br Mg A CO2 B + HCl C .

C c cng thc l A. CH3COOH.

B. CH3CH2COOH.

C. CH3CH2OH.

D. CH3CH2CH2COOH. Trang 21

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ANEHIT-XETON-AXIT CACBOXYLIC

Cu 175: Cho s chuyn ho sau: H C O O N a

C2H5O H

(C O O H2)

Cc cht A, B, D c th l A. H2 ; C4H6 ; C2H4(OH)2. B. H2 ; C2H4 ; C2H4(OH)2. C. CH4 ; C2H2 ; (CHO)2. D. C2H6 ; C2H4(OH)2. Cu 176 : Cho 19,8 gam mt anehit n chc A phan ng hoan toan vi dung dich AgNO3/NH3 (d). Lng Ag sinh ra phan ng ht vi dung dich HNO3 loang c 6,72 lit NO ktc. A co cng thc phn t la A. C2H4O. B. C3H6O. C. C3H4O. D. C4H8O. Cu 177: Cho 10,90 gam hn hp gm axit acrylic v axit propionic phn ng hon ton vi Na thot ra 1,68 lt kh (ktc). Nu cho hn hp trn tham gia phn ng cng H2 hon ton th khi lng sn phm cui cng l A. 11,1 gam. B. 7,4 gam. C. 11,2 gam. D. 11,0 gam. Cu 178: Cho 3,15 gam hn hp X gm axit axetic, axit acrylic, axit propionic va lm mt mu hon ton dung dch cha 3,2 gam brom. trung han ton 3,15 gam hn hp X cn 90 ml dd NaOH 0,5M. Thnh phn phn trm khi lng ca axit axetic trong hn hp X l A. 35,24%. B. 45,71%. C. 19,05%. D. 23,49%. Cu 179: Ha tan 26,8 gam hn hp hai axit cacboxylic no, n chc, mch h vo nc c dung dch X. Chia X thnh hai phn bng nhau. Cho phn 1 phn ng hon ton vi dung dch AgNO 3/NH3 d thu c 21,6 gam bc kim loi. trung ha hon ton phn 2 cn 200,0 ml dung dch NaOH 1,0M. Cng thc ca hai axit l A. HCOOH, C3H7COOH. B. CH3COOH, C2H5COOH. C. CH3COOH, C3H7COOH. D. HCOOH, C2H5COOH. Cu 180: Cho 13,4 gam hn hp X gm hai axit no, n chc, mch h, k tip nhau trong cng dy ng ng tc dng vi Na d, thu c 17,8 gam mui. Khi lng ca axit c s nguyn t cacbon t hn c trong X l A. 3,0 gam. B. 4,6 gam. C. 7,4 gam. D. 6,0 gam.

ANEHIT-XETON-AXIT CACBOXILIC

1B 11B 21A 31A 41A 51B 61B 71D 81D 91AD 101A 111BB

2C 12B 22C 32D 42D 52B 62DAD 72B 82B 92B 102C 112A

3C 13A 23C 33A 43D 53C 63C 73D 83B 93C 103A 113A

4C 14A 24B 34D 44A 54D 64D 74CB 84D 94B 104C 114A

5D 6D 7A 15A 16BD 17D 25C 26C 27A 35C 36C 37C 45C 46C 47C 55B 56C 57A 65D 66BA 67B 75D 76C 77C 85D 86D 87A 95AB 96C 97C 105C 106D 107A 115B 116C 117B Copyright Mr.Caoduan

8D 18A 28C 38D 48D 58A 68D 78B 88A 98C 108D 118A

9C 19C 29A 39D 49A 59BD 69C 79C 89A 99B 109C 119B

10D 20B 30A 40D 50C 60D 70A 80B 90CC 100D 110B 120A Trang 22

ANEHIT-XETON-AXIT CACBOXYLIC

121A 131B 141C 151A 161C 171A

122D 132A 142A 152B 162C 172A

123A 133B 143D 153C 163A 173C

124A 134B 144B 154A 164D 174B

125B 135D 145C 155B 165D 175B

126B 136D 146A 156B 166C 176A

127D 137B 147B 157C 167B 177A

128C 138B 148A 158A 168B 178C

129A 139D 149C 159A 169B 179A

130A 140A 150C 160B 170A 180D

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