TRNG THPT TRN PH T HO HC

THI TRC NGHIM M : 210 DNG CHO THI TH I HC T 1 MN THI: HO HC Thi gian: 90 pht (khng k thi gian giao ). thi gm 4 trang ----------------------I. PHN CHUNG CHO TT C TH SINH ( 40 cu, t cu 1 n cu 40 ) Cu 1: Cu hnh electron nguyn t no l ca nguyn t kim loi chuyn tip (nguyn t nhm B) trong Bng tun hon? A. 1s22s22p4 B. 1s22s22p63s2 C. 1s22s22p63s23p64s1 D. 1s22s22p63s23p63d64s2 Cu 2: Lin kt ho hc no sau y c tnh ion r nht? A. Cs2S B. NH3 C. HCl D. H2S Cu 3: Trong phn ng oxi ho - kh sau: H2S + KMnO4 + H2SO4 S + MnSO4 + K 2SO4 + H2O . H s ca cc cht tham gia phn ng ln lt l A. 3, 2, 5 B. 5, 2, 3 C. 2, 2, 5 D. 5, 2, 4 Cu 4: Cho tng cht : Fe, FeO, Fe(OH)2, Fe(OH)3, Fe3O4, Fe2O3, Fe(NO3)2, Fe(NO3)3, FeSO4, Fe2(SO4)3, FeCO3 ln lt phn ng vi HNO3 c nng. S phn ng thuc loi phn ng oxi ho - kh l A. 8 B. 5 C. 7 D. 6 Cu 5: Ion OH- c th phn ng c vi tt c cc ion no sau y? A. H+ ,NH4+ ,HCO3 ,CO32 B. Fe2+ ,Zn2+ ,HS,SO4 2 C. Ca2+ ,Mg2+ ,Al3+ ,Cu2+ D. Fe3+ ,Mg2+ ,Cu2+ ,HSO4 Cu 6: Trn 250 ml dung dch hn hp gm HCl 0,08M v H2SO4 0,01M vi 250 ml dung dch Ba(OH)2 aM thu c m gam kt ta v 500 ml dung dch c pH = 12, bit [ H+].[OH-] = 10-14. Gi tr m v a ln lt l A. 0,5582 v 0,03 B. 0,03 v 0,5582 C. 0,5825 v 0,06 D. 0,03 v 0,06 Cu 7: Cho FeS tc dng vi dung dch HCl thu c kh A. Nhit phn KClO 3 c xc tc MnO2 thu c kh B. Cho Na2SO3 tc dng vi dung dch HCl thu c kh C. Cc kh A, B, C ln lt l A. O2, SO2 , H2S B. O2, H2S, SO2 C. H2S, Cl2, SO2 D. H2S, O2, SO2 Cu 8: C th dng CuSO4 khan lm kh kh no trong cc kh H2S, CO2, NH3, CH3NH2 c ln hi nc? A. H2S B. CO2 C. CH3NH2 D. NH3 Cu 9: Mt tm kim loi bng vng b bm mt lp kim loi st b mt, ta c th dng kim loi no sau y loi tp cht ra khi tm kim loi vng? A. Dung dch Fe2(SO4)3 d B. Dung dch FeSO4 d C. Dung dch CuSO4 d D. Dung dch ZnSO4 d Cu 10: in phn dung dch cha x mol CuSO4 v y mol NaCl (vi in cc tr, mng ngn xp). dung dch sau in phn lm cho phenolphtalein chuyn sang mu hng th iu kin ca x v y l A. x > 2y B. y > 2x C. y < 2x D. 2y = x Cu 11: Ho tan 174 gam hn hp gm 2 mui cacbonat v sunfit ca cng mt kim loi kim vo dung dch HCl d. Ton b kh thot ra c hp th ti thiu bi 500 ml dung dch KOH 3M. Xc nh kim loi kim? A. Li B. K C. Na D. Rb Cu 12: Trong mt cc nc c cha: 0,03 mol Na+; 0,02 mol Ca2+; 0,01 mol Mg2+; 0,06 mol HCO3- v 0,01 mol Cl-; 0,01 mol SO42-. Nc trong cc l loi A. nc mm. B. nc cng tm thi. C. nc cng vnh cu. D. nc cng ton phn. Cu 13: C th phn bit 3 cht rn ring bit trong 3 l mt nhn: CaO, MgO, Al2O3 bng ho cht no sau y? A. Dung dch HCl. B. Dung dch HNO3 c.C. Dung dch NaOH. D. H2O. Cu 14: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 g. Gi tr ln nht ca V l A. 2 B. 1,2 C. 1,8 D. 2,4 Cu 15: Ho tan 5,6 gam Fe bng dung dch H2SO4(long d), thu c dung dch X. Dung dch X phn ng va vi V ml dung dch KMnO4 0,5M. Gi tr ca V cho l A. 80 ml B. 20 ml C. 40 ml D. 60 ml Cu 16: Dung dch NaOH c phn ng vi tt c cc cht trong dy no sau y? A. FeCl3, MgCl2, CuO, HNO3, NH3, Br2 B. H2SO4, CO2, NaHSO3, FeCl2, FeCl3, NO2, Cl2 C. Al, Al2O3, MgO, H3PO4, MgSO4, MgCl2 D. HNO3, HCl, CuSO4, KNO3, ZnO, Zn(OH)2 Cu 17: C 6 dung dch ring bit ng trong 6 l mt nhn: NH4Cl, (NH4)2SO4, Na2SO4, NaOH, FeCl3, AlCl3. Nu ch c dng mt thuc th nhn bit 6 dung dch trn, ta c th dng dung dch no sau y? A. Dung dch Na2CO3 B. Dung dch AgNO3 C. Dung dch Ba(OH)2 D. Dung dch KCl

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Cu 18: Cho 16,2 gam kim loi M (c ho tr n khng i) tc dng vi 3,36 lt O2 (kc). Ho tan cht rn sau phn ng bng dung dch HCl d thy thot ra 13,44 lt H2 (kc). Xc nh kim loi M? A. Mg B. Ca C. Fe D. Al Cu 19: Ho tan 20,8 gam hn hp bt gm FeS, FeS2, S bng dung dch HNO3 c nng d thu c 53,76 lt NO2 (sn phm kh duy nht, kc) v dung dch A. Cho dung dch A tc dng vi dung dch NaOH d, lc ly ton b kt ta nung trong khng kh n khi lng khng i th khi lng cht rn thu c l A. 16 gam B. 9 gam C. 8,2 gam D. 10,7 gam Cu 20: Cho dy bin ho sau: + HCl B +X+Z t0 pnc Al D E Al. + NaOH C + Y + Z Cc cht B, C, D, E, X, Y, Z ln lt l A. AlCl3, NaAlO2, Al2O3, Al(OH)3, Na2CO3, CO2, H2O B. AlCl3, NaAlO2, Al(OH)3, Al2O3, Na2CO3, CO2, H2O C. Al(OH)3, AlCl3, NaAlO2, Al2O3, Na2CO3, CO2, H2O D. NaAlO2,. AlCl3, Al(OH)3, Al2O3, Na2CO3, CO2, H2O Cu 21: Nhit phn mt loi qung c cng thc MgCO3.CaCO3 c kh A, cho kh A hp th hon ton vo dung dch KOH thu c dung dch B, bit dung dch B va tc dng c vi BaCl 2 va tc dng c vi NaOH. Xc nh cc cht tan c mt trong dung dch B? A. KHCO3 B. K2CO3 C. K2CO3 v KOH D. K2CO3 v KHCO3 Cu 22: Hp cht C4H8 c bao nhiu ng phn cu to? A. 5 B. 2 C. 4 D. 3 Cu 23: Caroten l sc t mu vng trong c c rt c cng thc phn t C 40H56. Hiro ho hon ton caroten thu c hirocacbon C40H78. Xc nh s lin kt trong phn t caroten? A. 13 B. 10 C. 12 D. 11 Cu 24: un 132,8 gam hn hp 3 ancol no n chc vi H2SO4 c 1400C cho n khi phn ng hon ton thu c 111,2 gam hn hp cc ete c s mol bng nhau. Tnh s mol mi ete? A. 0,1 B. 0,2 C. 0,25 D. 0,3 Cu 25: Cho cht sau y m-HO-C6H4-CH2OH (hp cht cha nhn thm) tc dng vi dung dch NaOH d. Sn phm to ra l
ONa

OH

ONa

ONa

A.
CH2ONa

B.
CH2ONa

C.
CH2OH

D.
CH2OH

Cu 26: Cho hn hp X gm 2 anehit no n chc. Ly 0,25 mol X cho phn ng vi dung dch AgNO 3/NH3 d thu c 86,4 gam kt ta, khi lng dung dch sau phn ng gim 71,6 gam. Xc nh cng thc ca 2 anehit ? A. HCHO v C2H5CHO B. CH3CHO v C2H5CHO C. HCHO v CH3CHO D. CH3CHO v C3H7CHO Cu 27: t chy hon ton a mol mt anehit X (mch h) to ra b mol CO 2 v c mol H2O. Bit b = a + c ; trong phn ng trng bc mt phn t anehit X cho 2 electron. X thuc dy ng ng A. anehit no, n chc B. anehit khng no, c mt ni i C=C, n chc C. anehit khng no, c 2 ni i C=C, n chc D. anehit no, hai chc Cu 28: Cho glixerol tc dng vi hn hp 3 axit bo gm C17H35COOH, C15H31COOH v C17H31COOH th to ra ti a bao nhiu sn phm Trieste cha ng thi 3 gc axit bo trn? A. 1 B. 2 C. 3 D. 4 Cu 29: Cho tt c cc ng phn n chc mch h, c cng cng thc phn t l C 2H4O2 ln lt tc dng vi Na, dung dch NaOH, dung dch NaHCO3 th s phn ng ho hc xy ra l A. 2 B. 4 C. 3 D. 5 Cu 30: ra sch chai l ng anilin ta nn dng cch no sau y? A. Ra bng x phng B. Ra bng dung dch HCl d sau ra li bng nc C. Ra bng nc ct D. Ra bng dung dch NaOH d sau ra li bng nc Cu 31: Bit X l mt aminoaxit. Khi cho 0,01 mol X phn ng va vi 80 ml dung dch HCl 0,125M thu c 1,835 gam mui khan. Mt khc, khi cho 0,01 mol X tc dng vi dung dch NaOH th cn 200 ml dung dch NaOH 0,1M. Xc nh cng thc X? A. NH2C2H4COOH B. NH2C3H6COOH C. (NH2)2C3H5COOH D. NH2C3H5(COOH)2 Cu 32: Khi thy phn Tripeptit H2N-CH(CH3)CO-NH-CH2-CO-NH-CH2-COOH s to ra cc - aminoaxit l A. H2NCH2COOH; CH3CH(NH2)COOHB. H2NCH(CH3)COOH; H2NCH(NH2)COOH C. H2NCH2CH(CH3)COOH; H2NCH2COOH D. CH3CH(NH2)CH2COOH; H2NCH2COOH

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Cu 33: Phn ng no sau y chng minh rng trong phn t ca glucoz, fructoz, sacacoz c nhiu nhm -OH? A. Cho dung dch cc cht trn tc dng vi Na thy gii phng kh H2 B. Cho dung dch cc cht trn tc dng vi dung dch AgNO3/NH3 C. Cho dung dch cc cht trn tc dng vi Cu(OH)2 nhit thng D. Cho dung dch cc cht trn tc dng vi dung dch Br2 Cu 34: Trong s cc polime sau y: t tm; si bng; len lng cu; t visco; t nilon- 6; t axetat; t nitron, th nhng polime c ngun gc t xenluloz l A. t tm, si bng, t nitron B. si bng, t visco, t axetat C. si bng, t visco, t nilon- 6 D. t visco, t nilon- 6, t axetat Cu 35: Cho cc cht sau: etyl axetat, anilin, ancol etylic, phenol, phenylamoniclorua, ancol bezylic, p-crezol. Trong cc cht ny s cht tc dng c vi dung dch NaOH l A. 3 B. 5 C. 6 D. 4 Cu 36: Cho cc cht: axit propionic (X), axit axetic (Y), ancol etylic (Z) v imetylete (T). Dy gm cc cht c sp xp theo chiu tng dn nhit si l A. Z, T, Y, X B. T, Z, Y, X C. T, X, Y, Z D. Y, T, X, Z Cu 37: Pht biu no sau y khng ng? A. Axit axetic tc dng vi dung dch NaOH, ly mui va to ra cho tc dng vi kh CO2 li thu c axit axetic B. Phenol tc dng vi dung dch NaOH, ly mui va to ra cho tc dng vi dung dch HCl li thu c phenol C. Anilin tc dng vi dung dch HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c Anilin D. Dung dch natri phenolat tc dng vi kh CO2, ly kt ta va to ra tc dng vi dung dch NaOH li thu c natri phenolat
2 hit Cu 38: Cho s sau: X A B An 2 chc . X c th l cht no trong cc cht (1 :1) to to

Br

NaOH

CuO

sau? A. Propen (propilen) B. Xiclopropan C. But-2-en D. Xiclobutan Cu 39: C 6 l ng ba cht lng: C2H5OH, C6H6, C6H5NH2 v ba dung dch: NH4HCO3, NaAlO2, C6H5ONa. Ch dng cht no sau y c th nhn bit c tt c cc l trn? A. Dung dch BaCl2 B. Dung dch NaOH C. Dung dch HCl D. Dung dch Ca(OH)2 Cu 40: C bao nhiu ng phn c cng cng thc phn t C7H8O tho mn cc tnh cht: c phn ng vi NaOH v c phn ng vi Na gii phng H2? A. 3 B. 4 C. 1 D. 2 II. PHN RING ( 10 cu) Th sinh ch c lm mt trong hai phn ( phn A hoc phn B ) A. Theo chng trnh Chun ( t cu 41 n cu 50 ) Cu 41: nhit khng i, h cn bng no s chuyn dch v pha thun nu tng p sut? A. 2SO3(k) 2SO2 (k) + O2 (k) C. 2CO2(k) 2CO(k)+ O 2(k)
B. 2H2(k) + O2(k) 2H 2O(k)

D. 2NO(k) N2 (k)+ O2 (k)

Cu 42: Khi cho axit axetic tc dng vi cc cht: KOH ,CaO, Mg, Cu, H2O, Na2CO3, Na2SO4, C2H5OH, th s phn ng xy ra l A. 5 B. 6 C. 7 D. 8 Cu 43: Khi cho cht no sau y tc dng vi H2O (Hg2+; 800C) to ra sn phm l xeton? A. Etilen B. Propilen C. Axetilen D. Propin Cu 44: Dy gm cc cp OXH/K c sp xp theo chiu tng dn tnh oxi ho ca dng oxi ho v gim dn tnh kh ca dng kh l A. Cu2+/Cu; Cr3+/Cr; Mg2+/Mg; Ag+/Ag; Fe2+/Fe B. Mg2+/Mg; Cr3+/Cr; Fe2+/Fe; Cu2+/Cu; Ag+/Ag C. Mg2+/Mg; Fe2+/Fe; Cr3+/Cr; Cu2+/Cu; Ag+/Ag D. Mg2+/Mg; Cr3+/Cr; Fe2+/Fe; Ag+/Ag; Cu2+/Cu Cu 45: Cho 5,76 gam Cu vo 500 ml dung dch NaNO3 0,3M, sau thm 500ml dung dch HCl 0,6M thu c kh NO v dung dch A. Th tch kh NO (ktc) l A. 1,68 lt B. 0,896 lt C. 1,344 lt D. 2,016 lt Cu 46: C 4 dung dch mui ring bit: CuCl 2, ZnCl2, FeCl3, AlCl3. Nu thm dung dch KOH (d) ri thm tip dung dch NH3 (d) vo 4 dung dch trn th s cht kt ta cn li sau phn ng l A. 2 cht B. 1 cht C. 3 cht D. 4 cht Cu 47: Cu no sau y l ng khi ni v hiu ng nh knh v ma axit? A. Kh gy ra hiu ng nh knh l CO2 v kh gy ra ma axit l SO2; NO2 B. Kh gy ra hiu ng nh knh l SO2 v kh gy ra ma axit l CO2; NO2 C. Kh gy ra hiu ng nh knh l SO2; CO2 v kh gy ra ma axit l NO2

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D. Kh gy ra hiu ng nh knh l NO2 v kh gy ra ma axit l SO2; CO2 Cu 48: ng vi cng thc C3H8On c bao nhiu ng phn ch cha nhm chc OH trong phn t c th ho tan c Cu(OH)2 ? A. 2 B. 3 C. 1 D. 4 Cu 49: Trong hp cht sau y c my lin kt peptit? H2N-CH2-CO-NH-CH-CO-NH-CH-CO-NH-CH2-CH2-COOH CH3 C6H5 A. 1 B. 2 C. 3 D. 4 Cu 50: Cho 8,55 gam cacbohirat A tc dng hon ton vi dung dch HCl, ri cho sn phm thu c tc dng vi lng d AgNO3/NH3 to thnh 10,8 gam Ag kt ta. A c th l cht no trong cc cht sau? A. Glucoz B. Fructoz C. Saccaroz D. Xenluloz B. Theo chng trnh Nng cao ( t cu 51 n cu 60 ) Cu 51: Trong cng nghip sn xut H2SO4 , giai on oxi ho SO2 thnh SO3 c biu din bng phng
V2O5,t trnh phn ng: 2SO (k) + O (k) 2SO , H < 0 (phn ng ta nhit) 2 2 3
o

Cn bng ha hc trn s chuyn dch v pha to ra sn phm l SO3 nu ta A. tng nng kh O2 v tng p sut. B. gim nng kh O2 v gim p sut C. tng nhit v gim p sut. D. gim nhit v gim nng SO2 . Cu 52: T lapsan c iu ch bng phn ng trng ngng t cc monome no sau y? A. Glixerol v axit terephtalic B. Etylenglicol v axit metacrylic C. Etylenglicol v axit terephtalic D. Glixerol v axit acrylic Cu 53: Dy gm cc cht u lm mt mu nu ca dung dch nc Br2 iu kin thng l A. CH3CHO, CH2=CH-COOH, CH3COCH3, C6H5OH, C6H5NH2 B. CH2=CH-COOH, CH3COCH3, C6H5OH, C6H5NH2, C6H5CH=CH2 C. CH3CHO,CH2=CH-COOH, C6H5OH, C6H5NH2, C6H5CH=CH2 D. CH3CHO, HCOOH, CH2=CH-COOH, C6H5CH3, C6H5NH2, C6H5CH=CH2 Cu 54: Xt cc cp OXH/K sau: Mg2+/Mg; Cr3+/Cr; Fe2+/Fe; Ag+/Ag; Cu2+/Cu. Pin in ho c sut in ng chun ln nht l pin in ho to bi 2 cp OXH/K no? A. Mg2+/Mg v Cr3+/Cr B. Fe2+/Fe v Ag+/Ag C. Ag+/Ag v Cu2+/Cu D. Mg2+/Mg v Ag+/Ag Cu 55: Chn hai dung dch mui X v mui Y tha mn iu kin sau: X + Y khng xy ra phn ng. Y + Cu khng xy ra phn ng. X, Y ln lt l mui no di y? A. NaNO3; NaHCO3 B. KNO3; NaHSO4 C. Fe(NO3)3; NaHSO4 D. Mg(NO3)2; KNO3 Cu 56: Nung 11,2 gam Fe v 26 gam Zn vi mt lng S d cho n khi phn ng xy ra hon ton. Sn phm ca phn ng cho tan hon ton trong dung dch H 2SO4 long, ton b kh sinh ra c dn vo dung dch CuSO4 10% (d = 1,2 gam/ml). Th tch ti thiu ca dung dch CuSO4 trn cn hp th ht kh sinh ra l A. 700 ml B. 800 ml C. 600 ml D. 500 ml Cu 57: Cht no sau y c kh nng loi c nhiu nht cc ion ra khi mt loi nc thi cng nghip c cha cc ion: Fe3+; NO3-; H+; Cu2+; Pb2+; Zn2+; Al3+; Ca2+? A. NaCl B. NaOH C. Na2CO3 D. NH3 Cu 58: Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc thu c sn phm c th trng hp to polime, khng tc dng c vi NaOH. S lng ng phn trn l A. 1 cht B. 2 cht C. 3 cht D. 4 cht Cu 59: Mt amino axit no X ch cha mt nhm -NH2 v mt nhm -COOH. Cho 0,89 gam X phn ng va vi HCl to ra 1,255 gam mui. CTCT ca X l A. H2NCH2COOH B. CH3CH(NH2)CH2COOH C. H2NCH2CH2COOH D. B, C, u ng Cu 60: Dng 340,1 kg xenluloz v 420,0 kg HNO3 nguyn cht c th thu c bao nhiu tn xenluloz trinitrat, bit s hao ht trong qu trnh sn xut l 20%? A. 0,75 tn B. 0,5 tn C. 0,6 tn D. 0,85 tn --------------------(Th sinh c php s dng Bng tun hon) X + Cu khng xy ra phn ng. X + Y + Cu xy ra phn ng.

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P N M 210

C U

.A

C U

.A

C U

.A

C U

.A

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15

D A B C D C C B A B C B D A C

16 17 18 19 20 21 22 23 24 25 26 27 28 29 30

B C D A B D A D B D A B C B B

31 32 33 34 35 36 37 38 39 40 41 42 43 44 45

D A C B D B A B C A B A D B A

46 47 48 49 50 51 52 53 54 55 56 57 58 59 60

B A A B C A C C D B B C B C B

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