BI 2: XC NH DN IN NG LNG CC I CA CHT IN LY MNH V CHT IN LY YU

I. Phng php: dn in ng lng cc i ca cht in ly mnh CH3COONa, NaCl, HCl c xc nh t dn in cc nng khc nhau nh nh lut Conraus (1) o dn in ring ca cc chui dung dch ca cc cht trn cc nng bit

trc. dn in ng lng c tnh t dn in ring o c theo biu thc (2) l dn in ring ca nc dng pha dung dch. Nu b qua trong biu thc (2). Dng ng thng biu din ph thuc c . << th c th

ri ngoi suy v tung gc (

dn in ng lng cc i ca cht in ly yu CH3COOH khng th xc nh bng phng php trn m c tnh gin tip t dn in ng lng cc i ca cht in ly mnh c ion chung nh CH3COONa, NaCl v HCl. II. Ha cht v dng c: KCl 0.1N NaCl 0.1N HCl 0.1N CH3COONa 0.1N My o dn My khuy t Beaker 50ml, 100ml Burette 25ml Pipette 10ml Bnh nh mc 100ml

III. Thc nghim: 1. Chun b cho th nghim:

Ra sch tt c m dng c thy tinh, trng bng nc ct. Ra sch in cc nhiu ln bng nc ct,cho n khi dn ca nc ra xung di 2 cm-1.

Ghi nhn dn ca nc ct dng pha dung dch, lu nc ct phi c dn di 2 cm-1.

Lu : ch dng nc ct cho th nghim. 2. Hiu chnh my Ly 10ml dung dch KCl 0.1M cho vo bnh nh mc 100ml. Thm nc n vch nh mc c dung dch chun KCl 0.01M.

a nhit quy chiu ca my o dn v 250C.

a h s nhit ca dn v 1.91%. Ly khong 40ml dung dch KCl 0.01M va pha vo cc 50ml. Trng in cc nhiu ln.

b dung dch . Ly li 50ml dung dch chun KCl 0.01M, o v ghi dn . Ghi nhn hng s in cc K1.

Tnh hng s in cc mi K2 theo biu thc

= K1.

Chnh hng s in cc v gi tr K2 va tnh c.

Chnh h s nhit v 0 dn in hin th l dn nhit th nghim.

3. Xc nh dn in ng lng cc i ca CH3COOH

Pha 100ml dung dch vi nhng nng sau t dung dch CH3COONa 0.1N. 5.00 x 10-2N 1.00 x 10-2N 3.00 x 10-2N 6.00 x 10-3N 1.50 x 10-2N 3.00 x 10-3N

Lu : Th tch dung dch ly pha long khng c di 10ml m bo chnh xc cn thit. Dng buret c chnh xc 0.05ml ly dung dch . Cn la chn cc dung dch dng pha long sao cho t phi ra, trng dng c nht. Ghi s liu dng pha dung dch vo bng.

STT

Dung dch trc pha long Th tch nng pha long

Dung dch sau pha long Th tch sau nng pha long

dung dch pha vo cc 50ml sch. Nh trng cc bng chnh dung dch s ng.

Cho cc cc ng dung dch va pha vo bnh n nhit. Ch cc cc cng ngp su trong nc cng tt. Ch cho cc dung dch n nh v nhit phng. Trong

lc ch i ra sch in cc bng nc ct cho n khi dn ca nc ra xung di 2 cm-1. Trong lc ch n nh nhit hy pha cc chui dung dch k

tip tit kim thi gian.

o dn ca tng dung dch , bt u t dung dch long nht nh sau. t nh giy lau pha bn ngoi cc l ca in cc thm kh in cc. Tuyt i khng a giy lau vo trong in cc. a in cc vo dung dch sao cho dung dch ngp l trn thnh in cc. Trng in cc vi ln bng cch nng ln v h in cc xung. Ch n khi n nh mi ghi nhn gi tr dn v nhit vo bng.

Lu : Nhit ca cc dung dch khng c chnh lch qu o ln lt t dung dch long n dung dch c. Cht in ly: dn in ring ca nc ct: STT CN T(0C)

0.1oC.

Lp li bc 1 n bc 3 cho NaCl v HCl. Tnh cc i lng cn li trong bng cho mi chui dung dch . Lu n v ca cc i lng.

Dng th

cho mi chui dung dch . Dng ng hi quy tuyn

tnh. Tnh phng trnh hi quy. Xc nh dn in ng lng cc i. Ngoi suy ng hi quy v tung gc xc nh dn in ng lng cc i. So snh gi tr ly t th v gi tr t phng trnh hi quy.

Tnh dn in ng lng cc i ca CH3COOH.

So snh dn in ng lng cc i thc nghim ca CH3COONa, NaCl, HCl v CH3COOH vi cc gi tr tra cu t s tay ha l.

Nhn xt v thc nghim.