XC NH CNG THC PHN T HP CHT HU C

Cu 1: Mt hp cht hu c X c khi lng phn t l 26. em t X ch thu c CO2 v H2O. CTPT ca X l:

A. C2H6.
B. C2H4.
C. C2H2.
D. CH2O.
Cu 2: Mt hp cht hu c A c M = 74. t chy A bng oxi thu c kh CO2 v H2O. C bao nhiu cng thc
phn t ph hp vi A?
A. 4.
B. 2.
C. 3.
D. A.1.
Cu 3: Hp cht X c thnh phn % v khi lng : C (85,8%) v H (14,2%). Hp cht X l
A. C3H8.
B. C4H10.
C. C4H8.
D. kt qu khc.
Cu 4: Hp cht X c %C = 54,54% ; %H = 9,1%, cn li l oxi. Khi lng phn t ca X bng 88. CTPT ca X l:
A. C4H10O.
B. C5H12O.
C. C4H10O2.
D. C4H8O2.
Cu 5: Phn tch hp cht hu c X thy c 3 phn khi lng cacbon li c 1 phn khi lng hiro, 7 phn khi
lng nit v 8 phn lu hunh. Trong CTPT ca X ch c 1 nguyn t S, vy CTPT ca X l A. CH4NS.
B. C2H2N2S.
C. C2H6NS.
D. CH4N2S.
Cu 6: Hp cht X c CTGN l CH3O. CTPT no sau y ng vi X ?
A. C3H9O3.
B. C2H6O2.
C. C2H6O.
D. CH3O.
Cu 7: Cht hu c X c M = 123 v khi lng C, H, O v N trong phn t theo th t t l vi
72 : 5 : 32 : 14. CTPT ca X l: A. C6H14O2N.
B. C6H6ON2. C. C6H12ON. D. C6H5O2N.
Cu 8: Mt hp cht hu c A c t khi so vi khng kh bng 2. t chy hon ton A bng kh O2 thu c CO2 v
H2O. C bao nhiu cng thc phn t ph hp vi A ?
A. 2.
B. A. 1.
C. 3. D. 4.
Cu 9: t chy hon ton 0,6 gam hp cht hu c X ri cho sn phm chy qua bnh ng dung dch Ca(OH)2 d
thy c 2 gam kt ta v khi lng bnh tng thm 1,24 gam. T khi ca X so vi H2 bng 15. CTPT ca X l:
A. C2H6O.
B. CH2O.
C. C2H4O.
D. CH2O2.
Cu 10: Khi t 1 lt kh X cn 6 lt O2 thu c 4 lt CO2 v 5 lt hi H2O (cc th tch kh o cng iu kin nhit
, p sut). CTPT ca X l:
A. C4H10O.
B. C4H8O2.
C. C4H10O2.
D. C3H8O.
Cu 11: t chy hon ton 3 gam hp cht hu c X thu c 4,4 gam CO2 v 1,8 gam H2O. Bit t khi ca X so
vi He (MHe = 4) l 7,5. CTPT ca X l:
A. CH2O2.
B. C2H6.
C. C2H4O.
D. CH2O.
Cu 12: t chy hon ton mt hp cht hu c X (C, H, N) bng lng khng kh va (gm 1/5 th tch O 2, cn
li l N2) c kh CO2 , H2O v N2. Cho ton b sn phm chy qua bnh ng dung dch Ba(OH) 2 d thy c 39,4
gam kt ta, khi lng dung dch gim i 24,3 gam. Kh thot ra khi bnh c th tch 34,72 lt (ktc). Bit d X O 2 < 2.
CTPT ca X l:
A. C2H7N.
B. C2H8N.
C. C2H7N2.
D. C2H4N2.
Cu 13: Cho 400 ml mt hn hp gm nit v mt hirocacbon vo 900 ml oxi (d) ri t. Th tch hn hp thu
c sau khi t l 1,4 lt. Sau khi cho nc ngng t cn 800 ml hn hp, ngi ta cho li qua dung dch KOH thy
cn 400 ml kh. Cc th tch kh u o cng iu kin nhit , p sut. Cng thc phn t ca cht hu c l:
A. C3H8.
B. C2H4.
C. C2H2.
D. C2H6.
Cu 14: t chy hon ton hp cht hu c cha C, H, Cl sinh ra 0,22 gam CO2, 0,09 gam H2O. Mt khc khi xc
nh clo trong hp cht bng dung dch AgNO3 ngi ta thu c 1,435 gam AgCl. T khi hi ca hp cht so vi
hiro bng 42,5. Cng thc phn t ca hp cht l:
A. CH3Cl.
B. C2H5Cl.
C. CH2Cl2.
D. C2H4Cl2.
Cu 15: Oxi ha hon ton 4,02 gam mt hp cht hu c X ch thu c 3,18 gam Na2CO3 v 0,672 lt kh CO2.
CTGN ca X l:
A. CO2Na.
B. CO2Na2.
C. C3O2Na.
D. C2O2Na.
Cu 16: t chy hon ton mt hirocacbon trong 0,5 lt hn hp ca n vi CO2 bng 2,5 lt O2 thu c 3,4 lt kh.
Hn hp ny sau khi ngng t ht hi nc cn 1,8 lt, tip tc cho hn hp kh cn li qua dung dch kim d th cn
li 0,5 lt kh. Cc th tch c o cng iu kin nhit , p sut. CTPT ca hirocacbon l:
A. C4H10.
B. C3H8.
C. C4H8.
D. C3H6.
Cu 17: t chy hon ton 1,605 gam hp cht hu c A thu c 4,62 gam CO2 ; 1,215 gam H2O v 168 ml N2
(ktc). T khi hi ca A so vi khng kh khng vt qu 4. Cng thc phn t ca A l:
A. C5H5N.
B. C6H9N.
C. C7H9N.
D. C6H7N.
Cu 18: Oxi ha hon ton 6,15 gam hp cht hu c X thu c 2,25 gam H2O ; 6,72 lt CO2 v 0,56 lt N2 (kc).
Phn trm khi lng ca C, H, N v O trong X ln lt l:
A. 58,5% ; 4,1% ; 11,4% ; 26%.
B. 48,9% ; 15,8% ; 35,3% ; 0%.
C. 49,5% ; 9,8% ; 15,5% ; 25,2%.
D. 59,1 % ; 17,4% ; 23,5% ; 0%.
Cu 19: Phn tch 0,31gam hp cht hu c X ch cha C, H, N to thnh 0,44 gam CO2. Mt khc, nu phn tch 0,31
gam X ton b N trong X chuyn thnh NH3 ri dn NH3 va to thnh vo 100 ml dung dch H2SO4 0,4M th phn
axit d c trung ha bi 50 ml dung dch NaOH 1,4M. Bit 1 lt hi cht X (ktc) nng 1,38 gam. CTPT ca X l:
A. CH5N.
B. C2H5N2.
C. C2H5N.
D. CH6N.

Cu 20: t chy 200 ml hi mt hp cht hu c X cha C, H, O trong 900 ml O2, th tch hn hp kh thu c l
1,3 lt. Sau khi ngng t hi nc ch cn 700 ml. Tip theo cho qua dung dch KOH d ch cn 100 ml kh bay ra. Cc
th tch kh o cng iu kin nhit , p sut. CTPT ca Y l:
A. C3H6O.
B. C3H8O2.
C. C3H8O.
D. C3H6O2.
Cu 21: Phn tch 1,5 gam cht hu c X thu c 1,76 gam CO2 ; 0,9 gam H2O v 112 ml N2 o 0oC v 2 atm. Nu
ha hi cng 1,5 gam cht Z 127o C v 1,64 atm ngi ta thu c 0,4 lt kh cht Z. CTPT ca X l:
A. C2H5ON.
B. C6H5ON2.
C. C2H5O2N.
D. C2H6O2N.
Cu 22: t chy hon ton mt th tch hi hp cht hu c A cn 10 th tch oxi (o cng iu kin nhit v p
sut), sn phm thu c ch gm CO2 v H2O vi mCO2 : mH2O = 44 : 9. Bit MA < 150. A c cng thc phn t l:
A. C4H6O.
B. C8H8O.
C. C8H8.
D. C2H2.
Cu 23: t chy 0,282 gam hp cht hu c X, cho sn phm i qua cc bnh ng CaCl2 khan v KOH d. Thy
bnh ng CaCl2 tng thm 0,194 gam cn bnh ng KOH tng thm 0,8 gam. Mt khc nu t chy 0,186 gam cht
X th thu c 22,4 ml kh N2 ( ktc). Bit rng hp cht X ch cha mt nguyn t nit. Cng thc phn t ca hp
cht X l:
A. C6H6N2.
B. C6H7N.
C. C6H9N.
D. C5H7N.
Cu 24: t chy hon ton 0,4524 gam hp cht A sinh ra 0,3318 gam CO2 v 0,2714 gam H2O. un nng 0,3682
gam cht A vi vi ti xt chuyn tt c nit trong A thnh amoniac, ri dn kh NH3 vo 20 ml dung dch H2SO4
0,5 M. trung ho axit cn d sau khi tc dng vi NH3 cn dng 7,7 ml dung dch NaOH 1M. Bit MA= 60. Cng
thc phn t ca A l:
A. CH4ON2.
B. C2H7N.
C. C3H9N.
D. CH4ON.
Cu 25: t chy hon ton 0,01 mol cht hu c X cn va 0,616 lt O2. Sau th nghim thu c hn hp sn
phm Y gm : CO2, N2 v hi H2O. Lm lnh ngng t hi H2O ch cn 0,56 lt hn hp kh Z (c t khi hi vi H2
l 20,4). Bit th tch cc kh u o ktc. Cng thc phn t X l:
A. C2H5ON.
B. C2H5O2N.
C. C2H7O2N.
D. A hoc C.
Cu 26: t chy hon ton 0,12 mol cht hu c X mch h cn dng 10,08 lt kh O2 (ktc). Dn ton b sn phm
chy (gm CO2, H2O v N2) qua bnh ng dung dch Ba(OH)2 d, thy khi lng bnh tng 23,4 gam v c 70,92
gam kt ta. Kh thot ra khi bnh c th tch 1,344 lt (ktc). Cng thc phn t ca X l:
A. C2H5O2N.
B. C3H5O2N.
C. C3H7O2N.
D. C2H7O2N.
Cu 27: t chy hon ton 0,1 mol cht X cn 6,16 lt kh O2 (ktc), thu c 13,44 lt (ktc) hn hp CO2, N2 v hi
nc. Sau khi ngng t ht hi nc, cn li 5,6 lt kh (ktc) c t khi so vi hiro l 20,4. Cng thc phn t ca X
l:
A. C2H7O2N.
B. C3H7O2N.
C. C3H9O2N.
D. C4H9N.
Cu 28: t chy hon ton 1,18 gam cht Y (CxHyN) bng mt lng khng kh va . Dn ton b hn hp kh sau
phn ng vo bnh ng dung dch Ca(OH)2 d, thu c 6 gam kt ta v c 9,632 lt kh (ktc) duy nht thot ra
khi bnh. Bit khng kh cha 20% oxi v 80% nit v th tch. Cng thc phn t ca Y l:
A. C2H7N.
B. C3H9N.
C. C4H11N.
D. C4H9N.
Cu 29: t chy hon ton mt l-ng cht hu c cha C, H, Cl thu -c 2,2 gam
CO2; 0,9 gam H2O. Khi xc nh clo trong l-ng cht bng dung dch AgNO3 th
thu -c 14,35 gam AgCl. Cng thc phn t ca hp cht l
A. C2H4Cl2.
B. C3H6Cl2.
C. CH2Cl2.
D. CHCl3.
Cu 30: t chy hon ton 10,4 gam hp cht hu c Y (cha C, H, O) ri cho
ton b sn phm chy ln l-t qua bnh 1 dng H2SO4 c, bnh 2 ng n-c vi
trong d-. Sau th nghim, ng-i ta thy khi l-ng bnh 1 tng 3,6 gam v
bnh 2 thu -c 30 gam kt ta. Cng thc phn t ca X l
A. C3H6O2.
B. C4H6O2.
C. C4H6O4.
D. C3H4O4.
Cu 31: t chy hon ton 5,8 gam mt hp cht hu c n chc X cn 8,96 lt kh O2 (ktc), thu c CO2 v H2O
c s mol bng nhau. CTGN ca X l:
A. C2H4O.
B. C3H6O.
C. C4H8O.
D. C5H10O.
Cu 32: t chy hon ton 0,2 mol hirocacbon X. Hp th ton b sn phm chy vo nc vi trong c 20 gam
kt ta. L c b kt ta ri un nng phn nc l c li c 10 gam kt ta na. y X khng th l:
A. C2H6.
B. C2H4.
C. CH4.
D. C2H2.
Cu 33.: t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy vo dung dch Ba(OH)2 (d) to ra 29,55 gam
kt ta, dung dch sau phn ng c khi lng gim 19,35 gam so vi dung dch Ba(OH)2 ban u. Cng thc phn t ca X l
A.C3H8.
B. C2H6.
C. C3H4.
D. C3H6.
Cu 34.: Hn hp X c t khi so vi H2 l 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng ca
CO2 v H2O thu c l
A.20,40 gam.
B. 18,60 gam.
C. 18,96 gam.
D. 16,80 gam.
Cu 35.: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t
chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l
A.20.
B. 40.
C. 30.
D. 10.

Cu 36: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh
Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t ca X l
A.C3H8.
B. C3H6.
C. C4H8.
D. C3H4.
Cu 37: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc
th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l
A.12,9.
B. 25,8.
C. 22,2.
D. 11,1.
Cu 38: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20%
th tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton
lng kh thin nhin trn l (Cho H = 1; C = 12; O = 16)
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
Cu 39.: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X
ri hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l
A.7,3.
B. 6,6.
C. 3,39.
D. 5,85.
Cu 40.: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi
o cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H6.
B. C2H4.
C. CH4.
D. C3H8
Cu 41: Trong mt bnh kn cha hi cht hu c X (c dng CnH2nO2) mch h v O2 (s mol O2 gp i s mol cn cho phn ng
chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l
0,95 atm. X c cng thc phn t l
A. C2H4 O2.
B. CH2O2.
C. C4H8O2.
D. C3H6O2.

Chuyn bi tp Ankan

1.: Cho m gam hn hp etanal v propanal phn ng hon ton vi lng d dung dch AgNO3 trong NH3, thu c 43,2 gam kt ta
v dung dch cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l
A.9,5.
B. 10,9.
C. 14,3.
D. 10,2.
2.: Ho tan hon ton 0,3 mol hn hp gm Al v Al4C3 vo dung dch KOH (d), thu c a mol hn hp kh v dung dch X. Sc kh
CO2 (d) vo dung dch X, lng kt ta thu c l 46,8 gam. Gi tr ca a l
A.0,55.
B. 0,60.
C. 0,40.
D. 0,45.
3.: Khi crackinh hon ton mt th tch ankan X thu c ba th tch hn hp Y (cc th tch kh o cng iu kin nhit v p
sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l
A. C6H14.
B. C3H8.
C. C4H10.
D. C5H12.
4.08a Cu 49: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l
A.2.
B. 3.
C. 5.
D. 4.
5.: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca
A.ankan.
B. ankin.
C. ankaien.
D. anken
6.: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm
v s mol ca X v Y trong hn hp M ln lt l
A.75% v 25%.
B. 20% v 80%.
C. 35% v 65%.
D. 50% v 50%.
7.: t chy hon ton mt hirocacbon X thu c 0,11 mol CO2 v 0,132 mol H2O. Khi X tc dng vi kh clo (theo t l s mol 1:1)
thu c mt sn phm hu c duy nht. Tn g i ca X l
A.2-Metylbutan.
B. etan.
C. 2,2-imetylpropan.
D. 2-Metylpropan.
8.: t chy hon ton mt th tch kh thin nhin gm metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th
tch), thu c 7,84 lt kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng
kh thin nhin trn l (Cho H = 1; C = 12; O = 16)
A. 70,0 lt.
B. 78,4 lt.
C. 84,0 lt.
D. 56,0 lt.
9.: Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi clo theo t l s mol 1:1 (trong iu kin
chiu sng) ch thu c 2 dn xut monoclo ng phn ca nhau. Tn ca X l (Cho H = 1; C = 12; Cl = 35,5)
A.2-metylpropan.
B. 2,3-imetylbutan.
C. butan.
D. 3-metylpentan.
10.: Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 v H2. T khi ca X so vi butan l 0,4. Nu
cho 0,6 mol X vo dung dch brom (d) th s mol brom ti a phn ng l
A.0,24 mol.
B. 0,36 mol.
C. 0,60 mol.
D. 0,48 mol
11.: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu c 6,72 lt
CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l
A.CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
12.: Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong mt phn t. t chy hon ton
1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l s mol 1 : 1), s dn xut
monoclo ti a sinh ra l
A. 3.
B. 4.
C. 2.
D. 5.
13.Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm ankan v anken. T khi
ca X so vi kh hiro l 21,75. Phn trm th tch ca butan trong X l
A. 33,33%
B. 50,00%
C. 66,67%
D. 25,00%
14.t chy hon ton hn hp X gm hai hirocacbon k tip nhau trong dy ng ng, thu c 2,24 lt kh CO2
(ktc) v 3,24 gam H2O. Hai hirocacbon trong X l

A. C2H2 v C3H4.

B. C2H4 v C3H6.

C. CH4 v C2H6

Chuyn anken

D. C2H6 v C3H8

1.: Cho buta-1,3-ien phn ng cng vi Br2 theo t l mol 1:1. S dn xut ibrom (ng phn cu to v ng phn hnh
h c) thu c l
A. 2.
B. 3.
C. 4. D. 1.
2.: Anken X hp nc to thnh 3-etylpentan-3-ol. Tn ca X l
A.3-etylpent-3-en.
B. 2-etylpent-2-en.
C. 3-etylpent-2-en.
D. 3-etylpent-1-en.
3.: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng A.12,4
gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2.
B. 0,2 mol C2H4 , 0,1 mol C2H2. C. 0,1 mol C3H6 , 0,2
mol C3H4. D. 0,2 mol C3H6 , 0,1 mol C3H4.
4.: Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH3-C(CH3)=CH-CH3,
CH2=CH-CH2-CH=CH2. S cht c ng phn hnh h c l
A.2.
B. 3.
C. 1.
D. 4.
5.: Cho iso-pentan tc dng vi Cl2 theo t l s mol 1 : 1, s sn phm monoclo ti a thu c l
A.2.
B. 3.
C. 5.
D. 4.
6.: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi
phn ng hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2
hirocacbon l
A.C2H2 v C4H6.
B. C2H2 v C4H8.
C. C3H4 v C4H8.
D. C2H2 v C3H8.
7.: Clo ho P C thu c mt polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch
trong mch PVC. Gi tr ca k l (cho H = 1, C = 12, Cl = 35,5)
A.3.
B. 6.
C. 4.
D. 5.
8.: Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X.
t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l
A.20.
B. 40.
C. 30.
D. 10.
9.: Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%.
Cng thc phn t ca X l (cho H = 1, C = 12, Cl = 35,5)
A.C3H6.
B. C3H4.
C. C2H4.
D. C4H8.
10.: Hirat ha 2 anken ch to thnh 2 ancol (ru). Hai anken l
A. 2-metylpropen v but-1-en (hoc buten-1).
B. propen v but-2-en (hoc buten-2).
C. eten v but-2-en (hoc buten-2).
D. eten v but-1-en (hoc buten-1).
11.: Hn hp gm hirocacbon X v oxi c t l s mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn
hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp kh Z c t khi i vi hiro bng 19. Cng thc phn t
ca X l
A.C3H8.
B. C3H6.
C. C4H8.
D. C3H4.
12.: Cht no sau y c ng phn hnh h c?
A. CH2=CH-CH=CH2.
B. CH3-CH=C(CH3)2.
C. CH3-CH=CH-CH=CH2.
D. CH2=CH-CH2CH3.
13.: Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t
khi so vi He l 5. Hiu sut ca phn ng hiro ho l
A.20%.
B. 25%.
C. 50%.
D. 40%.
14.: Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng
vi H2 (d, xc tc Ni, to), cho cng mt sn phm l:
A. xiclobutan, cis-but-2-en v but-1-en.
B. but-1-en, 2-metylpropen v cis-but-2-en.
C. xiclobutan, 2-metylbut-2-en v but-1-en.
D. 2-metylpropen, cis-but-2-en v xiclobutan.
15. Cho cc cht: CH2=CHCH=CH2; CH3CH2CH=C(CH3)2; CH3CH=CHCH=CH2; CH3CH=CH2;
CH3CH=CHCOOH. S cht c ng phn hnh h c l
A.4.
B. 3. C. 2. D. 1.
16.: t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml
CO2 (cc th tch kh o cng iu kin nhit v p sut). T khi ca X so vi kh hiro l
A.12,9.
B. 25,8.
C. 22,2.
D. 11,1.
17.: Cho hn hp hai anken ng ng k tip nhau tc dng vi nc (c H2SO4 lm xc tc) thu c hn hp Z gm hai
ru (ancol) X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lt dung dch
NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Cng thc cu to thu g n ca X v Y l
(Cho: H = 1; C = 12; O = 16; th tch dung dch thay i khng ng k)
A. C2H5OH v C3H7OH.
B. C3H7OH v C4H9OH.
C. C2H5OH v C4H9OH. D. C4H9OH v C5H11OH.
18.: Cho phn ng: C6H5-CH=CH2 + KMnO4 C6H5-COOK + K2CO3 + MnO2 + KOH + H2O. Tng h s (nguyn, ti
gin) tt c cc cht trong phng trnh ho h c ca phn ng trn l
A.27.
B. 24.
C. 34.
D. 31.
19.: S ng phn cu to ca C5H10 phn ng c vi dung dch brom l
A.8.
B. 7.
C. 9.
D. 5.

20.: Hn hp kh X gm mt ankan v mt anken. T khi ca X so vi H2 bng 11,25. t chy hon ton 4,48 lt X, thu
c 6,72 lt CO2 (cc th tch kh o ktc). Cng thc ca ankan v anken ln lt l
A.CH4 v C2H4.
B. C2H6 v C2H4.
C. CH4 v C3H6.
D. CH4 v C4H8.
21.: Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br
v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn g i ca X l
A. but-1-en.
B. xiclopropan.
C. but-2-en.
D. propilen.
22.: Dn 1,68 lt hn hp kh X gm hai hirocacbon vo bnh ng dung dch brom (d). Sau khi phn ng xy ra hon
ton, c 4 gam brom phn ng v cn li 1,12 lt kh. Nu t chy hon ton 1,68 lt X th sinh ra 2,8 lt kh CO2.
Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc)
A. CH4 v C2H4.
B. CH4 v C3H4.
C. CH4 v C3H6.
D. C2H6 v C3H6
23.: Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht
X, Y, Z thuc dy ng ng
A. ankan.
B. ankaien.
C. anken.
D. ankin.
24. Hiro ha hon ton hirocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l
A. 6.
B. 5.
C. 7.
D. 4.
25. t chy hon ton 3 lt hn hp X gm 2 anken kt tip nhau trong dy ng ng cn va 10,5 lt
O2 (cc th tch kh o trong cng iu kin nhit , p sut). Hirat ha hon ton X trong iu kin thch
hp thu c hn hp ancol Y, trong khi lng ancol bc hai bng 6/13 ln tng khi lng cc ancol
bc mt. Phn trm khi lng ca ancol bc mt (c s nguyn t cacbon ln hn) trong Y l
A. 46,43%.
B. 31,58%.
C. 10,88%.
D. 7,89%.
26. Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng, thu c hn hp Y c
t khi so vi H2 l 12,5. Hiu sut ca phn ng hiro ha l
A. 70%.
B. 60%.
C. 50%.
D. 80%.
27. Hirat ha 2-metylbut-2-en (iu kin nhit , xc tc thch hp) thu c sn phm chnh l
A. 2-metylbutan-2-ol.B. 3-metylbutan-2-ol.C. 3-metylbutan-1-ol.
D. 2-metylbutan-3-ol.

Chuyn bi tp Ankin

1.: Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Y gm
C2H4, C2H6, C2H2 v H2. Sc Y vo dung dch brom (d) th khi lng bnh brom tng 10,8 gam v thot ra 4,48 lt hn hp kh
(ktc) c t khi so vi H2 l 8. Th tch O2 (ktc) cn t chy hon ton hn hp Y l
A.22,4 lt.
B. 26,88 lt.
C. 44,8 lt.
D. 33,6 lt.
2.: t chy hon ton hn hp X gm C2H2, C3H4 v C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2. Nu ly cng mt
lng hn hp X nh trn tc dng vi mt lng d dung dch AgNO3 trong NH3, th khi lng kt ta thu c ln hn 4 gam.
Cng thc cu to ca C3H4 v C4H4 trong X ln lt l:
A. CHC-CH3, CH2=C=C=CH2. B. CH2=C=CH2, CH2=CH-CCH.
C. CHC-CH3, CH2=CH-CCH. D. CH2=C=CH2, CH2=C=C=CH2.
3.: un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn (xc tc Ni), thu c hn hp kh Y. Cho Y li t
t vo bnh nc brom (d), sau khi kt thc cc phn ng, khi lng bnh tng m gam v c 280 ml hn hp kh Z (ktc) thot ra.
T khi ca Z so vi H2 l 10,08. Gi tr ca m l
A.0,585.
B. 0,620.
C. 0,205.
D. 0,328.
4.: Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch
6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l
A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2.
C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4.
5.: un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b
hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lt hn hp kh Z ( ktc) c t khi so vi O2 l 0,5. Khi
lng bnh dung dch brom tng l
A.1,04 gam.
B. 1,32 gam.
C. 1,64 gam.
D. 1,20 gam.
6. Cho cc cht: axetilen, vinylaxetilen, cumen, stiren, xiclohexan, xiclopropan v xiclopentan. Trong cc cht trn, s cht phn ng
c vi dung dch brom l
A.6.
B. 4.
C. 5.
D. 3.
7.: Cho s chuyn ha: CH4 C2H2 C2H3Cl P C. tng hp 250 kg P C theo s trn th cn V m3 kh thin nhin (
ktc). Gi tr ca V l (bit CH4 chim 80% th tch kh thin nhin v hiu sut ca c qu trnh l 50%)
A.358,4.
B. 448,0.
C. 286,7.
D. 224,0.
8. Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3, to), thu c hn hp Y ch c hai hirocacbon. Cng thc phn
t ca X l
A.C2H2.
B. C4H6.
C. C5H8.
D. C3H4.
9.: Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so
vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l
A.16,0.
B. 3,2.
C. 8,0.
D. 32,0.

10.: t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO2 bng s mol H2O. Thnh phn phn trm
v s mol ca X v Y trong hn hp M ln lt l
A.75% v 25%.
B. 20% v 80%.
C. 35% v 65%.
D. 50% v 50%.
11.: Dn V lt ( ktc) hn hp X gm axetilen v hiro i qua ng s ng bt niken nung nng, thu c kh Y. Dn Y vo lng d
AgNO3 (hoc Ag2O) trong dung dch NH3 thu c 12 gam kt ta. Kh i ra khi dung dch phn ng va vi 16 gam brom v
cn li kh Z. t chy hon ton kh Z thu c 2,24 lt kh CO2 ( ktc) v 4,5 gam nc. Gi tr ca V bng
A. 11,2.
B. 13,44.
C. 5,60.
D. 8,96.
12.: Cho 4,48 lt hn hp X ( ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lt dung dch Br2 0,5M. Sau khi phn ng
hon ton, s mol Br2 gim i mt na v khi lng bnh tng thm 6,7 gam. Cng thc phn t ca 2 hirocacbon l (cho H = 1, C
= 12)
A.C2H2 v C4H6.
B. C2H2 v C4H8.
C. C3H4 v C4H8.
D. C2H2 v C3H8.
13.: Dy gm cc cht u tc dng vi AgNO3 (hoc Ag2O) trong dung dch NH3, l:
A. anehit axetic, butin-1, etilen. B. anehit axetic, axetilen, butin-2.
C. axit fomic, vinylaxetilen, propin. D. anehit fomic, axetilen, etilen.
14.: Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca
A.ankan.
B. ankin.
C. ankaien.
D. anken
15.: Hn hp kh X gm etilen, metan, propin v vinylaxetilen c t khi so vi H2 l 17. t chy hon ton 0,05 mol hn hp X ri
hp th ton b sn phm chy vo bnh dung dch Ca(OH)2 (d) th khi lng bnh tng thm m gam. Gi tr ca m l
A.7,3.
B. 6,6.
C. 3,39.
D. 5,85.
16.: Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48
gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt
ta. Phn trm th tch ca CH4 c trong X l
A. 20%.
B. 50%.
C. 25%.
D. 40%.
17.: t chy hon ton 1 lt hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lt kh CO2 v 2 lt hi H2O (cc th tch kh v hi o
cng iu kin nhit , p sut). Cng thc phn t ca X l
A. C2H6.
B. C2H4.
C. CH4.
D. C3H8

Hirocacbon thm
18: Cho 13,8 gam cht hu c X c cng thc phn t C7H8 tc dng vi mt lng d dung dch AgNO3 trong NH3, thu
c 45,9 gam kt ta. X c bao nhiu ng phn cu to tha mn tnh cht trn?
A. 2.
B. 5.
C. 4.
D. 6.
19.: S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l
A.2.
B. 4.
C. 3.
D. 5.
20. t chy hon ton 4,64 gam mt hirocacbon X (cht kh iu kin thng) ri em ton b sn phm chy hp
th ht vo bnh ng dung dch Ba(OH)2. Sau cc phn ng thu c 39,4 gam kt ta v khi lng phn dung dch
gim bt 19,912 gam. Cng thc phn t ca X l
A. C3H4.
B. CH4.
C. C2H4.
D. C4H10.
21, Cho dy cc cht: cumen, stiren, isopren, xiclohexan, axetilen, benzen. S cht trong dy lm mt mu dung dch
brom l
A. 2.
B. 3.
C. 4.
D. 5.
22. Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xc tc Ni) mt thi gian, thu
c hn hp Y c t khi so vi H2 bng 10. Dn hn hp Y qua dung dch brom d, sau khi phn ng xy ra hon
ton, khi lng brom tham gia phn ng l
A. 0 gam.
B. 24 gam.
C. 8 gam.
D. 16 gam.
23.t chy hon ton hn hp X gm hai hirocacbon (t l s mol 1 : 1) c cng thc n gin nht khc nhau,
thu c 2,2 gam CO2 v 0,9 gam H2O. Cc cht trong X l
A. mt ankan v mt ankin.
B. hai ankaien.
C. hai anken.
D. mt anken v mt ankin