116802615.

doc
Cu 21: din ly ca acid axetic CH3COOH 2M l 0,47%. Hy tnh hng s in li ca acid. (p s: 1,74 5 )
Cu 22: Hng s phn li acid HCOOH l Ka = 10-3,5. Tnh pH ca dung dch HCOOH 0,1M? (p s: Ph = 2,4)
Cu 23: Tnh pH ca dung dch NaHSO4 0,02M.rng HSO4- c Ka = 10-2 (S: pH = 2)
Cu 24: Hng s phn li ca acid benzonic C6H5COOH l 10-4,2. Tnh pH ca dd 0,1M? (S: pH = 8,6)
Cu 25: C th pha ch dd ng thi cha cc ion sau khng?
a/. Na+ , Ag+ , Clb/. Mg2+ , H+ , SO42- , NO3c/. Mg2+ , Na+ , SO42- , CO32d/. Ba2+ , K+ , SO42e/. H+ , Na+ , CO32Cu 26: c th tn ti cc dd c cha ng thi tng nhm cc ion sau y khng (b qua s in li yu v cht t
tan)
a/. HCO3- , Ca2+ ,H+ , K+
d/. NH4+ , Ca2+ , Ag+ , Brb/. Ba2+ , Na+ , OH- , HCO3e/. Cl- , HS- , Fe3+ , Na+
2+
+
2c/. Pb , NH4 , SO4 , NO3
f/. Cl- , NO3- ,S2- , Fe2+
Cau6 27: C 4 cation Cu2+, Ag+, K+, Ba2+ v 4 anion Cl-, NO3-,SO42- c th hnh thnh 4 dd no t cc ion trn, nu
mi dd ch cha 1 cation v 1anion (khng trng lp).
Cu 28: Trong 1 cc nc cha a mol Ca2+, b mol Mg2+, c mol Cl- v d mol HCO3-.
a/. Biu thc lin h gia a, b, c, d l?
b/. Nu ch dng nc vi trong nng p mol/l lm gim cng ca nc trong cc, th ngi ta thy
khi cho V lit nc vi trong vo, cng trong bnh l b nht,Biu thc lin h gia a, b v p l g? (S: V=
2b + a
)
p
Cu 29: Phi ly th tch dd HCl (V1) c pH=7 cho vo th tch dd KOH (V2) c pH=9 theo t l nh th no
V1 9
= )
c ddco1 pH=7 (S:
V2 2
Cu 30: Trn ln 50ml dd NaOH 5M vi 20ml dd NaON 30% (d=1,3 /ml). Tnh nng OH- ca dd NaOH mi
thu c (S: 6,2M)
Cu 31: Vit phng trnh ha hc sau dng phn t v ion rt gn (nu c)
a/. Pb(NO3)2 + ?
PbCl2 + i/. NaCO3 + HCl
b/. Nh4Cl + k/. NaHCO3 + NaOH
d/. MgCl + KNO3

m/. CuSO4 + Na2S

e/. Al(OH)3 + HCl

n/. FeSO4 + NaOHl

g/. HClO + KOH

p/. MgCO3 + ?
Na2CuO2 +

KOH

q/. Cu(OH)2 +

MgCl2 +

h/. Fe(No3)2 +

Cu 32: Dd A v HCl 0,3M

DD B cha NaOH 0,03M
Cho 200ml ddA tc dng vi V ml dd B so vi luong75 cn thit.
a/. Tnh V (S: 4l)
b/. Tnh khi lng kt ta thu c (S: m=11,65g)
c/. Tnh pH ca dd sau phn ng (S: pH=11,98)
Cu 33: Trn V lt dd HCl c pH=5 vi V lt dd NaOH c pH=7 ta thu c dd A c pH=8. Tm quan h gia V
V
9
=
v V (S:
)
V ' 11

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Cu 34: Tnh nng mol/l ca cc cht trong dd sau phn ng khi ta cho:
a/. 20 ml dd NaOH 2M tc dng vi 300 ml dd ZnSO4 0,2M (S: [Na2ZnO2]=[Na2SO4]=0, , [NaOH]d=0,5)
b/. 4 lt dd Ba(OH)2 0,02M tc dng vi 1lt dd ZnSO4 0,05M (S: [BaCl2]=0,001M , [BaZnO2]=0,006M)
c/. 100 ml dd KOH 2M tc dng vi 400ml dd ZnSO4 0,2M (S: [K2ZnO2]=[ZnO22-]=0,04M,
[K2SO4]=[SO42-]=0,16M)
d/. 500ml dd NaOH 3M tc dng vi 300ml dd ZnSO4 1M (S: [NaOH]d=0,375M , [Na2SO4]=
[SO42-]=0,375M)
e/. 2 lt dd Ba(OH)2 0,2M tc dng vi 500ml dd 0,5M (S: [BaZnO2]=6.10-3M)
Cu 35: Cho V ml dd NH 2M tc dng vi 400ml dd ZnSO 0,5M ta thu c mt kt ta A. em nung A n
khi lng khng i th c 12,15g cht rn. Tnh V.
(S: TH1: V=0,15 lt , TH2: V=0,25 lt) 2M tc dng vi 200ml dd KOH 3M ta thu c mt kt ta A. em
nung A n khi lng khng i th thu c 16,2g cht rn.
a/. Tnh V (S: V=0,125 lt)
b/. Tnh th tch dd KOH 3M ni trn phi rt vo dd ZnCl2 thu c lng kt ta ln nht (S: 83,3
ml)37: Cho 20ml dd AlCl3 tc dng vi 00ml dd NaOH 3M ta thu c mt kt ta em nung n khi lng
khng i th c 15,3g cht rn.
a/. Hy tnh nng mol/l ca dd AlCl3 (S: 1,5M)
b/. Tnh th tch dd NaOH thu c kt ta ln nht v th tch dd NaOH nh nht ta phi cho vo 250ml
dd AlCl3 khng c kt ta. (V1=0,375 lt , V2(t nht)=0,5 lt)
Cu 38: Rt 30ml ddA gm KO2 0,8M vKOH 0,2M vo V ml dd 4 0,5M thu c kt ta B. Nung B n khi
lng khng i th c 10,2g cht rn.
a/. Tnh TH2: V=0,42 lit)
b/. Tnh th tch V thu c khi lng kt ta ln nhtV nh nht khng c kt ta (S: V1=0,3 lt
Cu 39: Cn ly bao nhiu gam tinh th CuSO4.7H2O v bao nhiu gam dd CuSO4 8% c 80g dd CuSO4 16%
(S: m0g , mdd CuSO4 8%=240g)
Cu 40: Xc nh lng st() sunfat ngm nc FeSO4.7H2O cn ha tan trong 37,2g H2O c dd FeSO4 3,8
(S: 27,62g)
Cu 41: Cn ha tan 20g SO3 vo bao nhiu gam dd H2SO4 59% c dd H2SO4 8,4% (S: 300g)

B:TRC NGHIM
Cu 1: C 1 dd cht in li yu, khi tng nng cht in li th:
A: in li tng C: in li gim
B: din li khng tD: in li v hng s in li u tng
Cu 2: Phn ng gia acid v baz l phn ng:
A:C s cho proton
:C s cho nhn electron
B:Acid tc dng vi oxit baz :C s cho nhn proton
Cu 3: Chn pht biu sai:
Trong cc tiu phn t NH4+ - , Na+ , Fe(H2O)3+ , H2O theo thuyt Bronsted:
A:Acid l tiu phn NH4+ , Fe(H2O)3+
C:Lng tnh: HS2B:Baz l cc tiu phn CO3 ,
D:Trung tnh l cc tiu phn H2O , Na+
Cu 4: Trong cc phn ng sau: HSO4- + H2O
H3O+ + SO42(1)
H3COOH + OH (2)
Nc th hin vai tr:
A:Acid (1) v baz (2)
C: Acid c (1) v (2)
B:Acid (2) v baz (1) D:Baz c (1) v (2)
Cu 5: Dy cc dd c cng nng mol c sp xp theo chiu tng dn v pH l:
A:H2S , KCl , HNO3 , KOH
C:KOH , KCl , H2S , HNO3
B:HNO3 , H2S , KCl , KOH D:HNO3 , KOH , NaCl , H2S
Cu 6: Cp cht no sau y khi cho vo nc khng lm thay i pH ca dd
A: HCl , H2SO4
B: KCl , NaNO3
C: NH4Cl , AlCl3
D: NaHSO4 , Na2C
Cu 7: Cho 3 dd c cng nng mol/l: ), NaOH(2), Ba(OH) pH ca dd ny c xp theo dy:
A: (1) < (2) < (3)
B: (3) < (2) < (1)
C: (2) < (3) < (1)
D: (2) < (1) < (3)
Cu 8: Nh t t dd AlCl3 vo ng nghim ng dd NaOH . Hin tng quan st c:
A:Xut hin kt ta mu keo trng
C:Xut hin kt ta ri tan ngay

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B:Xut hin kt ta keo trng v tng dn n cc i, sau tan dd tr nn trong sut D:Xut hin kt ta xanh
Cu 9: Dd cha ion khng phn ng vi cc dd cha cc ion hay phn ng vi cc cht rn no di y:
A: HCO3- , HSO3- , AlO2C: CaCO3 , SO32- , OH- , S2B: Cu(OH)2 , FeO , CuO , Al2O3 D: FeS2 , CuS , BaSO4
Cu 10: Pht biu no sau y khng chnh xc:
A:Dd NH4Cl , CuCl2 , < 7
C:Dd NaCl , KNO3 , H2O u c pH = 7
C:Dd NaHCO3 , KHS , NaHSO4 c pH < 7
D:Dd Al(NO3)3 ,FeCl2 , CuSO4 c pH < 7
Cu 11: nhn bit c dd ng trong 4 l khc nhau l NH4Cl, Na2SO4, (NH4)2SO4 ta ch cn dng thm mt
trong 4 cht
A:Dd AgNO3
B:Dd BaCl2
C:Dd NaOH
D:Dd BaCl2
Cu 12: C 4 l mt nhn (dd): MgCl2, AlCl3, FeCl3c th dng 1 ha cht duy nht no sau y nhn bit
chng:
A:Dd HCl d
B: KCl
C: H2SO4
D: Dd NaOH
Cu 13: C 4 mui FeCl3, CuCl2v ZnCl2. Nu thm t t dd NaOH cho n d vo 4 mi trn, sau thm tip
NH3 d th s kt ta thu c l:
A: 1
B: 2
C: 3
D: 4
Cu 14: Tp hp ion no di y c th cng tn ti trong cng 1dd:
A: Mg2+ , Ca2+ , NO3- , OHC: HS- , OH- , HCO3- , H+
B: Fe2+ , Fe3+ , NO3- , CO32D: Na+ , SO42- , H+
Cu 15: Dd NaOH 0,1M, dd HCl 0,001M. Vy pH ca 2 dd trn ln lt l:
A: 1 v 2
B: 13 v 2
C: 2 v 13
D: 0,1 v 0,01
Cu 16: trn 200ml dd HCl 10-3M vi 200ml dd KOH c pH=2 th pH ca dd sau khi pha trn l D: 8
Cu 17: thu c 1 lit dd pH= sau khi pha trn th t l th tch ca dd HCl 10-3M vi dd KOH 10-3M l:A: 1:2
B: 11:9
C: 9:11
D: 2:15
Cu 18: Th tch dd KOH 0,001M cn pha thnh 1,5 lt dd c pH=9 l:A: 0,015 lt
B: 0,02 lt
C: 0,0015 lt
D: 0, lt
Cu 19: Thm t t dd H2SO4 98% vo nc v iu chnh c 1 lt dd [H+] ca dd l:
A: 2M B: 3M
C: 2,5M
D: 4M
Cu 20: Cn phi thm vo lt dd H2SO4 2M bao nhiu lt dd NaOH 1,8M thu c dd c pH=13
A: 1,235 lt
B: 1,25 lt
C: 1 lt
D: 0,9 lt
Cu 21: Th tch HNO3 10% (D=1,1g/ml) cn trung ha dd 200ml ,75M l:
A: B: 85,9 ml
C: 85 ml
D: 90ml
Cu 22: Trn 20ml dd hn hp gm HCl 0,08 mol/l v H2SO4 0,01 mol/l vi 250 ml dd NaOH a mol/l c 5 dd
c pH=12. Vy a c gi tr l:
A: 0,12M B: 0,13M
C: 0,14M
D: 0,15M
Cu 23: Cho 2
0ml dd HNO3 c pH=2. Nu thm 300ml dd H2SO4 0,05M vo dd trn th dd mi thu c c pH bng bao nhiu?
A:C: 3
D: 1,19
Cu 24: Mt dd A gm hn hp 2 acid HCl v H2SO4. trung ha 10ml dd A cn dng 40ml dd NaOH Mt khc
nu ly ml dd A cho tc dng vi 1 lng va , ri c cn dd thu c 13,2g mui khan. Vy nng mol/l ca
2 acid trong hn hp l:
A: 0,8M v 0,6M
B: 0,6M v 0,8M
C: 0,8M v 0,7D: 0,9M v 1,5M
Cu 25: Cho CO2 tc dng vi NaOH theo t l mol nCO2:nNaOH=1:3
A: pH=7B: pH<7C: pH>7 D: Kt qu khc
Cu 26: Trong cc oxit sau: CaO, Al2O3, SO2. Hy cho bit cht no ch phn ng c vi dd bazv cht no
phn ng c vi c dd acid ln dd baz. Chn kt qu ng theo th t trn:
A: SO2 , CaO B: SO2 , Al2O3 C: CuO , Al2O3 D: CuO , SO2
Cu 27: Nhm hidroxit l cht lng tnh c th tc dng vi cc acid v baz no trong 4 cht sau: Ba(OH)2,
NH4OH,, H2CO3.
A:C 4 cht trn NH4OH , H2CO3 C: Ba(OH)2 , H2SO4 Ch vi H2SO4
Cu 28: Tp hp ion no sau y c cha ion i khng vi io (nu coi rng 2ion gy ra phn ng trao i hay
trung ha l 1 cp ion i khng).
A: HCO3-, HSO3-,
C: Ba2+, Na+, NO3-, Cl2+
+
2B:CA , K , SO4 ,
D:Tt c 3 trng hp trn

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Cu 29: Cho dd X c cha cc ion sau: Ba2+, H+, Cl-. Mun tch c nhiu cation ra khi dd ny m khng a
ion no khc vo dd, ta c th cho dd X tc dng vi cht no sau y:
A: K2CO3 va
B: Na2CO3 va
C: NaOH va
D: Na2SO4 va
Cu 30: C 4 dd NaOH, HCl, H2SO4 ng trong cc l b mt nhn. Thuc th phn bit 3 dd ny l:
A:Na2CO3B:Al
C:CaCO3( phn)
D:Qu tm
Cu 31: Cho Cl2 hp th hon ton vo dd cha 2 mol NaOH. pH ca dd thu c l:
A:7
B:0
C:<7
D:>7
Cu 32: Cho 1 g NaOH rn tc dng vi dd cha 1HCl. Dd sau phn ng c ni trng:
A:acid
B:baz
C:trung tnh
D:lng tnh
Cu 33: Dd cha 0,063g HNO3 trong 1 lt c pH l
B: 3
C: 2,7
D: 2,5
Cu 34: Phi thm bao nhiu ml dd HCl 1M vo 90ml nc c dd c pH=1?
A: 10mlB: 20ml80ml
D: 100ml
Cu 35: Phi thm bao nhiu ml nc vo 10ml dd NaOH c pH=13 c 1dd c pH=12?A: 10mlB: 20mlC:
90mlD: 50ml
Cu 36: Thm 900ml nc vo 100ml dd HCl c pH=2 thu c dd A. Hi dd A c pH bng bao nhiu?0g
ACu 37: Trong 100ml dd A c ha tan 2,24l kh HCl (ktc). Tnh pH ca dd A
Cu 38: Cho a mol sc vo dd cha a mol KOH. Vy dd thu c c mi trng:
A: Acid
B: Baz
C: Trung tnh
D: Lng tnh
2+
+
Cu 39: Mt dd cha 0,02 mol Cu , 0,03 mol K , x mol Cl v y mol SO42-. Tng khi lng cc mui tan c
trong dd l 5,45g. Ga tr ca x v y ln lt l: (Trch TSC-2007-Khi A)
A: 0,01 v 0,03
B: 0,02 v 0,05
C: 0,05 v 0,01
D: 0,03 v 0,02
Cu 40: Trn 100ml dd gm Ba(OH)2 0,1M vi 400ml dd gm H2SO4 0,0375M v HCl 0,125M thu c dd X.
Ga tr pH ca dd X l:
A: 2
B: 1
C: 6
D: 7
(Trch TSH-C-2007-Khi B)
Cu 41: Cho m gam hn hp Mg v Al vo 2ml dd X cha hn hp acid HCl 1M v acid H2SO4 0,5M thu c
5,2 lt H2 (ktc) v dd Y (coi th tch dd khng i) dd Y c pH l: (Trch TSH-C-2007-Khi A)
A: 7
B: 1
C: 2
D: 6
Cu 42: Cho 1 mu hp kim Na-Ba tc dng vi nc d thu c dd X v 3,36 lt H2 (ktc). Th tch dd acid
H2SO4 2M cn dng trung ha dd X l:
A: 150ml
B: 75ml
C: 60ml
D: 30ml
(Trch TSC-2007-Khi A)
Cu 43: Thm m gam kali vo 30ml dd cha Ba(OH)2 0,1M v NaOH 01M thu c dd X. Cho t t dd X vo
20ml dd Al2(SO4)3 1M thu c kt ta Y. thu c kt ta Y ln nht th gi tr ca m l:
A: 1,95
B: 1,17
C: 1,71
D: 1,59
(Trch TSC-2007-Khi A)
Cu 44: Bit hng s phn li ca ion NH4+ l Ka=10-9,24. Vy thu c 25ml dd c pH=5 th s gam NH4Cl l:
A: 2,32 g
B: 2,56 g
C: 4,64 g
D: 1,16 g
-3,9
Cu 45: Acid nitr c hng s phn li acid l Ka=10 . Vy pH ca dd HNO2 0,021M l:
A: 2,35
B: 2,69
C: 2,61
D: 3,01