Bi tp kho st cht lng 1) Mot hon hp A gom Fe va mot kim loai M hoa tr 2.

-Hoa tan hoan toan 12,1g hon hp A bang H2SO4 loang th thu c 4,48lt kh H2(kc). -Hoa tan hoan toan 12,1g hon hp A bang H2SO4 ac nong th thu c 5,6 lt kh SO2(kc). a. Viet cac phng trnh phan ng co the xay ra. b. Xac nh kim loai M.

2) Hoa tan 29,4 g hh Al, Cu, Mg vao dd HCl d tao 14 lt kh 00C, 0,8 atm. Phan khong tan cho tac dung vi dd H2SO4 tao 6,72 lt kh SO2 kc.

a.Xac nh % khoi lng moi kim loai trong hh. b. Cho hh tren tac dung vi H2SO4 kh tao thanh c dan qua dung dch Ca(OH)2 1M sau 1 thi gian thu c 54 g ket tua. Tnh V Ca(OH)2 can dung 3) ot chay hoan toan 8,96 l H2S (ktc) trong kh SO2 (d), ngi ta thay tao thanh a (g) chat ran .Cho a gam chat ran chay trong 5,6 g Fe (nong) roi cho san pham hoa tan vao dd H2SO4 ac, nong(d), tnh khoi lng kh tao thanh va tm a g. 4) B tc cc phn ng sau: Bit rng D, E, Q l cc phi kim n cht
t C A B + C MnO 2
0

B pnc D + E D + H 2O F + G
t C E + F c A + B+ H2O E + M + H2O N + T E + R + H2O N + T M+R Q + H2O M+F Mui axit Y Mui axit Y + F Mui trung ha X + H2O
0

5) em ho tan ht 3,9 gam hn hp X gm Mg v kim loi M (ho tr III) bng dung dch HCl d

thu c 4,48 lt kh (ktc) a. Tnh th tch dung dch HCl 7,3% (D = 1,25 g/ml) ho tan 3,9 gam hn hp X b. Xc nh kim loi M, bit s mol ca M gp i ca Mg trong hn hp X
6) e hoa tan 4g oxit FexOy can 52,14 ml dd HCl 10%(D=1,05g/ml). Xac nh cong thc phan t cua oxit. 7) Cho 31.84g hon hp NaX, NaY (X,Y la hai halogen hai chu k lien tiep) vao dd AgNO3 d, thu d thu c 57,34g chat ket tua. a. Tm cong thc cua muoi. b. Tnh khoi lng moi muoi trong hon hp ban au. 8) Mt mui to bi kim loi ho tr II vi halogen. Cho a gam hp cht vo nc thu c 100ml dung dch A. Ly 1/2 dung dch, thm lng d dung dch AgNO3 thu c 9,4 gam kt ta. Cn cho 1/2 dung dch cn li tc dng vi Na2CO3 d thu c 2,1 gam kt ta. a. Xc inh cng thc phn t ca mui b. Tnh CM dung dch A. 9) Cho 2,55 gam hn hp X gm Al, Fe, Cu phn ng vi dung dch NaOH d, thu c 1,68 lit H 2(ktc), dung dch B v cht rn C. Cho C tc dng vi HCl d sinh ra 0,224 lit kh H2(ktc), dung dch E v cht rn F. Tnh phn trm v khi lng ca Al, Fe, Cu trong X: 10) C 2 kim loi A, B u c ho tr II. Khi lng nguyn t ca chng t l 3 : 5, s mol trong hn hp t l 2 : 1. Cho 8,8 gam hn hp kim loi trn tc dng vi dung dch HCl d thu c 6,72 lt H2 (ktc) a. Xc nh A, B

b. Nu cho 8,8 gam hn hp kim loi trn tc dng vi H2SO4 c nng th thu c V lt kh SO2 (ktc). Cho V lt SO2 tc dng vi 500ml dung dch Ca(OH)2 0,4M. Hi thu c nhng mui no? Tnh nng mol/l cc mui thu c (coi th tch dung dch khng thay i) 11) Khi nhiet phan 12,25g KClO3 ran, thu c hon hp ran A va 0,672 l kh (ktc). Hoa tan A trong nc roi cho dd loi qua AgNO3 d thu c 4,305g chat ket tua. Tnh thanh phan phan tram cua tng chat trong hon hp A. Cho rang tat ca KClO3 a b phan huy hoan toan. 12) Hoa tan hoan toan FexOy trong dung dch H2SO4 ac nong, thu c dung dch A va kh B. Sau o lam tiep cac th nghiem sau: Cho kh B tac dung vi dung dch brom, dung dch NaOH, dung dch Na2CO3, PCl5, kh clo (di anh sang mat tri). Cho dung dch A phan ng vi dung dch NaOH d, loc ket tua roi em nung trong khong kh en khoi lng khong oi c chat ran A1. Tron A1 vi bot nhom roi nung nhiet o cao thu c hon hp A2 gom cac oxit trong o co FenOm. Hoa tan A2 trong dung dch HNO3 th thu c chat kh de hoa nau ngoai khong kh. Viet ay u cac phng trnh phan ng xay ra trong cac qua trnh th nghiem tren. 13) Co 5 dung dch anh so t 1 en 5, o la nhng dung dch Ba(NO3)2, Na2CO3, MgCl2, K2SO4 va Na3PO4 ( so th t khong theo trat t cac chat hoa hoc). Xac nh ten cac chat c anh so. Biet rang: - Dung dch 1 tao thanh ket tua trang vi cac dung dch 3 va 4. - Dung dch 2 tao ket tua trang vi dung dch 4. - Dung dch 3 tao ket tua trang vi dung dch 1, 5. - Dung dch 4 tao ket tua trang vi cac dung dch 1, 2, 5. Ket tua sinh ra do dung dch 1 va dung dch 3 b phan huy nhiet o cao, tao ra oxit kim loai. 14) Kh hon ton 4,06 gam mt oxit kim loi bng CO nhit cao thnh kim loi. Dn ton b kh sinh ra vo bnh ng dung dch Ca(OH)2 d, thy to thnh 7 gam kt ta. Nu ly lng kim loi sinh ra ha tan ht vo dung dch H2SO4 long d th thu c 1,176 lt kh H2(ktc).Xc nh cng thc phn t ca oxit kim loi. 15) Ha tan hon ton 9,28 gam mt hn hp X gm Mg, Al, Zn vi s mol bng nhau trong mt lng va dung dch H2SO4 c nng, thu c dung dch Y v 0,07 mol mt sn phm duy nht cha lu hunh. Xc nh xem sn phm cha lu hunh l cht no trong s cc cht sau : H2S, S, SO2 ? 16) Cho 3, 87 gam hn hp A gm Mg v Al vo 250 ml dung dch X cha HCl 1M v H2SO4 0,5M, c dung dch B v 4,368 lt H2 (ktc). a . Chng minh rng trong dung dch B cn d axit. b.. Tnh thnh phn phn trm khi lng mi cht trong hn hp A. c. . Tnh th tch dung dch C gm NaOH 0,02M v Ba(OH)2 0,01M cn trung ha ht axit d trong B. d. Tnh th tch ti thiu ca dung dch C (vi nng trn) tc dng vi dung dch B lng kt ta nh nht. Tnh lng kt ta . e . Tm gii hn khi lng mui thu c trong dung dch B. 17) Tin hnh nung x1 gam Cu vi x2 gam oxi th thu c sn phm A1. un nng A1 trong x3 gam dung dch H2SO4 98%. Sau khi khi tan thu c dung dch A2 v kh A3. Kh A3 khng to kt ta vi dung dch Pb(NO3)2 nhng lm nht mu dung dch brom, c hp th hon ton bi 200 ml dung dch NaOH 0,15 M to ra 2,3 gam mui. Khi c cn dung dch A2 th thu c 30 gam tinh th CuSO4.5H2O. Cho dung dch A2 tc dng vi dung dch NaOH, thu c lng kt ta nhiu nht phi dng t nht 300 ml dung dch NaOH 1M. Cho lng kt ta tan trong HCl va , sau nhng mt thanh st vo dung dch. Sau thi gian phn ng, khi lng thanh st tng 0,8 gam. a. Tnh x1, x2, x3 b. Tnh khi lng st tan vo dung dch

c. Tnh khi lng mui c trong dung dch sau khi nhng thanh st vo.