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BI TP PHN IN MN PHN TCH THC PHM Page 1

Cu hi
1. Hy so snh cc phng php chun in th so vi nhng phng
php chun th tch
2. Chng minh rng trong phng php chun in th, th ca dung dch bin
i t ngt ti thi im st trc v st sau im tng ng.
3. Phn tch nhng u im ca phng php chun in th?
4. C my loi in cc? Trnh by cu trc ca in cc loi 3? Cho v d
5. Trnh by cu trc in cc loi 2? Cho v d
6. Trnh by cu trc in cc quihydron. Chng minh rng ngi ta c th dng
in cc ny o pH
7. C my loi phng php chun in th? Trnh by mt v d v phng
php kt ta
Bi tp
Bi 1 : Tnh Ep ca mt h Pin c cu to nh sau:
(Pt) H
2
|HCl Ag
+
|Ag
Cho: E
o
2H
+
/ H
2
= 0 (V) E
o
Ag
+
/Ag = 0,779 (V)
[HCl] = 0,78 M [Ag
+
] = 0,25 M
Bi 2 : Cho h Pin c cu to nh sau:
Cd|Cd
2+
|H
2
SO
4
|HgSO
4
.Hg
Cho bit: E
o
Cd
2+
/Cd = -0,4 (V) E
o
HgSO
4
/ SO
4
2-
= 0,486 (V)
[Cd
2+
]= 0,8 (M) [H
2
SO
4
]= 0,66 (M)
a. Vit cc phn ng c hai cc.
b. Tnh E
Bi 3 : Cho h pin c cu to nh sau:
Cd|CdCl
2
Hg
2
Cl
2
.Hg(Pt)
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BI TP PHN IN MN PHN TCH THC PHM Page 2

Bit: E
o
Cd
2+
/ Cd = - 0.4 (V),E
o
Hg
2
Cl
2
/2Hg = 0.286 (V), [CdCl
2
]= 0.56 M
a. Vit cc phn ng hai in cc. Phn ng trong pin
b. Tnh Ep
Bi 4: Cho h pin c cu to nh sau:
Zn |ZnCl
2
Hg
2
Cl
2
|Hg
Bit: E
o
Zn
2+
/ Zn = - 0.77 v , E
o
Hg
2
Cl
2
/ 2Hg = 0.465v
[ZnCl
2
] = 0.98 N
a. Vit cc phn ng hai in cc.
b. Tnh Ep
Bi 5 : Cho mt h pin c cu to nh sau:
Ag.AgCl |HCl Hg
2
Cl
2
.Hg
Cho bit rng: E
o
AgCl/Cl
-
= 0.223 ( V) , E
o
Hg
2
Cl
2
/ 2Hg = 0.465 (V)
[HCl]= 0.99 (M) o
HCl
= 0.95
a. Vit cc phn ng hai in cc.
b. Tnh Ep.
Bi 6 : Cho h pin c cu to nh sau:
Ag.AgCl |HCl | AgNO
3
|Ag.
Cho bit: E
o
AgCl/Ag = 0.223 (V) , E
o
Ag
+
/Ag = 0.8 (V)
[HCl] = 0.9 (M) , [AgNO
3
] = 0.8 (M)
a. Vit phn ng xy ra hai in cc.
b. Tnh Ep.
Bi 7 : Cho 1 pin c cu to nh sau : Ag AgNO CuCl Cu / // /
3 2

) ( 8 , 0 ); ( 34 , 0
2
V E V E
o
Ag Ag
o
Cu Cu
= =
+ +
; | | M AgNO 1
3
= c 85 , 0 = o ; | | M CuCl 7 , 0
2
= c
8 , 0 = o
a. Tnh
p
E
b. Phi thm bao nhiu gam AgNO
3
Ep tng thm 0.02 n v
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BI TP PHN IN MN PHN TCH THC PHM Page 3

Bit V
b
= 1lt
Bi 8 : Chn h pin cho cc phn ng chun sau:
a. Chun H
2
SO
4
bng dung dch tiu chun NaOH 0,1N
b. Chun Cu
2+
bng dung dch tiu chun Sn
2+
0,1N
c. Chun Fe
2+
bng dung dch tiu chun K
2
Cr
2
O
7
0,1N
Bi 9 : Chn h pin cho cc phn ng chun sau:
a. Chun H
2
SO
4
bng dung dch tiu chun NaOH 0,1N
b. Chun Sn
2+
bng dung dch tiu chun Cu
2+
0,1N
c. Chun Br
-
bng dung dch tiu chun Ag
+
0,1N
Bi 10 : Chn h pin cho cc phn ng chun sau:
a. Chun H
2
SO
4
bng dung dch tiu chun NaOH 0,1N
b. Chun Cu
+
bng dung dch tiu chun Ag
+
0,1N
c. Chun I
-
bng dung dch tiu chun Ag
+
0,1N
Bi 11: Lp pin trong xy ra cc phn ng sau:
a) Cu CdSO CuSO Cd + = +
4 4

b) HBr Ag H AgBr 2 2 2
2
+ = +
c) HCl Cl H 2
2 2
= +
d)
+ + +
+ = +
2 2 3
2 2 Fe Zn Fe Zn
e)
) (r
AgCl Cl Ag = +
+

Bi 12 : Chn in cc to h pin cho cc qu trnh chun sau :
- Chun dung dch Cl
-
bng dung dch Ag
+

- Chun dung dch HCl bng dung dch NaOH
- Chun dung dch H
2
SO
4
bng dung dch NaOH
- Chun dung dch Fe
2+
bng dung dch Cr
2
O
7
2-

- Chun dung dch Fe
2+
bng dung dch MnO
4
-

- Chun dung dch Sn
2+
bng dung dch Fe
3+
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BI TP PHN IN MN PHN TCH THC PHM Page 4

Bi 13: Ngi ta tin hnh chun 50 ml dung dch Fe
2+
bng dung dch tiu chun
Ag
+
0.05 M.
a. Chn h pin cho qu trnh chun trn
b. Cho th tch Ag
+
tiu tn ti im tng ng l 37ml. Tnh hm
lng g/lt dung dch st ban u
c. Cho E
o

Ag+/Ag
= 0.79 (V) v E
o

Fe3+/Fe2+
= 0.76 (V). Tnh Ep.
Tnh bc nhy th ti thi im d v thiu 0.1% qu trnh.
Bi 14: Ngi ta tin hnh chun 50 ml dung dch Sn
2+
bng dung dch Fe
3+
tiu
chun 0.05 M.
a. Chn h pin cho qu trnh chun .
b. Cho th tch Fe
3+
tiu tn ti im tng ng l 25ml.Tnh g/l dung
dch st ban u
c. Cho E
o

Sn4+/ Sn2+
= 0,15 (V) v E
o

Fe3+/Fe2+
= 0,76 (V). Tnh bc nhy th
ti thi im d v thiu 0,1% qu trnh.
Bi 15 : Ngi ta tin hnh chun 50 ml dung dch Fe
2+
bng dung dch K
2
Cr
2
O
7

tiu chun 0.02 M.
a. Thit lp h pin cho qu trnh chun trn
b. Vit phng trnh phn ng xy ra gia hai in cc v phng trnh
chung ca h. Tnh Ep
c. Cho E
o

Fe
3+
/ Fe
2+
= 0.76 (V) v E
o
Cr
2
O
7
2-
/Cr
3+
= 1.36 (V). Tnh bc nhy
th E
dd
ti thi im d v thiu 0.1% qu trnh.Cho pH=0
Bi 16 : Ngi ta tin hnh chun 50 ml dung dch Sn
2+
bng dung dch Ag
+
tiu
chun 0.05 M.
a. Chn h pin cho qu trnh chun .
b. Tnh g/lt Sn
2+
cho bit th tch bc tiu tn hi im tng ng l
25ml.
c. Tnh bc nhy th ti thi im d v thiu 0.1% qu trnh.
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BI TP PHN IN MN PHN TCH THC PHM Page 5

Bi 17 :Ngi ta tin hnh chun 100 ml dung dch NaCl bng dung dch Ag tiu
chun 0.05 M, ti im tng ng VAg tiu tn l 67 ml. Hai in cc c o
l: Ag.AgCl |HCl | Ag
+
|Ag .
a. Vit phng trnh phn ng xy ra gia hai in cc v phng trnh chung
ca h.
b. Cho E
o
AgCl/ Ag = 0.223 (V) , E
o
Ag
+
/Ag = 0.8 (V).
Yu cu: Tnh Ep.
Tnh th ti thi im khi cho d v thiu 0.1% qu trnh.
Bi 18 : Ngi ta tin hnh chun 100 ml dung dch Fe
2+
1 M, bng dung dch
Cr
2
O
7
2-
0.25 M, vi hai in cc tr (Pt):
Cho [H
+
] = 1 (M)
E
o
Fe
3+
/Fe
2+
= 0.77 (V)
E
o
Cr
2
O
7
2-
/ Cr
3+
= 1.36 (V)
a. Vit phng trnh phn ng xy ra ca qu trnh.
b. Tnh E
t
ca qu trnh.
c. Tnh th ca dung dch ti thi im d v thiu 0.1% qu trnh.
Bi 19 : Tnh E
cb
cho cc qu trnh chun sau : Cho E
0
2H+/H2
= 0, E
0
AgCl/Ag
=
0,248v, E
0
Ag+/Ag
= 0,8v, E
0
MnO 4-/Mn2+
= 1,54v, E
0
Sn4+/Sn2+
= -0.15v, E
0
Cr27 2-/Cr 3+
=
1,36V, [H
+
] = 1, E
0
Fe3+/Fe2+
= 0,77v
a. Chun dung dch Cl
-
bng dung dch Ag
+

b. Chun dung dch Fe
2+
bng dung dch Cr
2
O
7
2-

c. Chun dung dch Fe
2+
bng dung dch MnO
4
-

d. Chun dung dch Sn
2+
bng dung dch Fe
3+