UBND TNH NINH THUN

TRNG CAO NG NGH

THI KT THC VN HA NM 2012

MN THI: HA HC THI GIAN: 45 PHT
(Khng k thi gian pht )

Cu 1: (2 )
Vit cc ng phn v c tn hp cht ancol no, n chc mch h c cng thc phn
t tng ng l C4H10O.
Cu 2: (2 )
Cn bng phng trnh phn ng oxi ha kh sau:
a) FeO + HNO3 Fe(NO3)3 + NO2 + H2O
b) Fe + H2SO4 Fe2(SO4)3 + H2S + H2O
Cu 3: (3 )
Vit cc phng trnh ha hc thc hin s chuyn ha sau (mi mi tn vit mt
phng trnh phn ng v ghi r iu kin nu c).
(1)

(2)

(3)

(4)

(5)

(6)

Al AlCl3 Al(OH)3 NaAlO2 Al(OH)3 Al2O3 Al

Cu 4: (3 )
Dng 5,85 gam mt kim loi cha bit ha tr, tc dng hon ton vi nc thu c
1,68 lt kh (ktc).
a) Xc nh tn kim loi.
b) Dn 6,72 lt kh CO2 vo dung dch trn thu c m (g) mui. Tnh gi tr m?

(Cho K=39, Ca= 40, Mg= 24, Fe= 56, C= 12, O= 16)
..HT..

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P N V THANG IM
Cu 1

p n
CH3-CH2-CH2-CH2-OH
Butan-1-ol

(2 )

CH3-CH2-CH(OH)-CH3

Butan-2-ol

CH3-CH(CH3)-CH2-OH

2-metylpropanol

CH3-C(CH3)-CH3

2-metylpropan-2-ol

Cu 2
(2 )

im
Mi ng
phn v
cch c
tn ng
c 0,5
im.

OH
Cn bng phng trnh phn ng oxi ha kh sau:
a) FeO + 4 HNO3 Fe(NO3)3 + NO2 + 2 H2O

b) 8 Fe + 15H2SO4 4Fe2(SO4)3 + 3 H2S + 12 H2O

Cu 3

(1) 2Al + 3Cl2 2AlCl3

0,5

(3 )

(2) AlCl3 + 3NaOH Al(OH)3 + 3NaCl

0,5

(3) Al(OH)3 + NaOH NaAlO2 + 2H2O

0,5

(4) NaAlO2 + CO2 + 2H2O Al(OH)3 + NaHCO3

0,5

(5) 2Al(OH)3 Al2O3 + 3H2O

0,5

(6) 2Al2O3 2Al + 3O2

0,5
1

Cu 4
(3 )

a) Gi tn kim loi cn tm l R, x l ha tr ca R
2 R + 2x H2O 2 R(OH)x + x H2
nH2= 0,075 (mol)
nR= 0,15/x (mol)
MR= 5,85x/0,15=39x
x= 1 MR= 39
Vy kim loi cn tm l Kali
b) nCO2= 0,3 (mol)
nKOH= 0,15 (mol)
T l: nKOH/ nCO2= 0,5 to mui KHCO3 v CO2 d
CO2 + KOH KHCO3
nKHCO3= nKOH= 0,15 (mol)
m KHCO3= 0,15 . 100= 15 (g)

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