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POLYME HA MCH
hncuong@hcmus.edu.vn; hcuongpolymer@yahoo.com

Polyme ha (pht trin) mch

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Polyme ha (pht trin) bc

Polyme ha monome vinyl Ni i vinyl

t d ly/ng ly

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Polyme ha monome vinyl Polyme ha mch gc t do

Polyme ha mch cation

Polyme ha mch anion

Polyme ha monome vinyl Tm hot tnh

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Polyme ha mch gc t do
Cht khi mo gc t do

Polyme ha mch gc t do
Cht khi mo gc t do oxi ha kh

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Polyme ha mch gc t do

Polyme ha mch gc t do

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Polyme ha mch gc t do

Polyme ha mch gc t do

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Polyme ha mch gc t do

Polyme ha mch gc t do

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Polyme ha mch gc t do
Truyn mch ni phn t

Polyme ha mch gc t do
Truyn mch ni phn t

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Polyme ha mch gc t do
V sao propylen khng cho phn ng polyme ha mch gc t do?

Polyme ha mch gc t do
Yu t lp th: c kim sot bng yu t nhit ng, mt trong hai trng thi trung gian c li v nhit ng hn. Vd: s-PS > i-PS

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Polyme ha mch gc t do
Polyme ha mch gc t do dien 1,3-Butadien

Polyme ha mch gc t do
Polyme ha mch gc t do dien

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Polyme ha mch gc t do
Polyme ha mch gc t do dien Isopren Sp chnh: trans-1,4

Polyme ha mch gc t do
Phn ng t polyme ha mch gc t do styren do nhit (126C)

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Polyme ha mch gc t do
Phn ng t polyme ha mch gc t do MMA do nhit

Polyme ha mch gc t do
c im: + u: Cht khi mo tng i bn, r hn cc CKM khc ng dng ph bin trong cng nghip + Qu trnh tt mch ngu nhin Polyme c a phn tn PDI cao + Qu trnh truyn mch ngu nhin ni/lin phn t Polyme c s lng v chiu di nhnh rt khc nhau

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Polyme ha mch gc t do
LDPE

Polyme ha mch gc t do

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HDPE

LDPE

m-LLDPE

Polyme ha mch gc t do

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Polyme ha mch gc t do

Polyme ha mch gc t do
POLY(METHYL METHACRYLATE)

PMMA
CH3 n CH2 O C C OCH3 [ CH2 CH3 C] n C O OCH3

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Polyme ha mch gc t do
PMMA c dng lm sn Acrylic Elf was painted by Pete Halverson with acrylic paints

Polyme ha mch gc t do
POLY(VINYL CHLORIDE)

PVC
H n CH2 CH Cl [ CH2 C] Cl n

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Polyme ha mch gc t do

Polyme ha mch gc t do

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Polyme ha mch cation

Polyme ha mch cation

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Polyme ha mch cation

Polyme ha mch anion

Cht khi mo

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Polyme ha mch anion

Cht khi mo

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Polyme ha mch anion

C ch

Polyme ha mch anion

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Polyme ha mch anion

Polyme ha mch anion

Hot tnh monome

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Polyme ha mch anion

Phn ng khi mo anion

Polyme ha mch anion

Phn ng khi mo anion

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Polyme ha mch anion

Phn ng tt mch

Polyme ha mch anion

Tng hp copolyme khi SBS

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Polyme ha mch anion

ng dng: Keo 502 = Cyanoacrylat

Polyme ha mch anion

ng dng: Keo 502 = Cyanoacrylat

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Polyme ha mch phc phi tr

Polyme ha mch phc phi tr

Hogan v Bank tng hp PP v PE mch thng p sut thp, xc tc oxit kim loi

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Polyme ha mch phc phi tr

Polyme ha mch phc phi tr

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Polyme ha mch phc phi tr

Ziegler nghin cu phn ng cng alkyl nhm vo olefin

CKM Ziegler-Natta Karl Ziegler

Julio Natta

CKM Ziegler gm: CKM: TiCl3, TiCl4 Tr KM

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Polyme ha mch phc phi tr

Pht minh quan trng: R3Al + axit Lewis:

Pht minh quan trng: kim sot tnh iu ha

Polyme ha mch phc phi tr

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H: (a) Nhm trietyl li gn v chuyn mt nhm etyl trn nguyn t titan ti gc tinh th. Nhm vn to phc vi clov cc nguyn t cacbon; (b) Sau nguyn t titan gi ly mt phn t etylen nh cc electron ca ni i; (d) Ti to lin kt cng ha tr vi cacbon ca etylen. Cacbon cn li ca etylen lin kt vi cacbon ban u trn Ti. Lc ny Ti trng c th gi mt phn t etylen khc n t mt hng khc;

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Polyme ha mch phc phi tr

HDPE

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Polyme ha mch phc phi tr

Polyme ha mch phc phi tr

Polyme ha propen

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Polyme ha mch phc phi tr

Polyme ha mch phc phi tr

Polyme ha etylen

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C ch pht trin mch phc PT

C ch pht trin mch phc PT

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Mt s mch PP to thnh t cht khi mo metallocene

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