116802636.doc S IN LI ( t 3 ) - LP 11NC Cu 1: a) Thm vo 1 lt dd CH3COOH 0,1M ( Ka=1,58.105 ) mt lng HCl l 103 mol ( th tch dd khng thay i).

Tnh pH ca dd thu c? b) Dung dch NH3 1M c = 0,43%. Tnh hng s cn bng Kb v pH ca dd . Cu 2: a) C dd CH3COOH 0,1M ( Ka = 1,58 .105 ). Cn thm bao nhiu gam CH3COOH vo 1 lt dd in li ca axit gim i mt na ( xem nh khng c s bin i th tch dung dch )? Hy tnh pH ca dd mi ny. b) Trn 200ml dd gm HCl 0,1M v H2SO4 0,05M vi 200ml dd Ba(OH)2 c nng a mol/l thu c m gam kt ta v 500ml dd c pH =13. Tnh a v m? Cho bit trong cc dung dch vi dung mi l nc, tch s nng ion [H+]. [OH] = 1014 ( mol2/l2). Cu 3: Cho dd NaOH c pH= 12 (dd A) a) Cn pha long dd A bao nhiu ln thu c dd NaOH c pH= 11? b) Cho 0,5885g mui NH4Cl vo 100ml dd A v un si dd sau lm ngui v thm mt t phenolphtalein. Hi dd c mu g? Cu 4: a) C dung dch NH3 102M, Kb ca NH3 l 1,8 .105. Nu trong 100ml dd trn c ho tan 0,535g NH4Cl th pH ca dd l bao nhiu? 3,75 b) C dung dch cha ng thi HCOOH 0,01M v HCOONa 0,001M. Tnh pH ca dd . Cho bit K HCOOH = 10
5 Cu 5: Tnh pH ca dd CH3COONa 0,1M. Bit K CH 3COOH = 1,8.10 . Cu 6: a) Trn 100ml dd Ba(OH)2 0,5M vi 100ml dd KOH 0,5M c dd A. Tnh pH ca dd A? b) Tnh th tch dd HNO3 10% ( D = 1,1g/ml) trung ho dd A? Cu 7: Mt dung dch A gm hn hp 2 axit HCl v H2SO4. trung ho 10ml dd A cn 400ml dd NaOH 0,5M. Mt khc nu ly 100ml dd A em cho tc dng vi mt lng NaOH va , ri c cn dd thu c 12,95g mui khan. Tnh nng mol/l ca ion H+ trong mi dd axit? Cu 8: Cho 200ml dd HNO3 c pH=2. Tnh khi lng HNO3 c trong dd? Nu thm 300ml dd H2SO4 0,05M vo dd trn th dd thu c c pH l bao nhiu? 2 2 Cu 9: Dung dch A cha cc ion Na+ ( a mol) ; HCO3 ( b mol ); CO3 ( c mol ) v SO4 (d mol ). to kt ta ln nht ngi ta phi cho dd A tc dng vi 100ml dd Ba(OH)2 nng x mol/l. Tnh gi tr x ? Cu 10: Cho 27,4g Ba vo 500g dd hn hp gm (NH4)2SO4 1,32% v CuSO4 2,00%. Sau khi phn ng kt thc (un nh ui ht kh) ta thu c kh A, kt ta B v dd C. a) Tnh th tch kh A ktc? b) Lc b kt ta B ra sch ri nung nng nhit cao n khi lng khng i th thu c bao nhiu gam cht rn? c) Tnh C% ca dd C? Cu 11: Dung dch axit yu HClO 0,1M ( = 5. 104 ) a) Tnh pH v CM cc ion H+, OH trong dd trn. b) pH ca dd thay i nh th no, nu: + Thm vo dd mt lng KOH + Thm vo mt lng NaClO + Thm 1 lng Cl2 vo dd. Cu 12: Cho A l dd HCl 0,1M a) Tnh pH ca dd A? b) Pha long dd A thnh 100 ln thu c dd B. Tnh pH ca dd B? c) Pha long dd A n ln thu c dd C c pH = 4. Tnh n? Cu 13: Cho dd A c ho tan cc mui NH4HCO3, Ca(HCO3)2, NaHCO3, CaCl2. un si dung dch mt thi gian phn ng xy ra hon ton thu c dd B. Trn ln mt t dd B vi dd Ba(OH)2 thy to thnh kt ta v c kh thot ra. a) So snh pH ca dd A vi 7. Vit phng trnh phn ng v m t hin tng qua st c khi un si dd A? b) Trong dd B c nhng ion no ? Vit ptp xy ra khi trn ln B vi dd Ba(OH)2 ( dng phn t v ion thu gn) c) Nu trn ln B vi dd MgSO4 c thy kt ta to thnh hay khng? d) Nu trn ln B vi dd HCl th hin tng quan st c nh th no? e) Thi t t mt lung kh SO2 vo dd B th xy ra hin tng g? Vit phng trnh phn ng. + Cu 14: Cho cn bng in li ca CH3COOH trong nc: CH 3COOH CH3COO + H . Cn bng s chuyn dch v pha no nu: a) Thm axit HCl vo? b) Thm NaOH vo? c) Pha long dd bng nc ct? Cu 15: Vit phng trnh phn t ca cc phng trnh ion sau: 2+ 2 2+ 2 + a) Pb + SO4 PbSO4 b) Mg + OH Mg (OH ) 2 c) S + 2 H H 2 S

116802636.doc + + 2+ 2+ 3 d) NH 4 + OH NH3 + H2 O e) 2 H 3O + Mg (OH )2 Mg + 4 H2 O f) 3Ca + 2 PO4 Ca3 ( PO4 )2 Cu 16: Cn bng cc phng trnh ion sau: + 2+ a) Cu + H + NO3 Cu + NO2 + H 2 O b) Al2O3 + OH AlO2 + H2 O
+ 3+ c) FeO + H + NO3 Fe + NO + H2 O + 2 3+ d) FeCO3 + H + SO4 Fe + CO2 + SO2 + H2 O + 2 2+ 2 e) MnO4 + H + SO3 Mn + SO4 + H2 O Cu 17: Vit phng trnh phn t v ion thu gn xy ra khi cho tng cp cht sau tc dng vi nhua v t cho bit cht no l axit, cht no l baz? a) Zn(OH)2 + HNO3 b) Al(OH)3 + H2SO4 c) Zn(OH)2 + NaOH d) Al(OH)3 + NaOH e) NaHS + HBr f) NaHS + KOH g) KHCO3 + Ba(OH)2 d Cu 18: Cho 3 bnh mt nhn l A gm KHCO3 v K2CO3; B gm KHCO3 v K2SO4; C gm K2SO4 v K2CO3. Ch dng dd BaCl2 v dd HCl nu cch nhn bit mi bnh mt nhn trn v vit cc phng trnh phn ng. Cu 19: D on hin tng quan st c khi nh t t tng git dd HCl vo bnh cha dd Na2CO3 n d v khuy u; hoc lm ngc li ( cho Na2CO3 vo dd HCl ). Gii thch bng phn ng ho hc. Vn dng: Tnh khi lng mui v nng ion trong dd thu c trong 2 trng hp sau y: a) Cho t t 800ml dd HCl 0,625M vo 300ml dd Na2CO3 1M, khuy u. b) Cho 300ml dd Na2CO3 1M vo 800ml dd HCl 0,625M. Cu 20: Ho tan 7,2g mt hn hp gm 2 mui sunfat ca 2 kim loi A( ho tr 2) v B ( ho tr 3) vo nc c 2 dd X. Thm vo dd X mt lng BaCl2 va kt ta ht ion SO4 thu c 11,65g BaSO4 v dd Y. a) Tnh tng khi lng 2 mui clorua trong dd Y? b) Xc nh A,B bit s mol mui A gp i s mol mui B v t l khi lng mol ca B: A=7:8. Cu 21: C V lt dd cha 2 axit l HCl a M v H2SO4 b M. Cn c x lt dd cha 2 baz l NaOH c M v Ba(OH)2 d M trung ho va hai dd axit trn. Cc cht trn u c = 1. Lp biu thc tnh x theo V, a, b ,c, d? Cu 22: Trn ln 100ml dd NaHSO4 1 M vi 100ml dd NaOH 2M c dd A. a) Vit phng trnh phn t v phng trnh ion thu gn. b) C cn dd A th thu c hn hp nhng cht no? Tnh khi lng ca mi cht? c) Nu thay dd NaOH bng dd KOH c cng nng , cng th tch th khi lng ca mi cht l bao nhiu? Cu 23: Trn dd H2SO4 0,05M vi dd HCl 0,1M theo t l th tch 1:1 c 200ml dd A. a) Tnh pH ca dd A? b) Cn bao nhiu ml dd hn hp B cha ng thi NaOH 0,1M v KOH 0,05M trung ho dd A? + Cu 24: Cho cn bng sau: CH 3COOH CH3COO + H . Th nhim cho bit dd CH3COOH 1M c [H+] = 103M a) Tnh in li ? b) Nu pha long dd ni trn 100ln th c dd mi c [H+] = 4,08 .104 M. hy tnh in li ca CH3COOH trong dd? Rt ra kt lun: S pha long nh hng n in li ca cht in li yu nh th no? c) Nu thm vo dd CH3COOH ban u mt lng mui CH3COONa th nng [H+] v [OH] trong dd s tng hay gim. Ti sao? 2 Cu 25: Mt dd cha cc ion : K+; Mg2+; Al3+ v SO4 . Cho 75ml dd ny tc dng vi dd BaCl2 d, to thnh 55,92g cht kt ta. Bit cc cation c trong dd theo t l mol: nK + : nMg 2+ : nAl 3+ = 1: 2 :1 . Hy xc nh nng mol cc mui?

Cu 26: Hp th 4,48 lt kh CO2 (ktc) vo 0,5 lt dd c ho tan hai cht l NaOH 0,4M v KOH 0,2M c dd X. Chia X thnh 2 phn bng nhau: - Phn 1: trn ln vi 0,5 lt dd Ba(OH)2 0,1M. Tnh khi lng kt ta to thnh? - Phn 2: trn vi 0,5 lt dd BaCl2 0,1M. Tnh lng kt ta to thnh? Cu 27: a) Vit phng trnh phn ng di dng phn t v ion thu gn khi cho Ba(HCO3)2 phn ng cc dd HNO3, Ca(OH)2, Na2SO4, KHSO4. b) V sao dd NaHCO3 trong nc c tnh kim v khi un nng dd ny th tnh kim li mnh hn? Vit ptp. Cu 28: Tnh pH ca cc dd sau, bit NH3 c pKb = 4,8. a) Dd NH3 1M b) Dd NH4Cl 0,1M c) Dd cha ng thi NH3 1M v NH4Cl 0,1M d) Dd to thnh khi trn 50ml dd NH3 1,3M v 50ml dd HCl 0,8M ( gi s th tch thu c l 100ml) Ht..

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