TRC NGHIM ESTE PHN DNG V TUYN CHN 1: Cc cu trc nghim v l thuyt, xc nh CTCT, CTPT: Cu 1: S ng phn este mch

h ng vi cng thc phn t C4H6O2 l: A.5 B.2 C.4 D.6 Cu 2: S hp cht n chc, ng phn cu to ca nhau c cng cng thc phn t C4H8O2, u tc dng vi dung dch NaOH A.3 B.4 C.5 D.6 Cu 3:Cho cht X tc dng vi mt lng va dung dch NaOH, sau c cn dung dch thu c cht rn Y v cht hu c Z. Cho Z tc dng vi dung dch AgNO3 trong NH3 thu c cht hu c T. Cho T tc dng vi dung dch NaOH li thu c cht Y. Cht X c th l: A.HCOOCH=CH2 B.CH3COOCH=CH2 C.HCOOCH3 D.CH3COOCH=CH-CH3 Cu 4: Este X c c im sau: -t chy hon ton X to thnh CO2 v H2O c s mol bng nhau. -Thu phn X trong mi trng axit c cht Y (tham gia phn ng trng gng) v cht Z (c s nguyn t cacbon bng mt na s nguyn t cacbon trong X) Pht biu khng ng l: A. t chy hon ton 1 mol X sinh ra sn phm gm 2 mol CO2 v 2 mol H2O. B. un Z vi dd H2SO4 1700 C thu c anken C. Cht Y tan v hn trong nc D. Cht X thuc loi este no, n chc Cu 5:Hai este n chc X v Y l ng phn ca nhau. Khi ho hi 1,85 gam X, thu c th tch hi ng bng th tch ca 0,7 gam N2 ( o cng iu kin). Cng thc cu to thu gn ca X, Y l: A.C2H5COOCH3 v HCOOCH(CH3)2 B.HCOOC2H5 v CH3COOCH3 C.C2H3COOC2H5 v C2H5COOC2H3 D.HCOOCH2CH2CH3 CH3COOC2H5 Cu 6: Thu phn este c cng thc phn t C4H8O2 ( vi xc tc axit), thu c 2 sn phm hu c X, Y. T X c th iu ch trc tip ra Y. Vy cht X l: A.Ancol metylic B.Etyl axetat C.axit fomic D.ancol etylic Cu 7: Mt hn hp X gm 2 cht hu c n chc. Cho X phn ng va vi 500ml dung dch KOH 1M. Sau phn ng thu c hn hp Y gm 2 mui ca hai axit cacboxylic v mt ancol. Cho ton b lng ancol thu c trn tc dng vi Na d, sinh ra 3,36 lit H2( ktc). Hn hp X gm: A.mt axit v mt este B.mt este v mt ancol C.hai este D.mt axit v mt ancol Cu 8: X phng ho mt hn hp c cng thc phn t C 10H14O6 trong dung dch NaOH (d), thu c glixerol v hn hp gm ba mui (khng c ng phn hnh hc). Cng thc ca ba mui l A. CH2 = CH COONa, HCOONa v CH C COONa. C. HCOONa, CH C COONa v CH3 CH2 COONa. B. CH3 COONa, HCOONa v CH3 CH = CH COONa. D. CH2 = CH COONa, CH3 CH2 COONa v HCOONa p n: 1 2 3 4 5 6 7 8 D D A B B A D D v bt u t HCOO. Hng dn: Cu 1: Vit ng phn este, trc tin tnh s lk Lu : HCOOCH=CHCH3 c ng phn cis v trans Cu 2:C4H8O2 Tc dng NaOH c th l axit hoc este + 1 pi v 2 oxi axit no, n chc mch h c 2 ng phn ( t vit nh ) + Este no, n chc mch h c 4 ng phn Vy tng cng c 6 CTPT tha yu cu bi Cu 5: Nhn cc phng n este no, c CnH2nO2, M= 1,85/(0.7/28) = 74 C3H6O2 Cu 6: T ancol oxh to ra axit, v dc trc tip nn s C trong ancol = s C trong axit = 4/2=2

2: Bi ton t chy este Cu 1: Khi t chy hon ton 4,4 gam cht hu c X n chc thu c sn phm chy ch gm 4,48 lit CO2 ( ktc) v 3,6 gam H2O. Nu cho 4,4 gam cht X tc dng vi dung dch NaOH va n khi phn ng hon ton, thu c 4,8 gam mui ca axit hu c Y v cht hu c Z.Tn ca X l: A.Etyl propionat B.Metyl propionat C.isopropyl axetat D.etyl axetat Cu 2: Khi t chy hon ton este no n chc th s mol CO2 sinh ra bng s mol O2 phn ng. Tn gi ca este l: A.etyl axetat B.metyl axetat C.metyl fomiat D.propyl axetat Cu 3: t chy hon ton m gam este X cn 5,6 lit O2 (ddktc) thu c 12,4 gam hh Y gm CO2 v H2O, t khi Y so vi H2 l 15,5. Mc khc cho X qua LiAlH4 t0 thu c 1 cht hu c duy nht, X l : A: metyl propionat B: propyl propionat C: etyl axetat D: metyl fomat Cu 4 : Hn hp X gm 1 este n chc khng no 1 ni i v 1 este no n chc mch h. t chy 0,15 mol X ri cho ton b sn phm hp th vo bnh cha Ca(OH)2 d. Sau phn ng thy khi lng bnh tng 23,9 gam v c 40 gam kt ta. CTPT ca 2 este l: A: C2H4O2 , C3H4O2 B: C2H4O2 , C4H6O2 C: C2H4O2 , C5H8O2 D: C3H6O2 , C5H8O2 p n: 1 B 2 B 3 C 4 B

Hng dn: Cu 1: Cch 1: T nCO2 = nH2O =0,2 mol CnH2nO2 , BTKL nO2 = 0,25 mol t ta c nX*2 + nO2*2 = nCO2*2 + nH2O nX = 0,1/2 = 0,05 mol M = 88 C4H8O2 T gi thit th 2 d dng B.Metyl propionat Cch 2 tng gim khi lng : RCOOR RCOONa ( khi lng tng 23 - R) Ta c s mol phn ng = 0,05 =
4,8 4, 4 23 R '

R = 15 chn B

Cu 2 : c 2 cch c th vit ptpu hoc bo ton nguyn t oxi Cu 3: Dng s cho ( M tb =31) nCO2 = nH2O = 0,4/2 = 0,2 mol ( no, c ) BTKL mx = 4,4 gam, BTNT nO2 = 0,1/2 = 0,05 mol M =88 ( C4H8O2) X qua LiAlH4 t0 thu c 1 cht hu c duy nht X l etyl axetat Cu 4: Este1 : CnH2nO2 (n 2) ; Este2: CnH2n-2O2 (n 3) Ta c: nCO2 = 0,4 ; nH2O = 0,35 s C tb = 0,4/0,15 = 2,67 Este1 l C2H4O2 nEste2 = nCO2 nH2O = 0,05 mol nEste1 = 0,15-0,05=0,1 mol
2,67 = 2.0,1 + m.0,05 0,15

m=4 C4H6O2

3: Phn ng thy phn Cu 1: Este X khng no, mch h, c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x phng ho to ra mt anehit v mt mui ca axit hu c. C bao nhiu cng thc ph hp vi X? A.2 B.3 C.4 D.5 Cu 2: X l mt este no n chc, c t khi hi so vi CH4 l 5,5. Nu em un 2,2 gam este X vi dd NaOH d, thu c 2,05 gam mui. Cng thc cu to thu gn ca X l:A.HCOOCH2CH2CH3 B.HCOOCH(CH3)2 C.C2H5COOCH3 D.CH3COOC2H5 Cu 3:X phng ho 8,8 gam etyl axetat bng 200 ml dung dch NaOH 0,2M. Sau khi phn ng xy ra hon ton c cn dung dch thu c cht rn khan c khi lng l: A.8,56 gam B.3,28 gam C.10,4 gam D.8,2 gam Cu 4: Hn hp X gm axit HCOOH v axit CH3COOH (t l mol 1:1). Ly 5,3 gam hn hp X tc dng vi 5,75 gam C2H5OH ( c xc tc H2SO4 c) thu c m gam hn hp este ( hiu sut ca cc phn ng este ho u bng 80%). Gi tr ca m l: A.10,12 B.6,48 C.8,10 D.16,20

Cu 5: Khi thc hin phn ng este ho 1 mol CH3COOH v 1 mol C2H5OH, lng este ln nht thu c l 2/3 mol. t hiu sut cc i l 90% ( tnh theo axit) khi tin hnh este ho 1 mol CH3COOH cn s mol C2H5OH l ( bit cc phn ng este ho thc hin cng nhit ) A.0,342 B.2,925 C.2,412 D.0,456 Cu 6: X phng ho hon ton 17,24 gam cht bo cn va 0,06 mol NaOH. C cn dung dch sau phn ng thu c khi lng x phng l: A.17,80 gam B.18,24 gam C.16,68 gam D.18,38 gam Cu 7:Este n chc X c t khi hi so vi CH4 l 6,25.Cho 20 gam X tc dng vi 300 ml dung dch KOH 1M(un nng). C cn dung dch c sau phn ng thu c 28 gam cht rn khan. Cng thc cu to ca X l: A.CH2=CH-CH2COOCH3 B.CH2=CH-COOCH2CH3 C.CH3COOCH=CH-CH3 D.CH3-CH2COOCH=CH2 Cu 8: X phng ho hon ton 22,2 gam hn hp gm 2 este HCOOC2H5 v CH3COOCH3 bng dung dch NaOH 1M (un nng). Th tch dung dch NaOH ti thiu cn dng l: A.400 ml B.300 ml C.150 ml D.200 ml Cu 9: un nng 6,0 gam CH3COOH vi 6,0 gam C2H5OH ( c H2SO4 lm xc tc, hiu sut phn ng este ho bng 50%). Khi lng este to thnh l: A.6,0 gam B.4,4 gam C.8,8 gam D.5,2 gam Cu 10: Hai este n chc no A, B l ng phn ca nhau. X phng ha hon ton 66,6 gam hn hp hai este trn cn va 900 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 65,4 gam hn hp hai mui khan. Cng thc cu to v tnh khi lng ca A v B trong hn hp ban u, l : A. C2H5COOCH3 28,2 gam ; CH3COOC2H5 38,4 gam B. HCOOC3H7 40,6 gam ; CH3COOC2H5 26 gam C. HCOOC2H5 44,4 gam ; CH3COOCH3 22,2 gam D. C2H5COOC3H7 41,6 gam ; C3H7COOC2H5 25,0 gam Cu 11: Cho 10 gam hn hp 2 axit HCOOH v CH3COOH tc dng va vi 190ml dung dch NaOH 1M. Mt khc nu cho 10 gam hn hp trn tc dng vi 9,2 gam ru etylic c H2SO4 c xc tc v hiu sut phn ng este ho l 90% th lng este thu c l bao nhiu (chn trong cc s cho sau) ? A. 12,85 gam B. 13,00 gam C. 14,50 gam D. 13,788 gam. Cu 12: X l 1 este n chc. Thy phn 0,01 mol X vi 300 ml dd NaOH 0.1M n khi phn ng xy ra hon ton thu c dd Y. C cn dd Y th thu c phn hi ( ch c nc) v 2,38 gam cht rn khan. S CTCT c th c ca X l: A: 1 B: 2 C: 3 D: 4 1 2 3 4 5 6 7 8 9 10 11 12 C D B B C A D B B C D D

Trn y l cc cu trc nghim ESTE ly t thi tuyn sinh cc nm trc ( c b sung thm 1 s cu) nu c kin ng gp xin lin h thanhtinpk092007@gmail.com welcome to my blog : http://namkep.blogspot.com

Cc bi trc nghim ESTE hay ( su tm) Cu 1. Este X t t ru X1 n chc v axit X2 a chc c cng thc n gin l C2H3O2. Hy cho bit c bao nhiu cht tho mn ? A. 1 B. 2 C. 3 D. 4

Cu 2. X l mt este to t axit v ru no. t chy hon ton 1 mol X thu c 3 mol CO2. Hy cho bit c bao nhiu este tho mn? A. 1 B. 2 C. 3 D. 4 Cu 3. Glixerin un vi hn hp CH3COOH v HCOOH ( xc tc H2SO4 c) c th c ti a bao nhiu trieste (este 3 ln este)? A. 3 B. 4 C. 5 D. 6 Cu 4. Este X c cng thc phn t l C6H10O4. X khng tc dng vi Na. un nng X vi NaOH thu c cht c th phn ng Cu(OH)2 nhit thng to dung dch xanh lam nhng khng to kt ta gch khi un nng. Hy cho bit X c th c bao nhiu CTCT ? A. 1 B. 2 C. 3 D. 4 Cu 5. Este X khng tc dng vi Na nhng tc dng vi NaOH un nng thu c glixerin v natri axetat. Hy cho bit CTPT ca X. A. C6H8O6 B. C9H12O6 C. C9H14O6 D. C9H16O6 . Cu 6. Thc hin phn ng este ho gia axit axetic vi 2 ru no n chc l ng ng k tip nhau thu c hn hp 2 este. t chy hon ton 0,1 mol hn hp 2 este thu c 10,08 lt CO2. Hy la chn cng thc cu to ca 2 ru ? A. CH3OH v C2H5OH B. C2H5OH v CH3CH(OH)CH3 C. C2H5OH v CH3CH2CH2OH D. n-C3H7OH v n-C4H9OH Cu 7. C bao nhiu este mch h c cng thc phn t l C5H8O2 m khi thy phn trong mi trng kim cho 1 mui v mt anehit ? A. 8 B. 7 C. 6 D. 5 Cu 8. Este X khng tc dng vi Na. X tc dng dd NaOH thu c mt ru duy nht l CH3OH v mui natri aipat. CTPT ca X l. A. C10H18O4 B. C4H6O4 C. C6H10O4 D. C8H14O4 Cu 9.Cho 0,1 mol axit n chc X phn ng vi 0,15 mol ru n chc Y thu c 4,5gam este vi hiu sut 75%. Vy tn gi ca este? A. Metyl fomiat B. Metyl axetat C. Etyl axetat D.metyl propionat Cu 10. X l este to t axit n chc v ru 2 chc. X khng tc dng vi Na. Thu phn hon ton 0,1 mol X bng NaOH (va ) thu c hn hp sn phm c tng khi lng l 21,2 gam. Hy cho bit c nhiu este tho mn iu kin ? A. 1 B. 2 C. 3 D. 4 Cu 11. un nng 0,1 mol cht X ch cha mt loi nhm chc tc dng va vi NaOH trong dd thu c 13,4 gam mui ca axit hu c Y mch thng v 9,2 gam ru n chc. Cho ton b lng ru tc dng vi Na thu c 2,24 lt H2 (ktc). Xc nh CTCT ca X. A. ietyl oxalat B. Etyl propionat C. ietyl aipat D.imetyl oxalat Cu 12. Thy phn hon ton hn hp X gm 2 este n chc A, B cn dng 100 ml dd NaOH 1M thu c 6,8 gam mui duy nht v 4,04 gam hn hp 2 ru l ng ng lin tip nhau. Cng thc cu to ca 2 este l:A.HCOOCH3 & HCOOC2H5 B.CH3COOCH3 & CH3COOC2H5 C. C2H3COOCH3 v C2H3COOC2H5 D. HCOOC2H5 v HCOOC3H7 Cu 13. Thy phn hon ton 0,1 mol este E (mch h v ch cha mt loi nhm chc) cn dng va 100 ml dung dch NaOH 3M, thu c 24,6 gam mui ca mt axit hu c v 9,2 gam mt ru.Vy cng thc ca E l : A. C3H5(COOC2H5)3 B. (HCOO)3C3H5 C. (CH3COO)3C3H5 D. (CH2=CH-COO)3C3H5 Cu 14. Cho cc cht sau: CH3COOC2H3 (I) , C2H3COOH (II) , CH3COOC2H5 (III) v CH2=CH-COOCH3 (IV). Cht no va tc dng vi dung dch NaOH, dung dch nc brom. A. I, II, IV B. I, II, III C. I, II, III, IV D. I v IV. Cu 15.un 0,1 mol este n chc X vi NaOH (ly d 20% so vi lng P) chng ct ly ht ru Y cn li 10,4 gam cht rn khan. Oxi ho ht ru Y thnh anehit Z. Cho Z tc dng vi dd Ag2O d trong NH3 sinh ra 43,2 gam Ag (cc P xy ra hon ton). Vy X l: A. CH3CH2COOC2H5 B. CH3COOCH3 C. CH2=CH-COOCH3 D. CH3CH2COOCH3. Cu 16. Cho 0,1mol este X n chc un vi 100 gam dung dch NaOH 8%, phn ng hon ton thu c 108,8gam dung dch Y. Lm kh dung dch Y thu c 13,6 gam hn hp 2 cht rn. Cng thc ca X. A.CH3COOC2H5 B.CH3COOCH3 C.C2H5COOCH3 D.HCOOC3H7 Cu 17. un 0,1 mol este X n chc vi NaOH d sau cho tc dng vi Cu(OH)2 t0 thu c 0,2 mol Cu2O. Vy CT ca anehit l:

A. R-COO-CH=CR2 B. HCOO-CH=CR2 C. HCOOR D. H-COO-CR=CH2 . Cu 18. Mt ieste (X) xut pht t mt axit 2 chc v 2 ru n chc bc I. Cho 0,1 mol X tc dng vi dung dch NaOH (phn ng va ) thu c 13,4 gam mui v 9,2 gam hn hp ru. Vy cng thc ca X. A. CH3-OOC-COO-CH2-CH3 B. CH3-OOC-CH2-COO-C2H5 C. C2H5-OOC-COO-CH2-CH=CH2 D.CH3OOC-COOCH2CH2CH3 Cu 19. t chy hon ton 0,1 mol este n chc X cn 0,5 mol O2 thu c 8,96 lt CO2 v b mol H2O. a/ Vy s mol H2O thu c l :A.0,3 mol B. 0,35 mol C.0,2 mol D.0,4 b/ un nng 0,1 mol X vi 200 ml dd NaOH 1M , c cn dd sau phn ng thu c 12,2 gam cht rn khan. Vy cng thc ca X l : A. CH3COOCH3 B. CH2=CH-COOCH3 C. CH3COOC2H5 D. CH3CH2COOCH3 . Cu 20. Este X to t hn hp 2 axit n chc X1, X2 v glixerin. un nng X vi dung dch NaOH thu c 9,2 gam glixerin v 15 gam hn hp 2 mui. Hy cho bit cng thc ca 2 axit . A. HCOOH v CH3COOH B. HCOOH v C2H5COOH C. CH3COOH v C2H3COOHD. HCOOH v C2H3COOH. Cu 21. Este X n chc tc dng vi NaOH un nng thu c mui Y c cng thc phn t l C3H5O2Na v ru Y1. Oxi ha Y1 bng CuO nung nng thu c anehit Y2. Y2 tc dng vi Ag2O d, un nng thu c s mol Ag gp 4 ln s mol Y2. Vy tn gi ca X l : A. Etyl propionat B. metyl propionat C. metyl axetat D. propyl propionat. Cu 22. un nng este X n chc mch h vi NaOH thu c mui v ru. t chy hon ton 0,1 mol X cn 10,08 lt O2 (ktc) v thu c 8,96 lt CO2 (ktc). X khng c phn ng trng gng. Vy cng thc ca X l : A. HCOO-CH2-CH=CH2 B. CH3-COOCH2-CH=CH2. C. CH2=CH-COOCH3 D. CH3-COOCH=CH2 Cu 23. Hn hp X gm etyl axetat v n-propyl axetat. un nng hn hp X vi NaOH (va ) thu c 13,12 gam mui v 8,76 gam hn hp ru Y. Vy % khi lng ca etyl axetat trong hn hp X l : A. 56,85% B. 45,47% C. 39,8% D. 34,1% Cu 24. t chy hon ton este X thu c CO2 v nc theo t l mol 1: 1. Mt khc, cho m gam X tc dng vi NaOH d thu c 6,56 gam mui v 3,68 gam ru. Cho ton b lng ru tc dng vi Na d thu c 0,896 lt H2 (ktc). Vy cng thc ca este l : A.HCOOCH3 B.CH3COOCH2CH3 C.(COOCH2CH3)2 D.(CH3COO)2C2H4 Cu 25. un nng hn hp X gm 2 este n chc vi NaOH thu c 7,36 gam hn hp 2 mui ca 2 axit k tip nhau trong dy ng ng v 3,76 gam hn hp 2 ru k tip nhau trong dy ng ng. Vy 2 este l :A. HCOOCH3 v CH3COOC2H5 B. CH3COOCH3 v HCOOC2H5 C. CH3COOC2H5 v C2H5COOCH3 D.HCOOC3H7 v CH3COOC2H5 Cu 26. Este X c cng thc phn t l C5H8O2. un nng 0,1 mol X vi 200 ml dung dch NaOH 1M. C cn dung dch sau phn ng thu c 13,4 gam cht rn khan. Vy cng thc ca este l : A. CH3COO-CH2-CH=CH2 B. CH2=CH-COOC2H5 C. CH2=C(CH3)-COOCH3 D. HCOOCH=C(CH3)2. Cu 27. Este X c cng thc phn t C7H10O4 mch thng. Khi cho 15,8 gam X tc dng va vi 200 gam dd NaOH 4% th thu c mt ru Y v 17,6 gam hn hp 2 mui. Cng thc cu to ca 2 mui no sau y c th tha mn : A. C2H3COONa v C2H5COONa B. CH3COONa v C2H3COONa C. CH3COONa v C3H5COONa D. HCOONa v C2H3COONa