Phn dng bi tp chng 3

Ha hc nng cao 12

CHNG III: AMIN-AMINOAXIT-PROTEIN

A- TNG HP L THUYT

Amin Amin l hp cht hu c coi nh c to nn khi thay th mt hay nhiu Khi nim nguyn t H trong phn t NH3 bng gc hidrocacbon TQ: RNH2( Bc 1) VD: CH3 NH2 CH3 NH CH3 CTPT CH3 N CH3 CH3 Tnh baz: Ha tnh CH3 NH2 +H2O [CH3NH3]+OH To mui HCl R NH2 + HCl [R NH3]+Cl Kim NaOH Ancol Br2/H2 Cu(OH)2 Trng ngng 1/ Ha tnh ca Amin: a)Tnh baz:
trng

Aminoaxit Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino -NH2 v nhm cacboxyl -COOH. TQ: H2N R COOH C6H5 NH2 ( anilin ) VD: H2N CH2 COOH (glyxin) CH3 C H COOH (alanin) khng tan NH2

Peptit v Protein Peptit l hp cht cha t 2 50 gc amino axit lin kt vi nhau bi cc lin kt peptit CO NH Protein l loi polipeptit cao phn t c PTK t vi chc nghn n vi triu.

Lng tnh p/ ha este p/ trng gng

p/ thy phn. p/ mu biure.

To mui [C6H5 NH3]+Cl -

To mui H2N - R- COOH + HCl ClH3N R COOH To mui H2N R COOH + NaOH

To mui hoc thy phn khi un nng

Thy phn khi un nng

H2N RCOONa + H2O

To este

To hp cht mu tm

v - aminoaxit tham d p/
trng ngng

R NH2 + H OH R NH3+ + OH +) Lc baz ca amin c nh gi bng hng s baz Kb hoc pKb :

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 [ RNH 3+ ][OH ] Kb = v pKb = -log Kb. [ RNH 2 ] +) Anilin khng tan trong nc, khng lm i mu qu tm. +) Tc dng vi axit: RNH2 + HCl RNH3Cl

Ha hc nng cao 12

+) Cc mui amoni tc dng d dng vi kim: RNH3Cl + NaOH RNH2 + NaCl + H2O. b) So snh tnh baz ca cc amin: Tnh baz ca amin ph thuc vo s linh ng ca cp electron t do trn nguyn t nit: +) Nhm y e s lm tng linh ng ca cp electron t do (n) trn nguyn t N nn tnh baz tng. +) Nhm ht e s lm gim s linh ng ca cp e t do trn nguyn t N nn tnh baz gim. +) Khi c s lin hp n - ( nhm chc amin gn vo cacbon mang ni ) th cp e t do trn nguyn t N cng km linh ng v tnh baz gim. c) Phn ng th gc thm: +) Halogen ha: Tng t phenol, anilin tc dng vi nc Br2 to thnh kt ta trng 2,4,6- tribrom anilin. d) Phn ng vi axit nitr:
+) iu ch HNO2 : NaNO2 + H+ Na+ + HNO2.

+) Phn ng ca amin vi HNO2: Amin bc 1 s c hin tng si bt kh: R-NH2 + HO NO R OH + N2 + H2O. Amin bc 2 s to hp cht nit z mu vng: Amin bc 3 khng phn ng. 2/ Ha tnh ca Aminoaxit: a) Tnh cht lng tnh: +) Phn ng vi axit mnh: HOOC- CH2NH2 + HCl HOOC CH2 NH3 +Cl +) Phn ng vi baz mnh: NH2- CH2- COOH + NaOH H2N CH2 COOONa + H2O +) Tnh axit- baz ca dung dch amino axit ( R(NH2)a(COOH)b )ph thuc vo a,b. - Vi dung dch glyxin: NH2- CH2- COOH +H3N- CH2 COODung dch c mi trng trung tnh( a = b = 1) nn qu tm khng i mu - Vi dung dch axit glutamic ( a = 1, b= 2)lm qu tm chuyn thnh mu - Vi dung dch Lysin ( a=2, b =1)lm qu tm chuyn thnh mu xanh. b) Phn ng este ho ca nhm -COOH
kh HCl H 2 N - CH 2 - COOH + C2 H5 OH H2 N - CH2 - COOC2 H5 + H2 O

R R N H + HO N = O N N = O + H2O. R' R'

c) Phn ng trng ngng Trn con ng thnh cng khng c du chn ca k li bing 2

Phn dng bi tp chng 3

Ha hc nng cao 12

- Cc axit-6-aminohexanoic v 7-aminoheptanoic c phn ng trng ngng khi un nng to ra polime thuc loi poliamit.
xt ,t , p n H NH [CH 2 ]5 CO OH ( NH [CH2 ]5 CO ) n + nH2 O
0

policaproamit (nilon 6) 3/ Ha tnh ca peptit v protein: a) Phn ng thy phn:

H ,t +) Vi peptit: H2N- C H-CO-NH- C H-COOH+H2O NH2 - C H-COOH + NH2- C H-COO | | | | hayenzim
+ o

R1 R2 R1 R2 +) Vi protein: Trong mi trng axit hoc ba z, protein b thy phn thnh cc aminoaxit. b) Phn ng mu biure Tc dng vi Cu(OH)2 cho hp cht phc mu tm . a s cc aminoaxit trong thin nhin l -aminoaxit. Sau y l s liu lin quan n 15 aminoaxit thng gp trong cu trc ca protein:

CNG THC

TN GI

VIT TT

TAN

pHI

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 A. Axit monoaminomonocacboxylic 1/ C H2 COOH | NH2 2/ CH3 C H - COOH | NH2 3/ CH3 C H C H COOH | | CH3 NH2 4/ CH3 C H CH2 C H COOH | | CH3 NH2 Valin M= 117 Leuxin M= 131 Iso leuxin M= 131 Ile Lysin M= 146 Lys Leu Val Glyxin M= 75 Alanin M= 89 Ala Gly

Ha hc nng cao 12

25,5

5,97

16,6

6,00

6,8

5,96

2,4

5,98

5/ CH3 CH2 C H C H COOH | | CH3 NH2 B. Axit iaminomonocacboxylic 6/ C H2 CH2 CH2 CH2 C H COOH | | NH2 NH2

2,1

6,00

Tt

9,74

C. Axit monoaminoicacboxylic 7/ HOOC CH2 C H COOH | NH2 8/ HOOC CH2 CH2 C H COOH | NH2 9/ H2N C CH2 C H COOH || | O NH2 Asparagin M= 132 Glutamin M= 146 Asn 2,5 5,4 Glu 0,7 3,22 Axit aspactic M= 133 Axit glutamic M= 147 Asp 0,5 2,77

10/ H2N C CH2 CH2 C H COOH || | O NH2

D. Aminoaxit cha nhm OH , -SH, -SR 11/ HO CH2 C H - COOH | NH2 12/ CH3 C H C H COOH | | OH NH2

Serin M= 105 Gln 3,6 5,7

Threonin M= 119 Ser 4,3 5,68 4

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 13/ HS CH2 C H COOH | NH2 14/ CH3S CH2 CH2 C H COOH | NH2 E. Aminoaxit cha vng thm 15/ C6H5 CH2 C H COOH | NH2 Phenylalanin M= 165 Met Xistein M= 121 Thr

Ha hc nng cao 12

20,5

5,60

Methionin M= 149 Cys Tt 5,10

3,3

5,74

Phe

2,7

5,48

B- CC DNG BI TP V PHNG PHP GII

Dng 1: Gii ton amin tc dng vi axit hoc vi brom 1. Phn ng vi dung dch axit Vi amin A, c a nhm chc, gi s amin bc I R ( NH 2 ) a + aHCl R ( NH3 Cl )a nHCl nX v mmui = mamin + mHCl

S chc amin a = 2. Vi brom

C6H5NH2 + 3Br2 C6H2Br3NH2 + 3HBr

Cu 1.

Cho 0,4 mol 1 amin no, n chc tc dng vi dd HCl va thu c 32,6 gam mui. CTPT ca amin l B. C2H5NH2 C. C3H7NH2 D. C4H9NH2

A. CH3NH2
Cu 2.

Cho 10 gam amin n chc X phn ng hon ton vi HCl d thu c 15 gam mui. S ng phn cu to ca X l B. 7 C. 5 D. 4

A. 8
Cu 3.

trung ha 25 gam dung dch ca mt amin no, n chc X nng 12,4% cn dng 100ml dung dch HCl 1M. CTPT ca X l B. C2H7N C. CH5N D. C3H7N

A. C3H5N

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Cu 4.

Ha hc nng cao 12

Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho anilin tc dng vi NaNO2 trong dung dch HCl nhit thp (0-50C). iu ch c 14,05 gam C6H5N2+Cl- (vi hiu sut 100%) th lng anilin v natri nitrit cn dng va l C. 0,1 mol v 0,1 mol D. 0,1 mol v 0,3 mol

A. 0,1 mol v 0,4 mol B. 0,1 mol v 0,2 mol

Cu 5.

Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl d, thu c 3,925 gam hn hp mui. CT ca 2 amin trong hn hp X l B. C2H5NH2 v C3H7NH2 D. CH3NH2 v (CH3)3N

A. CH3NH2 v C2H5NH2 C. C3H7NH2 v C4H9NH2

Cu 6.

Trung ha hon ton 8,88 gam mt amin (bc I, mch C khng phn nhnh) bng dung dch HCl, to ra 17,64 gam mui. Amin c CT l B. CH3[CH2]2NH2 C. H2NCH2CH2NH2 D. H2N[CH2]3NH2

A. H2N[CH2]4NH2
Cu 7.

Cho 0,1 mol anilin tc dng va vi dung dch HCl. Khi lng mui thu c l B. 6,475g C. 19,425g D. 12,95g

A. 25,9g
Cu 8.

Th tch dung dch brom 5% (d=1,3g/ml) cn dng iu ch 3,96 gam kt ta 2,4,6B. 49,23 ml C. 88,61 ml D. 42,3 ml

tribrom anilin l A. 164,1 ml

Cu 9.

Cho 0,76 gam hn hp 2 amin n chc dy ng ng lin tip tc dng va vi dung dch HNO3 th thu c 2,02 gam hn hp mui khan. Hai amin l: B. metyl amin v etyl amin D. anilin v metyl amin

A. etyl amin v propyl amin C. anilin v benzyl amin

Cu 10.

Trung ha han tan 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l B. CH3CH2CH2NH2.

A. H2NCH2CH2CH2CH2NH2. C. H2NCH2CH2NH2
Cu 11.

D. H2NCH2CH2CH2NH2.

Cho 2,1 gam hn hp X gm 2 amin no, n chc, k tip nhau trong dy ng ng phn ng ht vi dung dch HCl (d), thu c 3,925 gam hn hp mui. Cng thc ca 2 amin trong hn hp X l B. CH3NH2 v C2H5NH2. D. C3H7NH2 v C4H9NH2.

A. C2H5NH2 v C3H7NH2. C. CH3NH2 v (CH3)3N.

Cu 12.

Mui C6H5N2+Cl- (phenyliazoni clorua) c sinh ra khi cho C6H5-NH2 (anilin) tc dng vi NaNO2 trong dung dch HCl nhit thp (0-5oC). iu ch c 14,05 gam C6H5N2+Cl(vi hiu sut 100%), lng C6H5-NH2 v NaNO2 cn dng va l: B. 0,1 mol v 0,2 mol. D. 0,1 mol v 0,3 mol.

A. 0,1 mol v 0,4 mol. C. 0,1 mol v 0,1 mol.

Cu 13.

(H A- 10) t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6g X tc dng vi dung dch HCl (d), s mol HCl phn ng l 6

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 A. 0,1

Cu 14.

Ha hc nng cao 12 C. 0,3 D. 0,2

B. 0,4

Cho 20 gam hn hp 3 amin no n chc l ng ng k tip c t l mol tng ng l 1: 10 : 5, tc dng va vi dungdch HCl thu c 31,68 gam hn hp mui. Tng s ng phn ca 3 amin trn l B. 14 C. 28 D. 16

A. 7 Cu 15. cacbon.

X l amin no n chc mch h v Y l amin no 2 ln amin mch h.c cng s

Trung ha hn hp gm a mol X v b mol Y cn dung dch cha 0,5 mol HCl v to ra 43,15 gam hn hp mui. Trung ha hn hp gm b mol X v a mol Y cn dung dch cha 0,4 mol HCl v to ra p gam hn hp mui. p c gi tr l : A. 40,9 gam B. 38 gam C. 48,95 gam D. 32,525 gam

Dng 2: Amin tc dng vi dung dch mui (tng t amoniac)

Mt s mui d to kt ta hiroxit vi dung dch amin

Vd: AlCl3 + 3CH3NH2 + 3H2O Al(OH)3 + 3CH3NH3Cl

Tng t NH3, cc amin cng to phc cht tan vi Cu(OH)2, Zn(OH)2, AgCl

Vd: Cu(OH)2 + 4CH3NH2 [Cu(CH3NH2)4](OH)2

Cu 1.

Cho 9,3 gam 1 amin no, n chc bc I tc dng vi dung dch FeCl3 d thu c 10,7 gam kt ta. CTPT ca amin l B. C2H5NH2 C. C3H7NH2 D. C4H9NH2

A. CH3NH2
Cu 2.

Cho 17,4 gam hn hp 2 amin n chc bc I c t khi so vi khng kh l 2, tc dng vi dung dch FeCl3 d thu c kt ta, em nung kt ta n khi lng khng i thu c m gam cht rn. Gi tr ca m l B. 10,7g C. 24,0g D. 8,0g

A. 16g
Cu 3.

Cho hn hp 2 amin n chc bc I c t khi hi so vi hiro l 19 (bit c 1 amin c s mol l 0,15) tc dng vi dung dch FeCl3 d thu c kt ta A. em nung A n khi lng khng i thu c 8g cht rn. CT ca 2 amin l B. CH3NH2 v C2H3NH2 D. CH3NH2 v CH3NHCH3

A. CH3NH2 v C2H5NH2 C. C2H5NH2 v C2H3NH2

Cu 4.

Hn hp X gm 2 mui AlCl3 v CuCl2. Ha tan hon ton hn hp X vo nc thu c 200ml dung dch A. Sc kh metyl amin ti d vo dung dch A thu c 11,7 gam kt ta. Mt khc, cho t t dung dch NaOH ti d vo dung dch A thu c 9,8 gam kt ta. Nng mol/l ca AlCl3 v CuCl2 trong dung dch A ln lt l B. 0,5M v 0,75M C. 0,75M v 0,5M D. 0,75M v 0,1M

A. 0,1M v 0,75M
Cu 5.

Cho 1 dd cha 6,75g mt amin no n chc bc I tc dng vi dd AlCl 3 d thu c 3,9g kt ta. Amin c cng thc l 7

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 A. CH3NH2.

Cu 6.

Ha hc nng cao 12 C. C2H5NH2. D. C3H7NH2

B. (CH3)2NH.

Cho 17,4 gam hn hp gm 2 amin n chc bc 1 c t khi so vi khng kh l 2 , tc dng vi dung dch FeCl3 (c d) thu c mt kt ta A.em nung A n khi lng khng i thu c m gam cht rn. Gi tr ca m l: B. 10,7 gam C. 24 gam D. 8 gam

A. 16 gam
Cu 7.

Hn hp X gm hai mui AlCl3 v CuCl2. Ho tan hn hp X vo nc thu c 200 ml dd A. Sc kh metyl amin ti d vo dd A thu c 11,7 gam kt ta. Mt khc cho t t dd NaOH ti d vo dd A thu c 9,8 gam kt ta. Nng mol/l ca AlCl3 v CuCl2 trong dd A ln lt l: B. 0,5M v 0,75M C. 0,75M v 0,5M D. 0,75M v 0,1M

A. 0,1M v 0,75M
Cu 8.

Cho hn hp gm 2 amin n chc bc 1 c t khi so vi H2 l 19 ( bit 1 amin c s mol bng 0,15) tc dng vi dung dch FeCl3 (c d) thu c mt kt ta A.em nung A n khi lng khng i thu c 8 gam cht rn. Cng thc phn t ca 2 amin trn l: B. C2H5NH2 v C3H7NH2 D. CH3NH2 v CH3NHCH3

A. CH3NH2 v C2H5NH2 C. C3H7NH2 v C4H9NH2

Cu 9.

Cho 7,3 gam mt ankylamin tc dng vi dung dch FeCl3 (d), thu c 10,7 gam kt ta. Cng thc ca ankylamin l: B. C2H5NH2. C. CH3NH2. D. C3H7NH2.

A. C4H9NH2.
Cu 10.

Khi cho amin X n chc vo dung dch cha hn hp NaNO2 v HCl thy c kh thot ra. Mt khc khi cho X tc dng vi dung dch FeCl 2 d thu c khi lng kt ta ng bng khi lng X tham gia phn ng. X l: B. etylamin C. butylamin D. propylamin

A. metylamin
Cu 11.

Cho m gam hn hp hai amin n chc bc I c t khi hi so vi hiro l 30 tc dng vi FeCl2 d thu c kt ta X. ly kt ta nung trong khng kh n khi lng khng i c 18,0 gam cht rn. Vy gi tr ca m l B. 15,0 gam C. 13,5 gam D. 27,0 gam

A. 30,0 gam
Cu 12.

Cho 17,4 gam hn hp 2 amin n chc bc I c t khi so vi khng kh bng 2. Tc dng vi dung dch FeCl3 d thu c kt ta, em nung kt ta n khi lng khng i c m gam cht rn. Gi tr ca m l B. 10,7 gam C. 24,0 gam D. 8,0 gam

A. 16,0 gam

Dng 3: Gii ton t chy amin

Amin no, n chc

Cn H 2 n + 3 N +

6n + 3 2n + 3 1 O2 nCO2 + H2 O + N2 4 2 2

Amin thm

Cn H 2 n 5 N + Amin C x H y Nt +

6n 5 2n 5 1 O2 nCO2 + H2 O + N2 4 2 2

(x +

y y t O2 ) xCO2 + H2 O + N2 4 2 2 8

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Amin n chc

Ha hc nng cao 12

Cx H y N +

(x +

y y 1 O2 ) xCO2 + H 2 O + N2 4 2 2 1 n H O (bao ton nguyn to) 2 2

Lu : - Khi t chy 1 amin ta lun c: n O2 pu = n CO2 +

-

Khi t chy 1 amin ngoi khng kh th nN2 sau pu = nN2 tren pt + nN2 trong kh ng khi t chy hon ton amin no, n chc, bc I, mch h thu c t l mol CO2 v H2O l 4:7. Tn gi ca amin l B. imetyl amin C. Etyl metyl amin D. Propyl amin

Cu 1.

A. Etyl amin
Cu 2.

t chy hon ton a mol amin no, n chc thu c 13,2 gam CO2 v 8,1 gam H2O. B. 0,1 C. 0,07 D. 0,2

Gi tr ca a l A. 0,05
Cu 3.

t chy hon ton cc amin no, n chc vi t l mol CO2 v H2O nm trong khong no sau y B. 0,4T1 C. 0,4T<1 D. 0,5T0,1

A. 0,5T<1
Cu 4.

t chy hon ton 1 ng ng X ca anilin th t l nCO2 : nH 2O = 1, 4545 . CTPT ca B. C8H9NH2 C. C9H11NH2 D. C10H13NH2

X l A. C7H7NH2
Cu 5.

t chy hon ton m(g) hn hp gm 3 amin thu c 3,36 lt CO2 (ktc), 5,4 gam H2O v 1,12 lt N2 (ktc). Gi tr ca m l B. 3,8 C. 4 D. 3,1

A. 3,6
Cu 6.

Khi t chy hon ton 1 amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. CTPT ca X l B. C2H7N C. C3H9N D. C4H9N

A. C3H7N
Cu 7.

t chy hon ton 0,1 mol mt amin no, mch h bng oxi va thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl d, s mol HCl phn ng l B. 0,4 C. 0,3 D. 0,2

A. 0,1
Cu 8.

t chy amin A vi khng kh va , sau phn ng thu c 17,6 gam CO2, 12,6 gam H2O v 69,46 lt N2 (ktc). Khi lng ca amin l B. 9g C. 11g D. 9,5g

A. 9,2 g
Cu 9.

t chy hon ton V lt hi 1 amin X bng mt lng oxi va to ra 8V lt hn hp gm kh CO2, khi N2, hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitro nhit thng gii phng kh nit. Cht X l C. CH3-CH2-CH2-NH2 D. CH2=CH-CH2-NH2

A. CH2=CH-NH-CH3 B. CH3-CH2-NH-CH3
Cu 10.

t chy hon ton V lt hi mt amin X bng mt lng oxi va to ra 8V lt hn hp gm kh cacbonic, kh nit v hi nc (cc th tch kh v hi u o cng iu kin). Amin X tc dng vi axit nitr nhit thng, gii phng kh nit. Cht X l C. CH3-CH2-CH2-NH2. D. CH2=CH-CH2-NH2. 9

A. CH2=CH-NH-CH3. B. CH3-CH2-NH-CH3.

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Cu 11.

Ha hc nng cao 12

Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 550 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 250 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l B. C3H6 v C4H8 C. CH4 v C2H6 D. C2H4 v C3H6

A. C2H6 v C3H8
Cu 12.

Hn hp kh X gm trimetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 750 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 350 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l B. C2H4 v C3H6 C. C3H6 v C4H8 D. C2H6 v C3H8

A. C3H8 v C4H10
Cu 13.

Hn hp kh X gm imetylamin v hai hirocacbon ng ng lin tip. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 480 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 180 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hai hirocacbon l B. C2H4 v C3H6. C. C2H6 v C3H8. D. C3H6 v C4H8.

A. CH4 v C2H6.
Cu 14.

Hn hp Q gm hai amin X v Y. Hp cht X c cng thc phn t CH5N, cng thc phn t ca Y hn X mt s nhm CH2 v t l mol ca X v Y tng ng l 5:1. t chy ht 4,28 gam hn hp Q th thu c 0,16 mol CO2. Cho bit Y c bao nhiu cng thc cu to? B. 4. C. 6. D. 8.

A. 2.
Cu 15.

Chia 42,8 gam mt hn hp M gm 2 amin no X, Y n chc ng ng k tip lm 2 phn bng nhau. Phn 1: tc dng va vi 0,3 lt dung dch H2SO4 1 M. Phn 2: t chy hon ton trong oxi to ra V lt N2 ( ktc). Xc nh cng thc phn t, s mol mi amin v V

A. 0,8 mol C2H5-NH2, 0,4 mol C3H7- NH2, 11,2 lt N2 B. 0,6 mol C2H5-NH2, 0,3 mol C3H7-NH2, 8,96 lt N2 C. 0,4 mol CH3-NH2, 0,2 mol C2H5-NH2, 3,36 lt N2 D. 0,8 mol CH3-NH2, 0,4 mol C2H5-NH2, 6,72 lt N2
Cu 16.

t chy hon ton 5,4g mt amin X n chc trong lng va khng kh. Dn sn phm kh qua bnh ng nc vi trong d thu c 24g kt ta v c 41,664 lt (ktc) mt cht kh duy nht thot ra. X tc dng vi HNO2 to ra kh N2. X l: B. metylamin C. anilin D. Etylamin

A. imetylamin
Cu 17.

Mt hn hp X gm 2 amin no A, B c cng s nguyn t C. Phn t B c nhiu hn A mt nguyn t N. Ly 13,44 lt hn hp X ( 273 oC, 1atm) em t chy hon ton thu c 26,4 gam CO2 v 4,48 lit N2 (ktc). Bit rng c hai u l amin bc 1. CTCT ca A v B v s mol ca chng l:

A. 0,2 mol CH3NH2 v 0,1 mol NH2CH2NH2. B. 0,2 mol CH3CH2NH2 v 0,1 mol NH2CH2CH2NH2. C. 0,1 mol CH3CH2NH2 v 0,2 mol NH2CH2CH2NH2. D. 0,2 mol CH3CH2NH2 v 0,1 mol NH2CH2NHCH3.
Cu 18.

t chy hon ton 1,37g mt amin thm A thu c 3,08g CO2, 0,99g H2O v 336 ml N2 ktc. Mt khc 0,1 mol A tc dng va 300 ml dd HCl 1M. Bit A c iu ch t toluen. Tn gi ca A l: 10

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 A. Phenyl amin

Cu 19.

Ha hc nng cao 12 C. o-amino toluen D. 2,4,6-triamino toluen

B. Benzyl amin

Hn hp kh X gm 2 amin no, n chc , mch h , thuc cng dy ng ng v mt anken. t chy hon ton m gam hn hp X thu c 1,65 mol CO 2 , 2,775 mol H2O v V lt N2 (ktc). Gi tr ca V l : B. 8,4 C. 3,36 D. 5,6

A. 2,8
Cu 20.

Khi t chy hon ton mt amin n chc X, thu c 8,4 lt kh CO2, 1,4 lt kh N2 (cc th tch kh o ktc) v 10,125 gam H2O. Cng thc phn t ca X l (cho H = 1, O = 16) B. C2H7N. C. C3H9N. D. C4H9N

A. C3H7N.
Cu 21.

t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va thu c 0,5 mol hn hp Y gm kh v hi. Cho 4,6g X tc dng vi dung dch HCl (d), s mol HCl phn ng l B. 0,4 C. 0,3 D. 0,2

A. 0,1
Cu 22.

Hn hp X gm amoniac v amin Y no, n chc, mch h c t l mol 1:1. t chy hon ton V lit X bng oxi (khng c xc tc) thu c CO2 , H2O v 0,1 mol N2 trong khi lng CO2 v H2O chnh lch nhau 0,2 gam. S CTCT tho mn Y

l: A. 2
Cu 23.

B. 1

C. 3

D. 4

Mt hn hp A gm CH4, C2H4, C3H4 v CH3NH2. t chy hon ton A bng 1 lng oxi va . Cho ton b sn phm qua bnh 1 ng P2O5 (d), bnh 2 ng dung dch Ca(OH)2 nhn thy khi lng bnh 1 tng 16,2 gam; bnh 2 xut hin 40 gam kt ta. Lc b kt ta ri un k dung dch bnh 2 thy xut hin thm 7,5 gam kt ta na. Th tch kh oxi ( ktc) tham gia phn ng l: B. 15,68 lt. C. 22,40 lt. D. 11,20 lt.

A. 44,8 lt.
Cu 24.

Hn hp kh X gm imetylamin v mt hirocacbon. t chy hon ton 100 ml hn hp X bng mt lng oxi va , thu c 750 ml hn hp Y gm kh v hi nc. Nu cho Y i qua dung dch axit sunfuric c (d) th cn li 360 ml kh (cc th tch kh v hi o cng iu kin). Cng thc phn t ca hirocacbon l B. C3H8 C. C4H8. D. C4H4

A. C2H4.
Cu 25.

t chy hon ton mt amin X bng mt lng khng kh (cha 80% th tch N2 cn li l O2) va thu c 35,2 gam CO2 ; 19,8 gam H2O v 5,5 mol N2. X tc dng vi HNO2 cho ancol bc 1. S cng thc cu to tha mn ca X l B. 1. C. 8. D. 2.

A. 3.
Cu 26.

Hn hp X gm O2 v O3 c t khi so vi H2 l 22 . Hn hp kh Y gm metylamin v etylamin c t khi so vi H2 l 17,833. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2, H2O v N2, cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l: B. 5 : 3 C. 2 : 1 D. 1 : 2

A. 3 : 5

Dng 4: Gii ton aminoaxit

CTC: (H2N)x-R-(COOH)y Da vo phn ng trung ha vi dung dch kim xc nh y

(H2N)x-R-(COOH)y + yNaOH (H2N)x-R-(COONa)y + yH2O

Trn con ng thnh cng khng c du chn ca k li bing

11

Phn dng bi tp chng 3 n NaOH = y = so nhom cacboxyl nX

Ha hc nng cao 12

Da vo phn ng vi dung dch axit xc nh x

(H2N)x-R-(COOH)y + xHCl (ClH3N)x-R-(COOH)y Ch :

Vic tm gc R da trn tng s nhm chc xc nh ha tr ca gc R v suy ra CTTQ ca gc nu

n HCl = x = so nhom amino nX

gi thit cho bit gc R c c im g? V d: H2NR(COOH)2 vi R l gc no

R l gc no ha tr III => R c dng CnH2n-1 Nu gc R khng r l no hay khng no th nn dng CTTQ l C xHy ri da vo khi lng ca gc R

bin lun
S dng phng php tng gim khi lng

(H2N)xR(COOH)y (H2N)xR(COOH)y 1 mol A mol Ch :

+ ddHCl +dd NaOH Gi s bi ton cho R ( NH 2 ) x (COOH ) y ddA ddB

1 mol a mol

khi lng tng 22y (gam) m (gam)

Xem nh ddA gm R(NH2)x(COOH)y HCl

+ dd NaOH

+ ddNaOH +dd HCl Nu s bi ton l R ( NH 2 ) x (COOH ) y ddA ddB

Xem nh ddA gm R(NH2)x(COOH)y NaOH

Cu 1.

+ dd HCl

Cho 0,1 mol -aminoaxit phn ng va vi 200ml dung dch HCl 0,5M thu c dung dch A. Cho dung dch NaOH 0,5M vo ddA th cn dng va ht 600ml. Vy s nhm NH2 v s nhm COOH ca -aminoaxit ny ln lt l B. 1 v 3 C. 1 v 2 D. 2 v 1

A. 1 v 1
Cu 2.

Cho 0,01 mol aminoaxit A tc dng va vi 80ml dung dch HCl 0,125M. C cn dung dch thu c 1,835 gam mui. Khi lng phn t ca A l B. 120 C. 147 D. 157

A. 97
Cu 3.

Trong phn t aminoaxit X c 1 nhm amino v 1 nhm cacboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui. CT ca X l B. H2NCH2COOH C. H2NC2H4COOH D. H2NC4H8COOH 12

A. H2NC3H5COOH

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Cu 4.

Ha hc nng cao 12

Cho 0,02 mol aminoaxit X tc dng va vi 200ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. CT ca X l C. H2NC3H6COOH D. H2NC3H5(COOH)2

A. (H2N)2C3H5COOH B. H2NC2H3(COOH)2
Cu 5.

Hp cht Y l 1 -aminoaxit. Cho 0,02 mol Y tc dng va vi 80ml dung dch HCl 0,25M. Sau c cn c 3,67 gam mui. Mt khc, trung ha 1,47 gam Y bng lng va dung dch NaOH, c cn dung dch thu c 1,91 gam mui. Bit Y c CT mch khng nhnh. CTCT ca Y l B. CH3 CH COOH

A. H2N CH2 CH2 COOH

NH2 C. HOOC CH2 CH2 CH COOH D. HOOC CH2 CH COOH

NH2
Cu 6.

NH2

Cho 0,2 mol -aminoaxit phn ng va vi 100ml dung dch HCl 2M thu c ddA. Cho dung dch A phn ng va vi dung dch NaOH, sau phn ng c cn sn phm thu c 33,9 gam mui. X c tn gi l B. Alanin C. Valin D. Axit glutamic

A. Glixin
Cu 7.

Cho 1 mol aminoaxit phn ng vi dung dch HCl d thu c m1 gam mui Y. Cng 1 mol aminoaxit X phn ng vi dung dch NaOH d, thu c m2 gam mui Z. Bit m2 m1 =7,5. CTPT ca X l B. C5H9O4N C. C4H8O4N2 D. C5H11O2N

A. C4H10O2N2
Cu 8.

Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH d, thu c ddY cha m+30,8 gam mui. Mt khc, nu cho m gam X tc dng hon ton vi ddHCl thu c dung dch Z cha m+ 36,5 gam mui. Gi tr ca m l B. 165,6 C. 123,8 D. 171,0

A. 112,2
Cu 9.

Cho 0,15 mol axit glutamic vo 175 ml ddHCl 2M, thu c dung dch X. Cho NaOH d vo dung dch X. Sau khi cc phn ng xy ra hon ton, s mol NaOH phn ng l B. 0,65 C. 0,70 D. 0,55

A. 0,5
Cu 10.

X l 1 -aminoaxit c CTTQ dng H2N R COOH. Cho 8,9 gam X tc dng vi 200ml dung dch HCl 1M, thu c ddY. phn ng ht vi cc cht trong dung dch Y cn dng 300ml dung dch NaOH 1M. CTCT ng ca X l

A. H2N CH2 COOH B. H2N CH2 CH2 COOH C. CH3 CH COOH D. CH3 CH2 CH COOH

NH2
Cu 11.

NH2

Cho 0,1 mol -aminoaxit X tc dng vi 50ml dung dch HCl 1M thu c ddA. Dung dch A tc dng va vi 250 ml dung dch NaOH 1M thu c ddB. C cn dung dch B cn li 20,625 gam cht rn khan. Tn gi ca X l 13

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 A. Alanin

Cu 12.

Ha hc nng cao 12 C. Axit aminosucxinic D. Tyrosin

B. Valin

Hn hp X gm glyxin v Lysin. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+22) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m + 51,1) gam mui. Gi tr ca m l : B. 103,4 g C. 123,8 g D. 171,0 g

A. 112,2 g
Cu 13.

Hn hp X gm 1 mol aminoaxit no, mch h v 1 mol amin no, mch h. X c kh nng phn ng ti a vi 2 mol HCl hoc va vi 2 mol NaOH. t chy hon ton X thu c 6 mol CO2, x mol H2O v y mol N2. Cc gi tr x, y tng ng l B. 8 v 1,5. C. 7 v 1,0. D. 7 v 1,5.

A. 8 v 1,0.
Cu 14.

Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l B. H2NC3H5(COOH)2. D. H2NC3H6COOH Cho mt -amino axit X c mch cacbon khng phn nhnh.

A. H2NC2H3(COOH)2. C. (H2N)2C3H5COOH. Cu 15.

- Ly 0,01mol X phn ng va vi dd HCl thu c 1,835g mui. - Ly 2,94g X phn ng va vi dd NaOH thu c 3,82g mui. Xc nh CTCT ca X? A. CH3CH2CH(NH2)COOH. C. HCOOCH2CH(NH2)CH2COOH.
Cu 16.

B. HOOCCH2CH2CH(NH2)COOH. D. HOOCCH2CH2CH2CH(NH2)COOH.

Hp cht X cha vng benzen, c cng thc phn t CxHyN. Khi cho X tc dng vi dung dch HCl thu c mui Y c cng thc dng RNH3Cl (R l gc hirocacbon). Phn trm khi lng ca nit trong X l 13,084%. S ng phn cu to ca X tha mn cc iu kin trn l B. 4. C. 5. D. 6.

A. 3.
Cu 17.

Cho 25,65 gam mui gm H2NCH2COONa v H2NCH2CH2COONa tc dng va vi 250 ml dung dch H2SO41M. Sau phn ng c cn dung dch th khi lng mui do H2NCH2COONa to thnh l: B. 18,6 gam C. 37,9 gam D. 12,4 gam

A. 29,25 gam
Cu 18.

Cho 0,02 mol cht X (X l mt -aminoaxit) phn ng va ht vi 160ml dd HCl 0,125 M th to ra 3,67g mui. Mt khc, 4,41g X khi tc dng vi mt lng NaOH va th to ra 5,73g mui khan. Bit X c mch cacbon khng phn nhnh. Vy cng thc cu to ca X l : B. CH3-CH2-CH(NH2)-COOH D. CH3-CH2-CH2-CH(NH2)-COOH

A. HOOC-CH(NH2)-CH(NH2)-COOH. C. HOOC-CH2-CH2-CH(NH2)-COOH.
Cu 19.

Dung dch X cha 0,01 mol ClH3N-CH2-COOH, 0,02 mol CH3-CH(NH2)COOH; 0,05 mol HCOOC6H5. Cho dung dch X tc dng vi 160 ml dung dch KOH 1M un nng phn ng xy ra hon ton. C cn dung dch sau phn ng thu c m gam cht rn khan. Gi tr ca m l: B. 16,335 gam C. 8,615 gam D. 14,515 gam

A. 12,535 gam

Trn con ng thnh cng khng c du chn ca k li bing

14

Phn dng bi tp chng 3

Cu 20.

Ha hc nng cao 12

Hn hp X gm 2 amino axit no, mch h. Ly 8,9 gam X cho tc dng vi dung dch HCl d c a gam mui, cng lng 8,9 gam X khi tc dng vi dung dch NaOH d th lng mui thu c l (a 1,45) gam. Hai amino axit l B. NH2CH2COOH v NH2C2H4COOH. D. NH2CH2COOH v NH2C3H6COOH.

A. NH2C4H8COOH v NH2C3H6COOH. C. NH2C2H4COOH v NH2C3H6COOH.

Cu 21.

Cho 17,8 gam hn hp hai amino axit no cha mt chc -COOH v mt chc -NH2 (t l khi lng phn t ca chng l 1,373) tc dng vi 110 ml dung dch HCl 2M, c dung dch A. tc dng ht cc cht trong dung dch A cn dng 140 ml dung dch KOH 3M. Phn trm s mol mi amino axit trong hn hp ban u bng B. 50% v 50%. C. 20% v 80%. D. 40% v 60%.

A. 25% v 75%.
Cu 22.

Cho m gam hn hp X gm axit glutamic v valin tc dng vi dung dch HCl (d), sau phn ng hon ton lm bay hi cn thn dung dch, thu c (m + 9,125) gam mui khan. Nu cho m gam X tc dng vi dung dch NaOH (d), kt thc phn ng to ra (m + 7,7) gam mui. Gi tr ca m l B. 39,60. C. 33,75. D. 32,25.

A. 26,40.

Cu 23. Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng va vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn khan? A. 14,025 gam
Cu 24.

B. 8,775 gam

C. 11,10 gam

D. 19,875 gam

Cho 0,15 mol hn hp X gm hai aminoaxit: R(NH2)(COOH)2 v R(NH2)2(COOH) vo 200 ml dung dch HCl 1,0M, thu c dung dch Y. Y tc dng va ht vi 400 ml dung dch NaOH 1,0M. S mol ca R(NH2)(COOH)2 trong 0,15 mol X l : B. 0,125 mol . C. 0,075 mol D. 0,05 mol

A. 0,1 mol
Cu 25.

Cho 0,12 mol alanin tc dng va vi dung dch HCl thu c dung dch X. Thm vo dung dch X 300 ml dung dch NaOH 1M thu c dung dch Y. C cn dung dch Y thu c m gam cht rn khan. Gi tr ca m l: B. 22,74 gam C. 20,10 gam D. 23,14 gam

A. 17,70 gam
Cu 26.

A l mt -amino axit mch cacbon khng phn nhnh. Cho 0,1 mol A vo dung dch cha 0,25 mol HCl (d), c dung dch B. phn ng ht vi dd B, cn va 300 ml dd NaOH 1,5 M un nng. Nu c cn dung dch sau cng, th c 33,725 g cht rn khan. A l: B. Alanin C. axit glutamic D. axit -amino butiric

A. Glixin

Dng 5: Gii ton mui amoni, este ca aminoaxit, axit

CTC ca mui amoni:

H2N R COONH4

hoc:

H2N R COONH3R

CTC este ca aminoaxit: H2N R COOR Mui amoni, este ca aminoaxit l hp cht lng tnh

H2N R COONH3R + HCl ClH3N R COONH3R H2N R COONH3R + NaOH H2N R COONa + RNH2 + H2O Trn con ng thnh cng khng c du chn ca k li bing 15

Phn dng bi tp chng 3 Ch : thng s dng LBTKL gii ton

Cu 1.

Ha hc nng cao 12

ng vi CTPT C2H7O2N c bao nhiu cht va phn ng vi dung dch NaOH va phn ng c vi dung dch HCl B. 3 C. 1 D. 4

A. 2
Cu 2.

Cht X c CTPT C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l B. Metyl aminoaxetat D. Amoni acrylat

A. Axit -aminopropionic C. Axit -aminopropionic

Cu 3.

Cho hai hp cht hu c X, Y c cng CTPT l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l C. CH3OH v NH3 D. CH3NH2 v NH3

A. CH3OH v CH3NH2 B. C2H5OH v N2

Cu 4.

Cht X c CTPT C4H9O2N. Bit X + NaOH Y + H2O Y + HCl d Z + NaCl

CTCT ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH C. H2NCH2COOC2H5 v ClH3NCH2COOH D. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH

Cu 5.

Hp cht X mch h c CTPT l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra 1 cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm qu tm m chuyn sang mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l B. 10,8 C. 9,4 D. 9,6

A. 8,2
Cu 6.

Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v 1 aminoaxit. Cho 25,75 gam X phn ng ht vi 300ml dung dch NaOH 1m, thu c dung dch Y. C cn dung dch Y thu c m gam cht rn. Gi tr ca m l B. 27,75 C. 26,25 D. 24,25

A. 29,75
Cu 7.

Cho 1,82 gam hp cht hu c n chc, mch h X c CTPT C3H9O2N tc dng va vi dung dch NaOH, un nng thu c kh Y v dung dch Z. C cn Z thu c 1,64 gam mui khan. CTCT thu gn ca X l B. CH3COONH3CH3 C. HCOONH2(CH3)2 D. HCOONH3CH2CH3

A. CH3CH2COONH4
Cu 8.

Cho hn hp X gm 2 cht hu c c cng CTPT C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z (ktc) gm 2 kh (u lm xanh giy qu tm m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l B. 14,3 C. 8,9 D. 15,7

A. 16,5
Cu 9.

Cu 9. Hp cht X c CTPT trng vi CTG, va tc dng vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t x thnh phn % theo khi lng ca cc nguyn t C, H, N ln lt bng 40,449%; 7,865%; 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon 16

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Ha hc nng cao 12

ton vi lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. CTCT thu gn ca X l A. CH2=CHCOONH4 B. H2N-COOCH2CH3
Cu 10.

C. H2NCH2COOCH3

D. H2NC2H4COOH

Cho cht hu c X c CTPT C2H8O3N2 tc dng vi dung dch NaOH thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l B. 68 C. 45 D. 46

A. 85
Cu 11.

Cho 1,86 gam hp cht c cng thc phn t C3H12O3N2 phn ng hon ton vi 200 ml dung dch NaOH 0,2M, thu c mt hp cht hu c bc 1 n chc v dung dch X ch cha cc cht v c. C cn X c a gam cht rn khan. Gi tr ca a l B. 2,275 C. 1,99 D. 3,56

A. 2,05
Cu 12.

(K) l hp cht hu c c CTPT l: C5H11NO2. un (K) vi dd NaOH thu c hp cht c CTPT l C2H4O2NNa v hp cht hu c (L). Cho hi (L) qua CuO/to thu c mt cht hu c (M) c kh nng tham gia phn ng trng bc. CTCT ca (K) l B. NH2-CH2-COO-CH2-CH2-CH3. D. H2N-CH2-CH2-COO-C2H5.

A. CH2=CH-COONH3-C2H5. C. NH2-CH2-COO-CH(CH3)2.
Cu 13.

Cho hn hp X gm 2 cht hu c c cng cng thc phn t C3H10N2O2 tc dng va vi dung dch NaOH v un nng thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m) hn km nhau mt nguyn t C. T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l: B. 20,1 gam C. 8,9 gam D. 15,7 gam

A. 16,5 gam
Cu 14.

Mt HCHC X c t l khi lng C : H : O : N = 9 : 1,75 : 8 : 3,5 tc dng vi dd NaOH v dd HCl theo t l mol 1 : 1 v mi trng hp ch to mt mui duy nht. Mt ng phn Y ca X cng tc dng vi dd NaOH v dd HCl theo t l mol 1: 1 nhng ng phn ny c kh nng lm mt mu dd Br2. Cng thc phn t ca X v cng thc cu to ca X, Y ln lt l:

A. C3H7O2N; H2N-C2H4-COOH; H2N-CH2-COO-CH3 B. C3H7O2N; H2N-C2H4-COOH; CH2=CH-COONH4 C. C2H5O2N; H2N-CH2-COOH; CH3-CH2-NO2 D. C3H5O2N; H2N-C2H2-COOH; CH C-COONH4
Cu 15.

(X) l HCHC c thnh phn v khi lng phn t l 52,18%C, 9,40%H, 27,35%O, cn li l N. Khi un nng vi dd NaOH thu c mt hn hp cht c cng thc phn t C2H4O2NNa v cht hu c (Y), cho hi (Y) qua CuO/t0 thu c cht hu c (Z) c kh nng tham gia phn ng trng gng. Cng thc cu to ca X l: B. NH2-CH2COO-CH2-CH2-CH3 D. H2N-CH2-CH2-COOC2H5

A. CH3(CH2)4NO2 C. NH2-CH2-COO=CH(CH2)3
Cu 16.

Cht X c cng thc phn t C4H10O2NCl. un nng X vi dung dch NaOH thu c cc sn phm NaCl, H2N- CH2- COONa, v ru Y. Cng thc cu to ca X l: B. CH3-CH2-OOC- CH2-NH3Cl D. CH3- CH(NH2)- COO-CH2-Cl

A. CH3-CH2-COO-CH2-NH3Cl C. CH3 -COO-CH2-CH2-NH3Cl

Trn con ng thnh cng khng c du chn ca k li bing

17

Phn dng bi tp chng 3

Cu 17.

Ha hc nng cao 12

Hp cht hu c X c CTPT l C3H10O4N2. X phn ng vi NaOH va , un nng cho sn phm gm hai cht kh u lm xanh qu m c tng th tch l 2,24 lt (ktc) v mt dd cha m g mui ca mt axit hu c. Gi tr m l B. 13,4. C. 6,9. D. 13,8.

A. 6,7.

(Gi X: H4NOOC-COONH3CH3)
Cu 18.

Cho 0,1 mol cht hu c X c CTPT C2H8O3N2 tc dng vi 0,2 mol NaOH, un nng thu c cht kh lm xanh qu tm m v dd Y. C cn dd Y thu c m gam cht rn khan. Gi tr ca m l: B. 12,5 C. 15 D. 21,8

A. 5,7
Cu 19.

Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l: B. vinylamoni fomat v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic.

A. amoni acrylat v axit 2-aminopropionic. C. axit 2-aminopropionic v amoni acrylat.

Cu 20.

C bao nhiu cht hu c n chc mch h c CTPT C3H9O2N tc dng c vi dd KOH (un nng) thu c kh hu c lm xanh giy qu tm m? B. 3 C. 1 D. 4

A. 2
Cu 21.

t chy hon ton 1 mol cht hu c X thu c sn phm gm 2 mol CO2, 11,2 lt N2 ( ktc) v 63 gam H2O. T khi hi ca X so vi He = 19,25. Bit X d phn ng vi dung dch HCl v NaOH. Cho X tc dng vi NaOH thu c kh Y. t chy Y thu c sn phm lm c nc vi trong. X c cng thc cu to l B. HCOONH3CH3. C. CH3CH2COONH4. D. CH3COONH4.

A. CH2(NH2)COOH.
Cu 22.

X c cng thc C4H14O3N2. Khi cho X tc dng vi dung dch NaOH th thu c hn hp Y gm 2 kh iu kin thng v u c kh nng lm xanh qu tm m. S CTCT ph hp ca X l: B. 2 C. 4 D. 5

A. 3
Cu 23.

Ly 9,1 gam hp cht X c cng thc phn t l C3H9O2N tc dng vi dung dch NaOH d, un nng, thu c 2,24 lt (ktc) kh Y (lm xanh giy qu tm m). t chy hon ton lng kh Y ni trn, thu c 8,8 gam CO2. X, Y ln lt l: B. CH3COONH3CH3; CH3NH2 D. CH2=CHCOONH4; NH3

A. HCOONH3C2H3; C2H3NH2 C. HCOONH3C2H5; C2H5NH2

Cu 24.

Mui A c cng thc l C3H10O3N2, ly 7,32 gam A phn ng ht vi 150ml dd KOH 0,5M. C cn dd sau phn ng th c phn hi v phn cht rn, trong phn hi c 1 cht hu c bc 3, trong phn rn ch l cht v c. Khi lng cht rn l: B. 6,06 g. C. 6,90 g. D. 9,42 g.

A. 11,52 g.

Dng 6: Gii ton protein-peptit

Peptit c cu to t cc gc -aminoaxit T n phn t -aminoaxit khc nhau th c n! ng phn peptit T n phn t -aminoaxit khc nhau th c n2 s peptit c to thnh

Trn con ng thnh cng khng c du chn ca k li bing

18

Phn dng bi tp chng 3

Ha hc nng cao 12

Phn ng thy phn khng hon ton peptit cho sn phm c th l -aminoaxit, ipeptit, tripeptit Phn ng thy phn hon ton peptit cho sn phm l cc gc -aminoaxit Cu 1.

S peptit ti a c th to ra t mt hn hp gm alanin v glyxin l B. 3 C. 4 D. 1

A. 2
Cu 2.

C bao nhiu tripeptit (mch h) khc nhau m khi thy phn hon ton u thu c 3 aminoaxit: glyxin, alanin v phenylalanin B. 9 C. 4 D. 6

A. 3
Cu 3.

Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l B. Dung dch NaCl D. Dung dch NaOH

A. Cu(OH)2 trong mi trng kim C. Dung dch HCl

Cu 4.

un nng cht H2N CH2 CONH CH(CH3) CONH CH3 COOH trong dung dch HCl d, sau khi phn ng kt thc thu c sn phm l

A. H2N CH2 COOH; H2N CH2 CH2 COOH B. H3N+ - CH2 COOHCl-; H3N- - CH2 CH2-COOHClC. H3N- - CH2 COOHCl-; H3N+ - CH(CH3) COOHClD. H2N CH2 COOH; H2N CH(CH3) COOH.
Cu 5.

Nu thy phn khng hon ton pentapeptit Gly-Ala-Gly-Ala-Gly th thu c ti a bao nhiu ipeptit khc nhau B. 1 C. 2 D. 4

A. 3
Cu 6.

Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol Phenylalanin (Phe). Thy phn khng hon ton x thu c ipeptit Val-Phe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l B. Gly-Ala-Val-Val-Phe D. Val-Phe-Gly-Ala-Gly

A. Gly-Phe-Gly-Ala-Val C. Gly-Ala-Val-Phe-Gly
Cu 7.

Thy phn 1250 gam protein X thu c 425 gam alanin. Nu phn t ca X bng 100.000vC th s mt xch alani c trong phn X l B. 382 C. 328 C. 479

A. 453
Cu 8.

ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha 1 nhm NH2 v 1 nhm COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l B. 60 C. 30 D. 45

A. 120
Cu 9.

Thy phn ht m gam tetrapeptit Ala-Ala-Ala-Ala (mch h) thu c hp gm 28,48 gam Ala, 32 gam Ala-Ala v 27,72 gam Ala-Ala-Ala. Gi tr ca m l B. 111,74 C. 81,54 D. 66,44

A. 90,6

Trn con ng thnh cng khng c du chn ca k li bing

19

Phn dng bi tp chng 3

Cu 10.

Ha hc nng cao 12

Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm 1 cc amino axit (cc amino axit ch c 1 nhm amino v 1 nhm cacboxyl trong phn t). Nu cho hn 10 hp X tc dng vi dung dch HCl d, c cn cn thn dung dch, th lng mui khan thu c l B. 16,30 gam C. 8,15 gam D. 7,82 gam

A. 7,09 gam

Cu 11. Khi thu phn hon ton 0,1 mol peptit A mch h (A to bi cc amino axit c mt nhn amino v mt nhm cacboxylic) bng lng dung dch NaOH gp i lng phn ng, c cn dung dch thu c hn hp cht rn tng so vi khi lng A l 78,2 gam. S lin kt peptit trong A l A. 10
Cu 12.

B. 20

C. 9

D. 18

X l mt -aminoaxit no, cha 1 nhm COOH v 1 nhm NH2. T m gam X iu ch c m1 gam ipeptit. T 2m gam X iu ch c m2 gam tripeptit. t chy m1 gam i peptit thu c 0,3 mol nc. t chy m2 gam tri peptit thu c 0,55 mol nc. Gi tr ca m l B. 13,35 gam C. 22,50 gam D. 26,70 gam

A. 11,25 gam
Cu 13.

Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm -NH2. Phn trm khi lng ca N trong X l 18,667%. Thu phn khng hton m gam hh M, Q (t l mol 1 : 1) trong mi trng axit c 0,945 gam M ; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l B. 58,725. C. 9,315. D. 8,389.

A. 5,580. Cu 14.

Cng thc no sau y ca tripeptit (A) tha iu kin sau:

+ Thy phn hon ton 1 mol A th thu c cc - amino axit l: 3 mol Glyxin , 1 mol Alanin, 1 mol Valin. + Thy phn khng hon ton A, ngoi thu c cc amino axit th cn thu c 2 i peptit: Ala-Gly ; Gly- Ala v Gly-Gly-Val. A. Ala-Gly-Gly-Gly-Val. C. Gly-Ala-Gly-Gly-Val.
Cu 15.

B. Gly-Gly-Ala-Gly-Val. D. Gly-Ala-Gly-Val-Gly.

X v Y ln lt l cc tripeptit v tetrapeptit c to thnh t cng mt amino axit no mch h, c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol Y thu c sn phm gm CO2, H2O, N2, trong tng khi lng ca CO2 v H2O l 47,8 gam. Nu t chy hon ton 0,3 mol X cn bao nhiu mol O2? B. 2,025 mol C. 3,375 mol D. 1,875 mol

A. 2,8 mol
Cu 16.

Tripeptit mch h X v tetrapeptit mch h Y u c to ra t mt amino axit no, mch h c 1 nhm COOH v 1 nhm NH2. t chy hon ton 0,1 mol X thu c sn phm gm CO2, H2O, N2 trong tng khi lng CO2, H2O l 36,3 gam. Nu t chy hon ton 0,2 mol Y cn s mol O2 l: B. 1,8 C. 2,8 D. 3,375

A. 1,875
Cu 17.

Cho mt ipeptit Y c cng thc phn t C6H12N2O3. S ng phn peptit ca Y (ch cha gc -amino axit) mch h l B. 7. C. 5. D. 4. 20

A. 6.

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Cu 18.

Ha hc nng cao 12

X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m (gam) hn hp cha X v Y c t l s mol ca X v Y tng ng l 1:3 vi dung dch NaOH va . Phn ng hon ton thu c dung dch T. C cn cn thn dung dch T thu c 23,745 gam cht rn khan. Gi tr ca m l B. 68,1. C. 17,025. D. 78,4

A. 19,455.
Cu 19.

X l tetrapeptit c cng thc Gly Ala Val Gly. Y l tripeptit c cng thc Gly Val Ala. un m gam hn hp A gm X, Y c t l mol tng ng l 4:3 vi dung dch KOH va sau khi phn ng xy ra hon ton c cn dung dch thu c 257,36g cht rn khan. Gi tr ca m l: B. 155,44 gam C. 167,38 gam D. 212,12 gam

A. 150,88 gam
Cu 20.

X l tetrapeptit Ala-Gly-Val-Ala, Y l tripeptit Val-Gly-Val. un nng m gam hn hp X v Y c t l s mol nX : nY = 1 : 3 vi 780 ml dung dch NaOH 1M (va ), sau khi phn ng kt thc thu c dung dch Z. C cn dung dch thu c 94,98 gam mui. m c gi tr l : B. 64,86 gam. C. 77,04 gam. D. 65,13 gam.

A. 68,1 gam.
Cu 21.

ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm NH2 v mt nhm COOH).t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton m (g) X ,lng CO2 sinh ra c hp th hon ton vo 600 ml dd hn hp gm NaOH 0,1M v Ba(OH) 2 0,2M sinh ra 11,82g kt ta. Tnh gi tr ca m l: B. 1,6 C. 6,4 D. 8

A. 1,6 v 6,4 gam

Cu 22.

X v Y ln lt l cc tripeptit v hexapeptit c to thnh t cng mt amino axit no mch h, c mt nhm -COOH v mt nhm -NH2. t chy hon ton 0,1 mol X bng O2 va thu c sn phm gm CO2, H2O, N2, c tng khi lng l 40,5 gam. Nu cho 0,15 mol Y cho tc dng hon ton vi NaOH (ly d 20% so vi lng cn thit), sau phn ng c cn dung dch th thu c bao nhiu gam cht rn? B. 9,99 gam C. 107,1 gam D. 94,5 gam

A. 87,3 gam
Cu 23.

Hn hp M gm mt peptit X v mt peptit Y (chng cu to t 1 loi aminoaxit, tng s nhm CONH trong 2 phn t l 5) vi t l s mol nX : nY = 1:3 .Khi thy phn hon ton m gam M thu c 81 gam glixin v 42,72 gam alanin. m c gi tr l B. 109,5 gam C. 116,28 gam D. 110,28 gam

A. 104,28 gam
Cu 24.

X l mt tetrapeptit. Cho m gam X tc dng va vi 0,3 mol NaOH thu c 34,95g mui. Phn t khi ca X c gi tr l: B. 432 C. 234 D. 342

A. 324
Cu 25.

Tripeptit M v tetrapeptit Q u c to ra t mt amino axit X mch h, phn t c mt nhm -NH2. Phtrm khi lng ca N trong X l 18,667%. Thu phn khng hon ton m gam hn hp M, Q (t l mol 1 : 1) trong mi trng axit thu c 0,945 gam M ; 4,62 gam ipeptit v 3,75 gam X. Gi tr ca m l B. 58,725. C. 5,580. D. 9,315.

A. 8,389.

C- BI TP TRC NGHIM LUYN TP Trn con ng thnh cng khng c du chn ca k li bing 21

Phn dng bi tp chng 3 Cu 1. S amin thm bc mt ng vi CTPT C7H9N l A. 2 B. 4 C. 5 D. 3

Ha hc nng cao 12

Cu 2. Dung dch no sau y lm qu tm chuyn sang mu xanh A. Glyxin B. Etylamin C.Anilin D. Phenylamoni clorua

Cu 3. S ng phn ca hp cht hu c c CT C3H9N l A. 5 B. 6 C. 7 D. 4

Cu 4. Cho cc cht sau: NH3 (1); C2H5NH2 (2); CH3CH2CH2NH2 (3); CH3NH2 (4). Chiu tng tnh bazo l A. 1 2 4 3 B. 1 4 2 3 C. 2 4 1 3 D. 4 2 3 1

Cu 5. Tnh bazo ca cc cht c sp xp nh sau. Chn phng n ng A. NH3 > CH3NH2 > C6H5NH2 C. C6H5NH2 > NH3 > CH3NH2 B. CH3NH2 > NH3 > C6H5NH2 D. CH3NH2 > C6H5NH2 > NH3

Cu 6. Dung dch cht no sau y khng lm i mu qu tm? A. Dung dch amoniac C. Dung dch anilin B. Dung dch natricacbonat D. Dung dch metylamin

Cu 7. Cho cc dung dch hex-1-en; benzen; v anilin. Ch dng 1 ha cht no sau y c th nhn c c ba cht trn A. NaOH B. HBr C. Dung dch Brom D. HNO3

Cu 8. Cht X c CTPT C3H7O2N v lm mt mu dung dch brom. Tn gi ca X l a. Axit -aminopropionic C. Axit -aminopropionic Cu 9. Hy ch ra cu sai trong cc cu sau y A. Tt c cc amin u c tnh bazo C. Tnh bazo ca anilin mnh hn metylamin B. Tnh bazo ca amoniac mnh hn anilin D. CTTQ ca amin no n chc l CnH2n+3N B. Metyl aminoaxetat D. Amoni acrylat

Cu 10. Khi t chy hon ton 1 amin n chc A ngi ta thu c 20,25 gam H 2O; 16,8 lt CO2 v 2,8 lt kh N2 (ktc). CTPT ca A l A. C3H5N B. C3H9N C. C3H7N D. C2H7N

Cu 11. A l hp cht hu c no, n chc cha C, H v 23,7% N. Vy s ng phn ca A l A. 1 B. 2 C. 3 D. 4

Cu 12. Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y thu c 9,55 gam mui khan. S CTCT ng vi CTPT ca X l A. 5 B. 4 C. 2 D. 3

Cu 13. Cho cc loi hp cht: Aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht va tc dung vi dung dch NaOH va tc dng vi dung dch HCl l A. X, Y, Z, T B. X, Y, T C. X, Y. Z D. Y, Z, T 22

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3

Ha hc nng cao 12 nH 2O nCO2 = 1,5 . Vy A

Cu 14. t chy hon ton mt amin no, n chc A thu c CO2, H2O v N2, bit t l T = l A. CH5N B. C2H7N C. C3H9N

D. C4H11N

Cu 15. trung ha 1 dung dch cha 0,45 gam amin no, n chc X cn 100ml dung dch HCl 0,1M. Vy X l A. CH5N B. C2H7N C. C3H9N D. C4H11N

Cu 16. -aminoaxit X cha 1 nhm NH2. Cho 10,3 gam X tc dng vi dung dch HCl d, thu c 13,95 gam mui khan. CTCT thu gn ca X l A. H2NCH2COOH C. CH3CH2CH(NH2)COOH B. H2NCH2CH2COOH D. CH3CH(NH2)COOH

Cu 17. Cho 3,21 gam mt ng ng ca anilin phn ng ht vi 300ml dung dch HCl 1M, Vy A c CTPT l A. C7H7NH2 B. C8H9NH2 C. C9H11NH2 D. C10H13NH2

Cu 18. Hai hp cht hu c X v y c cng CTPT l C3H7NO2, u l cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. Vinylamoni fomat v amoni acrylat B. Amoni acrylat v axit 2-aminopropionic C. Axit 2-aminopropionic v amoni acrylat D. Axit 2-aminopropionic v axit 3-aminopropionic Cu 19. Cho mt mu qu tm vo dung dch glixin. Vy qu tm s A. Ha B. Ha xanh C. Khng i mu d. Mt mu tm

Cu 20. Axit glutamic c CT l HOOC [CH2]2 CH(NH2)COOH. Vy tn IUPAC ca n l A. Axit-2-aminopenta-1,4-ioic C. Axit-3-aminopenta-1,5-ioic B. Axit-2-aminopenta-1,5-ioic D. Axit-1-aminopenta-1,4-ioic

Cu 21. Cho dung dch cc cht: glixin, metylamin, axit axetic. Ch dng 1 cht no di y c th nhn bit c c 3 cht trn A. NaOH B. HCl C. Na D. Qu tm

Cu 22. t chy hon ton mt lng cht hu c X thu c 3,36 lt kh CO2; 0,56 lt kh N2 (cc kh o ktc) v 3,15 gam H2O. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H 2N CH2 COONa. CTCT thu gn ca X l A. H2N CH2 COO C3H7 C. H2N CH2 CH2 COOH B. H2N CH2 COO CH3 D. H2N CH2 COO C2H5

Cu 23. Cho 8,9 gam mt hp cht hu c X c CTPT C3H7O2N phn ng vi 100ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. CTCT thu gn ca X l A. HCOOH3NCH=CH2 C. CH2=CHCOONH4 B. H2NCH2CH2COOH D. H2NCH2COOCH3 23

Trn con ng thnh cng khng c du chn ca k li bing

Phn dng bi tp chng 3 Cu 24. Policaproamit (nilon-6) c trng hp t cht no sau y: A. Axit glutamic C. Axit -aminocaproic B. Axit -aminocaproic D. Axit -aminoenantic

Ha hc nng cao 12

Cu 25. Hp cht A l mt -aminoaxit. Cho 0,01 mol A tc dng va vi 80 ml dung dch HCl 0,125M, sau c cn dung dch thu c 1,835 gam mui. Vy khi lng phn t ca A l A. 147 vC B. 149 vC C. 160 vC D. 155 vC

Cu 26. Este A c iu ch t aminoaxit v ancol metylic. t chy hon ton 0,1 mol A thu c 13,2 gam CO2 v 1,12 lt kh N2 (ktc). Vy A c CTCT l A. H2N CH2 COOCH3 C. CH3COOCH2CH3 B. H2N COOCH2CH3 D. H2N CH2 COOCH2NH2

Cu 27. Mt hp cht hu c Y mch thng c CTPT l C3H10O2N2. Y tc dng vi kim gii phng NH3 v to ra sn phm c kh nng to vi Cu(OH)2 thnh dung dch c mu tm. Vy CTCT ca Y l A. H2N CH2CH2COONH4 C. H2N CH2 COOCH2NH4 B. CH3CH(NH2)COONH4 D. H2N CH2 OCOCH2NH4

Cu 28. Cho 0,1 mol cht X c CTPT l CH6O3N2 tc dng vi dung dch cha 0,2 mol NaOH un nng thu c cht kh lm xanh qu tm m v dung dch Y. C cn dung dch Y thu c m (gam) cht rn khan. Gi tr ca m l A. 5,7 B. 12,5 C. 15 D. 21,8

Cu 29. Hp cht Y l mt -aminoaxit. Cho 0,02 mol Y tc dng va vi 80 ml dung dch HCl 0,25M, sau c cn dung dch thu c 3,67 gam mui. Mt khc, trung ha 2,94 gam Y bng 1 lng va dung dch NaOH, c cn dung dch thu c 3,82 gam mui. Bit Y c cu to khng phn nhnh. Vy CTCT ca Y l A. HOOC [CH2]2 CH(NH2)COOH C. H2N CH2 CH2 COOH B. HOOC CH2 NH2 D. HOOC CH2 CH(NH2)COOH

Cu 30. Aminoaxit cha 1 nhm amin bc nht trong phn t. t chy hon ton 1 lng X thu c CO2 v N2 theo t l 4:1. Vy X l A. H2N CH2 COOH C. H2N CH2 CH2 COOH B. H2N [CH2]3 COOH D. HOOC [CH2]2 CH(NH2)COOH

Cu 31. Khi t chy 0,1 mol A cha cc nguyn t C, H,O, N thu c hi nc, 0,3 mol CO2 v 0,05 mol N2. Bit A lm mt mu dung dch nc brom v khi tc dng vi NaOH gii phng 1 cht kh. Vy A l A. CH2 = CH COONH4 C. CH2 = CH(NH2)COONH4 B. H2N CH = CH COOH D. H2N CH2 CH = CH COOH

Cu 32. phn bit amin bc I v amin bc II, ngi ta dng ha cht no di y A. HNO3 B. HNO2 C. Cu(OH)2 D. NaOH

Cu 33. Nhn nh no sau y khng ng? A. Protein d tan trong nc to thnh dung dch keo. B. Lp vng ni ln khi nu tht, c l hin tng ng t protein. Trn con ng thnh cng khng c du chn ca k li bing 24

Phn dng bi tp chng 3

Ha hc nng cao 12

C. Vi lng trng trng, Cu(OH)2 phn ng vi cc nhm peptit CO NH cho sn phm mu tm D. Sa ti lu s b vn cc, to thnh kt ta do b ln men lm ng t protein. Cu 34. Chn phng n tt nht phn bit dung dch cc cht mt nhn ring bit sau: CH3NH2, H2NCH2COOH, CH3COONH4, albumin. A. Qu tm, dung dch HNO3 c, dung dch NaOH B. Cu(OH)2, qu tm, dung dch brom C. Dung dch brom, dung dch HNO3 c, dung dch I2. D. Dung dch AgNO3/NH3, dung dch brom, dung dch HNO3 c. Cu 35. Dung dch X cha HCl v H2SO4 c pH = 2. trung ha hon ton 0,59 gam hn hp 2 amin no, n chc, bc I (c s nguyn t C nh hn hoc bng 4) phi dng 1 lt dung dch X. CTCT ca 2 amin ln lt l A. CH3NH2 v C4H9NH2 B. C3H7NH2 v C4H9NH2 C. C2H5NH2 v C4H9NH2 D. A, C ng

Cu 36. Cho mt hn hp A cha NH3, C6H5NH2 v C6H5OH. A c trung ha bi 0,02 mol NaOH hoc 0,01 mol HCl. A cng phn ng va vi 0,075 mol Br2 to kt ta. S mol cc cht NH3, C6H5NH2, C6H5OH ln lt l A. 0,01 mol; 0,005 mol; 0,02 mol C. 0,005 mol; 0,02 mol; 0,005 mol B. 0,005 mol; 0,005 mol; 0,02 mol D. 0,01 mol; 0,005 mol; 0,02 mol

Cu 37. Ngi ta iu ch anilin bng cch nitro ha 500 gam benzen ri kh hp cht nitro sinh ra. Khi lng anilin thu c l bao nhiu, bit hiu sut mi giai on l 78% A. 346,7 gam B. 362,7 gam C. 463,4 gam D. 465,0 gam

Cu 38. Este X c iu ch t aminoaxit T v ancol etylic. T khi hi ca X so vi H2 bng 51,5. t chy hon ton 10,3 gam X thu c 17,6 gam kh CO2; 8,1 gam H2O v 1,12 lt kh N2 (ktc). CTCT thu gn ca X l A. H2N[CH2]2COOC2H5 C. H2N C(CH3)3 COOC2H5 B. H2N CH2 COO C2H5 D. H2N CH(CH3) COOC2H5

Cu 39. Cho dung dich metylamin d ln lt vo tng dung dch FeCl 3, AgNO3, NaCl, Cu(NO3)2. S trng hp thu c kt ta sau phan ng la: A. 1 B. 2 C. 3 D. 4

Cu 40. iu khng nh no sau y khng ng: A- Khi lng phn t ca mt aminoaxit ( gm mt chc NH2 v mt chc COOH) lun l s l B- Hp cht aminoaxit phi c tnh lng tnh C- Dung dch aminoaxit khng lm giy qu tm i mu D-Thu phn protit bng axit hoc kim s cho mt hn hp cc aminoaxit

Trn con ng thnh cng khng c du chn ca k li bing

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