N MN HC CNG NGH LC DU

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I. t vn
Mt thp chng ct c 24 a, lm vic p sut kh quyn
Thp chng ct:
Cng sut ca thp:

120 m3/h

S a:

24

Stripping :
- y 6 %
- GO 6%
- Kerosen 5 %
- Xng nng 5%
p sut ti nh thp : 1,5 atm
p sut gy ra ti mi a : 8mm Hg
V tr a np liu y thp
c m t nh Hnh1
Du th:
Bng 1 . c trng ca du th
T khi d= 0,840, Kw= 12,3
Phn chng Nhit
ct [%V]
3
5
10
15
20
25
30
35

[oC]
61
79
120
139
168
196
222
252

T khi tc Phn chng Nhit

thi
0.682
0.706
0.729
0.752
0.767
0.781
0.793
0.807

ct [%V]
40
45
50
55
60
65
70
75

Dng hi bay ln t du th(Va):

54%

Dng lng chy xung t du th:

46%

[oC]
272
296
322
349
375
401
427
461

T khi tc
thi
0.821
0.836
0.849
0.861
0.869
0.877
0.885
0.891

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 N MN HC CNG NGH LC DU
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Phn t lng trung bnh ca dng hi (Va):

153

Sn phm chng ct: Cn c vo ng TBP Hnh 3 ta c th chia du th thnh

6 phn on nh sau :
Phn on (P) kh:

1 % th tch

Phn on (P) xng nh:

12 % th tch

Phn on (P) xng nng:

16 % th tch

Phn on (P) kerosen:

6 % th tch

Phn on (P) Gas Oil:

16 % th tch

Phn on (P) cn kh quyn AR: 49 % th tch

P kh

Vng nh
thp

Xng nh
Nc

Vng xng
nng
Xng nng
Vng
kerosen
Kerosen
Vng Gas
Oil

Du th

Vng np
liu

Gas Oil

Vng y
thp

Hi nc

AR

Hnh 1. S thp chng ct kh quyn

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 N MN HC CNG NGH LC DU
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Nhng vn cn gii quyt :

1. Xc nh v tr a ly xng, kerosen, gas oil khi bit nhit ti a ly

xng, kerosen, gas oil ln lt tng ng l: 158 oC, 211 oC, v 251 oC.
2. Xy dng s iu khin v m t qu trnh iu khin thp chng ct

trong cu 1 thay i nhit vng ly sn phm m anh ch xc nh

tng ln 10 oC.
II. Gii quyt vn
1. Xc nh v tr a ly sn phm phn an xng nng

Phn t lng trung bnh ca cc phn on c xc nh bng Hnh 2

Hnh 2.Quan h gia phn t lng M , h s c trng Kw , nhit ti

hn TK , nhit si trung bnh phn t v nhit si trung bnh th
tch . nghing ng ASTM trc tung phn di [oC/%]

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T khi ca cc phn on c xc nh bng Hnh 3

Hnh 3.Cc ng c trng ca du th

(ng M c tm nh Hnh 2. ng flash c suy ra t ng TBP)

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 N MN HC CNG NGH LC DU
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C th ta c c bng s liu sau:

Bng 2: c trng cc phn on
(coi s o t khi bng s o khi lng ring)

Phn on

Th tch T khi

%V

(m3/h)

Khi
lng

Kh

1,2

0,667

(tn/h)
0,800

Xng nh

12
16
6
16
51
49
100

14,4
19,2
7,2
19,2
61,2
58,8
120

0,722
0,775
0,806
0,837
0,783
0,900
0,840

10,397
14,880
5,803
16,070
49,950
52,850
100,800

Xng nng
Kerosen
Gas Oil

AR
Du th

Phn

t S

lng M

Kmol/h

64

12,50

99
140
183
220
146
430
223

105,05
106,29
31,69
73,05
328,58
122,91
451,49

a. S vng ly sn phm Xng Nng

W3

V3

R3

W0 W1

R3

a ly
xng nng

S3

L3

W2

Thp
stripping

W3
W2

hi nc
S2

T2 = 211 oC
V2

R2

Wo

W1

R2

L3 = 19,2 m3/hXng nng

L2

Hnh 4: S dng vng xng nng

Stripping 5% so vi lng xng nng ly ra, Theo hnh 3.15 Tr63 [ 1] cn
42 kg hi nc stripping 1m3 xng nng .Vy lng hi nc cn dng
sripping l:
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 N MN HC CNG NGH LC DU
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W3 = 42.19,2 = 806,4 (Kg/h) = 44,8 (Kmol/h)

Ta c: V3 (tng lng hi cc phn on t xng nng tr ln) :
V3 = 1,2 + 14,4 +19,2 = 34,8 ( m3/h)
Khi lng ring ca dng V3:
0,800 + 10,397 + 14,880
= 0,749 (g/cm3)
34,8

S3 (dng hi stripping t dng lng L3) : S3 = L3 L3.

S3=

5.100
.19,2 = 1,01 (m3/h)
100.95

Ta coi rng: S3 c t khi bng t khi phn on xng nh : dS3 = 0,718 (g/cm3)
=> mS3 = 1,01.0,718.103 = 725,18 (Kg/h)
Ta c: mL3 = mL3 + mS3
19,2.0,775+1,01.0,718= (19,2+1,01). L3= 20,21. L3
=> L3 = R3 = 0,772 (g/cm3) mL3 = 15602 (kg/h)
Da vo cc s liu t vng ly Kerosen v nhng tnh ton bn trn ta c bng s
liu :

Bng 3: S liu lin quan ti vng ly xng nng

(Nhit T3 = 158 oC)
Dng

Nhit

T khi

Th tch Khi

lng Entanpy

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(oC)
Vo
V2(hi)
R2 (hi)
S2(hi)
R3 (lng)
Wo+W1+ W2
Ra
V3 (hi)
R2+ L2(lng)
R3 (hi)
Wo+W1+W2

(m3/h)

(kg/h)

Kcal/kg

31878
68360
294,5
R3
8345

185
180
184
88
691

5897430
12304800
54188
88R3
5766395

26065,2
74458
R3

156
120
155

4066171
8934960
155R3

8345

666

5557770

211
211
211
158
211

0.759
0.804
0.775
0.772

42.0

158
211
158

0.749
0.804
0.772

34.8

0.38

158

Kcal/h

Cn bng Entanpy cho bng s liu trn, ta c:

5897430+12304800+54188+88R3+5766395=4066171+8934960+155R3+5557770
R3 = 81551 Kg/h

Lu lng mol dng L3 = 106,29 (kmol/h)

Lu lng mol dng S 3 =
Phn t lng dng

L3 =

(bng 2)

1,01.0,718.1000
= 7,53 (kmol/h)
96.3
20,21.0,772.1000
= 137,1
106,29 + 7,53

Lu lng mol dng R3 = 81551/137,1 = 594,8 (kmol/h)

Tng s mol hi qua a ly xng nng l :
12,5+105,05 +106,29 + 594,8 +8345/18 = 1282,25 (Kmol/h)
S mol hi xng nng ti a ly xng nng :
R3+L3 = 594,8+106.29 = 701,1 (Kmol/h)
p sut hi ring phn : P3 =

701
. P3
1282,25

(1)

Gi x l v tr a ( tnh t trn xung ) ly sn phm xng nng

p sut ti a ly xng nng : P3 = 1,5 .760 + x.8

(2)

Theo bi ra nhit ly phn on xng nng l 158 oC , t ta v ng flash

ca xng nng vi T0 l 158 oC song song vi ng flash ca phn an xng
nng ti 1 atm ( nh hnh 5). Ta s xc nh c T50 ca ng flash ti 1 atm v
T50 ca ng flash ti 158oC . S dng hnh 6 ta s xc nh c p sut ring
phn ca xng nng ti 158oC l 644mmHg . P3 = 644mmHg (3)
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 N MN HC CNG NGH LC DU
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Hnh 5 . ng chng ct ca phn on xng nng

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 N MN HC CNG NGH LC DU
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Hnh 6 . Quan h T50 ng flash cc p sut di 760 mmHg

T (1) (2) (3) => x = 4,7
Vy v tr a ly xng nng l a s 5

TI LIU THAM KHO

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[1]. Ts. Phan T Bng, Gio trnh cng ngh lc du, nh xut bn xy dng
H Ni, 2002.
[2]. Ts. Phan T Bng, Gio trnh ha hc du m v kh t nhin, nh xut
bn giao thng vn ti H Ni, 1999.
[3]. S tay qu trnh v thit b cng ngh ha cht, tp 1, nh xut bn khoa
hc v k thut, H Ni, 2004.

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