VN 3.

BI TP HU C TRNG IM I HC 2012
Cu 1. Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hn hp gm 56,96 gam Ala, 64 gam Ala-Ala v 55,44 gam Ala-Ala-Ala. Gi tr ca m l A. 163,08. B. 111,74. C. 81,54. D. 66,44.

Cu 2. Thy phn hon ton 120 gam hn hp hai ipetit thu c 127,2 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu c l : A. 7,09 gam. B. 70,9 gam C. 8,15 gam D. 156,4 gam.

Cu 3. Cho 400 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 415,1 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l: A. 31 gam B. 62 gam C. 60 gam D. 31,45 gam

Cu 4. Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm -NH2. Phn trm khi lng ca N trong X l 18,667%. Thu phn khng hon ton ht m gam hn hp M, Q (t l mol 1 : 1) trong mi trng axit thu c 0,945 gam M ; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l A. 58,725. B. 5,580. C. 9,315. D. 8,389.

Cu 5. Cho 0,15 mol H2NC3H5(COOH)2 (axit glutamic) vo 125 ml dung dch HCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l A. 0,30. B. 0,45. C. 0,25. D. 0,55.

Cu 6. Cho 0,1 mol hp cht hu c c cng thc phn t CH6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng, sau khi phn ng xy ra hon ton thu c cht kh lm xanh giy qu tm m v dung dch Y. C cn dung dch Y thu c m gam rn khan. Gi tr ca m l A. 21,8. B. 15,0. C. 12,5. D. 8,5.

Cu 7. Cho 11,2 lt (ktc) hn hp X gm eten, propen v hiro c t khi so vi heli bng 3,94. Trong X, t l mol ca eten v propen l 2 : 3. Dn X qua bt Ni, t0 thu c hn hp Y c t khi so vi hidro bng 12,3125 (gi s hiu sut phn ng hiro ho hai anken l nh nhau). Dn Y qua bnh cha dung dch brom d thy khi lng bnh brom tng m gam. Tnh m A. 0,728 gam B. 3,2 gam. C. 6,4 gam D. 1,456 gam

Cu 8. Dn 5,6 lt axetilen ( ktc) qua cc nc cha Hg2+, un nng nh. Dn ton b kh thot ra qua dung dch AgNO3/NH3 d thu c 55,2 gam kt ta. Nu dn kh thot ra qua lng d dung dch nc Br2 th c bao nhiu gam brom phn ng A. 32 gam B. 48 gam C. 40 gam D. 16 gam

Cu 9. Oxi ho 6,4 gam mt ancol n chc thu c 9,92 gam hn hp X gm anehit, axit, nc v ancol d. Nu cho hn hp X tc dng ht vi NaHCO3 th thu c 1,344 lt CO2 ktc. Nu cho hn hp X tc dng vi dung dch AgNO3/NH3 d th khi lng kim loi bc thu c l A. 34,5 gam B. 45,90 gam C. 56,16 gam D. 21,6 gam Cu 10. Cho butan-1,2,4-triol tc dng vi hn hp hai axit cacboxylic n chc th thu c ti a bao nhiu trieste A. 10 B. 6 C. 4 D. 8

Cu 11. Hn hp X gm bn hp cht hu c u c cng thc phn t l C3H9NO2. Cho hn hp X phn ng vi dung dch KOH va th thu c 1344 ml (ktc) hn hp kh Y mi khai c t khi hi so vi hiro l 17,25 v dung dch Z. C cn dung dch Z thu c m gam cht rn khan. Gi tr ca m l A. 5,67 gam B. 4,17 gam. C. 5,76 gam. D. 4,71 gam ----------------------------------------------Cu 12. Mt hn hp X gm CH3OH; CH2=CH-CH2OH; CH3CH2OH; C3H5(OH)3. Cho 25,4 gam hn hp X tc dng vi Na d thu c 5,6 lt H2 (ktc). Mt khc, em t chy hon ton 25,4 gam hn hp X thu c a mol CO2 v 27 gam H2O. Gi tr ca a l A. ,25 B. C. ,4 D. ,2 Cu 13. Hn hp X gm axit axetic, axit fomic v axit oxalic. Khi cho m gam X tc dng vi NaHCO3 d th thu c 15,68 lt kh CO2 (ktc). Mt khc, t chy hon ton m gam X cn 8,96 lt kh O2 (ktc), thu c 35,2 gam CO2 v y mol H2O. Gi tr ca y l A. 0,8. B. 0,3. C. 0,6. D. 0,2.

Cu 14: X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va .Gi tr m l A. 68,10 gam. B. 64,86 gam. C. 77,04 gam. D. 65,13 gam Cu 15: Cho a mol cht bo X cng hp ti a vi 5a mol Br2 . t a mol X c b mol H2O v V lt CO2 .Biu thc lin h gia V, a v b l A. V = 22,4.(4a - b). B. V = 22,4.(b + 5a).C. V = 22,4.(b + 6a). D. V = 22,4.(b + 7a). Cu 16. X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amoni axit no mch h, c mt nhm COOH v mt nhm NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O v N2 c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? A. 87,3 gam B. 9,99 gam C. 107,1 gam D. 94,5 gam

Cu 17. Khi nung butan vi xc tc thch hp thu c hn hp T gm CH4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hn hp T thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp T lm mt mu va ht 12 gam Br2 trong dung dch nc brom. Hiu sut phn ng nung butan l: A. 75%. B. 65%. C. 50%. D. 45%. Cu 18. Crackinh pentan mt thi gian thu c 1,792 lt hn hp X gm 7 hirocacbon. Thm 4,48 lt H2 vo X ri nung vi Ni n phn ng hon ton thu c 5,6 lt hn hp kh Y. (th tch kh u o ktc). t chy hon ton Y ri cho sn phm chy hp th vo nc vi trong d, khi lng kt ta to thnh l: A. 25 g B. 35 g C. 30 g D. 20 g Cu 19. Hn hp X gm: HCHO, CH3COOH, HCOOCH3 v CH3CH(OH)COOH. t chy hon ton hn hp X cn V lt O2 (ktc) sau phn ng thu c CO2 v H2O. Hp th ht sn phm chy vo nc vi trong d thu c 30 gam kt ta. Vy gi tr ca V tng ng l A. 8,40 lt. B. 6,72 lt. C. 7,84 lt. D. 5,60 lt. Cu 20. t chy hon ton 29,16 gam hn hp X gm RCOOH, C2H3COOH, v (COOH)2 thu c m gam H2O v 21,952 lt CO2 (ktc). Mt khc, 29,16 gam hn hp X phn ng hon ton vi NaHCO3 d thu c 11,2 lt (ktc) kh CO2. Gi tr ca m l A. 10,8 gam B. 9,0 gam C. 8,1gam D. 12,6 gam. Cu 21. Cho hn hp X (gm CH3OH, C2H4(OH)2, C3H5(OH)3 c khi lng m gam. t chy hon ton m gam hn hp X thu c 5,6 lt kh CO2 ( ktc). Cng m gam hn hp X trn cho tc dng vi Na (d) thu c V lt kh H2 (ktc). Ga tr ca V l: A. 2,8 B. 3,36 C. 11,2 D. 5,6

Cu 22. un nng m gam hn hp (X) gm axit cacboxylic Y v este Z u n chc vi 400 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c p gam ancol R ( % O theo khi lng l 34,79) v 24,4 gam hn hp rn khan E gm hai cht c s mol bng nhau. Cho p gam R tc dng vi Na (d) thu c 0,56 lt kh. Gi s cc kh o ktc, hiu sut phn ng 100%. Gi tr m l A. 13,4g B. 14,8g C. 12,7g D. 8,7g

Cu 23: Este E (khng cha nhm chc no khc) c to t axit cacboxylic X v mt ankanol Y. Ly m gam E tc dng vi dung dch KOH d thu c m1 gam mui; m gam E tc dng vi dung dch Ca(OH)2 d thu c m2 gam mui. Bit rng, m2<m<m1. Cng thc thu gn ca Y l:
A. C3H7OH. B. C4H9OH C. C2H5OH D. CH3OH

Cu 24. Axit c v chua me l A. axit axetic B. axit oxalic

C. axit xitric

D. axit tactric

Cu 25. Cho hp cht hu c X c cng thc phn t CxHyO2 (trong % theo khi lng oxi l 23,53). Bit X tc dng vi dung dch KOH theo t l mol l 1 : 2. S ng phn cu to ca X tha tnh cht trn l A. 4. B. 10. C. 7. D. 6.

Cu 26. t chy hon ton 100 ml hn hp (X) gm metylamin v hai anken A, B thu c 289 ml kh CO2 v 319 ml hn hp kh N2 v hi H2O, ( cc kh o cng iu kin nhit , p sut). Mt khc ly 0,7 mol hn hp hai anken A, B tc dng ht vi dung dch brom, thu c m gam dn xut dibrom. Gi tr ca m l A. 136,5. B. 143,6. C. 138,46. D. 146,3.

Cu 27. S cht l ng phn cu to ca C7H16 c cha nguyn t cacbon bc 3 trong phn t l A. 4 cht B. 5 cht C. 6 cht D. 7 cht

Cu 28. X l mt -Aminoaxit no, cha 1 nhm -COOH v 1 nhm -NH2. T m gam X iu ch c m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam ipeptit thu c 0,3 mol nc. t chy m2 gam tripeptit thu c 0,55 mol H2O. Gi tr ca m l: A. 11,25 gam B. 13,35 gam C. 22,50 gam D. 26,70 gam

Cu 29. X l ipeptit Ala-Glu, Y l tripeptit Ala-Ala-Gly. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:2 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 56,4 gam cht rn khan. Gi tr ca m l: A. 45,6 B. 40,27. C. 39,12. D. 38,68.

Cu 30: Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l: A. 5. B. 4. C. 7. D. 6. Cu 31. X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 amin. S CTCT ph hp ca X l: A. 5 B. 3 C. 4 D. 2

Cu 32. Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CONH trong 2 phn t l 5) vi t l s mol nX : nY = 1: 2. Khi thy phn hon ton m gam M thu c 12 gam glixin v 5,34 gam alanin. m c gi tr l : A. 14,46g B. 110,28g C. 16,548 D. 15,86g Cu 33. Hn hp X c C2H5OH, C2H5COOH, CH3CHO (trong C2H5OH chim 50% theo s mol). t chy m gam hn hp X thu c 2,88 gam H2O v 2,912 lt CO2 (ktc). Mt khc 9 gam hn hp X thc hin phn ng trng bc thy c p gam Ag kt ta. Gi tr ca p l A. 12,96. B. 4,32. C. 8,64. D. 5,4. Cu 34. T khi ca mt hn hp kh ( gm 2 hidrocacbon mch h) so vi hidro l 17. iu kin tiu chun, trong bng ti, a mol ml hn hp tc dng va vi dung dch cha 0,8 a mol brom . Sau phn ng s mol kh cn li l 0,6 a mol . Cng thc phn t ca 2 hidrocacbon l: A. C2H2 v C3H8 B. CH4 v C4H6 C. C2H6 v C3H6 D. C2H6 v C3H4 Cu 35. Hn hp (X) gm metan, etylen, propan, vinylaxetilen. t chy ht m gam (X) ri cho sn phm chy hp th ht vo nc vi d, thu c a gam kt ta v khi lng dung dch nc vi sau phn ng gim b gam. Biu thc tnh m theo a, b l A. m 1,46a + b
9

B. m 1,46a - b
9

C. m 1,32a - b
9

D. m 1,32a + b
9

Cu 36. Cho mt hp cht hu c n chc (X) tc dng va dung dch cha 0,3 mol AgNO3/NH3 thu c kt ta. X l A. 2 metyl but 3-inal B. But 1inal C. But 2inal D. But 3inal

Cu 37. Hn hp X gm 2 este n chc. Cho 0,5 mol X tc dng vi dung dch AgNO3/NH3 thu c 43,2 gam Ag.Cho 14,08 gam X tc dng va vi dung dch KOH thu c hn hp mui ca hai axit ng ng kt tip v 8,256 gam hn hp hai ancol no h ng ng lin tip A, B ( MA < MB). Cng thc ca ancol(A) l A. CH3OH B. C2H5OH C. C3H7OH D. C4H9OH Cu 38. t chy hon ton 18 gam mt este n chc X thu c 20,16 lt kh CO2 v 12,96 gam H2O. Nu ly 21 gam X tc dng vi 200 ml dung dch KOH 1,2M c cn dung dch sau phn ng thu c 34,44 gam cht rn. Tng s nguyn t ca axit to ra X l A. 14 B. 18 C. 16 D. 17 Cu 39. Cho 3,56 gam alanin tc dng ht vi dung dch HNO2 thu c cht hu c X. Cho X tc dng vi kim loi K d, thu c m gam mui v V lt H2 o ktc. Gi tri m v V l A. 6,64 v 0,896 lt B. 5,12 v 0,488 lt C. 6,64 v 0,488 lt D. 6,96 v 0,896 lt

Cu 40. t chy hon ton 0,12 mol mt amin, no h bng oxi va thu c 0,6 mol hn hp gm CO2, H2O v N2. Cho 9,2 gam X tc dng va vi HCl. S mol HCl phn ng l A. 0,4 B. 0,3 C. 0,1 D. 0,2 Cu 41. Hn hp X gm 1 ankan v 1anken. Cho X tc dng vi 4,704 lt H2 o ktc. Sau khi phn ng xy ra hon ton thu hn hp Y gm 1 hidrocacbon v H2. t chy hon ton Y ri cho sn phm chy vo bnh nc vi d, thy khi lng bnh tng 16,2 gam v c 18 gam kt ta to thnh. Cng thc ca hai hidroacbon l A. C2H6 v C2H4 B. C2H8 v C3H6 C. C4H10 v C4H8 D. C5H10 v C5H12 Cu 42. Cho cc hp cht hu c thuc: ankadien; anken,ankin,ancol khng no ( 1 ni i) mch h, hai chc. Andehit no mch h hai chc. Axit khng no (c 1 ni i), mch h, n chc. amino axit ( c mt nhm chc amino v 2 nhm chc cacboxylic), no, mch h. Tng cc loi hp cht hu c trn tha mn cng thc CnH2n-2OxNy ( x, y thuc s nguyn) l A. 4 B. 5 C. 3 D. 2 Cu 43. X l este c cng thc phn t l C9H10O2, a mol X tc dng vi dung dch NaOH th c 2a mol NaOH phn ng. S ng phn cu to ca X tha mn tnh cht trn l: A. 6. B. 9. C. 12. D. 13. Cu 44. Cho phn ng:
CH=CH2 COOK

+
CH3

KMnO4

+ K2CO3 + KOH + MnO2 + H2O

COOK

Tng h s (nguyn, ti gin) ca cc cht tham gia phn ng trong phng trnh ha hc trn l: A. 20. B. 16. C. 19. D. 13. P N VN 3 1A 2D 3B 4D 5D 6C 7A 8B 9C 10D 11A 12D 13C 14A 15D 16D 17A 18A 19B 20D 21A 22A 23C 24B 25B 26B 27C 28A 29C 30A 31D 32A 33A 34D 35B 36D 37B 38B 39A 40A 41A 42A 43D 44C
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