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.com Cu 1: t chy hon ton 8,0 gam hn hp X gm hai ankin (th kh nhit thng) thu c 26,4 gam CO2. Mt khc, cho 8,0 gam hn hp X tc dng vi dung dch AgNO3 trong NH3 d n khi phn ng hon ton thu c lng kt ta vt qu 25 gam. Cng thc cu to ca hai ankin trn l A. CHCH v CH3-CCH. B. CHCH v CH3-CH2-CCH. C. CHCH v CH3-CC-CH3. D. CH3-CCH v CH3-CH2-CCH. Cu 2: Thc hin phn ng crackinh butan thu c mt hn hp X gm cc ankan v cc anken. Cho ton b hn hp X vo dung dch Br2 d thy c kh thot ra bng 60% th tch X v khi lng dung dch Br 2 tng 5,6 gam v c 25,6 gam brom tham gia phn ng. t chy hon ton kh bay ra thu c a mol CO2 v b mol H2O. Vy a v b c gi tr l: A. a = 0,9 mol v b = 1,5 mol B. a = 0,56 mol v b = 0,8 mol C. a = 1,2 mol v b = 1,6 mol D. a = 1,2 mol v b = 2,0 mol Cu 3: Khi nung butan vi xc tc thch hp thu c hn hp T gm CH 4, C3H6, C2H4, C2H6, C4H8, H2 v C4H10 d. t chy hon ton hn hp T thu c 8,96 lt CO2 (o ktc) v 9,0 gam H2O. Mt khc, hn hp T lm mt mu va ht 12 gam Br2 trong dung dch nc brom. Hiu sut phn ng nung butan l A. 45%. B. 75%. C. 50%. D. 65%. Cu 4: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Nung X vi Ni sau mt thi gian thu c hn hp kh Y c t khi so vi He l 5. Hiu sut phn ng hiro ha l: A. 50% B. 20% C. 40% D. 25% Cu 5: Hn hp X gm mt hirocacbon th kh v H2 (t khi hi ca X so vi H2 bng 4,8). Cho X i qua Ni un nng n phn ng hon ton thu c hn hp Y (t khi hi ca Y so vi CH 4 bng 1). CTPT ca hirocacbon l A. C3H6 B. C2H2 C. C3H4 D. C2H4

Cu 6. Khi Crckinh V lt butan c hn hp A ch gm cc anken v ankan. T khi hi ca hn hp A so vi H2 bng 21,75. Hiu sut ca phn ng Crckinh butan l bao nhiu? A. 33,33% B. 66,67% C. 46,67% D. 50.33%

Cu 7: C 49,125 gam cao su buna-S phn ng va ht vi 30 gam brom trong CCl4. T l s mt xch stiren v butaien trong loi cao su trn tng ng l A. 1: 2 B. 2: 3. C. 2: 1. D. 1: 3. Cu 8: Hn hp kh X c th tch 4,48 lt (o ktc) gm H 2 v vinylaxetilen c t l mol tng ng l 3:1. Cho hn hp X qua xc tc Ni nung nng thu c hn hp kh Y c t khi so vi H2 bng 14,5. Cho ton b hn hp Y trn t t qua dung dch nc brom d (phn ng hon ton) th khi lng brom phn ng l A. 32,0 gam. B. 3,2 gam. C. 8,0 gam. D. 16,0 gam. Cu 9: Hn hp X gm mt anehit v mt ankin c cng s nguyn t cacbon. t chy hon ton a (mol) hn hp X thu c 3a (mol) CO2 v 1,8a (mol) H2O. Hn hp X c s mol 0,1 tc dng c vi ti a 0,14 mol AgNO3 trong NH3 (iu kin thch hp). S mol ca anehit trong 0,1 mol hn hp X l A. 0,03. B. 0,04. C. 0,01. D. 0,02. Cu 10. un nng m gam hn hp X gm C2H2, C2H4 v H2 vi xc tc Ni n phn ng xy ra hon ton, thu c 8,96 lt (ktc) hn hp Y (c t khi so vi hir bng 8). t chy hon ton cng lng hn hp X trn, ri cho sn phm chy hp th hon ton trong dung dch nc vi trong d th khi lng kt ta thu c l A. 20 gam B. 50 gam C. 40 gam D. 30 gam

Bi tp hirocacbon hay v kh. Su tm: V Thanh Tng_sv khoa ha HKHTN-HQGHN