TNG HP THI CAO NG - I HC

I. HIROCACBON
Cu 1 (C_07): Khi cho ankan X (trong phn t c phn trm khi lng cacbon bng 83,72%) tc dng vi kh Cl 2 theo t l mol 1 : 1 (trong iu kin chiu sng) ch thu c hai dn xut monoclo ng phn ca nhau. Tn ca X l A. 2-metylpropan B. butan C. 3-metylpentan D. 2,3-imetylbutan Cu 2 (C_08): Cng thc n gin nht ca mt hirocacbon l CnH2n+1. Hirocacbon thuc dy ng ng ca A. anken B. ankin C. ankaien D. ankan Cu 3 (C_09): Cho cc cht: xiclobutan, 2-metylpropen, but-1-en, cis-but-2-en, 2-metylbut-2-en. Dy gm cc cht sau khi phn ng vi H2 (d, xc tc Ni, t0), cho cng mt sn phm l: A. xiclobutan, cis-but-2-en v but-1-en. B. but-1-en, 2-metylpropen v cis-but-2-en. C. xiclobutan, 2-metylbut-2-en v but-1-en. D. 2-metylpropen, cis-but-2-en v xiclobutan. Cu 4 (C_09): Cho cc cht: CH2=CH-CH=CH2; CH3-CH2-CH=C(CH3)2; CH3-CH=CH-CH=CH2; CH3-CH=CH2; CH3-CH=CH-COOH. S cht c ng phn hnh hc l A. 4. B. 3. C. 2. D. 1. Cu 5 (H_A_07): Mt hirocacbon X cng hp vi axit HCl theo t l mol 1:1 to sn phm c thnh phn khi lng clo l 45,223%. Cng thc phn t ca X l A. C2H4 B. C3H4 C. C3H6 D. C4H8 Cu 6 (H_A_07): Hirat ho 2 anken ch to thnh 2 ancol. Hai anken l A. Eten v but-1-en B. propen v but-2-en C. Eten v but-2-en D. 2-metylpropen v but-1-en Cu 7 (H_B_07): Brom ho mt ankan ch thu c mt dn xut monobrom duy nht c t khi so vi hiro l 75,5. Tn ankan l A. 3,3-imetylhexan B. 2,2-imetylpropan C. 2,2,3-trimetylpentan D. isopentan Cu 8 (H_A_08): Cho cc cht sau: CH2=CH-CH2-CH2-CH=CH2, CH2=CH-CH=CH-CH2-CH3, CH2=CH-CH2-CH=CH2, CH3-C(CH3)=CH-CH3. S cht c ng phn hnh hc l A. 2 B. 3 C. 1 D. 4 Cu 9 (H_A_08): Khi crackinh ton b mt th tch ankan X thu c ba th tch hn hp Y (cc th tch o cng iu kin nhit v p sut); t khi ca Y so vi H2 bng 12. Cng thc phn t ca X l A. C6H14 B. C3H8 C. C4H10 D. C5H12 Cu 10 (H_A_08): Cho iso-pentan tc dng vi Cl2 theo t l mol 1:1, s sn phm monoclo ti a thu c l A. 2 B. 3 C. 5 D. 4 Cu 11 (H_A_08): S ng phn hirocacbon thm ng vi cng thc phn t C8H10 l A. 2 B. 4 C. 3 D. 5 Cu 12 (H_B_08): Hirocacbon mch h X trong phn t ch cha lin kt v c hai nguyn t cacbon bc ba trong phn t. t chy hon ton 1 th tch X sinh ra 6 th tch CO2 ( cng iu kin nhit , p sut). Khi cho X tc dng vi Cl2 (theo t l mol 1: 1), s dn xut monoclo ti a sinh ra l A. 3 B. 4 C. 2 D. 5 Cu 13 (H_B_08): Ba hirocacbon X, Y, Z l ng ng k tip, khi lng phn t ca Z bng 2 ln khi lng phn t ca X. Cc cht X, Y, Z thuc dy ng ng A. ankaien B. anken C. ankin D. ankan Cu 14 (H_A_09): Hirocacbon X khng lm mt mu dung dch brom nhit thng. Tn gi ca X l A. xiclohexan. B. xiclopropan. C. stiren. D. etilen. Cu 15 (H_B_09): Dy gm cc cht u c kh nng tham gia phn ng trng hp l: A. stiren; clobenzen; isopren; but-1-en. B. 1,2-iclopropan; vinylaxetilen; vinylbenzen; toluen. C. buta-1,3-ien; cumen; etilen; trans-but-2-en. D. 1,1,2,2-tetrafloeten; propilen; stiren; vinyl clorua. Cu 16 (H_B_09): Cho hirocacbon X phn ng vi brom (trong dung dch) theo t l mol 1 : 1, thu c cht hu c Y (cha 74,08% Br v khi lng). Khi X phn ng vi HBr th thu c hai sn phm hu c khc nhau. Tn gi ca X l A. but-2-en. B. propilen. C. xiclopropan. D. but-1-en. Cu 17 (C_07): t chy hon ton mt th tch kh thin nhin gm: metan, etan, propan bng oxi khng kh (trong khng kh, oxi chim 20% th tch), thu c 7,84 lit kh CO2 ( ktc) v 9,9 gam nc. Th tch khng kh ( ktc) nh nht cn dng t chy hon ton lng kh thin nhin trn l A. 84,0 lit B. 70,0 lit C. 78,4 lit D. 56,0 lit Cu 18 (C_08): t chy hon ton mt hirocacbon X thu c 0,11 mol CO 2 v 0,132 mol H2O. Khi X tc dng vi kh Cl2 (theo t l mol 1 : 1) thu c mt sn phm hu c duy nht. Tn gi ca X l A. 2-metylbutan B. 2-metylpropan C. 2,2-imetylpropan D. etan Cu 19 (C_07): Dn V lit (ktc) hn hp X gm axetilen v hiro qua ng s ng bt Ni nung nng, thu c hn hp kh Y. Dn Y vo dung dch AgNO 3 (hoc Ag2O) trong NH3 d thu c 12 gam kt ta. Kh i ra khi bnh phn

ng va vi 16 gam Brom, cn li kh Z. t chy hon ton Z thu c 2,24 lit (ktc) kh CO 2 v 4,5 gam nc. Gi tr ca V l A. 5,60 B. 8,96 C. 11,2 D. 13,44 Cu 20 (C_08): t chy hon ton hn hp M gm mt ankan X v mt ankin Y, thu c s mol CO 2 bng s mol H2O. Thnh phn phn trm s mol ca X, Y trong hn hp M ln lt l A. 35% v 65% B. 75% v 25% C. 20% v 80% D. 50% v 50% Cu 21 (C_08): t chy hon ton 20,0 ml hn hp X gm C3H6, CH4, CO (th tch CO gp hai ln th tch CH4), thu c 24,0 ml CO2 (cc th tch kh o cng iu kin nhit , p sut). T khi ca X so vi H2 l A. 25,8 B. 12,9 C. 22,2 D. 11,1 Cu 22 (C_09): Hn hp kh X gm H2 v C2H4 c t khi so vi He l 3,75. Dn X qua Ni nung nng, thu c hn hp kh Y c t khi so vi He l 5. Hiu sut ca phn ng hiro ho l A. 20%. B. 25%. C. 50%. D. 40%. Cu 23 (C_09): kh hon ton 200 ml dung dch KMnO 4 0,2M to thnh cht rn mu nu en cn V lit kh C2H4 ( ktc). Gi tr ti thiu ca V l A. 2,240. B. 2,688. C. 4,480. D. 1,344. Cu 24 (C_09): Hn hp kh X gm 0,3 mol H2 v 0,1 mol vinylaxetilen. Nung X mt thi gian vi xc tc Ni thu c hn hp kh Y c t khi so vi khng kh l 1. Nu cho ton b Y sc t t vo dung dch Brom (d) th c m gam brom tham gia phn ng. Gi tr ca m l A. 16,0. B. 3,2. C. 8,0. D. 32,0. Cu 25 (H_A_07): Ba hirocacbon X, Y, Z k tip nhau trong dy ng ng, trong khi lng phn t Z gp i khi lng phn t X. t chy 0,1 mol Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 (d), thu c s gam kt ta l A. 10 B. 20 C. 30 D. 40 Cu 26 (H_A_07): Cho 4,48 lit hn hp X (ktc) gm 2 hirocacbon mch h li t t qua bnh cha 1,4 lit dung dch Br2 0,5M. Sau khi phn ng xy ra hon ton, s mol Br2 gim mt na v khi lng bnh tng 6,7 gam. Cng thc phn t ca hai hirocacbon l A. C2H2 v C4H6 B. C2H2 v C4H8 C. C2H2 v C3H8 D. C3H4 v C4H8 Cu 27 (H_A_07): Hn hp gm hirocacbon X v oxi c t l mol tng ng l 1:10. t chy hon ton hn hp trn thu c hn hp kh Y. Cho Y qua dung dch H2SO4 c, thu c hn hp Z c t khi i vi H2 bng 19. Cng thc phn t ca X l A. C3H4 B. C3H6 C. C4H8 D. C3H8 Cu 28 (H_A_07): Clo ho PVC thu c 1 polime cha 63,96% clo v khi lng, trung bnh 1 phn t clo phn ng vi k mt xch trong mch PVC. Gi tr ca k l A. 3 B. 4 C. 5 D. 6 Cu 29 (H_A_08): Hn hp X c t khi so vi H2 bng 21,2 gm propan, propen v propin. Khi t chy hon ton 0,1 mol X, tng khi lng CO2 v H2O thu c l A. 20,40 gam B. 18,60 gam C. 18,96 gam D. 16,80 gam Cu 30 (H_A_08): un nng hn hp kh gm 0,06 mol C2H2 v 0,04 mol H2 vi xc tc Ni, sau mt thi gian thu c hn hp kh Y. Dn ton b hn hp Y li t t qua bnh ng dung dch brom (d) th cn li 0,448 lit hn hp kh Z (o ktc) c t khi so vi O2 bng 0,5. Khi lng bnh ng dung dch brom tng l A. 1,04 gam B. 1,32 gam C. 1,64 gam D. 1,20 gam Cu 31 (H_A_08): Cho s chuyn ho: CH4 C2H2 C2H3Cl PVC. tng hp 250 kg PVC theo s trn th cn V m3 kh thin nhin ( ktc). Gi tr ca V l (bit CH 4 chim 80% th tch kh thin nhin v hiu sut ca ton b qu trnh l 50%) A. 358,4 B. 448,0 C. 286,7 D. 224,0 Cu 32 (H_B_08): Dn 1,68 lit hn hp kh X gm hai hirocacbon vo bnh ng nc brom (d). Sau khi phn ng xy ra hon ton, c 4 gam brom phn ng v cn li 1,12 lit kh. Nu t chy hon ton 1,68 lit X th sinh ra 2,8 lit kh CO2. Cng thc phn t ca hai hirocacbon l (bit cc th tch kh u o ktc) A. CH4 v C3H6. B. CH4 v C3H4. C. CH4 v C2H4. D. C2H6 v C3H6. Cu 33 (H_B_08): t chy hon ton 1 lit hn hp kh gm C2H2 v hirocacbon X sinh ra 2 lit CO2 v 2 lit hi H2O (cc th tch kh v hi o cng iu kin nhit , p sut). Cng thc phn t ca X l A. C3H8. B. C2H6. C. CH4 D. C2H4. Cu 34 (H_A_09): Hn hp kh X gm anken M v ankin N c cng s nguyn t cacbon trong phn t. Hn hp X c khi lng 12,4 gam v th tch 6,72 lt ( ktc). S mol, cng thc phn t ca M v N ln lt l A. 0,1 mol C2H4 v 0,2 mol C2H2. B. 0,2 mol C2H4 v 0,1 mol C2H2. C. 0,1 mol C3H6 v 0,2 mol C3H4. D. 0,2 mol C3H6 v 0,1 mol C3H4. Cu 35 (H_B_09): Hn hp kh X gm H2 v mt anken c kh nng cng HBr cho sn phm hu c duy nht. T khi ca X so vi H2 bng 9,1. un nng X c xc tc Ni, sau khi phn ng xy ra hon ton, thu c hn hp kh Y

khng lm mt mu nc brom; t khi ca Y so vi H2 bng 13. Cng thc cu to ca anken l A. CH2=CH2. B. CH2=CH-CH2-CH3. C. CH2=C(CH3)2. D. CH3-CH=CH-CH3. Cu 36 (H_B_09): Cho hn hp X gm CH4, C2H4 v C2H2. Ly 8,6 gam X tc dng ht vi dung dch brom (d) th khi lng brom phn ng l 48 gam. Mt khc, nu cho 13,44 lt ( ktc) hn hp kh X tc dng vi lng d dung dch AgNO3 trong NH3, thu c 36 gam kt ta. Phn trm th tch ca CH4 c trong X l A. 25%. B. 20%. C. 50%. D. 40%. Cu 37: (H_A_10) un nng hn hp kh X gm 0,02 mol C2H2 v 0,03 mol H2 trong mt bnh kn xc tc Ni, thu c hn hp kh Y. Cho Y li t t qua bnh ng dd nc Br2 d, sau khi phn ng kt thc khi lng bnh phn ng tng m gam v c 280 ml hn hp kh Z (ktc) thot ra. T khi ca Z so vi H2 l 10,08. Gi tr ca m l: A. 0,328 B. 0,62 C. 0,585 D. 0,205 Cu 38a: (H_A_10) t chy hon ton mt lng hirocacbon X. Hp th ton b sn phm chy qua bnh ng dd Ba(OH)2 d to ra 29,55 gam kt ta, dd sau phn ng c khi lng gim 19,35 gam so vi dd Ba(OH)2. CTPT ca X l: A. C2H6 B. C3H6 C. C3H8 D. C3H4 Cu 38b: (H_B_10) Hn hp kh X gm mt ankan v mt anken . T khi ca X so vi H 2 l 11,25. t chy hon ton 4,48lt X thu c 6,72 lt CO2 (kh ktc). Cng thc ankan, anken ln lt l: A. CH4, C2H4 B. C2H6 V C2H4 C. CH4, C3H6 D. CH4, C4H8 Cu 39: (C_A_10) t chy hon ton 6,72 lt hn hp gm 2 hirocacbon X v Y (MY>MX), thu c 11,2 lt CO2 v 10,8 gam H2O.CTPT ca X l: A. C2H6 B. CH4 C. C2H4 D. C2H2 Cu 40 : (C_A_10) S lin kt xichma trong phn t etilen, axetilen, buta-1,3-dien ln lt l: A. 5,3,9 B. 3,5,9 C. 4, 3, 6 D. 4, 2 , 6 Cu 41 : (C_A_10) Cho 3,12 gam ankin X phn ng vi 0,1 mol H2 (xc tc Pd/PbCO3 , to) thu c hn hp y ch c 2 hirocacbon. CTPT ca X l: A. C2H2 B. C5H8 C. C3H4 D. C4H6 Cu 42 : (C_A_10) Cht no sau y c ng phn hnh hc: A. but-2-in B. 1,2-dicloetan C. 2-clopropen D. But-2-en Cu 43 : (H_A_11) Hn hp X gm C2H2 v H2 c cng s mol. Ly mt lng hn hp X cho qua cht xc tc nung nng, thu c hn hp Ygm C2H4, C2H6, C2H2, H2. Sc Y vo dd B2 d th khi lng bnh Br2 tng 10,8 gam v thot ra 4,48 lt hn hp kh (ktc) c t khi so vi H2 l 8. Th tch O2 (ktc cn t chy hon ton Y l: A. 33,6 lit B. 22,4 lit C. 26,88 lit D. 44,8 lit Cu 44: (H_A_11 ) Cho 13,8 gam cht hu c X c cng thc phan t l C7H8 tc dng vi mt lng d dd AgNO3 trong NH3, thu c 45,9 gam kt ta. X c bao nhiu CTCT tho mn tnh cht trn. A. 5 B. 6 C. 4 D.2 Cu 45: t chy hon ton hn hp X gm C2H2, C3H4, C4H4 (s mol mi cht bng nhau) thu c 0,09 mol CO2 Nu ly mt lng hn hp X nh trn tc dng vi lng d dd AgNO3 trong NH3, thu c kt ta ln hn 4 gam. CTCT ca C3H4 v C4H4 ln lt l:.. Cu 46 (H_B _11) Hn hp kh X gm etilen, metan. Propin v vinylaxetilen c t khi so vi H 2 l 17. t chy hon ton 0,05 mol hn hp X ri hp th ton b sn phm chy vo bnh ng dd Ca(OH) 2 d th khi lng bnh tng thm m gam. Gi tr ca m l: A. 6,6 B. 7,3 C. 3,39 D. 5,85 Cu 47 (H_B _11) S ng phn cu to ca C5H10 phn ng c vi dd Br2 l: A. 8 B. 5 C. 9 D. 7 Cu 48 (H_B _11) Cho butan qua xc tc ( nhit cao) thu c hn hp X gm C4H10, C4H8, C4H6 , H2. T khi ca X so vi butan l 0,4. Nu cho 0,6 mol X vo dd Br2 d th s mol Br2 ti a phn ng l: A. 0,36 B. 0,24 C. 0,48 D. 0,6 Cu 49 (C_A _11) Sn phm ch yu trong hn hp thu c khi cho toluen phn ng vi brom theo t l s mol 1:1(Fe xc tc) l: A. benzyl bromua B.o-bromtoluen v p-bromtoluen C.p-bromtoluen v m-bromtoluen D.0-bromtoluen v m-bromtoluen Cu 50 (C_A _11) un si hn hp gm propyl bromua, KOH, C2H5OH thu c sn phn hu c l: A. propan-2-ol B. propan C. propin D. Propen Cu 51 (C_A _11) Cho cc cht axetilen, vinyl axetilen, cumen, stiren, xiclohexan, xiclopropan,xiclopentan. Trong s cc cht trn, cht phn ng dc vi dd Brom l: A. 6 B. 4 C. 7 D. 5 Cu 52: (H_A_12 ) t chy hon ton 4,64 gam mt hidrocacbon X(cht kh k thng) ri em ton b sn phm chy hp th ht vo bnh ng dd Ba(OH) 2. Sau phn ng thu c 39,4 gam kt ta v khi lng phn dd gim bt 19,912 gam. Cng thc phn t ca X l: A. CH4 B. C3H4 C. C4H10 D. C2H4 Cu 53: (H_A_12 ) Hidro ho hon ton hidrocacbon mch h X thu c isopentan. S cng thc cu to c th c ca X l: A. 6 B.7 C.4 D.5 Cu 54: (H_A_12 ) Hn hp X gm H2 v C2H4 c t khi so vi H2 l 7,5. Dn X qua Ni nung nng thu c hn hp

Y c t khi so vi H2 l 12,5. Hiu sut phn ng hidroho l: A. 70% B. 80% C. 60% D. 50% Cu 55: (H_B_12 ) Hn hp X gm 0,15 mol vinylaxetilen v 0,6 mol H2. Nung nng hn hp X (xt ni) mt thi gian thu c hn hp Y c t khi so vi H2 bng 10. dn ton b Y qua dd brom d , sau khi phn ng xy ra hon ton, khi lng brom tham gia phn ng l: A. 24gam B. 16gam C. 10 gam D. 8 gam Cu 56: (H_B_12 ) t chy hon ton hn hp X gm 2 hidrocacbon (t l s mol 1:1) c cng thc n gin nht khc nhau,thu c 2,2 gam CO2v 0,6 gam nc. Cc cht trong X l: A. 2ankadien B. mt anken v 1 ankin C. 2 anken D. 1 ankan v 1 ankin Cu 57: (H_B_12 ) Hidrat ho 2-metyl but-2-en (iu kin nhit thch hp) thu c sn phm chnh l: A. 3-metyl butan-2-ol B. 3-metyl butan-1-ol C. 2-metyl butan-2-ol D. 3-metyl butan-3-ol Cu 58: (C_A_12 ) Nung mt lng butan trong bnh kn (c xc tc thch hp) thu c hn hp kh X gm ankan v anken. T khi ca X so vi H2 l 21,75. Phn trm th tch ca butan trong X l: A. 33,33% B. 50 C. 66,67 D. 25 Cu 59: (C_A_12 ) t chy hon ton hn hp X gm 2 hidrocacbon k tip nhau trong dy ng ng, thu c 2,24 lt kh CO2(ktc) v 3,24 gam H2O. Hai Hidrocacbon trong X l: A. C2H2, C3H4 B. C2H4, C3H6 C. CH4, C2H6 D. C2H6, C3H8

II. DN XUT HAOLGEN ANCOL PHENOL

Cu 1 (C_07): S ancol bc hai, no, n chc, mch h l ng phn cu to ca nhau m phn t ca chng c phn trm khi lng cacbon bng 68,18% l A. 4 B. 3 C. 5 D. 2 Cu 2 (C_07): Cho cc cht c cng thc cu to nh sau: HO-CH 2-CH2-OH (X); HO-CH2-CH2-CH2-OH (Y); HOCH2-CH(OH)-CH2-OH (Z); CH3-CH2-O-CH2-CH3 (R); CH3-CH(OH)-CH2-OH (T). Nhng cht tc dng vi Cu(OH)2 to phc mu xanh lam l A. Z, R, T B. X, Y, R, T C. X, Y, Z, T D. X, Z, T Cu 3 (C_07): Hp cht hu c X (phn t c vng benzen) c cng thc phn t C 7H8O2 tc dng c vi Na v NaOH. Bit khi X tc dng vi Na, s mol H2 thu c bng s mol X phn ng, X tc dng vi NaOH theo t l mol 1:1. Cng thc cu to thu gn ca X l A. C6H5CH(OH)2 B. HOC6H4CH2OH C. CH3C6H3(OH)2 D. CH3OC6H4OH Cu 4 (C_08): Khi un nng hn hp ancol gm CH3OH v C2H5OH (xc tc H2SO4 c, 1400C) th s ete thu c ti a l A. 1 B. 3 C. 4 D. 2 Cu 5 (C_09): Trong thc t, phenol c dng sn xut A. nha poli(vinyl clorua), nha novolac v cht dit c 2,4-D. B. nha rezol, nha rezit v thuc tr su 666. C. poli(phenol-fomanehit), cht dit c 2,4-D v axit picric. D. nhc rezit, cht dit c 2,4-D v thuc n TNT. Cu 6 (H_A_07): Khi tch nc t mt cht X c cng thc phn t C4H10O to thnh 3 anken l ng phn ca nhau (tnh c ng phn hnh hc). Cng thc cu to thu gn ca X l A. CH3CH(CH3)CH2OH B. CH3CH(OH)CH2CH3 C. CH3OCH2CH2CH3 D. (CH3)3COH Cu 7 (H_A_07): Cho s sau C6H6
+Cl2 (t l 1:1) X Fe,to +NaOH c d to , Y p

Z. + axit HCl

Hai cht hu c Y, Z ln lt l

A. C6H6(OH)6, C6H6Cl6 B. C6H4(OH)2, C6H4Cl2 C. C6H5OH, C6H5Cl D. C6H5ONa, C6H5OH Cu 8 (H_B_07): S cht ng vi cng thc phn t C 7H8O (dn xut ca benzen) u tc dng vi dung dch NaOH l A. 1 B. 2 C. 3 D. 4 Cu 9 (H_B_07): Cc ng phn ng vi cng thc phn t C8H10O (u l dn xut ca benzen) c tnh cht: tch nc cho sn phm c th trng hp to polime, khng tc dng vi dung dch NaOH. S ng phn tho mn tnh cht trn l A. 1 B. 2 C. 3 D. 4 Cu 10 (H_A_08): Khi phn tch thnh phn ca mt ancol n chc X th thu c kt qu: tng khi lng ca cacbon v hiro gp 3,625 ln khi lng oxi. S ng phn ancol ng vi cng thc phn t ca X l A. 3 B. 4 C. 2 D. 1 Cu 11 (H_A_08): Khi tch nc t ancol 3-metylbutan-2-ol, sn phm chnh thu c l A. 3-metylbut-1-en B. 2-metylbut-2-en C. 3-metylbut-2-en D. 2-metylbut-3-en Cu 12 (H_B_08): Cho cc phn ng: HBr + C2H5OH (t0) C2H4 + Br2 C2H4 + HBr C2H6 + Br2 (askt, t l mol 1:1) S phn ng to ra C2H5Br l A. 1 B. 4 C. 3 D. 2 Cu 13 (H_B_08): nh hng ca nhm OH n gc C6H5- trong phn t phenol th hin qua phn ng gia phenol vi A. H2 (Ni, nung nng) B. nc Br2 C. dung dch NaOH D. Na kim loi Cu 14 (H_B_08): Cho s chuyn ho sau: Toluen
+Br2 (t l 1:1) X Fe,to +NaOH c d to , Y p

Z. + axit HCl d

Trong X, Y, Z u l hn hp ca cc cht hu c. Z c thnh phn chnh gm A. benzyl bromua v o-bromtoluen B. m-metylphenol v o-metylphenol C. o-metylphenol v p-metylphenol D. o-bromtoluen v p-bromtoluen Cu 15 (H_A_09): Hp cht hu c X tc dng c vi dung dch NaOH v dung dch brom nhng khng tc dng vi dung dch NaHCO3. Tn gi ca X l A. anilin. B. phenol. C. axit acrylic. D. metyl axetat. Cu 16 (H_A_09): Mt hp cht X cha ba nguyn t C, H, O c t l khi lng mC : mH : mO = 21 : 2 : 4. Hp cht X c cng thc n gin nht trng vi cng thc phn t. S ng phn cu to thuc loi hp cht thm ng vi cng thc phn t ca X l A. 3. B. 6. C. 4. D. 5. Cu 17 (H_B_09): Cho cc hp cht sau: (a) HOCH2-CH2OH. (b) HOCH2-CH2-CH2OH. (c) HOCH2-CH(OH)-CH2OH. (d) CH3-CH(OH)-CH2OH. (e) CH3-CH2OH. (f) CH3-O-CH2CH3. Cc cht u tc dng c vi Na, Cu(OH)2 l: A. (c), (d), (e). B. (a), (c), (d). C. (c), (d), (f). D. (a), (b), (c). Cu 18 (C_07): Khi thc hin phn ng tch nc i vi ancol X, ch thu c mt anken duy nht. t chy hon ton mt lng cht X ta thu c 5,6 lit kh CO2 ( ktc) v 5,4 gam nc. S ng phn cu to ph hp vi X l A. 2 B. 3 C. 4 D. 5 Cu 19 (C_07): t chy hon ton mt ancol X thu c CO2 v H2O c t l mol tng ng l 3 : 4. Th tch kh O2 cn dng t chy X bng 1,5 ln th tch CO2 thu c ( cng iu kin). Cng thc phn t ca X l A. C3H8O2 B. C3H8O C. C3H4O D. C3H8O3. Cu 20 (C_08): t chy hon ton mt ancol a chc, mch h X, thu c H2O v CO2 c t l mol tng ng l 3 : 2. Cng thc phn t ca X l A. C2H6O2. B. C2H6O C. C4H10O2. D. C3H8O2. Cu 21 (C_08): t chy hon ton hn hp M gm hai ancol X v Y l ng ng k tip ca nhau, thu c 0,3 mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H 2. Cng thc phn t ca X, Y l A. C3H6O, C4H8O B. C2H6O, C3H8O C. C2H6O2, C3H8O2 D. CH4O, C2H6O Cu 22 (H_A_07): Cho 15,6 gam hn hp 2 ancol n chc, k tip nhau trong dy ng ng tc dng ht vi 9,2 gam Na, thu c 24,5 gam cht rn. Hai ancol l A. C2H5OH v C3H7OH B. C3H5OH v C4H7OH C. C3H7OH v C4H9OH D. CH3OH v C2H5OH

Cu 23 (H_B_07): X l mt ancol no, mch h. t hon ton 0,05 mol X cn 5,6 gam oxi, thu c hi nc v 6,6 gam CO2. Cng thc ca X l A. C3H5(OH)3 B. C3H6(OH)2 C. C3H7OH D. C2H4(OH)2 Cu 24 (H_B_07): Cho m gam 1 ancol no, n chc X qua bnh CuO d, un nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi hi so vi H2 l 15,5. Gi tr ca m l A. 0,64 B. 0,46 C. 0,32 D. 0,92 Cu 25 (H_B_07): Khi t 0,1 mol cht X (dn xut ca benzen), khi lng CO 2 thu c nh hn 35,2g. Bit 1 mol X ch tc dng vi 1 mol NaOH. Cng thc cu to thu gn ca X l A. HOCH2C6H4COOH B. C6H4(OH)2 C. HOC6H4CH2OH D. C2H5C6H4OH Cu 26 (H_B_08): un nng mt ancol n chc X vi H2SO4 c trong iu kin nhit thch hp sinh ra cht hu c Y, t khi hi ca X so vi Y bng 1,6428. Cng thc phn t ca X l A. C4H8O B. C3H8O C. C2H6O D. CH4O Cu 27 (H_B_08): un nng hn hp gm hai ancol n chc, mch h, k tip nhau trong dy ng ng vi H2SO4 c 1400C. Sau khi phn ng kt thc thu c 6 gam hn hp gm 3 ete v 1,8 gam nc. Cng thc phn t ca hai ancol trn l A. CH3OH v C2H5OH B. C2H5OH v C3H7OH C. C3H5OH v C4H7OH D. C3H7OH v C4H9OH Cu 28 (H_A_09): Cho hn hp X gm hai ancol a chc, mch h, thuc cng dy ng ng. t chy hon ton hn hp X, thu c CO2 v H2O c t l mol tng ng l 3 : 4. Hai ancol l A. C3H5(OH)3 v C4H7(OH)3. B. C2H5OH v C4H9OH. C. C2H4(OH)2 v C4H8(OH)2. D. C2H4(OH)2 v C3H6(OH)2. Cu 29 (H_A_09): Khi t chy hon ton m gam hn hp hai ancol no, n chc, mch h thu c V lt kh CO2 ( ktc) v a gam H2O. Biu thc lin h gia m, a v V l: A. m = 2a - V/22,4 B. m = 2a - V/11,2 C. m = a + V/5,6 D. m = a - V/5,6 Cu 30 (H_A_09): un nng hn hp hai ancol n chc, mch h vi H2SO4 c, thu c hn hp gm cc ete. Ly 7,2 gam mt trong cc ete em t chy hon ton, thu c 8,96 lt kh CO2 ( ktc) v 7,2 gam H2O. Hai ancol l A. C2H5OH v CH2=CH-CH2-OH. B. C2H5OH v CH3OH. C. CH3OH v C3H7OH. D. CH3OH v CH2=CH-CH2-OH. Cu 31 (H_A_09): t chy hon ton 0,2 mol mt ancol X no, mch h cn va 17,92 lt kh O2 ( ktc). Mt khc, nu cho 0,1 mol X tc dng va vi m gam Cu(OH)2 th to thnh dung dch c mu xanh lam. Gi tr ca m v tn gi ca X tng ng l A. 9,8 v propan-1,2-iol. B. 4,9 v propan-1,2-iol. C. 4,9 v propan-1,3-iol. D. 4,9 v glixerol. Cu 32 (H_B_09): Cho X l hp cht thm; a mol X phn ng va ht vi a lt dung dch NaOH 1M. Mt khc, nu cho a mol X phn ng vi Na (d) th sau phn ng thu c 22,4a lt kh H2 ( ktc). Cng thc cu to thu gn ca X l A. HO-CH2-C6H4-OH. B. HO-C6H4-COOH. C. CH3-C6H3(OH)2. D. HO-C6H4-COOCH3. Cu 33 (DH-A-2010) t chy hon ton m gam hn hp 3 ancol n chc, thuc cng dy ng ng, thu c 3,808 lt kh CO2 (ktc) v 5,4 gam H2O. A. 5,24 B. 4,72 C. 7,42 D. 5,72 Cu 34 (H A- 2010) Mt hn hp M gm ancol no, n chc X v axit cacboxylic n chc Y, u mch h v c cng s nguyn t cacbon , tng s mol ca hai cht l 0,5 mol (s mol ca Y ln hn X). Nu t chy hon ton M th thu c 33,6 lt kh CO2( ktc) v 25,2 gam H2O. Mt khc nu un nng M vi H2SO4 c thc hin phn ng este ho (hiu sut 80%) th s gam este thu c l : A. 22,8 B. 18,24 C. 27,36 D. 34,2 Cu 35 (H A- 2010) Tch nc hn hp gm ancol etylic v ancol Y ch to ra 2 anken. t chy cng s mol mi ancol th lng nc sinh ra t anclo ny bng 5/3 ln lng nc sinh ra t ancol kia. Ancol Y l : A. CH3-CH2-CH(OH)-CH3 B. CH3-CH2-CH2-CH2-OH C. CH3-CH2-CH2-OH D. CH3-CH(OH)-CH3 Cu 36 (DH-B-2010) Hn hp X gm 1 ancol v 2 sn phm hp nc ca propen. T khi ca X so vi H 2 l bng 23. Cho m gam X i qua ng s ng CuO (d) nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp Y gm 3 cht hu c v hi nc, khi lng ng s gim 3,2 gam. Cho Y tc dng hon ton vi lng d dd AgNO 3 trong NH3, to ra 48,6 gam Ag. Phn trm khi lng ca propan-1-ol trong X l : A. 65,5% B. 16,3% C. 48,9% D. 83,7% Cu 37 (DH-B-2010) Cho 13,74gam 2,4,6-trinitrophenol vo bnh kn ri nung nhit cao. Sau khi phn ng xy ra hon ton, thu c X mol hn hp kh gm CO2, CO, N2 v H2. Gi tr ca X l : A. 0,6 B. 0,36 C. 0,54 D. 0,45 Cu 38 (DH-B-2010) t chy hon ton mt hn hp X gm 2 ancol (no, a chc, mch h, c cng snhm OH)

cn va V lt kh O2, thu c 11,2 lt kh CO2 v 12,6 gam H2O (cc kh o ktc). Gi tr ca V l : A. 14,56 B. 15.68 C. 11,2 D. 4,48 Cu 39 (DH-B-2010) C bao nhiu cht hu c mch h dng iu ch 4-metylpentan-2-ol ch bng phn ng cng H2 (xc tc Ni, nhit ) A. 3 B. 5 C. 2 D. 4 Cu 40 (DH-B-2010) Cho s phn ng : + O ( H + ,t 0 ) t0 Stiren + H 2 X + CuO ( Y + Br2 ) Z ) (H

Trong X, Y, Z u l sn phm chnh. Cng thc ca X,Y, Z ln lt l : A. C6H5CH0HCH3, C6H5COCH3 , C6H5COCH2Br B. C6H5CH2CH2OH, C6H5CH2CHO, C6H5CH2COOH C. C6H5CH2CH2OH, C6H5CH2CHO, m-BrC6H4CH2COOH D. C6H5CH0HCH3, C6H5COCH3 , m-BrC6H4COCH3 Cu 41 (H-B-2010) t chy hon ton m gam hn hp X gm 3 ancol (n chc, thuc cng dy ng ng), thu c 8,96 lt kh CO2(ktc) v 11,7 gam H2O. Mt khc nu un m gam X vi H2SO4 c th tng khi lng ete ti a thu c l : A. 7,85 gam B. 7,4 gam C. 6,5 gam D. 5,6 gam Cu 42 (C-a-2010) ng vi cng thc C3H6O c bao nhiu hp cht mch h bn khi tc dng vi H2 (xc tc Ni, nhit ) sinh ra ancol ? A. 3 B. 4 C. 2 D. 1 0 phn ng vi kim loi Na (d), thu c V lt kh H (ktc). Bit Cu 43 (C-a-2010) Cho 10 ml dd ancol etylic 46 2 khi lng ring ca ancol etylic nguyn cht bng 0,8g/ml. Gi tr ca V l : A. 0,896 B. 4,256 C. 3,36 D. 2,128 Cu 44 (C-a-2010) Oxi ho khng hon ton ancol isopropylic bng CuO nung nng, thu c cht hu c X. Tn X l : A. Dimetyl xeton B. Propanal C. Metyl phenyl xeton D. Metyl vinyl xeton Cu 45 (C-a-2010) Kh nng phn ng th nguyn t clo bng nhm -OH ca cc cht c xp theo chiu tng dn t tri sang phi l : A. phenyl clorua, propyl clorua, anlyl clorua B. anlyl clorua, phenyl clorua, propyl clorua, C. phenyl clorua, anlyl clorua , propyl clorua, D. anlyl clorua, propyl clorua, phenyl clorua Cu 47 (C-a-2010) Cho 4,6 gam mt ancol no, n chc, phn ng vi CuO nung nng, thu c 6,2 gam hn hp X gm anehit , nc v ancol d. Cho ton b lng hn hp X phn ng hon ton vi lng d dd AgNO 3 trong NH3, un nng, thu c m gam Ag. Gi tr ca m l : A. 21,6 B. 10,8 C. 43,2 D. 16,2 Cu 48 (C-a-2010) iu kin thch hp cht X phn ng vi cht Y to ra anehit axetic, cht X phn ng vi cht Z to ra ancol etylic. Cc cht X, Y, Z ln lt l : A. C2H4, O2, H2O B. C2H2 , H20 , H2 C. C2H2 , O2, H2O D. C2H4, H2O, CO Cu 49 (H-A-2011) Hp cht hu c X c vng benzen c CTPT trng CTGN.Trong X, t l khi lng cc nguyn t l m C :mH :mO=21 :2 :8. Bit khi X phn ng hon ton vi Na th thu c s mol kh H2 bng s mol ca X phn ng. X coa bao nhiu ng phn(cha vng benzen)tho mn tnh cht trn : A. 3 B. 9 C. 7 D. 10 Cu 50 (H-A-2011) Ancol etylic c iu ch t tinh bt bng phng php ln men vi hiu sut ton b qu trnh l 90%. Hp th ton b lng CO2 sinh ra khi ln men m gam tinh bt vo nc vi trong, thu c 330 gam kt ta v dd X. Bit khi lng ca X gim i so vi khi lng nc vi trong ban u l 132 gam. Gi tr ca m l : A. 324 B. 405 C. 297 D. 486 Cu 51 (H-A-2011) X, Y , Z l cc hp cht mch h, bn c cng CTPT C3H6O. X tc dng c vi Na v khng c phn ng trng bc. Y khng tc dng c vi Na nhng c phn ng trng bc. Z khng tc dng vi Na v khng c phn ng trng bc. Cc cht X, Y, Z ln lt l : A. CH3-CO-CH3, CH3-CH2-CHO, CH2=CH-CH2-OH B.CH3-CH2-CHO, CH3-CO-CH3, CH2=CH-CH2-OH C. CH2=CH-CH2-OH , CH3-CO-CH3, CH3-CH2-CHO, D. CH2=CH-CH2-OH , CH3-CH2-CHO, CH3-CO-CH3 Cu 51 (H-B-2011) Chia hn hp gm 2 ancol n chc X v Y (phn t khi ca X nh hn ca Y) l ng ng k tip thnh hai phn bng nhau. t chy hon ton phn 1 thu c 5,6 lt CO2(ktc) v 6,3 gam H2O un nng phn 2 vi H2SO4 c 140 oC to thnh 1,25gam hn hp 3 ete. Ho hi hon ton hn hp 3 ete trn thu c th tch hi bng th tch ca 0,42 gam N2 (trong cng iu kin, nhit , p sut) Hiu sut ca phn ng este X, Y ln lt l : A. 40% V 20% B. 25% V 35% C. 30% V 30% D. 20% V 40%

Cu 52 (H-B-2011) Cho phn ng C6H5-CH=CH2+KMnO4 C6H5COOK+K2CO3+MnO2+KOH+H2O Tng h s nguyn, ti gin ca tt c cc cht trong ptpu trn l : A. 24 B. 34 C. 27 D. 31 Cu 53 (C-A-2011) S ancol ng phn cu to ca nhauc CTPT l C5H12O, tc dng vi CuO un nng sinh ra xeton l : A. 3 B. 5 C. 4 D. 2 Cu 54 (C-A-2011) Cho m gam hn hp X gm phenol etanol phn ng hon ton vi Na(d) thu c 2,24 lt kh H2 (ktc). Mt khc phn ng hon ton ci m gam X cn 100ml dd NaOH 1M. Gi tr ca m l : A. 7,0 B. 10,5 C. 21,0 D. 14,0 Cu 55 (C-A-2011) t chy hon tn mt lng hn hp X gm 3 ancol thuc cng dy ng ngthu c 6,72 lt kh CO2 (ktc) v 9,9 gam H2O. Nu un nng cng vi lng hn hp X nh trnvi H2SO4 c nhit thch hp chuyn ht thnh ete th tng khi lng ete thu c l : A. 4,2 gam B. 6,45gam C. 7,4 gam D. 5,46gam Cu 56 (C-A-2011) un si hn hp gm propyl bromua, kali hidroxit, etanol thu c sn phm hu c l : A. propan-2-ol B. Propan C. Propin D. Propen Cu 57 (C-A-2011) S ng phn cu to ca nhau c CTPT l C8H10O, trong phn t c vng benzen, , tc dng vi Na, khng tc dng vi NaOH l : A. 6 B. 4 C. 7 D. 5 o Cu 58 (C-A-2011) Cht X tc dng vi benzen (xt, t ) to thnh etylbenzen. Cht X l : A. C2H2 B. CH4 C. C2H4 D. C2H6 Cu 59 (C-A-2012) Cho m gam hn hp hi X gm 2 ancol (n chc, bc 1, ng ng k tip) p/u vi CuO d, thu c hh hi Y gm nc v anehit. T khi hi ca Y so vi hidro bng 14,5. Cho ton b Y p/u hon ton vi lng d dd AgNO3 trong NH3, thu c 97,2 gam Ag. Gi tr ca m l : A. 14 B. 14,7 C. 10,1 D. 18,9 Cu 60 (C-A-2012) t chy hon ton m gam hh X gm 2 ancol n chc, cng dy ng ng, thu c 15,68 lt kh CO2 (ktc), v 17,1 gam nc. Mt khc thc hin pu este ha m gam X vi 15,6 gam axit axetic, thu c a gam este. Bit hiu sut pu este ha ca 2 ancol u bng 60%. Gi tr ca a l : A. 15,48 B. 25,79 C. 24,8 D. 14,88 Cu 61 (C-A-2012) S ancol bc mt l ng phn cu to ca nhau c CTPT C5H12O l : A. 4 B.1 C.8 D.3 Cu 62 (C-A-2012) Ln men 90kg glucozo thu c V lt ancol etylic (D=0,8g/ml) vi hiu sut ca qu trnh ln men l 80%. Gi tr ca V l : A. 71,9 B. 46 C. 23 D. 57,5 Cu 63 (C-A-2012) t chy hon ton hh X gm 2 ancol no, hai chc, mch h cn va V lt kh O 2, thu c V2 lt CO2 v a mol H2O. Cc kh o ktc, mi quan h V1, V2, a l : A. V1=2V2-11,2a B. V1=V2+22,4a C. V1=V2-22,4a D. V1=2V2+11,2a Cu 64 (H-A-2012) t chy hon ton 3 lt hn hp X gm 2 anken k tip nhau trong dy ng ng cn va 10,5 lt O2 (cc kh o cng nhit , p sut). Hidrat ha hon ton X trong k thch hp thu c hh ancol Y ,trong khi lng ancol bc hai =6/13 ln tng khi lng cc ancol bc 1. Phn trm khi lng ca ancol bc 1(c s nguyn t cacbon ln hn)trong Y l : A. 46,43% B. 10,88 C. 31,58 D. 7,89 Cu 65 (H-A-2012) Cc pht biu sau v phenol : (a) Phenol tan nhiu trong nc lnh (b) Phenol c tnh axit nhng phenol trog nc khng lm i mu qu tm (c) Phenol c dng sn xut phm nhum, cht dit nm mc. (d) Nguyn t H ca vng Benzen ca phenol d b thay th hn nguyn t H ca vng benzen. (e) Cho nc brom vo dd phenol thy xut hin kt ta S pht biu ng l : A. 4 B. 2 C. 5 D. 3 Cu 66 (H-A-2012) Trong ancol X, oxi chim 26,667% v khi lng. un nng X vi H 2SO4 c thu c anken Y . Phn t khi ca Y l : A. 42 B. 70 C. 28 D. 56 Cu 67 (H-A-2012) Cho dy cc hp cht thm : p-OH-CH2-C6H4-OH, p-OH-C6H4-COOC2H5, p-OH-C6H4-COOH, p-HCOO-C6H4-OH, p-CH3O-C6H4-OH. C bao nhiu cht trong dy tha mn ng thi 2 iu kin ? (a) Ch tc dng vi dd NaOH theo t l 1 :1 (b) Tc dng vi Na d to ra s mo H2 bng s mol cht phn ng. A. 3 B. 4 C. 1 D.2 Cu 68 (H-A-2012) t chy hon ton mt lng ancol X to ra 0,4 mol CO 2 v 0,5 mol H2O. X tc dng vi

Cu(OH)2 to dd mu xanh lam. Oxihoa X bng CuO to hp cht hu c a chc Y. Nhn xt no sau y ng vi X? A. Trong X c 3 nhm CH3 B. Hidrat ha but-2-en thu c X. C. Trong X c 2 nhm OH lin kt vi 2 nguyn t cacbon bc hai. D. X lm mt mu dd nc brom Cu 69 (H-B-2012) Cho hh X gm ancol metylic, etylen glicol v glixerol. t chy hon ton m gam X thu c 6,72 lt kh CO2(ktc). Cng m gam X trn cho tc dng vi Na d thu c ti a V lt kh H 2 (ktc). Gi tr ca V l : A. 6,72 B. 11,2 C. 5,6 D.3,36 Cu 70 (H-B-2012) Cho dy chuyn ha sau : o to CaC2 + H X + H 2 Y + H 2 ) Z 2O ( Pd / PbCO 3,t ) O ( HgSO 4, Tn gi ca X v Z ln lt l : A. etilen, ancol etylic B. Etan, etanal C. axetilen, ancol etylic D. axetilen,etilen glicol Cu 71 (H-B-2012) Hidrat ha 2-metyl but-2-en(k nhit , xc tc thch hp) thu c sp chnh l : A. 3-metylbutan-2-ol B . 3-metylbutan-1-ol C. 2-metylbutan-2-ol D. 2-metylbutan-3-ol Cu 72 (H-B-2012) Cho phenol ln lt tc dng vi : (CH3CO)2O v cc dd NaOH, HCl, Br2, HNO3, CH3COOH. S trng hp xy ra phn ng l : C. 1 D.4 A. 3 B. 2 Cu 73 (H-B-2012) t chy hon ton m gam hh X gm 2 ancol, thu c 13,44 lt kh CO2 (ktc) v 15,3 gam H2O. Mt khc cho m gam X tc dng vi Na(d), thu dc 4,48 lt kh H2 (ktc). Gi tr ca m l : A. 12,9 B.15,3 C.16,9 D.12,3

III. ANEHIT AXIT CACBOXYLIC

Cu 1 (C_08): t chy hon ton mt anehit X thu c s mol CO 2 bng s mol H2O. Nu cho X tc dng vi lng d dung dch AgNO3 trong NH3, un nng sinh ra s mol Ag gp bn ln s mol X phn ng. Cng thc ca X l A. HCHO B. HOC-CHO C. CH3CHO D. C2H5CHO. Cu 2 (C_08): Cho cc cht sau: CH3-CH2-CHO (1), CH2=CH-CHO (2), (CH3)2CH-CHO (3), CH2=CH-CH2-OH (4). Nhng cht phn ng hon ton vi lng d H2 (Ni, t0) cng to ra mt sn phm l A. (1), (2), (3) B. (1), (2), (4) C. (2), (3), (4) D. (1), (3), (4) Cu 3 (C_09): Qu trnh no sau y khng to ra anehit axetic? A. CH2=CH2 + H2O (t0, xc tc HgSO4) B. CH2=CH2 + O2 (t0, xc tc). 0 C. CH3COOCH=CH2 + dung dch NaOH (t ) D. CH3-CH2OH + CuO (t0) Cu 4 (C_09): Dy gm cc cht c th iu ch trc tip (bng mt phn ng) to ra axit axetic l A. CH3CHO, C2H5OH, C2H5COOCH3. B. CH3CHO, C6H12O6 (glucoz), CH3OH. C. CH3OH, C2H5OH, CH3CHO. D. C2H4(OH)2, CH3OH, CH3CHO. Cu 5 (H_A_07): Cho 0,1 mol anehit X tc dng vi lng d dung dch AgNO 3 trong dung dch NH3 , un nng thu c 43,2 gam Ag. Hiro ho X thu c Y, bit 0,1 mol Y phn ng va vi 4,6 gam Na. Cng thc cu to thu gn ca X l A. HCHO B. CH3CHO C. OHC-CHO D. CH3CH(OH)CHO Cu 6 (H_B_07): t chy hon ton a mol mt anehit X (mch h) to ra b mol CO2 v c mol H2O (bit b = a + c). Trong phn ng trng gng, mt phn t X ch cho 2 electron. X thuc dy ng ng anehit A. khng no c hai ni i, n chc. B. khng no c mt ni i, n chc C. no, n chc D. no, hai chc. Cu 7 (H_A_08): un nng V lit hi anehit X vi 3V lit H2 (xc tc Ni) n khi phn ng xy ra hon ton ch thu c hn hp kh Y c th tch 2V lit (cc th tch o cng iu kin nhit , p sut). Ngng t Y thu c cht Z; cho Z phn ng vi Na (d) sinh ra H2 c s mol bng s mol Z phn ng. Cht X l anehit A. khng no (cha mt ni i C=C), hai chc B. no, hai chc C. no, n chc D. khng no (cha mt ni i C=C), n chc Cu 8 (H_B_08): Axit cacboxylic no, mch h X c cng thc thc nghim (C3H4O3)n, vy cng thc phn t ca X l A. C6H8O6 B. C9H12O9 C. C12H16O12 D. C3H4O3. Cu 9 (H_A_09): Dy gm cc cht u iu ch trc tip (bng mt phn ng) to ra anehit axetic l: A. CH3COOH, C2H2, C2H4. B. C2H5OH, C2H4, C2H2. C. C2H5OH, C2H2, CH3COOC2H5. D. HCOOC2H3, C2H2, CH3COOH. Cu 10 (H_B_09): Khi cho a mol mt hp cht hu c X (cha C, H, O) phn ng hon ton vi Na hoc vi NaHCO3 th u sinh ra a mol kh. Cht X l A. etylen glicol. B. axit 3-hiroxipropanoic. C. axit aipic. D. ancol o-hiroxibenzylic. Cu 11 (C_07): Cho 2,9 gam mt anehit X phn ng hon ton vi lng d dung dch AgNO 3 trong NH3, ung nng, thu c 21,6 gam Ag. Cng thc cu to thu gn ca X l A. OHC-CHO B. HCHO C. CH2=CHCHO D. CH3CHO Cu 12 (C_07): Cho 5,76 gam axit hu c Y n chc, mch h tc dng ht vi CaCO 3 thu c 7,28 gam mui ca axit hu c. Cng thc cu to thu gn ca X l A. CH3COOH B. CH3-CH2-COOH C. CH2=CHCOOH D. CH2=CH-CH2COOH Cu 13 (C_08): Cho hn hp gm 0,1 mol HCHO v 0,1 mol HCOOH tc dng vi lng d dung dch AgNO 3 trong NH3, un nng. Sau phn ng xy ra hon ton, khi lng Ag to thnh l A. 21,6 gam B. 10,8 gam C. 43,2 gam D. 64,8 gam Cu 14 (C_09): Oxi ho m gam etanol thu c hn hp X gm axetanehit, axit axetic, nc v etanol d. Cho ton b X tc dng vi dung dch NaHCO 3 (d), thu c 0,56 lit kh CO2 ( ktc). Khi lng etanol b oxi ho to ra axit l A. 1,15 gam. B. 4,60 gam. C. 2,30 gam. D. 5,75 gam. Cu 15 (C_09): Trung ho 8,2 gam hn hp gm axit fomic v axit n chc X cn 100 ml dung dch NaOH 1,5M. Nu cho 8,2 gam hn hp trn tc dng vi lng d dung dch AgNO 3 trong NH3, ung nng th thu c 21,6 gam Ag. Tn gi ca X l

A. axit acrylic. B. axit propanoic. C. axit etanoic. D. axit metacrylic. Cu 16 (C_09): Cho 0,1 mol hn hp X gm hai anehit no, n chc, mch h, k tip nhau trong dy ng ng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 32,4 gam Ag. Hai anehit trong X l A. HCHO v C2H5CHO. B. HCHO v CH3CHO. C. C2H3CHO v C3H5CHO. D. CH3CHO v C2H5CHO. Cu 17 (H_A_07): t chy hon ton a mol axit hu c Y c 2a mol CO2. Mt khc, trung ho a mol Y cn va 2a mol NaOH. Cng thc cu to thu gn ca Y l A. HOOC-CH2-CH2-COOH B. C2H5-COOH C. HOOC-COOH D. CH3-COOH Cu 18 (H_A_07): Cho 6,6 gam mt anehit X n chc, mch h phn ng vi lng d AgNO3 (hoc Ag2O) trong dung dch NH3, un nng. Lng Ag sinh ra cho tc dng vi axit HNO 3 long, thot ra 2,24 lit kh NO (sn phm kh duy nht, o ktc). Cng thc cu to thu gn ca X l A. CH3CHO B. CH2=CHCHO C. HCHO D. CH3CH2CHO Cu 19 (H_B_07): trung ho 6,72 gam mt axit cacboxylic Y (no, n chc) cn 200 gam dung dch NaOH 2,24%. Cng thc ca Y l A. C3H7COOH B. C2H5COOH C. CH3COOH D. HCOOH Cu 20 (H_B_07): t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O 2 (o ktc), thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l A. 4,48 B. 6,72 C. 8,96 D. 11,2 Cu 21 (H_B_07): Oxi ho hon ton 2,2 gam mt anehit X n thu c 3 gam axit tng ng. Cng thc ca X l A. C2H5CHO B. C2H3CHO C. CH3CHO D. HCHO Cu 22 (H_A_08): Cho 3,6 gam anehit n chc X tc dng hon ton vi mt lng d dung dch AgNO 3 trong NH3 un nng, thu c m gam Ag. Ho tan hon ton m gam Ag bng dung dch HNO3 c, sinh ra 2,24 lit kh NO2 (sn phm kh duy nht, o ktc). Cng thc ca X l A. C3H7CHO B. HCHO C. C4H9CHO D. C2H5CHO Cu 23 (H_B_08): Cho 3,6 gam axit cacboxylic no, n chc X tc dng hon ton vi 500 ml dung dch gm KOH 0,12M v NaOH 0,12M. C cn dung dch thu c 8,28 gam hn hp cht rn. Cng thc phn t ca X l A. C2H5COOH B. C3H7COOH C. HCOOH D. CH3COOH Cu 24 (H_A_09): Cho hn hp kh X gm HCHO v H2 i qua ng s ng bt Ni nung nng. Sau khi phn ng xy ra hon ton, thu c hn hp kh Y gm hai cht hu c. t chy ht Y th thu c 11,7 gam H2O v 7,84 lt kh CO2 ( ktc). Phn trm theo th tch ca H2 trong X l A. 46,15%. B. 35,00%. C. 53,85%. D. 65,00%. Cu 25 (H_A_09): Cho 0,25 mol mt anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3, thu c 54 gam Ag. Mt khc, khi cho X phn ng vi H2 d (xc tc Ni, to) th 0,125 mol X phn ng ht vi 0,25 mol H2. Cht X c cng thc ng vi cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n+1CHO (n 0). C. CnH2n-1CHO (n 2). D. CnH2n-3CHO (n 2). Cu 26 (H_A_09): Cho hn hp X gm hai axit cacboxylic no, mch khng phn nhnh. t chy hon ton 0,3 mol hn hp X, thu c 11,2 lt kh CO2 ( ktc). Nu trung ha 0,3 mol X th cn dng 500 ml dung dch NaOH 1M. Hai axit l: A. HCOOH, HOOC-COOH. B. HCOOH, HOOC-CH2-COOH. C. HCOOH, C2H5COOH. D. HCOOH, CH3COOH. Cu 27 (H_B_09): Hn hp X gm axit Y n chc v axit Z hai chc (Y, Z c cng s nguyn t cacbon). Chia X thnh hai phn bng nhau. Cho phn mt tc dng ht vi Na, sinh ra 4,48 lt kh H2 ( ktc). t chy hon ton phn hai, sinh ra 26,4 gam CO2. Cng thc cu to thu gn v phn trm v khi lng ca Z trong hn hp X ln lt l A. HOOC-CH2-COOH v 54,88%. B. HOOC-COOH v 60,00%. C. HOOC-COOH v 42,86%. D. HOOC-CH2-COOH v 70,87%. Cu 28 (H_B_09): t chy hon ton mt hp cht hu c X, thu c 0,351 gam H2O v 0,4368 lt kh CO2 ( ktc). Bit X c phn ng vi Cu(OH)2 trong mi trng kim khi un nng. Cht X l A. C2H5CHO. B. O=CH-CH=O. C. CH2=CH-CH2-OH. D. CH3COCH3. Cu 29 (H_B_09): Hp cht hu c X tc dng c vi dung dch NaOH un nng v vi dung dch AgNO3 trong NH3. Th tch ca 3,7 gam hi cht X bng th tch ca 1,6 gam kh O2 (cng iu kin v nhit v p sut). Khi t chy hon ton 1 gam X th th tch kh CO2 thu c vt qu 0,7 lt ( ktc). Cng thc cu to ca X l A. HOOC-CHO. B. CH3COOCH3. C. HCOOC2H5. D. O=CH-CH2-CH2OH. Cu 30 (H_B_09): Hiro ho hon ton m gam hn hp X gm hai anehit no, n chc, mch h, k tip nhau

trong dy ng ng thu c (m + 1) gam hn hp hai ancol. Mt khc, khi t chy hon ton cng m gam X th cn va 17,92 lt kh O2 ( ktc). Gi tr ca m l A. 8,8. B. 10,5. C. 24,8. D. 17,8. Cu 31 (H_A_10): Cho 0,15 mol H2NC3H5(COOH)2 vo 175 ml dd HCl 2M, thu c dd X. Cho NaOH d vo dd X, sau khi pu xy ra hon ton s mol NaOH pu l: A. 0,5 B. 0,65 C. 0,55 D. 0,7 Cu 32 (H_A_10): Hn hp M gm ancol no, n chc X v axitcacboxylic n chc Y, u mch h v c cng s nguyn t C, tng s mol ca hai cht l 0,5mol(nY>nX) Nu t chy hon ton M thu c 33,6 lt kh CO 2 (ktc) v 25,2 gam H2O. Mt khc nu un nng M vi H 2SO4 c thc hin phn ng este ho (hiu sut 80%)th s gam este thu c l: A. 22,8 B. 18,24 C. 27,36 D. 34,2 Cu 33 (H_A_10): Axeton c iu ch bng cch oxi ho cumen nh oxi, sau thu phn trong dd H 2SO4 long. thu c 145 gam axeton th lng cumen cn dng (H=75%) l: A. 400gam B. 600 C. 500 D. 300 Cu 34 (H_A_10): Cho m gam hn hp etanal v propnl phn ng vi lng d dd AgNO 3 trong NH3., thu c 43,2gam kt ta v dd cha 17,5 gam mui amoni ca hai axit hu c. Gi tr ca m l: A. 10,2 B. 10,9 C. 9,5 D. 14,3 Cu 34 (H_A_10): Hn hp gm 0,1 mol mt axitcacboxylic n chc v 0,1 mol mui ca axit vi kim loi kim c tng khi lng l15,8 gam. Tn ca axit trn l: A. Axit etanoic B. Axit propanoic C. Axit butanoic D. Axit metanoic Cu 35 (H_A_10): Cho hn hp X gm ancol metylic v 2 axit cacboxylic (no, n chc, k tip nhau trog dy ng ng) tc dng ht vi Na, gii phng ra 6,72 lt kh H 2(ktc). Nu un nng hn hp X (c H 2SO4 c lm xt) th cc cht trong hn hp phn ng va vi nhau to 25 gam hn hp este (H=100%). Hai axit trong hn hp X l: A.CH3COOH, C2H5COOH B. HCOOH, CH3COOH C.C3H7COOH, C4H9COOH D.C2H5COOH, C3H7COOH Cu 36 (H_B_10): Hn hp X gm axit panmitic, axit stearic v axit linoleic. trug ho m gam X cn 40 ml dd NaOH 1M. Mt khc, nu t chy hon ton m gam X th thu c 15,232 lt kh CO2 (ktc) v 11,7 gam H2O. S mol ca axit linoleic trong m gam hn hp X l: A. 0,015 B. 0,01 C. 0,02 D. 0,005 Cu 37 (H_B_10): Hn hp Z gm 2 axit caboxylic n chc X, Y(M X>MY) c tng khi lng l 8,2 gam. Cho Z tc dng va vi dd NaOH , thu c dd cha 11,5 gam mui. Mt khc nu cho Z tc dng vi lng d dd AgNO3 trong NH3 thu c 21,6 gam Ag. Cong thc v % khi lng ca X trong Z l: A. C3H5COOH , 54,88% B. C2H3COOH, 43,9% C. C2H5COOH, 56,1% D. HCOOH, 45,12% Cu 38 (H_B_10): Cho hn hp M gm andehit X(no,n chc,mch h) v hirocacbon Y c tng s mol l 0,2. (nY<nX). t chy hon ton M, thu c 8,96 lt kh CO2 lt kh CO2 (ktc) v 7,2 gam H2O. Hirocacbon Y l: A. CH4 B. C2H2 C. C3H6 D. C2H4 Cu 39 (H_B_10): ........................................... Cu 40 (C_A_11): Cho s phn ng: o to to CH4 + X ( ) Y + Z ( ) T + M (t ) CH3COOH xt , xt , xt , (X,Z,M l cc cht c c) Cht T l: A. CH3CHO B. CH3COONa C. CH3OH D. C2H5OH Cu 41 (C_A_11): Hn hp G gm 2 andehit X v Y , trong Mx<M Y<1,6Mx. t chy hn hp G thu c s mol CO2= s mol H2O. Cho 0,1 mol hh G vo dd AgNO 3 trong NH3 thu c 0,25 mol Ag. Tng s nguyn t trong 1 ptu y l: A. 9 B.6 C. 10 D. 7 Cu 42(C_A_11) Dy gm cc cht xp theo chiu lc axit tng t tri sang phi l: A. HCOOH, CH3COOH, C2H5COOH B. CH3COOH, CH2ClCOOH, CHCl2COOH C. C6H5OH, CH3COOH, C2H5OH D. CH3COOH , HCOOH, (CH3)2CHCOOH Cu 43 (H_A_11) Hn hp X gm axit axetic, axit fomic, axit oxalic. Khi cho m gam X tc dng vi NaHCO3 (d) thu c 15,68 lt kh CO2 (ktc). Mt khc t chy hon ton m gam X cn 8,96 lt kh O2(ktc), thu dc 35,2 gam CO2 v y mol H2O. Gi tr ca y l: A. 0,8 B.0,3 C.0,2 D.0,6 Cu 44 (H_A_11) trung ha 3,88 gam hh X gm 2 axit cacboxylic no, n chc, mch h bng dd NaOH, c cn ton b dd sau pu dc 5,2gam mui khan. Nu t chy hon ton 3,88 gam X th th tch oxi (ktc) cn dng l:

A. 1,12 lt B. 3,36 C. 4,48 D. 2,24 Cu 45 (H_A_11) t chy hon ton x gam hh 2 axit cacboxylic 2 chc, mch h v u c 1 lin kt i C=C trong phn t, thu c V lt CO2 (ktc) v y mol H2O. Biu thc lin h gia x, y v V l: A. V=

28 28 28 28 (x-62y) B.V= (x+30y) C. V= (x-30y) D. V= (x+62y) 95 55 55 95

Cu 46 (H_A_11) t chy hon ton andehit X, thu c th tch CO2 =th tch hi nc.(trong cung k nhit , p sut). Khi cho 0,01 mol X tc dng vi mt lng d dd AgNO3, trong Nh3 th c 0,04 mol Ag. X l: A. Anehit fomic B. Anehit axetic C. Anehit khng no, mch h, 2 chc D.Anehit no, mch h, 2 chc Cu 47 (H_A_11) Ha hi 15,52gam hh gm 1 axit no n chc X v 1 axit no a chc Y( s mol X > s mol Y), thu c mt th tch hi bng th tch ca 5,6 gam N 2 (o cng nhit , p sut). Nu t chy ton b hh 2 axit trn thu c 10,752 lt CO2 (ktc). CTCT ca X, Y ln lt l: A. CH3COOH, HOOC-CH2-COOH B. HCOOH, HOOC-COOH C. CH3COOH, HOOC-CH2-CH2-COOH D. CH3CH2COOH, HOOC-COOH Cu 48 (H_B_11) hidro ha hon ton 0,025 mol hh X gm 2 andehit c khi lng 1,64 gam, cn 1,12lit H2(ktc). Mt khc cng cho lng X trn pu vi mt lng d dd AgNO 3 trong NH3 thu c 8,64 gam Ag. CTCT ca 2 anehit trong X l: A. HCHO, OHC-CH2-CHO B. CH2=C(CH3)CHO, OHC-CHO C. CH2=CH-CHO,OHC-CH2-CHO D.OHC-CH2-CHO, OHC-CHO Cu 49 (H_B_11) Hn hp M gn 1 andehit v 1 ankin(c cng s nguyn t cacbon). t chy hon ton x mol hh M, thu c 3x mol CO2 v 1,8x mol H2O. Phn trm s mol ca andehit trong hh M l: A. 40% B. 50 C. 20 D. 30 Cu 50 (H_B_11) Hn hp X gn 2 andehit n chc Y v Z (MY<MZ). Cho 1,89gam X tc dng vi mt lng d dd AgNO3 trong NH3, sau khi pu kt thc thu c 18,36 gam Ag v dd E. Cho ton b E tc dng vi dd HCl d thu c 0,784 lt CO2 (ktc). Tn ca Z l: A. andehit acrylic B.andehit butiric C.andehit axetic D. Andehit propionic Cu51 (H_B_12) : Cho 0,125 mol anehit mch h X phn ng vi lng d dung dch AgNO3 trong NH3 thu c 27 gam Ag. Mt khc, hiro ho hon ton 0,25 mol X cn va 0,5 mol H2. Dy ng ng ca X c cng thc chung l A. CnH2n(CHO)2 (n 0). B. CnH2n-3CHO (n 2). C. CnH2n+1CHO (n 0). D. CnH2n-1CHO (n 2). Cu 52 (H_B_12) : Hn hp X gm hai axit cacboxylic n chc. t chy hon ton 0,1 mol X cn 0,24 mol O2, thu c CO2 v 0,2 mol H2O. Cng thc hai axit l A. HCOOH v C2H5COOH. B. CH2=CHCOOH v CH2=C(CH3)COOH. C. CH3COOH v C2H5COOH. D. CH3COOH v CH2=CHCOOH. Cu 53 (H_B_12) : Cho axit cacboxylic X phn ng vi cht Y thu c mt mui c cng thc phn t C3H9O2N (sn phm duy nht). S cp cht X v Y tha mn iu kin trn l A. 3. B. 2. C. 4. D. 1. Cu 54 (C_B_12) : Trong phn t axit cacboxylic X c s nguyn t cacbon bng s nhm chc. t chy

hon ton mt lng X thu c s mol CO2 bng s mol H2O. Tn gi ca X l A. axit axetic. B. axit oxalic. C. axit fomic. D. axit malonic. Cu 55(C_B_12) Cho dy cc cht: etan, etanol, etanal, axit etanoic. Cht c nhit si cao nht trong dy l A. etanal. B. etan. C. etanol. D. axit etanoic Cu 56(C_B_12) : Cht no sau y va tc dng c vi dung dch NaOH, va tc dng c vi nc Br2? A. CH3CH2CH2OH. B. CH3COOCH3. C. CH3CH2COOH. D. CH2=CHCOOH. Cu 57 (C_B_12) : Cho dy cc cht: anehit axetic, axetilen, glucoz, axit axetic, metyl axetat. S cht trong dy c kh nng tham gia phn ng trng bc l A. 4. B. 5. C. 2. D. 3. Cu 58 (C_B_12) : Cho cc pht biu: (1) Tt c cc anehit u c c tnh oxi ho v tnh kh; (2) Tt c cc axit cacboxylic u khng tham gia phn ng trng bc; (3) Phn ng thy phn este trong mi trng axit l phn ng thun nghch; (4) Tt c cc ancol no, a chc u ha tan c Cu(OH)2. Pht biu ng l A. (2) v (4). B. (3) v (4). C. (1) v (3). D. (1) v (2).

Cu 59 (H_A_12) t chy hon ton 7,6 gam hn hp gm mt axit cacboxylic no, n chc, mch h v

mt ancol n chc (c s nguyn t cacbon trong phn t khc nhau) thu c 0,3 mol CO2 v 0,4 mol H2O. Thc hin phn ng este ha 7,6 gam hn hp trn vi hiu sut 80% thu c m gam este. Gi tr ca m l A. 4,08. B. 6,12. C. 8,16. D. 2,04. Cu 60 (H_A_12) Hn hp X gm axit fomic, axit acrylic, axit oxalic v axit axetic. Cho m gam X phn ng ht vi dung dch NaHCO3 thu c 1,344 lt CO2 (ktc). t chy hon ton m gam X cn 2,016 lt O2 (ktc), thu c 4,84 gam CO2 v a gam H2O. Gi tr ca a l A. 1,62. B. 1,80. C. 3,60. D. 1,44. Cu 61 (H_A_12) Ha hi 8,64 gam hn hp gm mt axit no, n chc, mch h X v mt axit no, a chc Y (c mch cacbon h, khng phn nhnh) thu c mt th tch hi bng th tch ca 2,8 gam N 2 (o trong cng iu kin nhit , p sut). t chy hon ton 8,64 gam hn hp hai axit trn thu c 11,44 gam CO2. Phn trm khi lng ca X trong hn hp ban u l A. 72,22% B. 65,15% C. 27,78% D. 35,25% H 3O + KCN Cu 62 (H_A_12) : Cho s chuyn ha : CH3Cl X Y t0 Cng thc cu to X, Y ln lt l: A. CH3NH2, CH3COOH B. CH3NH2, CH3COONH4 C. CH3CN, CH3COOH D. CH3CN, CH3CHO Cu 63 (H_A_12) : Dung dch X gm CH3COOH 0,03 M v CH3COONa 0,01 M. Bit 250C, Ka ca CH3COOH l 1,75.10-5, b qua s phn li ca nc. Gi tr pH ca dung dch X 250C l A. 6,28 B. 4,76 C. 4,28 D. 4,04

IV. ESTE LIPIT

Cu 1 (C_07): Polivinyl axetat l polime c iu ch bng phn ng trng hp A. C2H5COOCH=CH2 B. CH2=CHCOOC2H5. C. CH2=CHCOOCH3. D. CH3COOCH=CH2. Cu 2 (C_07): Este X khng no, mch h c t khi so vi oxi bng 3,125. X phng ho X thu c mt anehit v mt mui ca axit hu c. S cng thc cu to ph hp vi X l A. 4 B. 2 C. 3 D. 5 Cu 3 (C_07): Cho hp cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi dung dch AgNO3 trong NH3 ung nng thu c cht hu c T. Cho T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l A. CH3COOCH=CH2 B. HCOOCH=CH2. C. HCOOCH3. D. CH3COOCH=CH-CH3. Cu 4 (C_08): Cht hu c X c cng thc phn t C 4H6O4 tc dng vi dung dch NaOH (un nng) theo phng trnh phn ng: C4H6O4 + 2NaOH 2Z + Y oxi ho ht a mol Y th cn ht 2a mol CuO (un nng), sau phn ng to thnh a mol cht T (bit Y, Z, T l cc hp cht hu c). Khi lng phn t ca T l A. 118 vC B. 44 vC C. 82 vC D. 58 vC Cu 5 (C_09): S hp cht l ng phn cu to, c cng cng thc phn t C 4H8O2, tc dng c vi dung dch NaOH nhng khng tc dng c vi Na l A. 3. B. 2. C. 4 D. 1. Cu 6 (C_09): Pht biu no sau y sai? A. Nhit si ca este thp hn hn ancol c cng phn t khi. B. Trong cng nghip c th chuyn ho cht bo lng thnh cht bo rn. C. S nguyn t hiro trong phn t este n v a chc lun l mt s chn. D. Sn phm ca phn ng x phng ho cht bo l axit bo v glixerol. Cu 7 (H_A_07): Mnh khng ng l A. CH3CH2CH2COOCH=CH2 cng dy ng ng vi CH2=CHCOOCH3 B. CH3CH2CH2COOCH=CH2 tc dng vi dung dch NaOH to anehit v mui C. CH3CH2CH2COOCH=CH2 tc dng c vi dung dch Br2 D. CH3CH2CH2COOCH=CH2 c th trng hp to polime

Cu 8 (H_B_07): Cho glixerol phn ng vi hn hp axit bo panmitic v stearic, s loi trieste to ra ti a l A. 3 B. 4 C. 5 D. 6 Cu 9 (H_B_07): Thu phn este c cng thc C4H8O2 (xc tc axit), thu c 2 sn phm X v Y. T X c th iu ch trc tip ra Y. Vy X l A. Ancol metylic B. Axit fomic C. etyl axetat D. Ancol etylic Cu 10 (H_A_08): S ng phn este c cng thc phn t C4H8O2 l A. 5 B. 2 C. 4 D. 6 Cu 11 (H_A_08): Pht biu ng l: A. Phn ng gia axit v ancol khi c H2SO4 c l phn ng mt chiu. B. Tt c cc este phn ng vi dung dch kim lun thu c sn phm cui cng l mui v ancol C. Khi thu phn cht bo lun thu c C2H4(OH)2. D. Phn ng thu phn este trong mi trng axit l phn ng thun nghch Cu 12 (H_A_08): Cho glixerin trioleat (hay triolein) ln lt vo mi ng nghim cha ring bit: Na, Cu(OH) 2, CH3OH, dung dch brom, dung dch NaOH. Trong iu kin thch hp, s phn ng xy ra l A. 2 B. 3 C. 5 D. 4 Cu 13 (H_A_08): Cho s chuyn ho sau: C3H4O2 + NaOH X + Y X + H2SO4 long Z + T Bit Y v Z u c phn ng trng gng. Hai cht Y, Z l A. HCHO, CH3CHO B. HCHO, HCOOH C. CH3CHO, HCOOH D. HCOONa, CH3CHO Cu 14 (H_B_08): Khi t chy hon ton mt este no, n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l A. metyl fomat. B. metyl axetat C. n-propyl axetat D. etyl axetat Cu 15 (H_A_09): X phng ho mt hp cht c cng thc phn t C10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l: A. CH2=CH-COONa, CH3-CH2-COONa v HCOONa. B. HCOONa, CHC-COONa v CH3-CH2-COONa. C. CH2=CH-COONa, HCOONa v CHC-COONa. D. CH3-COONa, HCOONa v CH3-CH=CH-COONa. Cu 16 (C_07): un 12 gam axit axetic vi 13,8 gam etanol (c H 2SO4 c lm xc tc) n khi phn ng t ti trng thi cn bng, thu c 11 gam este. Hiu sut ca phn ng este ho l A. 50% B. 75% C. 55% D. 62,5% Cu 17 (C_07): Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lit CO2 ( ktc) v 3,6 gam nc. Nu cho 4,4 gam X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z. Tn ca X l A. isopropyl axetat B. etyl axetat C. metyl propionat D. etyl propionat Cu 18 (C_08): ung nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH (c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l A. 6,0 gam B. 4,4 gam C. 8,8 gam D. 5,2 gam Cu 19 (C_08): X phng ho 22,2 gam hn hp gm hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l A. 300 ml B. 200 ml C. 150 ml D. 400 ml Cu 20 (C_08): Este n chc X c t khi hi so vi CH 4 bng 6,25. Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M (un nng). C cn dung dch sau phn ng thu c 28 gam cht rn khan. Cng thc cu to thu gn ca X l A. CH2=CH-COO-CH2-CH3. B. CH3-CH2-COO-CH=CH2. C. CH3-COO-CH=CH-CH3. D. CH2=CH-CH2-COO-CH3. Cu 21 (C_09): Cho 20 gam mt este X (c phn t khi l 100 vC) tc dng vi 300 ml dung dch NaOH 1M. Sau phn ng, c cn dung dch thu c 23,2 gam cht rn khan. Cng thc cu to ca X l A. CH2=CHCH2COOCH3.B. CH3COOCH=CHCH3. C. C2H5COOCH=CH2. D. CH2=CHCOOC2H5. Cu 22 (H_A_07): X phng ho 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau phn ng xy ra hon ton, c cn dung dch thu c cht rn khan c khi lng l A. 3,28 gam B. 8,8 gam C. 8,56 gam D. 10,4 gam Cu 23 (H_A_07): Thu phn hon ton 444 gam mt lipit thu c 46 gam glixerol v 2 loi axit bo. Hai loi axit bo l A. C17H33COOH v C17H35COOH B. C17H31COOH v C17H33COOH C. C15H31COOH v C17H35COOH D. C17H33COOH v C15H31COOH Cu 24 (H_B_07): Mt este no, n chc X c t khi hi so vi metan l 5,5. un 2,2 gam X vi dung dch NaOH d, thu c 2,05 gam mui. Cng thc cu to thu gn ca X l

A. HCOOCH2CH2CH3 B. HCOOCH(CH3)2 C. C2H5COOCH3 D. CH3COOC2H5 Cu 25 (H_B_07): Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 (o cng iu kin). Cng thc cu to thu gn ca X v Y l A. C2H3COOC2H5 v C2H5COOC2H3 B. C2H5COOCH3 v HCOOCH(CH3)2 C. HCOOC2H5 v CH3COOCH3 D. HCOOCH2CH2CH3 v CH3COOC2H5 Cu 26 (H_B_08): Hp cht hu c no, a chc X c cng thc phn t C7H12O4. Cho 0,1 mol X tc dng va vi 100 gam dung dch NaOH 8% thu c cht hu c Y v 17,8 gam hn hp mui. Cng thc cu to thu gn ca X l A. CH3COO-(CH2)2-COOC2H5. B. CH3OOC-(CH2)2-COOC2H5. C. CH3COO-(CH2)2-OOCC2H5. D. CH3OOC-(CH2)2-COOC3H7. Cu 27 (H_B_08): X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l A. 18,24 gam B. 16,68 gam C. 18,38 gam D. 17,80 gam Cu 28 (H_A_09): X phng ho hon ton 1,99 gam hn hp hai este bng dung dch NaOH thu c 2,05 gam mui ca mt axit cacboxylic v 0,94 gam hn hp hai ancol l ng ng k tip nhau. Cng thc ca hai este l A. CH3COOCH3 v CH3COOC2H5. B. C2H5COOCH3 v C2H5COOC2H5. C. CH3COOC2H5 v CH3COOC3H7. D. HCOOCH3 v HCOOC2H5. Cu 29 (H_A_09): X phng ha hon ton 66,6 gam hn hp hai este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH, thu c hn hp X gm hai ancol. un nng hn hp X vi H2SO4 c 1400 C, sau khi phn ng xy ra hon ton thu c m gam nc. Gi tr ca m l A. 4,05. B. 8,10. C. 18,00. D. 16,20. Cu 30 (H_B_09): Hn hp X gm hai este no, n chc, mch h. t chy hon ton mt lng X cn dng va 3,976 lt kh O2 ( ktc), thu c 6,38 gam CO2. Mt khc, X tc dng vi dung dch NaOH, thu c mt mui v hai ancol l ng ng k tip. Cng thc phn t ca hai este trong X l A. C3H6O2 v C4H8O2. B. C2H4O2 v C5H10O2. C. C3H4O2 v C4H6O2. D. C2H4O2 v C3H6O2. Cu 31 (H_A_10): Thu phn hon ton 0,2 mol mt este E cn dng va 100g dd NaOH 24%, thu c mt ancol v 43,6gam hn hp mui ca hai axitcacboxylic n chc. Hai axit l: A.HCOOH, C2H5COOH B. HCOOH, CH3COOH C.CH3COOH, C2H5COOH D.C2H5COOH, C3H7COOH Cu 32 (H_A_10): t chy hon ton mt este n chc mch h X(phn t c s lin kt nh hn 3) thu c th tch CO2=6/7 th tch kh oxi phn ng(th tch kh o cng k)Cho m gam X tc dng hon ton vi 200ml dd KOH 0,7M thu c dd Y. Co cn dd Y thu c 12,88 gam cht rn khan. Gi tr ca m l: A. 6,66 B. 7,2 C. 10,56 D. 8,88 Cu 33 (H_B_10) Hp cht hu c mch h X c CTPT C6H10O4. Thu phn X to ra 2 ancol n chc c s nguyn t cacbon trong phn t gp i nhau. CTCT ca X l: A. CH3OCO-CH2-COO2H5 B. C2H5OCO-COOCH3 C. CH3OCO-COOC3H7 D. CH3OCO-CH2-CH2-COOC2H5 Cu 34 (H_B_10) Thu phn este Z trong mi trng axit thu c 2 cht hu c X, Y(MX<MY). Bng mt phn ng c th chuyn ho X thnh Y. Cht Z khng th l: A. metyl propionat B. Metyl axetat c. etyl axetat D. vinyl axetat Cu 35 (C_B_12) : Cho cc este: etyl fomat (1), vinyl axetat (2), triolein (3), metyl acrylat (4), phenyl axetat

(5). Dy gm cc este u phn ng c vi dung dch NaOH (un nng) sinh ra ancol l: A. (1), (2), (3). B. (1), (3), (4). C. (2), (3), (5). D. (3), (4), (5). Cu 36 (C_B_12) Cu 28: Cho dung dch cha m gam hn hp gm phenol (C6H5OH) v axit axetic tc dng va vi nc brom, thu c dung dch X v 33,1 gam kt ta 2,4,6-tribromphenol. Trung ha hon ton X cn va 500 ml dung dch NaOH 1M. Gi tr ca m l A. 21,4. B. 24,8. C. 33,4. D. 39,4. Cu 37 (C_B_12) Cu 45: Ha hi hon ton 4,4 gam mt este X mch h, thu c th tch hi bng th tch ca 1,6 gam kh oxi (o cng iu kin). Mt khc, thy phn hon ton 11 gam X bng dung dch NaOH d, thu c 10,25 gam mui. Cng thc ca X l A. C2H5COOCH3. B. CH3COOC2H5. C. C2H5COOC2H5. D. HCOOC3H7 Cu 38 (H_B_12) : t chy hon ton m gam hn hp X gm hai este ng phn cn dng 27,44 lt kh O2, thu c 23,52 lt kh CO2 v 18,9 gam H2O. Nu cho m gam X tc dng ht vi 400 ml dung dch NaOH 1M, c cn dung dch sau phn ng th thu c 27,9 gam cht rn khan, trong c a mol

mui Y v b mol mui Z (MY < MZ). Cc th tch kh u o iu kin tiu chun. T l a : b l A. 3 : 5. B. 3 : 2. C. 2 : 3. D. 4 : 3. Cu 39 (H_B_12) : Thy phn este X mch h c cng thc phn t C4H6O2, sn phm thu c c kh nng trng bc. S este X tha mn tnh cht trn l A. 6. B. 4. C. 5. D. 3. Cu 40 (H_B_12) : S trieste khi thy phn u thu c sn phm gm glixerol, axit CH3COOH v axit C2H5COOH l A. 2. B. 6. C. 4. D. 9. Cu 38 (H_B_12) : un nng m gam hn hp X gm cc cht c cng mt loi nhm chc vi 600 ml dung dch NaOH 1,15M, thu c dung dch Y cha mui ca mt axit cacboxylic n chc v 15,4 gam hi Z gm cc ancol. Cho ton b Z tc dng vi Na d, thu c 5,04 lt kh H2 (ktc). C cn dung dch Y, nung nng cht rn thu c vi CaO cho n khi phn ng xy ra hon ton, thu c 7,2 gam mt cht kh. Gi tr ca m l A. 34,51. B. 22,60. C. 34,30. D. 40,60. Cu 41 (H_B_12) : Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 22,35. B. 44,65. C. 33,50. D. 50,65. Cu 42 (H_B_12) : Cc polime thuc loi t nhn to l A. t visco v t xenluloz axetat. B. t nilon-6,6 v t capron. C. t visco v t nilon-6,6. D. t tm v t vinilon. Cu 43 (H_B_12) : Este X l hp cht thm c cng thc phn t l C9H10O2. Cho X tc dng vi dung dch NaOH, to ra hai mui u c phn t khi ln hn 80. Cng thc cu to thu gn ca X l A. HCOOC6H4C2H5. B. C2H5COOC6H5. C. CH3COOCH2C6H5. D. C6H5COOC2H5 Cu 44 (H_A_11) Este X c to thnh t etylen glicol v hai axit cacboxylic n chc. Trong phn t este, s nguyn t cacbon nhiu hn s nguyn t oxi l 1. Khi cho m gam X tc dng vi dung dch NaOH (d) th lng NaOH phn ng l 10 gam. Gi tr ca m l A. 14,5. B. 17,5. C. 15,5. D. 16,5. Cu 45 (H_A_11) : t chy hon ton 0,11 gam mt este X (to nn t mt axit cacboxylic n chc v mt ancol n chc) thu c 0,22 gam CO2 v 0,09 gam H2O. S este ng phn ca X l A. 5. B. 4. C. 6. D. 2. Cu 46 (H_B_11) : Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55 gam hn hp mui khan. Khi lng NaOH tham gia phn ng l A. 30 gam. B. 31,45 gam. C. 31 gam. D. 32,36 gam. Cu 47 (H_B_11) : Khi cho 0,15 mol este n chc X tc dng vi dung dch NaOH (d), sau khi phn ng kt thc th lng NaOH phn ng l 12 gam v tng khi lng sn phm hu c thu c l 29,7 gam. S ng phn cu to ca X tho mn cc tnh cht trn l A. 4. B. 2. C. 6. D. 5. Cu 48 (H_B_11) : Trong qu gc chn rt giu hm lng A. vitamin A. B. -caroten C. ete ca vitamin A. D. este ca vitamin A. . Cu 50 (C_A_11) x phng ho hon ton 52,8 gam hn hp hai este no, n chc, mch h l ng phn ca nhau cn va 600 ml dung dch KOH 1M. Bit c hai este ny u khng tham gia phn ng trng bc. Cng thc ca hai este l A. C2H5COOC2H5 v C3H7COOCH3. B. C2H5COOCH3 v CH3COOC2H5. C. HCOOC4H9 v CH3COOC3H7. D. CH3COOC2H5 v HCOOC3H7 Cu 51 (C_A_11) : Cho m gam cht hu c n chc X tc dng va vi 50 gam dung dch NaOH 8%, sau khi phn ng hon ton thu c 9,6 gam mui ca mt axit hu c v 3,2 gam mt ancol. Cng thc ca X l A. CH3COOCH=CH2. B. CH3COOC2H5. C. C2H5COOCH3. D. CH2=CHCOOCH3 Cu 52 (C_A_11) : Este X no, n chc, mch h, khng c phn ng trng bc. t chy 0,1 mol X ri cho sn phm chy hp th hon ton vo dung dch nc vi trong c cha 0,22 mol Ca(OH)2 th vn thu c kt ta. Thu phn X bng dung dch NaOH thu c 2 cht hu c c s nguyn t cacbon trong phn t bng nhau. Phn trm khi lng ca oxi trong X l

A. 37,21%.

B. 36,36%.

C. 43,24%.

D. 53,33%.

Cu 53 (H_A_12) Kh este no, n chc, mch h X bng LiAlH 4, thu c ancol duy nht Y. t chy

hon ton Y thu c 0,2 mol CO2 v 0,3 mol H2O. t chy hon ton 0,1 mol X thu c tng khi lng CO2 v H2O l A. 24,8 gam B. 28,4 gam C. 16,8 gam D. 18,6 gam
Cu 54 (H_A_12) : Cho s chuyn ha sau:

(a) C3H4O2 + NaOH X + Y (b) X + H2SO4 (long) Z + T (c) Z + dung dch AgNO3/NH3 (d) E + Ag + NH4NO3 (d) Y + dung dch AgNO3/NH3 (d) F + Ag +NH4NO3 Cht E v cht F theo th t l A. (NH4)2CO3 v CH3COOH B. HCOONH4 v CH3COONH4 C. (NH4)2CO3 v CH3COONH4 D. HCOONH4 v CH3CHO Cu 55 (H_A_12) : Cho cc pht biu sau: (a) t chy hon ton este no, n chc, mch h lun thu c s mol CO2 bng s mol H2O. (b) Trong hp cht hu c nht thit phi c cacbon v hiro. (c) Nhng hp cht hu c c thnh phn nguyn t ging nhau, thnh phn phn t hn km nhau mt hay nhiu nhm CH2 l ng ng ca nhau. (d) Dung dch glucoz b kh bi AgNO3 trong NH3 to ra Ag. (e) Saccaraz ch c cu to mch vng. S pht biu ng l A. 4. B. 5. C. 3. D. 2

V. CACBOHIRAT
Cu 1 (H_A_07): chng minh trong phn t ca glucoz c nhiu nhm hiroxyl, ngi ta cho dung dch glucoz phn ng vi A. Cu(OH)2 trong NaOH, un nng B. Kim loi Na C. Cu(OH)2 nhit thng D. AgNO3 (hoc Ag2O) trong dung dch NH3, un nng Cu 2 (H_B_07): Pht biu khng ng l A. dung dch mantoz phn ng vi Cu(OH)2 khi un nng cho kt ta Cu2O B. Sn phm thu phn xenluloz (xc tc axit, un nng) c th tham gia phn ng trng gng C. thu phn (xc tc axit, un nng) sacaroz cng nh mantoz u cho cng mt monosacarit. D. dung dch fructoz ho tan c Cu(OH)2 Cu 3 (C_08): Cho dy cc cht: glucoz, xenluloz, saccaroz, tinh bt, mantoz. S cht trong dy tham gia phn ng trng gng l A. 4 B. 5 C. 2 D. 3 Cu 4 (H_A_07): Cho m gam tinh bt ln men thnh ancol etylic vi hiu sut 81%. Ton b lng CO 2 sinh ra c hp th hon ton vo dung dch Ca(OH) 2, thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm 100 gam kt ta. Gi tr ca m l A. 550 B. 650 C. 750 D. 810 Cu 5 (C_07): Cho 50 ml dung dch glucoz cha r nng tc dng vi lng d dung dch AgNO3 trong NH3, un nng thu c 2,16 gam kt ta Ag. Nng mol/l ca dung dch glucoz dng l A. 0,20M B. 0,01M C. 0,10M D. 0,02M Cu 6 (H_B_07): Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc axit sunfuric c, nng. c 29,7 kg Xenluloz trinitrat , cn dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr m l A. 30 B. 42 C. 21 D. 10 Cu 7 (H_A_08): Gluxit (cacbohirat) ch cha hai gc glucoz trong phn t l A. saccaroz B. tinh bt C. mantoz D. xenluloz Cu 8 (H_A_08): Tinh bt, xenluloz, saccaroz v mantoz u c kh nng tham gia phn ng A. ho tan Cu(OH)2 B. trng ngng C. trng gng D. thu phn Cu 9 (H_B_08): Khi lng ca tinh bt cn dng trong qu trnh ln men to thnh 5 lit ancol etylic 460 l (bit hiu sut ca c qu trnh l 72% v khi lng ring ca ancol etylic nguyn cht l 0,8 g/ml)

A. 5,0 kg B. 5,4 kg C. 6,0 kg D. 4,5 kg Cu 10 (H_B_08): Th tch dung dch HNO3 67,5% (khi lng ring l 1,5 g/ml) cn dng tc dng vi xenluloz to thnh 89,1 kg xenluloz trinitrat l (bit lng HNO3 b hao ht l 20%) A. 70 lit B. 49 lit C. 81 lit D. 55 lit Cu 11 (C_08): T 16,20 tn xenluloz ngi ta sn xut c m tn xenluloz trinitrat (bit hiu sut phn ng tnh theo xenluloz l 90%). Gi tr ca m l A. 33,00 B. 29,70 C. 25,46 D. 26,73 Cu 12 (C_09): Cho cc chuyn ho sau: X + H2O Y Y + H2 sobitol Y + 2AgNO3 + 3NH3 + H2O amoni gluconat + 2Ag + NH4NO3. YE+Z Z + H2O X + G. X, Y v Z ln lt l A. xenluloz, fructoz v kh cacbonic. B. tinh bt, glucoz v ancol etylic. C. xenluloz, glucoz v kh cacbon oxit. D. tinh bt, glucoz v kh cacbonic. Cu 13 (C_09): Th tch dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut 59,4 kg xeluloz trinitrat (hiu sut 80%) l A. 42,34 lit. B. 42,86 lit. C. 34,29 lit. D. 53,57 lit. Cu 14 (H_A_09): Cacbohirat nht thit phi cha nhm chc ca A. ancol. B. xeton. C. amin. D. anehit. Cu 15 (H_B_09): Cho mt s tnh cht: c dng si (1); tan trong nc (2); tan trong nc Svayde (3); phn ng vi axit nitric c (xc tc axit sunfuric c) (4); tham gia phn ng trng bc (5); b thu phn trong dung dch axit un nng (6). Cc tnh cht ca xenluloz l: A. (2), (3), (4) v (5). B. (1), (3), (4) v (6). C. (3), (4), (5) v (6). D. (1), (2), (3) v (4). Cu 16 (H_B_09): Pht biu no sau y l ng? A. Amilopectin c cu trc mch phn nhnh. B. Glucoz b kh bi dung dch AgNO3 trong NH3. C. Xenluloz c cu trc mch phn nhnh. D. Saccaroz lm mt mu nc brom. Cu 17 (H_B_11) Cu 7: Cho cc pht biu sau v cacbohirat:

(a) Glucoz v saccaroz u l cht rn c v ngt, d tan trong nc. (b) Tinh bt v xenluloz u l polisaccarit. (c) Trong dung dch, glucoz v saccaroz u ho tan Cu(OH)2, to phc mu xanh lam. (d) Khi thu phn hon ton hn hp gm tinh bt v saccaroz trong mi trng axit, ch thu c mt loi monosaccarit duy nht. (e) Khi un nng glucoz (hoc fructoz) vi dung dch AgNO3 trong NH3 thu c Ag. (g) Glucoz v saccaroz u tc dng vi H2 (xc tc Ni, un nng) to sobitol. S pht biu ng l A. 4. B. 6. C. 5. D. 3. Cu 18 (H_B_11) : Cho cc pht biu sau: (a) C th dng nc brom phn bit glucoz v fructoz. (b) Trong mi trng axit, glucoz v fructoz c th chuyn ho ln nhau. (c) C th phn bit glucoz v fructoz bng phn ng vi dung dch AgNO3 trong NH3. (d) Trong dung dch, glucoz v fructoz u ho tan Cu(OH)2 nhit thng cho dung dch mu xanh lam. (e) Trong dung dch, fructoz tn ti ch yu dng mch h. (g) Trong dung dch, glucoz tn ti ch yu dng vng 6 cnh (dng v ). S pht biu ng l A. 4. B. 2. C. 3. D. 5. Cu 19 (H_B_11) : Thu phn hn hp gm 0,02 mol saccaroz v 0,01 mol mantoz mt thi gian thu c dung dch X (hiu sut phn ng thy phn mi cht u l 75%). Khi cho ton b X tc dng vi mt lng d dung dch AgNO3 trong NH3 th lng Ag thu c l A. 0,12 mol. B. 0,090 mol. C. 0,095 mol. D. 0,06 mol. Cu 20 (H_A_11) : Khi ni v peptit v protein, pht biu no sau y l sai? A. Tt c cc protein u tan trong nc to thnh dung dch keo. B. Protein c phn ng mu biure vi Cu(OH)2.

C. Lin kt ca nhm CO vi nhm NH gia hai n v -amino axit c gi l lin kt peptit. D. Thy phn hon ton protein n gin thu c cc -amino axit. Cu 21 (H_A_11) : Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 3,67 tn. B. 2,97 tn. C. 1,10 tn. D. 2,20 tn. Cu 23 (C_A_12) C mt s nhn xt v cacbohirat nh sau: (1) Saccaroz, tinh bt v xenluloz u c th b thu phn. (2) Glucoz, fructoz, saccaroz u tc dng c vi Cu(OH)2 v c kh nng tham gia phn ng trng bc. (3) Tinh bt v xenluloz l ng phn cu to ca nhau. (4) Phn t xenluloz c cu to bi nhiu gc -glucoz. (5) Thu phn tinh bt trong mi trng axit sinh ra fructoz. Trong cc nhn xt trn, s nhn xt ng l A. 2. B. 4. C. 3. D. 5. Cu 24 (C_A_12) : Cho cc cht: saccaroz, glucoz, fructoz, etyl fomat, axit fomic v anehit axetic. Trong cc cht trn, s cht va c kh nng tham gia phn ng trng bc va c kh nng phn ng vi Cu(OH)2 iu kin thng l A. 3. B. 5. C. 4. D. 2. Cu 25 (C_A_12) : Ln men dung dch cha 300 gam glucoz thu c 92 gam ancol etylic. Hiu sut qu trnh ln men to thnh ancol etylic l A. 54%. B. 40%. C. 80%. D. 60%. Cu 26 (C_A_12) Cho cc pht biu sau: (1) Fructoz v glucoz u c kh nng tham gia phn ng trng bc; (2) Saccaroz v tinh bt u khng b thy phn khi c axit H2SO4 (long) lm xc tc; (3) Tinh bt c to thnh trong cy xanh nh qu trnh quang hp; (4) Xenluloz v saccaroz u thuc loi isaccarit. Pht biu ng l A. (3) v (4). B. (1) v (3). C. (1) v (2). D. (2) v (4). Cu 27 (C_A_12) : Ln men 90 kg glucoz thu c V lt ancol etylic (D = 0,8 g/ml) vi hiu sut ca qu trnh ln men l 80%. Gi tr ca V l A. 71,9. B. 46,0. C. 23,0. D. 57,5. Cu 28 (H_B_12) : Thy phn hn hp gm 0,01 mol saccaroz v 0,02 mol mantoz trong mi trng axit, vi hiu sut u l 60% theo mi cht, thu c dung dch X. Trung ha dung dch X, thu c dung dch Y, sau cho ton b Y tc dng vi lng d dung dch AgNO3 trong NH3, thu c m gam Ag. Gi tr ca m l A. 7,776. B. 6,480. C. 8,208. D. 9,504 Cu 29 (H_B_12) : iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 24. B. 40. C. 36. D. 60. Cu 30 (H_B_12) : : Cc polime thuc loi t nhn to l A. t visco v t xenluloz axetat. B. t nilon-6,6 v t capron. C. t visco v t nilon-6,6. D. t tm v t vinilon. Cu 31 (H_A_12): Cho cc pht biu sau v cacbohirat: (a) Tt c cc cacbohirat u c phn ng thy phn. (b) Thy phn hon ton tinh bt thu c glucoz. (c) Glucoz, fructoz v mantoz u c phn ng trng bc. (d) Glucoz lm mt mu nc brom. S pht biu ng l: A. 3 B. 4 C. 1 D. 2

VI. AMIN AMINO AXIT - PROTEIN

Cu 1 (C_08): Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 5 B. 2 C. 3 D. 4 Cu 2 (C_09): S ng phn cu to ca amin bc mt c cng cng thc phn t C4H11N l A. 4. B. 2. C. 5. D. 3 Cu 3 (C_09): Cht X c cng thc phn t C3H7O2N v lm mt mu dung dch Brom. Tn gi ca X l A. metyl aminoaxetat. B. axit -aminopropionic. C. axit -aminopropionic. D. amoni acrylat. Cu 4 (C_09): Cht X c cng thc phn t C4H9O2N. Bit: X + NaOH Y + CH4O Y + HCl (d) Z + NaCl Cng thc cu to ca X v Z ln lt l A. H2NCH2CH2COOCH3 v CH3CH(NH3Cl)COOH. B. CH3CH(NH2)COOCH3 v CH3CH(NH3Cl)COOH. C. CH3CH(NH2)COOCH3 v CH3CH(NH2)COOH. D. H2NCH2COOC2H5 v ClH3NCH2COOH. Cu 5 (H_B_07): Mt trong nhng im khc nhau ca protit so vi lipit v glucoz l A. Protit lun l cht hp cht no B. Protit lun cha chc hiroxyl C. Protit c khi lng phn t ln hn D. Protit lun cha nit Cu 6 (H_B_07): Dy cc cht lm qu tm m thnh xanh l A. anilin, metyl amin, amoniac B. Amoni clorua, metyl amin, natri hiroxit C. anilin, amoniac, natri hiroxit D. Metyl amin, amoniac, natri axetat Cu 7 (H_B_07): Cho cc loi hp cht: aminoaxit (X), mui amoni ca axit cacboxylic (Y), amin (Z), este ca aminoaxit (T). Dy gm cc loi hp cht u tc dng vi dung dch NaOH v u tc dng vi dung dch HCl l A. X, Y, Z, T B. X, Y, T C. X, Y, Z D. Y, Z, T Cu 8 (H_A_08): Pht biu khng ng l: A. Trong dung dch H2N-CH2-COOH cn tn ti dng ion lng cc H3N+-CH2-COO-. B. Aminoaxit l hp cht hu c tp chc, phn t cha ng thi nhm amino v nhm cacboxyl C. Aminoaxit l nhng cht rn, kt tinh, tan tt trong nc v c v ngt D. Hp cht H2N-CH2-COOH3N-CH3 l este ca glyxin (hay glixin) Cu 9 (H_A_08): Cho cc dung dch ring bit sau: C6H5-NH3Cl (phenylamoni clorua), ClH3N-CH2-COOH, H2N-CH2-CH2-CH(NH2)-COOH, HOOC-CH2-CH2-CH(NH2)-COOH, H2N-CH2-COONa. S lng cc dung dch c pH < 7 l A. 2 B. 5 C. 4 D. 3 Cu 10 (H_B_08): Cht phn ng vi dung dch FeCl3 cho kt ta l A. CH3OHB. CH3NH2 C. CH3COOCH3 D. CH3COOH Cu 11 (H_B_08): un nng cht H2N-CH2-CONH-CH(CH3)-CONH-CH2-COOH trong dung dch HCl (d), sau khi phn ng kt thc thu c sn phm l A. H3N+-CH2-COOHCl-, H3N+-CH(CH3)-COOHCl-. B. H3N+-CH2-COOHCl-, H3N+-CH2-CH2-COOHCl-. C. H2N-CH2-COOH, H2N-CH(CH3)-COOH. D. H2N-CH2-COOH, H2N-CH2-CH2-COOH. Cu 12 (H_B_08): Hp cht hu c X c cng thc phn t C2H8O3N2 tc dng vi dung dch NaOH, thu c cht hu c n chc Y v cc cht v c. Khi lng phn t (theo vC) ca Y l A. 85 B. 45 C. 68 D. 46 Cu 13 (H_A_09): Thuc th c dng phn bit Gly-Ala-Gly vi Gly-Ala l A. dung dch NaOH. B. dung dch NaCl C. Cu(OH)2 trong mi trng kim. D. dung dch HCl. Cu 14 (H_B_09): Cho hai hp cht hu c X, Y c cng cng thc phn t l C3H7NO2. Khi phn ng vi dung dch NaOH, X to ra H2NCH2COONa v cht hu c Z; cn Y to ra CH2=CHCOONa v kh T. Cc cht Z v T ln lt l A. C2H5OH v N2. B. CH3NH2 v NH3. C. CH3OH v NH3. D. CH3OH v CH3NH2. Cu 15 (H_B_09): S ipeptit ti a c th to ra t mt hn hp gm alanin v glyxin l A. 2. B. 3. C. 4. D. 1. Cu 16 (C_07): trung ho 25 gam dung dch ca mt amin n chc X nng 12,4% cn dng 100 ml dung dch HCl 1M. Cng thc phn t ca X l A. CH5N B. C2H7N C. C3H7N D. C3H5N

Cu 17 (C_07): Hp cht X c cng thc phn t trng vi cng thc n gin nht, va tc dng c vi axit va tc dng c vi kim trong iu kin thch hp. Trong phn t ca X, thnh phn phn trm khi lng cc nguyn t C, H, N ln lt bng 40,449%; 7,865%; 15,73%; cn li l oxi. Khi cho 4,45 gam X phn ng hon ton vi mt lng va dung dch NaOH (un nng) thu c 4,85 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCOOCH2CH3. B. H2NCH2COOCH3. C. H2NCH2CH2COOH D. CH2=CHCOONH4. Cu 18 (C_08): Cho 5,9 gam amin n chc X tc dng va vi dung dch HCl, sau khi phn ng xy ra hon ton thu c dung dch Y. Lm bay hi dung dch Y c 9,55 gam mui khan. S cng thc cu to ng vi cng thc phn t ca X l A. 5 B. 2 C. 3 D. 4 Cu 19 (C_08): Trong phn t aminoaxit X c mt nhm amino v mt nhm caboxyl. Cho 15,0 gam X tc dng va vi dung dch NaOH, c cn dung dch sau phn ng thu c 19,4 gam mui khan. Cng thc ca X l A. H2NC4H8COOH B. H2NC3H6COOH C. H2NC2H4COOH D. H2NCH2COOH. Cu 10 (C_09): Thu phn 1250 gam protein X thu c 425 gam alanin. Nu phn t khi ca X bng 100.000 vC th s mt xch alanin c trong phn t ca X l A. 453. B. 382. C. 328. D. 479. Cu 21 (H_A_07): t chy hon ton mt amin n chc X, thu c 8,4 lit kh CO2, 1,4 lit N2 (cc th tch kh o ktc) v 10,125 gam nc. Cng thc phn t ca X l A. C3H7N B. C2H7N C. C3H9N D. C4H9N Cu 22 (H_A_07): -aminoaxit X cha mt nhm NH2. Cho 10,3 gam X tc dng vi axit HCl (d), thu c 13,95 gam mui khan. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH B. CH3CH2CH(NH2)COOH C. CH3CH(NH2)COOH D. H2NCH2COOH Cu 23 (H_A_07): t chy hon ton mt lng cht hu c X thu c 3,36 lit kh CO2, 0,56 lit kh N2 (cc th tch kh o ktc) v 3,15 gam nc. Khi X tc dng vi dung dch NaOH thu c sn phm c mui H2N-CH2-COONa. Cng thc cu to thu gn ca X l A. H2N-CH2-COO-C3H7 B. H2N-CH2-COO-C2H5 C. H2N-CH2-CH2-COOH D. H2N-CH2-COO-CH3 Cu 24 (H_A_07): Cho hn hp X gm hai cht hu c c cng cng thc phn t C 2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lit hn hp Z (ktc) gm hai kh u lm xanh qu tm m. T khi ca Z i vi Hiro bng 13,75. C cn dung dch Y c khi lng hn hp mui khan l A. 8,9 gam B. 14,3 gam C. 16,5 gam D. 15,7 gam Cu 25 (H_B_08): Cho 8,9 gam mt hp cht hu c X c cng thc phn t C 3H7O2N phn ng vi 100 ml dung dch NaOH 1,5M. Sau khi phn ng xy ra hon ton, c cn dung dch thu c 11,7 gam cht rn. Cng thc cu to thu gn ca X l A. H2NCH2CH2COOH B. H2NCH2COOCH3. C. CH2=CHCOONH4. D. HCOOH3NCH=CH2. Cu 26 (H_A_09): Cho 1 mol amino axit X phn ng vi dung dch HCl (d), thu c m1 gam mui Y. Cng 1 mol amino axit X phn ng vi dung dch NaOH (d), thu c m2 gam mui Z. Bit m2 m1 = 7,5. Cng thc phn t ca X l A. C5H9O4N. B. C4H10O2N2. C. C5H11O2N. D. C4H8O4N2. Cu 27 (H_A_09): Cho 10 gam amin n chc X phn ng hon ton vi HCl (d), thu c 15 gam mui. S ng phn cu to ca X l A. 4. B. 8. C. 5. D. 7. Cu 28 (H_A_09): Hp cht X mch h c cng thc phn t l C4H9NO2. Cho 10,3 gam X phn ng va vi dung dch NaOH sinh ra mt cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm giy qu tm m chuyn mu xanh. Dung dch Z c kh nng lm mt mu nc brom. C cn dung dch Z thu c m gam mui khan. Gi tr ca m l A. 10,8. B. 9,4. C. 8,2. D. 9,6. Cu 29 (H_B_09): Cho 0,02 mol amino axit X tc dng va vi 200 ml dung dch HCl 0,1M thu c 3,67 gam mui khan. Mt khc 0,02 mol X tc dng va vi 40 gam dung dch NaOH 4%. Cng thc ca X l A. (H2N)2C3H5COOH. B. H2NC2H3(COOH)2. C. H2NC3H5(COOH)2. D. H2NC3H6COOH. Cu 31 (H_B_09): Este X (c khi lng phn t bng 103 vC) c iu ch t mt ancol n chc (c t khi hi so vi oxi ln hn 1) v mt amino axit. Cho 25,75 gam X phn ng ht vi 300 ml dung dch NaOH 1M, thu c dung dch Y. C cn Y thu c m gam cht rn. Gi tr m l A. 29,75. B. 27,75. C. 24,25. D. 26,25. Cu 32 (H_B_10): : t chy hon ton 0,1 mol mt amin no, mch h X bng oxi va , thu c 0,5

mol hn hp Y gm kh v hi. Cho 4,6 gam X tc dng vi dung dch HCl (d), s mol HCl phn ng l A. 0,3. B. 0,1. C. 0,4. D. 0,2.

Cu 33 (H_B_10): Cu 16: Hai hp cht hu c X v Y c cng cng thc phn t l C3H7NO2, u l

cht rn iu kin thng. Cht X phn ng vi dung dch NaOH, gii phng kh. Cht Y c phn ng trng ngng. Cc cht X v Y ln lt l A. amoni acrylat v axit 2-aminopropionic. B. axit 2-aminopropionic v amoni acrylat. C. vinylamoni fomat v amoni acrylat. D. axit 2-aminopropionic v axit 3-aminopropionic Cu 34 (H_B_10): : Hn hp X gm alanin v axit glutamic. Cho m gam X tc dng hon ton vi dung dch NaOH (d), thu c dung dch Y cha (m+30,8) gam mui. Mt khc, nu cho m gam X tc dng hon ton vi dung dch HCl, thu c dung dch Z cha (m+36,5) gam mui. Gi tr ca m l A. 171,0. B. 112,2. C. 123,8. D. 165,6. Cu 35 (H_B_10): : ipeptit mch h X v tripeptit mch h Y u c to nn t mt aminoaxit (no, mch h, trong phn t cha mt nhm -NH2 v mt nhm -COOH). t chy hon ton 0,1 mol Y, thu c tng khi lng CO2 v H2O bng 54,9 gam. t chy hon ton 0,2 mol X, sn phm thu c cho li t t qua nc vi trong d, to ra m gam kt ta. Gi tr ca m l A. 45. B. 120. C. 30. D. 60. Cu 36 (H_B_10): : Thy phn hon ton 1 mol pentapeptit X, thu c 2 mol glyxin (Gly), 1 mol alanin (Ala), 1 mol valin (Val) v 1 mol phenylalanin (Phe). Thy phn khng hon ton X thu c ipeptit ValPhe v tripeptit Gly-Ala-Val nhng khng thu c ipeptit Gly-Gly. Cht X c cng thc l A. Gly-Ala-Val-Val-Phe. B. Gly-Phe-Gly-Ala-Val. C. Val-Phe-Gly-Ala-Gly. D. Gly-Ala-Val-Phe-Gly. Cu 37 (H_B_10): : Trung ho hon ton 8,88 gam mt amin (bc mt, mch cacbon khng phn nhnh) bng axit HCl, to ra 17,64 gam mui. Amin c cng thc l A. H2NCH2CH2CH2CH2NH2. B. CH3CH2CH2NH2. C. H2NCH2CH2CH2NH2. D. H2NCH2CH2NH2 Cu 38 (C_B_11): : Amino axit X c dng H2NRCOOH (R l gc hirocacbon). Cho 0,1 mol X phn ng ht vi dung dch HCl (d) thu c dung dch cha 11,15 gam mui. Tn gi ca X l A. glyxin. B. valin. C. alanin. D. phenylalanin. Cu 39 (C_B_11): Cho cc dung dch: C6H5NH2 (anilin), CH3NH2, NaOH, C2H5OH v H2NCH2COOH. Trong cc dung dch trn, s dung dch c th lm i mu phenolphtalein l A. 3. B. 4. C. 2. D. 5. Cu 40 (C_B_11): : Hai cht no sau y u tc dng c vi dung dch NaOH long? A. CH3NH3Cl v CH3NH2. B. CH3NH3Cl v H2NCH2COONa. C. CH3NH2 v H2NCH2COOH. D. ClH3NCH2COOC2H5 v H2NCH2COOC2H5 Cu 41 (C_B_11): : Amin X c phn t khi nh hn 80. Trong phn t X, nit chim 19,18% v khi lng. Cho X tc dng vi dung dch hn hp gm KNO2 v HCl thu c ancol Y. Oxi ha khng hon ton Y thu c xeton Z. Pht biu no sau y ng? A. Trong phn t X c mt lin kt . B. Phn t X c mch cacbon khng phn nhnh. C. Tn thay th ca Y l propan-2-ol. D. Tch nc Y ch thu c mt anken duy nht. Cu 42 (H_A_11): Cu 5: S ng phn amino axit c cng thc phn t C3H7O2N l A. 3. B. 4. C. 1. D. 2. Cu 43 (H_A_11): : Thnh phn % khi lng ca nit trong hp cht hu c CxHyN l 23,73%. S ng phn amin bc mt tha mn cc d kin trn l A. 4. B. 3. C. 2. D. 1. Cu 44 (H_A_11): Dung dch no sau y lm qu tm i thnh mu xanh? A. Dung dch lysin. B. Dung dch alanin. C. Dung dch glyxin. D. Dung dch valin. Cu 51: Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (cc amino axit ch c mt nhm amino v mt nhm cacboxyl trong phn t). Nu cho 1 hn hp X tc dng vi dung dch HCl (d), c cn cn thn dung dch, th lng mui khan thu 10 c l A. 7,82 gam. B. 8,15 gam. C. 16,30 gam. D. 7,09 gam. Cu 45 (H_B_11): Cu 17: Ancol v amin no sau y cng bc? A. (CH3)2CHOH v (CH3)2CHNH2. B. C6H5NHCH3 v C6H5CH(OH)CH3. C. (CH3)3COH v (CH3)3CNH2. D. (C6H5)2NH v C6H5CH2OH.

Cu 46 (H_B_11): Cho ba dung dch c cng nng mol: (1) H2NCH2COOH, (2) CH3COOH, (3)

CH3CH2NH2. Dy xp theo th t pH tng dn l: A. (2), (1), (3). B. (3), (1), (2). C. (2), (3), (1). D. (1), (2), (3). Cu 47 (H_B_11): : Cht hu c X mch h c dng H2N-R-COOR' (R, R' l cc gc hirocacbon), phn trm khi lng nit trong X l 15,73%. Cho m gam X phn ng hon ton vi dung dch NaOH, ton b lng ancol sinh ra cho tc dng ht vi CuO (un nng) c anehit Y (ancol ch b oxi ho thnh anehit). Cho ton b Y tc dng vi mt lng d dung dch AgNO3 trong NH3, thu c 12,96 gam Ag kt ta. Gi tr ca m l A. 3,56. B. 5,34. C. 2,67. D. 4,45. Cu 48 (C_A_12): Cu 22: Cho 20 gam hn hp gm hai amin no, n chc, mch h tc dng va vi V ml dung dch HCl 1M, thu c dung dch cha 31,68 gam hn hp mui. Gi tr ca V l A. 200. B. 100. C. 320. D. 50. Cu 49 (C_A_12): S nhm amino v s nhm cacboxyl c trong mt phn t axit glutamic tng ng l A. 1 v 1. B. 2 v 2. C. 2 v 1. D. 1 v 2. Cu 50 (C_A_12): Thy phn hon ton m gam ipeptit Gly-Ala (mch h) bng dung dch KOH va , thu c dung dch X. C cn ton b dung dch X thu c 2,4 gam mui khan. Gi tr ca m l A. 1,22. B. 1,46. C. 1,36. D. 1,64. Cu 51 (C_A_12): Cho cc cht hu c: CH3CH(CH3)NH2 (X) v CH3CH(NH2)COOH (Y). Tn thay th ca X v Y ln lt l A. propan2amin v axit aminoetanoic. B. propan2amin v axit 2aminopropanoic. C. propan1amin v axit 2aminopropanoic. D. propan1amin v axit aminoetanoic Cu 52 (C_A_12): Pht biu no sau y l ng? A. nhit thng, cc amino axit u l nhng cht lng. B. Cc amino axit thin nhin hu ht l cc -amino axit. C. Amino axit thuc loi hp cht hu c tp chc. D. Axit glutamic l thnh phn chnh ca bt ngt. Cu 53 (C_A_12): Cho 14,55 gam mui H2NCH2COONa tc dng hon ton vi dung dch HCl d, thu c dung dch X. C cn ton b dung dch X, thu c bao nhiu gam mui khan? A. 16,73 gam. B. 25,50 gam. C. 8,78 gam. D. 20,03 gam. Cu 54 (H_B_12): un nng m gam hn hp gm a mol tetrapeptit mch h X v 2a mol tripeptit mch h Y vi 600 ml dung dch NaOH 1M (va ). Sau khi cc phn ng kt thc, c cn dung dch thu c 72,48 gam mui khan ca cc amino axit u c mt nhm COOH v mt nhm NH2 trong phn t. Gi tr ca m l: A. 51,72. B. 54,30. C. 66,00. D. 44,48. Cu 55 (H_B_12): Cho 21 gam hn hp gm glyxin v axit axetic tc dng va vi dung dch KOH, thu c dung dch X cha 32,4 gam mui. Cho X tc dng vi dung dch HCl d, thu c dung dch cha m gam mui. Gi tr ca m l A. 44,65. B. 50,65. C. 22,35. D. 33,50. Cu 56 (H_B_12): t chy hon ton 50 ml hn hp kh X gm trimetylamin v hai hirocacbon ng ng k tip bng mt lng oxi va , thu c 375 ml hn hp Y gm kh v hi. Dn ton b Y i qua dung dch H2SO4 c (d), th tch kh cn li l 175 ml. Cc th tch kh v hi o cng iu kin. Hai hirocacbon l A. C2H4 v C3H6. B. C3H6 v C4H8. C. C2H6 v C3H8. D. C3H8 v C4H10. Cu 57 (H_B_12): Alanin c cng thc l A. C6H5-NH2. B. CH3-CH(NH2)-COOH. C. H2N-CH2-COOH. D. H2N-CH2-CH2-COOH. Cu 58 (H_A_12): Hn hp M gm mt anken v hai amin no, n chc, mch h X v Y l ng ng k tip (MX < MY). t chy hon ton mt lng M cn dng 4,536 lt O2 (ktc) thu c H2O, N2 v 2,24 lt CO2 (ktc). Cht Y l A. etylmetylamin. B. butylamin. C. etylamin. D. propylamin. Cu 59 (H_A_12): : Hn hp X gm 2 amino axit no (ch c nhm chc COOH v NH2 trong phn t), trong t l mO : mN = 80 : 21. tc dng va vi 3,83 gam hn hp X cn 30 ml dung dch HCl 1M. Mt khc, t chy hon ton 3,83 gam hn hp X cn 3,192 lt O2 (ktc). Dn ton b sn phm chy (CO2, H2O v N2) vo nc vi trong d th khi lng kt ta thu c l A. 20 gam. B. 13 gam. C. 10 gam. D. 15 gam.

Cu 60 (H_A_12): : Hp cht X c cng thc C8H14O4. T X thc hin cc phn ng (theo ng t l mol):

(a) X + 2NaOH X1 + X2 + H2O (b) X1 + H2SO4 X3 + Na2SO4 (c) nX3 + nX4 nilon-6,6 + 2nH2O (d) 2X2 + X3 X5 + 2H2O Phn t khi ca X5 l A. 198. B. 202. C. 216. D. 174. Cu 61 (H_A_12): : Cho dy cc cht: C6H5NH2 (1), C2H5NH2 (2), (C6H5)2NH (3), (C2H5)2NH (4), NH3 (5) (C6H5- l gc phenyl). Dy cc cht sp xp theo th t lc baz gim dn l : A. (4), (1), (5), (2), (3). B. (3), (1), (5), (2), (4). C. (4), (2), (3), (1), (5). D. (4), (2), (5), (1), (3). Cu 62 (H_A_12): : Dung dch cht no sau y lm qu tm chuyn thnh mu hng? A. axit -aminoglutaric B. Axit , -iaminocaproic C. Axit -aminopropionic D. Axit aminoaxetic

VII. VT LIU POLIME

Cu 1 (C_07): Polime dng iu ch thu tinh hu c (plexiglas) c iu ch bng phn ng trng hp A. CH2=CHCOOCH3 B. C6H5CH=CH2 C. CH2=C(CH3)COOCH3. D. CH3COOCH=CH2. Cu 2 (C_07): Trong cc loi t sau: t tm; t visco; t nilon-6,6; t axetat; t capron; t enang. Nhng loi t thuc t nhn to l A. t visco v t axetat B. t visco v t nilon-6,6 C. t nilon-6,6 v t capron D. t tm v t enang Cu 3 (C_08): T nilon 6,6 c iu ch bng phn ng trng ngng A. H2N-(CH2)5-COOH B. HOOC-(CH2)2-CH(NH2)-COOH C. HOOC-(CH2)4-COOH v HO-(CH2)2-OH D. HOOC-(CH2)4-COOH v H2N-(CH2)6-NH2. Cu 4 (C_09): Th tch dung dch axit nitric 63% (D = 1,4 g/ml) cn va sn xut 59,4 kg xeluloz trinitrat (hiu sut 80%) l A. 42,34 lit. B. 42,86 lit. C. 34,29 lit. D. 53,57 lit. Cu 5 (H_A_07): Nilon-6,6 l 1 loi A. t axetat B. t poliamit C. polieste D. t visco Cu 6 (H_B_07): Dy gm cc cht dng tng hp cao su Buna-S l A. CH2=C(CH3)-CH=CH2, C6H5-CH=CH2 B. CH2=CH-CH=CH2, C6H5-CH=CH2 C. CH2=CH-CH=CH2, CH3-CH=CH2 D. CH2=CH-CH=CH2, lu hunh Cu 7 (H_A_08): Khi lng ca mt on mch nilon-6,6 l 27346 vC v mt on mch t capron l 17176 vC. S lng mt xch trong on mch nilon-6,6 v capron nu trn ln lt l A. 113 v 152 B. 121 v 114 C. 121 v 152 D. 113 v 114 Cu 8 (H_B_08): Polime c cu trc mng khng gian (mng li) l A. PE B. amilopectin C. PVC D. nha bakelit Cu 9 (H_A_09): Poli(metyl metacrylat) v nilon-6 c to thnh t cc monome tng ng l A. CH2=CH-COOCH3 v H2N-[CH2]6-COOH. B. CH2=C(CH3)-COOCH3 v H2N-[CH2]6-COOH. C. CH3-COO-CH=CH2 v H2N-[CH2]5-COOH. D. CH2=C(CH3)-COOCH3 v H2N-[CH2]5-COOH. Cu 10 (H_B_09): Pht biu no sau y l ng? A. Poli(etylen terephtalat) c iu ch bng phn ng trng ngng cc monome tng ng. B. Trng ngng buta-1,3-ien vi acrilonitrin c xc tc Na c cao su buna-N. C. Trng hp stiren thu c poli(phenol-fomanehit). D. T visco l t tng hp. Cu 11 (H_B_10): Cc cht u khng b thu phn trong dung dch H2SO4 long nng l:

A. polietilen; cao su buna; polistiren. B. poli(vinyl axetat); polietilen; cao su buna. C. t capron; nilon-6,6; polietilen. D. nilon-6,6; poli(etylen-terephtalat); polistiren.

Cu 12 (C_A_11): Cho cc polime: (1) polietilen, (2) poli(metyl metacrylat), (3) polibutaien, (4)

polistiren, (5) poli(vinyl axetat) v (6) t nilon-6,6. Trong cc polime trn, cc polime c th b thu phn trong dung dch axit v dung dch kim l: A. (1), (4), (5). B. (1), (2), (5). C. (2), (5), (6). D. (2), (3), (6). Cu 13 (H_A_11): Sn phm hu c ca phn ng no sau y khng dng ch to t tng hp? A. Trng ngng hexametyleniamin vi axit aipic. B. Trng hp vinyl xianua. C. Trng ngng axit -aminocaproic. D. Trng hp metyl metacrylat. Cu 14 (H_A_11): : Xenluloz trinitrat c iu ch t phn ng gia axit nitric vi xenluloz (hiu sut phn ng 60% tnh theo xenluloz). Nu dng 2 tn xenluloz th khi lng xenluloz trinitrat iu ch c l A. 3,67 tn. B. 2,97 tn. C. 1,10 tn. D. 2,20 tn. Cu 15 (H_A_11): Cho s phn ng: C2H2 + HCN X; X trnghop polime Y; X + CH2=CH-CH=CH2 dongtrunghop polime Z. Y v Z ln lt dng ch to vt liu polime no sau y? A. T capron v cao su buna. B. T olon v cao su buna-N. C. T nitron v cao su buna-S. D. T nilon-6,6 v cao su cloropren. Cu 16 (H_B_11): Cho cc t sau: t xenluloz axetat, t capron, t nitron, t visco, t nilon-6,6. C bao nhiu t thuc loi t poliamit? A. 2 B. 1 C. 4 D. 3 Cu 17 (C_A_12): Pht biu no sau y l ng? A. Polietilen v poli(vinyl clorua) l sn phm ca phn ng trng ngng. B. T visco, t xenluloz axetat u thuc loi t tng hp. C. Si bng, t tm thuc loi polime thin nhin. D. T nilon6,6 c iu ch t hexametyleniamin v axit axetic. Cu 18 (C_A_12): Pht biu no sau y l sai? A. Cao su bunaN thuc loi cao su thin nhin. B. Lc baz ca anilin yu hn lc baz ca metylamin. C. Cht bo cn c gi l triglixerit hoc triaxylglixerol. D. Poli(metyl metacrylat) c dng ch to thy tinh hu c Cu 19 (H_B_12): Cc polime thuc loi t nhn to l A. t visco v t nilon-6,6. B. t tm v t vinilon. C. t nilon-6,6 v t capron. D. t visco v t xenluloz axetat. Cu 20 (H_B_12): iu ch 53,46 kg xenluloz trinitrat (hiu sut 60%) cn dng t nht V lt axit nitric 94,5% (D = 1,5 g/ml) phn ng vi xenluloz d. Gi tr ca V l A. 60. B. 24. C. 36. D. 40. Cu 21 (H_B_12): Cho cc cht: caprolactam (1), isopropylbenzen (2), acrilonitrin (3), glyxin (4), vinyl axetat (5). Cc cht c kh nng tham gia phn ng trng hp to polime l A. (1), (2) v (3). B. (1), (2) v (5). C. (1), (3) v (5). D. (3), (4) v (5). Cu 22 (H_A_12): Loi t no sau y c iu ch bng phn ng trng hp? A. T visco. B. T nitron. C. T nilon-6,6. D. T xenluloz axetat.

VIII. TNG HP HU C
Cu 1 (C_08): Hai cht hu c X1 v X2 u c khi lng phn t bng 60 vC. X1 c kh nng phn ng vi Na, NaOH, Na2CO3. X2 phn ng vi NaOH (un nng) nhng khng phn ng vi Na. Cng thc cu to ca X1, X2 ln lt l A. CH3COOH v HCOOCH3. B. (CH3)2CH-OH v HCOOCH3. C. CH3COOH v CH3COOCH3. D. HCOOCH3 v CH3COOH. Cu 2 (C_08): Cho dy cc cht: phenol, anilin, phenylamoni clorua, natri phenolat, etanol. S cht trong dy phn ng c vi dung dch NaOH l A. 4 B. 3 C. 1 D. 2

Cu 3 (C_08): Cho dy cc cht: HCHO, CH3COOH, CH3COOC2H5, HCOOH, C2H5OH, HCOOCH3. S cht trong dy c th tham gia phn ng trng gng l A. 2 B. 5 C. 4 D. 3 Cu 4 (C_08): Cho s chuyn ho sau (mi mi tn l mt phng trnh phn ng): Tinh bt X Y Z metyl axetat Cht Y, Z trong s trn ln lt l A. CH3COOH, CH3OH B. C2H4, CH3COOH C. C2H5OH, CH3COOH D. CH3COOH, C2H5OH Cu 5 (C_08): Cho dy cc cht: C6H5OH (phenol), C6H5NH2 (anilin), H2NCH2COOH, CH3CH2COOH, CH3CH2CH2NH2. S cht trong dy tc dng c vi dung dch HCl l A. 5 B. 2 C. 3 D. 4 Cu 6 (H_B_08): Cho dy cc cht: CH4, C2H2, C2H4, C2H5OH, CH2=CHCOOH, C6H5NH2 (anilin), C6H5OH (phenol), C6H6 (benzen). S cht trong dy tc dng c vi nc brom l A. 7 B. 5 C. 8 D. 6 Cu 7 (H_B_08): Cho dy cc cht: C2H2, HCHO, HCOOH, CH3CHO, (CH3)2CO, C12H22O11 (mantoz). S cht trong dy tham gia c phn ng trng gng l A. 6 B. 3 C. 5 D. 4 Cu 8 (H_B_08): Cho cc cht: ancol etylic, glixerol, glucoz, imetyl ete, v axit fomic. S cht tc dng c vi Cu(OH)2 l A. 2 B. 1 C. 3 D. 4 Cu 9 (H_A_08): Dy gm cc cht c sp xp theo chiu nhit si tng dn t tri sang phi l: A. CH3CHO, C2H5OH, C2H6, CH3COOH B. CH3COOH, C2H6, CH3CHO, C2H5OH C. C2H6, C2H5OH, CH3CHO, CH3COOH D. C2H6, CH3CHO, C2H5OH, CH3COOH Cu 10 (H_A_07): Pht biu khng ng l: A. axit axetic phn ng vi dd NaOH, ly mui va sinh ra cho tc dng vi kh CO2 li thu c axit axetic B. phenol phn ng vi dd NaOH, ly mui va to ra tc dng vi dung dch HCl li thu c phenol C. anilin phn ng vi dd HCl, ly mui va to ra cho tc dng vi dung dch NaOH li thu c anilin D. Dung dch natri phenolat phn ng vi kh CO2, ly kt ta va to ra cho tc dng vi dung dch NaOH li thu c natri phenolat Cu 11 (H_A_07): Dy gm cc cht u tc dng vi dung dch AgNO3/NH3 l: A. anehit axetic, but-1-in, etilen B. anehit axetic, axetilen, but-2-in C. axit fomic, vinylaxetilen, propin D. anehit fomic, axetilen, etilen Cu 12 (H_B_07): Cho tt c cc ng phn n chc, mch h, c cng cng thc phn t C 2H4O2 ln lt tc dng vi Na, NaOH, NaHCO3. S phn ng xy ra l A. 2 B. 3 C. 4 D. 5 Cu 13 (C_07): Cho s chuyn ho: glucoz X Y CH3COOH. Hai cht X, Y ln lt l A. CH3CH2OH v CH3CHO B. CH3CH2OH v CH2=CH2 C. CH3CH(OH)COOH v CH3CHO D. CH3CHO v CH3CH2OH Cu 14 (H_B_07): Cho cc cht axit propionic (X), axit axetic (Y), ancol etylic (Z), imetyl ete (T). Dy cc cht xp theo chiu tng dn nhit si l A. T, X, Y, Z B. T, Z, Y, X C. Z, T, Y X D. Y, T, X, Z Cu 15 (H_A_08): Pht biu ng l: A. Tnh axit ca phenol yu hn ca ancol B. Cao su thin nhin l sn phm trng hp ca isopren. C. Cc cht etilen, toluen v stiren u tham gia phn ng trng hp D. Tnh baz ca anilin mnh hn amoniac. Cu 16 (C_07): Cho cc cht: phenol, etanol, axit axetic, natri phenolat, natri hiroxit. S cp cht tc dng c vi nhau l A. 2 B. 3 C. 1 D. 4 Cu 17 (H_B_07): Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol, phenylamoni clorua, ancol benzylic, p-crezol.Trong cc cht ny, s cht tc dng c vi dung dch NaOH l A. 3 B. 4 C. 5 D. 6 Cu 18 (C_07): S hp cht hu c n chc, l ng phn cu to ca nhau c cng cng thc phn t C 4H8O2 u tc dng c vi dung dch NaOH l A. 5 B. 3 C. 4 D. 6 Cu 19 (H_B_07): Cho 3 cht lng benzen, stiren, anilin, ng trong 3 l ring bit mt nhn. Thuc th phn bit ba cht lng trn l A. dd phenolphtalein B. giy qu tm C. nc brom D. dung dch NaOH

Cu 20 (C_07): Ch dng Cu(OH)2 c th phn bit c cc dung dch ring bit sau: A. Saccaroz, glixerin (glixerol), anehit axetic, ru etylic B. glucoz, mantoz, glixerin (glixerol), anehit axetic C. glucoz, lng trng trng, glixerin (glixerol), ru etylic D. lng trng trng, glucoz, fructoz, glixerin (glixerol). Cu 21 (H_A_08): Este X c c im sau: - t chy hon ton X to thnh CO2 v H2O c s mol bng nhau. - Thu phn X trong mi trung axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X). Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. B. Cht Y tan v hn trong nc. C. Cht X thuc loi este no, n chc. D. un Z vi H2SO4 c 1700C thu c anken. Cu 22 (H_A_08): Trung ho 5,48 gam hn hp gm axit axetic, phenol v axit benzoic, cn dng 600 ml dung dch NaOH 0,1M. C cn dung dch sau phn ng, thu c hn hp cht rn c khi lng l A. 8,64 gam B. 6,48 gam C. 4,90 gam D. 6,80 gam Cu 23 (H_B_08): Oxi ho 1,2 gam CH3OH bng CuO nung nng, sau mt thi gian thu c hn hp sn phm X (gm HCHO, H2O v CH3OH d). Cho ton b X tc dng vi lng d dung dch AgNO 3 trong NH3 un nng, c 12,96 gam Ag. Hiu sut ca phn ng oxi ho CH3OH l A. 80,0% B. 65,5% C. 70,4% D. 76,6% Cu 24 (H_A_07): Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1 : 1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH (c xc tc H2SO4 c), thu c m gam hn hp este (hiu sut cc phn ng este ho u t 80%). Gi tr ca m l A. 6,48 B. 8,10 C. 10,12 D.16,20 Cu 25 (H_B_07): Trong 1 bnh kn cha hi cht hu c X (c dng C nH2nO2) mch h v O2 ( s mol O2 gp i s mol cn cho phn ng chy) 139,9oC, p sut trong bnh l 0,8 atm. t chy hon ton X sau a v nhit ban u, p sut trong bnh lc ny l 0,95 atm. X c cng thc phn t l A. C2H4O2 B. C3H6O2 C. C4H8O2 D. CH2O2 Cu 26 (C_07): Cho hn hp 2 anken ng ng k tip nhau tc dng hon ton vi nc (xc tc H2SO4, un nng) thu c hn hp Z gm hai ancol X v Y. t chy hon ton 1,06 gam hn hp Z sau hp th ton b sn phm chy vo 2 lit dung dch NaOH 0,1M thu c dung dch T trong nng ca NaOH bng 0,05M. Th tch dung dch thay i khng ng k. Cng thc cu to thu gn ca X v Y l A. C2H5OH v C3H7OH B. C3H7OH v C4H9OH C. C4H9OH v C5H11OH D. C2H5OH v C4H9OH Cu 27 (H_A_08): Cho m gam hn hp gm hai ancol no, n chc, k tip nhau trong dy ng ng tc dng vi CuO (d) nung nng, thu c hn hp rn Z v hn hp hi Y (c t khi so vi H 2 bng 13,75). Cho ton b Y phn ng vi lng d dung dch AgNO3 trong NH3 un nng, sinh ra 64,8 gam Ag. Gi tr ca m l A. 7,8 B. 8,8 C. 7,4 D. 9,2 Cu 28 (C_08): Mt hn hp X gm hai cht hu c n chc. Cho X phn ng va vi 500 ml dung dch KOH 1M. Sau phn ng thu c hn hp Y gm hai mui ca hai axit cacboxylic v mt ancol. Cho ton b lng ancol thu c trn tc dng vi Na (d), sinh ra 3,36 lit kh H2 ( ktc). Hn hp X gm A. mt este v mt ancol B. mt axit v mt este C. mt axit v mt ancol D. hai este Cu 29 (C_09): Cho cc cht HCl (X); C2H5OH (Y); CH3COOH (Z); C6H5OH (phenol) (T). Dy gm cc cht c sp xp theo tnh axit tng dn (t tri sang phi) l: A. (T), (Y), (X), (Z). B. (X), (Z), (T), (Y). C. (Y), (T), (Z), (X). D. (Y), (T), (X), (Z). Cu 30 (C_09): Cho m gam hn hp gm hai cht hu c n chc, mch h tc dng va vi dung dch c cha 11,2 gam KOH, thu c mui ca mt axit cacboxylic v mt ancol X. Cho ton b X tc dng ht vi Na thu c 3,36 lit kh H2 ( ktc). Hai cht hu c l A. mt este v mt axit. B. hai axit. C. hai este. D. mt este v mt ancol. Cu 31 (H_A_09): C ba dung dch: amoni hirocacbonat, natri aluminat, natri phenolat v ba cht lng: ancol etylic, benzen, anilin ng trong su ng nghim ring bit. Nu ch dng mt thuc th duy nht l dung dch HCl th nhn bit c ti a bao nhiu ng nghim? A. 5. B. 6. C. 3. D. 4. Cu 32 (H_A_09): Cho cc hp cht hu c: C2H2; C2H4; CH2O; CH2O2 (mch h); C3H4O2 (mch h, n chc). Bit C3H4O2 khng lm chuyn mu qu tm m. S cht tc dng c vi dung dch AgNO3 trong NH3

to ra kt ta l A. 3. B. 4. C. 5. D. 2. Cu 33 (H_B_09): Cho hn hp X gm hai hp cht hu c no, n chc tc dng va vi 100 ml dung dch KOH 0,4M, thu c mt mui v 336 ml hi mt ancol ( ktc). Nu t chy hon ton lng hn hp X trn, sau hp th ht sn phm chy vo bnh ng dung dch Ca(OH)2 (d) th khi lng bnh tng 6,82 gam. Cng thc ca hai hp cht hu c trong X l A. HCOOH v HCOOC2H5. B. HCOOH v HCOOC3H7. C. C2H5COOH v C2H5COOCH3. D. CH3COOH v CH3COOC2H5. Cu 34 (H_B_09): Cho cc hp cht hu c: (1) ankan; (2) ancol no, n chc, mch h; (3) xicloankan; (4) ete no, n chc, mch h; (5) anken; (6) ancol khng no (c mt lin kt i C=C), mch h; (7) ankin; (8) anehit no, n chc, mch h; (9) axit no, n chc, mch h; (10) axit khng no (c mt lin kt i C=C), n chc. Dy gm cc cht khi t chy hon ton u cho s mol CO2 bng s mol H2O l: A. (1), (3), (5), (6), (8). B. (2), (3), (5), (7), (9). C. (3), (4), (6), (7), (10). D. (3), (5), (6), (8), (9). Cu 35 (H_B_09): Hai hp cht hu c X v Y l ng ng k tip, u tc dng vi Na v c phn ng trng bc. Bit phn trm khi lng oxi trong X, Y ln lt l 53,33% v 43,24%. Cng thc cu to ca X v Y tng ng l A. HCOOCH3 v HCOOCH2CH3. B. HOCH2CHO v HOCH2CH2CHO. C. HOCH2CH2CHO v HOCH2CH2CH2CHO. D. HOCH(CH3)CHO v HOOCCH2CHO. Cu 36 (H_B_09): Dy gm cc cht c sp xp theo chiu tng dn nhit si t tri sang phi l: A. CH3CHO, C2H5OH, HCOOH, CH3COOH. B. CH3COOH, C2H5OH, HCOOH, CH3CHO. C. HCOOH, CH3COOH, C2H5OH, CH3CHO. D. CH3COOH, HCOOH, C2H5OH, CH3CHO. Cu 37 (H_B_09): t chy hon ton 1 mol hp cht hu c X, thu c 4 mol CO2. Cht X tc dng c vi Na, tham gia phn ng trng bc v phn ng cng Br2 theo t l mol 1 : 1. Cng thc cu to ca X l A. HO-CH2-CH2-CH=CH-CHO. B. HO-CH2-CH=CH-CHO. C. HOOC-CH=CH-COOH. D. HO-CH2-CH2-CH2-CHO.