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H Ni - 1996
Li ni u
TCVN 6178: 1996 hon ton tng ng vi ISO 6777: 1984 (E) TCVN 6178: 1996 do Tiu ban k thut nc tinh lc TCVN/TC/F9/SC1 thuc Ban k thut tiu chun TCVN/TC/F9 ung bin son, Tng cc Tiu chun - o lng - Cht lng ngh. B Khoa hc, Cng ngh v Mi trng ban hnh.
TCVN 6178:1996
1. Phm vi p dng Tiu chun ny quy nh phng php trc ph hp th phn t xc nh nitrit trong nc sinh hot, nc thi v nc th. 2. Lnh vc p dng 2.1 Khong xc nh Nng nit dng nitrit a (40 ml). 2.2 Gii hn pht hin Khi s dng cc cuvet c chiu di ng quang 40 mm v lng mu th 40 ml, gii hn pht hin c xc nh nm khong gia N = 0.001 n 0.002 mg/l. 2.3 nhy S dng 40 ml lng mu th v cuvet c chiu di ng quang 40 mm, cho hp thu vo khong 0.66 n v. S dng 40ml lng mu th v cuvet c chiu di ng quang 10mm, pN = 0,25 mg/l s cho hp thu vo khong 0,67 n v. 2.4 Cc cht gy nhiu Nu kim ca mu cao, c th gp mt vi cht loi nhiu (xem iu 9).
N N
= 0.062 mg/l s
Dng pipet thm 1.0 ml thuc th mu (4.3). Lc u v pha long vi nc ti vch. Lc v yn. pH trong giai on ny phi t 1.9 0.1. (xem iu 9). t nht 20 pht sau khi thm thuc th, o hp thu ca dung dch bc song c hp thu ln nht, khong 540 nm, trong cuvet c chiu di ng quang thch hp, s dng nc lm dung dch i chiu. Ch thch: - Bc sng c hp thu ln nht phi c kim tra khi phng php ny c s dng ln u v phi c s dng trong tt c cc ln xc nh tip theo. 7.3 iu chnh mu Nu mu ca mu th l mu c th lm nhiu vic o d hp thu, x l mu p nh m t trong iu 7.2, nhng thay thuc th mu (4.3) bng 1 ml dung dch axit octophotphoric (4.2). 7.4 Th mu trng Tin hnh th mu trng nh m t 7.2, nhng thay phn muth bng 40 ml 2 ml nc. 7.5 Chun b th chun Dng buret ly cc th tch ca dung dch nitrit chun (4.5) c a trong bng 1 vo dy chnh gm 9 bnh nh mc dung dch 50 ml. Pha long lng dung dch cha trong mi bnh trn vi nc cho th tch ca dung dch t ti 40 ml 2 ml v tin hnh nh m t trong 7.2, t on th 2 n cui, s dng cc cuvet c chiu di ng quang c quy nh trong bng 1. hp thu ca cc dung dch khc tr i hp thu ca bnh zezo v v th ca hp thu tng ng vi khi lng nitrit tnh theo nit, i vi tng chiu di ng quang. th phi tuyn tnh v phi i qua im gc to . 8. Biu th kt qu 8.1 Phng php tnh hp thu c hiu chnh, Ar, ca dung dch th c tnh theo cng thc:
T hp thu c hiu chnh Ar, xc nh trn th chun (7.5) i vi chiu di ng quang thch hp ca cuvet, hm lng nitrit tnh theo nit bng microgam trn lt c tnh theo cng thc:
mN V
Trong : MN l khi lng ca nit dng ni trit tng ng vi hp thu c iu chnh (Ar), tnh bng microgam; V l th tch ca phn mu th, tnh bng mililit. Kt qu c th c biu th bng nng khi lng nit
N 2
hoc ni trit
NO2
tnh bng
miligam trn lit, hoc tng nng cc cht cha ion ni trit c(NO ), tnh bng micromol trn lit. Cc h s chuyn i thch hp c a trong bng 2.
* c th s dng cuvet 50 mm Bng 2 pN mg/l PNO2mg/l pN=1 mg/l pNO2=1mg/l C(NO2-)= 1mol/l 1 0.304 0.014 3.29 1 0.046 C(NO2-) mol/l 71.4 21.7 1
Mg/l Dung dch chun Dung dch chun Dung dch chun Dung dch chun Nc thi sinh hot Nc bin Nc sng 0,20 0,30 0,000 0,040 0,40 1,60 1,01
ml 40 40 40 5 5
40 25
10 10
* Thng tin nhn c t kt qu trc nghim ca lin phng th nghim ca Anh c 5 thnh vin tham gia. ** Gi tr cao nht v thp nht t thc nghim ca lin phng th nghim. Tt c cc gi tr c 14 bc t do. 9. Cc trng hp c bit Nu mu th c tnh kim cao, pH khng t 1,9 0,1 sau khi x l phn mu th v pha long ti 40 ml, dung dch axit octophotphoric b sung (4.2) s c thm vo trc khi pha long, nh vy s t c pH quy nh. Tuy nhin, phng php s lm sai lch kim ca hidro cacbonat, t nht l 300 mg/l trong mt phn mu th l 40 ml ngoi sai lch vi pH c xc nh.
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Magi Kali Kali Natri Natri Hidro cacbonat Hidro Natri cacbonat Nitrat Kali Amoni Clorua Cadmi Clorua Km Axetat Mangan Clorua St (III) Clorua St (III) Clorua ng Axetat Nhm Sunfat Silicat Natri Ur _ Thiosunfat Natri Thiosunfat Natri Clo _ Clo _ Cloramin _ Cloramin _ Hidroxylamoni Natri polyphotphat (hexametaphotphat) Natri polyphotphat (hexametaphotphat)
* Khi lng cht c mt trong mu th. Khi lng cho l mt thnh phn hoc hp cht tr khi c ch r trong ngoc kp. ** nh hng ln nht c coi l khng nhiu l cc gi tr sau: 0,00 g 0,02 g; 1,00 g 0,08 g; 10,00 g 0,14 g (gii hn tin cy 95%).
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