TRNG THPT LP V 3

T: HO

Ngy

, thng 12 , nm 2012.

THI HC K I
MN: HO KHI 11

I. Mc tiu:
1.Kin thc: cng c cc kin thc
- Phn ng trao i ion trong dung dch cht in li. Vit phng trnh phn t v phng
trnh ion rt gon ca cc phn ng xy ra trong dd cht in li. pH ca dung dich.
- Tnh cht ca nit. Tnh cht ca: axit nitric, amoniac, mui amoni, mui nitrat.
- Nhn bit cc dung dch bng phng php ho hc.
- Ton: . Trn hn hp 2 dd axit vi dd baz. Tnh pH ca dung dch thu c.
. Tnh thnh phn % theo khi lng tng kim loi trong hn hp.
2. K nng:
- Vit phng trnh phn t v phng trnh ion rt gon ca cc phn ng xy ra trong dd
cht in li.
- Vit chui phn ng. Nhn bit cc dung dch bng phng php ho hc
- Tnh pH ca dung dch axit, baz. Tnh thnh phn % theo khi lng tng kim loi trong
hn hp.
II. Phng php :
T lun 100% , 5 cu = 10 im.
III.Chun b:

MA TRN THI HC K I
MN HO 11 NM HC: 2011 2012
Ch
Phn chung cho tt c th sinh
Hon thnh phng trnh
S cu
phn t - phng trnh ion
im
thu gn
Hon thnh chui phn
S cu
ng
im
Nhn bit cc dung dch.

Bi tp : Tnh thnh phn

Mc cn nh gi
Nhn bit
Thng hiu
Vn dng
1

Tng s
1

1
2

2
1

S cu
im

% theo khi lng tng

kim loi trong hn hp
Phn ring chng trnh c bn
Bi tp Tnh pH ca dung S cu
im
dch thu c
Phn ring chng trnh nng cao
S cu
Bi tp Tnh pH ca
im
dung dch axit yu baz
yu
Tng
S cu 2,5

1
2

1
1

1
1

* :

2
1

1
1,5

2
5

Cu 1: (2 )

Vit phng trnh phn t v phng trnh ion rt gn ca phn ng sau:

a/ BaCl2 + K2SO4
b) Na2CO3 + HCl
Cu 2: (2 ) Hy dng phng php ho cht nhn bit 3 dung dch sau: NH4Cl, NaNO3,
Na3PO4 ng trong 3 l ring bit. (Vit PTHH ca phn ng xy ra nu c).
Cu 3: (2 )
Vit cc phng trnh ho hc thc hin dy chuyn ho sau:
1
2
3
4
N2
NO
NO2
HNO3
Cu(NO3)2

Cu 4: (2,0 )
Ho tan hon ton 18,8g hn hp Mg v Fe vo trong dung dch HNO3 thy thot
ra 8,96 lt kh NO duy nht ktc.
a. Vit phng trnh ho hc ca cc phn ng xy ra.
b. Tnh thnh phn % theo khi lng ca mi kim loi trong hn hp ban u.

Phn ring chng trnh c bn

Cu 5: (2,0 )
Tnh pH ca dung dch thu c trong cc trng hp sau:
a/ Dung dch H2SO4 0,05 M
b/ Trn 500ml dung dch KOH 0,05M vi 250ml dung dch KOH 0,2M.

Phn ring chng trnh nng cao

Cu 5: (2,0 )
Tnh nng mol/lt ca cc ion trong dung dch v pH ca dung dch axit
CH3COOH 0,1M. Bit KCH3COOH = 1,75 . 10-5

P N THI HC K I
Cu
1

NI DUNG
Vit phng trnh in li ca cc cht:
a/ BaCl2 + K2SO4 BaSO4 + 2KCl
Ba2+ + SO42- BaSO4

b/ Na2CO3 + 2HCl 2NaCl + CO2 + H2O

CO32- + 2H+ CO2 + H2O
Nhn bit 3 dung dch:
- Dng dung dch AgNO3 bit c
Nu l dung dch NaCl s c kt ta trng, cn dung dch
Na3PO4 c kt ta vng, dung dch NaNO3 khng c hin tng.
AgNO3 + NaCl NaNO3 + AgCl
3AgNO3 + Na3PO4 3NaNO3 + Ag3PO4
1
N 2 + O2
2NO

2
2NO + O2
2NO2
3
4NO2 + O2 + 2H2O
4HNO3

4
2HNO3 + CuO
Cu(NO3)2 + H2O
3Mg(NO3)2 + 2NO+ 4H2O
3Mg + 8HNO3
x
8x/3
2x/3 mol
Fe(NO3)3 + NO + 2H2O
Fe + 4HNO3
y
4y
y mol
H phng trnh:

24x + 56y = 18,8

x = 0,27
2x/3 + y = 8,96 : 22,4 = 0,4
y = 0,22
%Mg =(24 x 0,27) x 100 : 18,8 = 34,47 %

%Fe = 100 34,47 = 65,53 %

IM
0,5
0,5
0,5
0,5

0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5

0,5
0,25
0,25

Phn ring chng trnh c bn

5

Tnh pH ca dung dch thu c trong cc trng hp sau:

a/ Dung dch H2SO4 0,005 M
H2SO4

2H+ + SO420,005M
0,01M
[H+] = 1,0 . 10-2 M

pH = 2
b/ nKOH = 0,5 x 0,05 = 0,025 mol ; nKOH = 0,25 x 0,2 = 0,05 mol
Vdd = 500 + 250 = 750 ml = 0,75 lt
Tng s mol KOH : nKOH = 0,025 + 0,05 = 0,075 mol
=> [OH-] = 0,075 : 0,75 = 10-1 M
=> [H+] = 10-13 M =>
pH = 13

0.25
0,25
0,5

0,25
0,25
0,25
0,25

Phn ring chng trnh nng cao

CH3COOH <=> CH3COO- + H+
Ban u
0,1M
0
0
Cn bng
0,1 x
x
xM
2
-5
Ka = x : (0,1 x) = 1,75 . 10
(0< x < 0,1)
x = 1,314 . 10-3
[CH3COO-] = [H+] = 1,314 . 10-3 M
pH = - lg[1,314 . 10-3] = 2,88

Trng THPT Lp V 3
T Ha

KIM TRA 1 TIT

Mn: HA HC - K10
THNG 9+10

0,25
0,25
0,25
0,5
0,25
0,5

Tn HS: .............
Lp: ..

A/ Phn chung (8,0):

Cu 1 (1): Xac inh s proton, notron, electron va in tich hat nhn trong nguyn t va ion
sau :

39
19

35
K; 17
Cl -

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Cu 2 (1) : Hay cho bit Na (Z =11), Ar (Z=18) la kim loai, phi kim hay khi him. Vi sao?
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Cu 3 (1): Nguyn t cua nguyn t A co 3 lp electron, co tng s electron phn lp p la
7 electron. Hay cho bit s electron phn mc nng lng cao nht la bao nhiu ?
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Cu 4 (1): Nguyn t Yco phn lp electron ngoai cung la 3p3. in tich hat nhn cua Y
la bao nhiu ?
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39

39

40

40

Cu 5 (1): Trong nhng cht sau: 18 X; 19Y; 19 Z; 18T nhng cht la ng vi cua nhau, vi
sao?
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16

35

Cu 6 (1): Cho 8 O; 17 Cl . Hay xac inh tng s hat (p,n,e) trong phn t Cl2 va trong
Cl2O.
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...................................................................................................................................................
39

40

35

37

Cu 7 (1): Cho 19 K, 19 K va 17 Cl, 17 Cl . Vit cng thc cac loai phn t kali clorua.
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Cu 8 (1): Tinh nguyn t khi trung binh cua nguyn t neon. Bit trong t nhin neon co
Ne (9%) va 20 Ne .
2 ng vi 22
10
10
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B/ Phn ring (2): Hoc sinh chon 1 trong 2 cu sau:
Cu 9: Nguyn t X co tng s ht proton, notron, electron trong nguyn t l 28. Trong
s ht mang in nhiu hn ht khng mang in l 8.
a. Xac inh s hat proton, notron va s khi trong nguyn t cua nguyn t X.
b. Vit ki hiu nguyn t cua nguyn t X.
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Cu 10: . Nguyn t khi trung binh ca clo l 35,5 vC. Nguyn t ny c hai ng v.
Bit :
- Phn trm ng v 1 gp 3 ln phn trm ng v 2.
- ng v 1 c s khi km ng v 2 l 2 vC.
Xc nh s khi mi ng v.
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Trng THPT Lp V 3
T Ha

KIM TRA 1 TIT

Mn: HA HC - K10

THNG 9+10

I. Muc ich, yu cu:

1. Kin thc:
- Thanh phn nguyn t
- ng vi. Nguyn t khi TB
- Cu hinh electron nguyn t
2. Ky nng: Vn dung kin thc giai ca bai tp co lin quan.
II. Ma trn :
Mc
Ni dung
Bit
Hiu
Vn dung
Thanh phn
1
1
nguyn t
1
1
ng vi. Nt
1
1
1
khi TB
1
1
2,0
Cu hinh
3
1
electron nt
3
1
5
3
1
Tng
5
3,0
2,0

Tng
2
2,0
3
4,0
4
4,0
9
10

III. Ni dung kim tra:

A/ Phn chung (8,0):
Cu 1 (1): Xac inh s proton, notron, electron va in tich hat nhn trong nguyn t va ion
sau :

39
19

35
K; 17
Cl -

Cu 2 (1) : Hay cho bit Na (Z =11), Ar (Z=18) la kim loai, phi kim hay khi him. Vi sao?
Cu 3 (1): Nguyn t cua nguyn t A co 3 lp electron, co tng s electron phn lp p la
7 electron. Hay cho bit s electron phn mc nng lng cao nht la bao nhiu ?
Cu 4 (1): Nguyn t Yco phn lp electron ngoai cung la 3p3. in tich hat nhn cua Y
la bao nhiu ?
39
39
40
40
Cu 5 (1): Trong nhng cht sau: 18 X; 19Y; 19 Z; 18T nhng cht la ng vi cua nhau, vi
sao?
16
35
Cu 6 (1): Cho 8 O; 17 Cl . Hay xac inh tng s hat (p,n,e) trong phn t Cl2 va trong
Cl2O.
39
40
35
37
Cu 7 (1): Cho 19 K, 19 K va 17 Cl, 17 Cl . Vit cng thc cac loai phn t kali clorua.
Cu 8 (1): Tinh nguyn t khi trung binh cua nguyn t neon. Bit trong t nhin neon co
Ne (9%) va 20 Ne .
2 ng vi 22
10
10
B/ Phn ring (2): Hoc sinh chon 1 trong 2 cu sau:
Cu 9: Nguyn t X co tng s ht proton, notron, electron trong nguyn t l 28. Trong
s ht mang in nhiu hn ht khng mang in l 8.
a. Xac inh s hat proton, notron va s khi trong nguyn t cua nguyn t X.
b. Vit ki hiu nguyn t cua nguyn t X.
Cu 10: . Nguyn t khi trung binh ca clo l 35,5 vC. Nguyn t ny c hai ng v.
Bit :
- Phn trm ng v 1 gp 3 ln phn trm ng v 2.
- ng v 1 c s khi km ng v 2 l 2 vC.
Xc nh s khi mi ng v.

IV. ap an:
Cu
1
2
3
4
5
6
7

Ni dung
39
19

35
17

Cl - : 17p,18e, 18n

: 19p, 19e, 20n

0,5

Na (Z =11) : 1s22s22p63s1. Kl vi co 1e lp ngoai cung

Ar (Z=18) : 1s22s22p63s23p6. KH vi co 8e lp ngoai cung
Cu hinh e cua A : 1s22s22p63s23p1.
Co 1 electron phn mc nng lng cao nht .
Cu hinh electron cua nguyn t M :1s22s22p63s23p3
Z = 15
Nhng cht la ng vi cua nhau

39
18

X, 4018T vi co cung s p =18

39
19

40
Y; 19
Z vi co cung s p =19

Tng s hat (p,n,e) trong Cl2 = 104

Tng s hat (p,n,e) trong phn t Cl2O = 128
Cng thc cac loai phn t kaliclorua:
39
19

im
0,5

0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5
0,5

K 1735Cl; 1939 K 1737Cl; 1940 K 1735Cl; 1940 K 1737Cl.

22.9 + 20.91
= 20,18
100
2 p + n = 28 p = e = 9

2 p n = 8
n = 10

Ta co A =

a) p = 9 , n = 10 , A = 19
19
19
b) 9 X hay 9 F
- Goi a la % cua ng vi 1, b la % cua ng vi 2
- Goi A la s khi cua ng vi 1, s khi cua ng vi 2 = A + 2
Ta co: a + b =100% ma a =3b b = 25% , a =75%
75 A + 25( A + 2)
A=
= 35,5 A= 35
100
Vy s khi cua ng vi 1 la 35; s khi cua ng vi 1 la 37

1,0
1,0
0,25
0,25
0,25
0,5
1,0
0,25