BI TP N TP CHNG HALOGEN A. L THUYT Cu 1: Clo phn ng c vi nhng cht no trong cc cht sau y?

* Hg, Al, Fe, Cu, Ni, P * Cc dung dch NaOH, Ca(OH)2, KI, H2SO3, H2S, AgNO2, HBr, NH4OH. * Cc kh: O2, He, CH4, C2H4, C2H2, H2, SO2, CO, NH3. Cu 2: Axit HCl phn ng c vi nhng cht no trong cc cht sau y, vit ptp minh ho. CuO, SiO2, SO2, Fe2O3, Hg, P2O5, CO2, Fe3O4, Na2O, Na2O2, Zn, C, MnO2, HI, Mg, Br2, F2, NH3, Pb(NO3)2, AgNO3, KClO3. Cu 3: a. T Cl2, Fe, K, H2O c th iu ch c nhng mui no? Nhng hiroxit no? b. T MnO2, NaCl, H2SO4 c, Fe, Cu v H2O ngh cch iu ch nhng cht sau: FeCl2, FeCl3, CuSO4 Cu 4: Tinh ch cc cht sau: a. I2 c ln NaCl, KBr, CuS b. NaCl c ln NaBr, NaI, NaOH. c. KCl c ln HgCl2, KBr Cu 5: Tch ri tng cht sau ra khi hn hp a. I2, CaO, Fe, Cu b. S, Fe, I2, KCl c. AlCl3, ZnCl2, CuCl2. d. MgCl2, Zn, Fe, Ag Cu 6: Nhn bit cc cht ng trong cc l mt nhn sau: 1. Khng gii hn thuc th: a. HCl, NaCl, NaOH, CuSO4 b. NaCl, HCl, KI, HI, HgCl2 c. NaCl, MgCl2, AlCl3, NaNO3 d. 2. Ch dng thm mt thuc th: a. HCl, KBr, ZnI2, Mg(NO3)2 b. NaCl, KI, Mg(NO3)2, HgCl2 3. Khng dng thm thuc th: a. CuCl2, HCl, KOH, ZnCl2 b. NaOH, HCl, AlCl3, Cu(NO3)2 c. CaCl2, HCl, Na2CO3 d. MgCl2, HCl, K2CO3, Pb(NO3)2 Cu 7: Nu v gii thch hin tng xy ra khi: a. a ra nh sng 1 ng nghim ng AgCl c nh thm mt t dung dch qu tm. b. Hy gii thch ti sao c th iu ch c nc clo nhng khng th iu ch c nc flo B. BI TON 1. Khi nung nng 44,1 gam KClO3 khng c xc tc, mt phn mui ny b phn tch cho 6,72lt oxi, mt phn b phn tch cho kalipeclorat v kaliclorua.

a. Vit cc ptp b. Tnh khi lng cc sn phm nhn c sau phn ng c. Tnh % khi lng mui kaliclorat b phn tch cho oxi. 2. Cho 69,6 gam mangan ioxit tc dng vi HCl c. Lng clo thu c dn qua 500ml dung dch NaOH 4M iu kin thng. Xc nh CTPT, vit CTCT nh nng mol/l ca cc mui to thnh (coi Vdd = const). 3. Tnh lng natri v th tch kh clo cn dng iu ch 4,68gam natri clorua, bit hiu sut phn ng t 80%. 4. Cho 19,5 gam Zn phn ng vi 7 lt clo th thu c 36,72gam km clorua. Tm hiu sut phn ng. 5. Mt mui clorua ca mt kim loi A c cha 31%A v khi lng. Khi lng nguyn t ca A l 47,9. nh ho tr ca kim loi A. 6. Cho 1,3gam st clorua tc dng vi lng d bc nitrat thu c 3,444gam bc clorua. nh cng thc ca mui st. 7. Cho 0,54 gam mt kim loi R c ho tr khng i tc dng vi dung dch HCl thu c 672ml H2. Xc nh CTPT, vit CTCT nh tn R? 8. Cho 1,03gam mui natri halogenua A tc dng vi AgNO3 d th thu c mt kt ta. Kh kt ta thu c 1,08gam Ag. nh tn mui A. 9. Cho 10,8 gam kim loi ho tr 3 tc dng vi kh clo to thnh 53,4g clorua kim loi. a. Xc nh tn kim loi? b. Tnh lng MnO2 v th tch dung dch HCl 37% (d = 1,19g/ml) cn iu ch lng clo dng cho phn ng trn. Bit hiu sut phn ng iu ch bng 80%. 10. Ho tan 25gam CaCl2. 6H2O trong 300gam nc. Dung dch thu c c khi lng ring bng 1,08g/ml. Tnh nng %, nng mol/l ca dung dch thu c. 11. Cn ly bao nhiu ml dung dch HCl 20% (d = 1,1) v nc c 500 ml dung dch HCl 4% (d = 1,02). 12. Cho 23,2 gam hn hp Fe v Cu phn ng vi HCl d thu c 6,72 lt H 2. Xc nh khi lng v thnh phn % khi lng ca cc cht trong hn hp u? 13. Cho 36,8 gam hn hp vi v vi ho tan vo 5 lt dung dch HCl va th thu c 4,48 lt CO2 A. nh thnh phn khi lng hn hp u B. nh nng mol/l ca dung dch thu c (coi Vdd = const). C. un nng 26,6 gam hn hp NaCl, KCl vi H2SO4 c d. Kh to thnh ho tan vo nc. Dung dch thu c cho tc dng ht vi Zn th thu c 4,48 lt kh. Xc nh khi lng v % khi lng cc cht trong hn hp u? 14. Ho tan hn hp CaO v CaCO3 bng dung dch Y th thu c 448ml kh CO2. C cn dung dch Y th thu c 3,33gam mui khan. a. Tnh s gam mi cht trong hn hp u? b. Cho tt c kh CO2 thu c trn hp th vo 100ml dung dch NaOH 0,25M th thu c nhng mui g? Bao nhiu gam? 15. C h NaI v NaBr. Ho tan hn hp vo nc v cho brom d v dung dch. Sau phn ng c cn dung dch th thy khi lng sn phn nh hn khi lng hai mui ban u l m gam. Ho tan sn phm vo nc v cho clo li qua n d. Sau phn ng em c cn

dung dch th thy khi lng sn phm thu c ln hai nh hn khi lng thu c ln 1 l m gam. Xc nh % khi lng ca NaBr trong hn hp u? 16. Cho 1,92 gam hp kim ng, km, magie tc dng va vi HCl ta c 0,03 mol kh v dung dch A. Cho NaOH d tc dng vi dung dch A th thu c 1 kt ta. Nung kt ta ti khi lng khng i c 0,8 gam cht rn. a. Vit ptp b. Xc nh thnh phn ca hn hp c. T hn hp Cu, Zn, Mg vit ptp iu ch ring 3 mui clorua? 17. Ho tan hon ton 1,70 gam hn hp gm km v kim loi A trong dung dch HCl thu c 0,672lt kh (ktc) v dung dch B. Mt khc, ho tan 1,9 gam kim loi A cn dng khng ht 200ml dung dch HCl 0,5M. a. Xc nh khi lng nguyn t A. Bit A thuc nhm IIA b. Tnh nng % cc cht trong dung dch B bit rng dung dch HCl c nng 10% v trung ho ht dung dch B phi dng ht 12,5 gam dung dch NaOH 29,2%. -----Ht-----