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BI DNG VN HA NGY MI - 18A/88 INH VN T - TP.

HI DNG
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2012 TP CH
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TP CH HA HC & TUI TR TR LI

BI HI CA NG NGHIP C
Nch Ym: polivinylclorua_2505

Hp th ht 4,48 lt CO
2
(kc) vo dung dch cha x mol KOH v y mol K
2
CO
3
thu c 200 ml
dung dch X. Ly 100 ml X cho t t vo 300 ml dung dch HCl 0,5M thu c 2,688 lt kh(kc). Mt
khc, 100ml X tc dng vi dung dch Ba(OH)
2
d thu c 39,4g kt ta. Gi tr ca x l:
A. 0,15 B. 0,2 C. 0,05 D. 0,1
Trch thi th ca HKH Hu - Nm 2012 ln 1
Hng dn:
Theo bi ra ta s d dng xc nh c
2
3 3
0, 2
CO HCO
n mol

+
=

(trong 100 ml dung dch X)


Vy => Trong 200 ml dung dch X s c:
2
3 3
0, 4
CO HCO
n mol

+
=


Theo nh lut bo ton nguyn t ta d dng xc nh c y = 0,2 mol
+ Gi s trong 100 ml dung dch X ch c
3
HCO

vi s mol l 0,2 mol



3 2 2
0,15 0,12
0,2
H HCO CO H O
+
+ +


iu ny l v l
+ Gi s trong 100 ml dung dch X ch c
2
3
CO

vi s mol l 0,2 mol

2
3 2 2
0,15 0,12 0,2
2H CO CO H O
+
+ +
iu ny l v l
=> Trong dung dch X s gm c c 2 mui:
2
3
CO

v
3
HCO


Vy khi: Hp th ht 4,48 lt CO
2
(kc) vo dung dch cha x mol KOH v y mol K
2
CO
3
thu c 200 ml
dung dch X th s c cc phn ng:

3
2
2 3 2 3
0,2 mol

x mol
0,2 mol
a
b
KHCO
KOH
CO
K CO K CO


Ta c a + b = 0,4 mol
Khi cho 100 ml dd X t t vo 300 ml dung dch HCl 0,5M
=> lun c hai phn ng xy ra ng thi (coi rng tc phn ng l nh nhau)

2
3 2 2
2
2
a a a
H CO CO H O
+
+ +

3 2 2
b b
b
H HCO CO H O
+
+ +


Ta c s mol ca kh CO
2
thot ra l 0,12 mol <
2
3 3
0, 2
CO HCO
n mol

+
=

=> mui cn d v acid ht


Ta c h phng trnh
2
2 3
0,12 0, 03
: 1: 3
2 0,15
mol
b = 0,09 mol
CO HCO
a b a
n n
a b

+ = =
=

+ =


Vy trong 200 ml dung dch X s c:
2
3 3
0, 4
CO HCO
n mol

+
=


vi s mol ca
2
2 3
0,1 0,3 mol; mol
CO HCO
n n

= =
Khi trong dung dch X theo nh lut bo ton nguyn t ta c: 0,1.2 + 0,3.1 = x + 0,2.2 => x = 0,1 mol
* Ghi ch: Ta coi rng tc phn ng ca hai ion
2
3
CO

v
3
HCO

l nh nhau

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