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Cu 1: X l mt este no n chc, c t khi hi i vi CH4 l 5,5. Nu em un 2,2 gam este X vi dung dch NaOH (d), thu c 2,05 gam mui. Cng thc cu to thu gn ca X l A. HCOOCH2CH2CH3. B. HCOOCH(CH3)2. C. C2H5COOCH3. D. CH3COOC2H5. Cu 2: Hai este n chc X v Y l ng phn ca nhau. Khi ha hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l: A. C2H5COOCH3 v HCOOCH(CH3)2. B. HCOOC2H5 v CH3COOCH3. C. C2H3COOC2H5 v C2H5COOC2H3. D. HCOOCH2CH2CH3 v CH3COOC2H5 Cu 3: Cho glixerol (glixerin) phn ng vi hn hp axit bo gm C 17H35COOH v C15H31COOH, s loi trieste c to ra ti a l : A. 6. B. 5. C. 3. D. 4. Cu 4: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lt CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam hp cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. etyl propionat. B. metyl propionat. C. isopropyl axetat. D. etyl axetat. Cu 5: Polivinyl axetat (hoc poli(vinyl axetat)) l polime c iu ch bng phn ng trng hp A. C2H5COO-CH=CH2. B. CH2=CH-COO-C2H5. C. CH3COO-CH=CH2. D. CH2=CH-COO-CH3 Cu 6: Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3 thu c cht hu c T. Cho cht T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. HCOOCH=CH2. B. CH3COOCH=CH2. C. HCOOCH3. D. CH3COOCH=CH-CH3 Cu 7: Polime dng ch to thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=C(CH3)COOCH3. B. CH2 =CHCOOCH3. C. C6H5CH=CH2. D. CH3COOCH=CH2 Cu 8: Nhng hp cht trong dy sau thuc loi este: A. etxng, du nhn bi trn my, du n. B. du lc, du da, du c. C. du m, hc n, du da. D. m ng vt, du thc vt, mazut. Cu 9: Poli etyl acrilat c iu ch bng cch trng hp monome sau: A. CH2=CHCOOCH2CH3. B. CH2=CHOOCCH3. C. CH3COOCH=CHCH3. D. CH2=CH-CH2OOCH. Cu 10. Hp cht hu c A n chc, c t khi hi so vi H2 l 43. un A vi dd KOH va ri c cn thu c 5,5 g mui ca axit hu c khan v 1,6 g ru. CTCT ca A l VT- collection 2/25/2009 16:04:00 a2/p2 1 Created on

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A. HCOO-CH2CH= CH2. B. HCOO-C(CH3)= CH2. C. CH3COO-CH=CH2. D. CH3-OOCCH= CH2 Cu 11. X l este thun chc c hai lin kt i trong phn t, khng lm mt mu dd nc brm. Khi X tc dng vi dd NaOH un nng, sinh ra mt mui v mt ru c t l s mol tng ng 2:1. t chy hon ton mt lng cht X th th tch hn hp CO2, H2O sinh ra bng 1,5 ln th tch ca ca hn hp X v oxi va t ht X cng 109,2 0C v1at. Cng thc cu to ca X l A. HCOO-CH2-CH2-OOCH. B. CH3-OOC-COO-CH3. C. CH3-OOC-CH2-COO-CH3. D. HCOO-(CH2)3-OOCH. Cu 12. Trong bnh kn dung tch khng i cha mt lng O2 gp i lng cn thit t chy hn hp hi hai este ng phn c cng thc phn t l CnH2nO2. Nhit v p sut trong bnh lc o u l 136,5 C v 1 atm. Sau khi t chy hon ton hai este, gi o nhit bnh 819 K, p sut trong bnh lc ny l 2,375 atm. Cng thc phn t v cng thc cu to ca 2 este. CTPT CTCT A. C3H 6O2 ; HCOOC2H 5 vCH3COOCH3 B. C 4H 6O2 ; CH3COOC2H 5 vC 2H 3COOCH 3 hoc 3COOC2H 5 vHCOOC H 5 CH 3 hoc 2H 3COOCH3 vHCOOC3H 5 C C. C 4H 6O2 ; HCOOC3H 7 vCH3COOC2H 5 hoc 3COOC2H 5 vC 2H 5COOCH3 CH hoc 2H 5COOCH vHCOOC H 7 C 3 3 D. Khng c phng n no trn l ng Cu 13. Cho 5,7 gam hn hp 2 este n chc, mch h, ng phn ca nhau tc dng vi 50ml dung dch NaOH. un nh, gi s phn ng xy ra hon ton. trung ho lng NaOH d cn 50ml dung dch H2SO4 0,25M, thu c dung dch D.Tnh tng s mol 2 este trong 5,7 gam hn hp bit rng trung ho 10ml dung dch NaOH cn 30ml dung dch H2SO4 0,25M. Chn phng n ng: A . 0,01mol B. 0,0375 mol C. 0,05mol D. 0,075 mol Cu 14. X phng ho hon ton 2,64 gam hn hp CH 3COOC2H5 v CH3CH2COOCH3 bng
dung dich NaOH 1M. Th tch dung dch NaOH cn dng l A. 30ml B. 60ml C. 40ml D. 50ml Cu 15. X l cht lng khng mu, khng lm i mu phenolphtalein. X tc dng c vi dung dch Na2CO3 v AgNO3/NH3. X l cht no sau y? A. H-COOCH3 B. HCOOH C. CH3COOH D. HCHO Cu 16. Thc hin phn ng ese ho gia aminoaxit X v ru metylic thu c este A c t khi hi so vi khng kh bng 3,069. CTCT ca X l A. HOOC- CH(NH2)-COOH B. H2N-CH2-CH2-COOH C. H2N-CH2-COOH D. CH3CH(NH2)COOH

Cu 17. C 3 hp cht hu c mch h A, B, C trong phn t mi cht u c cha C, H, O. Khi lng phn t mi cht u bng 60 vC. VT- collection 2/25/2009 16:04:00 a2/p2 2 Created on

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Xc nh cng thc cu to mi cht bit rng: A c phn ng vi vi; B mi c phn ng vi Na, phn ng trng bc; C c phn ng trng bc nhng khng c phn ng vi Na. Chn phng n ng:

C. A : H COOCH3 ; B : CH2 = CH COOH ; C : HCOOH

Cu 18. Hn hp A gm 2 este l ng phn ca nhau v u c to thnh t axit n chc v ru n chc. Cho 2,2 gam hn hp A bay o hi 136,5 C v 1atm th thu c 840 ml hi este. Mt khc em thu phn hon ton 26,4 gam hn hp A bng 100 ml dung dch NaOH 20% (d = 1,2 gam/ml) ri em c cn th thu c 33,8 gam cht rn (khan). Xc nh cng thc phn t v tnh % khi lng mi este trong hn hp A. A. Este 1 : C 2 H 5 COOC 3 H 7 ; %Este 1 = 45,5% Este 2 : C 3 H 7 COOC 2 H 5 B. Este 1 : C 2 H 5 COOCH 3 Este 2 : HCOOC 3 H 7 C. Este 1 : HCOOC 3 H 7 ; ; ; ; %Este 2 = 54,5% %Este 1 = 16,7% %Este 2 = 83,3% %Este 1 = 66,7%

Este 2 : CH 3 COOC 2 H 5 ; %Este 2 = 33,3% D. C 2 phng n B v C u ng Cu 19. Este no sau y khi thu phn trong mi trng baz thu c hai mui v mt
nc: A. CH3COOC2H5 B. CH3COOC6H5 C. CH2 = CH - COOCH3 D. HCOOCH = CH2 Cu 20. A l hn hp gm hai cht hu c mch thng X, Y (ch cha C, H, O) khi tc dng va vi 8 gam NaOH thu c mt ru n chc v hai mui ca hai axit hu c n chc. Lng ru thu c cho tc dng vi Na d c 2,24 lit H 2 (ktc). X, Y thuc loi hp cht g? A. 1 axit v 1 este B. 1 ru v 1 este C. 1 axit v 1 ru D. 2 este Cu 21. un 20,4 gam mt cht hu c A n chc vi 300ml dung dch NaOH 1M thu c mui B v hp cht h c C. Cho C phn ng vi Na d thu c 2,24 lit H 2(ktc). Khi nung B vi NaOH rn thu c kh D c t khi i vi O2 bng 0,5. Khi oxi ho C bng CuO c cht hu c E khng phn ng vi AgNO3/NH3. Xc nh CTCT ca A? A. CH3COOCH2CH2CH3 B. CH3COO-CH(CH3)2 C. CH3CH2COOCH(CH3)2 D. CH3CH2COOCH2CH2CH3 Cu 22. Cht X c cng thc phn t l C11H20O4. X tc dng vi NaOH to mui ca axit hu c Y mch thng v 2 ru l etanol v propanol-2. Cng thc cu to ng ca X l: A. C2H5OOC-(CH2)4-COOCH(CH3)2 B.C2H5OOC-(CH2)4-COOCH2CH2CH3 C. C2H5COO-(CH2)4-COOCH(CH3)2 D.C3H5OOC-(CH2)3-COOCH(CH3)2

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Cu 23. Hai este X, Y l dn xut ca benzen c cng thc phn t l C9H8O2. X, Y u cho
phn ng cng vi Br2 theo t l mol 1:1. X tc dng vi dung dch NaOH cho mt mui v mt anhit. Y tc dng vi dung dch NaOH d cho hai mui v nc (cc mui t X, Y u c phn t lng ln hn 82). Tm cng thc phn t ca X, Y. (chn p n ng) A. C6H3(CHO)(CH = CH2)(OH) v CH2 = CH - COOC6H5 B. C6H5COOCH = CH2 v HCOOCH = CH - C6H5 C. C6H5COOCH = CH2 v HCOO C6H4 (CH = CH2) D. C6H5COOCH = CH2 v CH2 = CH -COOC6H5 Cu 24. C 4 cht mch h ng vi cng thc phn t C 3H6O, C3H6O2, C3H4O, C3H4O2 c k hiu ngu nhin l A, B, C, D trong A, C cho phn ng trng gng; B, D phn ng c vi NaOH; D phn ng vi H2 to thnh B, oxi ho C thu c D. Tm cng thc cu to ca A, B, C, D. (chn p n ng) A. C2H5CHO, HO-CH2-CH2-CHO, CH2 = CH - CHO, H - COO - CH = CH2 B. C2H5CHO, C2H5 COOH, CH2 = CH - CHO, CH2 = CH - COOH C. C2H5CHO, C2H5 COOH, CH C - CH2 - OH , CH2 = CH - CHO D. C2H5CHO, HCOOC2H5, CH2 = CH - CHO, HCOOCH = CH2 Cu 25: Hn hp X gm 2 cht hu c mch h, cha cng mt loi nhm chc ho hc. Khi un nng 47,2 gam hn hp X vi lng d dung dch NaOH th thu c mt ru n chc v 38,2 gam hn hp mui ca 2 axit hu c n chc, k tip nhau trong dy ng ng. Mt khc, nu t chy ht 9,44 gam hn hp X cn va d 12,096 lt kh O2, thu c 10,304 lt kh CO2. Cc kh do iu kin chun. Cng thc cu to ca tng cht c trong X l: A. HCOOCH2-CH=CH2 v CH3COOCH2-CH=CH2 B. CH3COOCH2-CH=CH2 v C2H5COOCH2-CH=CH2 C. CH2=CHCOOCH2-CH3 v CH3CH=CH-COOCH2-CH3 D. CH2=CHCOOCH3 v CH3CH=CH-COOCH3

1 11 21

2 12 22

3 13 23

4 14 24

5 15 25

6 16 26

7 17 27

8 18 28

9 19 29

10 20 30

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1.D

2.B 3.A 4.B 5.C 6.B 7.A 8.B 9.A 10.D 11.D 12.A 13.C 14.A 15.B 16.C 17.D 18.D 19.B 20.D 21.B 22.A 23.D 24.B 25.A

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