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Analysis
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Many industries need pure substances to make products such as foods,
steel, computer chips and medicines.
⇒ What is pure substance?
A pure substance is a single substance not mixed with anything
else. E.g. white sugar or copper(II) sulphate crystals.
In nature, very few substances are pure. Most substances are impure
and in the form of mixtures.
⇒ What is a mixture? Give an example of a mixture.
A mixture contains two or more substances. E.g. seawater as it
contains water, salt and other dissolved solids.
Filtration
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- The solid is trapped by the filter paper. What do you call this
solid? residue
- The liquid goes through the filter paper. What do you call this
liquid? Filtrate
Quick Questions:
1. The dyes in ink go through filter paper. Why?
Because the dye molecules are smaller than the pores in the paper and
so go straight through them.
Crystallisation
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Use to separate a dissolved solid from a solution as well-formed
crystals.
NOTES: Some water must usually be left when aqueous solutions of salts
are being crystallized as the salt crystals need water of crystallization.
Sublimation
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- If a mixture of iodine and sand is heated in a beaker, the iodine
changes from solid to vapour directly.
- The vapour changes back to solid directly on a cold surface.
- The sand is not affected by the heat and remains in the beaker.
Simple Distillation
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Use to extract sodium chloride from sea water.
Quick Questions:
1. Where is the bulb of the thermometer placed?
It is placed beside the side arm of the distillation flask.
2. Why is it important that the thermometer does not dipped into the
solution?
This ensures that the thermometer measures the boiling point of the
substance that is being distilled.
Fractional Distillation
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To separate a mixture of two or more liquids which mix completely with
one another. (They are said to be miscible)
Quick Questions:
1. When a mixture of ethanol and water is being distilled, which one will
be distilled first? Ethanol
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78°C
Determining Purity
a) By chromatography
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Use to separate and identify mixtures of substances, such as coloured
dyes in inks and food. It is also use to analyse whether a substance is
pure or not.
What is a chromatogram?
It is the chromatography paper with the separated components .
Chromatogram 1 chromatogram 2
Chromatogram 2:
It shows that the substance is pure because it is only made up of only one
dye.
Rf values
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Rf value = distance moved by substance on the paper
Distance moved by the solvent
A B
Experiment on Chromatography
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Aim of experiment:
To separate and identify the different compounds in green ink using
paper chromatography.
Procedure:
a)Draw a starting line in the chromatography paper about 2 cm using
pencil.
b)Place a drop of fine ink on the pencil line.
c)Pour about 1 cm of ethanol in the beaker.
d) Lower the paper into the beaker containing the ethanol until the spots
of ink are just above the surface of the solvent. Cover the beaker with a
lid.
e) Leave it to develop.
f) Remove the paper when the solvent has almost reached the top of the
paper.
g) Allow the paper to dry and paste it in the space above.
Result:
List the colours seen in the paper
_______________________________________________________
Conclusion:
What can you conclude from this experiment?
_______________________________________________________
_______________________________________________________
Follow-up Questions:
In preparing the chromatogram, the following instructions were given.
Suggest a reason for each instruction.
1) The starting line should be drawn with a pencil rather than with ink.
Because ink is a mixture of dyes and therefore if used for drawing the
starting line, it will interfere with the chromatogram.
2) At the end of the experiment, the solvent front should be near the
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top of the paper.
To ensure that all the mixture are separated.
3) The spots of the solutions and dyes on the starting line should be
small.
This is to avoid smudging of the dyes that can affect the separation of
the mixtures.
b) By boiling point
Aim of experiment:
To study the effect of an impurity on the boiling point of propanone.
The setup use for the experiment to determine the boiling point of a
substance.
Procedure:
1. Pour 10 cm3 of propanone into a small distillation flask. Add two or
three boiling chips into the liquid to ensure smooth boiling.
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2. Clamp the small distillation flask in a beaker half-filled with water and
fix the thermometer so that the bulb is situated at the side outlet tube.
3.Heat the water gently while stirring continuously.
4. Record the temperature when the liquid boils.
5. Repeat the experiment with a mixture containing propanone and alcohol
Results:
Plot two graphs of time against temperature by showing clearly the main
difference between the boiling point of pure propanone and impure
propanone.
Follow-up questions:
1. What is the boiling point of a) pure propanone 56°C
b) propanone containing alcohol?
2. What are the effects of the alcohol on the boiling point of propanone?
The boiling point will increase.
The liquid will boil over a range of temperature.
The greater the amount of impurities, the higher the boiling point.
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1) The water bath should be change using a liquid which is higher than the
boiling point of ethylbenzene.
2) The thermometer should be change to a thermometer which has a
higher temperature range.
By melting point
Aim of experiment:
To study the effect of an impurity on the melting point of benzoic acid
The setup use for the experiment to determine the melting point of a
substance.
Procedure:
1. Put a small amount of pure solid benzoic acid into a melting point.
2. Secure the tube to the thermometer with a rubber band and place
them in a small beaker containing paraffin oil.
3. Heat the oil slowly while stirring continuously. Record the temperature
when the solid melts.
4. Repeat the experiment using a mixture containing benzoic acid and a
small amount of naphthalene as the impurity.
Results:
Plot two graphs of time against temperature by showing clearly the main
difference between the melting point of pure benzoic acid and impure
benzoic acid.
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Follow-up questions:
1. What is the melting point of
a) pure benzoic acid 122°C
b) benzoic acid contaminated with naphthalene? 118-121°C
2. State the effect of the impurity on the melting point of benzoic acid.
The melting point will decrease.
The substance will melt over a range of temperature.
The greater the amount of impurities, the lower the melting point
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