i hc hng hi 1999 Cu I: 1.1.

Cho bit cc loi nguyn liu chnh dng sn xut gang; nguyn
tc v cc phn ng ho hc xy ra trong qu trnh sn xut gang? (dung dch NH3) A + AgNO3 B + C + Ag (t0) B + NaOH D + H2O + NH3 (t0) D + NaOH E + Na2CO3
CaO

(askt) E + Cl2
0

G + HCl

(t ) G + NaOH CH3OH + H (Cc cht A, B, C H vit dng cng thc cu to vn tt).

Cu II:

Hn hp A gm Mg v kim loi M ho tr 3, ng trc hydro trong dy hot ng ho hc. Ho tan hon ton 1,275 gam A vo 125 ml dung dch B cha ng thi HCl nng C1 (M) v H2SO4 nng C2 (M), thy thot ra 1400 ml lt kh hydro (o iu kin tiu chun) v dung dch D. trung ho hon tin lng axit d trong D cn dng 59 ml dung dch Ba(OH)2 1M. Sau khi trung ho dung dch D cn thu c 0,0375 mol mt cht kt ta khng tan trong HCl. 1. Vit cc phng trnh phn ng dng ion thu gn. 2. Tm C1 v C2 ca dung dch B. 3. Tm nguyn t khi ca kim loi M (AM) v khi lng mi kim loi trong hn hp A em th nghim. Bit rng ho tan 1,35 gam M cn khng qu 200 ml dung dch HCl 1M.

Cu III:

t chy hon ton mt lng hai ru X v Y l hai ng ng lin tip trong dy ng ng r no n chc, thu c 11,2 lt CO2. Cng vi lng hn hp trn cho phn ng vi Na d th thu c 2,24 lt Hydro. Cc th tch kh u o iu kin tiu chun. 1. Xc nh cng thc phn t ca hai ru trn. Tnh thnh phn % khi lng mi ru trong hn hp. 2. Phn t X c s nguyn t ccbon t hn trong phn t Y. Sn phm oxy ho t t ca Y khng tham gia phn ng vi dung dch AgNO3 (c dung dch NH3). + Vit cng thc cu to ca Y. + Vit phng trnh phn ng este ho ca X v Y vi axit Motacrylic (km theo iu kin phn ng nu c). Nu cc sn phm este ny trong thc t. Cu IV A: 1. Hn hp kim loi vn gm Al, Fe v Ag. Hy trnh by phng php ho hc tch mi kim loi trn ra khi hp cht v dng nguyn cht. 2. a. Vit phng trnh phn ng iu ch Anilin t benzen, km theo iu kin phn ng nu c. b. Hy hon thnh s chuyn ho sau dng vit thnh phn ng v gi tn cc cht X, Y v Z: + C2H5OH + HCl + NH3 + HNO3 CH3 CH COOH X Y X Z + N2 + H2O NH2 HCl (xt) Cu IV B: 1. Hn hp Al2O3, Fe2O3 v vn ng. Hy trnh by phng php ho hc tch mi cht trn v dng nguyn cht. 2. Trnh by quy tc Zaixp v tch nc ca ruc v quy tc cng HX vo anken v Maccopnhicp. Vit cng thc cu to cc cht A, B, C , D, E, G trong cc dy chuyn ho sau: H2SO4 , t0 H2O; t0

a. CH3 CH2 CH2 CH2 CH2OH A B 0 H2SO4 , t Br2 (dung dch) b. C5H11OH D CH3 CHBr CHBr CH2 CH3 0 H2SO4 c, t +HCl Cl c. C5H11OH G CH3 - C - CH2 CH3
xc tc CH3

Trng cao ng s phm bc giang 1999 Cu I: 1. Cation R3+ c cu hnh electron lp ngoi cng l 2p6. - Vit cu hnh electron ca R v cho bit v tr ca n trong bng h thng tun hon cc nguyn t ho hc. - Anion X2- cng c cu hnh ging R3+. Cho bit nguyn t X l nguyn t no? Vit cu hnh electron ca X. - Nu tnh cht ho hc c trng ca R v X. Cho v d minh ho. 2. Bng nhng phng php ho hc no ngi ta c th iu ch c Ag t dung dch AgNO3. c Mg t MgCl 2? Vit cc phng trnh phn ng ho hc xy ra. Cu II: 1. ng ng l g? Cc ru etylic, n propilic, iso propylic c phi l ng ng ca nhau khng? Ti sao? - Cc hydrocacbon no di y l ng ng ca nhau: CH2 CH2 H2C CH2 H2 C CH2 CH2 CH2 H2C CH2 H2C CH2 H2C CH 2 CH2 CH CH2 H2C CH CH2 CH3 2. Th no l ru bc I, bc II, bc III? CHo v d. Bng phng php ho hc hy phn bit cc ru . Cu III: Nhit phn hon ton 3,78 gam hn hp gm hai mui Al(NO3)3 v AgNO3 ngi ta thu c 8,4 lt hn hp kh ( ktc) v cht rn A gm mt xt kim loi v mt kim loi. 1. Tnh phn trm mi mui trong hn hp u. 2. Tnh khi lng dung dch NaOH 4M (d = 1,15 gam/ml) c th ho tan ti a lng cht rn A. Cu IV: Cho 4,2 gam mt anehit A n chc, mch h phn ng hon ton vi dung dch AgNO3 trong dung dch NH3 d ngi ta thu c hn hp mui B. Nu cho lng bc to thnh tc dng vi dung dch HNO3 d thu c 3,79 nlt kh NO2 270C v 740 mmHg. 1. Tm cng thc phn t, cng thc cu to ca A. 2. Vit cc phng trnh phn ng iu ch A t N Butan. 3. Nu cc tnh cht ho hc c trng ca A. Cu V A. 1. Cho K, Zn, Fe ln lt vo cc dung dch sau: CuSO4 v ZnCl2. Vit cc phn ng ho hc c th xy ra.

2. Hy vit cc phng trnh phn ng ho hc c th xy ra khi cho axit aminoaxtic ln lt tc dng vi Na, NaOH, HCl, C2H5OH (c H2SO4 c). Cu V b. 1. S thu phn mui l g? C my trng hp mui b thu phn? Cho v d. 2. Vit cc phng trnh phn ng ho hc xy ra theo s sau: Cr2O3 Cr CrCl2 Cr(OH)2 Cr2O3 Na2Cr2O7 Na2CrO4 NaCrO2
Cao ng giao thng vn ti 1999

Cr(OH) 3

Cu I: 1. Gii thch ti sao nhm kim loi bn trong khng kh v nc, nhng rt d b ph hy trong mi trng axit (v d HCl) v mi trng kim (v d NaOH). 2. Nu cc tnh cht ho hc ging nhau v khc nhau c bn ca 3 hp cht hu c c sau: propenol, propenal v propenoic. 3. Cu kim loi thng c ln mt t Ag. Lm th no iu ch c Cu(NO3)2 tinh khit t loi Cu ni trn. Cu II: Ho tan 6,25 gam hn hp gm Zn v Al vo 275 ml dung dch HNO3, thu c dung dch A, cht rn B gm cc kim loi cha tan ht cn nng 2,516 gam v 1,12 lt hn hp kh D ( ktc) gm NO v N 2O. Hn hp kh D c t khi hi s vi H2 l 16,75. 1. Hi c cn dung dch A th thu c bao nhiu gam mui khan. 2. Tnh nng mol ca dung dch HNO3 ban u. Cu III: Trn a gam mt ru n chc vi b gam ca axit n chc, ri chia hn hp thnh 3 phn bng nhau: - Cho phn th nht phn ng ht vi Na, thu c 5,04 lt H2 ( ktc). - t chy hon ton phn th 2, thu c 59,4 gam CO2. - un nng phn th 3 vi H2SO4 c, thu c 15,3 gam este. Hiu sut phn ng este ho l 100%. t chy 5,1 gam este ny th thu c 11 gam CO2 v 4,5 gam H2O. 1. Xc nh cng thc ca ru v axit. 2. Tnh gi tr ca a v b. Cu IVa: 1. Ch dng qu tm, dung dch HCl v dung dch Ba(OH) 2 c th nhn bit c nhng ion no sau y trong cng mt dung dch: Na+, NH4+, HCO3-, CO32-, SO42-. 2. Hp cht A cu to bi C, H, O, N, c M = 89. t chy 1mol A thu c hi H2O, 3 mol CO2 v 0,5 mol N2. - Tm cng thc phn t ca A.

- Vit cng thc cu to ca cc ng phn ca A v cho bit cht no trong cc ng phn c th lm mt mu nc brm. Cu IVb: 1. Vit cc phn ng xy ra theo s sau: Cr CrCl2 CrCl3 Cr(OH)3 KCrO2 (1) (2) (3) (4) (5) Cr2O3 (6) Cho bit phn ng no l phn ng xi ho kh. 2. Vit cc phn ng xy ra khi cho amin axit axetic ln lt tc dng vi: dung dch HCl, dung dch NaOH, dung dch Na2CO3 v C2H3OH. Vit phn ng trng ngng ca amin axit axetic. Cho bit sn phm phn ng thuc loi cht g?

i hc thi nguyn 1999 Cu I: 1. C 5 l mt nhn ng 5 dung dch: NaOH, KCl, MgCl2, CuCl2, AlCl3. Hy phn bit tng dung dch m khng cn dng thm ho cht khc. Vit cc phng trnh phn ng xy ra. 2. Cho rt t t dung dch A cha x mol HCl vo dung dch B cha y mol Na2CO3. Hy bin lun cc trng hp xy ra theo y v x. Cu II: 1. Hy vit cc ng phn mch h ng vi cng thc phn t C3H6O3, C3H6O2. 2. Hy nu tnh cht ho hc ca glucoz v vit cc phng trnh phn ng minh ho. Cu III: A l mt hn hp gm Fe, Fe2O3, Fe3O4. 1. Cho dng kh CO d i qua 5,60 gam hn hp A nung nng thu c 4,48 gam st. Mt khc khi ho tan 5,60 gam hn hp A vo dung dch CuSO4 d thu c 5,84 gam cht rn. Tnh thnh phn % theo khi lng mi cht trong hn hp A. 2.Ly dung dch HCl 8% (d = 1,039 gam/ml) ho tan va 5,60 gam hn hp A ta c mt dung dch, cho dung dch ny tc dng vi lng d dung dch AgNO3 thu c kt ta D. Tnh th tch dung dch HCl 8% dng v khi lng kt ta D. Cho bit tnh xi ho ca tnh xi ho ca ion Fe 3+ mnh hn ion H+ v tnh kh ca nguyn t H mnh hn ion Fe 2+. Gi thit cc phn ng xy ra hon ton

Cu IV: Hn hp X gm: mt axit hu c no mch h 2 ln axit (A) v mt axit hu c khng no c mt ni i mch h n chc (B). S nguyn t cc bon trong phn t cht ny gp i s nguyn t cc bon trong phn t cht kia. t chy hon ton 5,08 gam hn hp X th cn 3,50 ml dung dch NaOH 0,2M v c hn hp mui Y. 1. Tm cng thc phn t ca A v B. 2. Tnh thnh phn % theo khi lng cc cht c trong X. 3. Tnh khi lng ca Y. Cu V: Hy cn bng cc phng trnh phn ng xi ho - kh sau bng phng php thng bng electron. a. K2S + K2Cr2O7 + H2SO4 S + Cr2(SO4)3 + K2SO4 + H2O. b. Fe3O4 + HNO3 Fe(NO3)3 + NO + H2O. c. K2SO3 + KMnO4 + KHSO4 K2SO4 + MnSO4 + H2O d. SO2 + KMnO4 + H2O K2SO4 + MnSO4 + H2SO4 CVI: 1. Hy nu nhng tnh cht vt l ho hc v cc phng php iu ch crm. 2. Hy nu nhn xt v tnh cht ho hc ca cc hp cht crm (II), crm (III), crm (VI). Cho cc v d minh ho.

Vin i hc m h ni 1999 2000 Cu I: 1. Vit cc phn ng thc hin cc bin ho sau (mi bin ho c th gm mt hay nhiu phn ng): a) Fe2O3 FeCl2 c) Ba(NO 3)2 Ba b) CuCO3 Cu d) CaCO 3 NaHCO 3 2. Nc cng l g? Phn loi cng ca nc? Nu 2 phng php lm mt cng tm thi ca nc (khng lm thay i cng vnh cu). Vit cc phn ng xy ra? Cu II: 1. T xenluloz v cc cht v c cn thit. Hy vit cc phn ng iu ch cc cht sau: C2H5OH, CH3COOH, CH3COOC2H5, xenluloz trinitrat. 2. Vit cc phn ng ca phnol C6H5OH, axit acrylic CH2 = C COOH, glyxerin C3H5(OH)3 vi Cu(OH)2, nc Brm.

Cu III: Nung 28,33 g h hp bt A gm Al , Fe 2O3, CuO , sau mt thi gian c hn hp rn B gm C Cu, Fe, Al2O3 v cc cht ban u cn d . Cho B tc dng va ht v 0,19 mol NaOH trong dung dch , thu c 2,016 l kh H2 v cn li hn hp rn Q. Cho Q tc dng vi dung dch CuSO4 d , thy khi lng cht rn sau phn ng tng 0,24 g (so vi khi lng ca Q) v c hn hp rn D. Ho tan ht D bng 760 ml dung dch HNO3 1M, va , thu c V lt kh NO. 1. Tnh s gam mi cht trong cc hn hp A v B. 2. Tnh V lt kh NO. Bit th tch kh o iu kin tiu chun. CIV. Ru A c mt loi chc. t chy hon ton 10,4 gam A cn dng ht 15,86 l kh O2 (ktc ) v thu c t l : s mol CO2 : s mol H2O = 5:6 1. Xc nh cng thc ti gin v cng thc phn t ca A 2. Ly 5,2gam A cho tc dng va ht vi 4gam CuO (nung nng) v thu c cht hu c B c kh nng trng gng . Xc nh cng thc cu to ca A. CuVa. 1. Nhn bit cc goi ho cht mt nhn sau: Al, Al2O3, Fe, Fe2O3. 2. Sp xp nhit si ca cc cht sau theo th t tng dn : CH3COOH, CH3OC2H5, C3H7OH. Gii thch s khc nhau v nhit si ca cc cht. CuVb. 1. Vit cc phn ng ca FeSO4, FeBr2, FeCl3 (trong dung dch ) vi nc brm , Cu. 2. So snh tnh linh ng ca nguyn t H trong nhm OH ca C2H5OH v CH3COOH. Gii thch. Ly 2 v d thuc cc loi phn ng khc nhau minh ho cho ni dung trn.

Trng i Hc GTVT tuyn sinh i Hc NM 1999 MN: Ho Hc Cu I. Vit phng trnh phn ng dng phn t v dng ion thu gn trong cc qu trnh sau:

a. Cho FeS tc dng vi dung dch H2SO4 (c, nng) cho kh SO2. b. Cho Fe3O4 tc dng vi dung dch HNO3 long cho kh NO . c. Cho Al tc dng vi dung dch HNO3 long cho kh N2. Cu II. T xenluloz , NaCl , H2O, bt st , khng kh . Hy iu ch cc cht sau : axit axetic,cao suBuna, Anilin,(este)propionat butyl. (Ch c dng thm trang thit b th nghimv cht xc tc cn thit ). Cu III. Chia 1,6 lt dung dch A cha HCl v Cu(NO3)2 lm hai phn bng nhau . 1. Phn 1 em in phn (cc in cc tr) vi cng dng 2,5 ampe, sau thi gian t thu c 3,136 lt ( ktc) mt cht kh duy nht ant. Dung dch sau khi in phn phn ng va vi 550 ml dung dch NaOH 0,8 M v thu c 1,96 g kt ta . Tnh nng mol ca cc cht trong dung dch A v thi gian t 2. Cho m gam bt st vo phn 2 ,lc u cho phn ng xy ra hon ton , sau phn ng thu c hn hp kim loi c khi lng bng 0,7m (gam) v V lt kh. Tnh m v V ( ktc ). Cu IV. Dn hn hp kh A gm mt hircacbon no v mt hircacbon khng no vo bnh nc Brm cha 10 gam Brm . Sau khi Brm phn ng ht th khi lng bnh tng ln 1,75 gam v thu c dung dch X , ng thi kh bay ra khi bnh c khi lng 3,65 gam . 1. t chy hon ton lng kh bay ra khi bnh thu c 10,78 gam CO2. Xc nh cng thc phn t ca cc hrcacbon v t khi ca A so vi H2. 2. Cho mt lng va nc vi trong vo dung dch X , un nng , sau thm tip mt lng d dung dch AgNO3 . Tnh s gam kt ta c to thnh . Cu V. a.(Dnh cho th sinh PTTH cha phn ban ) C 4 cht bt trng tng t nhau l: NaCl, AlCl3, MgCO3, BaCO3 . Ch c dng nc cng cc thit b cn thit (l nung ,bnh iiin phn v.v). Hy trnh by cch nhn bit tng cht trn. Cu V. b. (Dnh cho th sinh PTTH chuyn ban ) Vit phng trnh phn xy ra khi cho Cu ln lt vo tng dung dch sau: Hn hp NaNO3 v HCl ; AgNO3 ; FeCl3 ; HCl c O2 ho tan .

Trng i hc Bch Khoa H Ni

thi tuyn sinh i hc 1999 MN : Ho Hc Phn I: (Dnh cho tt c cc th sinh) Cu I. t Cacbon trong khng kh nhit cao, c hn hp kh A.Cho A

tc dng vi Fe2O3 nung nng c kh B v hn hp rn C . Cho B tc dng vi dung dch Ca(OH)2 c kt ta K v dung dch D; un xi D li c kt ta K . Cho C tan trong dung dch HCl, thu c kh v dungdch E. Cho E tc dng dung dch NaOH d c kt ta hn hp hiroxit F . Nung F trong khng kh c mt oxit duy nht . Vit cc phng trnh phn ng. Cu II. Trong cc ng phn ca hp cht C3H6O3 ,ng phn A va c tnh cht ca ru , va c tnh cht ca axit. Vit cc phng trnh phn ng ca A vi C2H5OH , CH3COOH, NaOH, phn ng trng ngng ca A ,v phn ng tch nc ca A to cht B lm mt mu nc Brm. Cu III. Ho tan hon ton mt lng hn hp A gm Fe3O4 v FeS2 trong dung dch HNO3 theo cc phn ng : Fe3O4 + HNO3 Fe(NO3)3 + NO2 + H2O FeS2 + HNO3 Fe(NO3)3 + NO2 + H2SO4 + H2O Th tch kh NO2 thot ra l 1,568 lt(o ktc ) Dung dch thu c cho tc dng va vi 200 ml dung dch NaOH 2M , lc kt ta em nung n khi lng khng i,c 9,67 g cht rn. Tnh s gam mi cht trong A v nng % ca dung dch HNO3 (gi thit HNO3 khng b mt do bay hi trong qu trnh phn ng). Cu IV. Cho mt lng hn hp CaC2 v Al4C3 tc dng vi nc d ,c hn hp kh A kh . Bnh B dung tch 5,6 lt 27,30C cha lng oxi va t chy ht A c p sut 1,43 atm. Cho A vo bnh B , nhit ny, p sut trong bnh l p Bt tia la In t chy ht hon ton A ri a bnh v 00 C , hi nc ho rn hon ton , chim th tch khng ng k ,p sut trong bnh lc ny l 0.86 atm . Tnh % khi lng CaC2, , Al4C3 trong hn hp ban u v tnh p sut p. Cu V. Lc 0,81 g bt nhm trong 200 mldung dch AgNO3 v Cu(NO3)2 mt thi gian ,thu c chn A v dung dch B .Cho tc dng vi NaOH d th c 100,8 ml kh Hiro(o ktc)v cn li 6,012 g hn hp 2 kim loi. Cho B tc dng vi NaOH d , c kt ta , nung n khi lng khng i thu c 1,6 g mt oxit. Tnh nng CM ( mol/lt) ca AgNO3 v Cu(NO3)2 trong dung dch u. Cu VI . t hon ton mt lng hn hp 2 ete : cho sn phm phn ng chy qua bnh ng P2O5 d ,khi lng bnh tng thm 6,21 g ; sau cho qua tip dung dch Ca (OH)2 d ,thu c 34,5 g kt ta. Cc este ni trn thuc loI g ? (n chc hay a chc ,no hay khng no). Mt khc cho 6,825 g hn hp 2 este tc dng va vi dung dch KOH, thu c 7,7 g hn hp 2 mui v 4,025 g mt ru.

Phn II: A.(Dnh cho th sinh cha phn ban ) Cu VII.a.Vit phng trnh phn ng ca Ba(HCO3)2 vi cc dung dch HNO3 ,
Ca(OH)2, Na2SO4 v NaHSO4 .

Tnh cng thc phn t v khi lng mi este ,bit rng khi lng phn t ca 2 mui hn km nhau khng qu 28 n v cacbon

Cu 8 A. T than vi v cc cht ,iu kin cn thit ,vit phng trnh phn ng iu ch axit fomic v axit axetic. B.(Dnh cho th sinh chuyn ban ) Cu VII.b. Vit phng trnh phn ng ca Cu,CuO vi H2, dung dch H2SO4 long ,
dung dch H2SO4 c nng,dung dch AgNO3 , dung dch HNO3 long . Cu 8 B. t chy hp cht hu c A cho kh CO2 v H2O. T khi hi ca A so vi H2 l 28. Tm cng thc phn t ca A. Vit phng trnh phn ng trng hp v phn ng vi H2 d ca cc ng phn cha ni i ca A .

Trng i hc dc H Ni Nm 1999 Phn chung cho mi th sinh Cu I. 1. Hp cht A c cng thc l MXX trong M chim 46,67% v khi lng , M l
kim loi , X l phi kim chu k 3. Trong ht nhn ca M c : n p = 4 , ca X c : n = p (trong n, n , p , p l s ntron v proton). Tng s proton trong MXX l 58. a) Xc nh tn , s khi ca M v tn , s th t nguyn t ca X trong bng h thng tun hon . b) Vit cu hnh electron ca X . 2. Bng phn ng ho hc , hy trnh by cch tch cc cht : Al2O3 , Fe2O3 , SiO2 ra khi hn hp ca chng . 3. V sao NH3 khng tn tI trong mI trng axit ? V sao ZnOH)2khng tn ti trong mi trng axit cng nh trong mI trng kim d ? Cu II. Cho mt bnh kn dung tch 112 lt trong N2 v H2 theo t l th tch 1: 4 00C v p sut 200 at vi mt t cht xc tc thch hp. Nung nng bnh mt thi gian , sau a nhit v 00 C thy p sut trong bnh gim 10% so vi p sut ban u 1. Tnh hiu sut phn ng ii ch NH3 . 2. Nu ly 12,5% lng NH3 to thnh c th ii ch c bao nhiu lt dung dch NH3 25% (d = 0,907 g/ml) ? 3. Nu ly 50% lng NH3 to thnh c th i ch c bao nhiu lt dung dch HNO3 67% ( d = 1,40 g/ml), bit hiu sut qu trnh iu ch HNO3 l 80% . 4. Ly mt th tch dung dch HNO3 67% trn pha long bng nc c dung dch mi , dung dch ny ho tan va 9 gam Al v giI phng hn hp kh NO v N2O c t khi so vi H2 l 16,75. Tnh th tch dung dch HNO3 675 dng . Cu III. t chy 11,6 gam cht A thu c 5,3 gam Na2CO3 4,5 gam H2O v 24,2 gam CO2.

1. Xc nh cng thc phn t ca A , bit rng mt phn t ca A ch cha mt nguyn t oxi. 2. Cho kh CO2 sc vo dung dch A , thu c cht B v mt dn xut ca Benzen . trung ho 4 gam hn hp B v cht C ( l ng ng k tip ca B ) cn dng 38,7 ml dung dch NaOH 1 M,. Tnh t l s mol ca B v C trong hn hp . 3. Cho B tc dng vi hn hp HNO3 c (d) v H2SO4 c thu c cht T . Cho 13,74 gam cht T ,vo mt bnh chu p sut ,dung tch khng i 560 cm3 v lm nphn hu cht T 19110 C . Tnh p sut trong bnh ti nhit , bit rng sn phm n l hn hp kh CO, CO2 , N2 ,H2 v p sut thc t nh hn p sut l thuyt 12%.

Phn Dnh Ring Cho Th sinh cha phn ban .

Cu IV.A. 1. Vit cng thc cu to v gi tn ca cc hp cht thm c cng cng thc phn t C7H8O. 2. C 4 ng nghim cha dn nhn cha cc cht ring r sau : Ru etylic , axit axetic, anehit axetic , phenol lng . Bng phng php ho hc hy phn bit cc cht .Vit phng trnh phn ng . 3. Vit phng trnh phn ng dng tng qut khi cho ru CNH2N+1-2AOH . Tc dng vi : Na ; HCl (phn ng este ho ); H2 d (Ni, t0) ; dung dch Br2 (d ).

Phn Dnh Ring Cho Th sinh chuyn ban . Cu IV. B

1. Vit y cc phng trnh phn ng ca dy chuyn ho sau : +HNO3 c (1 mol) Fe, HCl(d) +NaOH +Br2 C6H6 A C D B (1mol) H2SO4 c 2. Mt hn hp kh A gm 2 hirocacbon A1 V A2 c thnh phn v khi lng ca H tng ng l 25% v 14,29% . Cho A qua dung dch KMnO4 c kh A1 phn khng tan B1 v cht hu c B2 . Tch ly B2 ri cho tc dng vi HCl c cht B3 .T B3 c th iu ch c hirocacbon A3 c 7,69% H v khi lng . Hy xc nh cng thc cc cht v vit cc phng trnh phn ng , bit rng trong phn t A2 ,A3 u c 2 nguyn t cacbon.

a. phn bt buc:

Trng i hc thng mi Nm 1999

Cu I: 1. a) Cho cc cht Fe , FeS2 , FeCO3 , FeO, Fe(OH)2 ln lt tc dng vi HNO3

c ,nng . Vit phng trnh phn ng dng phn t , dng ion ( cho bit trong sn phm phn ng c kh NO2 hoc c kh CO2 hoc c H2SO4 ). b) Mt hn hp gm Al2O3 , CuO, Fe2O3 . Dng phng php ho hc tch ring tng cht ra khi hn hp . 2. a) C cc cht Butin 1 , buten 2 v n Butan ng trong cc bnh nt nhn . Hy nhn bit cc cht ni trn . b) T propan , vit phng trnh phn ng ho hc minh ho dy bin ho sau : t0 x. t +Cl2 ASKT + NaOH +CuO ,t0 +O2 x.t Propan A BCH3OH D E +HCl

? Cu II. A l dung dch AgNO3 nng a mol/l . Cho 13,8 gam hn hp bt Fe v bt Cu vo 750 ml dung dch A ; Sau khi phn ng kt thc thu c dung dch B v 37,2 gam cht rn E . Cho NaOH d vo dung dch B thu c kt ta ; Ly kt ta nung trong khng kh n khi lng khng i thu c 12 gam hn hp gm 2 oxit ca kim loi . 1. tnh % khi lng hai kim loi trong hn hp ban u . 2. tnh a ?

+ AgNO3, NH3 , H2O G

? + NaOH

Cu III.

un nng 7,2 gam este A vi dung dch NaOH d ; phn ng kt thc thu c glyxerin v 7,9 gam hn hp mui . Cho ton b hn hp mui tc dng vi H2SO4 long thu c 3 axit hu c no n chc mch h D , E , F ; Trong E, F l ng phn ca nhau ; E l ng ng k tip ca D. 1. Vit phng trnh phn ng minh ho th nghim trn ; Tm cng thc cu to ca 3 axit ; Cng thc cu to c th c ca este A. 2. t chy hon ton hn hp 3 axit trn ri cho sn phm chy hp th ht vo 500 ml dung dch NaOH 1 M ; Tnh s gam nui Natri to thnh . ( Cho cc phn ng xy ra hon ton ) B. phn t chn : Th sinh c th chn 1 trong 2 cu Iva hoc Ivb:

CuIVa:

1. a) Vit 6 phng trnh phn trc tip iu ch CaCl2 t canxi v c hp cht ca canxi. b) Vit cu hnh electron ca Ca0 , Ca2+ , S0 , S2- ; Bit canxi 20 ; lu hunh trong bng h thng tun hon cc nguyn t ho hc . 3. a) T tinh bt hoc xenlulo v cc cht v c , cht xc tc cn thit ; Vit phng trnh phn ng iu ch : axit Axtic , este Fomiat etyl , Anilin , Etylen glycol , P.V.C. b) Mt hn hp kh gm : Propan , Etylen , Axetylen .Hy tch ring tng cht ra khi hn hp .

Cu IV b:

1/ a) Bit CrO l oxit baz ; Cr2O3 L oxit lng tnh ; CrO3 l oxit axit . Vit phng trnh phn ng ca cc oxit trn vi HCl , vi NaOH . b) PH l g ? Dung dch HCl c PH = 3. Tnh nng ion [ H+] , [ OH -] , [ Cl ] theo mol /l. 2/ a) Vit phng trnh ng iu ch nilon 6-6 t OH CH2 (CH2) CH2 OH v O2N CH2 (CH2)4 CH2- NO2 v cc ho cht cn thit khc . c) Mt hn hp gm Benzen , Anilin , Phenol. Hy tch ring tng cht ra khi hn hp .

i hc xy dng nm 1999 cu i: 1/ Vit phng trnh phn ng dng phn t v ion thu gn sau y:
a/ Cl2 + b/ Fe + (c, nng) dung dch Ca(OH)2 dung dch Fe2(SO4)3 d/ H2SO3 + H2S e/ FeS2 + HNO3

c/ H2SO3 + Br2 + H2O f/ FeCO3 + HNO3 (c ,nng) 2/ Cho t t kh CO qua ng ng CuO nung nng . Kh A ra khi ng ng hp th hon ton vo nc vi trong ly d , thu c kt ta B. Cho cht rn cn li trong ng s vo cc ng HNO3 long d , thu c kh NO v dung dch C. Cho xt d vo dung dch C thu c kt ta D . Nung D n khi lng khng i , c cht rn E. Xc nh A,B,C,D,E v vit cc phng trnh phn ng xy ra. 3/ Kh NH3 b ln hi nc , c th dng cht no trong cc cht sau thu c NH3 khan : H2SO4 c, CaO, P2O5, , Ba(OH)2 c. Ti sao ? Cu II. 1/ Hp cht hu c X c cng thc tng qut l CXHYOZNt thnh phn % v khi lng ca N trong X l 15,7303% v ca O trong X L 35,9551%. Bit X khi tc dng vi HCl ch to ra mui dng R(O)2 NH3Cl ( R l gc hircacbon ). Xc nh cng thc phn t v cng cu to mch h ca X , bit rng X tham gia phn ng trng ngng .Vit cc phng trnh phn ng ca X vi dung dch H2SO4 ; dung dch Ba(OH)2 v phn ng trng ngng ca X.

Chng trnh ptth cha phn ban

2/ C mt hp cht hu c n chc Y, khi t chy Y ta ch thu c CO2 v H2O vi s mol nh nhau v s mol xy tiu tn gp 4 ln s mol ca Y. Xc nh cng thc phn t v cng cu to mch h ca Y , bit rng : Y lm mt mu dung dch nc brm v khi Y cng hp vi hir c ru n chc .Vit cc phng trnh phn ng xy ra (ghi r iu kin phn ng ).

Chng trnh ptth chuyn ban

2/ Cc polime dng sn xut t nilon 6,6 v t polietylentereftalat (t lapsan)c iu ch t cc monome tng ng no? Vit cc phn iu ch cc polime trn t cc monome tng ng . Cu III. em m gam hn hp A gm bt nhm v 1 oxit ca st chia thnh 2 phn u nhau : - Cho phn 1 tc dng vi mt lng va dung dch H2SO4 0,5 M thu c dung dch Bv 0,672 lt kh - Thc hin phn ng nhit nhm hon ton vi phn 2 . Hn hp sau phn ng cho tc dng vi dung dch NaOH d , thu c 0,1344 lt kh , tip tc cho dung dch H2SO4 0,5M vo ti d th thu c thm 0,4032 lt kh v dung dch C . Sau cho t t dung dch Ba(OH)2 vo dung dch C ti d th c kt ta D . em nung kt ta D trong khng kh n khi lng khng i th thu c 24,74 gam cht rn E . 1/ Xc nh cng thc phn t ca oxit st , tnh gi tr m v thnh phn % khi lng ca hn hp A . 2/ Tnh khi lng ca cc cht trong E v th tch ca dung dch H2SO4 dng trong c qu trnh th nghim .(Cc cht o iu kin tiu chun). Cu IV . Cho V lt (ktc) hn hp kh gm 2 olfin lin tip nhau trong dy ng ng hp nc (c H2SO4 long xc tc ) thu c 12,9 gam hn hp A gm 3 ru .Chia A thnh 2 phn u nhau : - Phn 1 em un trong H2SO4 c 1400C th thu c 5,325 gam B gm 6 ete khan . Xc nh cng thc cu to ca cc olfin , cc ru v cc ete . - Phn 2 em xy ho bng O2 khng kh nhit cao (c Cu xc tc) th thu c hn hp sn phm D ch gm anhit v xton . Sau cho D tc dng vi AgNO3 trong dung dch NH3 d (hoc Ag2O trong dung dch NH3 d ) th nhn c 17,28 gam Ag kim loi .Tnh % khi lng mi ru trong A v tnh gi tr V. - Nu thm 0,05 mol mt ru no n chc ,bc khc vo phn 2 ri tin hnh phn ng oxy ho bng O2 khng kh , sau phn ng trng bc nh trn th s nhn c bao nhiu gam Ag kim loi?

Trng i hc ngoi thng Nm 1999

a- chung cho mi th Phn sinh : Cu I: 1. Hy nu tnh cht ho hc chung ca kim loi .Vit phng trnh tng qut . 2. Lin kt trong tinh th kim loi ging nhau v khc nhau vi lin kt ion v lin kt cng ho tr ch no ? 3. Hon thnh cc phng trnh phn ng sau : a/ K + dd NaOH d/ Cu + dd FeCl3 b/ Ba + dd Na2SO4 e/ Zn + dd Ni(NO3)2 c/ Na + dd ZnCl2

Cu II.

M l hp cht ho hc gm Al v Cu (trong tinh th hp kim ) c cha 12,3% Al (v khi lng 1/ Tm cng thc ca M. 2/ Ho tan trong HNO3 long thu c 2 mui A, B. Tch ring A, B ri ln lt cho tc dng vi dung dch NH3 d th A to ra kt ta A1 , B to ra dung dch B1 . Cho A1 v B1 tc dng vi NaOH c th A1 to ra dung dch A2 , cn B1 to ra kt ta B2 . Cho A2, B2 tc dng vi HNO3 li to ra A, B ban u . Vit phng trnh phn ng .

Cu III:

Cu IV .

Hn hp A gm Al v Al2O3 c t l s gam mAl : mAl2O3 = 0,18 : 1,02 . Cho tan trong dung dch NaOH (va ) thu c dd B v 0,672 lit H2 (ktc). Cho B tc dng vi 200 ml dd HCl c kt ta D. Nung D nhit cao n khi lng khng i thu c 3,57 gam cht rn . 1. Tnh nng ( mol/l) ca dd HCl . 2. Nu pha long dd HCl n 10 ln th PH ca dd sau khi pha long l bao nhiu ?

A l hp cht hu c ( CXHYOZ) c phn t khi MA = 74 vc. 1. Tm cng thc phn t ca A. 2. Khi A c 32,43% C (v khi lng ), hy vit cc phng trnh phn ng khi : a) A + H2O ? c) A + Cu(OH)2 + NaOH ? b) A + H2 ? d) A + AgNO3 + dd NH3 ?

Cu V.

Cho x gam hn hp X gm 2 este l ng phn ca nhau bay hi iu kin thch hp , chim th tch ca 6,4 gam O2 cng iu kin . t chy X to ra CO2 v H2O vi t l s mol l 1:1 . Mt khc un nng X vi NaOH d thu c m (gam) hn hp 2 mui v p (gam) hn hp ru l ng ng k tip nhau . 1. Tm cng thc ca A, B. 2. Tnh x v m khi p = 7,8 ; m p < 8 B. Phn ring cho tng loi th sinh : Cu VI a. ( theo chng trnh chuyn ban )

Cho xenluloz phn ng anhidrit axetic c cht xc tc l H2SO4 c thu c 6,6 gam axit Axetic v 11,1 gam hn hp A gm xenluloz triaxetat v xenluloz diaxetat. Tnh thnh phn % v khi lng cc cht trong A . Cu VI b. ( theo chng trnh cha phn ban ) Theo em nhng cu sau y ng hay sai : 1. Cht tc dng vi dd axit v vi dd baz phi l cht lng tnh . 2. Hai cht c phn t khi bng nhau phi l hai ng phn ca nhau . 3. Ch c oxit phi kim mi l oxit axit . 4. Hai nguyn t c s in tch ht nhn Z bng nhau c th c s khi A khc nhau. 5. Hai nguyn t c s in tch ht nhn Z khc nhau c th c s khi A bng nhau. Hy gii thch kin ca em .

i hc y h ni
Phn bt buc: Cu i:
1. Nc cng l g ? Gii thch nguyn nhn gy ra cng tm thi trong nc t nhin? 2.Mt cc nc cha 0,01 mol Na+ ; 0,02 mol Cl- ; 0,01 mol Mg+ ; 0,02 mol Ca+ v 0,05 mol HCO3- . un xi cc nc trn mt hi lu , hi s mol mi ion trong nc sau khi un bng bao nhiu ?T kt lun nc trong cc ban u thuc loi nc c cng tm thi , vnh cu hay ton phn ? 3. C th dng dd no trong cc dd: HCl ; NaOH ; Na2CO3 ; NaCl lm gim cng ca nc trong cc ban u ? Vit cc phng trnh phn ng . 4. Cho 4,72 gam hn hp bt Fe, FeO, Fe2O3 tc dng vi CO d nhit cao . Phn ng xong thu c 3,92 gam Fe . Nu ngm cng lng hn hp trn trong dd CuSO4 d , phn ng xong thu c 4,96 gam cht rn . Xc nh khi lng ca mi cht trong hn hp ban u .

Cu ii:

1.

A, B , C, D , E l cc cht hu c c mch h ch cha C, H,O u khng lm mt mu nc brm , u c khi lng phn t l 74. Cho cc cht tc dng vi Na; dd NaOH ; dd AgNO3 trong NH3 thu c kt qu sau : a b + + c + d + + e + + + -

Du (+) c phn ng na Du (-) khng phn NaOH ng AgNO3 / NH3

+ -

Vit cng thc cu to ca A, B , C, D, E ( ch cn vit mi cht mt ng phn) v vit cc phng trnh phn ng xy ra . 2. T mt loi mn ca cha 60% xenluloz c dng lm nguyn liu sn xut ru etylic. Nu dng mt tn mn cuqa trn c th iu ch c bao nhiu lt ru 700 ? Bit rng hiu xut ca qu trnh l 70%, khi lng ring ca ru etylic nguyn cht l 0,8 g/ml. Cu iii:A l mt loi oxit ca kim loi ho tr m ( trong s cc kim loi cho di ). Ho tan hon ton 1,08 gam A trong HNO3 2M (long ) thu c 0,112 lt kh NO (ktc) v dd D. a/ Xc nh cng thc phn t ca A . b/ Cho 1,08 gam A vo ng s , nung nng ri dn kh CO i qua ti d . Sau khi phn ng xy ra hon ton thu c cht rn B. Nu ho tan B trong dung dch H2SO4 long , d th dd sau phn ng c th lm mt mu dd KMnO4 khng ? Nu c th c th lm mt mu bao nhiu ml KMnO4 0,1 M. Cu iv: E l hn hp ca 2 ng phn mch thng ( chab C, H, O) ch cha mt nhm chc . un nng m gam hn hp E vi 1,5 lt dung dch NaOH 0,2 M n khi phn ng xy ra hon ton . trung ho NaOH d cn thm vo hn hp sau phn ng 120 ml dung dch

HCl 0,5 M . C cn hn hp sau trung ho thu c 22,71 gam hn hp 2 mui khan v 11,04 gam hn hp ru n chc bc mt c phn t lng khc nhau . a/ Xc nh cng thc cu to ca 2 ru trn . b/ Xc nh cng thc cu to ca 2 cht trong hn hp E.

Phn t chn: th sinh phi lm mt trong 2 cu Va hoc Vb.

Cu va:1. a/ Vit cu hnh electron ca S ( z = 16) v cng thc electron ca phn
t SO2 ; SO3 bit trong cc hp cht ny xung quanh O c 8 electron. b/ Cn bng : 2SO2 + O2 2SO3 s chuyn dch v pha no khi tng p sut ? Ti sao? 2. T xenloluz v cc cht v c cn thit , vit phng trnh phn ng iu ch cc cht : Glyxerin ; xenluloz triaxetat ; cao su Buna . 3. Vit phng trnh phn ng thu phn : Hp cht A nh xc tc men ; hp cht B trong dung dch NaOH d . H2N - CH - CO - NH - CH - COOH (A) CH3 (CH2)4NH2 Cu vb: 1.Ch dng mt ho cht phn bit cc dung dch sau y ng trong 3 l ring bit :

CuSO4 ; Cr2(SO4)3 ; FeSO4 . Vit cc phng trnh phn ng. 2. Vit phng trnh phn ng thu phn : Hp cht A nh xc tc men ; hp cht B trong dung dch NaOH d . H2N - CH2 - CO - NH - CH - COOH (A) CH2 - C6H5 4. nu phng php iu ch nha epxit v nha urefomadeit.

Trng H Nng Nghip I tuyn sinh I hc

Mn : ho hc

Nm 1999 Khi A

A.Phn chung cho mi th sinh: Cu I: 1/ Cho ba bnh dung dch mt nhn l A gm KHCO3 v K2CO3 , B gm KHCO3 v K2SO4 , D gm K2CO3 v K2SO4 . Ch dng dch BaCl2 v dung dch HCl , nu cch nhn bit mi bnh dung dch mt nhn trn v vit cc phng trnh phn ng km theo. 2/ Vit phng trnh phn ng ( nu c ) mi cht sau vi dung dch NH4OH : a/ AlCl3 ; b/ K2SO4 ; c/ CaC2 ; d/ CuCl2. Cu II. 1/ Tnh cht ho hc ca phenol (C6H5OH) . Hy chng t phenol c tnh axit yu hn axit cacbonic. +A +B +D 2/ Cho dy : H2CO2 CH5O2N HCOONa Ag. (1) (2) (3) Cho bit A, B , D l nhng cht no ? Vit phng trnh phn ng cho dy bin ho . Cu III. Cho 1,568 lt hn hp kh X gm 2 hircacbon mch h vo bnh nc Brm d . Sau khi phn ng hon ton ch cn lI

448 cm3 kh thot ra v c 8 gam brom phn ng . Mt khc , nu t chy hon ton lng X trn ri dn ton b sn phm chy vo bnh nc vI trong th c 15 gam kt ta . Lc b kt ta ri un nng nc lc , thu thm ti a 2 gam kt ta na. (Cc th tch kh u o ktc). 1/ Xc nh cng thc cu to phn t 2 hircacbon. 2/ Tnh t khi hI ca X so vi Hydro. 3/ Vit cc phng trnh phn ng tch ring mi kh khi X . PHn Ring (Th sinh ch lm mt cu 4a hoc 4b ) Cu IV a. (Dnh cho th sinh thi theo chng trnh cha phn ban) Cho m gam hn hp X gm Na2O v Al2O3 lc vi nc cho phn ng hon ton thu c 200 ml dung dch A ch cha mt cht tan duy nht c nng 0,5 M .Thi kh CO2 d vo dung dch A c a gam kt ta . 1/ Tnh m gam v thnh phn %(theo khi lng) cc cht trong X . 2/ Tnh a v th tch CO2 ( KTC) phn ng . Cu IV b. (Dnh cho th sinh thi theo chng trnh chuyn ban) 1/ Vit phng trnh phn ng chng t Cr(OH)3 lng tnh . 2/ Cho 16 gam mt mu X cha Cr2O3 c ln tp cht tr phn ng hon ton vi nc Brm trong KOH m c. Ho tan sn phm vo nc ri lc b tp cht tr khng tan , c dung dch A .Cho dun g dch BaCl2 d vo dung dch A c 50 6 gam kt ta . Tnh % khi lng Cr2O3 tinh khit trong mu X .

HC VIN CNG NGH BCVT NM 1999

A. PHN CHUNG CHO MI TH SINH : Cu I: 1/ Trong phng th nghim , oxi c iu ch bng cch nhit phn kaliclorat hoc kalipermanganat. a) Vit phng trnh phn ng iu ch oxi theo hai cch nu. Cho bit hai phn thuc loi g ( trao i , oxi ho - kh ). b) T mt gam mi ho cht ban u , phn ng no s cho nhiu oxi hn (Nu hiu sut phn nh nhau )? 2/ a. Cho isopropen tc dng vi brm , isopentan tc dng vi clo (c chiu sng ) theo t mol l 1:1 th trong mi trng hp to ra bao nhiu ng phn ? vit cng thc cu to.

b. Cho bit nhng tnh cht ho hc ging nhau v khc nhau quan trng nht ca axit acrylic v axit lactic ( axit 2- hirxi prpanic ) v axit pr prpanic.Vit phng trnh chuyn ho gia chng.Trnh by phng php nhn bit 3 axit ng trong 3 l mt nhn . Cu II. Ho tan hon ton m gam hn hp gm FeS2 v Cu2S vo H2SO4 c nng , thu c dung dch A v kh SO2 . Hp th ht SO2 vo 1 lt dung dch KOH 1 M thu c dung dch B . Cho 1 / 2 lng dung dch A tc dng vi mt d dung dch NH3 ly kt ta nung n khi lng khng i thu c 3,2 gam cht rn . Cho dung dch NaOH d vo 1/ 2 lng dung dch A. Ly kt ta nung n khi lng khng i , sau thi hiro (d) i qua cht rn cn li , sau khi phn ng hon ton thu c 1,62 gam hi nc . 1. Tnh m. 2. Tnh s gam cc mui c trong dung dch B . Cu III. Cho 0,42 lt hn hp kh B gm 2 hircacbon mch h i rt chm qua bnh ng nc brm d . Sau khi phn ng xy ra hon ton thy c 0,28 lt kh i ra khi bnh v c 2 gam brm tham gia phn ng . Cc th tch kh o ktc.T khi hi ca B so vi hiro l 19. Hy xc dnh cng thc phn t v s gam mi hp cht c trong hn hp B.PHN DNH RING CHO TNG LOI TH SINH. Cu IVa:(Dnh cho th sinh ng k theo chng trnh TH cha phn ban) 1/ a. Vit cu hnh electron ca cc ion Fe3+, Fe2+, S2-, bit s th t ca S, Fe trong bng h thng tun hon l 16 v 26. b. Vit phng trnh phn ng khi cho FeCl2 tc dung dch vi KI, dung dch Na2CO3. c. Theo nh ngha mi v axit , baz , th NH3, NH4+ cht no l axit , cht no l baz ?Cho phn ng minh ho , gii thch ti sao NH3 c tnh cht 2/ Hy dng cc phng php ho hc phn bit cc ho cht HCOOH, CH3CH2CHO, CH3COOH vCH3COOCH3. Cu IVb: (Dnh cho th sinh ng k theo chng trnh TH CHUYN BAN) 1/ Hy d on v gii thch hin tng trong cc th nghim sau : Thm tng git dung dch NaOH vo dung dch Cr2(SO4)3 cho n d . Thm vi git nc Br2, , thm tng git H2SO4 n d . Vit phng trnh phn ng . 2/ T than , vi v cc cht v c khc vit phng trnh phn ng iu ch 2,4,6 tribrmphenol v 2,4,6 tribromanilin

I HC AN NINH NM 1999 PHn I : Bt buc cho ton b cc th sinh .

Cu 1. 1. Hy cho bit nguyn nhn s bin i tun hon tnh cht ca cc

nguyn t . 2. S th t ca nguyn t A l 8, nguyn t B l 17, nguyn t C l 19 . Vit cu hnh electron ca chng v vho bit vhng thuc chu k no ,nhm no ? 3. ng phn l g? nguyn nhn to ra ng phn trong cc hp cht hu c . Cho cc v d minh ho . 4. T n-butanol v cc cht v c cn thit khc , hy tm cch iu ch metyl etyl te. Cu 2. Cho a gm hn hp bt Zn v Cu (Zn chim 90% khi lng ) tc dng vi dung dch HCl d , thu c kh H2 . Lng H2 ny va phn ng hon ton vi b gam mt oxit st t trong mt ng s nung . Hi nc thot ra t ng s vho hp th hon ton vo 150 gam dung dch H2SO4 98% c dung dch H2SO4 c nng nh hn nng ca dung dch axit ban u l 14,95%(dung dch C) . phn ng hon ton vi 5,65% khi lng cht rn sn phm c trong ng s cn dng 20 gam dung dch C un nng , c SO2 thot ra . 1. Tnh a v b? 2. Dng 150 ml dung dch C c th ho tan ht b gam oxit st khng ? Cu 3. C A gam hn hp X gm mt axit no n chc A v mt este to ra bi mt axit no n chc B l ng ng k tip ca A v mt ru no n chc . Cho agam hn hp X tc dng vi lng va NaHCO3 , thu c 1,92 gam mi , nu cho agam hn hp X tc dng vi mt lng va NaOH un nng , thu c 4,38 gam hn hp 2 mui ca axit A v B v 0,03 mol ru , ru ny c t khi hi so vi hir l 23 . t chy hn hp 2 mui bng mt oxi d th thu c mui Na2CO3 , hi nc v 2,128 lt CO2 (ktc). Gi thit cc phn ng u xy ra hon ton . 1. Cho bit hn hp X gm axit v este no? 2. Tnh a?

PHn II. Cu 4a. (Dnh cho cc th sinh thi theo chng trnh cha phn ban)

1. a) C mt vt bng st trng thic (vt A) v mt vt bng st trng km (vt B) u c vt sy st ti lp st , t trong khng kh m th vt no r nhanh hn? gii thch . b) Nu cc phng php thng dng chng n mn kim loi . Hy gii thch v sao bo v v tu bin ngi ta thng gn thanh km vo v ngoi tu(phn ngm di nc bin ) 2. C 5 dung dch nc ca propanal, etanol, glixrin, glucoz, saccarz ng trong 5 l khng nhn.C th dng mt thuc th (khng k axit v kim) pht hin tng dung dch . Trnh by qu trnh th nghim . Cu 4b. (Dnh cho cc th sinh thi theo chng trnh chuyn ban) 1. a) Th no l phn ng oxi ho kh. b) Cn bng cc phng trnh phn ng sau di dng ion Mn+2 + H2O2 + OH MnO2 + H2O + H+ Ag+ + NO + H2O

Ag + NO3 IO3 MnO4 + I

+ H+ 2 + H2O I + H+ Mn+2 + Cl2 + H2O +Cl+ H2O

+ Cl

Cr+3 + ClO-3

+ -OH 4-2 CrO

2. Hon thnh s bin ho sau ( vit cng thc cc cht ng vi cc ch ci

cng cc cht phn ng v nhng iu kin cn thit ). Cho bit A , B c mch cacbon nh cht u . CH3 CH3COOC2H5 CH2 CH2 CH2OH A C + D B E + F

G H I

i hc kinh t quc dn nm 1999 phn I: Chung cho mi th sinh

Cu I: 1. Hy nu v gii thch bng phng trnh phn ng cc hin tng xy ra trong tng th nghim sau : a) Cho CO2 li chm qua dung dch nc vi trong . Sau cho tip nc vi trong vo dung dch va thu c cho n d . b) Cho KOH d tc dng vi dung dch FeCl2 . Ly kt ta thu c lu trong khng kh . 2. Khi cho 17,40 gam hp kim Y gm st , ng , nhm phn ng ht vi H2SO4 long ,d ta c dung dch A ; 6,4 gam cht rn ; 9,856 lt kh B 27,30C v 1 at . a) Tnh phn tm khi lng mi kim loi trong hp kim Y. b) Hy tnh nng cc cht trong dung dch A , bit rng H2SO4 dng c nng 2M v c ly d 10% so vi lng cn thit phn ng ( th tch dung dch khng thay i trong cc th nghim ). Cu II. 1. Vit cng thc cu to thu gn v cc phng trnh phn ng minh ho tnh cht ho hc ca axit acrylic . 2. Amin bc nht X dng R- NH2 c t khi hi so vi hiro bng 15,5 . Hy gi tn v vit phng trnh phn ng minh ho tnh cht ho hc ca X . 3. Hn hp A gm hai anken. Khi dn 3,696 lit A i qua bnh ng nc brm d th khi lng bnh tng thm 7,00 gam . a) Hy tnh khi lng hp cht hu c thu c khi dn 1,848 lt hn hp A i qua nc un nng v c cht xc tc thch hp . b) Cho hn hp gm 7,392 lt A vi 3,969 lt hiro i qua niken t nng th c hn hp B . Tnh t khi ca B so vi etan . Bit rng th tch cc kh u o 27,30C , 1 at v cc phn ng iu xy ra hon ton .

PHn II. Cho tng loi th sinh

Cho th sinh theo chng trnh cha phn ban

Cu III. A: 1. Trong s cc cht sau y nhng cht no c th phn ng c vi nhau ? NaOH , Fe2O3 , K2SO4 , CuCl2 , CO2, Al, NH4Cl Vit cc phng trnh phn ng v nu iu kin phn ng (nu c ) 2. Pha long 10 ml HCl vi nc thnh 250 ml . Dung dch thu c c pH= 3. Hy tnh nng ca HCl trc khi pha long v pH ca dung dch . CuIV. A: Cho 2,20 gam hp cht X n chc gm C, H , O phn ng ht vi Ag2O (trong NH3) to ra 10,8 gam bc . 1. Vit cng thc cu to thu gn v gi tn X . 2. Vit cc phng trnh phn ng xy ra khi iu ch X t ankan tng ng .

Cho th sinh theo chng trnh chuyn ban

3. T X v cc cht v c hy vit cc phng trnh phn ng (c nu iu kin phn ng ) c dng iu ch : a) Etyl axetat b) Etylenglycol 4. Dng mt thuc th hy tm cch phn bit X vi cc cht va c iu ch trn ( cc cht ring bit nhau ).

Cu III b. in phn ( dng in cc tr ) dung dch mui sunfat kim loi ho tr 2 vi cng dng 3A.Sau 1930 giy thy khi lng catt tng 192 gam . 1. Vit phng trnh phn ng xy ra ti mi in cc v phng trnh chung cho qu trnh in phn . 2. Cho bit tn kim lai trong mui sunfat. 3. Hy tnh th tch ca lng kh to thnh ti ant 250C v 770 mmHg. 4. Nu kh thu c c ln hi nc hy gii thiu 3 ho cht c th lm kh kh . Cu IVb. Hy dng mt thuc th phn bit cc ho cht sau y ( ng trong tng l ring bit b mt nhn ) : axit propionic , glixerin , n-propanol , glacoz . Vit cc phng trnh phn ng gii thch cch phn bit.

I HC KIN TRC H NI
NM 1999

CU I: 1) Gang l g ?vit cc phng trnh phn ng xy ra trong qu trnh luyn gang ? 2) Hon thnh cc phng trnh phn ng sau : a) FeS2 + H2SO2 ,n b) FeSO4 + Br2 c) NaHCO3 + Ba(OH) 2 d) NaAlO2 + CO2 + H2O Cu II: T mtan v cc cht v c cn thit vit cc phng trnh phn ng iu ch polivinylaxtt. 1) So snh tnh cht ca ru propilic v ru iso- propilic. 2) Cho 3 cht CH3COOH ; HCOOCH3 v CH3COOCH3. . Hy nhn bit mi cht bng phn ng ho hc . Cu III: Ho tan hon ton hn hp 3 kim loi Zn, Cu v Ag vo 500 ml dung dch HNO3 a mol /l thu c 1,944 lt kh A ( ktc) ho nu trong khng kh v dung dch B .

1. Ly 1/2 dung dch B cho tc dng vi dubg dch NaCl d c 2,1525

gam kt ta D . Nung D nhit cao n khi lng khng i c 1,8 gam cht rn . Tnh s gam mi kim loi tronh hn hp ban u . 2. Nu cho m gam bt Cu vo 1/2 dung dch B khu u cho phn ng hon ton c 0,168 lt kh A ( ktc ) , 1,99 gam cht rn khng tan v dung dch E . Tnh m? tnh a mol/l ? tnh nng mi loi ion trong dung dch E . Bit th tch dung dch coi nh khng i . Cu IV: un nng hn hp 2 ru mch h vi H2SO4 cc hn hp cc ete. Ly X l mt trong cc ete em t chy hon ton th ta c t l: nx : n02 Mt khc khi cho axit A l ng ng ca axit xalc tc dng vi mt trong hai ru trn khi c mt ca H2SO4 c lm xc tc c este B . x phng ho hon ton 8,7 gam este B cn 200ml NaOH 0,5 M. Tm cng thc cu to ca 2 ru v axt A.

thi tuyn sinh i hc HSP H NI 2 NM 1999 PHn A(Cho tt c th sinh ) Cu I.(4 im) 1) in phn 2 lt dung dch CuSO4 0,5 M vi in cc tr . Sau mt thi gian , ngng in phn v cho i qua dung dch sau in phn mt lung kh A ly d th thu c 72 gam kt ta mu en . Bit rng khi t kh A trong oxi d th to thnh hi nc v kh B , kh B lm mt mu nc brm - Xc nh cng thc phn t ca cc kh A, B. - Tnh th tch kh thot ra ant (ktc) .

- Tnh th dung dch axit HNO3 60% (D = 1,37 g/ml ) cn thit ho tan lng kim loi kt ta trn ant. 2)Bit X l mt oxit kim loi . xc nh cng thc ca X , ngi ta lm 2 th nghim sau: Th nghim 1: Kh hon ton 1,6 gam X th cn 672 ml hiro (ktc). Th nghim 2: L lng kim loi thu c th nghim 1 ho tan trong dung dch axit clohyric d th thu c 448 ml hiro (ktc). Hy gii thch hin tng trn v xc nh cng thc ca X . Cu II. (4 im) 1) Cho mt hp cht hu c A tc dng vi dung dch NaOH un nng th to thnh hp cht hu c B v NaCl . Oxi ho B ta c hp cht hu c C , oxi ho C ta c hp cht hu c D (A,B,C ,D c cng s nguyn t cacbon ) . Cho D tc dng vi bt km th c kh hiro thot ra . Hy xc nh cng thc cu to ca A, B , C, D v vit cc phng trnh phn ng xy ra . Bit rng kh B b tch nc th to ra iso butilen ( 2-metylpropen ). 2) Hp cht hu c X l mt aminoaxit mch thng ,bit rng : - Cho 0,01 mol X tc dng va vi 80ml dung dch HCl 0,125 M to thnh 1,835 gam mui . - Cho 2,91 gam X tc dng vi mt lng dung dch NaOH va th to thnh 3,82 gam mui Xc dnh cng thc cu to v tn go ca X ,bit nhm amino lin kt vi cacbon v tr PHn B (Cho tng loi th sinh ) Cu III. A(2im ): (cho th sinh thi theo chng trnh Cha phn ban ) 1) Ho tan ln lt NaOH , Na2CO3 v NaHCO3 vo nc ta c dung dch A . Hy nhn bit cc ion c trong dung dch A . 2) Vit cc phng trnh phn ng iu ch propanol 2 t propanal(ghi r iu kin phn ng ). Cu IIIb.(2 im ): (cho th sinh thi theo chng trnh chuyn ban ) 1) Lm th no iu ch AlCl3 tinh khit t AlCl3 b ln mt lng nh CrCl3 2) Hy trnh by mt cch xc nh thnh phn nh lng ca mi ng phn trong hn hp gm CH3-COOH, HO- CH2-CHO v HCOO-CH3.
Trng i hc thu sn Nm 1999

A.phn chung Dnh cho tt c th sinh . Cu I : 1, a. Nu nguyn tc v phng php iu ch kim loi ?

b. Gii thch hin tng xy ra khi cho 1 ming Al nguyn cht vo 1 ng nghim ng nc ,sau nh t t dung dch NaOH VO ng nghim . Vit phng trnh phn ng xy ra . 2. a) C 3 cht hu c n chc c cng nhm nh chc : CH2O2 , C2H4O2 , C3H4O2 . Hy cho bit cng tc cu to v gi tn 3 cht ? b) Hon thnh s bin ho v vit cng thc cu to ca cc cht X, Y, Z: H2O Trng hp +H2 Trng hp CaC2X Caosu Buna Y Z (x.t) Cu II. Cho 4,6 gam hn hp gm Rb v mt kim loi km M tc dng vi nc th thu c 1 dung dch km . trung ho hon ton dung dch kim ny ngi ta phi dng ht 800 ml dung dch HCl 0,25 M. a) Xc nh xem kim loi M l kim loi no ? b) Tnh thnh phn % v khi lng ca kim loi trong hn hp ban u . c)Tnh th th kh thot ra trong phn ng khi hn hp tc dng vi nc O0C v 2atm Cu III: Mt hn hp kh gm H2 V 2 hydrcacbon c cng s nguyn t cacbon trong phn t (mt cht c 1 ni i v mt cht c 1 ni 3 ) . t chy hon ton 90 ml hn hp y th thu c 120 ml CO2 .Mt khc nu un nng 90 ml hn hp trn vi bt Ni n khi phn ng hon ton th ch cn li 40 ml 1hydrcacbon no duy nht . a) Tm cng thc phn t ca 2 hydrocacbon ? b) Tnh thnh phn % v th tch ca hn hp ban u ?
B- Phn ring

Cu IV a: Dnh cho th sinh theo chng trnh phn ban 1, a) Cho bt Fe vo dung dch CuSO4 th mu xanh ca dung dch nht dn , ngc li khi cho bt Cu vo dung dch Fe2(SO4)3 khng mu tr thnh c mu xanh m dn . Gii thch cc hin tng xy ra . b) C 5 mu kim loi : Ba , Mg , Fe ,Al , Ag.Nu ch c dung dch H2SO4 long ( khng dng bt c 1 ho cht no khc k c qu tm v nc nguyn cht ) c th nhn bit c nhng kim loi no bng phn ng c th ? 2. a) Bng phng php ho hc hy tch : CO2 , C2H4 , C2H2 ra khi hn hp . b) C hn hp 3 ng phn : CH3 CH2 COOH , CH3 COOCH3 , CH3 CH CHO OH

Hy nhn bit tng ng phn trong hn hp bng phng php ho hc . Cu IV b: Dnh cho th sinh theo chng trnh cha phn ban 1. a) Hy cho 2 phng php iu ch Na t 2 hp cht khc nhau ca Natri ? b) Tm 4 phng php khc mhau iu ch NaOH v vit phng trnh phn ng xy ra trong qu trnh iu ch ? 2. a) Vit cc phng trnh phn ng theo s sau: t0, p + Br2 + HOH O2 O2 C7H16 A1 A2 A3 A4 C6H5- OH C 6H 5 - COOC2H5 b) Vit cng thc cu to ca C4H6O2 . Bit rng khi cho cht tham gia phn ng trng gng cho ta 1 axit 2 ln axit .
i hc quc gia h ni

thi tuyn sinh i hc nm 1999 Mn thi Ho Hc . Khi A & B Thi gian 180 pht

A: phn dnh cho tt c cc th sinh Cu I 1. Trnh by phng php ho hc phn bit cc cp cht sau: a.Dung dch MgCl 2 v FeCl2. b.Kh CO2 v kh SO2 . Trong mi trng hp ch dng mt thuc th thch hp.Vit cc phng trnh phn ng. 2. Cho 5,22 gam mt mui cacbonat kim loi ( hp cht X).tc dng hon ton vi dung dch HNO3 . Phn ng lm gii phng ra hn hp kh gm 0,336 lit kh NO v x lt kh CO 2 . Cc th tich kh u c o KTC. a. Hy xc nh mui cacbonat kim loi v th tch kh CO2 .(x). b. Cho a gam hn hp gm FeS2 v hp cht X trn vi s mol bng nhau vo mt bnh kn cha lng oxi d , p sut trong bnh l p1 atm . un nng bnh phn ng sy ra hon ton ri a bnh v nhit ban u , p sut kh trong bnh lc ny l p2 at, khi lng cht rn thu c l b gam .Bit rng th tch cht rn trong bnh trc v sau

phn ng khng ng k .Hy xc nh cc t s p1/p2 v a/b .

Cu II 1. Nu nh ngha ru bc 2 . Vit cng thc cu to v gi tn cc ru bc hai c cng thc phn t C5H12O. un nng hn hp cc ru vi H2SO4 c 1800 C ; Hy vit cng thc cu to v gi tn cc sn phm chnh. 2. C nhiu v tai nn giao thng xy ra do ngi li xe ung ru .Hm lng ru trong mu ngi li xe kkhng c vt qu 0,02% theo khi lng . xc nh hm lng ru , ngi ta chun bng K2Cr2O7 trong mi trng axit ;khi y Cr2O7-2 cho Cr 3+ . a. Hy vit v cn bng phng trnh phn ng . b. Khi chun 25,0 gam huyt tng mu ca mt ngi li xe cn dng 20,0 ml K2Cr2O7 0,010 M . nu ngi y li xe th c hp php khng ? ti sao? Gi thit rng trong th nghim trn ch ring etanol tc dng vi K2Cr2O7 . 3. Hp cht A c cng thc phn t C2D6O ( D la teri), A tc dng vi natri gii phng mt cht kh .Hy xc nh cu to ca A v vit s iu ch n xut pht t cc cht v c cn thit.

B. Phn dnh cho tng loi th sinh Cu III1 : Dnh cho th sinh theo chong trnh cha phn ban: 1.Cho mt lng Cu2S tc dng hon ton vi dung dch HNO 3 un nng .Phn ng to thnh dung dch A1 v lm gii phng kh A2 khng mu v b ho nu trong khng kh.Chia A1 lm 2 phn .Thm dung dch BaCl2 vo phn 1 , thy to thnh kt ta trng A3 thc t khng tan trong axit d. Thm lng d dung dch NH3 vo phn 2,ng thi khuy u hn hp , thu c dung dch A4 c mu xanh lam m. a. Hy ch ra A1,A2,A3,A4 l g ? b. Vit cc phong trnh phn ng m t cc qu trnh ho hc va nu trn. 2. a. Vit cng thc cu trc v gi tn cc hirocacbon mch h c t khi hi so vi Nit bng 2 . b. Ngi ta iu ch mi hirocacbon trn t ru tng ng (c cng mch cacbon). Hy cho bit iu kin chung ca phn ng ; vit cng thc cu to thu gn ca cc ru.

Cu III2 : Dnh cho th sinh thi theo chng trnh KHTN 1. a. Tnh pH ca dung dch A l hn hp gm HF 0,1M v NaF 0,1M. b. Tnh pH ca 1 lit dung dch trn trong 2 trng hp sau: - Thm 0,01 mol HCl vo. - Thm 0,01 mol NaOH vo. Bit hng s axit ( Hng s in ho ) ca HF l K a =6,8 . 10-4 . Cho log 6,8 =0,83. 2. a.Ankaien l g ? Vit cng thc cu trc v gi tn ankaien C5H8 m c ng phn cis-trans. b.Trong tinh du chanh c cht limonen C10H16 ( Xem cng thc bn). Hir ho limonen thu c mentan C10H20 .Hy vit phng trnh phn ng v cng thc cu toca mentan . c.Cho limonen tc dng vi nc ( axit xc tc) thu c tecpinhirat C10H20O2 dng lm thuc ho . Hy vit phng trnh phn ng v cng thc cu to ca tecpinhirat ; gii thch hng ca phn ng .
.

CH2 CH3 CH3 Cu III3 : Dnh cho th sinh theo chng trnh ban KHTN KT 1.a. Trnh by nguyn tc ca phng php amoniac iu ch Na2CO3 .Vit cc phong trnh phn ng minh ho . b. Cho dung dch NaOH 25% c khi lng ring D = 1,28 g /ml . Hi 150 ml dung dch kim c kh nng hp th ti a bao nhiu lit kh CO2 o iu kin tiu chun . 2.a. Hy xp xp CH 3COOH , CH3CH2CH2OH v C6H5OH theo trnh ttng tnh linh ng ca nguyn t hir. Bng phng php ho hc hy chng minh rng cc cht u c hir linh ng v chng minh s ng n ca trnh t sp xp . b. iu ch CH 3COOCH2CH2CH3 v CH3COOC6H5 ngi ta cho CH3CH2CH2OH tc dng vi CH3COOH v cho C6H5OH tc dng vi (CH3CO)2O .Vit cc phng trnh phn ng v cho bit phn ng no cn cht xc tc H2SO4 ,phn ng no cn NaOH . ______________________________

i hc lm nghip thi tuyn sinh nm 1999 mn ho hc

thi gian 180 pht

Cu I : 1. Vit phng trnh phn ng km theo iu kin ( nu c ) ca axit C3H7COOH vi tng cht sau : K, CaO, Na2CO3 , KOH ; ru etylic; ru C2H4(OH)2; CH3NH2 2. Xut pht t xenlulz (C6H10O5)n hy iu ch : a) C2H5OH b) C2H3COOC2H5 Cu II: C hn hp A cha cc cht Al, Mg, Al2O3 . Ly 20,1gam hn hp A cho tc dng vi dung dch NaOH d, sau khi phn ng xong thu c 6,72 lit kh H2 ktc. Mt khc nu ho tan ht 20,1 gam hn hp A vo V ml dung dch HCl 1 M th thu c 15,68 lit kh H2 (ktc) v dung dch B. Cn phi dng ht 299 ml dung dch KOH 1M mi trung ho ht lng axit cn d trong dung dch B. 1) Tm s gam mi cht c trong hn hp A. 2) Tnh V? Cu III : Hn hp B gm hai andehyt no, n chc, mch thng, k tip nhau trong dy ng ng. Khi cho 3,32 gam hn hp B tc dng vi dung dch AgNO3 trong dung dch amoniac (ly d) , thu c 10,8 gam Ag. Mt khc nu cho 3,32 gam hn hp B tc dng vi H2 d c xc tc Ni nung nng th thu c hn hp hai ru. Chia hn hp hai ru thnh hai phn bng nhau: Phn I cho tc dng vi Na d sinh ra V1 lit H2 27,30c v 1 atm. Phn II cho tc dng vi CH3COOH d c xc tc H2SO4 thu c b gam hn hp hai este. 1) Tm cng thc phn t v s mol ca mi andehyt trong B. 2) Tm V1 v b . Bit cc phng trnh phn ng xy ra hon ton. Cu IVa : Dnh cho th sinh cha phn ban 1. Vit phng trnh phn ng biu din s sau : Fe Fe FeCl2 Fe(OH)3 Fe2(SO4)3 FeSO4 2. Vit phn ng ca HNO3 long vi tng cht sau : Mg, FeO, Fe2O3, FeCO3. Cu IVb : Dnh cho th sinh trung hc chuyn ban 1. Vit phng trnh phn ng biu din s sau : CrO CrCl2 CrCl3 Cr(OH)3 Cr2O3 Cr Cr(NO3)3 2. Vit phn ng (nu c ) ca tng cht CrO, Cr2O3, CrO3 vi dung dch KOH; dung dch H2SO4 long.

trng i hc dn lp phng ng nm 1999 a. phn chung cho th sinh.

Cu 1: 1/ tm 3 phng php khc nhau iu ch CaCO3 , vit phng trnh phn ng. 2/ c 4 dung dch ng trong 4 cc mt nhn HCL,NaCL,NaOH,Na 2CO3,, hy nhn bit m ch c dng mt ho cht lm thuc th. 3/ hon thnh dy bin ho sau. vit phng trnh phn ng c ghi r iu kin: +H2O +M H2O

A G

-H2O

T.hp

CaC2 buna

X T.hp +M

cao su

4/ Vit ng phn mch h c th c ca hp cht hu c ng vi cng thc phn t C3H6O2. Cu 2: t chy hon ton m gam cht hu c A thu c 6,16 gam CO2 ; 1,89 gam H2O v lng oxi tham gia phn ngd va bng lng CO2 to ra. 1/ Tnh m v cng thc n gin nht ca A. 2/ Xc nh cng thc phn t, cng thc cu to ca A.bit A l mt monome c th to ra polime c tnh n hi cao. nu em trng hp A,ngoi sn phm chnh, cn c sn phm phno,nu c hy vit cng thc ca sn pgm ph . 3/ Dn 3,36 lt kh A (ktc) li t t qua 1 lt dung dch nc Brm 0,2 M,thy dung dch nc Brm mt mu hon ton v khng c khng kh bay ra. hy xc ng khi lng cc sn phm cng thu c. Bit sn phm cng v tr 1,2 gp 4 ln (v s mol) sn phm cng v tr 1,4. Cu 3: Ho tan 63,8 gam hn hp BaCL2 v CaCL2 vo 500 gam H2O thu c dung dch A.thm 500ml dung dch Na2CO3 1,4 M vo dung dch A,sau phn ng thu c 59,4 gam kt ta v dung dchB. 1/ Tnh nng phn trm ca mi mui trong dung dch A. 2/ Thm vo dung dch B mtlng va dung dch HCl 0,5 M (d=1,05g/ml) thu c dung dch C. Tnh th tch dung dch HCl 0,5 M dng v nng phn trm ca mui trong dung dch C. B. Phn dnh cho tng loi th sinh:(th sinh c th chn mt trong hai cu sau) Cu IVa. 1/ Ch t FeS2, khng kh, NaCL, H2O,cc cht xc tc, cc thit b, vit phn ng iu ch 4 axt v 3 hiroxt. 2/ So snh tnh cht ho hc ca benzenvi metan v vi etylen.Vit phn ng minh ho. Cu IVb. 1/Ho tan hon ton 0,5 gam mt hn hp gm Fe v kim lai B thuc nhm IIA(phn nhm chnh nhm II) bng mt lng d dung dch HCl thu c 1,12 lt H2 (ktc). Xc nh kim loi B. C th xc nh v tr ca B trong bng h thng tun hon hay khng?Vit cu hnh electron ca n. 2/ Cho bit qui lut th ca vng benzen. T benzen v cc ho cht cn thit vit phn ng iu ch : a/ Octo-bromo nitro benzen; meta-bromo nitro benzen. b/ Octo-amino phenol; meta-amino phenol. Bit C=12; H=1; O=16; Be=9; Br=80; Na=23; Ba=137; Ca=40; Cl=35,5;

Mg=24;

Fe=56;

Trng CSP Bc Ninh nm 1999 khi : b

A.phn chung cho c th sinh chuyn ban v cha chuyn ban.

Cu I:(2,5 im) vit phng trnh phn ng xy ra khi: 1)Nhit phn cc mui: MgCO3, AlNO3, KNO3, Ba(HCO3)2, Na2SO4, Cu(NO3)2. 2)in phn mt dung dch cha CuSO4 v NaCl. Cu II: (2,5 im)

Hp cht hu c A c cng thc (CHO)n A c th tc dng vi Na, NaOH, dung dch Br2.khi t chy 1 mol A cho di 6mol CO2.Hy bin lun tm cng thc phn t ca A v cc phng trnh phn ng xy ra. Cu III: (2 im) Mt loi phn ngm nc c to thnh t cation M +, Al3+ v SO42- . Nung 9,06 gam phn c 4,47 gam phn khan. Mt khc, cho 9,06 gam phn ho tan vo nc ri cho tc dng vi Ba(OH) 2 d c 9,32 gam kt ta A v kh C.Lng kh C to thnh tc dng va vi 100ml dung dch HCl 0,2 M. Xc nh cng thc phn t ca phn. Cu IV:(2 im) Hn hp X cha hai hn hp cht hu c no, cho 14,8 gam hon hp X tc dng vi 100ml dung dch AgNO3 2M trong amoniac d n khi phn ng xy ra hon ton v trong dung dch ht ion Ag+ . Ly hn hp mui amoni to thnh cho tc dng vi axit sunfuric long, d ri chng ct thu c axit hu c Y. Cho lng axit to thnh tc dng va vi 100 ml dung dch NaCO31M thy to thnh 16,4 gam mui . Xc nh cng thc phn t ca cc cht trong hn hp X v tnh thnh phn phn trm mi cht theo khi lng.
B/ Phn ring dnh cho tng loi i tng th sinh.

CuVa:(1 im) Dnh cho th sinh chuyn ban: Xc nh v tr ca cc nguyn t c s proton l 29, 42, 31, 35 trong bng h thng tun hon. CuVb (1 im) Dnh cho th sinh chuyn ban; Xc dnh v tr ca cc nguyn t c s proton la 31, 35, 27, 21 trong bng h thng tun hon. Cho bit :AL=27, S=32, O=16, H=1, Ba=137, CL=35,5. N=15, C=12, Na=23. Ch :Cn b khng gii thch g thm

thi tuyn sinh i hc nm 1999 trng i hc hng hi

(Ch :th sinh cha phn ban (CPB) lm cc cu1, 2, 3, 3, 4A;th sinh chuyn ban(CB) lm cc cu1,2, 3, 4b) Cu I. 1.1 . Cho bit cc loi nguyn liu chnh dng sn xut gang: nguyn tc v cc phn ng ho hc xy ra trong qu trnh sn xut gang. 1.2. Vit phng trnh phn ng theo s sau y; (dung dch NH3 ) A + AgNO3 B + C + Ag. B + NaOH (t0) (t0). D + H2O + NH3 D + NaOH E + Na2CO3. CaO

(askt) F + Cl2 G +HCl. (t0) G + NaOH CH3OH + H2. (Cc cht A, B, C, .... , H vit dng cng thc cu to vn tt). Cu II. Hn hp A gm Mg v kim loai M ho tr 3, ng trc Hydro trong dy hot ng ho hc. Ho tan hoan ton 1,275 gam A vo 125 ml dung dch B cha ng thi HCl nng C1 (M) v H2SO4 nng C2 (M). Thy thot ra 1400 ml kh Hydro (o ktc) v dung dch D. trung ho hon ton lng axit d trong D cn dng 50 ml dung dch Ba(OH)2 1M . Sau khi chung ho D thu c 0,0375 mol mt cht kt ta khng tan trong HCl. 1.1. Vit cc phng trnh phn ng dng ion thu gn. 1.2. Tnh C1 v C2 ca dung dch B. 1.3. Tm nguyn t khi ca kim loi M(AM) v khi lng mi kim loi trong hn hp A em th nghim. Bit rng ho tan 1,35 gam M cn khng qu 2000 ml dung dch HCl 1M. Cu III. t chy hon ton mt lng gm hai ru X v Y l hai ng ng lin tip ca dy ng ng ru no n chc, thu c 1,12 l khi CO2. Cng vi lng hn hp trn cho phn ng vi Na d th thu c 2,24 l Hydro .Cc th tch kh o iu kin tiu chun. 3.1. Xc nh cng thc phn t 2 ru trn. Tnh thnh phn phn trm mi ru trong hn hp . 3.2. Phn t X c s nguyn t cacbon t hn phn t Y.Sn phm oxi ho t t ca Y khng tham gia phn ng vi dung dch AgNO3(c dung dch NH3). - Vit cng thc cu to ca Y. - Vit phng trnh phn ng este ho ca X v Y vi axit Metacrylic (km theo iu kin nu c). Nu ng dng ca sn phm este ny trong thc t. Cu 4 A 1. Hn hp kim loi vn gm Al, Fe, v Ag,.hy trnh by phng php ho hc tch ring mi kim loai trn khi hp cht trn v dng nguyn cht 2.a. vit phng trnh phn ng iu ch Anilin t Benzen, km theo iu kin phn ng nu c. b. Hon thnh s d phn ng sau dng vit thnh phng trnh phn v gi tn cc cht X, Y, Z. + HNO3 CH3 - CH3 - COOH X Y Z + N2 +H2O C2H5OH +HCl +NH3 X | HCl (xt) NH2 Cu4B. 1. Hn hp gm Al2O3 v ng vn .Hy trnh by phng php ho hc tch mi cht ra khi hn hp tn v dng ngun cht. 2.Trng by quy tc Ziasep v tch nc ca ru v quy tc cng HX vo Anken ca Maccopnhicop. Vit cng thc cu to cc cht A, B, C, D, E, G trong dy chuyn ho sau. H2SO4 H2O;t0 a. CH3 - CH2 - CH2 - CH2 - CH2OH A B. H2SO4 H2SO4 ,t0 Br2(dung dch) b. C5H11OH D CH3 - CHBr - CH2 -CH3 . Cl H2SO4(,t0 ) +HCl | c. C5H10OH G CH3 -C - CH2 - CH3 (E) xc tc | CH3

i hc thu li nm 1999 Cu I: 1/ Hon thnh s phn ng sau ( mi mi tn l mt phn ng ).

Cr K2CrO4

CrCl2 K2Cr2O7

CrCl3

Cr(OH)3

KCrO2

Cr 2O3 2/ Cho cht lng l : axton , anehit propionic v ru iso propylic ng trong 3 l ring bit b mt nhn hiu . a) Hy phn bit 3 cht trn bng cc phn ng ho hc . b) Trnh by cc phn ng axeton t nguyn liu ban u l mn ca ( cc cht v c , xc tc v iu kin cn thit c ). Cu II. 1. ho tan 4 gam FeXOY cn 52, 14 ml dung dch HCl 10% ( D = 1,05 g/ml ) . Hy xc nh cng thc phn t ca st oxit . 2. Oxy ho ru etylic bng xc tc ta thu c hn hp A gm anhit , axit axetic , nc v mt phn ru khng b oxi ho . a) Vit cc phng trnh phn ng xy ra trong cc qu trnh ni trn . b) Cn dng phn ng g nhn bit s c mt ca ru trong hn hp A ? c) Trnh by cc phn ng ho hc ( c iu kin v xc tc cn thit ) iu ch axit axtic nguyn cht v cao su Buna t hn hp A . Cu III. Hn hp Y gm 3 kim loi Na, Al , Fe c nghin nh trn u . Chia Y thnh 3 phn bng nhau : - Ho tan hon ton phn 1 trong 0,5 lit dung dch HCl 1,2 M sinh ra 5,04 lit kh v dung dch A . - Ho tan hon ton phn 2 bng dung dch NaOH (d ) sinh ra 3,92 lit kh . - Cn phn 3 cho tc dng vi H2O (d)sinh ra 2,24 lit kh . 1. tnh s gam mi kim loi trong hn hp Y . 2. Cho dung dch A tc dng vi 300ml dung dch KOH 2M.Thu ly kt ta,ra sch ri nung ngoi khng kh n khi lng khng i th c a gam cht rn.Tnh khi lng a. ( Cc th tch trong bi u o ktc) Cu IV . Mt hn hp cht hu c A c cu mch thng ,thnh phn ch gm C, H v O. Bit rng trongA t l nguyn t H v O l 2:1 v t khi hi ca A so vi hyro l 36. 1. Xc nh cng thc cu to c th c ca A . 2. un nng 3,96 gam mt ng phn ca A vi dung dch HCl long n khi phn ng xy ra hon ton thu c hn hp 2 cht hu c B v C (cng chc) . Cho B v C phn ng hon ton vi Ag2O trong dung dch NH3 th c m gam Ag v kh CO2 ( vi gi thit CO2 khng phn ng dung dch NH3 ) . Cho ton b kh CO2 hp th ht vo 250 ml dung dch Ca(OH)2 0,12 M c dung dch D . a) Tnh khi lng m. b) Tnh nng mol/l ca cc cht trong dung dch D.