Cu 4: Mt H D.C2HCOOC2. 5 3 C.HCOOCH(CH. ) . B.

CH2:Thy 5glixerit trung tnh trong mi trng kim d, hai axit bo no, n chc phn ng thu A.HCOOC2Hphn2este C H O (X) c to bi glixerol v sau loichng ct hn hp sauhn km nhau 2 CU 3 5COOCH3 Bit 0,01 mol X phn ng vi 0,03 mol NaOH cho ra 2 mui c tng khi lng l 8,9 4 6 2 nguyn t cacbon. X ng c mt cht hu cbic phn v: trng gng. Bit t khi hi ca X so vi hiro nh hn 25. Cng glixerol gam. Vy X c to thc cu to ca este l A.1 axitTm cng thc 2 axit panmitic (C16) CU1: stearic (C18) ; cu to ca Y. A.CH2=CHCOOCH3. B.1 axit panmitic (C16) ; 2 axit stearic (C18) C.1 axit myristic (C14) ; 2 axit panmitic (C16) B.HCOOCH=CHCH3. D.1 axit panmitic (C16) ; 2 axit myristic (C14) C.HCOOCH2CH=CH2 2 este n chc. Bit 0,2 mol X tc dng va vi 600 ml dung dch NaOH Cu 5:Hn hp X cha D.CH3Sau phn ng thu c 25,2 gam mui khan v 4,6 gam ancol. Cng thc ca 2 este l: 0,5M. COOCH=CH2 A.HCOOC2H5 v CH3COOC6H5 B.CH3COOC2H5 v HCOOC6H4CH3 C.HCOOC2H5 v HCOOC6H5 D.CH3COOC2H5 v HCOOOC6H5 Cu 3:t chy hon ton mt lng hn hp 2 este ng ng, cho sn phm phn ng chy qua bnh ng P 2O5 d, khi lng bnh tng thm 6,21 gam, sau cho qua tip dung dch Ca(OH) 2 d, thu c 34,5 gam kt ta. Cc este trn thu c loi: A.No, a chc B.Khng no, n chc C.No, n chc D.Khng no a chc Cu 6:X phng ha hon ton 8,8g este bng NaOH thu c mui A v ru B. Khi nung ton b mui A vi O 2 thu c 5,3g Na 2CO3, kh CO2 v H2O. Chng ct ly ru B khan. Cho lng ru B tc dng ht vi Na thu c 6,8g mui v kh H 2 c th tch bng 1/2 th tch hi ru B phn ng (o cng iu kin nhit v p sut). Cng thc cu to ca este l: A. HCOOCH3 B. C2H5COOCH3 C. CH3COOC2H5 D. CH3COOC2H3 Cu7: iu nhn nh no sau y khng ng vi prtt? a. Prtt c cu to nn t cc a-aminaxit. b. Prtt c phn ng mu vi dd CuSO 4. c. Prtt b thu phn trong mi trng axit hoc kim. d. Prtt to kt ta khi un nng. Cu 8:T hn hp gm glixrin v hai axit C 17H31COOH, C17H33COOH c th iu ch c bao nhiu loi este (c 3 chc este). (chn p n ng) a. 4 b. 6 c. 8 d. 10 Cu 10: Hai este X, Y n chc l dn xut ca benzen v u c tng s lin kt + v l 6. X tc dng vi dung dch NaOH cho mt mui v mt anehit con Y tc dng vi dung dch NaOH th cho hai mui v nc. Cc mui u c khi lng phn t ln hn 67u. Vy cng thc cu to ca X, Y ln lt l: a. HCOOC6H4CH=CH2 v CH2=CHCOOC6H5 b. C6H5COOCH=CH2 v CH2=CHCOOC6H5 c. HOOCC6H4CH=CH2 v HCOOCH=CHC6H5 d. HCOOC6H4CH=CH2 v C6H5COOCH=CH2 Cu 11:Hai cht hu c (ch cha C, H, O) c s mol bng nhau v bng 1 mol. Cho chng tc dng va vi nhau to ra sn phm X khng tan trong nc v c khi lng nh hn tng khi lng hai cht ban u l 18 gam. Gi thit cc phn ng xy ra hon ton. Vy X thuc loi hp cht: a. Mui ca axit hu c b. Axit c. Este d. Ancol Cu 12: Mt triglixerit X c to bi glixerol v hai loi axit bo no, n chc hn km nhau 2 nguyn t C. Bit 0,01 mol X phn ng vi 0,03 mol NaOH cho ra 2 mui c tng khi lng l 8,9 gam. Vy X c to bi glixerol v: a. 1 axit stearic + 2 axit panmitic b. 1 axit panmitic + 2 axit stearic c. 1 axit oleic + 2 axit panmitic d. 1 axit linoleic + 2 axit panmitic Bi13 Thy phn este n chc X (c khi lng phn t nh hn 120u) thu c cht X 1, X2 u lm mt mu dung dch nc brom. Khi cho X tc dng vi LiAlH4 th ch to ra cht hu c Y. t chy hon ton Y, th tch kh CO2 v hi nc to thnh gp 6 ln th tch hi Y (o cng iu kin nhit v p sut). Vy tn gi ca X l: A. Vinyl fomiat B. Prop-2-en-1-yl fomiat C. Vinyl acrylat D. Anlyl acrylat Bi14 Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO 3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O 2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO 2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l:

A. CH3COOCH3 B. OHCCH2CH2OH C. HOOC-CHO D. HCOOC2H5 Bi15 un nng 0,1 mol cht hu c X vi mt lng va dung dch NaOH thu c 13,4 gam mui ca mt axit hu c Y v 9,2 gam mt ru n chc. Cho ru bay hi 127 0C v 600 mmHg thu c th tch l 8,32 lt. ( Na = 23, O = 16, H = 1). Cng thc cu to ca X l: A. C2H5OOC-COOC2H5 B. CH3OOC-CH2-COOCH3 C. CH3COOC2H5 D. CH3OOC-COOCH3 Bi16 Cho 0,13 mol hn hp X gm CH 3OH, HCOOH, HCOOCH3 tc dng va vi 0,05 mol NaOH un nng. Oxi ha ancol sinh ra thnh anehit, cho lng anehit ny tc dng h t vi Ag2O/NH3 (d) c 0,4 mol Ag. S mol ca HCOOCH3 l: A. 0,05 mol B. 0,04 mol C. 0,02 mol D. 0,08 mol Bi17 Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tc h hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l (cho H = 1, C = 12, N = 14, O = 16) A. HCOOC2H5 v CH3COOCH3. B. C2H3COOC2H5 v C2H5COOC2H3. C. C2H5COOCH3 v HCOOCH(CH3)2. D. HCOOCH2CH2CH3 v CH3COOC2H5. Bi18 Cho hn hp X gm ru metylic v hai axit k tip nhau trong dy ng ng ca axit axetic tc dng ht vi Na gii phng ra 6,72 lt H 2 (ktc). Nu un nng hn hp X (c H 2SO4 c xc tc) th cc cht trong hn hp phn ng va vi nhau to thnh 25 gam hn hp este. Cng thc ca 2 axit trong hn hp X l A. HCOOH v CH3COOH. B. C2H5COOH v C3H7COOH. C. C3H7COOH v C4H9COOH. D. CH3COOH v C2H5COOH. Bi19 Cht bo A c ch s axit l 7 . x phng ho 10 kg A, ngi ta un nng n vi dung dch cha 1,420 kg NaOH. Sau khi phn ng xy ra hon ton trung ho hn hp, cn dng 500 ml dung dch HCl 1M. Khi lng x phng (kg) thu c l A. 10,3425. B. 10,3625. C. 10,3645. D. 10,3445. Bi20 Cho 6 gam mt este ca axit cacboxilic no n chc v ru no n chc phn ng va vi 100ml dung dch NaOH 1M. Tn gi ca este l A. Propyl fomiat B. metyl fomiat C. metyl axetat D. etyl axetat Bi21 Mt este X mch h to t axit n chc v etilen glicol. Ho hi a gam X thu c th tch hi bng th tch ca 6,4g O2 ( cng iu kin). Mt khc a gam X tc dng ht vi dung dch NaOH un nng thu c 32,8g mui. Cng thc cu to ca X l: A. (CH3COO)2C2H4 B. (C2H3COO)2C2H4 C. (HCOO)2C2H4 D. (C3H5COO)2C2H4 Bi22 Mt este n chc c thnh phn khi lng m C : mO = 3 : 2. Cho este trn tc dng mt lng dung dch NaOH va thu c mt mui c khi lng bng 12/11 k hi lng este. Cng thc cu to este l: A. C2H5COOCH3 B. HCOOCH=CH2 C. HCOOC2H5 D. CH3COOCH3 Bi23 X phng ho 100g cht bo c ch s axit bng 7 cn a gam dd NaOH 25%, thu c 9,43g glyxerol v b gam mui natri. Gi tr ca a v b l: A. 49,2g v 103,37g B. 49,2g v 103,145g C. 51,2g v 103,145g D. 51,2g v 103,37g Bi24 Thu phn hon ton 0,2 mol mt este E cn dng va 100 gam dung dch NaOH 24%, thu c mt ancol v 43,6 gam hn hp mui ca hai axit cacboxylic n chc. Hai axit l:

A. C2H5COOH v C3H7COOH B. HCOOH v C2H5COOH C. HCOOH v CH3COOH D. CH3COOH v C2H5COOH Bi25 t chy 1,6 gam mt este E n chc c 3,52 gam CO 2 v 1,152 gam H2O. Nu cho 10 gam E tc dng vi 150ml dung dch NaOH 1M , c cn dung dch sau phn ng thu c 16 gam cht rn khan . Vy cng thc ca axit to nn este trn c th l: A. CH2=CH-COOH B. HOOC(CH2)3CH2OH C. HOOC-CH2-CH(OH)-CH3 D. CH2=C(CH3)-COOH Bi2 6 Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l: A. 9 B. 7 C. 8 D. 6 Bi27 E l este mch khng nhnh ch cha C, H, O, khng cha nhm chc no khc. un nng mt lng E vi 150 ml dung dch NaOH 1M n kt thc phn ng. trung ho dung dch thu c cn 60ml dung dch HCl 0,5M. C cn dung dch sau khi trung ho c 11,475 gam hn hp hai mui khan v 5,52 gam hn hp 2 ancol n chc. Cng thc cu to ca este l: A. CH3CH2CH2-OOC-CH2CH2COOCH3 B. HCOOCH3 v CH3COOC2H5 C C2H5-COO-C2H5 D CH3-CH2-OOC-CH2COOCH3 Bi28 S lng ng phn mch h phn ng c vi NaOH ng vi khi lng phn t 74 vC l: A. 2. B 3. C. 4. D5 Bi29 Trong phn ng thu phn sau: CH3COOC2H5 + H2O CH3COOH + C2H5OH. tng hiu sut phn ng (tng t l % este b thu phn), ta nn: 1.Thm H2SO4 2.Thm HCl 3.Thm NaOH 4.Thm H2O . Trong 4 bin php ny, chn bin php ng A. 1, 2 B. 3, 4 C. Ch c 4 D. Ch c 3 Bi30 un nng 4,03 kg cht bo tripanmitin vi lng d dung dch NaOH. Khi lng glixerol v khi lng x phng cha 72% mui natri pamitat iu ch c ln lt l: A. 0,41 kg v 5,97 kg B. 0,42 kg v 6,79 kg C. 0,46 kg v 4,17 kg D. 0,46 kg v 5,79 kg Bi31 Mt este ti a ba chc c to ra t mt axit v ru n chc. Khi thy phn este ny thu c 1,24 gam hn hp hai ru ng ng. Khi ha hi 1,24 gam hn hp hai ru th th tch thu c bng th tch ca 0,96 gam O2 cng iu kin. Hai ru trong hn hp l: A. c th l CH 3OH v C2H5OH hoc CH3OH v C3H7OH. B.Ch c l CH 3OH v C2H5OH. C. c th l CH 3OH v C2H5OH hoc C2H5OH v C3H7OH. D. Ch c l CH 3OH v C3H7OH Bi32 Cho 27,2 gam hn hp X gm 2 cht hu c A, B mch h c cng chc ho hc tc dng vi dung dch NaOH d, thu c sn phm gm mt mui duy nht ca mt axit n c hc khng no v 11 gam hn hp hai ancol no, n chc, ng ng k tip. t chy hon ton 13,6 gam X cn 0,75 mol O2 v thu c 14,56 lt CO2 ( ktc). Tn gi ca A v B l A. Metyl acrylat v etyl acrylat. B. Etyl acrylat v propyl acrylat C. Metyl metacrylat v etyl metacrylat D. Metyl propionat v etyl propionat Bi33 Thu phn 2,15 gam este X n chc, mch h (xc tc axit) n khi phn ng hon ton thu c hn hp hai cht hu c Y, Z. Cho Y, Z phn ng vi dung dch AgNO 3/NH3 d thu c 10,8 gam bc. Cng thc cu to ca X l: A. HCOOCH=CH-CH3.

B.HCOOC(CH3)=CH2. C. HCOOCH2CH=CH2 D. CH3COOCH=CH2. Bi34X phng ha hon ton 0,1 mol mt este no n chc bng 26 gam dung dch MOH 28% ( M l kim loi kim) ri tin hnh chng ct sn ph m thu c 26,12 gam cht lng v 12,88 gam cht rn khan. t chy hon ton cht rn ny thu c 8,97 gam mt mui duy nht . M v cng thc ca este l A. Na v CH3COOC4H9. B. K v C2H5COOC4H9. C.Na v C2H5COOCH3. D. K v C2H3COOC2H5 Bi35X phng ho hon ton 0,1 mol mt este n chc bng 180 ml dung dch MOH 1 mol/lt (M l kim loi kim). C cn dung dch thu c cht rn A. t ht cht rn A thu c 12,42 gam M 2CO3. Kim loi M l A. Li. B. Na C. K. D. Rb. Bi36 un nng 0,1 mol cht hu c A vi lng va vi dung dch NaOH thu c 13,4 gam mui ca axit hu c a chc B mch h v mt ru n chc C. t chy hon ton B cho 8,96 lt CO 2 (ktc) v 10,8 gam nc. Cng thc cu to thu gn ca A l: A. CH(COOCH3)3 B. CH3CH2OOCCOOCH2CH3 C. C2H5OOCCH2COOC2H5 D. C2H5OOCCH2CH2COOC2H5 Bi37 Cho cc cht sau: dung dch HCl, dung dch Br2, dung dch CH 3COOH, dung dch NaOH, dung dch Na2CO3, dung dch C2H5ONa, dung dch CH3COONa. C bao nhiu cht phn ng c vi phenol? A. 4 B. 6 C. 3 D. 5 Bi38 t chy hon ton 200 ml hp cht hu c X (cha C, H, O) vi 1200 mL kh O 2 (ly d). Sau phn ng th tch kh cn 1700 ml, sau khi qua dung dch H 2SO4 c cn 900 ml v sau khi qua KOH cn 100 mL. Xc nh cng thc phn t ca X, bit cc th tch kh o trong cng iu kin. A. C4H8O2 B. C3H8O C. C3H6O2 D. C4H8O Bi39 Cho 1,68 gam este X vo bnh kn dung tch 0,448lt, sau nng nhit bnh lm bay hi este X. Ngi ta thy khi este bay hi ht 273 0C th p sut trong bnh ng bng 1 a tm. Tnh khi lng phn t cuae este. A. 127 B. 254 C. 168 D. 244 Bi40 Chia hh X gm ru etylic v axit axetic (trong s mol ru nhiu hn s mol axit) thnh hai phn bng nhau. Phn th nht cho tc dng vi Na (d) thu c 5,6lt H 2 (ktc). Phn th hai un nng vi mt t H 2SO4 c ti phn ng este ha han tan, thu c 8,8 gam este. Tnh s mol ru v axit trong X. A. 0,4 mol ru v 0,1 mol axit; B. 0,8 mol ru v 0,2 mol axit; C. 0,2 mol ru v 0,3 mol axit; D. 0,6 mol ru v 0,5 mol axit. Bi41 Trong 4 cng thc phn t sau: C 3H4O2, C4H6O2, C3H6O2, C4H8O2.Chn cng thc phn t ng vi mt este m khi b thy phn th cho ta 2 cht hu c u tham gia phn ng trng gng. A. Ch c C 3H4O2 B. Ch c C4H6O2 C. C3H4O2 v C4H6O2 D. C3H6O2 v C4H8O2 Bi42 Thy phn 1 mol este X cn 2 mol KOH. Hn hp sn phm thu c gm glixerol, axit axetic v axit propionic. C bao nhiu CTCT tha mn vi X? A. 3 B. 4 C. 6 D. 12 Bi43 Pht biu no di y khng ng ? A. M ng vt ch yu cu thnh t cctriglixerit cha cc gc axit bo, no, tn ti trng thi rn B .Du thc vt ch yu cha cc triglixerit ca gc axit bo khng no, tn ti trng thi lng C. Hiro ha du thc vt lng s to thnh cc m ng vt rn D. Cht bo nh hn n c v khng tan trong nc Bi44 Hp cht hu c E mch h, ch cha mt loi nhm chc,c cng thc phn t C 8H14O4. Cho E tc dng vi dung dch NaOH thu c mt ru duy nht l CH 3OH v mt mui natri ca axit hu c F c mch cacbon khng phn nhnh. E c cng thc cu to l : A. CH3OCOCH2CH(CH3)CH2COOCH3. B. CH3OCOCH(CH3)CH(CH3)COOCH3 C. CH3OCOCH2C(CH3)2COOCH3 D. CH3OCOCH2CH2CH2CH2COOCH3 Bi45

Thu phn triglixerit X trong NaOH ngi ta thu c hn hp hai mui gm natrioleat v nat ristearat theo t l mol ln lt l: 1 : 2. Khi t chy a mol X thu c b mol CO 2 v c mol H2O. Lin h gia a, b, c l: A. b-c =4a b-c =2a b-c =3a b= c-a Bi46 t chy hon ton gam hn hp X gm hai este ng phn ca nhau cn dng 0,525 mol O 2 v thu c 0,45 mol CO2, 0,45 mol H2O. Nu cho m gam X tc dng ht vi 0,2 mol NaOH, ri kh cn dung dch to thnh cn li 12,9 gam cht rn khan. Phn trm khi lng ca este c gc axit nh hn trong X l. A. 60 B. 33,33 C. 66,67 D. 50 Bi47 Cho cc cht: C 6H4(OH)2 , HO-C6H4-CH2OH , (CH3COO)2C2H4 , CH2Cl-CH2Cl , HOOC-CH2-NH3Cl , CH3COOC6H5 . S cht c th tc dng vi NaOH theo t l mol l 1 : 2 l: A. 4 B. 3 C.5 D.6 Bi48Mt este E mch h c cng thc phn t C5H8O2. un nng E vi dung dch NaOH thu c hai sn phm hu c X, Y, bit rng Y lm mt mu dung dch nc Br 2. Kt lun khng ng v X, Y: A. X l mui, Y l ancol khng no B. X l mui, Y l anehit C. X l mui, Y l xeton D. X l ancol, Y l mui ca axit khng no Bi49 a. Cht git ra tng hp c th dng git ra c trong nc cng b.Cc triglixerit u c phn ng cng hiro c. Phn ng thu phn cht bo trong mi trng kim l phn ng mt ch iu d. C th dng nc v qu tm phn bit cc cht lng: Glixerol, axit fomic, trioleatglixerol. Nhng pht biu ng l: A. a,c,d B. b, c, d C. b,c D. a,b,c,d Bi50 C cc nhn xt sau: 1.Axit bo l axit hu c c s cacbon chn t 12 cacbo n tr nn. 2. Gim n l dung dch axit axetic c nng t 2% - 5%. 3. Khi cho 1 mol axit hu c (X) tc dng vi Na d, s mol H2 sinh ra bng s mol X v khi t chy axit X th thu c n(H2O) : nCO2 =1. Vy X l axit no n chc mch h. 4. Khi t chy hirocacbon no th ta c n(H 2O) : nCO2 >1. S nhn xt sai l: A. 4 B. 3 C. 2 D. 1