S Gio dc v o to Hng Yn

K thi chn hc sinh gii cp tnh nm hc 2009 - 2010

Mn thi: Ho hc - Lp 12 (Thi gian lm bi 180 pht) chnh thc

Cu I. (1,50 im) Khi lng ring ca nhm clorua khan (trng thi hi) o 2000C v 8000C, trong cng p sut kh quyn ln lt l 6,9 g/dm3 v 1,5 g/dm3. 1. Xc nh phn t khi ca nhm clorua mi nhit trn. Bit rng, hng s kh R = 0,082 l.atm/mol.K. 2. Vit cng thc phn t v cng thc cu to ca nhm clorua mi nhit trn. Cu II. (2,00 im) 1. Dung dch X gm CH3COOH 0,1 M v CH3COONa 0,1 M. a. Tnh pH ca dung dch X. b. Tnh pH ca dung dch thu c sau khi: - Thm 0,001 mol HCl vo 1 lt dung dch X. - Thm 0,001 mol NaOH vo 1 lt dung dch X. Bit rng: Ka (CH3COOH) = 10-4,76 ; KW (H2O) = 10-14 c. C nhn xt g v s bin i pH ca dung dch sau khi thm HCl v NaOH ? 2. C hin tng g xy ra nu trn 5,00 ml dung dch H2C2O4 0,040 M vi 5,00 ml dung dch SrCl2 0,080 M ? Bit rng: KW (H2O) = 10-14 ; K a1 (H2C2O4) = 10-1,25; K a 2 (H2C2O4) = 10-4,27. Tch s ion Ks(SrC2O4) = 10-6,4. Cu III. (1,50 im) C cc dung dch sau: Bari hiroxit, ch axetat v magie sunfat. 1. Chn hai thuc th m mi thuc th c dng c th phn bit c cc cation trong cc dung dch trn. 2. Chn mt thuc th c dng c th phn bit c cc anion trong cc dung dch trn. 3. Chn hai thuc th m mi thuc th c dng c th phn bit c cc dung dch trn. Vit cc phng trnh phn ng (nu c) gii thch.
HSG 12 - 2010

Bit rng: S thu phn ca cc ion trong dung dch khng ng k; thuc th cc trng hp trn l nhng cht khc nhau.

Cu IV. (1,50 im) 1. Cho cc s chuyn ho sau: a. (CH3)2CHCH2COOH Br X NH Y , P

2 3

, b. (CH3)2CHCOCOOH NH M H N Pt
3 2

O ,H c. CH2=CH-CH=CH2 G t I H K Vit cng thc cu to cc sn phm hu c X, Y, M, N, G, I, K. 2. T metan v cc ha cht cn thit, hy vit cc phng trnh phn ng to ra C6H5-N=N-C6H4-N(CH3)2. Cu V. (2,00 im) Cho a gam hn hp gm 2 amino axit no, cha 1 nhm amino (NH2) v 1 nhm cacboxyl (COOH) tc dng vi 110 ml dung dch HCl 2M, thu c dung dch A. tc dng ht vi cc cht trong dung dch A cn dng 140 ml dung dch KOH 3M. Mt khc, t chy hon ton a gam hn hp 2 amino axit trn v cho ton b sn phm chy qua bnh ng dung dch NaOH d, thy khi lng bnh tng thm 32,8 gam. Bit rng, t chy amino axit th nit to thnh dng n cht. 1. Xc nh cng thc phn t ca 2 amino axit trn. Bit rng, t l phn t khi ca 2 amino axit l 1,373. 2. Tnh % s mol ca mi amino axit trong hn hp u. Cu VI. (1,50 im) Phn tch nguyn t trong hp cht hu c A ch cha C, H, O, trong C chim 71,006% v H chim 10,059%. 1. Xc nh cng thc phn t ca A. Bit rng, phn t khi ca A l 338 u. 2. Thc nghim cho bit: A tc dng vi axit to thnh este; hiro ha A c xc tc Pd to thnh hp cht X; X cng tc dng vi axit to thnh este; oxi ha X bng KMnO4 to thnh CO2 v mt axit icacboxylic c mch cacbon khng phn nhnh. Hy a ra mt cng thc cu to ph hp c th c ca X v A vi cu trc i xng v mch cacbon khng phn nhnh. Vit cc phng trnh phn ng gii thch. C6 H 5CO3 H
0 2 3 +

HSG 12 - 2010

Cho: H = 1; O = 16; C = 12; Cl = 35,5; N = 14; Na = 23; K = 39; Al = 27; Ca = 40; Sr = 88.

HSG 12 - 2010