E THI TH AI HOC MON HOA LAN 3

Thi gian : 90 phut khong ke thi gian phat e . e thi co 60 cau gom 8 trang

Ho, ten th sinh: ................................................ So bao danh:..................................................... Cho khoi lng nguyen t (theo vC) cua cac nguyen to : Na = 23 ; K = 39 ; Ba = 137 ; Ca = 40; Mg = 24 ; Al = 27 ; Fe = 56; Zn = 65 ; Cu = 64 ; Ag = 108 ; Cr = 52 ; Sn = 119 ; S = 32 ; Si = 28 ; C = 12 ; Cl = 35,5 ; Br = 80 ; N = 14 ; P = 31 ; O = 16 ; I = 127 ; H = 1. I. PHAN CHUNG CHO TAT CA TH SINH (40 Cau, t cau 1 en cau 40) Cau 1: Oxi hoa 28,8 gam Mg bang V lt hon hp kh A ( ktc) gom O2 va O3 co t khoi hi oi vi H2 la 20, thu c m gam hon hp X gom Mg va MgO. Hoa tan hoan toan hon hp X bang mot lng va u dung dch hon hp HCl 1M va H2SO4 0,5M, thu c H2O, H2 va dung dch Y cha ( m + 90,6) gam hon hp muoi. Cac phan ng xay ra hoan toan. Gia tr cua V la A. 2,688. B. 5,376. C. 1,344. D. 6,272. Cau 2: Cach phan biet nao sau ay khong ung? A. Dung quy tm phan biet cac dung dch: Na2SO4, Na2CO3, NaCl, H2SO4, BaCl2, NaOH. B. Dung CO2 va H2O phan biet cac chat bot mau trang: BaCO3, BaSO4, NaCl, Na2CO3, Na2SO4. C. Dung dung dch Ba(OH)2 d phan biet cac dung dch: FeCl2, AlCl3, NH4NO3, (NH4)2SO4, Fe(NO3)3, NaCl, MgCl2. D. Dung H2O phan biet cac chat: BaO, Al2O3, Fe, Al, K2O, Na. Cau 3: Oxi hoa m gam ancol n chc A bang oxi (co xuc tac thch hp ) c hon hp X, roi chia thanh ba phan bang nhau. Cho phan mot tac dung vi mot lng d dung dch AgNO3/NH3 thu c 6,48 gam Ag. Cho phan hai tac dung vi dung dch NaHCO3 d thu c 0,672 lt kh ( ktc). Cho phan ba tac dung vi Na ( va u), thu c 1,232 lt H2 (ktc) va 6,22 gam chat ran. Cong thc cau tao cua A la A. CH3CH2CH2OH. B. CH2=CHCH2OH. C. CH3OH. D. CH3CH2OH. Cau 4: Amin X (C5H13N) tac dung vi dung dch HCl tao ra muoi dang RNH3Cl ( R la goc hirocacbon), este nh chc co mach cacbon khong phan nhanh Y ( C6H10O4), tac dung vi dung dch NaOH tao ra mot muoi va mot ancol, hirocacbon Z ( C6H10) tac dung vi dung dch AgNO3/NH3 tao ra ket tua vang nhat C6H9Ag, ancol T ( C5H12O) tac dung vi CuO, nhiet o tao ra xeton. Hai chat co cung so cong thc cau tao trong trng hp nay la A. X va Y. B. X va Z. C. Y va Z. D. Y va T. Cau 5: Cho mot dong ien co cng o khong oi i qua 2 bnh ien phan mac noi tiep. Bnh 1 cha 400 ml dung dch CuSO4 va NaCl (ien cc tr, mang ngan xop), bnh 2 cha 100 ml dung dch hon hp AgNO3 0,2M; Cu(NO3)2 0,4M, Fe(NO3)3 0,2M (ien cc tr). Sau mot thi gian ngat dong ien, thay anot bnh 1 thoat ra 1,12 lt kh ( ktc), ong thi dung dch thu c lam phenoltalein khong mau hoa hong . Catot cua bnh 2 tang them A. 4,08 gam. B. 4,72 gam. C. 3,28 gam. D. 3,92 gam. Cau 6: Cho cac phan ng sau: H , t 0 (1) FeS2 + HNO3 ac nong (2) CrO3 + H2O (3) Protein + H2O (4) HI + H2SO4 ac (5) CaOCl2 + HCl (6) CH3CH(OH)CH3 + CuO
t MnO 2 , t t Ni, t (7) SiO2 + C (8) KClO3 (9) Triolein + H2 So phan ng oxi hoa-kh xay ra la A. 4. B. 7. C. 6. D. 5. Cau 7: Cho cac chat sau: Triolein, glucoz, tinh bot, fructoz, axit fomic, xenluloz, phenol, anilin, saccaroz, axetilen, alanin, anehit axetic. Chon ket luan ung trong cac ket luan sau: A. Co 5 chat tham gia trang gng va 5 chat tac dung c vi Cu(OH)2 nhiet o thng. B. Co 4 chat tham gia trang gng va 5 chat tac dung c vi Cu(OH)2 nhiet o thng. C. Co 5 chat tham gia trang gng va 6 chat tac dung c vi Cu(OH)2 nhiet o thng. D. Co 4 chat tham gia trang gng va 4 chat tac dung c vi Cu(OH)2 nhiet o thng. Cau 8: Axit A co cong thc n gian ( C4H3O2)n, khong lam mat mau nc brom. So cong thc cau tao cua A trong trng hp nay la A. 1. B. 2. C. 3. D. 4. Cau 9: Cho cac nguyen t nguyen to sau: X ( Z = 17), Y ( Z = 11), R ( Z = 19), T ( Z = 9), U ( Z = 13), V ( Z = 16) va cac ket luan: (1) Tnh kim loai: U < Y < R. (2) o am ien: V < X < T.
0 0 0 0

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(3) Ban knh nguyen t: U < X < T. (4) Hp chat tao bi X va R la hp chat cong hoa tr. (5) Tnh chat hoa hoc c ban X giong T va Y giong R. (6) Hp chat tao bi Y va T la hp chat ion. So ket luan ung la A. 2. B. 5. C. 4. D. 3. Cau 10: Hoa tan hoan toan 7,68 gam bot Cu vao dung dch cha 0,48 mol HNO3, khuay eu thu c V lt hon hp NO2, NO (ktc) va dung dch X cha hai chat tan. Cho tiep 200 ml dung dch NaOH 2M vao dung dch X, loc bo ket tua, co can phan dung dch roi nung en khoi lng khong oi thu c 25,28 gam chat chat ran. Cac phan ng xay ra hoan toan. Gia tr cua V la A. 5,376. B. 1,792. C. 2,688. D. 3,584. Cau 11: Thuy phan hoan hon hp X gom hai este hai chc, mach h co cung cong thc phan t C4H6O4 can va ung 100 ml dung dch NaOH 1M, roi co can thu c 6,76 gam hon hp muoi va a gam hon hp ancol. Oxi hoa toan bo lng ancol sinh ra bang CuO roi cho toan bo san pham tao thanh tac dung vi mot lng d dung dch AgNO3/NH3 thu c m gam ket tua. Cac phan ng xay ra hoan toan. Gia tr cua m la A. 34,56. B. 43,20. C. 51,84. D. 30,24. Cau 12: Tien hai th nghiem sau vi hai hirocacbon ong phan A, B the kh trong ieu kien thng: dungd chBr2 dungd chBr2 dungd chNaOH,t 0 dungd chNaOH,t 0 A A1 A2. B B1 B2. Biet A2 hoa tan c Cu(OH)2 tao ra dung dch xanh lam trong suot, con B2 th khong co kha nang nay. Chon ket luan ung trong cac ket luan sau: A. Dung dung dch AgNO3/NH3 phan biet c A va B ng trong hai lo mat nhan. B. A va B cung co 8 lien ket xch ma trong phan t. C. A co 8 lien ket xch ma trong phan t, con B co 9 lien ket xch ma trong phan t. D. Cho A va B tac dung vi HBr thu c mot san pham duy nhat. Cau 13: Hoa tan hon hp X gom Al va Na c tron theo t le mol 1: 2 vao nc thu c dung dch Y va 2,24 lt H2 ( ktc). Cho V ml dung dch HCl 1M vao dung dch Y, khuay eu thu c 2,34 gam ket tua. Cac phan ng xay ra hoan toan. Gia tr cua V la A. 30 hoac 70. B. 70 hoac 110. C. 70 hoac 80. D. 80 hoac 110. Cau 14: Ket luan nao sau ay khong ung? A. Phan ng cua phenol vi dung dch Br2 tao ket tua mau trang, chng minh nhom OH anh hng len vong benzen. B. Phan ng cua glucoz vi dung dch AgNO3/NH3 tao ra ket tua Ag, chng minh glucoz la chat oxi hoa. C. Phan ng cua benzen vi Cl2, bot Fe, chng minh tnh chat hirocacbon no cua benzen. D. Phan ng cua natri phenolat vi kh CO2, phenol tach ra lam dung dch van uc, chng minh phenol co tnh axit yeu. Cau 15: ot chay hoan toan a mol chat beo A thu c b mol CO2 va c mol H2O. Biet b c = 5a, va hiro hoa hoan toan m gam A can va ung 2,688 lt H2 ( ktc) thu c 35,6 gam san pham B. Mat khac thuy phan hoan toan m gam A trung tnh bang mot lng dung dch NaOH va u, roi co can thu c x gam xa phong. Gia tr cua x la A. 36,48. B. 12,16. C. 36,24. D. 12,08. Cau 16: Cho cac phat bieu sau: (1) Cho xenluloz vao ong nghiem cha nc Svayde, khuay eu thay xenluloz tan ra. (2) T visco, t axetat la t tong hp. (3) Toluen va etylbenzen co cung nhiet o nong chay. (4) Trong cong nghiep, axeton va phenol c ieu che t cumen. (5) T nitron ( hay olon) c dung e det vai may quan ao am hoac ben thanh si len an ao ret. (6) Cac hp chat hu c thng co nhiet o nong chay, nhiet o soi cao ( kho bay hi). (7) Trong phan ng trang gng glucoz ong vai tro chat oxi hoa. (8) Hiro hoa hoan toan xiclobutan va buta-1,3-ien thu c mot hirocacbon duy nhat. So phat bieu ung la A. 7. B. 6. C. 5. D. 4.

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Cau 17: Hoa tan 14,24 gam hon hp X gom Fe2(SO4)3, CuSO4 va FeSO4 vao nc thu c dung dch Y. Biet trong hon hp X lu huynh chiem 22,47% ve khoi lng. Cho dung dch Y tac dung vi mot lng dung dch Ba(OH)2 va u thu c m gam ket tua. Cac phan ng xay ra hoan toan. Gia tr cua m la A. 31,34. B. 29,20. C. 15,95. D. 35,10. Cau 18: Tien hanh cac th nghiem sau: (1) Suc CO2 t t cho en d vao dung dch hon hp NaOH va Ba(OH)2. (2) Nho dung dch NH3 t t cho en d vao dung dch AlCl3. (3) Suc etilen t t vao dung dch KMnO4. (4) Nho dung dch Ba(OH)2 t t cho en d vao dung dch K2Cr2O7. (5) Nho dung dch NH3 t t cho en d vao dung dch CuSO4. (6) Nho dung dch NaOH t t cho en d vao dung dch Cr2(SO4)3. (7) Suc CO2 t t cho en d vao dung dch Ba(AlO2)2. (8) Suc kh H2S vao dung dch FeCl2. So trng hp thu c ket tua khi ket thuc th nghiem la A. 6. B. 5. C. 4. D. 3. Cau 19: Chia m gam hon hp X gom hai ancol ong ang ke tiep ( MA < MB) thanh hai phan bang nhau. un phan mot vi H2SO4 ac 1400C en khi phan ng xay ra hoan toan thu c 5,28 gam hon hp Y gom ba ete co so mol bng nhau va 1,08 gam H2O. un phan hai vi H2SO4 ac 1700C, roi hap thu toan bo lng olefin sinh ra vao bnh ng 100 ml dung dch KMnO4 1M thay khoi lng bnh tang them 2,73 gam, ong thi nong o dung dch KMnO4 con lai trong bnh sau phan ng la 0,5M. Hieu suat phan ng tach nc tao olefin cua A va B lan lt la A. 50% va 75%. B. 75% va 50%. C. 40% va 60%. D. 60% va 40%. Cau 20: Chat kh X sinh t phan ng cua thuoc tm vi dung dch axit clohiric, chat kh Y sinh t phan ng oxi hoa hoan toan quang pyrit sat, chat kh Z sinh ra t phan ng nhiet phan amoni nitrit bao hoa, chat kh T sinh ra t phan ng nhiet phan kaliclorat xuc tac manganioxit. So chat kh va ong vai tro chat kh va ong vai tro chat oxi hoa khi tng tac vi cac chat khac la A. 1. B. 2. C. 3. D. 4. Cau 21: Hon hp X gom Mg va SiO2 c tron theo t le khoi lng 1:1 va a c nghien mn. Nung m gam hon hp trong ieu kien khong co khong kh thu c hon hp Y. Cho toan bo hon hp Y tac dung vi dung dch NaOH d, thu c 2,688 lt H2 (ktc). Cac phan ng xay ra hoan toan. Gia tr cua m la A. 5,04. B. 9,60. C. 14,40. D. 28,80. Cau 22: Cac hirocabon mach h X, Y, Z, R va T co cong thc phan t khong theo th t: C10H8, C5H12, C4H6, C3H4 va C4H10. Biet rang: X tac dung vi dung dch Br2 theo t le mol 1:1, 400C tao ra hai san pham ong phan. Y trang thai ran va thang hoa ngay nhiet o thng. Z tac dung vi dung dch AgNO3/NH3 tao ra ket tua mau vang nhat. R tac dung vi Cl2 ( askt) theo t le mol 1:1 tao ra mot dan xuat duy nhat. Cong thc phan t cua X, Y, Z, R va T theo th t la A. C4H6, C10H8, C3H4, C4H10, C5H12. B. C3H4, C10H8, C4H6, C4H10, C5H12. C. C4H6, C10H8, C3H4, C5H12, C4H10. D. C3H4, C10H8, C4H6, C5H12, C4H10. Cau 23: T mot loai nguyen lieu co cha 81% tinh bot c dung lam nguyen lieu san xuat ancol etylic. Neu dung 1 tan nguyen lieu tren co the ieu che c bao nhieu lt ancol etylic 500 ? Biet hieu suat cua qua trnh la 80% va khoi lng rieng cua ancol etylic nguyen chat la 0,8g/ml. A. 575. B. 460. C. 920. D. 1150. Cau 24: Tong so hat proton, ntron, electron trong hai nguyen t X va Y la 92, trong o tong so hat mang ien nhieu hn tong so hat khong mang ien la 28. So hat mang ien cua Y nhieu hn cua X la 8. V tr cua X va Y trong bang tuan hoan cac nguyen to hoa hoc la A. X nam o th 13, chu ky 3 nhom IA; Y nam o th 17 chu ky 3 nhom VIIA. B. X nam o th 13, chu ky 3 nhom IIIA; Y nam o th 17 chu ky 3 nhom VIIA. C. X nam o th 12, chu ky 3 nhom IIA; Y nam o th 17 chu ky 3 nhom VA. D. X nam o th 12, chu ky 3 nhom IIIA; Y nam o th 16 chu ky 3 nhom IVA. Cau 25: A la quang hematit cha 60% Fe2O3, B la quang manhetit co cha 69,6% Fe3O4. Tron x tan A vi y tan B thu c quang D va t 1 tan quang D co the ieu che c 0,5 tan gang co cha 4% cacbon. Moi lien he gia x va y la A. x: y = 2:1. B. x: y = 1:2. C. x: y = 5:2. D. x: y = 2:5.

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Cau 26: Cho cac tnh chat sau: the ran trong ieu kien thng (1), tan trong nc (2), phan ng vi Cu(OH)2 nhiet o thng (3), phan ng vi Cu(OH)2/NaOH un nong tao ra ket tua o gach (4), phan ng vi dung dch AgNO3/NH3 (5), phan ng vi H2 (6), phan ng vi nc brom (7), phan ng vi mau vi dung dch iot (8), phan ng thuy phan (9). Trong cac tnh chat nay, ngi ta thay glucoz co x tnh chat, fructoz co y tnh chat va saccaroz co z tnh chat. Gia tr cua x, y va z theo th t la A. x = 6, y = 5, z = 4. B. x = 6, y = 6, z = 5. C. x = 7, y = 6, z = 4. D. x = 7, y = 6, z = 5. Cau 27: Hon hp X gom etan va propan co t khoi hi oi vi H2 la 20,25. un X trong mot bnh kn khi co mat chat xuc tac thch hp e thc hien phan ng e hiro hoa ( tach loai mot phan t hiro). Sau phan ng thu c hon hp kh Y co t khoi hi oi vi H2 la 13,5. Biet rang san pham phan ng ch co olefin va hiro, etan va propan b e hiro hoa vi hieu suat nh nhau. Hieu suat phan ng e hiro hoa (tach H2) cua etan va propan la A. 75%. B. 80%. C. 60%. D. 50%. Cau 28: Ket luan nao sau ay khong ung? A. Khi un nong khong co khong kh phot pho o chuyen thanh hi, khi lam lanh th hi cua no nhng tu lai thanh phot pho trang. B. Khi un nong en 2500C trong ieu kien khong co khong kh, photpho trang chuyen dan thanh photpho o la dang ben hn. C. Trong ieu kien thch hp Si tac dung c vi tat ca cac chat: Ca, Mg, Fe, F2, Cl2, C, S, N2. D. Trong ieu kien thch hp C tac dung c vi tat ca cac chat: CO2, H2O, HNO3, H2SO4 ac nong, MgO, ZnO. Cau 29: Nhiet phan 31,6 gam KMnO4 thu c 29,04 gam hon hp ran A. Cho toan bo hon hp ran A tac dung vi mot lng d dung dch HCl ac, en khi phan ng xay ra hoan toan thu c V lt kh mau vang luc ( ktc). Gia tr cua V la A. 4,032. B. 6,272. C. 5,376. D. 7,616. Cau 30: Ket luan nao sau ung? A. Co 4 chat lam mat mau nc brom trong day cac chat: Glucoz, fructoz, trioein, cumen, toluen, benzen, buta ien. B. Co 4 chat tac dung c vi H2 trong day cac chat: Benzen, triolein, glucoz, saccaroz, xiclobutan, axit linoleic. C. Phan ng gia poliisopren vi HCl la phan ng phan cat mach polime. D. Phan ng gia axit axetic va ancol etylic e tao ra etylaxetat c goi la phan ng the. Cau 31: Thuy phan hoan toan 0,1 mol mot peptit X c cau tao bi glyxin va alanin bang dung dch NaOH roi co can thu c 57,6 gam chat ran. Biet so mol NaOH a dung gap oi so vi lng can thiet va khoi lng chat ran thu c sau phan ng tang hn so vi ban au la 30,2 gam. So cong thc cau tao cua X trong trng hp nay la A. 4. B. 6. C. 8. D. 10. Cau 32: Cho cac phat bieu sau: (1) Lu huynh ta phng (S) va lu huynh n ta (S), khac nhau ve cau tao tinh the va mot so tnh chat vat l. (2) Trong cong nghiep, N2 c ieu che t phan ng nhiet phan NH4NO2 bao hoa. (3) S an mon kim loai la s pha huy kim loai hoac hp kim do tac dung cua cac chat trong moi trng xung quanh. (4) Ozon co tnh oxi hoa yeu hn oxi. (5) Chat co mang tinh the phan t co nhiet o nong chay thap hn so vi chat co mang tinh the nguyen t. (6) Tnh chat hoa hoc cua hp kim hoan toan khac tnh chat hoa hoc cua cac n chat tham gia tao thanh hp kim. (7) Khi ot trong kh oxi, amoniac chay vi ngon la mau vang, tao ra kh nit va hi nc. (8) Phot pho o phat quang mau luc nhat trong bong toi nhiet o thng. So phat bieu ung la A. 4. B. 5. C. 6. D. 7. Cau 33: Cho 4,08 gam Mg tac dung vi dung dch hon hp Cu(NO3)2 va H2SO4, un nong, khuay eu en khi phan ng xay ra hoan toan, thu c dung dch A; 0,896 lt hon hp kh B ( ktc) gom hai kh khong mau, trong o co mot kh hoa nau ngoai khong kh va 1,76 gam hon hp hai kim loai co cung so mol. Biet t khoi hi cua B oi vi H2 la 8. Khoi lng muoi tao thanh trong dung dch A la A. 23,80. B. 39,16. C. 19,32. D. 21,44. Cau 34: Thc hien cac phan ng sau: Isopentan tac dung vi Cl2 (askt) theo t le mol 1:1 (1), isopren tac dung vi dung dch Br2 theo t le mol 1:1 400C (2), un 3-metylhexan-3-ol vi H2SO4

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ac 1700C (3), tach hai phan t hiro t phan t isopentan (4). Trng hp sinh ra cung so san pham la A. (1) va (2). B. (2) va (3). C. (1) va (3). D. (2), (3) va (4). Cau 35: Chia hon hp X gom phenol, axit acrylic va glixerol thanh hai phan. Phan mot co khoi lng 7 gam phan ng va u vi 2,94 gam Cu(OH)2 nhiet o thng. Phan co so mol la 0,16 mol lam mat mau va ung 80 ml dung dch Br2 2M. Cac phan ng xay ra hoan toan. Thanh phan phan tram khoi lng phenol trong hon hp X la A. 26,86%. B. 13,43%. C. 40,29%. D. 20,14%. Cau 36: Khao sat tnh chat hoa hoc cua Al va Cr qua cac phan ng sau: (1) Phan ng vi dung dch NaOH ac, nong. (2) Phan ng vi Cl2 nhiet o thng. (3) Phan ng vi dung dch HNO3 loang nguoi. (4) Phan ng vi dung dch AgNO3. (5) Phan ng vi H2O. (6) Phan ng vi dung dch H2SO4 ac nong. Trong cac tnh chat nay A. Al co 5 tnh chat va Cr co 5 tnh chat. B. Al co 4 tnh chat va Cr co 4 tnh chat. C. Al co 5 tnh chat va Cr co 3 tnh chat. D. Al co 4 tnh chat va Cr co 3 tnh chat. Cau 37: Hoa tan hoan toan m gam hon hp X gom Na2CO3 va NaHCO3 vao nc thu c dung dch A. Nho rat t t 100 ml dung dch hon hp HCl 0,4M va H2SO4 0,3M vao dung dch A, khuay eu thu c 0,896 lt CO2 (ktc) va dung dch B. Cho dung dch B tac dung vi mot lng d dung dch Ba(OH)2 thu c 18,81 gam ket tua. Cac phan ng xay ra hoan toan. Gia tr cua m la A. 9,72. B. 11,40. C. 9,28. D. 13,08. Cau 38: Nho dung dch NaOH t t vao dung dch hon hp X gom ZnCl2, CrCl2, CuCl2, FeCl3, SnCl2, AlCl3, MgCl2 cho en khi ket tua khong con thay oi na, loc thu c ket tua roi em nung en khoi lng khong oi thu c chat ran Y. Cho toan bo chat ran Y tac dung vi mot lng d kh CO, nung nong thu c chat ran Z. Cac phan ng xay ra hoan toan. Chat ran Z gom A. Cr, Cu, Fe, SnO2, MgO. B. Cr, Cu, Fe, Sn, MgO. C. Cr, Cu, Fe, MgO. D. Cu, Fe, Sn, MgO. Cau 39: Hon hp X gom mot axit no, n chc mach h A va mot axit n chc mach h co mot noi oi B c tron theo t le mol 1:1. Trung hoa hon hp X bang mot lng dung dch NaOH va u thu c dung dch Y. Co can dung dch Y roi ot chay toan bo lng muoi thu c 2,12 gam chat bot mau trang va hon hp Z gom CO2 va H2O. Biet khoi lng CO2 va H2O hn kem nhau 2,96 gam. Cong thc cau tao cua A va B lan lt la A. HCOOH va CH2=CHCOOH. B. HCOOH va CH2=C(CH3)COOH. C. CH3COOH va CH2=CHCOOH. D. CH3COOH va CH2=C(CH3)COOH. Cau 40: Ket luan nao sau ay ung? A. Co 4 kim loai co the ieu che bang phng phap ien phan dung dch muoi trong day cac kim loai: Na, Cu, Mg, Al, Ag, Pb, Ca, K. B. Co 4 chat lam mem c nc cng tam thi trong day cac chat: Na3PO4, HCl, K2SO4, Ca(OH)2, Na2CO3, BaCl2, NaCl, K2CO3. C. Co 4 kim loai co kieu mang tinh the lap phng tam khoi trong day cac kim loai: Na, K, Ba, Ca, Mg, Be, Sr. D. Co 4 dung dch cho pH > 7 trong day cac dung dch: Na2CO3, BaCl2, CH3COONa, KHCO3, AlCl3, NaNO3, NH4Cl. II. PHAN RIENG [ 10 cau] Th sinh ch c lam mot trong hai phan ( phan A hoac B) A. Theo chng trnh Chuan ( 10 cau, t cau 41 en cau 50) Cau 41: Cho cac mo ta sau: (1) Nho dung dch NaOH vao dung dch K2Cr2O7, thay dung dch chuyen t mau da cam sang vang ti. (2) Nho dung dch KOH t t vao dung dch Cr2(SO4)3, thay xuat hien ket tua, ket tua tang dan va tan i. (3) Nho dung dch hon hp Na2CO3 va NaHCO3 t t vao dung dch H2SO4, sau mot thi gian thay sui bot kh. (4) Cho bot Cr vao dung dch NaOH ac nong, khuay eu thay bot Cr tan ra. (5) Nho dung dch NH3 t t cho en d vao dung dch ZnCl2, thay xuat hien ket tua, ket tua tang dan va tan i. (6) Cho mot mieng P trang vao benzen, thay mieng P b tan ra. So mo ta ung la A. 2. B. 3. C. 4. D. 5.

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Cau 42: Phan tch ancol no, n chc, mach h D thu c ket qua: mC + mH = 4,5mO. Oxi hoa D bang CuO thu c san pham tham gia c phan ng trang gng. So cong thc cau tao cua D trong trng hp nay la A. 1. B. 2. C. 4. D. 3. Cau 43: Anehit mach h A tac dung vi H2 theo t le mol n A : n H 2 = 1:2 va trang gng theo t le mol n A : n Ag = 1:4. ot chay hoan toan m gam A can va ung V lt O2 ( ktc). Hap thu toan bo san pham chay vao dung dch nc voi trong d thu c a gam ket tua. Moi lien he gia m vi V va a la 11a 25V 11a 25V 11a 5V 11a 5V A. m B. m C. m D. m . . . . 25 28 25 28 25 8 25 8 Cau 44: Cho 6,48 gam hon hp X gom Mg va Fe tac dung vi 90 ml dung dch CuSO4 1M thu c chat ran Y va dung dch Z cha hai muoi. Hoa chat ran Y can toi thieu V ml dung dch HNO3 4M, thu c NO la san pham kh duy nhat. Them dung dch NaOH d vao dung dch Z. Loc lay ket tua em nung ngoai khong kh en khoi lng khong oi c 4,8 gam chat ran T. Cac phan ng xay ra hoan toan. Gia tr cua V la A. 200. B. 120. C. 100. D. 80. Cau 45: Xet cac he can bang sau trong mot bnh kn: (1) N2 (k) + 3H2 (k) 2NH3 (k), H1 < 0. (2) N2O4 (k) 2NO2 (k), H2 > 0. Chon ket luan ung trong cac ket luan sau: A. Tang ap suat can bang (1) chuyen dch theo chieu thuan va can bang (2) chuyen dch theo chieu nghch. B. Tang ap suat can bang (1) va can bang (2) cung khong b chuyen dch can bang. C. Tang nhiet o can bang (1) va can bang (2) cung khong b chuyen dch. D. Tang nhiet o can bang (1) chuyen dch theo chieu thuan va can bang (2) chuyen dch theo chieu nghch. Cau 46: e tac dung va u vi m gam hon hp X gom Cr va kim loai M co hoa tr khong oi can va ung 2,24 lt hon hp kh Y (ktc) gom O2 va Cl2 co t khoi hi oi vi H2 la 27,7 thu c 11,91 gam hon hp Z gom cac oxit va muoi clorua. Mat khac cho m gam hon hp X tac dung vi mot lng d dung dch HNO3 ac nguoi thu c 2,24 lt NO2 ( ktc) la san pham kh duy nhat. Cac phan ng xay ra hoan toan. Kim loai M la A. Zn. B. Mg. C. Cu. D. Ca. Cau 47: Chat kh X c dung e tay trang giay va bot giay, chat chong nam moc lng thc, thc pham, chat kh Y gay ra hien tng ma axit, chat kh Z trong y hoc dung e cha sau rang. X, Y va Z theo th t la A. SO2, NO2, CO2. B. SO2, NO2, O3. C. Cl2, SO2, O3. D. Cl2, NO2, CO. Cau 48: Cho cac ket luan sau ve polime: (1) Hau het cac polime the ran, khong bay hi, khong co nhiet o nong chay xac nh. (2) a so cac polime khong tan trong cac dung moi thong thng. (3) T nitron c ieu che t phan ng trung hp, t lapsan c ieu che t phan ng trung ngng. (4) PE, PVC, PPF, PVA va thuy tinh hu c c dung lam chat deo. (5) T visco, t xenluloz axetat la t tong hp. (6) Phan ng thuy phan tinh bot tao thanh -glucoz la phan ng phan cat mach polime. (7) Nha bakelit, cao su lu hoa co mach cacbon phan nhanh. (8) Cac polime tham gia phan ng trung ngng, trong phan t phai co lien ket boi hoac vong kem ben co the m ra. So ket luan ung la A. 6. B. 7. C. 5. D. 4. Cau 49: Hon hp X gom amin no, n chc, mach h A va O2 (lng O2 trong X gap 3 lan lng O2 can dung e ot chay hoan toan A). Bat tia la ien ot chay hoan toan hon hp X, thu c hon hp kh Y. Dan hon hp Y i qua bnh ng dung dch H2SO4 ac thu c hon hp kh Z co t khoi hi oi vi H2 la 17,1. Cong thc phan t cua A la A. CH5N. B. C2H7N. C. C3H9N. D. C4H11N. Cau 50: Hai hp chat hu c A va B lan lt co cong thc phan t C8H10O2 va C8H10O ( eu la dan xuat cua benzen),

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tach nc thu c san pham trung hp co the tao polime. A tac dung vi NaOH theo t le mol tng ng 1:1 va tac dung vi Na theo t le mol tng ng 1:2. B khong tac dung vi dung dch NaOH nhng tac dung vi Na. Chon ket luan ung trong cac ket luan sau: A. A co 6 cong thc cau tao, B co 2 cong thc cau tao. B. A co 6 cong thc cau tao, B co 3 cong thc cau tao. C. A co 5 cong thc cau tao, B co 2 cong thc cau tao. D. A co 5 cong thc cau tao, B co 3 cong thc cau tao. B. Theo chng trnh Nang cao ( 10 cau, t cau 51 en cau 60) Cau 51: Cho biet phan ng sau: H2O(k) + CO(k) H2(k) + CO2(k). 7000C hang so can bang Kc = 1,873. Nong o cac chat luc can bang nhiet o 7000C nh sau: [ H2] = [CO2] = 0,03M. Nong o cua H2O va CO ban au la A. 0,04. B. 0,03. C. 0,05. D. 0,06. Cau 52: Chia 0,16 mol hon hp X gom hai anehit n chc A va nh chc B (MA < MB) thanh hai phan bang nhau. Hiro hoa phan mot can va ung 3,584 lt H2 (ktc). Cho phan hai tac dung vi mot lng d dung dch AgNO3/NH3 thu c 25,92 gam Ag va 8,52 gam hon hp hai muoi amoni cua hai axit hu c. Cac phan ng xay ra hoan toan. Thanh phan phan tram khoi lng cua A trong hon hp X la A. 49,12%. B. 50,88%. C. 34,09%. D. 65,91%. Cau 53: Cac chat hu c mach h X, Y, Z, R va T co cong thc phan t khong theo th t: C2H6O2, C2H2O4, C2H2O2, C3H6 va C4H8. Biet rang: X hoa tan c a voi, Y tham gia c phan ng trang gng, Z hoa tan c Cu(OH)2 nhiet o thng tao ra dung dch xanh lam trong suot, hirat hoa R thu c ancol duy nhat. X, Y, Z, R va T theo th t la A. C2H2O4, C2H2O2, C2H6O2, C4H8, C3H6. B. C2H2O4, C2H2O2, C2H6O2, C3H6, C4H8. C. C2H2O2, C2H2O4, C2H6O2, C4H8, C3H6. D. C2H2O2, C2H2O4, C2H6O2, C3H6, C4H8. Cau 54: ien phan dung dch AgNO3 vi ien cc tr mot thi gian, thu c dung dch A cha hai chat tan co cung nong o mol/l ong thi thay khoi lng dung dch giam 9,28 gam so vi ban au. Cho tiep 2,8 gam bot Fe vao dung dch A, un nong, khuay eu thu c NO la san pham kh duy nhat, dung dch B va chat ran D. Cac phan ng xay ra hoan toan. Khoi lng muoi tao thanh trong dung dch B la A. 13,64 gam. B. 10,24 gam. C. 15,08 gam. D. 11,48 gam. Cau 55: Quang cromit dung e san xuat crom, quang apatit c dung e san xuat axit photphoric, phen crom-kali co mau xanh tm, c dung e thuoc da, lam chat cam mau trong nganh nhuom vai. Cong thc cua quang cromit, quang apatit va phen crom-kali theo th t la A. Fe2O3.Cr2O3, 3Ca3(PO4)2.CaF2, K2SO4.CrSO4.24H2O. B. FeO.Cr2O3, Ca3(PO4)2.3CaF2, K2SO4.Cr2(SO4)3.24H2O. C. FeO.Cr2O3, 3Ca3(PO4)2.CaF2, K2SO4.Cr2(SO4)3.24H2O. D. Fe2O3.Cr2O3, 3Ca3(PO4)2.CaF2, K2SO4.CrSO4.24H2O. Cau 56: Nhiet phan 50,4 gam amoni icromat nhiet o cao thu c 38,4 gam hon hp ran A. Hieu suat phan ng nhiet phan amoni icromat la A. 60%. B. 80%. C. 70%. D. 50%. Cau 57: Cho cac ket luan sau: (1) Hiro la nhien lieu sach ang c nghien cu s dung thay the mot so nguyen lieu khac gay o nhiem moi trng. (2) Seuxen, moocphin la loai gay nghien cho con ngi. (3) Dung nc a va nc a kho e bao quan thc pham (tht, ca,). (4) Clo va cac hp chat cua clo la nguyen nhan gay ra s suy giam tang ozon. (5) Dung bot lu huynh e x ly thuy ngan b ri ra khi nhiet ke b v. (6) CO2 la chat kh gay ra hieu ng nha knh. (7) NO2, SO2 gay ra hien tng ma axit. (8) Dung bot S e hap thu thuy ngan. (9) Dung nc voi d e x l s bo cac chat thai co cha cac ion: Zn2+, Cu2+, Pb2+, Hg2+,trong mot bai thc hanh. So phat bieu ung la A. 6. B. 9. C. 7. D. 8. Cau 58: Hon hp X gom mantoz va saccaroz c chia thanh hai phan bang nhau. Phan mot phan ng va u vi 4,9 gam Cu(OH)2. Thuy phan phan hai, trung hoa dung dch sau phan ng va bang phng phap thch hp, tach thu c m gam hon hp Y, toan bo hon hp Y lam mat

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mau va ung 160 ml dung dch Br2 1M. Cac phan ng xay ra hoan toan. Khoi lng hon hp X la A. 34,20. B. 68,40. C. 54,72. D. 109,44. Cau 59: Cao su lu hoa co cha 3,14% lu huynh. Gia thiet rang S a thay the cho H cau metylen trong mach cao su. So mat xch isopren co mot cau isunfua S S la A. 34. B. 36. C. 32. D. 30. Cau 60: ot chay mot amin, no n chc, mach h A trong mot bnh kn bang mot lng khong kh va u 136,50C va ap suat P1 . Sau khi phan ng xay ra hoan toan van gi nhiet o bnh khong thay oi va ap suat luc bay gi la P2. Biet 52P1 = 49P2. Biet khong kh gom co 20% O2 va 80% N2 theo the tch. Cong thc phan t cua A la A. CH5N. B. C2H7N. C. C3H9N. D. C4H11N. ...................................HET..................................

a nhau van dam ng roi cung en luc chia tay nhau, sau buoi hoc nay la Thay Tro chia tay nhau, thi gian con lai khong nhieu, phai co gang hoc tro a, nhng ngi than ang trong ch tui con o. Nhng chang ng sap ti se co nhieu kho khan, cuoc i thng khong nh chung ta ngh, phai co gang vt qua, roi ay hanh phuc se mm ci. Nam hoc nay, do tnh hnh sc khoe khong tot nen Thay khong lo cho tui con chu ao, Thay xin loi, a so tui con y thc hoc rat tot. Vao ai hoc phai co gang hoc e c ra trng, phai biet lo cho than mnh thang tram ngan quan giac th de nhng thang c long mnh th rat kho . Cho du cuoc song co khac nghiet nh the nao i chang na Thay van tin rang hoc tro cua Thay se vt qua tat ca. Co vap nga phai co gang ng day, khong c bo cuoc, mn bai v va hoi nhng ban hoc nam trc e biet c cach hoc tren o. Ngay mai nay dau khong con ben tui con, Thay van mong rang hoc tro cua Thay luon vng chai tren oi chan mnh trong cuoc song...

AP AN THI TH AI HOC MON HOA (14.06.2012)

1B 11D 21B 31B 41C 51C 2D 12C 22C 32A 42C 52A 3D 13B 23C 33C 43A 53A 4C 14B 24B 34B 44C 54D 5A 15A 25D 35A 45A 55C 6B 16C 26C 36C 46A 56A 7B 17A 27D 37A 47B 57B 8C 18C 28D 38C 48C 58B 9C 19A 29D 39D 49B 59D 10D 20C 30D 40B 50A 60A

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