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TRNG THPT CHUYN L HNG PHONG THI TUYN SINH LP 10 NM HC 2004-2005
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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MN: HA HC
CHNH THC Thi gian: 150 pht (Khng k thi gian pht )
Cu I (4):
1/ Vit phng trnh phn ng ca cc cht sau y vi dung dch axit clohydric: KMnO
4
, Fe
2
O
3
, R
x
O
y
.
2/ Nu phng php ha hc tch ring cc kh trong hn hp gm O
2
, HCl v CO
2
.
3/ Ch dng bt st lm thuc th, hy phn bit 5 dung dch cha trong cc l ring bit sau: H
2
SO
4
,
Na
2
SO
4
, Na
2
CO
3
, MgSO
4
, BaCl
2
.

Cu II (4):
1/ T tinh bt v cc cht v c cn thit, vit cc phng trnh phn ng iu ch: etyl axetat, poli
etilen (PE).
2/ Cho 10,1 (g) dung dch ru etylic trong nc tc dng vi natri d thu c 2,8 lt kh (ktc). Xc
nh ru, bit rng khi lng ring ca ru etylic nguyn cht l 0,8 g/ml.
3/ Hn hp kh X gm anken A, C
2
H
2
v H
2
. un nng 1,3 lt hn hp X vi niken xc tc thu c sn
phm l mt hydrocarbon no duy nht c th tch l 0,5 lt (cc th tch kh o cng iu kin). Xc nh
cng thc phn t ca A v th tch cc cht trong hn hp X.

Cu III (6):
1/ Cho 44,8 lt kh HCl (ktc) ha tan hon ton vo 327 gam nc c dung dch A.
a/ Tnh nng phn trm ca dung dch A.
b/ Cho 50 gam CaCO
3
vo 250 gam dung dch A, un nh n khi phn ng xy ra hon ton th thu c
dung dch B. Tnh nng phn trm cc cht c trong dung dch B.
2/ Ha tan hon ton a gam CuO vo 420 gam dung dch H
2
SO
4
40% ta c dung dch X cha H
2
SO
4
d
c nng 14% v CuSO
4
c nng C%. Tnh a v C.
3/ Ha tan hon ton mt oxit kim loi ha tr II vo mt lng dung dch H
2
SO
4
20% (va ) ta c
dung dch mui Y c nng 22,64%. Xc nh nguyn t lng ca M.

Cu IV (6):
t chy hon ton 0,2 mol mt anken A, ton b sn phm chy c hp th vo 295,2 gam dung
dch NaOH 20%. Sau th nghim, nng NaOH d l 8,45%. Bit rng cc phn ng xy ra hon ton.
a/ Xc nh cng thc phn t ca A.
b/ Hn hp X (gm A v H
2
) c t khi hi vi hidro l 6,2. un nng X vi niken xc tc n khi phn
ng hon ton thu c hn hp Y.
- Chng minh rng Y khng lm mt mu dung dch brom.
- t chy hon ton Y c 25,2 gam hi nc. Tnh th tch mi kh trong hn hp X (ktc).


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( thi gm 6 cu)
Cu I (2):
1 . t chy cacbon trong khng kh nhit cao, c hn hp kh (A). Cho (A) tc dng vi Fe
2
O
3

(r) nung nng thu c hn hp kh (B) v hn hp cht rn (C). Cho (B) tc dng vi dung dch
Ca(OH)
2
thu c kt ta (D) v dung dch (E). Cho dung dch NaOH d vo dung dch (E) li c kt
ta (D). Cho (C) tan hon ton trong dung dch HCl, thu c kh v dung dch (F). Cho (F) tc dng vi
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dung dch NaOH d, c hn hp kt ta (G). Nung (G) trong khng kh c mt oxit duy nht. Vit
cc phng trnh phn ng xy ra.
2 . T nguyn liu Fe
3
O
4
(r), hy trnh by cch iu ch : a/ FeCl
2
(r) ; b/ FeCl
3
(r).
Vit cc phng trnh phn ng xy ra.
Cu II (1):
C 5 l mt nhn, mi l ng mt dung dch khng mu sau: NaCl, Na
2
SO
4
, MgSO
4
, Al
2
(SO
4
)
3
,
BaCl
2
. Ch c dng mt oxit (rn), lm th no nhn bit dung dch ng trong mi l bng phng
php ha hc? Vit cc phng trnh ha hc.
Cu III (2):
Cho 14,8 g hn hp rn (X) gm kim loi M (ha tr II), oxit ca M v mui sunfat ca M ha tan
trong dung dch H
2
SO
4
long, d th thu c dung dch (A) v 4,48 lt (ktc). Cho NaOH d vo dung
dch (A) thu c kt ta (B). Nung (B) nhit cao n khi lng khng i th cn li 14,0 g cht
rn.
Mt khc, cho 14,8 g hn hp (X) vo 0,2 lt dung dch CuSO
4
2M. Sau khi phn ng kt thc, tch b
cht rn, em phn dung dch c cn n ht nc th cn li 62 g cht rn.
1 . Xc nh kim loi M.
2. Xc nh phn trm khi lng cc cht trong hn hp (X).
Cu IV (2):
1 . Hy vit cng thc cu to c th c ng vi cng thc phn t C
4
H
8
Br
2
. Cho bit cng thc cu to
no ph hp vi cht c to thnh t phn ng C
4
H
8
+ Br
2
C
4
H
8
Br
2
?
2 . Vit cc phng trnh ha hc ca cc phn ng sau (ghi r iu kin phn ng, nu c):
a/ C
12
H
22
O
11
+ H
2
O A
1
+ A
2
b/ CO
2
+ H
2
O B + O
2

c/ B + H
2
O A
1
d/ C H|-HNCH
2
CO-|
n
OH + H
2
O
Cu V (1):
Cho s chuyn i ha hc sau. Hy vit cc phng trnh ha hc di dng cng thc cu to rt
gn:
C
2
H
4
C
2
H
6
O C
2
H
4
O
2
C
4
H
8
O
2
C
2
H
3
O
2
Na
Cu VI (2):
Cho mt hn hp kh A cha 7,0 g C
2
H
4
v 1,0 g H
2
phn ng vi nhau c mt xc tc thu c hn
hp kh B. Mt na khi lng kh B phn ng va vi 25 ml dung dch brom 1M. Mt na khi
lng kh B cn li em t chy vi lng d oxi ri cho ton b sn phm chy hp th hon ton vo
100 ml dung dch NaOH 22,4% (t trng d = 1,25 g/ml) thu c dung dch C.
1 . Xc nh hiu sut phn ng gia C
2
H
4
v H
2
.
2 . Xc nh nng phn trm ca cc cht c trong dung dch C.


I HC QUC GIA TP H CH MINH K THI TUYN SINH LP 10 NM HC 2007-2008
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Cu I (2):
Hy xc nh cc cht X, Y, Z, T v lp phng trnh ha hc ca nhng phn ng c s sau y:
(a) X + O
2 (k)
XO
2

(b) X + H
2
SO
4
XO
2
+ Y
(c) XO
2
+ CaO Z
(d) Z + HCl T + XO
2
+ Y
(e) XO
2
+ Y + KMnO
4
H
2
XO
4
+ MnXO
4
+ K
2
XO
4

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(f) XO
2
+ O
2
XO
3

(g) XO
2
+ H
2
X
(k)
X + Y
T cc phng trnh ha hc trn, kt lun v tnh cht tng qut ca XO
2
.
Cu II (1,5):
Ha tan 3,7 kg MgSO
4
.7H
2
O vo 2 lt nc (t trng 1kg/l) v un nng nc bay hi bt thu c A
kg dung dch magie sunfat bo ha 100
0
C. Khi h nhit ca A kg dung dch trn t 100
0
C xung n
0
0
C th c B kg MgSO
4
.7H
2
O tch ra. Xc nh A, B. Cho bit dung dch magie sunfat bo ha 0
0
C c
nng 21,2% cn 100
0
C l 42,5%.
Cu III (1,5):
Cho kh thot ra khi 3,0 g km tc dng vi 18,69 ml dung dch axit clohydric 14,6% (khi lng ring
l 1,07 g/ml) i qua 4 (g) ng (II) oxit nung nng. Tnh th tch dung dch axit sunfuric 19,6% (khi
lng ring 1,14 g/ml) cn ch ha vi hn hp thu c ly ng kim loi ra.
Cu IV (1):
Xc nh cc cht cha bit v vit phng trnh ha hc ca nhng phn ng ng vi s sau:
Fe +HCl X
1
+ Cl
2
X
2
+ Na
2
SO
3
X
4
+ Na
2
S FeS
Cu V (1,5):
Mt mol alkyl ioua, cha bit cng thc cu to, tc dng vi lng d dung dch kali hydroxit trong
ru to nn hn hp ca hai alken ng phn c t l 1:7 v khi lng. Sn phm chnh thu c ca
phn ng c khi lng l 49 g. Xc nh cu to ca hp cht ban u v sn phm phn ng.
Cu VI (1,5):
a/ Cho bit cc cch iu ch glixerol t ngun nguyn liu t nhin. Vit cc phng trnh ha hc.
b/ Khi t chy m g hn hp ca glixerol v etilen glicol (CH
2
OH)
2
kh c to thnh cho i qua
huyn ph cha 50 g canxi cacbonat trong 1200 ml nc, to nn dung dch trong sut. Xc nh th tch
kh ( nhit 20
0
C v p sut 1,03 atm) thot ra khi cho m g hn hp hai alcol tc dng vi Na.
Cu VII (1):
Mt mol ru n chc A1 c oxi ha thnh axit hu c tng ng B. Ngi ta dehydrat ha (kh
nc) cng mt mol ru A1, to thnh mt anken, ri sau khi hydrat ha (cng nc) anken li to
thnh mt ru A2 l ng phn ca ru A1 ban u. T cc sn phm ca nhng phn ng (B v
A2) ngi ta tng hp este C. t chy hon ton este C thu c 80,6 lt kh cacbonic (ktc). Tm cu
to este C, cho bit hiu sut to thnh este l 60% cn cc phn ng khc xy ra hon ton.

I HC QUC GIA TP H CH MINH K THI TUYN SINH LP 10 NM HC 2008-2009
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Cu 1: Vit cc phng trnh ha hc ca phn ng xy ra, nu c, trong cc qu trnh sau (nu khng c
phn ng phi ghi r khng phn ng):
a/ Nung hn hp bt st v lu hunh trong mi trng khng c oxi.
b/ Sc kh clo vo dung dch natri hidroxit ngui.
c/ un si k dung dch canxi hidrocacbonat bo ha.
d/ un nhm oxit trong dung dch natri hidroxit.
Cu 2: Xc nh X v hon thnh cc phng trnh phn ng sau (ch c thm H
2
O nu cn thit):
a/ XH
3
+ MnO
2
Mn
3
O
4
+ XO b/ KXO
2
+ KI + H
2
SO
4
I
2
+ XO + K
2
SO
4

c/ Ag + HXO
3
AgXO
3
+ XO d/ XO
2
+ C CO
2
+ XO
e/ XO + O
2
XO
2
f/ XO + XH
3
X
2

Cho bit X
2
l cht kh chim phn ln trong khng kh.
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Cu 3: X, Y, Z l 3 ha cht c dng ph bin lm phn bn ha hc. Chng l cc phn bn n cung
cp 3 thnh phn chnh: m, ln v kali cho cy trng. Ba ha cht trn u tan trong nc, bit:
- Dung dch nc ca X cho kt ta mu trng vi dung dch natri cacbonat d.
- Khi cho d dung dch natri hidroxit vo dung dch nc ca Y v un si, nhn thy c mi khai bay ra,
nhng cho dung dch axit clohidric vo dung dch Y th khng thy c hin tng g xy ra. Dung dch Y cng
to kt ta trng vi dung dch bari clorua.
- Dung dch nc ca Z to kt ta trng vi dung dch bc nitrat, nhng khng to kt ta vi dung dch bari
clorua.
Phng on thnh phn ha hc ca X, Y, Z v vit cc phng trnh ha hc minh ha cho cc th nghim
m t trn
Cu 4: Dung dch A cha ng thi 2 mui bc nitrat v ng (II) nitrat vi nng mol ca mui ng gp
4 ln nng mol ca mui bc.
a/ Nhng mt thanh km vo 250 ml dung dch A. Sau mt thi gian, ly thanh km ra v lm kh, thy khi
lng thanh km tng 1,51 gam. Bit rng lc ny dung dch sau phn ng cha 3 mui. Tnh nng mol
ca mui km trong dung dch sau phn ng.
b/ Nu gi thanh km trong 250 ml dung dch A mt thi gian lu th thy sau phn ng, dung dch A ch
cha mt mui duy nht vi nng 0,54M. Tnh nng mol ca cc mui trong dung dch A ban u.
c/ Trong th nghim cu b/, khi lng thanh km sau phn ng thay i bao nhiu so vi ban u?
Trong c bi, chp nhn rng tt c kim loi mi sinh ra u bm vo thanh km v th tch dung dch khng
thay i trong qu trnh phn ng.
Cu 5: Cho chui chuyn ha sau:
A H
2
O, Al
2
O
3
B (C
2
H
6
O) Al
2
O
3
+ ZnO C (C
4
H
6
) A D (C
6
H
10
) Pt E (C
6
H
6
)
300
0
C 450
0
C 600
0
C 300
0
C
E (C
6
H
6
) HNO
3
F (C
6
H
5
NO
2
) Fe + HCl G (C
6
H
8
NCl) NaOH H (C
6
H
7
N)
H
2
SO
4

Xc nh cng thc cu to ca cc hp cht trong chui chuyn ha trn v vit li cc phng trnh ha hc.
Cho bit 1 mol D ch phn ng c vi 1 mol brom v E khng phn ng vi brom trong dung dch.
Cu 6: Mt hn hp kh gm hidrocacbon C
n
H
2n
v hidro c th tch chung l 3,360 lt (ktc) c cho qua
xc tc platin 200
0
C. Sau mt thi gian phn ng, th tch hn hp kh l 2,464 lt (ktc) tng ng vi
lng C
n
H
2n
phn ng c 80%. Nu cho hn hp kh ban u qua dung dch nc brom thy khi lng
tng 2,1 gam. Xc nh thnh phn (%th tch) kh ban u v cng thc phn t ca C
n
H
2n
.



I HC QUC GIA TP H CH MINH K THI TUYN SINH LP 10 NM HC 2010
TRNG PH THNG NNG KHIU MN THI: HA HC
Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu 1: Vit cc phng trnh ha hc minh ha cho cc th nghim sau:
a/ Cho ming Ca vo ng nghim cha dung dch FeCl
2
, sau khi phn ng ht, hn hp phn ng ln a
thy tinh v phi ngoi khng kh.
b/ Cho bt Cu vo dung dch axit sunfuric m c ri un nng, dn kh sinh ra qua dung dch Ca(OH)
2
.
Cu 2: T cc nguyn liu ban u gm: Cu kim loi, dung dch axit clohidric, vi, nc, khng kh, than
, hy nu phng php (vit cc phng trnh ha hc) iu ch cc sn phm sau:
a/ CuCl
2
b/ Ca(OH)
2
v C
2
H
2
.
Cu 3: t 2,500 g uranium (U) trong khng kh thu c 2,949 g mt oxit ca uranium. Hy xc nh cng
thc ha hc ca oxit ny. (U = 238)
Cu 4: Hon thnh cc chui phn ng sau:
a/ Al AlCl
3
Al(OH)
3
Al
2
O
3
Al.
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b/ S ZnS H
2
S SO
2
K
2
SO
3
.
Cu 5: xc nh hm lng ion st (II) trong nc, ngi ta dng phng php chun vi dung dch
KMnO
4
trong mi trng axit. Phn ng xy ra theo s sau:
FeSO
4
+ KMnO
4
+ H
2
SO
4
Fe
2
(SO
4
)
3
+ MnSO
4
+ K
2
SO
4
+ H
2
O
a/ Hy lp phng trnh ha hc ca phn ng trn, xc nh cht oxi ha, cht kh.
b/ Xc nh hm lng st (II) (g/l) trong mt mu nc, bit rng 25,00 ml mu nc ny phn ng va
vi 14,50 ml dung dch KMnO
4
0,010 M.
Cu 6: t chy hon ton mt cht hu c X c khi lng mol l 86 gam thu c nc v kh cacbonic c
s mol bng nhau. Xc nh cng thc phn t v vit cc cng thc cu to c th c ca X, nu bit X c
kh nng cho phn ng trng gng. Xc nh cng thc cu to chnh xc ca X, nu bit X c mt nguyn
t cacbon phi i xng (nguyn t cacbon phi i xng c 4 nhm th khc nhau).
Cu 7: Xc nh cng thc cu to ca cc cht A, B, ... M trong s chuyn i ha hc sau:
a/ A + Na B + 1/2H
2
b/ C
3
H
6
+ Br
2
C
c/ C + 2B D + 2NaBr d/ D + 2H
2
O xt E
e/ E + 2H
2
xt F f/ F xt G + H
2
O
g/ A + CH
3
COOH H h/ nH xt I
i/ I + nNaOH K + nCH
3
COONa
k/ A + HCl xt L l/ nL xt M
Cho bit: i/ D c cng thc phn t C
7
H
8
; ii/ Ch c C
3
H
6
v G l cc hp cht c cu to mch vng;
iii/ RC CH + H
2
O RCOCH
3
; iv/ I, K v M l cc polime.
Cu 8: Cho 45,0 (g) mt hn hp X cha metanol, glixerol v nc phn ng va vi natri kim loi to
thnh V (lt) kh hidro (ktc) v m (g) mt hn hp cht rn Y. Tt c m (g) hn hp Y ny phn ng hon
ton vi 250 ml dung dch HCl 20,0% (t trng 1,098 g/ml).
a/ Tnh th tch V (lt) kh hidro (ktc) c to thnh.
b/ Tnh khi lng (g) ca natri kim loi tham gia phn ng.
c/ Tnh khi lng m (g) hn hp cht rn Y c to thnh.
d/ Nu t chy hon ton 18,0 (g) hn hp X trn thu c 15,12 (g) nc. Xc nh hm lng % khi
lng cc cht c trong hn hp X.

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Cu 1:
a/ Bng cch vit cc phng trnh ha hc, hy cho bit cch iu ch axit sunfuric t H
2
S, khng kh v
nc.
b/ Nu cch phn bit 2 kh SO
2
v SO
3
bng phng php ha hc.
Cu 2:
Nung mt hn hp cha MgCO
3
v CaCO
3
cho n khi khi lng khng i, thy khi lng hn hp
gim mt 47,5%. Xc nh % khi lng cc cht c trong hn hp ban u v sau phn ng.
Cu 3:
Cn phi pha bao nhiu gam dung dch Al
2
(SO
4
)
3
17,1% vi 100 g dung dch K
2
SO
4
17,4% thu c
dung dch (X) cha 2 mui Al
2
(SO
4
)
3
v K
2
SO
4
theo t l mol 1:1 ? Sau khi dung dch (X) 20
0
C trong mt
thi gian di, tinh th mui kp ngm nc K
2
SO
4
. Al
2
(SO
4
)
3
. 24H
2
O s tch ra. Tnh khi lng tinh th
mui ngm nc thu c. Bit rng 100 gam nc c th ha tan ti a 14 gam K
2
SO
4
. Al
2
(SO
4
)
3
.
Cu 4:
Hai mu bt kim loi, mt mu l magie, mt mu l nhm, c khi lng m bng nhau. Cho hai mu trn
vo hai bnh khc nhau, vi mi bnh u cha 400 ml dung dch HCl 2M, thy bt kim loi u tan hon ton.
Chia mi dung dch thu c thnh hai phn bng nhau , ly mt phn t mi dung dch em c cn cn thn
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thu c hai mui rn khan c khi lng khc bit nhau l 2,76 gam. Tnh khi lng m. Mi na dung dch
cn li c thm 100 ml dung dch NaOH 4,5M, thy xut hin kt ta, c lc, nung ti khi lng khng
i. Tnh khi lng cc cht thu c sau khi nung. Vit cc phng trnh ha hc xy ra.
Cu 5:
Bia c sn xut bng cch ln men dung dch c cha maltoz (C
12
H
22
O
11
) . Phn ng ln men dung dch
maltoz to thnh ru etylic v kh cacbonic c s mol bng nhau. Cho 50 lt dung dch maltoz c t trng
1,052 g/cm
3
, cha 8,4% khi lng maltoz.
a/ Vit phng trnh ha hc v tnh khi lng ru etylic tinh cht c to thnh t qu trnh ln men hon
ton 50 lt dung dch maltoz trn.
b/ Nu t 50 lt dung dch maltoz trn thu c 4,4 lt bia c t trng 1,1 g/cm
3
th % khi lng ru etylic
trong bia l bao nhiu?
Cu 6:
t chy hon ton 1 mol hp cht hu c (A) cn dng 6 mol kh oxi, to thnh hai hp cht c t l
khi lng l 0,51. Cho bit hp cht hu c (A) khng phn ng vi natri kim loi.
a/ Xc nh cc cng thc cu to c th c ca (A).
b/ Cho bit (A) c to thnh t mt hp cht hu c (B) v bng mt phn ng ha hc duy nht. Xc nh
cht (B) v cng thc cu to ng ca (A). Vit phng trnh ha hc t (B) to thnh (A).
Cu 7:
Natri azua (NaN
3
) c iu ch t init oxit, natri v kh amoniac. Sn phm ph ca phn ng ny cn
c natri hidroxit v kh nit. Vit phng trnh ha hc. Nu cho 31,2 gam natri phn ng vi lng d
amoniac v init oxit, thu c 21 gam natri azua. Tnh hiu sut ca phn ng ny.


S GIO DC V O TO K THI TUYN SINH VO LP 10 CHUYN
THNH PH H CH MINH Nm hc: 2008 2009
Mn thi: HA HC
CHNH THC Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu 1 (4):
1 . Vit phng trnh phn ng thc hin dy chuyn ha sau:
MnO
2
Cl
2
HCl FeCl
2
Fe(OH)
2
FeSO
4
Fe(NO
3
)
2

CaCl
2
Ca(NO
3
)
2
CaCO
3
Ca(HCO
3
)
2

2 . C 5 dung dch cha trong 5 l ring bit gm cc cht: Na
2
CO
3
, BaCl
2
, MgCl
2
, H
2
SO
4
, NaOH c nh
s bt k 1, 2, 3, 4, 5. Thc hin cc th nghim c kt qu nh sau:
-Cht l 1 tc dng vi cht l 2 cho kh bay ln, v tc dng vi cht l 4 to thnh kt ta.
-Cht l 2 cho kt ta trng vi cht l 4 v l 5.
Hy cho bit tn cht ng vi tng l 1, 2, 3, 4, 5. Gii thch v vit phng trnh ha hc minh ha.
Cu 2 (2):
Trn 2 a cn v tr thng bng c 2 cc h trong khng kh, mi cc u ng 100 g dung dch HCl
3,65%. Thm vo cc th nht 8,4 g MgCO
3
, thm vo cc th hai 8,4 g NaHCO
3
.
a/ Sau khi phn ng kt thc, cn cn gi v tr thng bng khng? Nu khng th lch v bn no?Gii thch.
b/ Nu mi bn a cn cng ly 100 g dung dch HCl nhng nng l 10% v cng lm nh th nghim ban
u th khi phn ng kt thc, cn cn gi v tr thng bng khng? Gii thch.
Cu 3 (2):
Ngi ta dng kh CO d nhit cao kh hon ton 53,5 g hn hp X cha CuO, Fe
2
O
3
, PbO v
FeO thu c hn hp kim loi Y v hn hp kh Z. Cho Z tc dng ht vi dung dch Ca(OH)
2
d, phn ng
xong ngi ta thu c 60 g kt ta trng.
a/ Vit phng trnh ha hc ca cc phn ng.
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b/ Xc nh khi lng ca hn hp kim loi Y.
Cu 4 (4):
Ha tan hon ton hn hp X bng Fe v Mg bng mt lng va dung dch HCl 20% thu c dung
dch Y. Bit nng ca MgCl
2
trong dung dch Y l 11,787%.
a/ Vit phng trnh phn ng.
b/ Tnh nng % ca mui st trong dung dch Y.
c/ Nu thm vo dung dch Y ni trn mt lng dung dch NaOH 10% va tc dng th nng % ca
cht c trong dung dch sau phn ng l bao nhiu?
Cu 5 (4):
t chy hon ton mt hn hp kh A gm C
2
H
2
, C
2
H
4
, CH
4
, C
3
H
4
, C
2
H
6
th thu c 8,96 lt CO
2
(ktc)
v 9 g nc.
a/ Vit phng trnh phn ng chy.
b/ Tnh th tch kh oxi cn dng (ktc).
c/ Tnh khi lng ca hn hp A.
Cu 6 (4):
t chy hon ton m (g) mt hidrocacbon X, dn ton b sn phm chy ln lt qua bnh 1 ng H
2
SO
4

c d, bnh 2 ng dung dch Ca(OH)
2
d. Sau khi phn ng xy ra hon ton, ngi ta thy:
-Bnh 1: c khi lng tng thm 21,6 g.
-Bnh 2: c 100 g kt ta trng.
a/ Vit cc phng trnh phn ng xy ra.
b/ Tnh m .
c/ Xc nh cng thc phn t ca X bit t khi hi ca X so vi oxi l 2,25.
d/ Vit cng thc cu to c th c ng vi cng thc phn t ni trn.



S GIO DC V O TO K THI TUYN SINH VO LP 10 NM HC 2012 - 2013
THNH PH H CH MINH Kha ngy: 21 . 6 . 2012
Mn thi: HA HC (Mn chuyn)
CHNH THC Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu 1 (3):
1.1 Trnh by cch tinh ch kh metan trong hn hp kh gm metan, sunfur, axetilen, etilen vi mt hcht
duy nht (nguyn cht hoc dung dch.
1.2 Nu hin tng quan st c v vit phng trnh ha hc khi tin hnh cc th nghim sau:
a/ Cho Na
2
CO
3
vo dung dch FeCl
2
.
b/ Cho Na kim loi vo dung dch CuSO
4
.
c/ Thi SO
2
n d vo dung dch KMnO
4
.
d/ Cho Ba kim loi vo dung dch cha Na
2
SO
4
.
1.3
a/ Hon thnh cc phng trnh ha hc sau:
KMnO
4
+ HCl kh A
FeS + HCl kh B
Na
2
SO
3
+ H
2
SO
4
kh C
Al + NaOH + H
2
O kh D
b/ Cho kh A tc dng vi kh D, kh B tc dng vi kh C, kh A tc dng vi kh B trong nc, kh A tc
dng vi kh C trong nc. Vit cc phng trnh ha hc xy ra.
Cu 2 (2):
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2.1 Kh hon ton 16 gam bt oxit st A bng kh CO nhit cao. Sau khi phn ng kt thc, khi lng
cht rn gim 4,8 gam.
a/ Xc nh cng thc ca oxit st A.
b/ T oxit st A, thc hin chuyn ha sau bng cc phng trnh ha hc vi iu kin thch hp (nu c):
(A) + CO (B) + CO
2
(B) + HCl (C) + H
2
(C) + Cl
2
(D)
(C) + NaOH (E) + (G) (D) + NaOH (F) + (G) (E) + ... + ... (F)
(E) + ... A + H
2
O (F) A + H
2
O
2.2 Ch c dng thm nc v cc iu kin th nghim cn thit, nu phng php nhn bit 5 gi bt
trng ca 5 cht sau: NaCl, Ba(HCO
3
)
2
, Na
2
CO
3
, MgCl
2
, Na
2
SO
4
. Vit cc phng trnh ha hc minh ha.
2.3 Cho cc hp cht hu c: metan, etilen, axetilen, benzen, glucoz.
a/ Hy chn mt hp cht hu c cho trn thch hp nht iu ch trc tip ru etylic. Bit rng khi t
chy hon ton hp cht ny th thu c n
kh cacbonic
= n
nc
v n
oxi phn ng
= 1,5n
khi cacbonic
. Vit phng trnh
ha hc iu ch ru etylic t hp cht hu c va tm c trong iu kin thch hp.
b/ Cho Na kim loi d tc dng vi 10 ml ru etylic 96
0
. Tnh th tch kh thu c (ktc). Bit khi lng
ring ca C
2
H
5
OH l 0,8 g/ml v ca nc l 1 g/ml.
Cu 3 (2):
3.1 Mt khong vt c tng s nguyn t trong phn t khng qu 25, c thnh phn % v khi lng l
14,06% K; 8,66% Mg; 34,6% O; 4,33% H v cn li l mt nguyn t khc. Hy xc nh cng thc ha hc
ca khong vt .
3.2 Hn hp A gm mt ankan v mt anken. t chy hon ton hn hp A thu c a mol H
2
O v b mol
CO
2
. Hi t l
a
b
c gi tr trong khong no?
Cu 4 (2):
un nng m (g) hn hp X gm CH
4
v C
2
H
4
vi 0,3 gam H
2
(c Ni lm xc tc) n khi phn ng xy ra
hon ton thu c 5,6 lt (ktc) hn hp kh Y cha 3 cht.
a/ Tm khong xc nh ca m bi ton c ngha.
b/ Tnh s mol ca mi kh trong Y trong hai trng hp m = 3 gam v m = 6,4 gam.
Cu 5 (2):
Mt hn hp bt X gm st v kim loi M c ha tr khng i. Nu ha tan ht m (g) hn hp X trong
dung dch HCl th thu c 7,84 lt H
2
(ktc). Nu cho m (g) hn hp X tc dng hon ton vi kh clo th th
tch clo cn dng l 8,4 lt (ktc). Bit t l s nguyn t ca st v M trong hn hp l 1 : 4.
a/ Vit cc phng trnh ha hc xy ra.
b/ Tnh th tch kh clo ha hp vi kim loi M (ktc).
c/ Xc nh kim loi M nu bit m (g) = 8,2 (g).
d/ Tnh th tch H
2
thu c (ktc) khi ha tan
1
10
m (g) hn hp X trong dung dch NaOH d.



S GIO DC V O TO K THI TUYN SINH LP 10 THPT CHUYN
THNH PH CN TH NM HC: 2012 2013
KHA NGY: 21 06 2012
CHNH THC

MN THI: HA HC
Thi gian lm bi: 120 pht (Khng k thi gian pht )
Bi 1 (3,5):
1 . Tm cc cht A, B, D, E, F v vit phng trnh ha hc ca cc phn ng xy ra theo dy bin ha sau:
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Tinh bt A C
2
H
5
OH B D


F E CH
4

2 . Cho cc dung dch ring bit mt nhn sau: Na
2
SO
4
, AlCl
3
, FeCl
2
, NaHSO
4
, FeCl
3
. Mt hc sinh cho rng nu
dng dung dch Na
2
S th c th phn bit cc dung dch trn ngay ln th u tin. Kt lun ca hc sinh c ng
khng? V sao?
3 . Nu hin tng, vit cc phng trnh ha hc xy ra trong cc th nghim sau:
- Cho Na vo dung dch CuSO
4
.
- Cho t t n d dung dch KOH vo dung dch AlCl
3
.
- Cho bt Cu vo dung dch FeCl
3
.
- Cho rt t t n d dung dch HCl vo dung dch K
2
CO
3
v khuy u.
Bi 2 (3):
Hn hp X gm 3 kim loi Al, Fe, Cu. Cho m gam hn hp X vo dung dch CuSO
4
(d) sau khi phn ng xy ra
hon ton thu c 35,2 gam kim loi. Nu cng ha tan m gam hn hp X vo 500 ml dung dch HCl 2M n khi
phn ng xy ra hon ton thu c 8,96 lt kh (ktc), dung dch Y v a gam cht rn.
a.Vit cc phng trnh phn ng xy ra v tm gi tr ca a .
b.Cho t t dung dch NaOH 2M vo dung dch Y v khuy u n khi bt u thy xut hin kt ta th dng
ht V
1
lt dung dch NaOH 2M. Tip tc cho tip dung dch NaOH vo n khi lng kt ta khng c s thay i na
th lng dung dch NaOH 2M dng ht 600 ml.
Tm cc gi tr m v V
1
.
Bi 3 (3,5):
Cho hn hp X gm 3 hidrocacbon A, B, C mch h, th kh ( iu kin thng). Trong phn t mi cht
c th cha khng qu mt lin kt i, trong c hai cht vi thnh phn phm trm th tch bng nhau. Trn
m gam hn hp X vi 2,688 lt O
2
thu c 3,136 lt hn hp kh Y (cc th tch kh u o ktc). t chy
hon ton hn hp Y, ri thu ton b sn phm chy sc t t vo dung dch Ca(OH)
2
0,02M , thu c 2,0 gam
kt ta trng v khi lng dung dch gim i 0,188 gam. un nng dung dch ny li thu thm 0,2 gam kt ta
na. (Cho bit cc phn ng ha hc u xy ra hon ton)
a.Tnh m v th tch dung dch Ca(OH)
2
dng.
b.Tm cng thc phn t, cng thc cu to ca 3 hidrocacbon.
c.Tnh thnh phn % th tch ca 3 hidrocacbon trong hn hp X.


UBND TNH BC NINH THI TUYN SINH VO LP 10 THPT CHUYN
S GIO DC V O TO NM HC 2012 2013
Mn thi: HA HC (dnh cho th sinh vo lp chuyn Ha)
Thi gian lm bi: 150 pht (Khng k thi gian giao )
CHNH THC Ngy thi: 30 thng 6 nm 2012

Cu I (2,5):
1 . NaCl c ln tp cht Ca(HCO
3
)
2
. Trnh by cch thu NaCl tinh khit.
2 . Hon thnh cc phng trnh ha hc sau v ch r cht oxi ha, cht kh.
a. Cl
2
+ NH
3
t
0
N
2
+ HCl
b. NH
3
+ Na NaNH
2
+ H
2

c. MnSO
4
+ NH
3
+ H
2
O
2
MnO
2
+ (NH
4
)
2
SO
4

d. (NH
4
)
2
Cr
2
O
7
t
0
N
2
+ Cr
2
O
3
+ H
2
O
3 . Nu hm lng ca mt kim loi trong mui cacbonat l 40% th hm lng phn trm ca kim loi trong
mui photphat l bao nhiu? Tng hay gim? iu c ng vi mi kim loi khng? Gii thch.
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4 . Bng phng php ha hc, hy nhn bit ba axit HCl, HNO
3
, H
2
SO
4
cng trong mt dung dch long ch cha
cc axit.
5 . Vit cc cng thc cu to mch h ca C
5
H
8
bit rng khi hidro ha hon ton ta thu c isopentan. Hy cho
bit nhng cht no c kh nng trng hp thnh cao su?
Cu II (2,5): Cho oxit M
x
O
y
ca kim loi M c ha tr khng i.
1 . Xc nh cng thc oxit trn bit rng 3,06 g M
x
O
y
nguyn cht tan trong HNO
3
d thu c 5,22 g mui.
2 . Khi cho 7,050 g loi oxit trn c ln tp cht tr trong khng kh, mt phn ht m, mt phn bin thnh mui
cacbonat, sau mt thi gian khi lng mu oxit l 7,184 g. Ha tan mu oxit ny vo nc thu c dung dch
A, khi lng cn cn li l 0,209 g. Ha tan cn trong dung dch HCl d, cn li 0,012 g cht rn khng tan.
a. Tnh phn trm khi lng tp cht trong mu oxit ban u.
b. Tnh phn trm khi lng oxit b ht m v b bin thnh mui cacbonat.
3 . Ly 4,2 g hn hp B gm MgCO
3
v CaCO
3
cho tc dng vi dung dch HCl c d, kh CO
2
thu c cho hp
th hon ton bi dung dch A ni trn. Tnh khi lng kt ta thu c.
Cu III (2,5):
1 . T 10 tn qung hemantit c cha 48% Fe
2
O
3
v 1,2 tn cacbon s sn xut c bao nhiu tn gang cha 96%
Fe v 4% C (Gi thit cc nguyn t Mn, Si.... khng ng k v hiu sut cc qu trnh u t 100%).
2 . Cho t t dung dch NaOH 1M vo 100 ml dung dch cha HCl 0,5M v AlCl
3
1M n d.
a.Nu hin tng v vit cc phng trnh ha hc xy ra gii thch.
b.Tnh th tch dung dch NaOH dng thu c lng kt ta ln nht.
c.Tnh th tch dung dch NaOH dng thu c 3,9 g kt ta.
Cu IV (2,5): un nng 132,8 g hn hp X gm 3 ru no AOH, BOH, ROH vi H
2
SO
4
c 140
0
C ta thu c
111,2 g hn hp 6 ete c s mol bng nhau. Mt khc, nu un hn hp X vi H
2
SO
4
c 180
0
C th thu c hn hp
Y ch cha 2 kh olefin.
1 . Xc nh cng thc phn t, cng thc cu to ca cc ru.
2 . Tnh % khi lng ca mi ru trong hn hp X.
3 . Bit hn hp Y lm mt mu va 800 ml dung dch brom 2M. Tnh khi lng nc thu c khi to ra hn
hp Y.


I HC QUC GIA H NI CNG HA X HI CH NGHA VIT NAM
TRNG I HC KHOA HC T NHIN c lp T do Hnh phc
THI TUYN SINH H PH THNG TRUNG HC CHUYN NM 2008
Mn thi: HA HC (Dnh cho th sinh vo lp chuyn Ha hc)
Thi gian lm bi: 150 pht (Khng k thi gian giao )
Cu I (1,5):
1 . C 4 cht kh A, B, C, D. Kh A to nn khi nung nng KMnO
4
, kh B bay ra cc m, kh C bay ra cc dng
khi in phn dung dch NaCl c mng ngn. Kh D l cht hu c c t khi so vi hidro l 8. Cho bit A, B, C, D l
nhng kh g? Nhng kh no phn ng vi nhau tng i mt? Vit cc phng trnh phn ng .
2 . T cc nguyn liu chnh gm: qung apatit Ca
5
F(PO
4
)
3
, st pyrit FeS
2
, khng kh v nc. Hy vit cc phng
trnh phn ng iu ch:
a/ Superphotphat n b/ Superphotphat kp.
Cu II (1):
1 . C hai aminoaxit E v F cng cng thc phn t C
3
H
7
NO
2
, dng cng thc cu to ca chng vit phng trnh
phn ng gia gia mt phn t E v mt phn t F to ra sn phm mch h.
2 . Cho A v B l hai hp cht hu c n chc (cha C, H, O) u c khi lng mol l 74 g. A phn ng c vi c
Na v NaOH, cn B phn ng vi dung dch NaOH to ra mui c khi lng mol nh hn 74. Hy vit cc cng thc
cu to ng ca A, B v vit cc phng trnh phn ng minh ha.
Cu III (2):
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Cho 23,22 gam hn hp G gm Cu, Fe, Zn, Al vo cc cha dung dch NaOH d thy cn li 7,52 gam cht rn khng
tan v thu c 7,84 lt kh (ktc). Lc ly phn cht rn khng tan ri ha tan ht n vo lng d dung dch HNO
3

long, cc phn ng u to ra kh NO v tng th tch NO l 2,688 lt (ktc). Gi thit cc phn ng u t hiu sut
100% . Xc nh thnh phn % khi lng ca mi kim loi trong hn hp G.
Cu IV (2):
Chia 156,8 gam hn hp L gm FeO, Fe
3
O
4
v Fe
2
O
3
thnh hai phn bng nhau. Cho phn th nht tc dng ht vi
dung dch HCl d c 155,4 gam mui khan. Phn th hai tc dng va ht vi 500 ml dung dch M l hn hp HCl,
H
2
SO
4
long thu c 167,9 gam mui khan.
Vit cc phng trnh ha hc xy ra. Xc nh % khi lng Fe trong L v nng mol ca dung dch M.
Cu V (2):
Hai cht hu c X, Y to nn bi cc nguyn t C, H, O. Trong C chim 40% khi lng mi cht, khi lng mol
ca X gp 1,5 ln khi lng mol ca Y. Khi t chy hon ton 0,03 mol hn hp X, Y cn dng va ht 1,68 lt oxi
(ktc).
Cho 1,2 gam Y tc dng ht vi dung dch NaOH thu c m gam mui khan.
Cho 1,8 gam X tc dng ht vi dung dch NaOH thu c 1,647m gam mui khan.
Tm cng thc n gin nht, cng thc phn t v cng thc cu to c th c ca X, Y.
Cu VI (1,5):
Hai este P v Q c khi lng mol hn km nhau 28 gam, phn t mi cht u cha C, H v 2 nguyn t O. Cho 32,4
gam hn hp Z gm P, Q tc dng vi dung dch NaOH va , sau c cn dung dch th thu c 32,8 gam cht
rn khan. Phn bay hi gm nc v hai ru, trong phn hi ca hai ru chim th tch bng th tch ca 11,2
gam N
2
o cng iu kin. Khi t chy hon ton mt lng mol nh nhau ca hai ru th s mol CO
2
to ra hai
ru hn km nhau 3 ln.
Xc nh cng thc cu to ca mi este v % khi lng cc cht trong hn hp Z.


I HC QUC GIA H NI THI TUYN SINH LP 10
TRNG I HC KHOA HC T NHIN H TRUNG HC PH THNG CHUYN 2011
MN THI: HA HC
Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu I: (1,5 ) Thi dng kh CO i qua ng s cha 6,1 gam hn hp A gm CuO, Al
2
O
3
v mt oxit ca kim loi R
t nng, ti khi phn ng hon ton th cht rn cn li trong ng c khi lng 4,82 gam. Ton b lng cht rn ny
phn ng va vi 150 ml dung dch HCl 1M. Sau phn ng thy thot ra 1,008 lt kh H
2
(ktc) v cn li 1,28 gam
cht rn khng tan.
(a) Vit cc phng trnh phn ng xy ra.
(b) Xc nh kim loi R v cng thc oxit ca R trong hn hp A.
Cu II: (1,5 ) Ha tan ht 37,725 gam hn hp B gm nhng lng bng nhau v s mol ca NaHCO
3
, KHCO
3
,
CaCl
2
v BaCl
2
vo 130 ml nc ct, sau thm tip 4,65 gam Na
2
O. Khuy u cho cc phn ng xy ra hon ton,
sau lc b kt ta, thu c dung dch C. Hy tnh nng % ca tng cht trong dung dch C. Gi thit rng kt
ta dng khan, cc cht khng b tht thot trong qu trnh th nghim.
Cu III: (1,5 ) t chy hon ton 0,1 mol cht hu c D, sn phm ch gm 4,48 lt kh CO
2
(ktc) v 5,4 gam H
2
O.
Vit cng thc cu to cc cht tha mn tnh cht trn ca D.
Cu IV: (1,5 ) Cht hu c E c to bi ba loi nguyn t v ch cha mt loi nhm chc, trong hidro chim
6,85%, oxi chim 43,84% khi lng ca E. Khi lng mol ca E nh hn 250 gam. Ly 4,38 gam E cho tc dng vi
dung dch NaOH va , sn phm gm ancol v 4,92 gam mui. Tm cng thc phn t v vit cng thc cu to ca
E.
Cu V: (2 ) Dung dch X l dung dch HCl, dung dch Y l dung dch NaOH. Cho 60 ml dung dch X vo cc cha
100 gam dung dch Y, to ra dung dch ch cha mt cht tan. C cn dung dch, thu c 14,175 gam cht rn Z.
Nung Z n khi lng khng i th ch cn li 8,775 gam cht rn.
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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(a) Tnh nng C
M
ca dung dch X v nng C% ca dung dch Y v cng thc ca Z.
(b) Cho 16,4 gam hn hp X
1
gm Al, Fe vo cc ng 840 ml dung dch X. Sau phn ng thm tip 1600 gam dung
dch Y vo cc. Khuy u cho phn ng hon ton, lc kt ta, em nung ngoi khng kh n khi lng khng i,
thu c 13,1 gam cht rn Y
1
. Tm thnh phn % khi lng cc kim loi trong hn hp X
1
.
Cu VI: (2 ) Cho ancol A
1
c khi lng mol 76 gam tc dng vi axit cacboxylic B
1
c cht M mch h. Mi
cht A
1
v B
1
ch cha mt loi nhm chc. Khi t chy hon ton 17,2 gam cht M, cn dng va ht 14,56 lt oxi
(ktc). Sn phm chy ch gm CO
2
v H
2
O theo t l s mol tng ng l 7 : 4. Mt khc c 17,2 gam M phn ng
va ht vi 8 gam NaOH. Bit M c cng thc phn t trng vi cng thc n gin nht. Xc nh cng thc cu to
ca A
1
, M v B
1
.


B GIO DC V O TO CNG HA X HI CH NGHA VIT NAM
TRNG I HC S PHM H NI c lp T do Hnh phc
CHNH THC
THI TUYN SINH
VO TRNG TRUNG HC PH THNG CHUYN NM 2012
Mn thi: HA HC
(Dng cho th sinh thi vo lp chuyn Ha hc)
Thi gian lm bi: 120 pht
Cu 1 (2):
1 . C 4 cht rn mu trng, ring bit dng bt gm: NaCl, Na
2
CO
3
, CaCO
3
, BaSO
4
. Ch c dng thm nc v
kh cacbonic, nu phng php nhn bit 4 cht rn trn.
2 . Cho 0,2 mol CuO tan ht trong dung dch H
2
SO
4
20%, un nng (lng va ) sau lm ngui dung dch n
10
0
C. Tnh khi lng tinh th CuSO
4
. 5H
2
O tch khi dung dch bit rng tan ca CuSO
4
10
0
C l 17,4 gam.
Cu 2 (2):
1 . Khi cho m gam dung dch H
2
SO
4
nng C% tc dng ht vi hn hp Na v Mg (d) thy c 0,05m gam kh H
2

thot ra. Tm gi tr ca nng C.
2 . Hn hp A gm mt ankan v mt anken, t chy hon ton A th thu c a mol CO
2
v b mol H
2
O. Hi t s
a : b c gi tr trong khong no?
Cu 3 (2):
1 . Ha tan m gam oxit ca mt kim loi M c ha tr II bng lng va dung dch H
2
SO
4
20% thu c dung dch
mui c nng 22,64%. Xc nh kim loi M.
2 . Cho X l mt ancol (ru) no, mch h. t chy hon ton a mol X cn dng va ht 3,5a mol oxi. Xc nh
cng thc v gi tn ru X. Vit phng trnh phn ng iu ch ru X t propen (C
3
H
6
), cc cht v c v iu
kin cn thit coi nh c .
Cu 4 (2):
1 . Ha tan hon ton 3,28 gam hn hp A gm Mg v Fe vo dung dch H
2
SO
4
long, d thu c 1,568 lt kh (ktc).
Nu cho hn hp A trn vo mt cc cha 400 ml dung dch CuSO
4
, sau khi phn ng hon ton thu c 4,4 gam cht
rn B. Tnh nng mol/l ca dung dch CuSO
4
.
2 . Hn hp kh X gm hai hidrocacbon mch h c cng thc C
n
H
x
v C
n
H
y
. T khi ca hn hp kh X i vi nit
bng 1,5. Khi t chy hon ton 8,4 gam hn hp kh X th thu c 10,8 gam H
2
O. Xc nh cng thc phn t, vit
cng thc cu to v gi tn hai hidrocacbon.
Cu 5 (2):
1 . Ha tan hon ton 3,28 gam hn hp A gm Al, Fe trong 500 ml dung dch HCl 1M thu c dung dch B. Thm
200 dung dch NaOH 12% vo dung dch B sau em kt ta nung ngoi khng kh n khi lng khng i th
c 1,6 gam cht rn. Tnh thnh phn % theo khi lng cc kim loi c trong hn hp A.
2 . t chy hon ton hp cht hu c X thu c hn hp kh gm CO
2
, hi nc v N
2
. T khi ca hn hp kh ny
so vi hidro l 13,75 trong th tch CO
2
bng 4/7 th tch hi nc, s mol oxi dng t chy bng 1/2 tng s
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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mol CO
2
v H
2
O to thnh. Xc nh cng thc phn t, vit cng thc cu to v gi tn X bit rng khi lng phn
t ca X nh hn 100 vC.


B GIO DC V O TO CNG HA X HI CH NGHA VIT NAM
TRNG I HC S PHM H NI c lp T do Hnh phc

THI TUYN SINH
VO TRNG TRUNG HC PH THNG CHUYN NM 2010
Mn thi: HA HC
(dng cho th sinh thi vo chuyn Ha) Thi gian lm bi : 120 pht
Cu 1.
1. Hy nu hin tng, vit phng trnh phn ng xy ra khi ln lt cho kim loi Ba ti d vo cc dung
dch sau: a. CuSO
4
. b. NaHCO
3
. c. (NH
4
)
2
SO
4
. d. Al(NO
3
)
3
.
2. T vi, mui n, nc v cc iu kin cn thit, hy iu ch:
a. Na
2
CO
3
. b. NaHCO
3
. c. CaCl
2
. d. Nc Gia-ven.

Cu 2.
1. Hy nhn bit cc dung dch v cht lng ng trong cc l mt nhn: dung dch Glucoz, cn 100
o
,
dung dch axit axetic, lng trng trng, benzen.
2. Bit axit Lactic c cng thc: CH
3
-CH(OH)-COOH. Hy vit phng trnh phn ng xy ra khi cho axit
Lactic ln lt tc dng vi cc cht:
a. Na d. b. C
2
H
5
OH (H
2
SO
4c
, un nng nh). c. Dung dch Ba(OH)
2
.

d. Dung dch KHCO
3
.
Cu 3.
1. C mt hn hp rn gm: Al, Fe
2
O
3
, Cu, Al
2
O
3
. Hy trnh by s tch cc cht trn ra khi nhau m
khng lm thay i lng ca mi cht. Vit cc phng trnh phn ng xy ra.
2. Cho cc phn ng : A + 2NaOH 2B + H
2
O
B + HCl D + NaCl
D + C
2
H
5
OH
2 4
o
H SO
t

CH
2
(OH)COOC
2
H
5
+ H
2
O
Hy xc nh cng thc cu to ca cc cht A, B, D. Bit A c cng thc phn t l C
4
H
6
O
5
.
Cu 4.
1. Ha tan hon ton hn hp X gm Fe v Zn bng mt lng va dung dch H
2
SO
4
10%, thu c dung
dch Y v 22,4 lt H
2
(ktc). Nng ca ZnSO
4
trong dung dch Y l 11,6022%. Tnh khi lng ca mi
kim loi trong hn hp X.
2. Cho 5,53 gam mt mui hirocacbonat A vo dung dch H
2
SO
4
long va , sau khi phn ng xy ra hon
ton thu c 4,62 gam mui sunphat trung ho. Cho 15,8 gam A vo dung dch HNO
3
va , ri c cn t
t dung dch sau phn ng th thu c 37,6 gam mui B. Xc nh cng thc phn t ca B.
Cu 5.
1. Thng thng trong cht bo c ln mt lng nh axit bo t do. Bit rng ch s axit ca cht bo l s
mg KOH cn thit trung ho axit bo t do c trong 1 gam cht bo.
a. Mun trung ho 1,12 kg mt loi cht bo c ch s axit l 6 th cn bao nhiu lt dung dch NaOH 0,2M ?
b. x phng ha hon ton 210 kg mt loi cht bo c ch s axit l 8 cn 10,32 kg NaOH. Tnh khi
lng x phng thu c? Bit mui ca cc axit bo chim 50% khi lng ca x phng.
2. Cho 32,8 gam hn hp A gm 2 cht hu c X, Y tc dng va vi 0,2 lt dung dch NaOH 1M thu c
hn hp 2 ru R
1
OH, R
2
OH v 18,8 gam mt mui RCOONa (trong R, R
1
, R
2
ch cha cacbon, hiro v R
2
= R
1
+ 14). Cho ton b 2 ru tc dng vi Na d thu c 6,72 lt H
2
(ktc). Xc nh cng thc cu to ca
2 cht X, Y.

CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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B GIO DC V O TO CNG HA X HI CH NGHA VIT NAM
TRNG I HC S PHM H NI
---------------------------------
c lp T do Hnh phc
----------------------------
CHNH THC
THI TUYN SINH
VO KHI TRUNG HC PH THNG CHUYN 2011
Mn thi: Ha Hc
(dng ring cho th sinh thi vo lp chuyn Ha hc)
Thi gian lm bi 120 pht
Cu I.
1. Ha tan mt oxit st vo dung dch H
2
SO
4
long d, c dung dch X. Dung dch X c kh nng lm
mt mu dung dch nc brom, lm mt mu dung dch thuc tm v ha tan c bt ng.
a. Xc nh cng thc oxit st v vit cc phng trnh phn ng xy ra.
b. Vit cc phng trnh phn ng khi cho oxit st tc dng vi dung dch HNO
3
long (to ra kh NO)
v dung dch H
2
SO
4
c nng.
2. Hn hp gm CuO, Fe
2
O
3
ch dng thm dung dch HCl v bt Al, nu 3 cch tch ly Cu kim loi
t hn hp Y (cc phng tin cn thit c ).
3. Cho BaO vo dung dch H
2
SO
4
(long), sau khi phn ng kt thc thu c kt ta A v dung dch B
(c kh nng to kt ta vi CO
2
). Cho bt Al d vo dung dch B thu c kh E v dung dch D. Ly
dung dch D cho tc dng vi dung dch Na
2
CO
3
thu c kt ta F. Xc nh cng thc A, B, D, E, F.
Vit cc phng trnh phn ng xy ra.
Cu II.
1. Hp cht hu c A (C, H, O) c mch cc bon khng phn nhnh, ch cha mt loi nhm chc trong
phn t, c phn t khi bng 144 vC. Cho 14,4 gam A tc dng vi 100 ml dung dch NaOH 2M va
, thu c hn hp gm mt mui v mt ru vi c im s nguyn t cacbon trong hai gc
hidrocacbon bng nhau.
Xc nh cng thc cu to ca A.
2. Hn hp kh X ( iu kin thng) gm mt ankan A (C
m
H
2m+2
) v mt anken B (C
n
H
2n
). T khi hi
ca anken so vi ankan l 2,625.
a. Tm cng thc ca hai hidrocacbon.
b. Vit cc phng trnh phn ng iu ch A t B, c dng thm cc cht v c v iu kin cn thit.
Cu III.
1. Mt hn hp A gm Na v Al.
- Cho m gam A vo mt lng d H
2
O thu c 1,344 lt kh, dung dch B v phn khng tan C.
- Cho 2m gam A tc dng vi dung dch NaOH d thu c 20,832 lt kh. Cc phn ng u xy ra hon
ton, cc th tch kh o iu kin tiu chun.
a. Tnh khi lng tng kim loi trong m gam A.
b. Cho 50 ml dung dch HCl vo dung dch B. Sau khi phn ng kt thc, thu c 0,78 gam kt ta. Xc
nh nng mol/lt ca dung dch HCl.
2. Trn CuO vi oxit kim loi M (ha tr II khng i) theo t l s mol 1:2 c hn hp A. Cho mt
lung kh CO nng (d) i qua 1,2g A n phn ng hon ton, thu c cht rn B. Ha tan ht B cn
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 4 5

50ml dung dch HNO
3
1M, thu c dung dch C ch cha mui ca 2 kim loi v V lt kh NO duy nht
( ktc).
Xc nh kim loi M v tnh V.
Cu IV.
1. Cho 728 ml hn hp A gm 2 hirocacbon mch h th kh i qua dung dch nc Br
2
d n khi
phn ng xy ra hon ton thy c 2g Br
2
phn ng v thu c 448 ml kh ktc. Nu t chy hon
ton 1456 ml hn hp A sau cho sn phm chy vo 500g dung dch Ca(OH)
2
x% thu c 7,5 g kt
ta. Lc tch kt ta, un nng phn nc lc thu c ti a l 4 g kt ta na. Bit th tch cc kh o
iu kin tiu chun, cc phn ng xy ra hon ton.
Tm x v xc nh cng thc phn t ca 2 hirocacbon trong hn hp A.
2. t chy hon ton 27,4 cm
3
hn hp kh B gm CH
4
, C
3
H
8
v CO thu c 51,4 cm
3
CO
2
.
a. Tnh thnh phn % v th tch ca propan trong hn hp B.
b. Hi 1 lt hn hp B nng hay nh hn 1 lt N
2
?
(Cc kh c o cng iu kin nhit , p sut)

S gio dc v o to
NAM NH
K THI VO LP 10 THPT CHUYN L HNG PHONG
n m h c: 2010 2011

chnh thc
Mn: Ha hc
(Dnh cho th sinh thi vo lp chuyn Ha)
thi gm c: 02 trang Thi gian lm bi: 120 pht (khng kthi gi an gi ao )
Ngy thi: 20 th ng 6 n m 2010
Cu I: (3,0 im)
1. Cho ln lt tng cht: Fe, BaO, Al
2
O
3
v KOH vo ln lt cc dung dch: NaHSO
4
, CuSO
4
. Hy vit
cc phng trnh phn ng xy ra.
2. Mt hn hp gm Al, Fe, Cu v Ag. Bng phng php ho hc hy tch ri hon ton cc kim loi ra
khi hn hp trn.
3. C 5 l mt nhn ng 5 dung dch: NaOH, KCl, MgCl
2
, CuCl
2
, AlCl
3
. Hy nhn bit tng dung dch
trn m khng dng thm ho cht khc. Vit cc phng trnh phn ng xy ra.
Cu II: (2,0 im)
1. Hirocacbon X l cht kh ( nhit phng, 25
0
C). Nhit phn hon ton X (trong iu kin khng c
oxi) thu c sn phm C v H
2
, trong th tch kh H
2
thu c gp i th tch kh X (o cng iu
kin). Xc nh cc cng thc phn t tha mn X.
2. Ba cht hu c mch h A, B, C c cng thc phn t tng ng l: C
3
H
6
O, C
3
H
4
O
2
, C
6
H
8
O
2
. Chng
c nhng tnh cht sau:
- Ch A v B tc dng vi Na gii phng kh H
2
.
- Ch B v C tc dng c vi dung dch NaOH.
- A tc dng vi B (trong iu kin xc tc, nhit thch hp) thu c sn phm l cht C.
Hy cho bit cng thc cu to ca A, B, C. Vit cc phng trnh phn ng xy ra.
3. Metan b ln mt t tp cht l CO
2
, C
2
H
4
, C
2
H
2
. Trnh by phng php ho hc loi ht tp cht
khi metan.
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Cu III: (3,0 im)
1. Ha tan hon ton 0,297 gam hn hp Natri v mt kim loi thuc nhm II
A
trong bng tun hon cc
nguyn t ha hc vo nc. Ta c dung dch X v 56 ml kh Y (ktc). Xc nh kim loi thuc nhm II
A

v khi lng ca mi kim loi trong hn hp.
2. Hn hp X gm ba kim loi Al, Fe, Cu. Cho m gam hn hp X vo dung dch CuSO
4
(d) sau khi phn ng
xy ra hon ton thu c 35,2 gam kim loi. Nu cng ha tan m gam hn hp X vo 500 ml dung dch HCl
2M n khi phn ng xy ra hon ton thu c 8,96 lt kh H
2
(ktc), dung dch Y v a gam cht rn.
a. Vit cc phng trnh phn ng xy ra v tm gi tr ca a.
b. Cho t t dung dch NaOH 2M vo dung dch Y v khuy u n khi thy bt u xut hin kt ta th
dng ht V
1
lt dung dch NaOH 2M, tip tc cho tip dung dch NaOH vo n khi lng kt ta khng c s
thay i na th lng dung dch NaOH 2M dng ht 600 ml. Tm cc gi tr m v V
1
.
Cu IV: (2,0 im)
1. T tinh bt, cc ha cht v c v iu kin cn thit khc c . Vit phng trnh ha hc iu ch
Etyl axetat ( ghi r iu kin nu c).
2. C a gam hn hp X gm mt axit no n chc A v mt este B. B to ra bi mt axit no n chc A
1

v mt ru no n chc C (A
1
l ng ng k tip ca A). Cho a gam hn hp X tc dng vi lng
va NaHCO
3
, thu c 1,92 gam mui. Nu cho a gam hn hp X tc dng vi mt lng va
NaOH un nng thu c 4,38 gam hn hp hai mui ca 2 axit A, A
1
v 1,38 gam ru C, t khi hi
ca C so vi hiro l 23. t chy hon ton 4,38 gam hn hp hai mui ca A, A
1
bng mt lng oxi
d th thu c Na
2
CO
3
, hi nc v 2,128 lit CO
2
(ktc). Gi thit phn ng xy ra hon ton.
a. Tm cng thc phn t, cng thc cu to ca A, A
1
, C, B.
b. Tnh a.

S GIO DC V O TO
TUYN QUANG
K THI TUYN SINH VO LP 10 THPT CHUYN
NM HC 2011-2012

chnh thc
Mn: HO HC
Thi gian: 120 pht (khng k thi gian giao )

Cu 1(3,0 im)
1. Vit cc phng trnh phn ng thc hin dy bin ha ha hc sau:
FeFeCl
2
FeSO
4
Fe
2
(SO
4
)
3
Fe(NO
3
)
3
Fe(NO
3
)
2
Fe(OH)
2
Fe(OH)
3
Fe
2
O
3

2. Ch c dng thm qu tm v cc ng nghim, hy ch r phng php nhn ra cc dung dch
b mt nhn sau: NaHSO
4
, Na
2
CO
3
, Na
2
SO
3
, BaCl
2
, Na
2
S.
3. C th tn ti ng thi trong dung dch cc cp cht sau y khng? Gii thch v vit phng
trnh phn ng (nu c).
a) CaCl
2
v Na
2
CO
3
; b) NaOH v NH
4
Cl ; c) Na
2
SO
4
v KCl;
d) HCl v NaHSO
3
; e) NaOH v KNO
3

Cu 2: (2,5 im)
1.T vi, than v cc cht v c cn thit, hy vit cc phng trnh phn ng iu ch
benzen, cao su buna (ghi r iu kin phn ng nu c).
2. t hn hp gm cacbon v lu hunh trong kh oxi d, thu c hn hp kh A. Cho kh A li
qua dung dch NaOH thu c dung dch B v kh C. Cho kh C qua hn hp cha CuO v MgO nung nng
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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thu c cht rn D v kh E. Cho kh E li qua dung dch Ca(OH)
2
thu c kt ta F v dung dch G. Thm
dung dch KOH vo dung dch G li thy kt ta F xut hin, un nng G cng thy xut hin kt ta F.
Hy xc nh thnh phn A, B, C, D, E, G, F v vit cc phng trnh phn ng xy ra.
Cu 3: (2,5 im)
Ho tan hon ton 5,94 gam Al vo dung dch NaOH d c kh th nht. Cho 1,896 gam
KMnO
4
tc dng ht vi axit HCl c, d c kh th hai. Nhit phn hon ton 12,25 gam KClO
3
c
xc tc, thu c kh th ba.
Cho ton b lng cc kh iu ch trn vo mt bnh kn ri t chy cc phn ng xy ra
hon ton. Sau lm lnh bnh cho hi nc ngng t ht v gi thit cc cht tan ht vo nc thu
c dung dch E.
Vit cc phng trnh phn ng v tnh nng C% ca dung dch E.
Cu 4: (2,0 im)
Hn hp A gm C
2
H
2
v H
2
. Cho 10,08 lt A i qua ng ng cht xc tc Ni un nng, thu c
6,944 lt hn hp kh B gm 4 cht. Dn B i chm qua bnh ng nc brom d cho phn ng xy ra
hon ton, thu c 4,48 lt hn hp kh C. Bit rng 1mol A c khi lng 10 gam v cc th tch kh
u o iu kin tiu chun.
Hy vit cc phng trnh phn xy ra v tnh thnh phn phn trm theo th tch ca cc kh
trong hn hp A, B, C.


S GIO DC V O TO K THI TUYN SINH VO LP 10 THPT CHUYN
TUYN QUANG NM HC 2010-2011
Mn: Ho hc
chnh thc
Thi gian: 120 pht (khng k thi gian giao ) (
thi ny c 1 trang)
Cu 1:(3,0 im)
1. Vit cc phng trnh phn ng thc hin dy bin ha ha hc sau:

FeS
2
SO
2
S

SO
2

H
2
SO
4
CuSO
4

CuS.
2. t chy hon ton 0,1 mol mt hidrocacbon, ri cho ton b sn phm chy hp th vo bnh ng
lng d dung dch NaOH thy khi lng ca bnh NaOH tng thm 23 gam. Xc nh cng thc phn
t ca hidrocacbon v vit cng thc cu to rt gn dng mch h c th c ca hidrocacbon trn.
3. Xc nh cng thc ha hc ca hp cht XH
3
. Bit rng trong hp cht oxit ca X ha tr V c cha
56,34% oxi theo khi lng.
Cu 2: (3,0 im)
1. T vi v cc thit b, ha cht cn thit hy vit cc phng trnh phn ng iu ch cc cht sau:
cao su buna, polietilen, este etylaxetat (ghi r iu kin phn ng nu c).
2. C 6 dung dch sau ng ring bit trong cc l mt nhn: Ba(OH)
2
, BaCl
2
, NaCl, HCl, NH
4
HSO
4,
H
2
SO
4
. Ch dng thm mt thuc th, hy trnh by phng php ha hc nhn bit cc dung dch
trn. Vit cc phng trnh phn ng xy ra.
Cu 3: (2,0 im)
Nhng mt thanh kim loi st v mt thanh kim loi km vo cng mt cc cha 800 ml dung dch
CuSO
4
. Sau mt thi gian ly hai thanh kim loi ra khi cc th thy mi thanh kim loi u c mt lng
Cu bm vo, khi lng dung dch trong cc gim mt lng l 0,75 gam. Trong dung dch sau phn ng,
nng mol/l ca ZnSO
4
gp hai ln nng mol/l ca FeSO
4
. Thm dung dch NaOH d vo cc, lc
ly kt ta em nung ngoi khng kh n khi lng khng i, thu c 20 gam cht rn.
1. Tnh s gam Cu bm trn mi thanh kim loi.
2. Xc nh nng mol/l ca dung dch CuSO
4
ban u.
Cu 4: (2,0 im)
Khi thc hin phn ng crackinh 35 lt butan nhit v p sut thch hp thu c 67 lt hn hp kh
X theo 3 phn ng:
C
4
H
10

CH
4
+ C
3
H
6

(1)

CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 4 8

C
4
H
10
C
2
H
6
+ C
2
H
4 (2)

C
4
H
10

H
2
+ C
4
H
8
(3)
Chia hn hp X lm 2 phn bng nhau
Phn 1: Cho t t qua bnh ng nc brom d, cn li hn hp kh B khng b hp th. Tch hn hp
kh B c 3 hidrocacbon B
1
,

B
2
, B
3
theo th t khi lng phn t tng dn. t chy B
1
,

B
2
, B
3
thu
c nhng sn phm c th tch CO
2
t l tng ng l 1:3:1.
Phn 2: Cho phn ng hp nc nh xc tc c bit thu c hn hp A gm cc ru khc nhau.
1. Tnh t l % th tch butan tham gia phn ng.
2. Tnh t l % th tch mi kh trong hn hp X.
3. Tnh khi lng ca hn hp A. (gi thit cc phn ng vi brom v hp nc xy ra hon ton, cc
th tch kh o iu kin tiu chun).


S GD&T VNH PHC


K THI VO LP 10 THPT CHUYN NM HC 2009-2010
THI MN: HO HC
Dnh cho cc th sinh thi vo lp chuyn Ho
Thi gian lm bi: 120 pht, khng k thi gian giao

( thi c 01 trang)
Cu 1.(2,5 im)
1. Mt hn hp X gm cc cht: K
2
O, KHCO
3
, NH
4
Cl, BaCl
2
c s mol mi cht bng nhau. Ho
tan hn hp X vo nc, ri un nh thu c kh Y, dung dch Z v kt ta M. Xc nh cc cht trong
Y, Z, M v vit phng trnh phn ng minh ha.
2. Cho s bin ha :
A
A
A
+X,t
0
+Y,t
0
+Z,t
0
Fe
+G
D
+E
G

Bit rng A + HCl D + G + H
2
O . Tm cc cht ng vi cc ch ci A, Bv vit cc phng trnh
ha hc.
Cu 2. (2,0 im)
1. Ha tan 3,38 gam oleum X vo lng nc d ta c dung dch A. trung ha
1
20
lng
dung dch A cn dng 40 ml dung dch NaOH 0,1 M . Tm cng thc ca oleum.
2. Ch c dng thm 1 thuc th v cc ng nghim, hy trnh by phng php ha hc nhn
ra cc dung dch b mt nhn NaHSO
4
, Na
2
CO
3
, NaCl, BaCl
2
, Na
2
S.
Cu 3. (1,5 im)
1. Polime X cha 38,4% cacbon; 56,8% clo v cn li l hydro v khi lng. Xc nh cng thc phn t,
vit cng thc cu to ca X v gi tn, cho bit trong thc t X dng lm g?
2. T metan v cc cht v c cn thit khc. Hy vit cc phng trnh phn ng ho hc (ghi r
iu kin) iu ch X ni trn.
Cu 4.(2 im)
Cho 6,72 lt hn hp kh gm mt ankan v mt olefin i qua dung dch Brom thy khi lng
bnh Brom tng 4,2 gam v thot ra 4,48 lt kh. t chy kh thot ra thu c 8,96 lt kh CO
2
. Xc nh
cng thc phn t ca cc hirocacbon, bit th tch cc kh o ktc.
Cu 5. (2 im)
Ha tan hon ton 9,18 gam Al nguyn cht cn V lt dung dch axit HNO
3
, nng 0,25M, thu
c mt kh X v mt dung dch mui Y. Bit trong X s nguyn t ca nguyn t c s thay i s
oxiha l 0,3612.10
23
(s Avogadro l 6,02.10
23
). phn ng hon ton vi dung dch Y to ra mt
dung dch trong sut cn 290 gam dung dch NaOH 20%.
1. Xc nh kh X v vit cc phng trnh phn ng xy ra?
CHNH THC
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 4 9

2. Tnh V?
S GIO DC & O TO K THI TUYN SINH LP 10 THPT CHUYN NGUYN TRI
HI DNG Nm hc: 2012 2013
Mn thi: HA HC
CHNH THC Kha ngy thi: 20 thng 6 nm 2012
Thi gian lm bi: 120 pht (Khng k thi gian pht )
Cu 1 (2 ):
1 . Cho hn hp gm Al
2
O
3
, Cu, Fe
2
O
3
vo dung dch H
2
SO
4
long d thu c dung dch X v cht rn Y. Cho
t t dung dch NaOH ti d vo dung dch X thu c dung dch Z v kt ta M. Nung kt ta M ngoi khng
kh n khi lng khng i thu c cht rn N. Cho kh H
2
d i qua N nung nng thu c cht rn P. Sc
kh CO
2
ti d vo dung dch Z thu c kt ta Q.
a . Xc nh thnh phn cc cht c trong X, Y, Z, M, N, P, Q. Bit cc phn ng xy ra hon ton.
b . Vit cc phng trnh phn ng xy ra.
2 . Cho hn hp kim loi Mg, Fe vo dung dch cha hn hp mui Cu(NO
3
)
2
, AgNO
3
. Phn ng xy ra hon
ton, thu c hn hp cht rn A gm 3 kim loi v dung dch B cha 2 mui. Trnh by phng php tch
ring tng kim loi ra khi hn hp A. Vit phng trnh ha hc.
Cu 2 (2 ):
Cho 2 hp cht hu c X, Y (cha C, H, O) ch cha mt loi nhm chc hc v c khi lng mol phn
t u bng 46 gam.
1 . Xc nh cng thc cu to ca X, Y. Bit X,Y u phn ng vi Na, dung dch ca Y lm qu tm ha .
2 . T X vit cc phng trnh ha hc iu ch poli(vinyl clorua), polietilen.
Cu 3 (2 ):
1 . Hy chn cc cht thch hp v vit cc phng trnh phn ng hon thnh s bin ha sau:
+ (X) + (X) + .... Cho bit:
(A) (B) (D) (P) Cc cht A, B, D l hp cht ca Na;
+ (Y) Cc cht M v N l hp cht ca Al;
+(X) +... + (Y) Cc cht P, Q, R l hp cht ca Ba;
(M) (N) (Q) (R) Cc cht N, Q, R khng tan trong nc.
-X l cht kh khng mi, lm c dung dch nc vi trong;
-Y l mui Na, dung dch Y lm qu tm.
2 . T 9 kg tinh bt c th iu ch c bao nhiu lt ru (ancol) etylic 46
0
. Bit hiu sut ca c qu trnh iu
ch l 72%, khi lng ring ca ru etylic nguyn cht l 0,8 g/ml.
Cu 4 (2 ):
Nung 9,28 gam hn hp A gm FeCO
3
v mt oxit st trong khng kh n khi lng khng i. Sau khi
phn ng xy ra hon ton, thu c 8 gam mt oxit st duy nht v kh CO
2
. Hp th ht lng kh CO
2
vo
300 ml dung dch Ba(OH)
2
0,1M, kt thc phn ng thu c 3,94 gam kt ta.
1 . Tm cng thc ha hc ca oxit st.
2 . Cho 9,28 gam hn hp A tc dng vi dung dch HCl d, sau khi phn ng kt thc thu c dung dch B.
Dn 448 ml kh Cl
2
(ktc) vo B thu c dung dch D. Hi D ha tan ti a bao nhiu gam Cu ?
Cu 5 (2 ):
Thy phn hon ton 19 gam hp cht hu c A (mch h, phn ng c vi Na) thu c m
1
gam cht B v
m
2
gam cht D cha hai loi nhm chc.
-t chy m
1
gam cht B cn 9,6 gam oxi thu c 4,48 lt CO
2
v 5,4 gam nc.
-t chy m
2
gam cht D cn 19,2 gam oxi thu c 13,44 lt CO
2
v 10,8 gam nc.
1 . Tm cng thc phn t ca A, B, D.
2 . Xc nh cng thc cu to ca A, B, D.
Bit th tch cc kh c o ktc.


CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

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S GIO DC V O TO

K THI VO LP 10 THPT CHUYN LAM SN
NM HC: 2010 2011

chnh thc

Mn: Ha hc
(Dnh cho th sinh thi vo lp chuyn Ha)
thi gm c: 02 trang Thi gian lm bi: 120 pht (khng k thi gian giao )
Ngy thi: 20 thng 6 nm 2010
Cu I: (3,0 im)
1. Cho ln lt tng cht: Fe, BaO, Al
2
O
3
v KOH vo ln lt cc dung dch: NaHSO
4
, CuSO
4
. Hy vit cc
phng trnh phn ng xy ra.
2. Mt hn hp gm Al, Fe, Cu v Ag. Bng phng php ho hc hy tch ri hon ton cc kim loi ra khi
hn hp trn.
3. C 5 l mt nhn ng 5 dung dch: NaOH, KCl, MgCl
2
, CuCl
2
, AlCl
3
. Hy nhn bit tng dung dch trn
m khng dng thm ho cht khc. Vit cc phng trnh phn ng xy ra.
Cu II: (2,0 im)
1. Hirocacbon X l cht kh ( nhit phng, 25
0
C). Nhit phn hon ton X (trong iu kin khng c oxi)
thu c sn phm C v H
2
, trong th tch kh H
2
thu c gp i th tch kh X (o cng iu kin).
Xc nh cc cng thc phn t tha mn X.
2. Ba cht hu c mch h A, B, C c cng thc phn t tng ng l: C
3
H
6
O, C
3
H
4
O
2
, C
6
H
8
O
2
. Chng c
nhng tnh cht sau:
- Ch A v B tc dng vi Na gii phng kh H
2
.
- Ch B v C tc dng c vi dung dch NaOH.
- A tc dng vi B (trong iu kin xc tc, nhit thch hp) thu c sn phm l cht C.
Hy cho bit cng thc cu to ca A, B, C. Vit cc phng trnh phn ng xy ra.
3. Metan b ln mt t tp cht l CO
2
, C
2
H
4
, C
2
H
2
. Trnh by phng php ho hc loi ht tp cht khi
metan.
Cu III: (3,0 im)
1. Ha tan hon ton 0,297 gam hn hp Natri v mt kim loi thuc nhm II
A
trong bng tun hon cc nguyn t
ha hc vo nc. Ta c dung dch X v 56 ml kh Y (ktc). Xc nh kim loi thuc nhm II
A
v khi lng ca
mi kim loi trong hn hp.
2. Hn hp X gm ba kim loi Al, Fe, Cu.
Cho m gam hn hp X vo dung dch CuSO
4
(d) sau khi phn ng xy ra hon ton thu c 35,2 gam kim loi.
Nu cng ha tan m gam hn hp X vo 500 ml dung dch HCl 2M n khi phn ng xy ra hon ton thu c
8,96 lt kh H
2
(ktc), dung dch Y v a gam cht rn.
a. Vit cc phng trnh phn ng xy ra v tm gi tr ca a.
b. Cho t t dung dch NaOH 2M vo dung dch Y v khuy u n khi thy bt u xut hin kt ta th dng ht
V
1
lt dung dch NaOH 2M, tip tc cho tip dung dch NaOH vo n khi lng kt ta khng c s thay i na
th lng dung dch NaOH 2M dng ht 600 ml. Tm cc gi tr m v V
1
.
Cu IV: (2,0 im)
1. T tinh bt, cc ha cht v c v iu kin cn thit khc c . Vit phng trnh ha hc iu ch Etyl
axetat ( ghi r iu kin nu c).
2. C a gam hn hp X gm mt axit no n chc A v mt este B. B to ra bi mt axit no n chc A
1
v
mt ru no n chc C (A
1
l ng ng k tip ca A). Cho a gam hn hp X tc dng vi lng va
NaHCO
3
, thu c 1,92 gam mui. Nu cho a gam hn hp X tc dng vi mt lng va NaOH un nng
thu c 4,38 gam hn hp hai mui ca 2 axit A, A
1
v 1,38 gam ru C, t khi hi ca C so vi hiro l
23. t chy hon ton 4,38 gam hn hp hai mui ca A, A
1
bng mt lng oxi d th thu c Na
2
CO
3
, hi
nc v 2,128 lit CO
2
(ktc). Gi thit phn ng xy ra hon ton.
a. Tm cng thc phn t, cng thc cu to ca A, A
1
, C, B.
b. Tnh a.


S GIO DC&O TO THI TUYN SINH LP 10 THPT CHUYN L QU N
QUNG TR MN THI: HO HC
Kho ngy: 07/7/2008
Thi gian lm bi: 150 pht (Khng k thi gian giao )

CHNH THC
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 5 1

Cu I (2,0 im)
1. Hy vit cc phng trnh phn ng (c bn cht khc nhau) iu ch mui.
2. Ch dng thm mt cht, hy nhn bit 5 cht rn Al, FeO, BaO, ZnO, Al
4
C
3
ng trong cc l
ring bit. Vit cc phng trnh phn ng xy ra.
3. Cho hai dung dch long FeCl
2
v FeCl
3
(gn nh khng mu). C th dng cht no sau y: dung
dch NaOH; nc brom; Cu; hn hp dung dch (KMnO
4
, H
2
SO
4
) nhn bit hai dung dch trn? Vit cc
phng trnh phn ng xy ra.
Cu II (2,5 im)
1.a.Vit cc cng thc cu to c th c ng vi cc cng thc phn t sau: C
5
H
10
, C
3
H
5
Cl
3
.
b. un nng glixerol vi hn hp hai axit C
15
H
31
COOH v C
17
H
35
COOH (c H
2
SO
4
m c lm
cht xc tc) to thnh hn hp cc este. Hy vit cc cng thc cu to c th c ca cc este.
2. Vit cc phng trnh phn ng hon thnh s sau:


A B


Trong A l hp cht hu c; F l bari sunfat.
3. Ho tan hon ton hn hp X gm a mol Cu
2
S ; 0,05 mol FeS
2
trong HNO
3
long, va thu c
dung dch Y(ch c mui sunfat) v kh NO. Cho dung dch Ba(OH)
2
d vo dung dch Y s thu c bao
nhiu gam kt ta?
Cu III (2,0 im)
1. Hy gii thch cc trng hp sau v vit cc phng trnh phn ng:
a. Kh CO
2
dng dp tt a s cc m chy, nhng khng dng dp tt m chy Mg.
b. Trong phng th nghim ngi ta ng axit flohiric trong bnh bng nha hay thu tinh? V sao?
2. Khi nung hon ton cht A th thu c cht rn B mu trng v kh C khng mu. Cht B phn
ng mnh lit vi nc to thnh dung dch D lm phenolphtalein. Kh C lm vn c dung dch D. Khi
cho B tc dng vi cacbon nhit cao th thu c cht E v gii phng kh F. Cho E phn ng vi nc
th thu c kh khng mu G. Kh G chy cho nc v kh C. Xc nh cc cht A, B, C, D, E, F, G v vit
cc phng trnh phn ng xy ra.
3. Cho 2 bnh kn A, B c cng th tch v u 0
0
C. Bnh A cha 1 mol kh clo; bnh B cha 1 mol
kh oxi. Cho vo mi bnh 2,4 gam kim loi M c ho tr khng i. Nung nng cc bnh cc phn ng xy
ra hon ton ri a v nhit ban u. Sau phn ng thy t l p sut kh trong 2 bnh A v B l
9 , 1
8 , 1
(th
tch cc cht rn khng ng k). Hy xc nh kim loi M.
Cu IV(1,5 im)
1. Ho tan hon ton mt ming bc kim loi vo mt lng d dung dch HNO
3
15,75% thu c kh
NO duy nht v a gam dung dch X; trong nng C% ca AgNO
3
bng nng C% ca HNO
3
d. Thm
a gam dung dch HCl 1,46% vo dung dch X. Hy xc nh % AgNO
3
tc dng vi HCl.
2. Dn H
2
n d i qua 25,6 gam hn hp X gm Fe
3
O
4
, MgO, CuO nung nng cho n khi phn
ng xy ra hon ton. Sau phn ng thu c 20,8 gam cht rn. Mt khc 0,15 mol hn hp X tc dng va
vi 225ml dung dch HCl 2M. Hy vit cc phng trnh phn ng xy ra v tnh % s mol ca mi cht
trong hn hp X.
Cu V(2,0 im)
t chy mt hirocacbon X th kh vi 0,96 gam kh oxi trong bnh kn ri cho cc sn phm sau
phn ng ln lt qua bnh (1) cha CaCl
2
khan d; bnh (2) cha 1,75 lt Ca(OH)
2
0,01M. Sau th nghim
thy bnh (2) thu c 1,5 gam kt ta v cui cng cn 0,112 lt kh duy nht thot ra (o ktc). Xc nh
cng thc phn t ca hirocacbon X. Bit cc phn ng xy ra hon ton.
Cho C= 12, H=1, O= 16, Ca= 40, Cl=35,5; N= 14

S GIO DC & O TO K THI TUYN SINH VO LP 10 THPT QUC HC
THA THIN HU KHA NGY 19.06.2006
MN: HO HC (Chuyn)
CHNH THC (Thi gian lm bi: 150 pht )
+X, xt men
C
G
D
H
E
I
F
F
+ Y1
+ Y2
+ Z1
+ Z2
+ T1
+ T2
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 5 2

S bo danh: .........Phng: ......
Cu 1: (2 im)
a. T tinh bt v cc cht v c cn thit khc, hy vit cc phng trnh phn ng ha hc iu ch:
Etyl axetat, ibrometan.
b. t chy 2,7gam hp cht A cha C,H,O cn dng ht 3,696 lt oxi (ktc), thu c CO
2
v hi nc
theo t l
2 2
H O CO
V : V 5 : 4 = Tm cng thc phn t ca A. Bit t khi hi ca A so vi N
2
l 3,215.
Cu 2: (1,5 im)
C 3 l b mt nhn cha cc dung dch:
- L X gm K
2
CO
3
v NaHCO
3

- L Y gm KHCO
3
v Na
2
SO
4

- L Z gm Na
2
CO
3
v K
2
SO
4

Ch c dng dung dch BaCl
2
v dung dch HCl. Nu cch nhn bit cc l v vit cc phng trnh
phn ng ha hc minh ha.
Cu 3: (2,25 im)
1. C 2 dung dch H
2
SO
4
v NaOH. Bit rng 20ml dung dch H
2
SO
4
tc dng va vi 60ml dung dch
NaOH. Mt khc cho 20ml dung dch H
2
SO
4
trn tc dng vi 5,91gam BaCO
3
, trung ha lng H
2
SO
4
d
sau phn ng ta cn 10ml dung dch NaOH ni trn. Tnh nng mol/l ca hai dung dch .
2. Ha tan mt mui cacbonat kim loi M bng mt lng va dung dch H
2
SO
4
9,8% ta thu c dung
dch mui c C% = 14,18%. Xc nh cng thc mui cacbonat .
Cu 4: (2 im)
t chy hon ton 2,24 lt mt hydrocacbon A th kh (ktc). Sn phm chy thu c sau phn ng
cho qua bnh ng 400 ml dung dch Ca(OH)
2
0,5M thy khi lng bnh tng 18,6 gam v c 10 gam kt ta.
Xc nh cng thc phn t, cng thc cu to c th c ca A.
Cu 5: (2,25 im)
Hn hp X gm CaCO
3
, MgCO
3
v Al
2
O
3
, trong khi lng ca Al
2
O
3
bng 1/10 khi lng cc mui
cacbonat. Nung X nhit cao n khi lng khng i thu c cht rn Y c khi lng bng 56,80%
khi lng hn hp X.
a. Tnh phn trm khi lng mi cht trong X.
b. Ha tan cht rn thu c sau khi nung 22,44 gam X trn bng dung dch HCl 1,6M. Hy xc nh th
tch dung dch HCl dng.

Cho: Al = 27 ; Mg = 24; Ca = 40 ; Ba = 137 O = 16 ; Cl = 35,5 ; S = 32 ; C = 12 ; H = 1 .



S GIO DC V O TO
TNH PH YN

THI TUYN SINH TRUNG HC PH THNG CHUYN
NM HC 2008-2009
Mn thi: HA HC
Thi gian: 150 pht (khng k thi gian pht )


CU 1:(3,0 im) Cho s bin ho :





Tm cng thc cc cht A
1
, A
2
, A
3
, B
1
, B
2
, B
3
, X, Y, Z, T . Vit cc phng trnh phn ng .
CU 2:(2,5 im)
C 5 dung dch: HCl ; NaOH; Na
2
CO
3
; BaCl
2;
NaCl. Cho php dng qu tm hy trnh by cch nhn
bit cc dung dch trn, bit rng dung dch Na
2
CO
3
cng lm qu tm ho xanh.
CU 3:(2,5 im)
Vit phng trnh phn ng xy ra (nu c) khi cho cc cht Al, Fe
3
O
4
, Al
2
O
3
ln lt tc dng vi
cc dung dch H
2
SO
4
long, dung dch KOH .
+X +Y
B
1
B
2
B
3
Fe(OH)
3

A
1
+Z
A
2
+T
A
3
t
o
Fe(OH)
3

CHNH THC
CHUYN THI VO KHI CHUYN HA-BI DNG HC SINH GII

NGUYN ANH T: 0979.879.702 5 3

CU 4:(2,0 im)
t chy hon ton V (lt) m tan (ktc). Cho tt c sn phm chy hp th vo bnh ng 500ml
dung dch Ba(OH)
2
0,2 M thy to thnh 15,76 gam kt ta .
a) Tnh th tch V.
b) Khi lng dung dch trong bnh tng hay gim bao nhiu gam?
CU 5:(2,0 im)
Ho tan ht 4 gam mt kim loi M vo 96,2 gam nc thu c dung dch baz c nng 7,4% v V
lt kh (ktc).Xc nh kim loi M.
CU 6:(2,0 im)
Cho 23,8 gam hn hp X (Cu, Fe, Al) tc dng va 14,56 lt kh Cl
2
( ktc). Mt khc c 0,25 Mol
hn hp tc dng vi dung dch HCl d thu c 0,2 Mol kh ( ktc). Tnh phn trm khi lng mi kim loi
trong hn hp X.
CU7:(2,0 im)
Chia 39,6 gam hn hp ru etylic v ru A c cng thc C
n
H
2n
(OH)
2
thnh hai phn bng nhau.
Ly phn th nht tc dng ht vi Na thu c 5,6 lt H
2
(ktc). t chy ht hon ton phn th hai thu
c 17,92 lt CO
2
( ktc). Tm cng thc phn t ru A.
CU 8:(2,0 im)
Ho tan 4 gam hn hp Fe v mt kim loi ho tr 2 vo dung dch HCl d thu c 2,24 lt kh H
2

(ktc). Nu ch dng 2,4 gam kim loi ho tr 2 cho vo dung dch HCl th dng khng ht 500ml dung dch
HCl 1M. Tm kim loi ho tr 2 .
CU 9:(2,0im)
t chy hon ton 0,324 gam hp cht hu c X (C, H, O )sn phm chy dn qua bnh cha 380 ml
dung dch Ba (OH)
2
0,05 M ta thy kt ta b tan mt phn ng thi khi lng bnh tng 1,14 gam. Cn nu
sn phm chy dn qua 220 ml dung dch Ba(OH)
2
0,1M th thu kt ta cc i.
Tm cng thc phn t ca X, bit M
X
= 108 .
Cho : C = 12, Ba = 137, H = 1, Fe = 56, Cl = 35.5 , Al = 27, Cu = 64

Y BAN NHN DN TNH KON TUM K THI TUYN SINH VO LP 10
S GIO DC V O TO NM HC 2012 2013
Mn thi: HA HC (chuyn)
CHNH THC Ngy thi: 07 / 07 / 2012
thi ny c 2 trang Thi gian: 120 pht (Khng k thi gian pht )


Cu I ( 3 ):
1 . Khng cn lp lun, hy xc nh cc cht A, B, C, D ri hon thnh phng trnh ha hc theo s
sau:
a . FeS
2
+ O
2
(A) | + ...
b . (A) + O
2
(B)
c . (B) + ... (C) + + HCl
d . Cu + ... (A) | + ...
e . CuSO
4
+ ... (D) + ...
g . (D) + BaCl
2
(C) + + ...
2 . Cho cc cht sau: ru etylic, axit axetic, saccaroz, benzene, glucoz.
Cht no phn ng vi: nc, Ag
2
O trong NH
3
, axit axetic, CaCO
3
, Cl
2
(khi c nh sng to thnh mt
sn phm duy nht).
Vit cc phng trnh ha hc ca cc phn ng xy ra (iu kin phn ng, cht xc tc c ).
Cu II (2 ):
1 . Ch c dng thm nc lm thuc th, hy nhn bit cc cht rn khan mu trng c cha trong
cc bnh ring bit mt nhn sau: NaOH, CuSO
4
, Ba, Ag, Mg(NO
3
)
2
.
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2 . Tch tng cht ra khi hn hp gm: Fe(OH)
2
, K
2
SO
4
, SiO
2
.
Cu III (2 ):
1 . Hn hp A gm ru etylic, axit axetic v etyl axetat. Chia 7,84 gam A thnh hai phn bng nhau:
- Phn 1: tc dng ht vi Na thy thot ra 0,672 lt kh (ktc).
- Phn 2: tc dng va vi 300 ml dung dch NaOH 0,1M.
Tnh khi lng v % khi lng tng cht trong A. Cc phn ng xy ra hon ton.
2 . Hn hp X gm 2 ancol c dng ROH v ROH (t l mol 3 : 5). Hn hp Y gm 2 axit CH
3
COOH v
C
2
H
5
COOH (t l mol 2 : 3).
-Cho 43,8 gam hn hp X tc dng ht vi Na, thu c 8,96 lt H
2
(ktc).
-Cho hn hp Y tc dng va vi NaHCO
3
, thu c 4,48 lt CO
2
(ktc).
un nng 43,8 gam hn hp X vi lng hn hp Y nh trn, c H
2
SO
4
lm xc tc. Gi s cc cht
phn ng vi tc nh nhau, cc phn ng xy ra vi hiu sut bng nhau v u bng 80%. Tnh tng
khi lng este thu c.
Cu IV (2 ):
1 . Dn kh CO n d i qua 12,8 gam hn hp X gm Fe
3
O
4
, MgO v CuO nung nng, thu c 10,4
gam cht rn. Mt khc, ha tan ht 0,3 mol hn hp X th cn 450 ml dung dch HCl 2M. Cc phn
ng xy ra hon ton. Hy vit cc phng trnh ha hc ca cc phn ng xy ra v tnh s mol ca mi
cht trong 12,8 gam hn hp X.
2 . Cho hn hp Mg, Al vo dung dch cha 2 mui CuSO
4
v FeSO
4
. Phn ng xy ra hon ton.
Trng hp 1: sau phn ng thu c dung dch A ch cha mt mui v cht rn B.
Trng hp 2: sau phn ng thu c dung dch X v cht rn Y ch cha mt kim loi.
Xc nh thnh phn tng cht trong A, B, X, Y v vit cc phng trnh ha hc ca cc phn ng xy
ra.
Cu V (1 ):
Khi nung qung olomit CaCO
3
. MgCO
3
(c ln 8% tp cht tr) nhit cao, thu c hn hp
rn c khi lng bng 67% khi lng qung trc khi nung.
1 . Tnh hiu sut phn hy qung.
2 . Tnh % khi lng tng cht c trong hn hp rn sau khi nung.


TRNG THPT CHUYN H NI K THI TUYN SINH LP 10 TRUNG HC PH THNG
AMSTERDAM Nm hc : 2012 - 2013
Mn thi: HA HC (Dnh cho th sinh vo lp chuyn Ha hc)
CHNH THC Thi gian lm bi: 120 pht (Khng k thi gian pht )

Cu I :
1 . Khi thu kh oxi vo ng nghim bng cch y khng kh, phi v tr ng nghim nh th no? V sao? i vi
kh hidro c lm c nh th khng? V sao?
2 . Nu hin tng, vit cc phng trnh ha hc xy ra khi tin hnh cc th nghim sau:
a/ Dn kh CO
2
t t n d vo cc ng dung dch Ca(OH)
2
.
b/ Thm H
2
SO
4
c vo cc ng ng knh trng.
3 . t kim loi R trong kh oxi d thu c cht rn X
1
, trong phn t X
1
nguyn t oxi chim 20% v khi lng. T
R hoc X
1
c th iu ch trc tip cc mui X
2
, X
3
. T X
1
khng th iu ch trc tip c X
4
. Bit phn t khi M
ca cc cht tha mn M X
1
< M X
4
< M X
2
< M X
3
. Xc nh R, chn cc cht X
1
, X
2
, X
3
, X
4
ph hp v vit cc
phng trnh ha hc.
Cu II :
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1 . Khi hp th hon ton 0,05 mol CO
2
hoc 0,35 mol CO
2
vo 500 ml dung dch Ba(OH)
2
a mol/l u thu c m
gam cht kt ta. Tm gi tr ca m v a.
2 . Trn V (l) dung dch Pb(NO
3
)
2
0,5M vi V (l) dung dch AgNO
3
0,6M thu c dung dch X. em 1,2 g bt Al tc
dng vi 100 ml dung dch X. Sau phn ng lc, lm kh tch c t gam cht rn v dung dch Y. Thm t t dung
dch Z cha 0,2M NaOH v b mol/l Ba(OH)
2
vo dung dch Y n khi lng kt ta t cc i th dng ht 50 ml
dung dch Z. Vit cc phng trnh ha hc xy ra v tm gi tr ca t, b.
Cu III :
1 . Chia 49,7 g mt hn hp A gm bt MgO v Al
2
O
3
thnh 2 phn bng nhau. Cho phn 1 vo 500 ml dung dch HCl
nng x mol/l un nng v khuy u cc phn ng xy ra hon ton. Lm bay hi cn thn hn hp sau phn
ng, thu c 59,225 g mui khan. Phn 2 cho vo 750 ml dung dch HCl x mol/l ri tin hnh th nghim nh phn 1
thu c 63,35 g mui khan. Tm x v khi lng mi oxit trong hn hp A.
2 . Ha tan 6,94 g hn hp X gm bt Al v mt oxit st trong 180 ml dung dch H
2
SO
4
1M (long) thu c 0,672 lt
kh (ktc) v dung dch Y. Lng axit ly d 20% so vi phn ng. Tm cng thc ha hc ca oxit v khi lng mi
mui trong dung dch Y.
Cu IV :
1 . Cc hp cht X, Y, Z, T u cha C, H, O tha mn:
X + 6O
2
t
0
6CO
2
+ 6H
2
O
X ? 2Y + 2CO
2

Y + Z T + H
2
O
T + 5O
2
t
0
4CO
2
+ 4H
2
O
Xc nh X, Y, Z, T v vit cc phng trnh phn ng.
2 . Hn hp kh X gm axetilen v hidro c t l mol l 1 : 2. Cho V (l) (ktc) hn hp X qua bt Ni nung nng thu
c hn hp kh Y gm 4 cht. Dn hn hp Y t t qua dung dch Br
2
d, sau phn ng thy tng 5,4 g. t chy
phn kh thot ra th thu c 4,48 l CO
2
(ktc) v 10,8 g H
2
O. Tm V.
3 . Axit no n chc X tin hnh phn ng este ha vi ru etylic thu c este Z. Sau phn ng tch hn hp Y gm
este, axit, ancol. Chia 29,6 g Y thnh 2 phn bng nhau. Phn 1 phn ng vi 125 ml dung dch NaOH 1M thu c
dung dch cha m g mui v 6,9 g ru. t chy phn 2 bng kh oxi d thu c 29,7 g CO
2
v 13,5 g H
2
O.
a/ Vit cng thc cu to ca X, Z.
b/ Tm m v tnh hiu sut phn ng este ha.

PHNG GIO DC & O TO THANH THU

THI CHN HC SINH GII LP 9 THCS
NM HC: 2012 - 2013
Mn: Ha hc
Thi gian: 150 pht, khng k thi gian giao
thi c: 1 trang
Cu 1:(2,5 im)
Hon thnh cc phng trnh phn ng di y:
a) MgSO
4
+ ? MgCl
2
+ ?
b) KHS + ? H
2
S + ?
c) Fe
3
O
4
+ H
2
SO
4 (l)
? + ? + ?
d) Cu + ? CuSO
4
+ ? + H
2
O
e) Ca(HCO
3
)
2
+ ? CaCO
3
+ ?
g) Al
2
O
3
+ KHSO
4
? + ? + ?
Cu 2:(3,5 im)
a) C 4 cht bt mu trng l: Na
2
O, P
2
O
5
, MgO, Al
2
O
3
ch c dng thm nc v qu tm, hy nu
cch phn bit tng cht.
b) Bng phng php ha hc hy tch tng cht ra khi hn hp cht rn gm FeCl
3
, CaCO
3
, AgCl.
Cu 3:(4,0 im)
chnh thc
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1) C V
1
lt dung dch cha 7,3 gam HCl (dung dch A) v V
2
lt dung dch cha 58,4 gam HCl (dung
dch B). Trn dung dch A vi dung dch B ta c dung dch C. Th tch dung dch C bng V
1
+ V
2
= 3
lt
a. Tnh nng mol/l ca dung dch C.
b. Tnh nng mol/l ca dung dch A v dung dch B. Bit : C
M(B)
- C
M(A)
= 0,6M
2) Ha tan mt lng mui cacbonat ca mt kim loi M ha tr II bng mt lng va dung dch
H
2
SO
4
14,7% thu c dung dch mui sunfat 17%. Xc nh kim loi M.
Cu 4:(10 im)
1) Cho 16,8 lt CO
2
( ktc) hp th hon ton vo 600 ml dung dch NaOH 2M thu c dung dch A.
Tnh khi lng cc mui c trong dung dch A.
2) Cho dung dch HCl 0,5M tc dng va vi 10,8 gam hn hp A gm Fe, FeO, FeCO
3
, thy thot ra
mt hn hp kh c t khi i vi H
2
l 15 v to ra 15,875 gam mui clorua.
a. Tnh th tch dung dch HCl dng.
b. Tnh % khi lng ca mi cht trong hn hp A.
3) Mt hn hp X gm kim loi M (M c ha tr II v III) v oxit M
x
O
y
ca kim loi y. Khi lng hn
hp X l 27,2 gam. Khi cho X tc dng vi 0,8 lt HCl 2M th hn hp X tan ht cho dung dch A v 4,48
lt kh (ktc). trung ha lng axit d trong dung dch A cn 0,6 lt dung dch NaOH 1M. Xc nh M,
M
x
O
y
.
Bit rng trong hai cht ny c mt cht c s mol bng 2 ln s mol cht kia.
Cho: Mg = 24; O = 16; H = 1; Cl = 35,5; Fe = 56; S = 32; Na =23; C=12,

S GIO DC & O TO
NGH AN

K THI CHN HC SINH GII TNH LP 9 THCS NM
HC 2010 - 2011

Mn thi: HA HC - BNG A
Thi gian: 150 pht (khng k thi gian giao )

Cu I (4,0 im).
1/ Chn 7 cht rn khc nhau m khi cho 7 cht ln lt tc dng vi dung dch HCl c 7 cht kh
khc nhau thot ra. Vit cc phng trnh phn ng minh ho.
2/ Cho cc s phn ng ho hc sau y:
X
1
+ X
2
Na
2
CO
3
+ H
2
O
X
3
+ H
2
O X
2
+ X
4
+ H
2

X
5
+ X
2
X
6
+ H
2
O
X
6
+ CO
2
+ H
2
O X
7
+ X
1

X
5
X
8
+ O
2

Chn cc cht X
1
, X
2
, X
3
, X
5
, X
6
, X
7
, X
8
thch hp v hon thnh cc phng trnh ho hc ca cc
phn ng trn.
3/ Em hy xut thm 4 phn ng khc nhau trc tip iu ch X
2
Cu II (3,0 im).
Cho 26,91 (g) kim loi M vo 700 ml dung dch AlCl
3
0,5M, sau khi phn ng xy ra hon ton thu
c V lt H
2
(ktc) v 17,94 (g) kt ta. Xc nh kim loi M v gi tr ca V.
Cu III (6,0 im):
Chia 80 (g) hn hp X gm st v mt oxit ca st thnh hai phn bng nhau:
Ho tan ht phn I vo 400 (g) dung dch HCl 16,425% c dung dch A v 6,72 lt kh H
2
(ktc).
Thm 60,6 (g) nc vo A c dung dch B, nng % ca HCl d trong B l 2,92%.
1/ Tnh khi lng mi cht trong hn hp X v xc nh cng thc ca oxit st.
CHNH

in phn dung d ch
c mng ngn
in phn nng chy
Cr i ol i t
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2/ Cho phn II tc dng va ht vi H
2
SO
4
c nng ri pha long dung dch sau phn ng bng nc,
ta thu c dung dch E ch cha Fe
2
(SO
4
)
3
. Cho 10,8 (g) bt Mg vo 300 ml dung dch E khuy k, sau
khi phn ng xy ra hon ton thu c 12,6 (g) cht rn C v dung dch D. Cho dung dch D tc dng vi
dung dch Ba(OH)
2
d, lc kt ta v nung n khi lng khng i c m (g) cht rn F (trong iu
kin th nghim BaSO
4
khng b phn hu). Tnh C
M
ca dung dch E v gi tr m.
Cu IV (4,0 im).
1/ Vit phng trnh ha hc ( dng cng thc cu to thu gn) thc hin cc bin ha theo s
sau:

Axetilen Etilen Etan

P.V.C Vinylclorua icloEtan Etylclorua
2/ Cho vo bnh kn hn hp cng s mol C
5
H
12
v Cl
2
to iu kin phn ng xy ra hon ton
thu c sn phm hu c m trong mi phn t ch cha mt nguyn t Clo. Vit cc cng thc cu to
c th c ca cc sn phm hu c .
Cu V (3,0 im).
t chy hon ton 1 (g) hn hp X gm C
2
H
2
, C
3
H
6
, C
2
H
6
. Hp th ton b sn phm chy vo 2 lt
dung dch Ca(OH)
2
0,02 M thu c 1 (g) kt ta. Mt khc 3,36 lt hn hp X (ktc) lm mt mu ti a
200 ml dung dch Br
2
0,5 M. Tnh th tch mi kh c trong 1 (g) hn hp X.
Cho: H = 1; Li = 7; C = 12, O = 16; Na = 23; Mg = 24; S = 32; Cl = 35,5; K = 39; Ca = 40;
Fe = 56; Cu = 64; Br = 80; Ba= 137.
(1)
(2)
(8)
(7)
(5)
(6)
(3)
(4)