Ôn Hóa Vô Cơ LTĐH

1
V Thanh Tng
Sv khoa ha HKHTN-HQGHN
Gii thiu:
Tng n tp kin thc ha hc v c

1. Chuyn 01: cu to nguyn t v bng h thng tun hon
2. Chuyn 02: lin kt ha hc
3. Chuyn 03: tc phn ng, cn bng ha hc
4. Chuyn 04: s in ly, in phn
5. Chuyn 05: bi tp tng hp v kim loi, phi kim
- Dng 1: dng bi tp hn hp
- Dng 2: bi tp kim loi tc dng vi dd mui
- Dng 3: phn ng nhit nhm
6.
Chuyn 06: bi tp v phn ng oxi ha kh (HNO3; H2SO4 c

nng)
7.
Chuyn 07: bi ton CO2, SO2 tc dng vi dd kim
8. Chuyn 08: bi ton cho Al, Zn v hp cht tc dng vi dd kim
(B n tp tuyn sinh i hc nm 2012-2013)

Trong qu trnh son bi c tham kho ti liu ca cc thy, c, cc bn hc sinh, sinh vin v c
bit l mt s thi n luyn, thi th H-C ca cc trng THPH chuyn H Ni Amsterdam,
THPT chuyn Nguyn Hu, H Ty, H Ni, THPT Ph Dc Qunh Ph, Thi Bnh,.....
Mi kin ng gp xin gi v a ch e-mail thanhbach20112011.tb.vnu@gmail.com. Rt mong
nhn c kin ca cc thy, c, cc bn,..
Chc cc bn hc sinh mt k thi thnh cng
H Ni, ma thi 2012

Tng hp chuyn luyn thi ha hc v c. Nm hc 2012-2013. Ngi son: V Thanh Tng_sv khoa
ha HKHTN-HQGHN. Mi thc mc lin h st 098.555.6536 hoc 01219.030.111
V Thanh Tng_HKHTN-HQGHN
Chuyn 01: Cu to nguyn t v bng htth

A/ L thuyt
1. Cu to nguyn t
a. nh ngha: nguyn t l ht v cng nh b, trung ha v in, nguyn t gm lp v gm cc electron dch
chuyn v ht nhn nguyn t gm proton v ntron, trong nt lun c s p=s e
b. Ht nhn nguyn t(Gm proton v ntron) lun c 1 s N/ s P 1,51
Proton: mp=1,667 . 10-27kg
qp=+1,6 . 10-19
-27
Notron: mn=1,667 . 10 kg
qn=0
c. S khi nguyn t A=P+N
d. Cng thc tnh khi lng nt trung bnh
A= (A1x1+A2x2+....)/(x1+x2+....)
trong x1, x2, .... l s mol, t l s nt, % v s nt
2. Cch vit cu hnh electron
a. Gin trt t mc nng lng
4f
3d
4d
5d
2p
b.
c.
-
3p
4p
5p
6p
1s
2s
3s
4s
5s
6s
7s
Vit sp xp cc electron theo trt t mc nng lng nh trn
Sp xp electron vo cc obitan nguyn t tun theo 2 qui tc hun v nguyn l pauli
Cc e phn b vo cc obitan sao cho s e c thn l ln nht
Cc e c chiu t quay ngc nhau
3. S lc v bng htth
a. Trong mt chu k chiu tng ca in tch ht nhn bn knh nt gim dn, m in tng dn, tnh kim loi
gim dn, tnh phi kim tng dn, tnh bazo ca oxit kim loi tng ng gim dn, tnh axit tng dn, ha tr cao
nht vi oxi tng dn, vi hiro gim dn
b. Trong mt nhm theo chiu tng ca in tch ht nhn bn knh nguyn t tng dn, m in gim dn, tnh
kim loi tng dn, tnh phi kim gim dn, tnh bazo tng dn, tnh axit gim dn,
B/ Bi tp
DNG I: XC NH S N, P, E TRONG NGUYN T
Bi 1. Nguyn t ca mt nguyn t X c tng s ht c bn (e, p, n) l 82, trong s ht mang in nhiu hn s ht
khng mang in l 22.
a) Xc nh s hiu nguyn t, s khi v k hiu nguyn t.
b) Vit cu hnh electron nguyn t X v ca ion to thnh t X.
3
Bi 2. Tng s ht proton, ntron, electron c trong mt loi nguyn t ca ,nguyn t Y l 54, trong tng s ht
mang in nhiu hn s ht khng mang in l 1,7 ln.
Hy xc nh s hiu nguyn t, s khi v vit k hiu nguyn t X.
Bi 3. Mt kim loi M c tng s khi bng 54, tng s ht p, n, e trong ion M2+ l 78. Vy nguyn t kim loi M c k
hiu no sau y?
54
24
Cr ,
54
25
Mn ,
54
26
Fe ,
54
27
Co .
Bi 4. Bit rng tng s cc loi ht (p, n, e) trong nguyn t R l 40, trong ht khng mang in km hn s ht
mang in l 12. Xc nh tn ca nguyn t R v vit k hiu nguyn t R ( Bit ZNa=11, ZMg=12, ZAl=13, ZCa=20,
ZK=19).
Bi 5. Tng s proton, ntron, electron trong nguyn t ca nguyn t X l 10. Hy xc nh s khi nguyn t ca
nguyn t X.
Bi 6. Tng s proton, ntron, electron trong nguyn t ca nguyn t Y l 21.
Hy xc nh thnh phn cu to nguyn t, gi tn v vit k hiu nguyn t X.
Bi 7. Tng s proton, ntron, electron trong nguyn t ca nguyn t R l 34.
Hy da vo bng tun hon xc nh nguyn t R.
Bi 8. Nguyn t ca nguyn t R c tng s proton, ntron, electron bng 54, s ht proton gn bng s ht ntron .
Tnh Z v A ca nguyn t nguyn t R.
Bi 9. Cho cc nguyn t X, Y, Z. Tng s ht p, n, e trong cc nguyn t ln lt l 16, 58, 78. S ntron trong ht
nhn v s hiu nguyn t ca mi nguyn t khc nhau khng qu 1 n v.
Hy xc nh cc nguyn t v vit k hiu cc nguyn t.
Bi 10. Trong phn t M2X c tng s ht (p, n, e) l 140 ht , trong s ht mang in nhiu hn s ht khng mang
in l 44 ht. S khi ca nguyn t M ln hn s khi ca nguyn t X l 23. Tng s ht (p, n, e) trong nguyn t M
nhiu hn trong nguyn t X l 34 ht.
Vit cu hnh electron ca cc nguyn t M v X. Vit cng thc phn t ca hp cht M2X.
Bi 11. Hp cht Y c cng thc MX2 trong M chim 46,67% v khi lng. Trong ht nhn M c s ntron nhiu
hn s proton l 4 ht. Trong ht nhn X s ntron bng s proton. Tng s proton trong NX2 l 58.
a) Tm AM v AX.
b) Xc nh cng thc phn t ca MX2.
2
Bi 12. Cho bit tng s electron trong ion AB 3 l 42. Trong cc ht nhn ca A cng nh B s proton bng s ntron.
Xc nh s khi ca A, B. Bit s khi ca A gp i ca B.
Bi 13. C hp cht MX3 . Cho bit :
4
- Tng s ht p, n, e l 196, trong s ht mang in nhiu hn s ht khng mang in l 60. Nguyn t khi ca
X km hn ca M l 8.
- Tng 3 loi ht trn trong ion X- nhiu hn trong ion M3+ l 16.
Hy xc nh nguyn t M, X ?
DNG II: DNG BI TP LIN QUAN N XC NH KHI LNG NGUYN T TRUNG BNH
Bi 14. Trong t nhin brom c hai ng v bn :
t.
79
35
Br chim 50,69% s nguyn t v
81
35
Br chim 49,31% s nguyn
Hy tm nguyn t khi trung bnh ca brom.

Bi 15. ng c hai ng v bn
65
29
Cu v
63
29
Cu . Nguyn t khi trung bnh ca ng l 63,54.
Tnh thnh phn phn trm ca mi ng v.

Bi 16. Nguyn t khi trung bnh ca brom l 79,91. Brom c hai ng v, bit ng v
nh nguyn t khi ca ng v 2.
Bi 17. Bo trong t nhin c hai ng v bn:
11
ng v 5 B . Bit AB = 10,81.
10
5
79
35
Br chim 54,5% . Hy xc
B v 115 B . Mi khi c 760 nguyn t 105 B th c bao nhiu nguyn t

27
Bi 18. Mt nguyn t X c 2 ng v vi t l nguyn t l

. Ht nhn nguyn t X c 35 proton. Trong nguyn t
23ng v th hai nhiu hn trong ng v th nht l 2 ht.
ca ng v th nht c 44 ntron. S ntron trong nguyn t
Tnh nguyn t khi trung bnh ca X.
Bi 19. Nguyn t X c 3 ng v l X1 chim 92,23% , X2 chim 4,67% v X3 chim 3,10%. Tng s khi ca 3 ng
v l 87. S ntron trong X2 nhiu hn trong X1 l 1 ht. Nguyn t khi trung bnh ca X l 28,0855.
a) Hy tm X1 , X2 v X3 .
b) Nu trong X1 c s ntron bng s proton. Hy tm s ntron trong nguyn t ca mi loi ng v
Bi 20. Cho mt dung dch cha 8,19 gam mui NaX tc dng mt lng d dung dch AgNO3 thu c 20,09 gam kt
ta . a) Tm nguyn t khi v gi tn X.
b) X c hai ng v, gi s s nguyn t ca ng v th nht nhiu gp 3 ln s nguyn t ca ng v th hai. Ht
nhn ca ng v th nht c t hn ht nhn ng v th hai 2 ntron.
Tm s khi ca mi ng v.
Bi 21. Trong t nhin bo(B) c hai ng v:
10
5
B v 115 B . Nguyn t khi trung bnh ca bo 10,81.
a) Tnh phn trm ca mi ng v.

b) Tnh phn trm khi lng
37
11
5
B trong axit boric H3BO3 ( Bit H l ng v 11 H ; O l ng v 168 O ).

37
Bi 22. Trong t nhin ng v 17 Cl chim 24,23% s nguyn t. Tnh thnh phn phn trm v khi lng 17 Cl c
35
16
trong HClO4 v phn trm v khi lng 17 Cl c trong KClO3 (vi H l ng v 11 H ; O l ng v 8 O ; K l ng v
39
19 K ) ? Cho nguyn t khi trung bnh ca clo bng 35,5.
5
Bi 23. Mt nguyn t R c 3 ng v X, Y, Z , bit tng s ht ca 3 ng v bng 129, s ntron ng v X hn ng
v Y mt ht. ng v Z c s proton bng s ntron.
Xc nh in tch ht nhn nguyn t v s khi ca 3 ng v X, Y, Z ?
Bi 24. Cho hp cht XY2 to bi hai nguyn t X, Y. Y c hai ng v :
81
Y . Trong XY2, phn trm khi lng ca X l bng 28,51%.
79
Y chim 55% s nguyn t Y v ng v
Tnh nguyn t khi trung bnh ca X, Y.

35
37
Bi 25. Clo trong t nhin gm hai ng v 17 Cl v 17 Cl ; Silic gm hai ng v

SiCl4 gm c bao nhiu loi phn t c thnh phn ng v khc nhau.
38
14
Si v
39
14
Si . Hp cht silic clorua
Bi 26. C hai ng v 11 H (k hiu l H) v 12 H (k hiu l D).

a) Vit cc loi cng thc phn t hiro c th c.
b) Tnh phn t khi ca mi loi phn t.
c) 1 lt hiro giu teri ( 12 H ) iu kin tiu chun nng 0,1 gam. Tnh thnh phn phn trm khi lng tng
ng v ca hiro.
Bi 27. Hiro c nguyn t khi l 1,008. Hi c bao nhiu nguyn t ca ng v 12 H trong 1 ml nc ( cho rng trong
nc ch c ng v 11 H v 12 H ) ?
( Cho khi lng ring ca nc l 1 g/ml)
Bi 28. Agon tch ra t khng kh l hn hp ba ng v : 99,6%
15 g Ar iu kin tiu chun.
40
Ar ; 0,063%
38
Ar ; 0,337%
36
Ar . Tnh th tch ca
Bi 29. Hiro c iu ch bng cch in phn nc, hiro gm hai loi ng v 11 H v 12 D . Hi trong 100 g
nc ni trn c bao nhiu ng v 12 D ? Bit rng nguyn t khi ca hiro l 1,008 v oxi l 16.
16
17
18
12
13
Bi 30. Trong t nhin oxi c ba ng v 8 O ; 8 O ; 8 O , cacbon c hai ng v 6 C ; 6 C .Hi c th c bao nhiu loi
phn t kh cacbonic hp thnh t cc ng v trn ? Vit cng thc phn t v tnh phn t khi ca chng.
35
37
Bi 31. Hiro c ba ng v 11 H , 12 H v 13 H . Clo c hai ng v l 17 Cl v 17 Cl . Hy cho bit c bao nhiu phn t

hiro clorua to thnh t cc ng v khc nhau v tnh phn t khi ca mi phn t.
16
17
18
Bi 32. Trong t nhin oxi tn ti 3 ng v bn : 8 O ; 8 O ; 8 O v hiro c ba ng v bn l : 11 H , 12 H v 13 H . Hi

c bao nhiu phn t nc c to thnh v phn t khi ca mi loi l bao nhiu?
DNG III: BI TP LIN QUAN N VIT CU HNH ELECTRON CA NGUYN T
Bi 33. Cho bit cc nguyn t
32
16
S,
23
11
Na . Hy xc nh s ht electron v tng s cc ht c trong ion S2- , Na+.
Bi 34. Cho cc ion : NO 3 , NH +4 , HSO 4 , bit ZN = 7; ZO = 8 ; ZH = 1 ; ZS = 16. Hy xc nh :

- Tng s ht proton , electron c trong cc ion .
- Tng s ht ntron c trong c trong cc ht nhn nguyn t to nn cc ion .
6
Bi 35. Nguyn t A c cu hnh electron ngoi cng l 3p4 . T l ntron v proton l 1:1. nguyn t B c s ntron
bng 1,25 ln s ntron ca A. Khi cho 7,8 gam B tc dng vi lng d A ta thu c 11 g hp cht B2A. Xc nh s
th t , s khi ca A, B.
Bi 36. Hy vit cu hnh electron nguyn t ca cc nguyn t sau:
6C
, 8O ,
12
Mg ,
15
P,
20
Ca ,
18
Ar ,
32
Ge ,
35
Br,
30
Zn ,
29
Cu .
- Cho bit nguyn t no l kim loi , nguyn t no l phi kim, nguyn t no l kh him? V sao
- Cho bit nguyn t no thuc nguyn t s , p , d , f ? V sao?
Bi 37. Cho cc nguyn t c k hiu sau :
20
10
Ne ,
39
19
K,
35
17
Cl .
Hy vit cu hnh electron v v cu to nguyn t .

Bi 38. S dng bng h thng tun hon, hy xc nh cc nguyn t v vit cu hnh electron nguyn t di dng
lng t nu cho bit cc nguyn t c Z bng 7 ; 14 ; 16 .
Bi 39. Hy vit cu hnh electron : Fe , Fe2+ , Fe3+ , S , S2- , Rb v Rb+ .
(Bit s hiu : ZFe = 26 ; ZS = 16 ; ZRb = 37 )
Bi 40. Vit cu hnh electron nguyn t ca cc nguyn t c s hiu sau :
Sr (Z = 21) ; Ti (Z=22) ; V (Z=23) ; Cr (Z=24) ; Mn (Z=25) ; Co (Z=27) ; Ni (Z=28) .
Bi 41.a) Nguyn t ca nguyn t X c cu hnh electron lp ngoi cng l 4s24p4 . Hy vit cu hnh electron ca
nguyn t X.
t Y.
b) Nguyn t ca nguyn t Y c tng s electron cc phn lp p l 11. Hy vit cu hnh electron ca nguyn
Bi 42. Nguyn t R bt i 1 electron to ra cation R+ cu hnh electron phn lp ngoi cng l 2p6 . Vit cu hnh
electron nguyn t v s phn b electron theo obitan ca nguyn t R.
Bi 43. Cu hnh electron lp ngoi cng ca nguyn t R v ion X2- , Y+ u l 4s24p6.
sao ?
Hy vit cu hnh electron nguyn t R, X, Y v cho bit nguyn t no l phi kim, kim loi hay lng tnh ? V
Bi 44. Nguyn t A khng phi l kh him , nguyn t c phn lp electrron ngoi cng l 4p. Nguyn t ca nguyn
t B c phn lp electron ngoi cng l 4s.
a) Nguyn t no l kim loi , l phi kim ?
b) Xc nh cu hnh electron ca A v B. Bit tng s electron ca 2 phn lp ngoi cng ca A v B bng 7.
Bi 45. Nguyn t ca nguyn t A c tng s electron trong cc phn lp p l 7. Nguyn t ca nguyn t B c tng s
ht mang in nhiu hn tng s ht khng mang in l 8.
Xc nh A, B. Vit cu hnh electron nguyn t ca nguyn t A, B.
7
Bi 46. Phn lp electron cui cng ca hai nguyn t A, B ln lt l 3p, 4s . Tng s electron ca hai phn lp ny l
5, hiu s electron ca hai phn lp ny l 3.
a) Xc nh in tch ht nhn ca hai nguyn t A v B.
b) S ntron ca nguyn t B ln hn s ntron trong nguyn t A l 4 ht v tng s khi ca A v B l 71. Xc
nh s khi ca A v B.
Bi 47. Tng s ht proton , ntron , electron ca nguyn t mt nguyn t kim loi l 34.
a) Xc nh tn nguyn t da vo bng tun hon cc nguyn t ho hc).
b) Vit cu hnh electron ca nguyn t ca nguyn t .
c) Tnh tng obitan v s electron trong nguyn t ca nguyn t trng thi c bn.
Bi 48. Mt loi kh clo c cha hai ng v v clo tacdng vi H2, ly sn phm ho tan vo nc c dung dch A.
Chia dung dch A thnh hai phn bng nhau :
Phn 1: trung ho ht 125 ml dung dch Ba(OH)2 0,88M .
Phn 2: Cho tc dng vi AgNO3 d thu c 31,57 gam kt ta .
Tnh phn trm s nguyn t ca mi ng v .
Cu 49. Nguyn t X , ion Y2+ v ion B- u c cu hnh electron l 1s22s22p63s23p6.
a) Vit cu hnh electron nguyn t ca Y v B .
b) Cu hnh electron trn c th l cu hnh ca nhng nguyn t , ion no ?
Chuyn 02: Lin kt ha hc

A/L thuyt
1. Phn loi v nh ngha cc loi lin kt
-
lin kt cng ha tr: l s hnh thnh do s gp chung e ca cc ng t ng t thng l phi kim

lin kt ion: l s nhng, nhn e to thnh ion, anion thng xy ra gia kim loi, phi kim in hnh
2. hiu m in
a.
b.
c.
,7
th lin kt l lin kt cng ha tr khng phn cc

th lin kt l lin kt cng ho tr phn cc
th lin kt l lin kt ion
B/ Bi tp
Chuyn 03: Tc phn ng, cn bng ha hc

A/ L thuyt
I/ l thuyt phn tc phn ng
Tc phn ng v = c/t bin thin nng ca cht tham gia hoc cht to thnh chia cho thi gian thc
hin phn ng
Hng s tc phn ng l: vn tc tng ln ln khi nhit tng ln 100C
II/ l thuyt phn cn bng ha hc

Cho phn ng: Aa + Bb Cc + Dd , phn ng xy ra 2 chiu ta lun c hng s cn bng
K = [A]a[B]b/[C]c[D]d
Nguyn l chuyn dch cn bng: khi tc ng mt nhn t vo mt phn ng th phn ng s xy ra theo
chiu chng li nhn t
B/ Bi tp
Cu 1: Cho cc nhn xt
(1)Bt c p ha hc no cng phi t n trng thi cn bng ha hc
(2) Khi p thun nghch trng thi cn bng th phn ng dng li
(3) trng thi cn bng, khi lng cc cht 2 v ca phng trnh p phi bng nhau
(4) Ch c p thun nghch mi c trng thi cn bng ha hc. S nhn xt ng l:A. Khng c B. Mt
C. Hai
D. Ba
Cu 2: Xt cc phn ng (cc cht trng thi kh)
1. CO + O2 CO2
2. H2O + CO H2 + CO2
3. PCl5 PCl3 + Cl2
4. NH3 + SO2 NO + H2O
Biu thc K ca cc cn bng ho hc trn c vit ng:
K = ([CO]2.[O2]) / [CO2]2(I) K = [CO2]2 / ([CO]2.[O2](II)
K = ([H2O].[CO]) / ([H2].[CO2])(III)
K = ([PCl3].[Cl2]) / [PCl5] (IV)
K = ([NH3]4.[O2]5) / ([NO]4.[H2O]6)(V)
A. (I) (III) (V)
B. (III) (IV) (V)C. (II) (IV) D. (I) (II) (III)
Cu 3: Trong phn ng iu ch kh oxi trong phng th nghim bng cch nhit phn mui kali clorat, nhng bin php
no di y c s dng nhm mc ch tng tc phn ng?
a) Dng cht xc tc mangan ioxit.
b) Nung hn hp kali clorat v mangan ioxit nhit cao
c) Dng phng php di nc thu kh oxi
d) Dng kali clorat v mangan ioxit khan
Hy chn phng n ng trong s cc phng n sau:
A. a, c, d
B. b, c, d.
C. a, b, d
D. a, b, c
Cu 4: T khi ca hh 2 kh N2 v H2 so vi hiro l 4,15. Gi s p tng hp NH3 t hn hp trn t 100%, th sau p
cn d, hay va cc kh l: A. D N2 B. D H2 C. Va D. A, B
Cu 5: Xt cct 0yu t i vi phn ng:
2KCl(r) + 3O2(k)
2KClO3(r)
(1) Kch thc ca cc tinh th KClO3
(2) Nhit
(3) Cht xc tc
(4) p sut
Cc yu t khng lm nh hng n tc p l:
A. (1)(4)
B. Ch (4)
C. (1)(2)
D. Ch (1)
Cu 6: Cho phn ng sau trng thi cn bng:
2H2(k) + O2(k) H2O(k) (H<0)
Tc ng lm thay i hng s cn bng l
A. cho thm cht xc tc
B. tng p sut
C. thm oxi
thay i nhit
Cu 7: Trng thi cn bng trong p thun nghch l trng thi cn bng ng v:
9
A. Phn ng vn xy ra tip tc
B. Nng cc cht khng thay i
C. Tc phn ng thun v nghch bng nhau
D. Tt c u ng
Cu 8: Cho p sau y: N2 + 3H2 2NH3 + Q
Khi tng p sut, cn bng chuyn dch theo chiu no?
A. Chiu nghch
B. Chiu gim nng NH3
C. Chiu ta nhit.
D. Chiu tng s phn t kh.
hp NH3 t hh trn t 100%,th sau p cn d,hay va cc kh l: A. D N2 B. D H2
C. Va
D. A,
B
Cu 9: Trong cc phn ng sau, phn ng no p sut khng nh hng n cn bng phn ng:
A. N2 + 3H2 2NH3
B. N2 + O2 2NO
C. 2NO + O2 2NO2
D. 2SO2 + O2 2SO3
Cu 10: Cho phn ng thun nghch trng thi cn bng:
N2 + 3H2 2NH3 , H = -92 kJ Khi tng p sut, ng thi tng nhit ca h th cn bng dch chuyn theo chiu:
A. Chiu thun.
B. Chiu nghch.
C. Khng xc nh c. D. Khng thay i.
Cu 11: Cho p tng hp amniac: N2 + 3H2 2NH3 H < 0. p xy ra trong bnh kn,c pittng iu khin p
sut,c h thng nc bn thnh bnh, c h thng cung cp nhit bng in Bin php k thut no sau y c th lm
tng hiu sut tng hp NH3
A. Dn dn ko pittng ln, dn nc lnh thng xuyn qua thnh bnh trong qu trnh tng hp.
B. Dn dn nn pittng xung, cung cp nhit cho bnh thng xuyn trong qu trnh tng hp.
C. Dn dn nn pittng, dn nc lnh thng xuyn qua thnh bnh trong qu trnh tng hp.
D. Thng xuyn b sung cht xc tc, v dn dn ko pittng ln, dn nc lnh qua thnh bnh
Cu 12: t chy hh C v S (th tch khng ng k) trong bnh kn ng kh oxi d, sau a bnh v nhit ban
u th p sut bnh so vi trc khi t s:
A. Tng
B. Gim C. Khng i D.Tng hoc gim
Cu 13: Trong qu trnh sn xut gang, xy ra phn ng:
Fe2O3 (r) + 3CO (k)
2Fe(r) + 3CO2 (k). H > 0.
C th dng bin php no di y tng hiu sut phn ng.
A. Tng nhit phn ng B. Tng kch thc qung Fe2O3
C. Nn kh CO2 vo l
D. Tng p sut kh ca h
Cu 14: Cho phn ng tng hp NH3 sau: 2N2 + 3 H2 2NH3 H < 0. Cho cc phng php sau:
(1)
Tng nng ca N2, H2.
(2) Gim nng ca NH3.
(3) B sung H2SO4
(5). Tng nhit
(4)Tng p sut.
(6). Gim nhit
C th tng hiu sut phn ng bng cch:
A. (1), (3), (4), (5)
B. (1), (2), (4), (6).
C. ( 1), (2), (3), (4), (6).
D. (1), (3), (4), (6).
Cu 15: Tm nhn xt ng:
A. Khi them cht xc tc vo phn ng tng hp NH3 N2 + H2, NH3 s lm tng hiu sut ca phn ng.
B. Khi h : 2SO2 + O2 2SO3 trng thi cn bng. Thm vo SO2, trng thi cn bng mi, ch s SO3 l c nng
cao hn so vi trng thi cn bng c.
C. Trong tt cc cc cn bng ha hc: Nu ta ch cn thay i 1 trong 3 yu t sau y: p sut, nhit , nng th h
phn ng s chuyn dch sang mt trng thi cn bng mi.
D. Trong bnh kn ng hn hp NO2 v O2 tn ti cn bng: 2NO2N2O4. Nu ngm bnh trn vo nc thy mu
ca bnh nht dn, do : chiu nghch ca phn ng l chiu thu nhit.
Cu 16: Xt cc yu t sau y tr li 2 cu hi sau y:
(I): Nhit (III): Nng ca cc cht phn ng
(II): Cht xc tc(IV): Bn cht ca cc cht phn ng.
Yu t no nh hng n vn tc phn ng este ho:
A. (I), (II), (III)
B. (II), (III), (IV)
C. (III), (IV), (I)
D. (I), (II), (III), (IV).
Cu 17: Xt cc yu t sau y tr li 2 cu hi sau y:
(I): Nhit
(III): Nng ca cc cht phn ng
(II): Cht xc tc
(IV): Bn cht ca cc cht phn ng.
10
Yu t no nh hng n cn bng ca phn ng este ho
A. (I), (III) B. (III), (IV), (I) C. (I), (II), (III) D. (IV), (I), (II)
Cu 18: Trong phn ng este ho gia ru v axit hu c th cn bng s dch chuyn theo chiu to ra este khi ta:
(1) Gim nng ancolhay axit
(2) Cho ancol d hay axit d
(3) Dng cht ht nc tch nc
(4) Chng ct ngay tch este ra. p n ng l :
A. (1)(3)(4) B. (2)(3)
C. (2)(3)(4)
D. (2)(4)
Cu 19: Cho 0,255 mol N2O4 phn hu v t n cn bng trong th tch bnh l 1,5 lt. Theo s sau:
N2O4(k) 2NO2(k) . KCB = 0,36 ti 100oC. Nng ca NO2 v N2O4 100oC ti thi im cn bng:
A. [N2O4] 0,0833M v [NO2] 0,174M.
B. [N2O4] 0,1394M, [NO2] 0.0612
C. [N2O4] 0,144 v [NO2] 0.052M
D. [N2O4] 0,0947M, [NO2] 0.15067.
Cu 20: Cho phn ng: CO + Cl2 COCl2
Khi bit cc nng cc cht lc cn bng [Cl2] = 0,3 mol/l;
[CO] = 0,2 mol/l; [COCl2] = 1,2 mol/l
Hng s cn bng ca phn ng thun nghch l:
A. 20
B. 40
C. 60
D. 80
Cu 21: Nng lc ban u ca H2 v I2 u l 0,03 mol/l. Khi t n trng thi cn bng, nng HI l 0,04 mol/l.
Hng s cn bng ca p tng hp HI l:A. 16
B. 32 C. 8
D. 10
Cu 22: Bnh kn c th tch 0,5 lt cha 0,5 mol H2 v 0,5 mol N2. Khi phn ng t cn bng c 0,02 mol NH3 c
to nn.
Hng s cn bng ca phn ng tng hp NH3 l:
A. 0,0017
B. 0,003
C. 0,055
D. Kt qu khc
Al(NO3)3+N2O+NO+H2O
Cu 23: Cho p : Al+ HNO3
C tng h s cn bng ti gin l 168. Tng h s cn bng ti gin ca cc sn phm l : A. 96
B. 74
C. 68
D. Kt qu khc
Cu 24: Cho bit p. ho hc sau:
H2O (k) + CO (k) H2 (k) + CO2 (k)
Kcb =0,167 ( 200oC)
Nng H2 v CO trng thi cn bng ?, bit rng hn hp ban u gm 3 mol H2O v 4 mol CO trong bnh V= 10 lt
200oC.
A. 0.02M , 0,03M
B. 0.03M ; 0,02M
C. 0.2M ; 0,3M
D. 0,1 M; 0,2M
Cu 25: Trong mt bnh kn, nhit khng i, ngi ta trn 512g kh SO 2 v 128g O2. Khi c cn bng kh SO2 cn
li bng 20% lng ban u. Nu p sut ban u l 3 atm th p sut lc cn bng l bao nhiu?A.2,3 atm B.2,2 atm
C.1,1 atm D.1,15 atm
Cu 26: Nn 2 mol N2 v 8 mol H2 vo bnh kn c th tch 2 lt (cha sn cht xc tc vi th tch khng ng k) v
gi cho nhit khng i. Khi phn ng trong bnh t ti trng thi cn bng, p sut cc kh trong bnh bng 0,8 ln
p sut lc u (khi mi cho vo bnh, cha xy ra phn ng). Nng ca kh NH3 ti thi im cn bng l gi tr no
trong s cc gi tr sau?
A. 1M
B. 2M
C. 4M
D. 3M
Cu 27: Cho phn ng:
CH3COOH + C3H7OH CH3COOC3H7 + H2O
Ban u ta cho 2 mol axit axetic tc dng vi 2 mol ancol isopropylic th cn bng s t c khi c 1.2 mol
isopropylic axetat c to thnh.Lc ta thm 2 mol axit axetic vo hn hp phn ng, cn bng s b ph v v
chuyn dch ti trng thi cn bng mi. Lc ny s mol mi cht trong hn hp l:
A.[CH3COOH]=1.95,[C3H7OH]=0.95,[CH3COOC3H7]=2.05,[H2O]= 2.05
B. [CH3COOH] = 2.8, [C3H7OH] = 0.8, [CH3COOC3H7] = 1.2, [H2O] =1.2
C. [CH3COOH]=2.28, [C3H7OH]=0.28,[CH3COOC3H7]= 1.72,[H2O]=1.72
D. [CH3COOH] = 2.8, [C3H7OH]= 0.8, [CH3COOC3H7]= 1.2, [H2O] =1.72
Cu 28: Dung dch 0,1M ca mt monoaxit c in ly bng 5%. Hy xc nh hng s cn bng ca axit ny:
A. 2,4.10-4
B. 3,7.10-3
C. 2,6.10-4
D. 4,2.10-2
Cu 29: Trong mt bnh kn, nhit khng i, ngi ta trn 512g kh SO 2 v 128 gam O2. Khi c cn bng kh SO2
cn li bng 20% lng ban u. Nu p sut ban u l 3 atm th p sut lc cn bng l bao nhiu?
A. 2,3 atm
B. 2,2atm
C. 1,1atm D. 1,15 atm
11
Cu 30: Mt p c thc hin 100C mt 48 pht, 500C mt 3 pht. Nu p c thc hin nhit l 350C th
mt mt thi gian xp x l: A. 8.5 pht B. 8 pht C. 4.3 pht D. KQ khc
Cu 31: Cho phn ng A + B C. Bit rng nu nng ban u ca cht A l 0,02M, ca cht B l 0,004M th sau
25 pht lng cht C hnh thnh l 10% khi lng ca hn hp. Nu nng cht A vn nh c, nng cht B l
0,02M th sau bao lu lng cht C thu c cng l 10%.
A. 5 pht
B. 10 pht
C. 4 pht
D. 15 pht
Cu 32: T khi ca hn hp 2 kh N2 v H2 so vi hiro l 4,15. Gi s phn ng tng hp NH3 t hh trn t 100%, th
sau p cn d, hay va cc kh l: A.D N2 B.D H2 C.Va D.A, B
Cu 33: Cho phn ng A + B C. Bit rng nu nng ban u ca cht A l 0,02M, ca cht B l 0,004M th sau
25 pht lng cht C hnh thnh l 10% khi lng ca hn hp. Nu nng cht A vn nh c, nng cht B l
0,02M th sau bao lu lng cht C thu c cng l 10%.
A. 5 pht
B. 10 pht
C. 4 pht
D. 15 pht
Cu 34: Cho phn ng: 2SO2 + O2 2SO3.Vn tc phn ng thay i th no nu th tch hn hp gim i 3 ln:
A. Tng 27 ln
B. Gim 27 ln C. Tng 9 ln
D. Khng i
Cu 35: Cho phn ng: 2A + B 2C + D
Tc ca phn ng thay i th no nu nng ca cht A tng ln 2 ln cn nng cht B khng i:
A. Khng i B. Gim 4 ln C. Tng 4 ln D. Tng 2 ln
Cu 36: Cho phn ng: 2SO2 + O2
2SO3. toC nng lc cn bng ca cc cht l: [SO2]=0,2 [O2]=0,1
[SO2]=1,8
Tc phn ng thun v nghch s thay i th no?
A. V'n > 9Vn B. V'n = 9VnC. V'n < 9Vn
D. p n khc
(V'n vn tc phn ng nghch sau , Vn vn tc phn ng nghch ban u)
Cu 37: Trong cc cp phn ng sau, cp no c tc phn ng ln nht: A. Fe + dd HCl 0,1M
B. Fe +
dd HCl 0,2M
C. Fe + dd HCl 0,3M D. Fe + dd HCl 20% (d= 1.2 g/ml)
Cu 38: Cho phn ng: 2A +B C. Nng ban u ca A l 6M, ca B l 5M. Hng s vn tc k = 0,5. Vn tc
phn ng khi c 55% cht B tham gia phn ng xp x l:
A. 2,5
B. 1,5
C. 3,5
D. Tt c u sai
Cu 39: Cho phn ng: N2 + 3H2
2NH3. Hn hp A ban u gm N2 v H2 c d/H2=3,6. Thc hin phn ng di
iu kin thch hp thu c hn hp B. Bit H = 75%. Cho hn hp qua CuO d th thy khi lng bnh gim 6,4
gam. Hi V (lit)?
A. 25,6
B. 11,2
C. 19,91
D. 59,73
Cu 40: Cho 10 lit H2 v 6.72 lit Cl2 tc dng vi nhau ri ha tan vo 385,4 g nc ta thu c dung dch A. Ly 50 g
dung dch A cho tc dng vi dung dch AgNO3 d ta thu c 7,175 g kt ta. Hiu sut gia phn ng H2 v Cl2 l:
A. 66,67% B. 33,33% C. 8,33%
D. 44,8%
Cu 41: Cho hn hp A gm N2, H2 O0C, 2atm c d/H2 = 3,1. ung nng xy ra phn ng to ra NH3 ri cho qua
CuO d. Hi 136,50C th p sut ca bnh l:
A. 2
B. 3
C. 4
D. Thiu d kin
Cu 42: Cho phn ng: N2O4(k) 2NO2(k). Ban u ta cho 5,6 lit (ktc). Sau khi phn ng thc hin c mt thi gian,
sc hn hp kh vo nc th thu c 1 dung dch c kh nng ha tan m gam FeCO 3, to ra 0,04 mol hn hp kh X
c d/H2 = 20,25. H = ? % A. 75
B. 50
C. 30 C. 20
Cu 43: 2SO2 + O2 2SO3. Cho 8,96 lit hn hp A gm SO2, O2. Thc hin phn ng ri cho qua dung dch Ba(OH)2
th thu c 6,63 gam kt ta. H = ?
A. 66,67
B. 33,33
C. 100
D. 50
Cu 44: 3O2 2O3. Cho 1 mol oxi qua tia UV, thu c hn hp kh A. Dn hn hp A qua KI thu c 1 dung dch
ha tan ti a ? gam Zn. Bit th tch gim 40% th tch hn hp A.
A. 24,375
B. 19,5
C. 48,75
D. 39
Cu 45: Cho 1 th tch khng kh cn thit i qua bt than un nng thu c hn hp A cha CO, N2. Trng A vi 1
lng khng kh gp 2 ln lng cn thit t chy CO ta c hn hp kh B. t chy B hn hp kh D trong
N2 chim 79,21% th tch. Hi H = ?A. 85 B. 50
C. 60 D. 80
Cu 46: Cho phn ng: A + B C. Ban u: [A] = 0.7, [B] = 1.0. Sau 10s: [A] = 0.68. Hi tc trung bnh ca phn
ng trong khong thi gian trn l bao nhiu:
A. 0.001 mol/l.sB. 0.002 mol/l.sC. 0.001 mol/s D.0.002 mol/s
Cu 47: Bit rng khi nhit tng ln 100 C th tc ca mt phn ng ha hc tng ln 3 ln. Hi tc ca phn
ng tng ln bao nhiu ln khi nng nhit t 140C ln 540C:
A. Tng 12 ln
B. Tng 9 ln C. Tng 81 ln
D. Tng 243 ln
12
Cu 48: Cho mt mu vi nng 10 gam vo 200 ml dung dch HCl 2M. Tc phn ng ban u s gim nu
A. Nghin nh vi trc khi cho vo
B. Thm 100ml dd HCl 4M
C. Tng nhit phn ng
D. Thm 500ml dd HCl 1M
Cu 49: Cho phn ng: N2 + 3H2 2NH3
Bit rng khi nhit tng thm 100C th tc ca phn ng trn tng ln 2 ln. Khi gim nhit t 55 0C xung
250C, tc phn ng khng i th ta c th thc hin cch sau:
A. Gim p sut c h i 2 ln
B. Tng p sut c h ln 2 ln
C. Tng nng H2 ln 2 ln
D. im nng H2 i 2 ln
Cu 50: Khi nhit phn cc cht sau: NH4NO3, NH4NO2, NH4HCO3, CaCO3, KMnO4, NaNO3, Fe(NO3)2. S p thuc
p oxi ho kh l: A. 3.
B. 6.
C. 5.
D. 4.
Chuyn 04: S in li in phn

A/ L thuyt
I/ S in li
1. Cc nh ngha c bn, phn loi cc cht in li
a. cht in li mnh: l cht khi ha tan trong nc phn li hon ton thnh cc tiu phn nh( cc cation v
anion), c in li = 1
b. cht in li yu: l cht c in li < 1
2. Hng s in li, hng s cn bng

Gi s c pt in li: AB An+ + Bn- ta lun c
- in li = C/C0 = N/N0
- hng s cn bng K= [A][B]/ [AB] v c h s t lng
-trong trng hp << 1 ta c K =C2
3. Tch s ion ca nc v ph dung dch

- Trong mi dd u c [H+][OH-] = 10-14
- cch xc nh pH dd: pH = -lg[H+]
4. nh ngha axit, bazo, mui

- axit l cht, ion c kh nng phn li ra H+( hay nhng proton)
- bazo l cht, ion c kh nng nhn H+( nhn proton)
- cht lng tnh l cht c kh nng nhng v nhn H+
5. S thy phn
Nhn xt: mt s cation ca kim loi t Mg2+ tr i khi ha tan trong nc cho mi trng axit( trong
c gc NH4+) pH < 7
Gc axit yu khi tan trong nc b thy phn trong mi trng kim pH > 7
Mui to bi kim loi trung bnh, yu v gc axit yu c mi trng ty thuc vo kh nng thy phn
ca cc ion
B/ Bi tp
13
Cu 1: Hn hp X gm axit fomic, axit axetic v axit oxalic tc dng va vi dung dch NaOH 10% thu c dung
dch Y trong nng phn trm ca HCOONa v CH3COONa ln lt l 2,532% v 3,053%. Nng % ca
(COONa)2 trong ddY l :
A. 10,045%
B. 8,645%
C. 9,978%
D. Kq khc
Cu 2: Dung dch axit fomic 0,92% c khi lng ring 1g/mol. in li ca axit fomic trong iu kin ny l
0,5%.Tnh nng mol ca dung dch (b qua s in li ca nc )
A. 10-3M
B. 10-2M
C.10-1 M
D. 1 M
Cu 3: Trong 500ml dung dch CH3COOH 0,02M c in li 4% c cha bao nhiu ht vi m?
A. 6,02 1021
B.1,204 1022 C. 6,26 1021 D. 1,204 1023
Cu 4: Dung dch HCOOH 0,1M c in li l 0,2%.Pha long dung dch bao nhiu ln c in li tng 4 ln.
A. 14 ln
B. 15 ln
C. 16 ln
D. 17 ln
Cu 5: Dung dch CH3COOH c in li = 1%, nng CA, pH = a. Dung dch NH3 c in li = 0,1%, nng
CB, pH = b
Cho b = a +9.Quan h CA&CB?
A. CA= 1/CB B. CA = 8CB
C. CA = C8 +5 D. CA = 9CB
Cu 6: Tnh pH ca dung dch HCOOH 0,1M c Ka= 1,6.10-4 ?
A. 2,9
B. 1,2
C. 2,4
D. Kt qu khc
Cu 7: Dung dch A cha: HF 0,1M; NaF 0,1M; Ka=6,8.10-4. Dung dch A c pH?
A. 2,17
B. 3,17
C. 3,3
D. 4,2
Cu 7: Axit axetic c hng s phn li l 1,8.10-5. Tnh nng ca H+ trong dung dch CH3COOH 0,02M
A. 6 10-4 B. 6 10-3
C. 1,34 10-4
D. 1,34 10-3
-5
Cu 8: Dung dch NH3 0,1M c Kb=1,80x10 th [OH ] c gi tr l:
A. 1,34x10-3 B. 1,34x10-2
C. 2,68x10-3
D. 1,34x10-5
Cu 9: Trong dung dch CH3COOH 0,043M c =20% th [H+], [CH3COO-] v [CH3COOH] c gi tr l:
A. 0,0086, 0,0086 v 0,034M
B. 0,0096, 0,001 v 0,068M
C. 0,096, 0,096 v 0,034M
D. 0,001, 0,0086 v 0,068M
Cu 10: Cho dung dch X cha hn hp gm CH3COOH 0,1M v CH3COONa 0,1M. Bit 250C Ka ca CH3COOH l
1,75.10-5 v b qua s phn li ca nc. Gi tr pH ca dung dch X 25o l
A. 1,00
B. 4,24
C. 2,88
D. 4,76
Cu 11: Lng SO3 cn thm vo dung dch H2SO4 10% c 100g dung dch H2SO4 20% l:
A. 2,5g
B. 8,88g
C. 6,66g
D. 24,5g
Cu 12: Cho dung dch G cha cc ion Mg2+, SO42- ; NH4+ v ClChia dung dch G thnh hai phn bng nhau. Phn th nht tc dng vi dung dch NaOH d, un nng, c 0,58 gam
kt ta v 0,672 lt kh (ktc). Phnth hai tc dng vi dung dch BaCl2 d, c 4,66 gam kt ta. Khi lng ca cc
cht tan trong dung dch G.
A. 6,11 gam B. 3,055 gam C. 6 gam
D. 3 gam
Cu 12: C 10ml dung dch axit HCl c pH = 3. Cn thm bao nhiu ml nc ct thu c dung dch axit c pH = 4?
A. 90ml
B. 100ml
C. 10ml
D. 40ml
Cu 14: Phi thm bao nhiu ml dung dch Ba(OH)2 0,05M (Ba(OH)2 l baz mnh) vo 9ml nc c 1 dung dch
c pH =12
A. 2ml
B. 3ml
C. 5ml
D. 1ml
Cu 15: Trn 20ml dung dch HCl 0,05M vi 20ml dung dch H 2SO4 0,075M. Nu coi th tch sau khi pha trn bng
tng th tch ca hai dung dch u th pH ca dung dch thu c l:
A1
B. 2
C. 3
D. 1,5
Cu 16: Phi thm bao nhiu ml dung dch HCl 2M vo 10 ml Ba(OH)2 0,1 M c 1 dung dch c [H+] =0,04 M?
A. 20ml
B. 15ml
C. 10ml
D. 30ml
Cu 17: Dung dch A cha 2 axit H2SO4 cha bit CM v HCl 0,2 M.dung dch B cha 2 baz NaOH 0,5M v Ba(OH)2
0,25M. Tnh CM ca H2SO4 bit 100 ml dung dch trung ha va 120ml ddch B?
A. 1M
B. 0,5M
C. 0,75M
D. 0,25M
Cu 18: Trn 100ml dung dch H2SO4 vi 100ml dung dch NaOH c pH=12.Dung dch thu c c pH = 2.Tnh nng
mol ca dung dch H2SO4 ban u ?
A. 0,02M
B. 0,04M
C. 0,015M
D. 0,03M
Cu 19: Cho 2 dung dch : dung dch A cha 2 axit H2SO40,1M v HCl 0,2M v dung dch B cha 2 baz NaOH 0,2M
v KOH 0,3 M .Phi thm bao nhiu ml dung dch B vo 100ml dung dch A c 1 dung dch c pH=7?
A. 60ml
B. 120ml
C. 100ml
D. 80ml
14
Cu 20: Thm 25 ml dung dch NaOH 2M vo 100ml dung dch H 2SO4, dung dch thu c tc dng vi Na 2CO3 d cho
ra 2,8 l kh CO2 (ktc).Tnh nng mol ca dung dch H2SO4 ban u?
A. 1,5M
B. 1,75M
C. 3M
D. 1M
Cu 21: Trn 100 ml dung dch (gm Ba(OH)2 0,1M v NaOH 0,1M) vi 400 ml dung dch (gm H2SO4 0,0375M v
HCl 0,0125M), thu c dung dch X. Gi tr pH ca dung dch X l
A. 7.
B. 2.
C. 1.
D. 6.
Cu 22: Cho mu hp kim K-Ba tc dng vi nc d thu c dung dch X v 4,48 l kh ktc.Trung ho X cn a lit
dung dch HCl c pH=2. Tnh a?
A. 2 lit
B. 4 lit
C. 6 lit
D. 8 lit
Cu 23: Hn hp Y gm dung dch HCl v H2SO4 c th tch bng nhau.Cho m gam hn hp Ca,Fe vo 400ml Y thu
c 6,272 l kh.Gi s V khng i.Tm pH dung dch sau phn ng?
A. 1
B. 2
C. 13
D. Kt qu khc
Cu 24: Trn 400ml dung dch HCl 0,05M v H2SO4 0,025M vi 600ml dung dch Ba(OH)2 a mol/l thu c m gam kt
ta v 1000ml dung dch c pH=12.Tm m?
A. 2,33
B. 3.495
C. 4,60
D. 6,99
Cu 25: Dung dch X cha cc ion sau: Al3+, Cu2+, SO42- v NO3-. kt ta ht ion SO42- c trong 250 mL dung dch X
cn 50 mL dung dch BaCl2 1M. Cho 500 mL dung dch X tc dng vi dung dch NH3 d th c 7,8 gam kt ta. C
cn 500 mL dung dch X c 37,3 gam hn hp mui khan. Nng mol/l NO3- l:
A. 0,2 M
B. 0,3 M
C. 0,4 M
D. 0,6 M
Cu 26: Dung dch A 0,01mol HCl v 0,02mol NaCl.in phn A c mng ngn ti khi ant thot ra 0,224 l kh th
ngng li,trong bnh cn 1 l dung dch B. Dung dch B c pH =?
A. 1
B. 2
C. 12
D .13
Cu 27: Dung dch HCl c pH =5 (V1) cho vo dung dch KOH pH =9 (V2).Tnh V1/V2 dung dch mi pH=8
A. 0,1
B. 10
C. 2/9
D. 9/11
Cu 28: 400ml dung dch NaOH c pH = a tc dng vi 500ml dung dch HCl 0,4M.C cn dung dch thu 15,7g cht
rn.Tm a?
A. 12,5
B. 13,477
C.13,875
D. 13,3
Cu 29: 100ml dung dch A cha HCl 2M v HNO3 1,5M tc dng va vi 0,1 l dung dch B cha NaOH 0,5M v
KOH a M.Tm a?
A. 1
B. 2
C. 3
D. 4
Cu 30: A l dung dch HCl,B l dung dch NaOH.Tin hnh 2 th nghim: Th nghim 1:Trn A,B theo t l VA : VB =
3 :2 th c dung dch X.1 l dung dch X tc dng va vi 17g AgNO3
Th nghim 2:Trn A,B theo t l VA : VB = 2 : 3 th c dung dch Y.1 l dung dch Yc pH=13. Tnh CM ca 2 dung
dch A v B
A. 0,1M;0,2M
B. 0,1M;0,1MC. 0,2M;0,1M
D. 0,2M;0,2M
Cu 31: Trung ho dung dch HCl 21,9% bng dung dch NaOH 30%. Dung dch mui c nng % l
A. 34,6%
B. 19,5%
C. 13%
D. Kt qu khc
Cu 32: Cho 8,96 lt kh CO2 (ktc) vo 250 ml dung dch NaOH 2M c dung dch X. Cho X tc dng vi dung dch
Ca(OH)2 d c a gam kt ta. Nu cho X tc dng vi dung dch CaCl2 d c b gam kt ta. Gi tr (a b) bng:
A. 0 g
B. 15 g
C. 10 g
D. 30 g
Cu 33: Ho tan 17 gam hn hp X gm K v Na vo nc c dung dch Y v 6,72 lt kh H2 (ktc). trung ho
mt na dung dch Y cn dung dch hn hp H2SO4 v HCl (t l mol 1:3). Khi lng mui khan thu c l:
A. 20,65 g B. 34,20 gam C. 41,30 gam D. 20,83 gam
Cu 34: Cho 14,6 gam hn hp X gm Na v Al vo nc d c 11,2 lt kh H2 (ktc). Khi lng Al c trong X l:
A. 8,85 gam
B. 5,4 gam
C. 5,4 gam hoc 8,85 gam
D. 5,4 hoc 8,10 gam
Cu 35: Cho V lt kh CO2 (ktc) vo dung dch Ca(OH)2 c 3 gam kt ta, lc b kt ta un nng dung dch nc
lc th c thm 1 gam kt ta na. Tm V.
A. 0,672 lt B. 0,896 lt
C. 0,784 lt
D. 1,12 lt
Cu 36: Cho V lt dung dch NaOH 2M vo dung dch cha 0,1 mol Al2(SO4)3 v 0,1 mol H2SO4 n khi phn ng
hon ton, thu c 7,8 gam kt ta. Gi tr ln nht ca V thu c lng kt ta trn l
A. 0,45.
B. 0,35.
C. 0,25.
D. 0,05.
Cu 37: Ha tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110 ml dung dch KOH 2M vo X, thu c a gam
kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l
A. 20,125
B. 12,375
C. 22,540
D. 17,710
15
Cu 38: Cho 0,448 lt kh CO2 ( ktc) hp th ht vo 100 ml dung dch cha hn hp NaOH 0,06M v Ba(OH)2
0,12M, thu c m gam kt ta. Gi tr ca m l
A. 3,940
B. 1,182
C. 2,364
D. 1,970
Cu 39: Cho t t tng git V lit dd HCl 0,1M vo dung dch K2CO3 thu c dung dch B v 0,56 L (ktc) kh CO2.
Cho dung dch B tc dng vi dung dch Ca(OH)2 d thy to ra 1,5 gam kt ta. V bng :
A. 800 ml
B. 650 ml
C. 500 ml
D. 400 ml
Cu 40: 100 mL ddch hn hp X cha NaOH 1,5M v Ba(OH)2 2M c trung ha bi V (L) dung dch Y cha H2SO4
0,5M v HCl 1M. Sau phn ng thu c a gam kt ta. Gi tr ca V v a ln lt l :
A. 0,2750; 32,0
B. 0,1375; 23,3 C. 0,1375; 16,0 D. 0,2750; 46,6
Cu 41: Mt hn hp X c khi lng m gam gm Ba v Al. Cho m gam X tc dng vi nc d, thu c 8,96 lt kh
H2.Cho m gam X tc dng vi dung dch Ba(OH)2 d thu c 22,4 lt kh H2. (Cc phn ng u xy ra hon ton, cc
th tch kh o iu kin tiu chun), m c gi tr l
A. 29,9 gam. B. 27,2 gam. C. 16,8 gam. D. 24,6 gam.
Cu 42: Cho V lt kh CO2 ( ktc) hp th hon ton vo 200 ml dung dch hn hp KOH 1M v Ba(OH)2 0,75M thu
c 27,58 gam kt ta. Gi tr ln nht ca V l
A. 6,272 lt. B. 8,064 lt.
C. 8,512 lt.
D. 2,688 lt.
Cu 43: Trong mt cc ng ha cht l 200 mL dung dch AlCl3 2M. Rt vo cc 200 mL dung dch NaOH nng
a (M) thu c mt kt ta. em kt ta sy kh, nung n khi lng khng i thu c 5,1 gam cht rn. Vy a
bng:
A. 1,5 M.
B. 1,5 M hoc 3,0 M.
C. 1,5 M hoc 7,5 M.
D. 1,0 M hoc 1,5 M.
Cu 44: 200 ml dung dch A cha cc ion: NH 4+; K+; Cl- SO42-; vi nng mol/l tng ng l 0,5M; 0,1M; 0,1M;
0,25M. Nu dd A c iu ch t 3 mui th l nhng mui no?
A. (NH4)2SO4, KCl, K2SO4
B. NH4Cl, KCl, K2SO4.
C. (NH4)2SO4, NH4Cl, K2SO4 D. (NH4)2SO4, NH4Cl, KCl
Cu 45: Cho 27,4 gam bari kim loi vo 500 gam dung dch hn hp (NH4)2SO4 1,32% v CuSO4 2% un nng thu c
kh A, kt ta B v dung dch C. Th tch kh A (ktc) v khi lng kt ta B ln lt bng:
A. 6,72 lv 26,21 gam
B. 4,48 l v 26,21 gam
C. 6,72 l v 32,34 gam
D. 4,48 l v 32,34 gam
Cu 46: Nh t t 0,25 lt dung dch NaOH 1,04M vo dung dch gm 0,024 mol FeCl3; 0,016 mol Al2(SO4)3 v 0,04
mol H2SO4 thu c m gam kt ta. Gi tr ca m l
A. 4,128
B. 2,568
C. 1,560
D. 5,064
Cu 47: Ho tan hon ton 47,4 gam phn chua KAl(SO4)2.12H2O vo nc, thu c dd X. Cho ton b X tc dng
vi 200 ml dd Ba(OH)2 1M, sau phn ng thu c m gam kt ta. Gi tr ca m l
A. 46,6
B. 54,4
C. 62,2
D. 7,8
Cu 48: Ha tan ht m gam ZnSO4 vo nc c dung dch X. Cho 110ml dung dch KOH 2M vo X, thu c a gam
kt ta. Mt khc, nu cho 140 ml dung dch KOH 2M vo X th cng thu c a gam kt ta. Gi tr ca m l
A. 20,125.
B. 12,375.
C. 22,540.
D. 17,710.
Cu 49: Trn 100 ml dung dch hn hp gm H2SO4 0,05M v HCl 0,1M vi 100 ml dung dch hn hp gm NaOH
0,2M v Ba(OH)2 0,1M thu c dung dch X. Dung dch X c pH l
A. 1,2
B. 1,0
C. 12,8
D. 13,0
Cu 50: Ho tan hon ton m gam hn hp X gm Na2O v Al2O3 vo H2O thu c 200 ml dung dch Y ch cha cht
tan duy nht c nng 0,5M. Thi kh CO2 (d) vo Y thu c a gam kt ta. Gi tr ca m v a ln lt l :
A. 13,3 v 3,9B. 8,3 v 7,2 C. 11,3 v 7,8 D. 8,2 v 7,8
Cu 51: Mt dung dch cha hn hp gm 0,02 mol Al2(SO4)3 v 0,02 mol Na2SO4. Thm dung dch cha 0,07 mol
Ba(OH)2 vo dung dch trn th khi lng kt ta sinh ra l
Cu 52: Cho 200ml dung dch Al2(SO4)3 tc dng vi dung dch NaOH 1M ngi ta nhn thy khi dng 220ml dung
dch NaOH hay dng 60ml dung dch NaOH trn th vn thu c lng kt ta bng nhau. Tnh nng ca dung dch
Al2(SO4)3 ban u.
A. 0,125M. B.0,15M
C.0,075M.
D. 0,25M
Cu 53: Trn 3 dung dch H2SO4 0,1M; HNO3 0,2M; HCl 0,3M vi nhng th tch bng nhau thu c dung dch A.
Ly 300 ml dung dch A cho phn ng vi V lt dung dch B gm NaOH 0,2M v KOH 0,29M thu c dung dch C c
pH = 2. Gi tr V l:
A. 0,424 lt B. 0,414 lt C. 0,214 lt
D. 0,134 lt
16
Cu 54: Dung dch X cha hn hp NaOH a mol/lit v Ba(OH)2 b mol/lit. trung ho 50 ml dung dch X cn 60 ml
dung dch HCl 0,1M. Mt khc cho mt lng d dung dch Na2CO3 vo 100 ml dung dch X thy to thnh 0,394 gam
kt ta. a, b ln lt l:
A. 0,1M v 0,01M
B. 0,1M v 0,08M
C. 0,08M v 0,01 M
D. 0,08M v 0,02M
Cu 55: Cho 12,4 gam P tc dng hon ton vi oxi, sau cho ton b sn phm ho tan vo 80ml dung dch NaOH
25% (d= 1,28). Nng % ca mui to thnh trong dung dch l:
A. Na3PO430% v NaH2PO420%
B. NaH2PO4 14,68% v Na2HPO4 26,06%
C. NaH2PO410% v Na2HPO426,06%
D. Na3PO4 20%
Cu 56: 1l dung dch X c cha 0,2mol Fe2+ ; 0,3mol Mg2+ v 2anion Cl-,NO3-.C cn cn thn dung dch thu c
69,8g cht rn.Tnh nng mol ln lt ca 2 anion trn
A. 0,5M; 0,5M
B. 0,4M; 0,6M C. 0,6M; 0,4M
D. 0,2M; 0,8M
Cu 57: Dung dch A cha cc ion Cu2+;Fe3+,Cl-. kt ta ht ion Cl- trong 10ml dung dch A phi dng ht 70ml dung
dch AgNO3 1M.C cn 100ml dung dch A thu c 43,25g hn hp mui khan.Tnh nng mol cc ion
Cu2+,Fe3+,ClA. 2M,1M,7M
B. 2M,1M,0,7M
C. 0,2M;0,1M;7M
D. 0,2M;0,1M;0,7M
Cu 58: Dung dch X cha cc ion: Fe3+, SO42-, NH4+, Cl-. Chia dung dch X thnh hai phn bng nhau: Phn mt tc
dng vii lng d dung dch NaOH, un nng thu c 0,672 lt kh ( ktc) v 1,07 gam kt ta; Phn hai tc dng
vi lng d dung dch BaCl2, thu c 4,66 gam kt ta. Tng khi lng cc mui khan thu c khi c cn dung
dch X l (qu trnh c cn ch c nc bay hi)
Cu 59: Dung dch X c cha 0,07 mol Na+, 0,02 mol SO42- v x mol OH-. Dung dch Y c cha y mol H+ v tng s
mol ca ClO4-v NO3- l 0,04. Trn X v Y c 100 ml dung dch Z. pH ca ddch Z bng
A. 2
B. 12
C. 1
D. 13
Cu 60: Dung dch A gm 5 ion: Mg2+, Ba2+, Ca2+, 0,1 mol Cl- v 0,2 mol NO3-. Thm t t dung dch K2CO3 1M vo
dung dch A n khi lng kt ta ln nht th th tch dung dch K2CO3 cho vo l:
A. 150 ml
B. 300 ml
C. 200 ml
D. 250 ml
Chuyn 05: Bi tp tng hp v kim loi, phi kim v bi

tp v HNO3; H2SO4 c nng
A/ Nhc li l thuyt tc ha hc ca cc hp cht v c
B/ Bi tp
Cu 1. Ho tan hon ton hn hp gm 16,8 gam Fe v 9,6g Cu trong V lt dd HNO3 2M . Sau khi phn ng xy ra hon
ton thu c dd cha 91,5g mui v kh NO l sn phm kh duy nht. Gi tr V l
A. 0,6
B. 0,8
C. 0,9
D. 0,7
Cu 2. Cho a gam hn hp A gm Fe2O3, Fe3O4 v Cu vo dd HCl d thy c 1 mol axit phn ng v cn li 0,256a gam cht
rn khng tan. Mt khc, kh hon ton a gam hn hp A bng H2 d thu c 42g cht rn. Tnh % khi lng Cu trong
hn hp A?
A. 25,6%
B. 50%
C. 44,8%
D. 32%
Cu 3. Hn hp kh A gm CO v H2. Hn hp B gm O2 v O3 c t khi i vi H2 l 20. t chy hon ton 10V lt
kh A cn lng th tch kh B l (cc kh o cng iu kin nhit , p sut)
A. 2V
B. 6V
C. 4V
D. 8V
Cu 4. Ho tan a gam Al vo 450 ml dd NaOH 1M thu c 13,44 lt H2 (ktc) v dd A. Ho tan b gam Al vo 400 ml
dung dch HCl 1M thu c 3,36 lt H2 (ktc) v dd B. Trn dd A vi dd B n phn ng hon ton th thu c m gam kt
ta. Gi tr m l
A. 31,2
B. 3,9
C. 35,1
D.7,8
17
Cu 5. Cho 1 lng bt Zn vo dd X gm FeCl2 v CuCl2. Khi lng cht rn sau khi phn ng hon ton nh hn khi
lng bt Zn ban u l 0,5g. C cn phn dd sau phn ng thu c 13,6g mui khan. ng khi lng mui tromg dd X l
A. 14,1g
B. 13,1g
C. 17,0g
D. 19,5g
Cu 6. Chia 156,8g hn hp A gm FeO, Fe3O4, Fe2O3 thnh 2 phn bng nhau. Cho phn 1 tc dng vi dd HCl d c
155,4g mui khan. Phn 2 tc dng va vi dd hn hp M gm HCl, H2SO4 long thu c 167,9g mui. S mol HCl
trong dd M l
A. 1,00 mol
B. 1,75 mol
C. 1,80 mol
D. 1,50 mol
Cu 7. Cho 8,4g Fe tc dng vi O2 thu c 10,4g hn hp X gm Fe, FeO, Fe3O4. Cho ton b X vo V lt dd HNO3 2M.
Sau phn ng thu c 1,12 lt kh NO (ktc) l sn phm kh duy nht v dd A. Tnh V v khi lng cht tan trong dd A
A. 0,2 v 36,3g
B. 0,2 v 27g
C. 0,25 v 27g
D. 0,225 v 33,2g
Cu 8. Ho tan hon ton 80g hn hp X gm CuSO4, FeSO4, Fe2(SO4)3 (trong S chim 22,5% v khi lng) trong nc
c dd X. Thm dd NaOH d vo dd X. Lc kt ta en nung trong khng kh n khi lng khng i thu c cht rn
Y, thi CO d qua Y thu c hn hp rn Z. Bit cc phn ng xy ra hon ton. Khi lng ca Z l
A. 30g
B. 36g
C. 26g
D. 40g
Cu 9. Ho tan hon ton 3,76g hn hp: S, FeS, FeS2 trong HNO3 d thu c 0,48 mol NO2 v dd X. Cho dd Ba(OH)2 d
vo X, lc kt ta, nung n khi lng khng i th khi lng cht rn thu c l
A. 15,145g
B. 17,545g
C. 2,4g
D. 18,355g
Cu 10. Mt hn hp X gm Na, Al, Fe (vi t l Na : Al l 5 : 4) tc dng vi H2O d th thu c V lt kh, dd Y v cht
rn Z. Cho dd Z tc dng vi dd H2SO4 long d th thu c 0,25V lt kh (cc kh o cng iu kin). Thnh phn % khi
lng ca Fe trong hn hp X l
A. 14,4%
B. 33,43%
C. 20,07%
D. 34,8%
Cu 11. Cho hn hp X gm 0,09 mol Fe v 0,05 mol Fe(NO3)2.7H2O vo 500 ml dd HCl 1M, kt thc phn ng thu c dd
Y v kh NO (sn phm kh duy nht). Hi dd Y ho tan ti a bao nhiu gam Cu?
A. 3,84
B. 4,48
C. 4,26
D. 7,04
Cu 12. Cho 49,8g hn hp X gm Cu, Fe, Fe2O3 vo dung dch H2SO4 long (d), khuy u cho cc phn ng xy ra hon
ton thy c 2,4g kim loi khng tan, 1,12 lt kh thot ra v thu c dd Y. Cho dd NH3 n d vo dung dch Y, lc kt
ta ri nung trong khng kh n khi lng khng i cn li 40g cht rn khan. P trm k lng ca Cu trong hn hp X l
A. 4,83%
B. 20,64%
C. 24,19%
D. 17,74%
Cu 13. Dn 0,5 mol hn hp kh gm H2 v CO c t khi so vi H2 l 4,5 qua ng ng 0,4 mol Fe2O3 v 0,2 mol CuO
un nng. Sau phn ng hon ton cho cht rn trong ng vo dd HNO3 long, d thu c V lt kh NO (sn phm kh duy
nht, ktc). Gi tr ca V l
A. 20,907
B. 3,730
C. 34,720
D. 7,467
Cu 14. t hn hp gm 0,4 mol Fe v 0,2 mol Cu trong bnh ng kh oxi, sau mt thi gian thu c m gam cht rn.
em cht rn ny tc dng vi dung dch HCl d, sau phn ng hon ton c 3,36 lt kh thot ra (ktc) v 6,4g kim loi
khng tan. Gi tr ca m l
A. 44,8
B. 41,6
C. 40,8
D. 38,4
Cu 15. Cho 13,12g hn hp X gm Fe, Fe3O4, Fe2O3 vo dung dch HNO3 long, d thu c sn phm kh gm hai kh NO
v N2O c th tch V lt (ktc) v c t khi so vi H2 l 18,5. Mc khc nu cho cng lng X trn tc dng vi kh CO (d)
sau phn ng thu c 9,8g Fe. Gi tr ca V l
A. 2,24
B. 0,448
C. 3,36
D. 3,136
Cu 16. Cho m gam bt Fe vo dung dch cha 0,2 mol AgNO3, 0,1 mol Cu(NO3)2, khuy u n khi cc phn ng xy ra
hon ton thu c 19,44g cht rn. Gi tr m l
A. 5,04
B. 3,36
C. 5,6
D. 8,4
Cu 17: Cho 10,8 gam hn hp A gm Mg v Fe tc dng vi 500 ml dung dch AgNO 3 0,8M, sau khi phn ng xy ra
hon ton thu c dung dch B v 46 gam cht rn D . Thnh phn % khi lng ca mt kim loi trong hn hp A l
A. 51,85%
B. 22,32%
C. 77,78%
D. 25,93%
Cu 18. Cho 8g hn hp X gm Al, Zn, Mg tc dng vi dd HNO3 long d, thu c dd Y v 2,24 lt hn hp kh Z gm
NO v N2O ( ktc). T khi ca hn hp kh Z so vi H2 l 16,4. Khi lng mui thu c v s mol axit HNO3 phn l
A. 25,9 v 0,25
B. 17,3 v 0,50
C. 32,8 v 0,52
D. 14,2 v 0,45
Cu 19. Nung nng 18,6g hn hp bt cc kim loi Zn v Fe vi bt S mt thi gian thu c hn hp rn X. Hon tan
hon ton hn hp rn X vo dd H2SO4 long, d thy c 6,72 lt hn hp kh (ktc) bay ra. Thnh phn % khi lng mi
kim loi Zn v Fe l
A. 52,1% v 47,9%
B. 25,55% v 74,45%
C. 42,8% v 51,8%
D. 68,89% v 30,11%
Cu 20. Ho tan hon ton hn hp X gm Fe v Mg bng 1 lng va dd H2SO4 10%, thu c dd Y. Nng ca
FeSO4 trong dd Y l 5%. Nng % ca MgSO4 trong dd Y l bao nhiu?
A. 4,2%
B. 5,7%
C. 7,9%
D. 8,2%
18
Cu 21. Cho m gam hn hp X gm Fe2O3, CuO, ZnO, MgO, Al2O3) tc dng vi H2 un nng, sau mt thi gian thu c
1,08g H2O v cht rn Y. Cho cht rn Y vo dung dch HNO3 long, d thu c V lt kh NO (ktc, sn phm kh duy
nht). Gi tr V l
A. 0,448 lt
B. 0,672 lt
C. 0,896 lt
D. 1,12 lt
Cu 22. in phn 1 dung dch cha 0,1 mol HCl, 0,2 mol FeCl3, 0,1 mol CuCl2 vi hai in cc tr n khi catot thu
c 3,2g Cu th anot thu c th tch kh (ktc) l
A. 1,12 lt
B. 2,24 lt
C. 3,36 lt
D. 4,48 lt
Cu 23. Cho phng trnh ho hc ca phn ng tng hp NH3 : N2(k) + 3H2 (k)
2NH3 (k) H < 0
Khi t n trng thi cn bng t khi ca hn hp kh trong bnh so vi H2 l d1. un nng bnh sau mt thi gian
phn ng t n trng thi cn bng mi, t khi ca hn hp kh trong bnh so v H2 l d2. So snh d1v d2 thu c:
A. d1 < d2
B. d1 > d2
C. d1= d2
D. d1 d2
Cu 24. Cho m gam Fe tc dng vi dd H2SO4 thu c kh A v 11,04 g mui. Cho bit s mol Fe phn ng bng 37,5% s
mol H2SO4 phn ng. Gi tr m l
A. 33,6g
B. 3,36g
C. 4,24g
D. 3,2256g
Cu 25. Ho tan 4,5g tinh th MSO4.5H2O vo nc thu c dd A. in phn dung dch A vi vi in cc tr. Nu thi
gian l t giy th thu c kim loi ti catot v 0,007 mol kh t anot. Nu thi gian in phn l 2t giy th thu c 0,024
mol kh. Xc nh M v t, cho I = 1,93A
A. Cu v 965
B. Zn v 1400
C. Zn v 965
D. Cu v 1400
Cu 26. Trn 0,54g bt Al vi 50g hn hp Fe2O3, CuO, ZnO, MgO, ri tin hnh phn ng nhit nhm mt thi gian
(khng c khng kh), thu c hn hp rn X . Ho tan X trong dd HNO3 d thu c 0,896 lt hn hp kh Y gm NO2
v NO (ktc). T khi hi ca hn hp Y so vi H2 l
Cu 1: Trn 10,8 gam bt nhm vi 34,8g bt Fe3O4 ri tin hnh phn ng nhit nhm thu c hn hp A. ha
tan ht A bng HCl thu c 10,752 lt H2(ktc). Hiu sut phn ng nhit nhm v th tch dung dch HCl 2M
cn dng l?
A. 80% v 1,08lt
B. 20% v 10,8lt
C. 60% v 10,8lt
D. 40% v 1,08lt
Cu 2: nung hn hp A gm Al, Fe2O3 c hn hp B (hiu sut 100%). Ha tan ht B bng HCl d c 2,24
lt kh (ktc), cng lng B ny nu cho phn ng vi dung dch NaOH d thy cn 8,8g rn C. Khi lng cc
cht trong A l?
A. mAl=2,7g, mFe2O3=1,12g
B. mAl=5,4g, mFe2O3=1,12g
C. mAl=2,7g, mFe2O3=11,2g
D. mAl=5,4g, mFe2O3=11,2g
Cu 3: Hn hp A gm 0,56g Fe v 16g Fe2O3 m (mol) Al ri nung nhit cao khng c khng kh c hn
hp D. Nu cho D tan trong H2SO4 long c v(lt) kh nhng nu cho D tc dng vi NaOH d th thu c
0,25V lt kh. Ga tr ca m l?
A. 0,1233
B. 0,2466
C. 0,12
D. 0,3699
Cu 4: C 26,8g hn hp bt nhm v Fe2O3. Tin hnh nhit nhm cho ti hon ton ri ha tan ht hn hp
sau phn ng bng dung dch HCl c 11,2 lt H2(ktc). Khi lng cc cht trong hn hp ban u l?
A. mAl=10,8g;m =1,6g
B. mAl=1,08g;m =16g
C. mAl=1,08g;m =16g
D. mAl=10,8g;m =16g
Cu 5: Hn hp X gm Al v Fe2O3. Ly 85,6gam X em nung nng thc hin phn ng nhit nhm, sau mt
thi gian thu c m gam cht rn Y. Chia Y lm 2 phn bng nhau:
19
- Phn 1: Ha tan trong dung dch NaOH d thy thot ra 3,36lt kh (ktc) v cn li m1 gam cht khng tan.
- Phn 2: Ha tan ht trong dung dch HCl thy thoat ra 10,08 lt kh (ktc). Phn trm khi lng Fe trong Y l?
A. 18%
B. 39,25%
C. 19,6%
D. 40%
Cu 6: Hn hp X gm Al v Fe2O3. Ly 85,6gam X em nung nng thc hin phn ng nhit nhm, sau mt
thi gian thu c m gam cht rn Y. Chia Y lm 2 phn bng nhau:
- Phn 1: Ha tan trong dung dch NaOH d thy thot ra 3,36lt kh (ktc) v cn li m1 gam cht khng tan.
- Phn 2: Ha tan ht trong dung dch HCl thy thoat ra 10,08 lt kh (ktc). Thnh phn cht rn Y gm cc cht
l?
A. Al, Fe2O3, Fe, Al2O3
B. Al, Fe, Al2O3
C. Fe, Al2O3
D. C A, C ng
Cu 7: Cho 17,04 gam hn hp rn A gm Ca, MgO, Na2O tc dng ht vi 720 ml dung dch HCl 1M (va ) thu
c dung dch A. Khi lng mui NaCl c trong dung dich A l
A. 8,775g.
B. 4,68g.
C. 14,04g.
D. 15,21g.
Cu 8: Cho cc cht Fe, FeO, Fe2O3, Fe3O4, FeCO3, Fe(NO3)2, FeI2, FeS, FeS2, Fe(OH)2. C bao nhiu cht khi tc dng
vi dung dch HNO3 c, nng to sn phm kh (gi s ch c NO2) c s mol bng s mol ca cht ?
A. 5
B. 6
C. 7
D. 8
Cu 9: Cho m gam bt st vo dung dch hn hp cha 0,16 mol Cu(NO3)2 v 0,4 mol HCl, lc u cho phn ng xy
ra hon ton. Sau phn ng thu c hn hp kim loi c khi lng bng 0,7m gam v V lt kh (ktc). Gi tr ca V
v m ln lt l
A. 4,48 lt v 21,55 gam
B. 2,24 lt v 33,07 gam
C. 4,48 lt v 33,07 gam D. 1,12 lt v 18,20 gam
Cu 10: Ha tan ht 26,43 gam hn hp bt gm Mg, Al, Al2O3 v MgO bng 795 ml dung dch hn hp gm HCl 0,5M v
H2SO4 0,75M (va ). Sau phn ng thu c dung dch X v 4,368 lt kh H2 ( ktc). C cn dung dch X thu c khi
lng mui khan l
A. 86,58 gam.
B. 95,92 gam.
C. 100,52 gam.
D. 88,18 gam.
Cu 11: Cho cc cht: AgNO3, Cu(NO3)2, MgCO3, Ba(HCO3)2, NH4HCO3, NH4NO3 v Fe(NO3)2. Nu nung cc cht trn n
khi lng khng i trong cc bnh kn khng c khng kh, ri cho nc vo cc bnh, s bnh c th to li cht ban u sau
cc th nghim l
A. 5.
B. 4.
C. 6.
D. 3.
Cu 12: Ho tan 16,8 gam hn hp 2 mui cacbonat v sunfit ca cng mt kim loi nhm IA trong bng tun hon
vo dung dch HCl d, thu c 3,36 lit hn hp kh (ktc). Kim loi l
A. Rb
B. Li
C. Na
D. K
Cu 13: Cho dung dch NaOH 20% tc dng va vi dung dch FeCl2 10%. un nng trong khng kh cc phn
ng xy ra hon ton. Nng % ca mui to thnh trong dung dch l
A. 7,49%
B. 8,45%
C. 6,32%
D. 3,17%
20
Cu 14: Cho m gam hn hp X gm Al4C3 v CaC2 vo nc d thu c dung dch A; a gam kt ta B v hn hp kh
C. Lc b kt ta. t chy hon ton kh C ri dn sn phm chy vo dung dch A thu c thm a gam kt ta na.
Hi trong hn hp X, Al4C3 v CaC2 c trn vi t l mol th no
A. 1: 1
B. 1:2
C. 1:3
D. 2:1
Cu 15: Dung dch A cha a mol CuSO4 v b mol FeSO4. Thm c mol Mg vo dung dch A, sau phn ng hon ton
thu c dung dch c 2 mui. Quan h gia a, b v c l
A. a c a + b
B. a < c < a + b
C. a < c a + b
D. a c < a + b
Cu 16: Hn hp X gm Zn, Fe, Cu. Cho 18,5 gam hn hp X tc dng vi dung dch HCl d thu c 4,48 lit
H2(ktc). Mt khc cho 0,15 mol hn hp X phn ng va vi 3,92 lt kh Cl 2 (ktc). S mol Fe c trong 18,5 gam
hn hp X l
A. 0,12 mol
B. 0,1 mol
C. 0,08 mol
D. 0,15 mol
Cu 17: Chia 156,8 gam hn hp L gm FeO, Fe3O4, Fe2O3 thnh hai phn bng nhau. Cho phn th nht tc dng
ht vi dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va vi dung dch M l hn hp
HCl, H2SO4 long thu c 167,9 gam mui khan. S mol ca HCl trong dung dch M l
A. 1,75 mol
B. 1,50 mol
C. 1,80 mol
D. 1,00 mol
Cu 18: Cho a gam Na vo 160 ml dung dch gm Fe2(SO4)3 0,125M v Al2(SO4)3 0,25M. Tch kt ta ri nung
n khi lng khng i th thu c 5,24 gam cht rn. Gi tr a no sau y l ph hp?
A. 9,43.
B. 11,5.
C. 9,2.
D. 10,35.
Cu 19: Cho V lt hn hp kh A gm clo v oxi tc dng va ht vi hn hp B gm 0,2 mol Al v 0,1 mol Mg

th thu c 25,2 gam hn hp mui clorua v oxit ca 2 kim loi. S mol ca Cl2 c trong V lt hn hp kh A l
A. 0,15.
B. 0,3.
C. 0,2.
D. 0,25.
Cu 20: Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v
80% th tch N2) n khi phn ng xy ra hon ton, thu c cht rn v hn hp kh Y c thnh phn th tch: N 2
= 84,77%; SO2 = 10,6% cn li l O2. Thnh phn % theo khi lng ca FeS trong X l
A. 68,75%
B. 59,46%
C. 26,83%
D. 42,3%
Cu 21: Nung m gam hn hp X gm KClO3 v KMnO4 thu c cht rn Y v O2. Bit KClO3 phn hy hon
ton, cn KMnO4 ch b phn hy mt phn. Trong Y c 0,894 gam KCl chim 8,132% theo khi lng. Trn
lng O2 trn vi khng kh theo t l th tch VO2 : VKK =1:3 trong mt bnh kn ta thu c hn hp kh Z. Cho
vo bnh 0,528 gam cacbon ri t chy ht cacbon, phn ng hon ton, thu c hn hp kh T gm 3 kh O 2,
N2, CO2, trong CO2 chim 22,92% th tch. Gi tr m (gam) l
A. 12,59
B. 12,53
C. 12,70
D. 12,91
Cu 22: Dng mt lng dung dch H2SO4 nng 20%, un nng ha tan va a mol CuO. Sau phn ng
lm ngui dung dch n 1000C th khi lng tinh th CuSO4.5H2O tch ra khi dung dch l 30,7 gam. Bit
rng tan ca dung dch CuSO4 1000C l 17,4 gam. Gi tr ca a l
21
A. 0,1.
B. 0,15.
C. 0,2.
D. 0,25.
Cu 23: Cho 6,0 gam Mg tc dng ht vi dung dch HCl 18,25% (va ). Sau phn ng thu c dung dch
mui A v hiro that ra. Bit phn ng xy ra hon ton. Vy nng phn trm ca dung dch mui s l:
A. 22,41%
B. 22,51%
C. 42,79%
D. 42,41%
Cu 24: Cho m gam Ba vo 600ml dung dch cha KOH 0,1M v NaOH 0,1M thu c dung dch X. Cho
t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M c kt ta Y. thu c kt ta Y ln nht th
gi tr m ti thiu v khi lng kt ta Y ln lt l:
A. 8,22 gam v 13,98 gam.
B. 0,00 gam v 3,12 gam.
C. 8,22 gam v 19,38 gam.
D. 2,74 gam v 4,66 gam.
Cu 25: Cho hn hp cha x mol Zn, y mol Fe vo dung dch cha z mol CuSO4, sau khi kt thc phn
ng ngi ta thu c cht rn gm hai kim loi. Mi lin h gia x, y v z l:
A. x z < x + y.
B. x z.
C. x < z < y.
D. x + y = z.
Cu 26: Ha tan hon ton 8,94 gam hn hp gm Na, K v Ba vo nc, thu c dung dch X v 2,688
lt kh H2 (ktc). Dung dch Y gm HCl v H2SO4 c t l mol tng ng l 4 : 1. Trung ho dung dch X
bi dung dch Y, tng khi lng cc mui c to ra l:
A. 13,70 gam.
B. 12,78 gam.
C. 14,62 gam.
D. 18,46 gam.
Cu 27: Cho hn hp bt gm 0,48g Mg v 1,68 gam Fe vo dung dch CuCl2 ri khuy u n phn
ng hon ton thu c 3,12 gam cht rn khng tan X. S mol CuCl2 tham gia phn ng l:
A. 0,06mol.
B. 0,04mol.
C. 0,05mol.
D. 0,03mol.
Cu 28: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO

v Fe3O4 nung nng. Sau khi cc phn ng xy ra hon ton, khi lng hn hp rn gim 0,32 gam. Gi
tr ca V l:
A. 0,560.
B. 0,112.
C. 0,448.
D. 0,224.
Cu 29: Sc kh H2S cho ti d vo 100 ml dung dch hn hp gm Fe2(SO4)3 0,1M v CuSO4 0,2M; phn
ng xong thu c a gam kt ta. Gi tr ca a l:
A. 3,68 gam.
B. 4 gam.
C. 2,24 gam.
D. 1,92 gam.
Cu 30: Ha tan hon ton m gam hn hp X gm Na2O v Al2O3 vo nc thu c 200ml dung dch A
ch cha mt cht tan duy nht c nng 0,5M. Sc kh CO2 d vo dung dch A c a gam kt ta. Gi
tr ca m v a ln lt l:
A. 16,4 gam v 7,8 gam. B. 8,2 gam v 7,8 gam. C. 16,4 gam v 15,6 gam. D. 8,2 gam v 6,8 gam.
Cu 31: Cho 84,6 gam hn hp hai mui CaCl2 v BaCl2 tc dng ht vi 1 lt dung dch cha Na2CO3
0,25M v (NH4)2CO3 0,75M sinh ra 79,1 gam kt ta. Thm 600ml Ba(OH)2 1M vo dung dch sau phn
ng thu c m gam kt ta v V lt kh ktc . Gi tr ca m v V l:
A. 98,5 gam v 2,688 lt.
B. 98,5 gam v 26,88 lt.
C. 9,85 gam v 26,88 lt.
D. 9,85 gam v 2,688 lt.
Cu 32: xc nh hm lng Fe3O4 trong mt mu qung manhetit, ngi ta tin hnh nh sau: Ha tan
10 gam mu qung vo dung dch H2SO4 d c 500 ml dung dch A. Chun 25 ml dung dch A bng
dung dch KMnO4 0,01M th thy ht 12,4 ml dung dch chun. Hm lng Fe3O4 trong mu qung l:
A. 28,76%.
B. 86,30%.
C. 57,536%.
D. 18,85%.
CHUYN 06: BI TP V PHN NG OXI HA KH

22
Cu 1: Cho 6,72 gam Fe vo dung dch cha 0,3 mol H2SO4 c, nng (gi thit SO2 l sn phm kh
duy nht). Sau khi phn ng xy ra hon ton, thu c (cho Fe = 56)
A. 0,12 mol FeSO4.
B. 0,03 mol Fe2(SO4)3 v 0,06 mol FeSO4.
C. 0,02 mol Fe2(SO4)3 v 0,08 mol FeSO4. D. 0,05 mol Fe2(SO4)3 v 0,02 mol Fe d.
Cu 2: Cho 0,015 mol Fe vo dung dch cha 0,04 mol HNO3 n khi phn ng xy ra hon ton, thu
c kh NO (sn phm kh duy nht) v dung dch X. C cn dung dch X th thu c m gam mui khan.
Gi tr ca m l
A. 1,92.
B. 3,20.
C. 2,7
D. 3,84.
Cu 3: Cho 6,72 gam Fe vo 400 ml dung dch HNO3 1M, n khi phn ng xy ra hon ton, thu c
kh NO (sn phm kh duy nht) v dung dch X. Dung dch X c th ho tan ti a m gam Cu. Gi tr ca
m l A. 1,92.
B. 3,20.
C. 0,64.
D. 3,84.
1. Ha tan hon ton 12g hn hp Fe, Cu (t l mol 1:1) bng axit HNO3 thu c V lit hn hp kh X
(kc) gm NO v NO2 v dd Y (ch cha 2 mui v axit d). T khi ca X i vi H2 bng 19. Gi tr ca V
l:
A. 4,48
B. 5,6
C. 2,24
D. 3,36
2. Hn hp X gm Cu v Fe c t l khi lng tng ng l 7:3. Ly m gam X phn ng hon ton vi
dd cha 0,7 mol HNO3. Sau phn ng cn li 0,75m gam cht rn v c 0,25 mol kh Y gm NO v NO2. Gi
tr ca m l:
A. 40,5
B. 50,4
C. 50,2
D. 50
3. Hn hp gm 0,15 mol Cu v 0,15 mol Fe phn ng va vi dd HNO 3 thu c 0,2 mol kh NO
(kc, sn phm kh duy nht). Tng khi lng cc mui trong dd sau phn ng l
A. 64,5g
B. 40,8g
C. 51,6
D. 55,2
4. Ha tan 5,6g hn hp Cu v Fe vo dd HNO3 1M, sau khi phn ng xy ra hon ton c 3,92g cht
rn khng tan v kh NO (sn phm kh duy nht). Bit trong hn hp ban u Cu chim 60% khi lng.
Th tch dd HNO3 dng l
A. 0,07 lit
B. 0,08 lit
C. 0,12 lit
D. 0,16 lit
5. Ha tan 14,8 g hn hp Fe v Cu vo lng d dd hn hp HNO 3 v H2SO4 c nng. Sau phn ng
thu c 10,08 lit NO2 v 2,24 lit SO2 (u kc). Khi lng Fe trong hn hp ban u l
A. 5,6g
B. 8,4g
C. 18g
D. 18,2g
2. Dng hn hp st v cc oxit phn ng vi cht oxi ha mnh (Quy i nguyn t)
1- kh hon ton 3,04 gam hn hp X gm Fe, FeO, Fe 2O3, Fe3O4 th cn 0,05 mol H2. Mt khc ha tan
hon ton 3,04 gam hn hp X trn bng dung dch H2SO4 c nng d th thu c V ml kh SO2 (sn phm
kh duy nht ktc). Gi tr ca V l
A. 224.
B. 448.
C. 336.
D. 112.
2. Ly 11,36 gam hn hp X gm Fe, FeO, Fe2O3, Fe3O4 em ho trong HNO3 long d nhn c 1,344 lt
NO v dung dch X. C cn dung dch X c m gam mui khan. Gi tr ca m l:
A. 49,09 g
B. 34,36 g
C. 35,50 g
D. 38,72 g
3. Ly m gam hn hp (FeO, Fe2O3, Fe3O4) em ho vo HNO3 m c d th nhn c 4,48 lt NO2 (ktc)
v dung dch X. C cn dung dch X c 145,2 gam mui khan. Vy m c gi tr l:
A. 77,7 g
B. 35,7 g
C. 46,4 g
D.15,8 g
4- Cho hn hp X gm Fe, FeO, Fe3O4 c khi lng 4,04 gam phn ng vi dung dch HNO3 d thu c 336 ml kh
NO(ktc, sn phm kh duy nht). S mol HNO3 tham gia phn ng l:
A. 0,06 (mol).
B. 0,036 (mol).
C. 0,125(mol).
D. 0,18(mol).
23
5. Trn 0,5g bt Al vi hn hp bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm trong iu kin khng
c khng kh mt thi gian c hn hp rn X. Ha tan X trong dd HNO 3 c nng d th th tch kh NO2
(sn phm kh duy nht) thu c kc l
A. 0,672lit
B. 0,896lit
C. 1,12lit
D. 1,344
6: Ha tan hon ton 20,88 gam mt oxit st bng dung dch H2SO4 c, nng thu c dung dch X v
3,248 lt kh SO2 (sn phm kh duy nht, ktc). C cn dung dch X, thu c m gam mui sunfat
khan. Gi tr ca m l
A. 52,2.
B. 54,0.
C. 58,0.
D.
48,4.
Pht trin bi ton:
Trng hp 1: Cho nhiu sn phm sn phm kh nh NO2, NO ta c vn t h bnh thng tuy nhin cht
nhn e by gi l HNO3 th cho 2 sn phm.
Trng hp 2: Nu ra yu cu tnh th tch hoc khi lng ca HNO3 th ta tnh s mol da vo bo ton
nguyn t N khi ta s c:
i
Kh
nHNO3 = nmu
NO3 + n NO3 =3 n Fe + n NO( n NO2 )
3. Dng t chy St trong khng kh ri cho sn phm phn ng vi cht oxi ha (Bo ton e)
Cu 1(HA -10): Nung 2,23 gam hn hp X gm cc kim loi Fe, Al, Zn, Mg trong oxi, sau mt thi gian
thu c 2,71 gam hn hp Y. Ha tan hon ton Y vo dung dch HNO3 (d), thu c 0,672 lt kh NO (sn
phm kh duy nht, ktc). S mol HNO3 phn ng l
A. 0,12.
B. 0,14.
C. 0,16.
D. 0,18.
+
NO3 + 3e +
4H NO + 2H2O
0,12
0,03mol
+
2
2H
+ O H2 O
0, 06 mol
0, 03mol
S mol HNO3 phn ng = 0,18 mol

1: Nung nng 12,6 gam Fe ngoi khng kh sau mt thi gian thu c m gam hn hp X gm Fe, FeO,
Fe2O3 v Fe3O4 . Hn hp ny phn ng ht vi dung dch H2SO4 c nng (d), thu c 4,2 lt kh SO2 (sn
phm kh duy nht, ktc). Tnh m?
S: 15 gam.
2 Nung nng m gam bt st ngoi khng kh, sau phn ng thu c 20 gam hn hp X gm Fe, FeO, Fe 2O3
v Fe3O4 . Ha tan ht X trong dung dch HNO3 long thu c 5,6 lt hn hp kh Y gm NO v NO2 c t
khi so vi H2 l 19. Tnh m v th tch HNO3 1M dng?
3. Ly m gam st em t trong oxi khng kh ta c hn hp rn X (gm 4 cht rn) cn nng 12 gam, hn
hp rn X em ho trong HNO3 d nhn c 2,24 lt kh NO (ktc). Vy m c gi tr l:
A. 8,96 g
B. 9,82 g
C. 10,08 g
D. 11,20 g
4. Ly p gam Fe em t trong oxi ta c 7,52 gam hn hp X gm 3 oxit. Hn hp X em ho tan trong
H2SO4 m c d c 0,672 lt SO2 (ktc). Vy p c gi tr l:
A. 4,8 g
B. 5,6 g
C. 7,2 g
D. 8,6 g
5. m gam phoi Fe ngoi khng kh sau 1 thi gian thu c 12g cht rn X gm Fe, FeO, Fe 3O4, Fe2O3.
Ha tan ht X trong dd H2SO4 c nng thu c 2,24 lit kh SO2 (kc). Gi tr ca m l
A. 9,52
B. 9,62
C. 9,42
D. 9,72
6. Cho 11,2g Fe tc dng vi oxi c m gam hn hp X gm cc oxit. Ha tan ht X vo dd HNO3 d thu
c 896 ml NO (kc, sn phm kh duy nht). Gi tr ca m l
24
A. 29,6
B. 47,8
C. 15,04
D. 25,84
7. m gam bt Fe ngoi khng kh mt thi gian thu c 11,8g hn hp gm Fe v cc oxit st. Ha tan
hon ton hn hp bng dd HNO3 long thu c 2,24 lit kh NO duy nht (ktc). Gi tr ca m l
A. 9,94
B. 10,04
C. 15,12
D. 20,16
4. Dng kh khng hon ton Fe2O3 sau cho sn phm phn ng vi cht oxi ha mnh l HNO3 hoc
H2SO4 c nng (Bo ton e)
1. Cho kh CO i qua m gam oxit Fe2O3 t nng, ta c 13,92 gam hn hp Y (gm 4 cht rn). Hn hp X
ho trong HNO3 c d c 5,824 lt NO2 (ktc), Vy m c gi tr l
A. 15,2 g
B. 16,0 g
C. 16,8 g
D. 17,4 g
2. Cho kh CO i qua ng cha 10 gam Fe2O3 t nng, thu c m gam hn hp X (gm 3 oxit). Hn
hp X em ho trong HNO3 c nng d nhn c 8,96 lt NO2. Vy m c gi tr l:
A. 8,4 g
B. 7,2 g
C. 6,8 g
D. 5,6 g
3. Cho kh CO i qua ng cha m gam oxit Fe2O3 t nng thu c 6,69 gam hn hp X (gm 4 cht
rn), hn hp X ho vo HNO3 d c 2,24 lt kh Y gm NO v NO2, t khi ca Y i vi H2 bng 21,8.
Vy m gam oxit Fe2O3 l
A. 10,2 g
B. 9,6 g
C. 8,0 g
D. 7,73 g
4. Ly 8 gam oxit Fe2O3 t nng cho CO i qua, ta nhn c m gam hn hp X gm 3 oxit, hn hp X
em ho vo H2SO4 c nng d, nhn c 0,672 lt SO2 (ktc). Vy m gam X c gi tr l:
A. 8,9 g
B. 7,24 g
C. 7,52 g
D. 8,16 g
5. Cho kh CO i qua Fe2O3 t nng, ta c m gam hn hp rn X gm 4 cht. Hn hp rn X em ho
vo HNO3 m c nng d, nhn c 2,912 lt NO2 (ktc) v 24,2 gam Fe(NO3)3 khan. Vy m c gi tr l
A. 8,36 gam
B. 5,68 gam
C. 7,24 gam
D. 6,96 gam
6. Cho 11,36g hn hp Fe, FeO, Fe3O4, Fe2O3 phn ng ht vi dd HNO3 d thu c 1,344 lit kh NO
(kc, sn phm kh duy nht) v dd X. C cn dd X thu c s gam mui khan l
A. 38,72
B. 35,5
C. 49,09
D. 34,36
7. Cho 1 lung kh CO qua m gam bt Fe2O3 nung nng thu c 14g hn hp X gm 4 cht rn. Cho hn
hp X tan hon ton trong dd HNO3 thu c 2,24 lit kh NO (ktc). Gi tr ca m l
A. 16,4
B. 14,6
C. 8,2
D. 20,5
8. Kh Fe2O3 bng CO nhit cao thu c hn hp X gm 4 cht rn. Chia X thnh 2 phn bng
nhau. P1 tc dng vi dd HNO3 d thu c 0,02 mol NO v 0,03 mol N 2O. P2 tan hon ton trong dd H2SO4
c nng thu c V lit kh SO2 (ktc). Gi tr ca V l
A. 2,24
B. 3,36
C. 4,48
D. 6,72
AI HC CC NM
Cu 1: thu ly Ag tinh khit t hn hp X (gm a mol Al2O3, b mol CuO, c mol Ag2O), ngi ta
ho tan X bi dung dch cha (6a + 2b + 2c) mol HNO3 c dung dch Y, sau thm (gi thit
hiu sut cc phn ng u l 100%)
A. c mol bt Al vo Y.
B. c mol bt Cu vo Y.
C. 2c mol bt Al vo Y.
D. 2c mol bt Cu vo Y.
Cu 2: Cho m gam hn hp X gm FeO, Fe2O3, Fe3O4 vo mt lng va dung dch HCl 2M, thu c
dung dch Y c t l s mol Fe2+ v Fe3+ l 1 : 2. Chia Y thnh hai phn bng nhau. C cn phn mt thu c
m1 gam mui khan. Sc kh clo (d) vo phn hai, c cn dung dch sau phn ng thu c m2 gam mui
khan. Bit m2 m1 = 0,71. Th tch dung dch HCl dng l
A. 240 ml.
B. 80 ml.
C. 320 ml.
D. 160 ml.
25
Cu 3: Nung nng 16,8 gam hn hp gm Au, Ag, Cu, Fe, Zn vi mt lng d kh O2, n khi cc phn ng
xy ra hon ton, thu c 23,2 gam cht rn X. Th tch dung dch HCl 2M va phn ng vi cht rn
X l :
A. 400 ml.
B. 200 ml.
C. 800 ml.
D. 600 ml.
Cu 4: Hn hp X gm CuO va Fe2O3. Hoa tan hoan toan 44 gam X bng dung dich HCl (d), sau phan ng
thu c dung dich cha 85,25 gam mui. Mt khac, nu kh hoan toan 22 gam X bng CO (d), cho hn
hp khi thu c sau phan ng li t t qua dung dich Ba(OH)2 (d) thi thu c m gam kt tua. Gia tri cua
m la
A. 76,755
B. 73,875
C. 147,750
D. 78,875
Cu 5: Cho m gam hn hp bt X gm ba kim loi Zn, Cr, Sn c s mol bng nhau tc dng ht vi lng d
dung dch HCl long, nng thu c dung dch Y v kh H2. C cn dung dch Y thu c 8,98 gam mui
khan. Nu cho m gam hn hp X tc dng hon ton vi O2 (d) to hn hp 3 oxit th th tch kh O2
(ktc) phn ng l
A. 2,016 lt.
B. 0,672 lt.
C. 1,344 lt.
D. 1,008 lt.
Cu 6: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml axit H2SO4 0,1M (va
). Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l (cho H = 1,
O = 16, Mg = 24, S = 32, Fe = 56, Zn = 65)
A. 6,81 gam.
B. 4,81 gam.
C. 3,81 gam.
D. 5,81 gam.
Cu 7: ho tan hon ton 2,32 gam hn hp gm FeO, Fe3O4 v Fe2O3 (trong s mol FeO
bng s mol Fe2O3), cn dng va V lt dung dch HCl 1M. Gi tr ca V l
A. 0,16.
B. 0,18.
C. 0,08.
D. 0,23.
Cu 8: Cho 2,13 gam hn hp X gm ba kim loi Mg, Cu v Al dng bt tc dng hon ton vi
oxi thu c hn hp Y gm cc oxit c khi lng 3,33 gam. Th tch dung dch HCl 2M va
phn ng ht vi Y l
A. 90 ml.
B. 57 ml.
C. 75 ml.
D. 50 ml.
Cu 9: Hn hp X gm CuO va Fe2O3. Hoa tan hoan toan 44 gam X bng dung dich HCl (d), sau phan ng
thu c dung dich cha 85,25 gam mui. Mt khac, nu kh hoan toan 22 gam X bng CO (d), cho hn
hp khi thu c sau phan ng li t t qua dung dich Ba(OH)2 (d) thi thu c m gam kt tua. Gia tri cua
m la
A. 76,755
B. 73,875
C. 147,750
D. 78,875
Chuyn 07: SO2; CO2 tc dng vi dd kim

Cu 1. Hp th hon ton 2,24 lt CO2 (ktc) vo dung dch nc vi trong c cha 0,075 mol Ca(OH)2. Sn phm thu
c sau phn ng gm:
A. Ch c CaCO3 B. Ch c Ca(HCO3)2
C. CaCO3 v Ca(HCO3)2 D. Ca(HCO3)2 v CO2
Cu 2. Hp thu ht CO2 vo dung dch NaOH c dung dch A. Bit rng:Cho t t dung dch HCl vo dung dch A th
phi mt 50ml dd HCl 1M mi thy bt u c kh thot ra. Mt khc cho dd Ba(OH)2 d vo dung dch A c 7,88 gam
kt ta. Dung dch A cha?
A. Na2CO3
B. NaHCO3
C. NaOH v Na2CO3
D. NaHCO3, Na2CO3
Cu 3. Dn 5,6 lt CO2 (ktc) vo bnh cha 200ml dung dch NaOH nng a M; dung dch thu c c kh nng tc
dng ti a 100 ml dung dch KOH 1M. Gi tr ca a l?
26
A. 0,75
B. 1,5
C. 2
D. 2,5
Cu 4. (i hc khi A nm 2007). Hp th hon ton 2,688 lt CO2 (ktc) vo 2,5 lt dung dch Ba(OH)2 nng a mol/l,
thu c 15,76 gam kt ta. Ga tr ca a l?
A. 0,032
B. 0,048
C. 0,06
D. 0,04
Cu 5. Hp th ton b 0,896 lt CO2 vo 3 lt dd Ca(OH)2 0,01M c?
A. 1g kt ta
B. 2g kt ta
C. 3g kt ta
D. 4g kt ta
Cu 6. Hp th 0,224lt CO2 (ktc) vo 2 lt Ca(OH)2 0,01M ta thu c m gam kt ta. Ga tr ca m l?
A. 1g
B. 1,5g
C. 2g
D. 2,5g
Cu 7. (i hc khi B-2007). Nung 13,4 gam 2 mui cacbonat ca 2 kim loi ha tr II, c 6,8 gam rn v kh X. kh X
sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan sau phn ng l?
A. 5,8gam
B. 6,5gam
C. 4,2gam
D. 6,3g
Cu 8. Thi CO2 vo dd cha 0,02 mol Ba(OH)2. Gi tr khi lng kt ta bin thin trong khong no khi CO2 bin thin
trong khong t 0,005 mol n 0,024 mol?
A. 0 gam n 3,94g
B. 0,985 gam n 3,94g
C. 0 gam n 0,985g
D. 0,985g n 3,251g
Cu 9. Sc 2,24 lt (ktc) CO2 vo 100ml hn hp dung dch gm KOH 1M v Ba(OH)2 0,75M. Sau khi kh b hp th
hon ton thy to m g kt ta. Tnh m
A. 19,7g
B. 14,775g
C. 23,64g
D. 16,745g
Cu 10. Sc 4,48 lt (ktc) CO2 vo 100ml hn hp dung dch gm KOH 1M v Ba(OH)2 0,75M. Sau khi kh b hp th
hon ton thy to m g kt ta. Tnh m
A. 23,64g
B. 14,775g
C. 9,85g
D. 16,745g
Cu 11. Hp th 3,36 lt SO2 (ktc) vo 0,5 lt hn hp gm NaOH 0,2M v KOH 0,2M. C cn dung dch sau phn ng
thu c khi lng mui khan l
A. 9,5gam
B. 13,5g
C. 12,6g
D. 18,3 g
Cu 12. Cho 6,72 lit kh CO2 (ktc) vo 380 ml dd NaOH 1M, thu c dd A. Cho 100 ml dd Ba(OH)2 1M vo dd A c
m gam kt ta. Ga tr m bng:
A. 19,7g
B. 15,76g C. 59,1g
D.55,16g
Cu 13. Hp th ht 0,672 lt CO2 (ktc) vo bnh cha 2 lt dung dch Ca(OH)2 0,01M. Thm tip 0,4gam NaOH vo bnh
ny. Khi lng kt ta thu c sau phn ng l?
A. 1,5g
B. 2g C. 2,5g
D. 3g
Cu 14. Cho 0,012 mol CO2 hp th bi 200 ml NaOH 0,1M v Ca(OH)2 0,01M.Khi lng mui c l?
A. 1,26gam B. 2gam
C. 3,06gam D. 4,96 g
Cu 15. Hp th 4,48 lt CO2 (ktc) vo 0,5 lt NaOH 0,4M v KOH 0,2M. Sau phn ng c dd X. Ly 1/2 X tc dng
vi Ba(OH)2 d, to m gam kt ta. m v tng khi lng mui khan sau c cn X ln lt l
A. 19,7 g v 20,6 g B. 19,7gv 13,6g
C. 39,4g v 20,6g
D. 1,97g v 2,06g
Cu 16. Hp th ton b 0,3 mol CO2 vo dung dch cha 0,25 mol Ca(OH)2. khi lng dung dch sau phn ng tng hay
gim bao nhiu gam?
A. Tng 13,2gam
B. Tng 20gam
C. Gim 16,8gam
D. Gam 6,8g
Cu 17. Cho 0,14 mol CO2 hp th ht vo dung dch cha 0,11 mol Ca(OH)2. Ta nhn thy khi lng CaCO3 to ra ln
hn khi lng CO2 dng nn khi lng dung dch cn li gim bao nhiu?
A. 1,84g
B. 3,68 gam C. 2,44 gam D. 0,92 gam
Cu 18. Cho 0,14 mol CO2 hp th ht vo dung dch cha 0,08mol Ca(OH)2. Ta nhn thy khi lng CaCO3 to ra nh
hn khi lng CO2 dng nn khi lng dung dch cn li tng l bao nhiu?
A. 2,08 gam B. 1,04 gam C. 4,16g
D. 6,48 gam
Cu 19. V lt kh CO2 (ktc) vo 1,5 lt Ba(OH)2 0,1M c 19,7 gam kt ta. Ga tr ln nht ca V l?
A. 1,12
B. 2,24
C. 4,48
D. 6,72
Cu 20. Dn 8,96 lit CO2 (ktc) vo V lit dd Ca(OH)2 1M, thu c 40g kt ta.Ga tr V l:
A.0,2 n 0,38
B. 0,4
C. < 0,4
D. >=0,4
Cu 21. Thi V ml (ktc) CO2 vo 300 ml dd Ca(OH)2 0,02M, thu c 0,2g kt ta.Ga tr V l:
A. 44.8 hoc 89,6
B. 44,8 hoc 224
C. 224
D. 44,8
Cu 22. Thi V lit (ktc) CO2 vo 100 ml dd Ca(OH)2 1M, thu c 6g kt ta. Lc b kt ta ly dd un nng li c kt
ta na. Ga tr V l:
27
A. 3,136
B. 1,344
C. 1,344 hoc 3,136
D. 3,36 hoc 1,12
Cu 23. Dn V lt CO2 (kc) vo 300ml dd Ca(OH)2 0,5 M. Sau phn ng c 10g kt ta. V bng:
A. 2,24 lt
B. 3,36 lt
C. 4,48 lt D. A,C ng
Cu 24. Hp th ton b x mol CO2 vo dung dch cha 0,03 mol Ca(OH)2 c 2 gam kt ta. ga tr x?
A. 0,02 mol v 0,04 mol
B. 0,02mol v 0,05 mol
C. 0,01mol v 0,03 mol
D. 0,03mol v 0,04 mol
Cu 25. T khi hi ca X gm CO2 v SO2 so vi N2 bng 2.Cho 0,112 lt (ktc) X qua 500ml dd Ba(OH)2. Sau th nghim
phi dng 25ml HCl 0,2M trung ha Ba(OH)2 tha. % mol mi kh trong hn hp X l?
A. 50 v 50
B. 40 v 60
C. 30 v 70
D. 20 v 80
E.p n khc
Cu 26. Cho 5,6 lt hn hp X gm N2 v CO2 (ktc) i chm qua 5 lt dung dch Ca(OH)2 0,02M phn ng xy ra hon
ton thu c 5 gam kt ta. Tnh t khi hi ca hn hp X so vi H2.
A. 18,8
B. 1,88
C. 37,6
D. 21
Cu 27. Hp th ht V lt CO2 (ktc) vo 300 ml dung dch NaOH x mol/l c 10,6 gam Na2CO3 v 8,4 gam NaHCO3. Ga
tr V, x ln lt l?
A. 4,48lt v 1M
B. 4,48lt v 1,5M
C. 6,72 lt v 1M
D. 5,6 lt v 2M
Cu 28. Sc CO2 vo 200 ml hn hp dung dch gm KOH 1M v Ba(OH)2 0,75M. Sau khi kh b hp th hon ton
thy to 23,6 g kt ta. Tnh VCO2 dng ktc
A. 8,512 lt B. 2,688 lt C. 2,24 lt
D. A,B ng
Cu 29. t chy hon ton 0,1 mol etan ri hp th ton b sn phm chy vo bnh cha 300 ml dd NaOH 1M. Khi
lng mui thu c sau phn ng?
A. 8,4g v 10,6g
B. 84g v 106g
C. 0,84g v 1,06g
D. 4,2g v 5,3g
Cu 30. t chy hon ton 0,1 mol C2H5H ri hp th ton b sn phm chy vo bnh cha 75 ml dd Ba(OH)2 2 M.
Tng khi lng mui thu c sau phn ng l? (Ba=137)
A. 32,65 g
B. 19,7g
C. 12,95g
D. 35,75g
Cu 31. (Khi A-2007). Ba hidrocacbon X, Y, Z l ng ng k tip trong khi lng phn t Z gp i khi lng
phn t X. t chy 0,1 mol cht Y, sn phm kh hp th hon ton vo dung dch Ca(OH)2 d thu c s gam kt ta
l?
A. 20
B. 40
C. 30
D. 10
Cu 32. t A gm 2 hidrocacbon lin tip. Hp th sn phm vo 3 lt dd Ca(OH)2 0,01M c kt ta v khi lng dd
tng 2,46g. Cho Ba(OH)2 vo li thy c kt ta na. Tng khi lng kt ta 2 ln l 6,94g. Tm khi lng mi
hidrocacbon dng?
A. 0,3g v 0,44g
B. 3g v 4,4g
C. 0,3g v 44g
D. 30g v 44g
Cu 33. t 2 ru metylic v etylic ri hp th sn phm chy vo 150ml Ba(OH)2 1M thy c kt ta v khi lng dung
dch gim 4,6g.Thm Ba(OH)2 d vo c 19,7g kt ta na. % khi lng mi ru l?
A. 40 v 60
B. 20 v 80
C. 30,7 v 69,3
D. 58,18 v 41,82
Cu 34. ( H khi A nm 2007). Cho m gam tinh bt ln men thnh ancol etylic vi H=81%. Ton b CO2 c hp th
vo dd Ca(OH)2, c 550 gam kt ta v dd X. un X thu thm 100 gam kt ta. m l?
A. 550
B. 810
C. 650
D. 750
Cu 35. t chy 0,225 mol ru n chc A bng oxi va . Hp th ht sn phm chy vo 100 ml dd Ba(OH)2 1,5M
c 14,775g kt ta. Ru A c cng thc no di y?
A. CH3OH
B. C2H5OH
C. C3H7OH
D. C4H7OH
Cu 36. t 10 gam cht A (C, H, O). Hp th sn phm chy vo 600 ml NaOH 1M thy khi lng dd tng 29,2 gam.
Thm CaCl2 d vo dd sp c 10 gam kt ta. Xc nh A bit CTPT trng vi CTGN.
A. C5H8O2 B. C5H10O2 C. C5H6O4 D. C5H12O
Cu 37. t 2,6 gam hidrocacbon A ri hp th sn phm vo bnh 500ml KOH, thm BaCl2 d vo, sau png thy 19,7
gam kt ta. Lc b kt ta ri thm Ba(OH)2 d vo phn nc lc thy 19,7 gam kta na. Xc nh CTPT A bit 90
<MA <110.
A. C2H2
B. C4H4
C. C6H6
D. C8H8
28
Chuyn 08: Phn ng ca Al, Zn v hp cht vi dd kim

Cu 1: Cho 3,42gam Al2(SO4)3 tc dng vi 25 ml dung dch NaOH to ra c 0,78 gam kt ta. Nng mol ca
NaOH dng l?(Na=23;Al=27;S=32;O=16)
A. 1,2M
B. 2,8M
C. 1,2 M v 4M
D. 1,2M hoc 2,8M
Cu 2: Cho 150 ml dung dch NaOH 7M tc dng vi 100 ml dung dch Al2(SO4)3 1M . Xc nh nng mol/l NaOH
trong dung dch sau phn ng. (Na=23;Al=27;S=32;O=16)
A. 1M
B. 2M
C. 3M
D. 4M
Cu 3: Trong mt cc ng 200ml dung dch AlCl 3 2M. Rt vo cc Vml dung dch NaOH c nng a mol/lt, ta
c mt kt ta; em sy kh v nung n khi lng khng i c 5,1g cht rn. Nu V= 200ml th a c gi tr
no?(Na=23;Al=27;Cl=35,5;O=16;H=1)
A. 2M B. 1,5M hay 3M
C. 1M hay 1,5M
D. 1,5M hay 7,5M
Cu 4: Ho tan a(g) hn hp bt Mg- Al bng dung dch HCl thu c 17,92 lit kh H2 (ktc). Cng lng hn hp trn
ho tan trong dung dch NaOH d thu c 13,44 lt kh H2 ( kc). a c gi tr l: (Mg=24;Al=27;H=1;Cl=35,5;Na=23)
A. 3,9
B. 7,8
C. 11,7
D. 15,6
Cu 5: Cho a mol AlCl3 vo 200g dung dch NaOH 4% thu c 3,9g kt ta. Gi tr ca a l:
(Al=27;Na=23;Cl=35,5;O=16;H=1)
A. 0,05
B. 0,0125
C. 0,0625
D 0,125
Cu 6: Cho 200ml dung dch H2SO4 0,5M vo mt dung dch c cha a mol NaAlO2 c 7,8g kt ta. Gi tr ca a l:
(Na=23;Al=27;S=32;O=16)
A. 0,025
B. 0,05
C. 0,1
D. 0,125
Cu 7: Cho 18,6 gam hn hp gm Zn v Fe tc dng va vi 7,84 lt Cl2(ktc). Ly sn phm thu c ha tan vo

nc ri cho tc dng vi dung dch NaOH 1M. Th tch NaOH cn dng lng kt ta thu c l ln nht v nh
nht ln lt l?(Zn=65;Fe=56;Na=23;O=16;H=1)
A. 0,7 lt v 1,1 lt B. 0,1 lt v 0,5 lt
C. 0,2 lt v 0,5
D. 0,1 lt v 1,1
Cu 8: C mt dung dch cha 16,8g NaOH tc dng vi dung dch c ha tan 8 gam Fe2(SO4)3. Sau li thm vo
13,68gam Al2(SO4)3. T cc phn ng ta thu c dung dch A c th tch 500ml v kt ta. Nng mol cc cht trong
dung dch A l? (Al=27;Fe=56;Na=23;O=16;H=1)
A. [Na2SO4=0,12M], [NaAlO2=0,12M]
B. [NaOH=0,12M], [NaAlO2=0,36M]
C. [NaOH=0,6M], [NaAlO2=0,12M]
D. [Na2SO4=0,36M], [NaAlO2=0,12M]
Cu 9: Ha tan 21 gam hn hp gm Al v Al2O3 bng HCl c dung dch A v 13,44 lt H2(ktc). Th tch dung dch
(lt) NaOH 0,5M cn cho vo dung dch A thu c 31,2 gam kt ta l? (Al=27;Na=23;Cl=35,5;O=16;H=1)
A. 2,4
B. 2,4 hoc 4
C. 4
D. 1,2 hoc 2
29
Cu 10: Ha tan 3,9 gam Al(OH)3 bng 50ml NaOH 3M c dung dch A. Th tch dung dch(lt) HCl 2M cn cho
vo dung dch A xut hin tr li 1,56 gam kt ta l? (Al=27;Na=23;Cl=35,5;O=16;H=1)
A. 0,02
B. 0,24
C. 0,06 hoc 0,12
D. 0,02 hoc 0,24
Cu 11: 200 ml gm MgCl2 0,3M; AlCl3 0,45 M; HCl 0,55M tc dng hon ton vi V(lt) gm NaOH 0,02M v
Ba(OH)2 0,01M. Ga tr ca V(lt) c kt ta ln nht v lng kt ta nh nht l?
(Al=27;Na=23;Cl=35,5;O=16;H=1;Mg=24;Ba=137)
A. 1,25lt v 1,475lt
B. 1,25lt v 14,75lt
C. 12,5lt v 14,75lt
D. 12,5lt v 1,475lt
Cu 12: Cho m gam hn hp X gm Na2O v Al2O3 tc dng vi H2O cho phn ng hon ton thu c 200 ml dung
dch A ch cha mt cht tan duy nht c nng 0,5M. Thi kh CO2 d vo dung dch A c a gam kt ta. Ga tr
ca m v a l? (Al=27;Na=23;O=16;H=1)
A. 8,2g v 78g B. 8,2g v 7,8g C. 82g v 7,8g D. 82g v 78g
Cu 13: Rt 150 ml dung dch NaOH 7M vo 50 ml dung dch Al2(SO4)3. Tm khi lng cht d sau th nghim:
(Al=27;Na=23;O=16;H=1;S=32)
A. 16g
B. 14g
C. 12g
D. 10g
Cu 14: Cho 8 gam Fe2(SO4)3 vo bnh cha 1 lt dung dch NaOH a M, khuy k phn ng xy ra hon ton; tip tc
thm vo bnh 13,68g Al2(SO4)3. Cui cng thu c 1,56 gam kt ta keo trng. Tnh gi tr nng a?
(Al=27;Fe=56;Na=23;O=16;H=1;S=32)
A. 0,2M
B. 0,4M
C. 0,38M
D. 0,42M
Cu 15: Ha tan 5,34gam nhm clorua vo nc cho 200ml dung dch. Thm tip dung dch NaOH 0,4M vo dung
dch trn, phn ng xong thu c 1,56 gam kt ta. Nng mol dung dch HNO3 l?
(Al=27;Na=23;Cl=35,5;O=16;H=1)
A. 0,6M v 1,6M
B. 1,6M hoc 2,4M
C. 0,6M hoc 2,2M
D. 0,6M hoc 2,6M
Cu 16: Cho 200Ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6
gam. Ga tr ln nht ca V l?(H=1;O=16;Al=27)
A. 1,2
B. 1,8
C. 2,4
D. 2
(Cu 7 TTS i hc khi B nm 2007)
Cu 17: Thm m gam Kali vo 300ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t
dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu c lng kt ta Y ln nht th ga tr
ca m l?(H=1;O=16;Na=23;Al=27;S=32;K=39;Ba=137)
A. 1,59
B. 1,17
C. 1,71
D. 1,95
(Cu 21 TTS Cao ng khi A nm 2007)
Cu 18: Hn hp X gm Na v Al. Cho m gam X vo mt lng d nc th that ra V lt kh. Nu cng cho m gam X
vo dung dch NaOH(d) th c 1,75V lt kh. Thnh phn % theo khi lng ca Na trong X l (bit cc th tch kh
o trong cng iu kin; Na=23;Al=27)
30
A. 39,87%
B. 77,31%
C. 49,87%
D. 29,87%
(Cu 21 TTS i hc khi B nm 2007)
Cu 19: Cho dung dch NaOH 0,3M vo 200 ml dung dch Al2(SO4)3 0,2M thu c mt kt ta trng keo. Nung kt
ta ny n khi lng lng khng i th c 1,02g rn. Th tch dung dch NaOH l bao nhiu?
(Al=27;Na=23;S=32;O=16;H=1)
A. 0,2lt v 1 lt
B. 0,2lt v 2 lt
C. 0,3 lt v 4 ltD. 0,4 lt v 1 lt
Cu 20: Khi cho 130 ml AlCl3 0,1M tc dng vi 20 ml dung dch NaOH, th thu c 0,936gam kt ta. Nng
mol/l ca NaOH l? (Al=27;Na=23;Cl=35,5;O=16;H=1)
A. 1,8M
B. 2M
C. 1,8M v 2M
D. 2,1M

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1

Tng n tp kin thc ha hc v c

Chuyn 06: bi tp v phn ng oxi ha kh (HNO3; H2SO4 c

Chuyn 07: bi ton CO2, SO2 tc dng vi dd kim

8. Chuyn 08: bi ton cho Al, Zn v hp cht tc dng vi dd kim

(B n tp tuyn sinh i hc nm 2012-2013)

Mi kin ng gp xin gi v a ch e-mail thanhbach20112011.tb.vnu@gmail.com. Rt mong

nhn c kin ca cc thy, c, cc bn,..

Chc cc bn hc sinh mt k thi thnh cng

H Ni, ma thi 2012

Chuyn 01: Cu to nguyn t v bng htth

Br chim 50,69% s nguyn t v

Br chim 49,31% s nguyn

Hy tm nguyn t khi trung bnh ca brom.

Cu . Nguyn t khi trung bnh ca ng l 63,54.

Tnh thnh phn phn trm ca mi ng v.

B v 115 B . Mi khi c 760 nguyn t 105 B th c bao nhiu nguyn t

Bi 18. Mt nguyn t X c 2 ng v vi t l nguyn t l

B v 115 B . Nguyn t khi trung bnh ca bo 10,81.

a) Tnh phn trm ca mi ng v.

B trong axit boric H3BO3 ( Bit H l ng v 11 H ; O l ng v 168 O ).

Y chim 55% s nguyn t Y v ng v

Tnh nguyn t khi trung bnh ca X, Y.

Bi 25. Clo trong t nhin gm hai ng v 17 Cl v 17 Cl ; Silic gm hai ng v

Si . Hp cht silic clorua

Bi 26. C hai ng v 11 H (k hiu l H) v 12 H (k hiu l D).

Bi 31. Hiro c ba ng v 11 H , 12 H v 13 H . Clo c hai ng v l 17 Cl v 17 Cl . Hy cho bit c bao nhiu phn t

Bi 32. Trong t nhin oxi tn ti 3 ng v bn : 8 O ; 8 O ; 8 O v hiro c ba ng v bn l : 11 H , 12 H v 13 H . Hi

Na . Hy xc nh s ht electron v tng s cc ht c trong ion S2- , Na+.

Bi 34. Cho cc ion : NO 3 , NH +4 , HSO 4 , bit ZN = 7; ZO = 8 ; ZH = 1 ; ZS = 16. Hy xc nh :

Hy vit cu hnh electron v v cu to nguyn t .

Chuyn 02: Lin kt ha hc

lin kt cng ha tr: l s hnh thnh do s gp chung e ca cc ng t ng t thng l phi kim

th lin kt l lin kt cng ha tr khng phn cc

Chuyn 03: Tc phn ng, cn bng ha hc

II/ l thuyt phn cn bng ha hc

Chuyn 04: S in li in phn

2. Hng s in li, hng s cn bng

3. Tch s ion ca nc v ph dung dch

4. nh ngha axit, bazo, mui

Chuyn 05: Bi tp tng hp v kim loi, phi kim v bi

B. 2,24 lt v 33,07 gam

C. 4,48 lt v 33,07 gam D. 1,12 lt v 18,20 gam

Cu 19: Cho V lt hn hp kh A gm clo v oxi tc dng va ht vi hn hp B gm 0,2 mol Al v 0,1 mol Mg

Cu 28: Cho V lt hn hp kh ( ktc) gm CO v H2 phn ng vi mt lng d hn hp rn gm CuO

CHUYN 06: BI TP V PHN NG OXI HA KH

S mol HNO3 phn ng = 0,18 mol

Chuyn 07: SO2; CO2 tc dng vi dd kim

Chuyn 08: Phn ng ca Al, Zn v hp cht vi dd kim

D. 1,2M hoc 2,8M

D. 1,5M hay 7,5M

Cu 7: Cho 18,6 gam hn hp gm Zn v Fe tc dng va vi 7,84 lt Cl2(ktc). Ly sn phm thu c ha tan vo

C. 0,06 hoc 0,12

D. 0,02 hoc 0,24

B. 1,6M hoc 2,4M

C. 0,6M hoc 2,2M

D. 0,6M hoc 2,6M

C. 0,3 lt v 4 ltD. 0,4 lt v 1 lt

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