Welcome to Process Design in Chemical Engineering

Process Simulation
M phng qu trnh ha hc l g ? S liu no cn thit cho qu trnh m phng? Chng trnh m phng l g? Phng php m phng mt qu trnh s dng computer (PC & Laptop) Mc tiu: Hiu r v m phng v m phng trong cng ngh ha hc Bit cch s dng phn mm Hysys/Unisim S dng Hysys/Unisim m phng cc thit b, qu trnh chnh

What is Chemical Process Simulation ?

M phng qu trnh vn hnh ca mt nh my ha hc, hoc mt qu trnh ch bin s dng m phng Steady State v Dynamic
bit

Water (100 kg/s, 1atm, 95oC

Ethanol+Water (50:50, 150 kg/s, 1atm, 83oC
Mun bit

Input-1 Input-2

Process Unit (Mixer)

Output

Cc thng s chnh
( bit & cha bit)
Input streams: o p sut (P) o Nhit (T) o Thnh phn dng (x) o Tng lu lng (F) Thng s thit b o Trng thi n nh o c bo n (q = 0) o Khng b r r Output stream o p sut? o Lu lng dng tngr? o Lu lng dng cu t? o Thnh phn cu t? o Nhit ? Phn tch pha o Dng vo v dng ra Thng s vt l khc: nht, t trng, ca cc dng

What did We do ?
Cung cp cc thng tin: thng s u vo thng s thit b: trn on nhit, khng r r, S dng cc m hnh ton hc m t ton b qu trnh cng ngh: Thng tin cha bit s dng MB, EB, VLE v so snh cc property correlations M phng qu trnh ha hc (hn hp n nh) Thc hin m phng: Thi gian thc hin cn thit Cc li c th mc phi chnh xc ca kt qu nhn c

Qu trnh m phng s dng Hysys/Unisim

Hysys/Unisim l g? Hysys/Unisim c th lm g? Cc cng c trong Hysys/Unisim? Cch s dng Hysys/Unisim? Mc ch ca bi ging:

M phng cc qu trnh trong cng nghip

Cc ng dng trong Hysys/Unisim, cch s dng, cc module, cc tin ch

Bit cch s dng tng Module trong Hysys/Unisim

Sau khi m phng s nhn c s cng ngh bng Hysys v kt qu m phng r rng

Advantages of Simulator
Giao din ha p Khng phi lp trnh S dng cc gi property packages c sn gip tit kim thi gian v cng sc Thu c nhiu kt qu c gi tr ln C th thc hin nhiu chc nng

Hysys Modules
Steady State Reactor (general, CSTR, PFR) Movers (Pump, compressor, expander, valve) Mixer Splitter (Tee) Exchangers (Heater/ Cooler, S & T, LNG) Flash Drums (2-phase (VL), 3-phase (VLL)) Separator (Component splitter, distiller, Absorber, Cyclone, Gas filter, Extractor) Pipe segment Set Adjust Recycle Balance Spreadsheet Dynamic

ChemicoPhysical

Tank Furnace Air Cooler

Logical

PID Controller

Giao din ban u

To Case thng thng

Ch dng cho m phng thp chng

Cc Case s dng gn y

Simulation Basis Manager

Thit lp cu t Xut nhp file lu thnh phn

Cc Tab

La chn cc cu t

To cu t gi

To cu t gi

Thit lp tnh cht ca cu t gi

La chn Fluid Packages

Thit lp h nhit ng Xut nhp file lu h nhit ng

La chn Fluid Packages

La chn m hnh nhit ng ph hp ng vai tr quan trng ti chnh xc kt qu m phng Cc thng s xc nh t h nhit ng
Hng s cn bng pha K Enthanpi ca pha lng v pha hi Entropy ca pha lng v pha hi T trng ca pha lng v pha hi

 Cc

Dng theo phng php hiu chnh

(Generalized Correlation Methods): GS, CS,IGS, Dng phng trnh trng thi (Equation of State Methods): SRK, PR, SRKS, BWRS,... Dng theo hot (Liquid Activity Methods): NRTL, UNIQUAC, Dng c bit (Special Packages): AMINE, ALCOHOL, SOUR,

m hnh nhit ng

C s la chn h nhit ng:

c trng nhit ng ca h (h s K)
Thnh phn hn hp Phm vi nhit p sut Tnh sn c ca cc thng s ca h

La chn H nhit ng

La chn EOS

Thit lp cc phn ng

Thit lp phn ng

CC DNG PHN NG
Conversion : phn ng tnh ton da vo chuyn ha Equilibium: phn ng tnh ton da trn hng s cn bng K Heterogeneous Catalytic Kinetic: phn ng tnh ton da trn hng s tc phn ng Simple Rate

Thit lp phn ng

H s t lng

 chuyn ha

chuyn ha

Thit lp n v tnh
Tools / Preferences / Variable tab

Vo mi trng m phng

Vo mi trng m phng

Hysys Module Palette

General Reactor
Dng nguyn liu, dng sn phm Cung cp P hoc P ca dng sn phm Thit lp dng nng lng Khng t Q: phn ng on nhit

Q cn thit hoc T ca dng sn phm

T phn ng chnh l T ca dng sn phm Conversion: khi bit chuyn ho Equilibrium: dung cho phn ng Equilibrium Gibbs: phn ng Equilibrium

General Reactor: Conversion

General Reactor: Conversion

General Reactor: Conversion

General Reactor: Conversion

Hysys tnh ton nh th no?

Mi Module trong Hysys l mt chng trnh tnh ton cn thng s ban u (ca dng vo v thit b), trc khi tnh ton dng ra cho module Ch tnh ton mt module ti mi thi im Ngay khi cc thng s ban u c nhp vo cho module, Hysys s tnh ton cho module S1

S2

S3

S4

S5

If we specify S2 fully(A unsolved)

If we specify S4 fully

S1

S2

S3

S4

S5

What will happen, if we specify S1 fully in the first (original) BFD?

V d
Mt s c dng tun hon n gin

Reaction A B
Feed A Reactor
Recycle Loop

Separation Unit
Purge

Unreacted A
Dng bit Dng cha bit

Xy dng s khi (BFD)

Reaction A B B Separation Unit Purge

Feed A

Reactor
Recycle Loop

Unreacted A
bit cc thng s ca dng Feed, nhng Hysys vn cha th tnh ton? Ti sao? Lm th no kch hot Hysys ?

S dng cng c Recycle

Component Splitter

Mixer

Reactor

Recycle

Tee

S dng cng c Recycle D on cc thng s ca dng ra bit specs ca Mixer, Hysys c th tnh g?

Hysys tnh ton Mixer

Mixer

Reactor

Component Splitter

Recycle

Tee

Hysys tnh ton cho thit b phn ng

Mixer

Reactor

Component Splitter

Recycle

Tee

Hysys tnh ton component splitter

Mixer

Reactor

Component Splitter

Recycle

Tee

Hysys tnh ton Tee

Mixer

Reactor

Component Splitter

Recycle

Tee

Recycle l cng c khng thc t, Lm th no dng trc v sau Recycle ging nhau ph thuc vo suy on ban u Recycle s c mu vng

Thit lp dng vt liu

Composisions
Mol Frc. C1
C2

Mol Frc. iC5

nC5

0.330
0.143

0.069
0.059

C3
iC4

0.101
0.098

nC6
C7+

0.078
0.042

nC4

0.080

Phase Envelope

Nh tay ng giao din

Tr li PFD
C 3 cch:
Bm vo phm

Bm vo phm Bm vo Tool PFD, chn View