TRNG I HC VINH TRNG THPT CHUYN

THI KHO ST CHT LNG LP 12 LN CUI NM 2012 Mn: HA HC (Thi gian lm bi: 90 pht; 50 cu trc nghim) M thi 132

H v tn .................................................................. S bo danh ..........................

Cho khi lng nguyn t ca cc nguyn t (theo vC): C = 12; H = 1; O = 16; S = 32; Cu = 64; Fe = 56; Al = 27; N = 14; Li = 7; Na = 23; Mg = 24; Cl = 35,5; Rb = 85; K = 39; Pb = 207; Ag = 108; Br = 80. A. PHN CHUNG CHO TT C TH SINH (40 cu: T cu 1 n cu 40) Cu 1: T nilon-6,6 l sn phm trng ngng gia hexametylen iamin vi axit A. picric. B. phtalic. C. benzoic. D. aipic. Cu 2: Cho cc cht NaCl, FeS2, Fe(NO3)2, NaBr, CaCO3, NaI. C bao nhiu cht m khi tc dng vi dung dch H2SO4 c, un nng th c phn ng oxi ha-kh xy ra? A. 3. B. 6. C. 5. D. 4. Cu 3: Cho 10,1 gam hn hp X gm hai ancol n chc X1, X2 thuc cng dy ng ng (X1 chim 80% v s mol v MX 1 < MX 2 ) tc dng ht vi 6,9 gam Na kt thc phn ng thu c 16,75 gam cht rn. Cng thc ca X1, X2 ln lt l A. C2H5OH v C3H7OH. B. CH3OH v C4H9OH. C. CH3OH v C2H5OH. D. C2H5OH v C4H9OH.
+ NaOH Cu 4: Cho s phn ng: C2H4 X Y ,t X. Trong s cc cht CH3CHO, CH3COOH, CH3COOC2H5, C2H5OH, C2H5Cl, s cht tha mn vi iu kin ca X l A. 2. B. 4. C. 1. D. 3. Cu 5: Ha tan 51,1 gam hn hp X gm NaCl v CuSO4 vo nc c dung dch Y. in phn dung dch Y vi in tr mng ngn xp n khi nc bt u b in phn 2 in cc th dng li, th th tch kh anot sinh ra gp 1,5 ln th tch kh sinh ra catot (cc th tch kh o cng iu kin nhit , p sut). Phn trm khi lng ca CuSO4 trong hn hp X l A. 94,25%. B. 73,22%. C. 68,69%. D. 31,31%. Cu 6: Dung dch cha 0,6 mol H2SO4 c, un nng ha tan ht m gam Fe, sau phn ng ch thu c dung dch X v kh SO2 (sn phm kh duy nht). Gi tr m l A. 15,40. B. 22,75. C. 8,60. D. 8,96. Cu 7: Hp cht hu c Y cha C, H, O trong oxi chim 55,17% theo khi lng v c s phn ng:
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X Y X Z X. X, Y, Z ln lt l B. C2H4Cl2, (CHO)2, (COOH)2. A. C2H4(OH)2, (CHO)2, CH2Cl-CH2Cl. C. (COOH)2, (CHO)2, CH2Cl-CH2Cl. D. CH3OH, CH2O, CH3Cl. Cu 8: Dung dch NaHSO4 tc dng c vi tt c cc cht c trong nhm no sau y? A. NaNO3, AlCl3, BaCl2, NaOH, KOH. B. BaCl2, NaOH, FeCl3, Fe(NO3)2, KCl. C. NaHCO3, BaCl2, Na2S, Na2CO3, KOH. D. Na2S, Cu(OH)2, Na2CO3, FeCl2, NaNO3. Cu 9: Cho m gam bt Mg vo 500 ml dung dch FeCl3 1M. Sau khi cc phn ng xy ra hon ton, khi lng dung dch thay i 2,4 gam so vi dung dch ban u (nc bay hi khng ng k). Gi tr no ca m trong cc gi tr sau l khng tha mn? A. 2,4. B. 12,3. C. 8,7. D. 9,6. Cu 10 Cho m gam mt kim loi tc dng va vi 12,5m gam dung dch H2SO4 14% (long), sau khi phn ng xy ra hon ton thu c dung dch X. Dung dch X c khi lng th no so vi dung dch H2SO4 ban u? (bit trong qu trnh phn ng nc bay hi khng ng k) A. Tng 8,00%. B. Tng 2,86%. C. Tng 7,71%. D. Tng 8,97%. Cu 11: Cho 30,8 gam hn hp Cu v Fe3O4 tc dng vi dung dch cha a mol HNO3. Sau khi cc phn ng xy ra hon ton thu c 2,24 lt kh X (sn phm kh duy nht, ktc), dung dch Y cha 64,6 gam mui nitrat v cn li 6,4 gam kim loi. Cng thc phn t kh X v gi tr ca a ln lt l A. NO2 v 0,2. B. NO v 0,7. C. NO v 0,8. D. N2O v 1,0. Cu 12: t chy hon ton x mol hn hp hai anehit no, c cng s nguyn t cacbon thu c 67,2x lt CO2 (ktc) v 43,2x gam H2O. Mt khc cho x mol hn hp trn tc dng vi dung dch AgNO3 d, trong NH3, sau phn ng hon ton thu c khi lng Ag l A. 345,6x gam. B. 324x gam. C. 216x gam. D. 378x gam. Cu 13: X l mt amin bc 3 iu kin thng th kh. Ly 7,08 gam X tc dng ht vi dung dch HCl th khi lng mui thu c l A. 10,73 gam. B. 14,38 gam. C. 11,46 gam. D. 12,82 gam. Trang 1/4 - M thi 132

Cu 14: C th iu ch mt loi thuc dit nm l dung dch CuSO4 5% (d = 1,024 gam/ml) theo s sau: CuS CuO CuSO4. thu c 3125 lt thuc dit nm trn cn bao nhiu tn nguyn liu cha 80% CuS v khi lng (cn li l tp cht tr)? Bit hiu sut ca c qu trnh iu ch l 80% A. 0,1200 tn. B. 0,1250 tn. C. 0,1875 tn. D. 0,1500 tn. Cu 15: Hn hp lng X gm benzen, phenol, axit benzoic, ancol benzylic. Ly 10,48 gam X tc dng vi Na va , sau phn ng hon ton thu c 0,896 lt H2 (ktc). Cng 10,48 gam hn hp X tc dng va vi 60 ml dung dch NaOH 1M. Khi em 5,24 gam X tc dng vi dung dch NaHCO3 d th c 0,448 lt kh CO2 (ktc). Phn trm s mol ca benzen trong hn hp l A. 14,88%. B. 20%. C. 25%. D. 10%. Cu 16: Anken khi hirat ha ch thu c mt ancol duy nht l A. propen. B. but-1-en. C. pent-2-en. D. hex-3-en. Cu 17: Cho 24,64 lt (ktc) hn hp kh X gm CO, CO2, N2 c tng khi lng l 32,4 gam i qua 100 ml dung dch cha NaOH 0,4M v Ba(OH)2 0,4M sau cc phn ng hon ton thu c m gam kt ta. Gi tr ca m l? A. 19,70. B. 15,76. C. 3,94. D. 7,88. Cu 18: Kim loi M c ha tr n khng i tc dng vi HNO3 theo phn ng M + HNO3 M(NO3)n + NO2 + NO + H2O ; bit VNO2 : VNO = 2 :1

T l s phn t HNO3 khng b kh v b kh trong phng trnh ha hc trn l A. 8 : 3. B. 5 : 3. C. 3 : 8. D. 3 : 5. Cu 19: Ha tan ht 17,94 gam mt kim loi kim vo mt lng nc d thu c dung dch X. Cho dung dch X tc dng vi 36,92 gam P2O5 th thu c dung dch Y ch cha hai mui c nng mol bng nhau. Kim loi kim l A. Na. B. Rb. C. K. D. Li. Cu 20: Hn hp kh v hi gm CH3OH, C2H6, C3H8, CH3-O-CH3 c t khi hi so vi H2 l 19,667. t chy hon 11,5 gam hn hp trn thu c 12,32 lt CO2 (ktc) v m gam H2O. Gi tr ca m l A. 14,4. B. 15,79. C. 13,4. D. 15,163. Cu 21: Cho cc cht: Fructoz, vinyl axetat, triolein (glixerol trioleat), glucoz, Ala-Gly-Ala. S cht tc dng c vi Cu(OH)2 l A. 3. B. 5. C. 4. D. 2. Cu 22: Cho cc dung dch khng mu ng ring bit trong cc l mt nhn: BaCl2, MgSO4, Na2SO4, KNO3, K2S. Nu khng dng thm thuc th no khc th nhn bit c nhiu nht bao nhiu dung dch trong cc dung dch trn? A. 3. B. 2. C. 4. D. 5. Cu 23: Hp cht hu c c dng sn xut t tng hp l A. poli(metyl metacrylat). B. poli(vinyl xianua). C. polistiren. D. poliisopren. Cu 24: Cho cc nguyn t X (Z = 11); Y(Z = 13); T(Z=17). Nhn xt no sau y l ng? A. Cc hp cht to bi X vi T v Y vi T u l hp cht ion. B. Theo chiu X, Y, T bn knh ca cc nguyn t tng ng tng dn. C. Nguyn t cc nguyn t X, Y, T trng thi c bn u c 1 electron c thn. D. Oxit v hiroxit ca X, Y, T u l cht lng tnh. Cu 25: C cc cht lng: etylen glicol, axit axetic, propyl axetat, ancol etylic, anehit axetic v butyl amin. Dy ha cht nhn bit cc cht trn l A. Cu(OH)2 v dung dch NaOH. B. dung dch AgNO3 v dung dch HCl. C. Cu(OH)2 v dung dch NaCl. D. dung dch AgNO3/NH3 v dung dch KMnO4. Cu 26: Ch t cc ha cht: KMnO4, FeS, NaCl, dung dch H2SO4 v khng s dng phng php in phn th c th iu ch c ti a bao nhiu cht kh? A. 3. B. 4. C. 5. D. 2. Cu 27: X l hp cht hu c n chc cha C, H, O. Ly 14,4 gam X tc dng va vi 50 gam dung dch NaOH 16%, sau phn ng hon ton c cn dung dch, thu c 22,4 gam cht rn khan. T X iu ch axit acrylic cn t nht bao nhiu phn ng? A. 1. B. 2. C. 3. D. 4. Cu 28: Dy gm cc kim loi c cng kiu mng tinh th lp phng tm din l A. Al, Ca, Cu. B. Al, Cr, Cu. C. Ca, Cr, Al. D. Ca, Ba, Mg. Cu 29: Nung hn hp gm x mol Fe(NO3)2, y mol FeS2 v z mol FeCO3 trong bnh kn cha mt lng d khng kh. Sau khi cc phn ng xy hon ton a bnh v nhit ban u thy p sut bnh khng i so vi ban u. Mi lin h gia x, y, z l A. 6x + 2z = y. B. 3x + z = y. C. 9x + 2z = 3y. D. 6x + 4z = 3y.
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Cu 30: Hn hp X gm CH3OH v C2H5OH c cng s mol. Ly 4,29 gam X tc dng vi 7,2 gam CH3COOH (c H2SO4 c xc tc) thu c m gam hn hp este (hiu sut phn ng este ha u bng 50%). Gi tr m l A. 4,455. B. 4,860. C. 9,720. D. 8,910. Cu 31: Ha tan ht 23,2 gam hn hp rn X gm FeO, Fe2O3, Fe3O4 trong dung dch HCl long, d ri c cn dung dch sau phn ng thu c 45,2 gam mui khan. Nu kh hon ton lng X trn s thu c bao nhiu gam st? A. 11,6. B. 11,2. C. 16,8. D. 12,8. Cu 32: Hiro ha hon ton hirocacbon X (cha mt lin kt mch h hoc mt vng no) thu c hirocacbon Y cha 18,18% H v khi lng. S cng thc cu to tha mn vi iu kin ca X l A. 1. B. 4. C. 3. D. 2. Cu 33: ng vi cng thc phn t CnH2n-2O2 khng th c loi hp cht hu c: A. Axit no, n chc mch vng. B. Este n chc, mch h, c mt ni i trong mch cacbon. C. Anehit no, hai chc, mch h. D. Axit n chc c hai ni i trong mch cacbon. Cu 34: Hn hp bt no sau y tan ht trong dung dch HCl d? A. Fe3O4 v Cu c t mol tng ng 1:2. B. Fe(NO3)2 v Cu c s mol bng nhau. C. CuS v Fe2O3 c s mol bng nhau. D. CaCO3, MgSO4 v BaSO4 c s mol bng nhau. Cu 35: Ancol etylic khng tc dng vi A. NaOH. B. C2H5OH. C. HCl. D. CH3COOH. Cu 36: Ly 10,32 gam hn hp gm petanal v anlyl fomat tc dng vi dung dch AgNO3 d trong NH3, sau khi cc phn ng hon ton thu c m gam Ag. Gi tr ca m l A. 12,96. B. 25,92. C. 10,8. D. 21,6. Cu 37: St khng b n mn in ha khi tip xc vi kim loi no sau y trong khng kh m? A. Sn. B. Zn. C. Ni. D. Pb. Cu 38: Axit cacboxylic c kh nng cng hp vi H2 l A. axit panmitic. B. axit oleic. C. axit stearic. D. axit axetic. Cu 39: Thc hin phn ng nhit nhm (trong iu kin khng c oxi) hn hp gm Fe3O4, Al thu c 80,4 gam hn hp X. Chia X thnh hai phn: phn 2 c khi lng gp 3 ln khi lng phn 1. Phn 1 tc dng va vi 100ml dung dch NaOH 1M. Phn 2 khi tc dng vi HNO3 c nng, d th thu c V lt kh NO2 ( ktc). Gi tr ca V l A. 25,20. B. 20,16. C. 10,08. D. 45,36. Cu 40: Hp cht hu c: OHC-CH(OH)-CH=CH-CHO c tn gi l A. 3-hiroxi prop-1-en-1,3-ial. B. 4-hiroxi pent-2-en-1,5-ial. C. 2-hiroxi pent-3-en-1,5-ial. D. 1-hiroxi prop-2-en-1,3-ial. B. PHN RING: Th sinh ch c chn lm 1 trong 2 phn (Phn I hoc Phn II) Phn I. Theo chng trnh Chun (10 cu: T cu 41 n cu 50) Cu 41: t chy hon ton m gam hn hp X gm FeS2 v mt oxit st cn dng 0,6 mol O2 thu c 0,4 mol Fe2O3 v 0,4 mol SO2. Cho m gam hn hp X trn tc dng vi dung dch H2SO4 c nng, d n khi cc phn ng xy ra hon ton, sn phm kh duy nht l SO2 th s mol H2SO4 tham gia phn ng l bao nhiu? A. 3,0 mol. B. 2,8 mol. C. 2,4 mol. D. 2,0 mol. Cu 42: Dy gm cc cht m khi cho tng cht tc dng vi dung dch HI u sinh ra sn phm c it l A. Fe2O3, Fe3O4, Fe2(SO4)3, Cl2. B. Fe3O4, FeO, AgNO3, FeS. C. AgNO3, Na2CO3, Fe2O3, Br2. D. Fe(OH)3, FeO, FeCl3, Fe3O4. Cu 43: Hp cht m khng th dng 1 phn ng ha hc to ra butaien l A. vinyl axetilen. B. but-2-en. C. ancol etylic. D. etilen Cu 44: Hp cht hu c X c cng thc phn t C2H7NO2. em 15,4 gam X tc dng ht vi dung dch NaOH thu c m gam hn hp 2 cht hu c (u lm i mu qu tm m). Gi tr ca m l A. 16,4. B. 19,8. C. 24,4. D. 13,2. Cu 45: Bng phng php ha hc, c th phn bit 3 dung dch khng mu: HCl long, KNO3, Na2SO4 ng trong 3 l mt nhn ch vi thuc th l A. Qu tm. B. BaCl2. C. Na2CO3. D. Bt Fe. Cu 46: Nung nng 0,5 mol hn hp X gm H2, N2 trong bnh kn c xc tc thch hp, sau mt thi gian thu c hn hp Y. Cho 1 2 hn hp Y i qua ng ng CuO d, un nng thy khi lng cht rn trong ng gim nhiu nht l 3,2

gam. T khi hi ca X so vi H2 l A. 7,2. B. 11,4. C. 3,6. D. 3,9. Cu 47: Nh t t dung dch NaOH vo dung dch X (dung mi H2O) thy xut hin kt ta, cho tip dung dch HCl vo li thy kt ta tan ra. Vy cht tan trong dung dch X l A. C2H5NH3Cl. B. CH3COONa. C. C6H5NH3Cl. D. C6H5ONa. Trang 3/4 - M thi 132

Cu 48: Cho 2,75 gam hn hp M gm 2 ancol X, Y qua CuO, t nng, sau phn ng hon ton thu c hn hp Z gm 2 anehit n chc, ng ng k tip. Ly ton b lng Z thu c trn thc hin phn ng trng bc th thu c ti a 27 gam Ag. Khng nh khng ng l A. T X v Y u c th dng 1 phn ng ha hc to ra axit axetic. B. X chim 50% s mol trong hn hp M. C. Khi t chy hon ton hn hp M th s mol O2 cn dng gp 1,5 ln s mol CO2 to ra. D. X v Y c th tc dng vi nhau. Cu 49: t chy hon ton m gam hn hp X gm hai amino axit X1, X2 (cha 1 chc axit, 1 chc amin v X2 nhiu hn X1 mt nguyn t cacbon), sinh ra 35,2 gam CO2 v 16,65 gam H2O. Phn trm khi lng ca X1 trong X l A. 80%. B. 20%. C. 77,56%. D. 22,44%. Cu 50: Cho cc cht Al, Zn, Cr, Sn, Pb, Si c bao nhiu cht tan c trong dung dch NaOH c un nng? A. 5. B. 6. C. 3. D. 4. Phn II. Theo chng trnh Nng cao (10 cu: T cu 51 n cu 60) Cu 51: Hp cht hu c X mch h, phn t cha mt loi nhm chc c cng thc phn t C6HyOz. Trong X oxi chim 44,44% theo khi lng. X tc dng vi NaOH to mui Y v cht hu c Z. Cho Y tc dng vi dung dch HCl to ra cht hu c Y1 l ng phn ca Z. Cng thc ca Z l A. CH3-COOH. B. CH3-CHO. C. HO-CH2-CHO. D. HO-CH2-CH2-CHO. Cu 52: Trong cc cht sau: SO2, C2H4, FeSO4, Cl2, FeCl2, HCl c bao nhiu cht c phn ng vi dung dch nc brom? A. 5. B. 3. C. 2. D. 4. Cu 53: Hp cht kh tham gia phn ng th nguyn t H ca vng benzen hn so vi benzen v s th u tin v tr ortho v para so vi nhm c sn l A. C6H5COOH. B. C6H5OH. C. C6H5Cl. D. C6H5CH3. Cu 54: Cho hp cht hu c X c cng thc: H2N-CH(CH3)-CO-NH-CH2-CO-NH-CH2-CH2-CO-NH-CH(C6H5)-CO-NH-CH(CH3)-COOH. Khng nh ng l A. Trong X c 4 lin kt peptit. B. Khi thy phn X thu c 4 loi -amino axit khc nhau. C. X l mt pentapeptit. D. Trong X c 2 lin kt peptit. Cu 55: Nhn xt no sau y khng ng v nc? A. H2O l cht lng tnh. B. H2O lc c tnh oxi ha, lc c tnh kh. C. Phn t H2O l phn t dung mi lng cc. D. Phn t H2O c cu trc chp tam gic. Cu 56: Thm vi git dung dch KSCN (khng mu) vo dung dch X cha cc ion Fe3+ , Na + , Fe2+ , Al3+ , Cl v SO2 th c hin tng? 4 A. To dung dch mu xanh lam. B. To dung dch mu mu. C. To kt ta mu nu . D. To kt ta mu trng xanh. Cu 57: Cho 27,6 gam axit salixylic (axit o-hiroxibenzoic) tc dng ht vi anhirit axetic, th khi lng este thu c l A. 30,4 gam. B. 32 gam. C. 48 gam. D. 36 gam. Cu 58: X l hp cht hu c tp chc thm c cng thc phn t C7H6O2. Khi cho 0,1 mol X tc dng vi Cu(OH)2 va , trong mi trng dung dch NaOH d th khi lng sn phm hu c thu c l A. 16,8 gam. B. 18,2 gam. C. 13,8 gam. D. 18,4 gam. Cu 59: Ha tan hon ton 40 gam hn hp gm FeS2, CuS, FeS bng dung dch HNO3 th thu c dung dch X ch cha hai mui v 4 mol NO2, khng c kt ta to ra. Cho dung dch NH3 d vo dung dch X, lc ly kt ta em nung n khi lng khng i th thu c bao nhiu gam cht rn? A. 32,0. B. 21,4. C. 24,0. D. 16,0. Cu 60: Nung mt lng mui sunfua ca mt kim loi ha tr khng i trong bnh cha oxi d th thot ra 5,6 lt kh X (ktc) v cht rn Y. Cht rn Y c nung vi bt than d to ra 41,4 gam kim loi. Nu cho ton b kh X i chm qua bt Cu d nung nng th th tch kh gim i 20%. Cng thc ca mui sunfua l A. PbS. B. Cu2S. C. ZnS. D. FeS.

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Trng thpt chuyn

p n mn ha ln CUI - nm 2012

Cu hi 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

p n D D B C D A A C D C C A C D B D C B A D A D B C A C B A B A

Cu hi 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

p n C D D B A B B B A C C A D B D C C B C A C A C D D B D B D A