TP. HCM Q.

THI TH I H C MN HA H C

Th i gian lm bi: 90 pht; (60 cu tr c nghi m)

M thi 312 Cau 1: Nhng loai hp chat hu c mach h nao ng vi cong thc tong quat CnH2nO. a. Ru khong no n chc b. Anehit no c. Xeton d. Tat ca eu ung Cau 2: Can bang phng trnh phan ng sau bang phng phap thang bang electron : KClO3 + HCl Cl2 + KCl + H2O Cac he so theo th t cac chat lan lt la: a. 2,3,3,1,3 b. 1,3,3,1,3 c. 2,6,3,1,3 d. 1,6,3,1,3 Cau 3: T khoi hi cua mot anehit X oi vi hiro bang 28. Cong thc cau tao cua anehit la: b. CH2=CH-CHO c. HCHO d. C2H5CHO a. CH3CHO Cau 4: Cho 8,8 gam mot hon hp gom 2 kim loai 2 chu k lien tiep thuoc phan nhom chnh nhom II tac dung vi dung dch HCl d cho 6,72 lt kh hiro ieu kien tieu chuan, H=100%. Hai kim loai o la: a. Be va Mg b. Ca va Sr c. Mg va Ca d. Sr va Ba Cau 5: Co mot hp chat hu c n chc Y, khi ot chay Y ta ch thu c CO2 va H2O vi so mol nh nhau va so mol oxi tieu ton gap 4 lan so mol cua Y. Biet rang: Y lam mat mau dung dch brom va khi Y cong hp hiro th c ru n chc. CTCT mach h cua Y la: a. CH3-CH2-OH b. CH2=CH-CH2-CH2-OH c. CH3-CH=CH-CH2-OH d. CH2=CH-CH2-OH . Cau 6: Cho phan ng : Na2SO3 + KMnO4 + H2O co san pham la : a. Na2SO4, KOH, K2MnO4 c. Na2SO4, MnO2, KOH d. Cac chat khac b. SO3 , MnO2, KOH Cau 7: Mot chat hu c X cha C , H , O ch cha mot loai chc. Cho 2,9 gam X phan ng vi dung dch AgNO3 / NH3 d thu c 21,6g Ag. Vay X co the la : a. HCHO b. OHC CHO c. CH2(CHO)2 d. CH3 CHO Cau 8: Pha loang 25ml H2SO4 96% (d=1,839g/ml) vi H2O thanh 0,5lt dung dch co nong o mol la : a. 0,45 M b. 0,9 M c. 1,2 M d. 2,5 M Cau 9: Khi cho 0,56 lt (ktc) kh HCl hap thu vao 50ml dung dch AgNO3 8% (d=1,1g/ml). Nong o % HNO3 thu c la : a. 6,3% b. 1,575% c. 3% d. 3,5875% Cau 10: Hai hydrocacbon A, B la ong ang ke tiep co t khoi hi so vi H2bang 12,65. Vay A va B b. C2H4 , C3H6 c. C2H2 , C3H4 d. C3H4, C4H6 co the la : a. CH4, C2H6 Cau 11:Cho 3g hon hp gom 3 kim loai ng trc Hiro trong day ien hoa phan ng het vi H2SO4 d, thu c 1,008 lt H2 (ktc). Co can dung dch thu c m gam chat ran. Vay m co the bang : a. 7,32g b. 5,016g c. 2,98g d. Ket qua khac Cau 12:Hon hp X gom: C3H8, C4H10 co t khoi hi oi vi H2 bang 25,5. Thanh phan % theo so mol la a. 20 va 80 b. 50 va 50 c. 25 va 75 d. Ket qua khac Cau 13: X la nguyen to nhom VA. Cong thc hidroxit (trong o X the hien so oxi hoa cao nhat) nao sau ay la khong ung : a. HXO3 b. H3XO3 c. H4X2O7 d. H3XO4 Cau 14: So sanh tnh axit cua cac chat sau ay: CH2Cl-CH2COOH (1), CH3COOH (2) , HCOOH (3), a. (3) > (2) > (1 ) > (4) b. (4) > (2) > (1 ) > (3) CH3-CHCl-COOH (4) c. (4) > (1) > (3). > (2) d. Ket qua khac Cau 15: ot chay 1,68 lt hon hp CH4, C2H4 (ktc) co M =20 thu x gam CO2. Vay X bang : a. 6,6g b. 4,4g c. 3,3g d. Ket qua khac

Cau 16: ot chay chat hu c A co mCO2: mH2O = 1,833. Vay CTCT cua A la: a. C3H7OH b. CH3OC2H5 c. Glyxerin d. a,b,c eu ung. Cau 17: ot chay ankan X co mol X : mol O2 = 2 : 13. Khi Cracking X se thu c tat ca may olefin ? a. 1 b. 2 c. 3 d. 4 Cau 18: Hydrocacbon co %H = 14,29 va khong co ong phan se co CTPT la: a. C2H4 b. C4H10 c. C3H6 d. a,c eu ung Cau 19: ot chay hydrocacbon A co mCO2: mH2O = 4,889. Vay CTTN cua A la: a. (CH2)n b. (C2H6)n c. (CH3)n d. (CH)n Cau 20: Hai chat hu c X va Y eu n chc la ong phan cua nhau. ot chay hoan toan 5,8 gam hon hp X va Y can 8,96 lt oxi (ktc) thu c kh CO2 va hi nc theo t le VCO2 : Vhi H2O = 1 : 1 (o cung ieu kien). Cong thc n gian cua X va Y la: a. C2H4O b. C3H6O c. C4H8O d. C5H10O Cau 21:Khi dan mot luong kh clo qua dung dch KOH loang nguoi ngi ta thu c san pham co cha: c. KClO3 d . Khong phan ng a. KClO b. KClO2 Cau 22: Khi cho Cl2 vao dung dch Ca(OH)2 ta thu c clorua voi. Vay 2 cong thc cua Clorua voi la: b. CaOCl2 c. CaCl2 va Ca(OCl)2 d. b,c eu ung a. Ca(OCl)2 Cau 23: ot ru A. Dan het san pham chay vao bnh ng dd Ca(OH)2 d thay co 3 gam ket tua va khoi lng bnh tang them 2,04 gam. Vay A la : a. CH3OH b. C2H5 OH c. C3H7OH d. C4H9OH Cau 24: Hoa tan het 1,62g Ag bang axit nong o 21% ( d=1,2 g/ml) ; thu c NO. The tch dung dch axit nitric toi thieu can phai dung la : a. 4ml b. 5ml c. 7,5ml d. Gia tr khac Cau 25: Mot oxit kim loai MxOy trong o M chiem 72,41% ve khoi lng . Kh hoan toan oxit nay bang CO, thu c 16,8 gam M. Hoa tan hoan toan lng M nay bang HNO3 nong thu c 1 muoi va x mol NO2. Vay x co gia tr la : a. 0,45 b. 0,6 c. 0,75 d. 0,9 Cau 26: Hon hp X gom 2 axit no: A1 va A2. ot chay hoan toan 0,3mol X thu c 11,2 lt kh CO2 (ktc). e trung hoa 0,3 mol X can 500ml dung dch NaOH 1M. Cong thc cau tao cua 2 axit la: b. HCOOH va HOOC-COOH a. CH3COOH va C2H5COOH c. HCOOH va C2H5COOH d. CH3COOH va HOOC-CH2-COOH Cau 27: Cho 1,152g hon hp Fe, Mg vao 0,1 lt dung dch AgNO3. Khi phan ng xong thu c 5,792g hon hp 2 kim loai . Vay % Mg la: a. 58,34% b. 41,66% c. 72,2%d. Ket qua khac Cau 28: Cho 24,8 gam hon hp gom 1 kim loai kiem tho va oxit cua no tac dung vi dung dch HCl d thu c 55,5g muoi khan. Kim loai tren se la : a. Ca b. Sr c. Ba d. Mg Cau 29: Co 3 chat ran Ba(HCO3)2, Mg(HCO3)2, (NH4)2CO3 k hieu A, B, C. Lay chat B nung thu chat ran B1. Cho B1 vao H2O thu dung dch B2. Vay : a. B la Mg(HCO3)2 , ddB2 la Mg(OH)2 b. B la Ba(HCO3)2, ddB2 Ba(OH)2 c. B la Ba(HCO3)2, ddB2 BaCO3 d. B la Mg(HCO3)2 , ddB2 MgCO3 Cau 30: 30g hon hp Cu, Fe tac dung u vi 14 lt kh Cl2 (ktc). Vay %Cu theo khoi lng : a. 45% b. 60% c. 53,33% d. 35,5% Cau 31: ot chay hon hp 2 ru ong ang co so mol bang nhau, ta thu c khi CO2 va hi nc co t le so mol nCO2 : nH2O = 2 : 3.Cong thc phan t 2 ru lan lt la: a. CH4O va C3H8O b. C2H6O va C3H8O c. CH4O va C2H6O d. C2H6O va C4H10O

Cau 32: Cho 2,8g bot Fe va 2,7g bot Al vao dung dch co 0,175mol Ag2SO4 . Khi phan ng xong thu c x gam hon hp 2 kim loai. Vay x la : a. 39,2g b. 5,6g c. 32,4g d. Ket qua khac Cau 33: Dung dch A gom HCl, H2SO4 co pH = 2. e trung hoa hoan toan 0,59 gam hon hp 2 amin n chc no bac 1 (co so C khong qua 4) phai dung 1 lt dung dch A. CTPT 2 amin : b. CH3NH2 va C2H5NH2 a. CH3NH2 va C4H9NH2 c. C3H7NH2 d. C4H9NH2 va CH3NH2 hoac C2H5NH2 Cau 34: Cho phan ng : C4H6O2 + NaOH B + D ; D + Z E + Ag B co the ieu che trc tiep c t CH4 va C2H6. Vay B co the la : a. CH3COONa c. a, b eu ung d. a, b eu sai b. C2H5COONa Cau 35: Hai chat hu c A, B eu co cong thc phan t C3H4O2. Cho 0,1 mol moi chat tac dung vi NaOH d, ta lan lt thu c cac muoi natri co khoi lng tng ng la 9,4g; 6,8g. CTCT cua A va B: a. CH3COOH va HCOOCH3 b. CH2=CH=COOH va HCOOCH=CH2 c. C2H5COOH va CH3COOCH3 d. Cac cong thc khac Cau 36:Cho 9,4g K2O vao 200g dung dch KOH 5,6% thu dung dch A x%. Vay x la : a. 8% b. 9,6% c. 10,7% d. Ket qua khac Cau 37:Tron V1 lit dung dch H2SO4 co pH = 3 vi V2 lit dung dch NaOH co pH = 12thu c dung dch co pH = 4, th t le V1: V2 co gia tr la bao nhieu : a. 9:11 b. 101:9 c. 99:101 d. Ty le khac Cau 38: ot chay hoan toan 1,52 gam mot ru X thu c 1,344 lt CO2 (ktc) va 1,44 gam H2O. CTPT cua X la: a. C3H8O2 b. C3H8O3 c. C4H8O2 d. C5H10O2 Cau 39: Dan hai luong kh clo i qua hai dung dch KOH: dung dch mot loang va nguoi, dung dch hai am ac un nong ti 100oC. Neu lng muoi KCl sinh ra trong hai dung dch bang nhau th t le the tch clo i qua hai dung dch KOH bang bao nhieu ? a. 5/6 b. 5/3 c. 8/3 d. 10/3 Cau 40: Cho 2,4 gam mot hp chat hu c X tac dung hoan toan vi dung dch AgNO3 d trong NH3 thu c 7,2 gam Ag. CTCT cua X: a. CH3CHO b. C2H5CHO c. HCHO d. C3H7CHO ----------------------------------------------------------------------------------------