CHUYN ANKEN&ANKADIEN - LTDH

BI TP ANKEN ANKADIEN

I. L THUYT
Cu 1. C bao nhiu ng phn (k c ng phn hnh hc) c cng cng thc phn t l C5H10. A. 12 B. 10 C. 9 D. 8 Cu 2. Tn theo danh php quc t ca cht (CH3)2CHCH=CHCH3 l: A.1-Metyl-2-isopropyleten C. 1-Isopropylpropen Cu 3. Trong cc cng thc cu to: (I)CH3CH2CH=CHCH3 (IV) HOOC-CCl=CHBr (II) CHBr=CHBr (V)CH3CH=C(CH3)2 (III) CH2= CHCH2CH3 B.1,1-imetylbuten-2 D.4-Metylpenten-2

Cng thc cu to c ng phn cis trans l: A.III, IV. B.I, II, III. C.I, II, IV. D.I, II, IV, V

Cu 4. Cht 1-Brom-2,4-imetylheptaien-2,5 c s ng phn cis, trans l: A. 2 Cu 5. Cho cc mnh : (I).Anken v ankaien l ng ng ca nhau v u c lin kt i trong phn t. (II).Ankaien v ankin l ng phn ca nhau. (III).Hirocacbon khng no l hirocacbon c lin kt i trong phn t. (IV).Ankaien l hirocacbon c nhiu lin kt i trong phn t. (V).Anken v ankaien u lm mt mu dung dch nc brm. Nhng mnh ng l: A. I,IV,V B. II,III,IV C. I,II,III D. I,IV,V B.3 C. 4 D. 5

Cu 6. Nhng cht no sau y khng phi l ng phn ca ba cht cn li A.2-metylbut-1-en C.3-metybut-1-en B.2-metylbut-2-en D.2,3-imetylbut-2-en

Cu 7. (2009A): Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l

Gv Nguyn Hong Anh HKH HTN Nhn gia s ha hc cho mi i tng T 0988.473.410

CHUYN ANKEN&ANKADIEN - LTDH A. xiclohexan. B. xiclopropan. C. stiren. D. etilen.

Cu 8. (2011B): S ng phn cu to ca C5H10 phn ng c vi dung dch brom l A. 8. B. 7. C. 9. D. 5.

Cu 9. (2007A): Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l A. 2-metylpropen v but-1-en. C. eten v but-2-en . B. propen v but-2-en. D. eten v but-1-en.

Cu 10. Mt Hirocacbon mch h tc dng vi HCl sinh ra sn phm chnh l 2-Clo-3metyl butan. Hirocacbon ny c tn gi l: A. 3-Metyl buten-1 C. 2-Metyl buten-2 B. 2-Metyl buten-1 D. Mt anken khc

Cu 11. em hn hp cc ng phn mch h ca C4H8 cng hp vi H2O (H+, to) th thu c ti a s sn phm cng l: A. 3 B. 4 C. 5 D. 6

Cu 12. Etilen c ln cc tp cht SO2, CO2, hi nc. C th loi b cc tp cht bng cch no di y: A.Dn hn hp qua bnh ng dung dch brm d v bnh ng CaCl2 khan. B.Dn hn hp qua bnh ng dung dch natri clorua d. C.Dn hn hp qua bnh ng dung dch NaOH c D.Dn hn hp ln lt qua bnh ng dung dch brm d v H2SO4 c. Cu 13. Polime c tn l polipropilen cng thc l:

A.

CH2 n
CH2 CH CH2 CH3 n

B.

CH2 CH CH3 n

C.

D.

CH2 CH CH2 CH CH2 CH3 CH3 n

Cu 14. (2011A): Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh hc) thu c l A. 2. Cu 15. B. 3. C. 4. D. 1.

Phn ng ca etilen vi dung dch thuc tm c hin tng l: B. Dung dch khng i mu D.c bt kh,dung dch khng mu

A. Dung dch khng mu C.Dung dch khng mu,kt ta en

Gv Nguyn Hong Anh HKH HTN Nhn gia s ha hc cho mi i tng T 0988.473.410

CHUYN ANKEN&ANKADIEN - LTDH Cu 16. Tng cc h s (nguyn,ti gin) ca phn ng gia etilen v dung dch thuc tm l B. 14. C. 20. D. 16.

A. 12.

II.MT S BI TP C BN
Cu 1. A l mt hirocacbon, th tch metylaxetilen bng 1,75 th tch hi A c cng khi lng trong cng iu kin. S ng phn mch h ca A l: A. 6 B. 5 C. 4 D. 3

Cu 2. (2008B): Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankaien. B. anken. C. ankin. D. ankan.

Cu 3. Cho 1,12g anken cng vi Br2,Ta thu c 4,32g sn phm cng. Anken l: A. C3H6. B. C2H4. C. C5H10. D. C6H12. Cu 4. Cng HBr vo mt anken thu c sn phm c % Br v khi lng l 65%. Anken l A. C2H4. B. C3H6. C. C4H8. D. C5H10.

Cu 5. Cho etylen vo bnh cha brom lng to ra 1,2 - bometan..Th tch etylen (o ktc) tc dng vi brom bit rng sau khi cn li thy bnh brom tng ln 21g l A. 16,8 l B. 11,2 l C. 17,6 l D. 6,72 l Cu 6. Mt hn hp A gm 2 olefin kh l ng ng k tip nhau . Cho 4,2 gA i qua dung dch nc brom d thy c 22,4gBr2 phn ng ca 2 olefin l: A. C2H4 v C3H6 C. C4H8 v C5H10 B. C3H6 v C4H8 D. C5H10 v C6H12 Cng thc phn t

Cu 7. (2009B): Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-1-en. B. xiclopropan. C. but-2-en. D. propilen.

Cu 8. (2007A): Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5) A. C3H6. B. C3H4. C. C2H4. D. C4H8.

Cu 9. Mt hn hp kh gm C2H4 v H2. T khi ca hn hp ny so vi H2 l 7. Phn trm th tch ca C2H4 trong hn hp l:

Gv Nguyn Hong Anh HKH HTN Nhn gia s ha hc cho mi i tng T 0988.473.410

CHUYN ANKEN&ANKADIEN - LTDH A. 60% B. 70% C. 80% D. p n khc

Cu 10. Hn hp A gm 0,3 mol C2H4 v 0,2 mol H2. un nng hn hp A c Ni lm xc tc, thu c hn hp B. Hn hp B lm mt mu va 2 lt dung dch Br2 0,075M. Hiu sut phn ng gia etilen v hiro l: A. 75% B.50% C. 100% D. 20%.

Cu 11. Polietilen c trng hp t etilen. Hi 280 gam polietilen c trng hp t bao nhiu phn t etilen? A. 56,02.1023. C. 156,02.1023. B. 106,02.1023. D. Khng xc nh c.

Cu 12. Khi lng phn t ca polietilen bng 33600 vC, ca polipropilen bng 69300 vC. S mt xch trong cng thc phn t ca mi loi polime trn ln lt l: A. 1200 v 1650. B.2020 v 1500. C.120 v 1650. D.1700 v 1650

Cu 13. Hn hp gm 1 ankan v 1 anken. t chy hn hp A th thu c a mol H2O v b mol CO2. Hi t s T = a/b c gi tr trong khong no: A. 1,2 < T < 1,5 B. 1< T < 2 C. 1 T 2 D. p n khc Cu 14. t chy 1 hn hp hirocacbon X thu c 2,24lit CO2 (ktc) v 2,7 gam H2O. Th tch oxi tham gia phn ng chy ktc l: A. 5,6 lit B. 2,8 lit C. 4,48 lit D. p n khc

III.MT S BI TP NNG CAO

Cu 1. Hn hp kh X gm Hiro v mt Hirocacbon. Nung nng 24,64 lt hn hp X (ktc), c Ni lm xc tc, phn ng xy ra hon ton, bit rng c Hirocacbon d. Sau phn ng thu c 20,4 gam hn hp kh Y. T khi hn hp Y so vi Hiro bng 17. Khi lng H2 c trong hn hp X l: A. 3 gam B. 2 gam C. 1 gam D. 0,5 gam Cu 2. (2007A): Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C = 12) A. C2H2 v C4H6. C. C3H4 v C4H8. B. C2H2 v C4H8. D. C2H2 v C3H8.

Cu 3. Cho 2,24 lt mt hn hp kh A (o ktc) gm etan ,propan , propilen sc qua bnh ng dung dch brom d ,thy khi lng bnh tng thm 2,1g . Nu t chy kh cn li s thu c mt lng CO2 v 5,76 g H2O.Thnh phn % th tch mi kh l:
Gv Nguyn Hong Anh HKH HTN Nhn gia s ha hc cho mi i tng T 0988.473.410

CHUYN ANKEN&ANKADIEN - LTDH A. 20% , 30% , 50% C. 50% , 30%, 20% B.30% , 20%, 50% D. p n khc

Cu 4. (2008B): Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C3H6. C. CH4 v C2H4. B. CH4 v C3H4. D. C2H6 v C3H6.

Cu 5. (2009B): Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=C(CH3)2. C. CH2=CH-CH2-CH3. B. CH2=CH2. D. CH3-CH=CH-CH3.

Cu 6. Hn hp kh A gm eten v propan. t chy mt t hn hp A ta thu c kh CO2 v hi nc theo t l th tch 11:15. Thnh phn % theo khi lng ca hn hp l: A. 45% v 55% C. 18,52% v 81,48% B. 25% v 75% D. 28,13% v 71,87%

Cu 7. (2010B): Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l A. CH4 v C2H4. C. CH4 v C3H6. B. C2H6 v C2H4. D. CH4 v C4H8.

Cu 8. t chy hon ton 1,52 gam hp cht hu c X mch h. Sn phm thu c cho qua dung dch Ba(OH)2, thu c 3,94 gam kt ta v dung dch Y. C cn Y ri nung n khi lng khng i thu c 4, 59 g cht rn. Xc nh CTPT ca X: A. C4H8 B. C3H6 C. C6H14 D. C3H4

Cu 9. (2007A): Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l (cho H = 1, C = 12, O = 16, Ca = 40) A. 20. B. 40. C. 30. D.10

Gv Nguyn Hong Anh HKH HTN Nhn gia s ha hc cho mi i tng T 0988.473.410