www.themegallery.

com

BO CO CNG NGH NANO NG NANO CACBON (CARBON NANO TUBES)

CC PHNG PHP CH TO NG NANO CACBON V FULREN CC TNH CHT C BIT CA NG NANO CACBON NG DNG CA NG NANO CACBON V FULREN

GV: Nguyn Th Lng NHM 12: Ng Trung Hiu

TP.HCM 11/2011

I - CC PHNG PHP CH TO

Lng ng pha hi ha hc (CVD).

Phng in h quang.

CC PHNG PHP CH TO

Dng ngun Laze

Nghin bi v nhit

I - CC PHNG PHP CH TO * C ch mc ng Nano Carbon

Ht xc tc c to trn Kh CnHn s c phn li thnh cc nguyn t carbon v cc sn phm ph khc nh cht xc tc Cc sn phm sau phn ly s lng ng trn cc ht xc tc. y s xy ra qu trnh to cc lin kt C-C v hnh thnh CNTs. Kch thc ng CNTs ph thuc vo kch thc cht xc tc.
C ch mc ng nano carbon

I - CC PHNG PHP CH TO * C ch mc ng Nano Carbon

Kch thc ca cc ht xc tc kim loi v cc iu kin lin quan khc quyt nh ng nano l ng n vch (SWCNTs) hay a vch (MWCNTs). Lin kt gia cc ht xc tc v m ng nano ccbon quyt nh c ch mc: mc t nh ca ht ln hay mc t ln to thnh CNTs.

nh SEM ca CNTs vi cc ht xc tc u ng v cui ng

I - CC PHNG PHP CH TO
1- Phng php lng ng pha hi ha hc (CVD)
Nguyn l:

S dng carbon t hidro carbon(CH4,C2H2) hoc CO v nng lng nhit hoc plasma hay Laze phn ly cc phn t kh thnh cc nguyn t carbon hot ha.Cc nguyn t cacbon ny khuch tn xung , v lng ng ln cc ht kim loi xc tc xc tc (Fe, Ni, Co). CNTs c to thnh.(nht t vo 650-900 c)
u nhc im - D ch to v r tin - sch khng cao, thng phi dng thm cc cch lm sch
nh SEM cc ng carbon nano mc bng phng pho CVD

I - CC PHNG PHP CH TO
1- Phng php lng ng pha hi ha hc (CVD)
Mt s k thut dng CVD to CNTs thng c s dng
- Phng php CVD nhit - Phng php CVD tng cng Plasma - Phng php CVD xc tc Alcohol - Phng php CVD nhit c Laze h tr - Phng php mc bay hi - Phng php CVD xc tc vi CoMoCat

I - CC PHNG PHP CH TO
1- Phng php lng ng pha hi ha hc (CVD)
Phng php CVD nhit
Cu to: gm mt ng thch anh c bao quanh bi mt l nhit Hot ng: kh cha carbon c a vo ng to thnh carbon nguyn t. Di nhit cao, cc nguyn t carbon b phn tn trn cc ht nano kim loi v tr thnh trung ha. Nguyn t carbon sau lng ng thnh CNTs.

S khi h CVD nhit

I - CC PHNG PHP CH TO
1- Phng php lng ng pha hi ha hc (CVD)
Hin nay gim thi gian nung nhit cho l ban u. Phng th nghim ng nano xut s dng thay th mt ng l trn bng 4 ng l s dng ng thp khng r. do vy m thi gian chun l t gim i t 2 ngy xung cn 2h.

I - CC PHNG PHP CH TO
1- Phng php lng ng pha hi ha hc (CVD)
Dy truyn ch to CNTs bng phng php CVD nhit:

I - CC PHNG PHP CH TO 2- Phng php phng in h quang

Nguyn l: Hi carbon c to ra bng phng mt lung h quang in gia hai in cc lm bng than hoc graphit. CNTs t mc ln t hi carbon. u nhc im: - L phng php n gin cho CNTs cht lng cao v cu trc hon ho. - Khng th iu khin c ng knh cng nh chiu di ca CNTs (do tnh khng lin tc v khng n nh).

H thit b ch to CNTs bng phng php h quang in

I - CC PHNG PHP CH TO 2- Phng php phng in h quang

Cc k thut ch to CNTs bng h quang khc -H to CNTs bng h quang ngoi khng kh -H to CNTs bng h quang trong nit lng -H to CNTs bng h quang trong t trng -H to CNTs bng h quang vi in cc Plasma quay

H phng in h quang bng plasma quay

I - CC PHNG PHP CH TO
3- Phng php dng ngun Laze
Nguyn l: Mt chm Laze nng lng cao(xung hoc lin tc) lm bay hi mt bia Graphit trong l nhit cao khong 12000C. Kh tr He v Ne trong l gi p sut 500 torr v a hi carbon v cc lng ng. Cc nguyn t carbon lng ng li to thnh cc m c th gm fullerence v MWCNTs.

H to CNTs bng phng php chm Laze

www.themegallery.com

I - CC PHNG PHP CH TO 3- Phng php dng ngun Laze

Cc nguyn t, phn t cc bon lng ng li to thnh cc m c th gm fullerence v MWCNTs. to ra SWCNTs th bia phi c xc tc kim loi (Co, Ni, Fe hoc Y). u nhc im: - Sn phm thu c c sch cao - Kh tn km do ngun Laze phi c cng sut ln, in cc than c sch cao, lng sn phm to ra t.
Company Logo

I - CC PHNG PHP CH TO 4- Phng php nghin bi v nhit

Dng bnh thp khng r c cha cc bi thp khng r vi cng cao v vo bnh thp bt graphit tinh khit (98%). Bnh thp khng r c thi kh Argon vi p sut 300 kPa. Quay bnh bi thp khng r nghin bt graphit khong 15 gi. Sau khi nghin, bt c rt nhiu ng nano cc bon a vch. Ngi ta cho rng qu trnh nghin to ra cc ht graphit nhiu mm pht trin ng nano cc bon v khi nung nhit, cc mm pht trin thnh ng nano cc bon.