V C

DNG 1 : PHNG PHP BO TON KHI LNG

Cu 1: Ho tan hon ton 2,81 gam hn hp gm Fe2O3, MgO, ZnO trong 500 ml dd axit H2SO4 long 0,1 M va . Sau phn ng, hn hp mui sunfat khan thu c khi c cn dung dch c khi lng l? S: 6,81 gam Cu 2: Ho tan hon ton 3,22 gam hn hp X gm Fe, Mg, Zn bng mt lng va dung dch H2SO4 long, thu c 1,344 lt kh H2 ktc v dung dch cha m gam mui. Ga tr ca m l? S : 8,98 Cu 3: Nung 13,44 gam hn hp 2 mui cacbonat ca 2 kim loi ho tr 2. Thu c 6,8 gam cht rn v kh X. Lng kh X sinh ra cho hp th vo 75 ml dung dch NaOH 1M, khi lng mui khan thu c sau phn ng l? Cu 4: Khi cho 4 g hn hp kim loi gm Cu, Zn, Al vo dd H2SO4 c nng d thu c 4,48 lt kh SO2 ktc. Khi lng mui clorua thu c khi cho 4 gam hn hp trn tc dng vi kh Clo. Cu 5: Ho tan hon ton 10 gam hn hp hai mui XCO3, Y2(CO3)3 bng dd HCl. Ta thu c dung dch Z v 0,672 lt kh bay ra ktc. C cn dung dch Z th thu c m g mui khan. Tnh m. S : 10.33 Cu 6: Thi mt lung kh CO d i qua ng s ng m gam hn hp gm CuO, Fe2O3, FeO, Al2O3. Nung nng c hn hp rn c khi lng 16 gam dn hon ton kh thu c vo dung dch nc vi trong d thy c 15 gam kt ta trng. Tnh m? Cu 7: Cho 14,5 gam hn hp Mg, Zn, Fe tc dng ht vi dung dch H 2SO4 long thy thot ra 6,72 lt kh H2 ktc. C cn dung dch sau phn ng thu c m gam mui khan. Gi tr ca m l. s : 43,3 Cu 8: Dn mt lung kh kh CO d qua ng nghim ng m gam hn hp X gm Fe 2O3 v CuO nung nng thu c cht rn Y. Kh ra khi ng c dn vo bnh dung dch Ca(OH)2 d thu uc 40 gam kt ta. Ho tan cht rn Y trong dung dch HCl d thy c 4,48 lt kh H 2 bay ra ktc. Tnh m? S : 24 gam Cu 9: Ho tan hon ton 23 gam hn hp mui cc bonat ca kim loi ho tr I, v mt mui ca kim loi ho tr II bng dung dch HCl d thy thot ra 4,48 lt kh CO2 ktc. C cn dung dch sau phn ng th khi lng mui khan thu c l. Cu 10: Cho 7,28 gam kim loi M tc dng hon ton vi dung dch HCl, sau phn ng thu c thu c 2,912 lt kh H2 27,3oC. M l kim loi no? Cu11: Kh hon ton hn hp X gm FeO v Fe2O3 bng H2 nhit cao, kt thc th nghim thu c 9 gam H2O v 22,4 gam cht rn. % S mol ca FeO trong hn hp X l: Cu 12: Cho mt lung kh CO i qua ng s ng m gam Fe 2O3 nung nng. Sau mt thi gian thu c 13,92 gam hn hp X gm Fe, FeO, Fe3O4 v Fe2O3. Ho tan ht X bng HNO3 c nng c 5,824 lt kh NO2 ktc. Tnh m Cu 13: Thi mt lung kh CO i qua ng s ng m gam hn hp gm Fe3O4 v CuO nung nng thu c 2,32 gam hn hp cht rn. Ton b kh thot ra cho hp th ht vo bnh ng dung dch Ca(OH)2 d thu c 5 gam kt ta. m c gi tr l? Cu 14: Kh hon ton 17,6 gam hn hp X gm Fe, FeO, Fe2O3 cn 2,24 lt CO ktc. Khi lng st thu c l?

Cu 15: in phn 250 ml dung dch CuSO4 vi in cc tr, khi catt bt u c bt kh th ngng in phn, thy khi lng ca tt tng 4,8 gam. Nng mol/lt ca CuSO4 ban u l? Cu 16: Nhit phn hon ton 9,4 gam mui Nitrat ca mt kim loi thu c 4 gam mt oxit. Cng thc ca mui l g? Cu 17: Nung 6,58 gam Cu(NO3)2 trong bnh kn mt thi gian, thu c 4,76 gam cht rn v hn hp kh X. Ho tan hon ton X vo H2O c 300 ml dung dch Y. Dung dch Y c pH bng?

DNG 2 : PHNG PHP BO TON NGUYN T

VD1: Cho chui phn ng nh sau: Fe Fe3O4 Fe2O3 Fe2(SO4)3 Fe(NO3)3 Fe(OH)3 Fe2O3 Fe3O4 Vit cc ptp xy ra v tnh s mol ca cc nguyn t trong hp cht. a ra nhn xt VD2: Cho hn hp gm 0,1 mol Fe; 0,2 mol FeO, 0,2 mol Fe 2O3 v 0,1 mol Fe3O4 tc dng hon ton vi dd H2SO4 c nng. Vit cc ptp xy ra v tnh khi lng mui thu c. Cu 1: Cho 1,6 gam bt Fe2O3 tc dng vi axit d HCl. Khi lng mui sau phn ng l? Cu 2: Ho tan hon ton hn hp gm Fe, FeO, Fe2O3, Fe3O4 trong dd HNO3 long nng d thu c 4,48 lt kh NO duy nht ktc v 96,8 gam mui Fe(NO3)3. Tnh s mol HNO3 phn ng. s : 1,4 mol Cu hi ph: Tnh m H2O to thnh, khi lng oxit ban u xit ban u. Cu 3: Hn hp X gm mt xit ca st c khi lng 2,6 gam. Cho kh CO d i qua X nung nng, kh i ra hp th vo dung dch nc vi trong d th thu c 10 gam kt ta. Tnh tng khi lng ca Fe c trong X l? S : 1 gam . Cu 4: Ho tan hon ton m gam Fe trong dung dch HCl thu c x gam mui clorua. Nu ho tan hon ton m gam Fe trong dung dch HNO3 long d th thu c y gam mui nitrat. Khi lng 2 mui chnh lch nhau 23 gam. Ga tr ca m l? Cu 5: Ho tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 va thu c dung dch X ch cha hai mui sunfat v kh duy nht NO. Ga tr ca a l? S : a = 0,06 mol Cu 6: Cho kh CO i qua ng s cha 16 gam Fe 2O3 un nng sau phn ng thu c hn hp rn X gm Fe, FeO, Fe3O4, Fe2O3. Ho tan hon ton X bng H2SO4 c nng thu c dung dch Y. C cn dung dch Y thu c lng mui khan l bao nhiu? S : 40 Cu hi thm : Nu cho bit kh SO2 thu uc l 0,3 mol, Tnh s mol H2SO4. Cu 7: Ho tan hon ton hn hp X gm 6,4 gam Cu v 5,6 gam Fe bng dung dch HNO3 1M sau phn ng thu c dung dch A v kh NO duy nht. Cho tip dung dch NaOH d vo dung dch A thu c kt ta B v dung dch C. Lc kt ta B ri em nung ngoi khng kh n khi lng khng i th khi lng cht rn thu c l? S: 16 Cu 8: Ho tan hon ton hn hp X gm 0,4 mol FeO v 0,1 mol Fe2O3 vo dung dch HNO3 long d, thu c dung dch A v kh NO duy nht. Dung dch A cho tc dng vi dung dch NaOH d thu c kt ta. Ly ton b kt ta nung trong khng kh n khi lng khng i thu c cht rn c khi lng l? S: 48 gam

Cu 9: Ho tan hon ton a gam hn hp X gm Fe v Fe2O3 trong dd HCl thu c 2,24 lt kh H2 ktc v dung dichj B. Cho dung dch B tc dng vi dung dch NaOH d lc ly kt ta, nung trong khng kh n khi lng khng i thu c cht rn c khi lng bng 24 gam. Tnh a? s: 21.6 gam . THM : VD 1: Dng CO kh hn hp A gm a mol FeO v b mol Fe 2O3 thu c hn hp cht rn B gm x mol Fe2O3, y mol Fe3O4, z mol FeO, t mol Fe. Biu thc lin h gia a, b, c, d, x, y, z, t l A. a 2b = 2x + 3y + z + t B. a + 2b = 2x + 3y z t C. a + 2b = 3x + 2y + z + t D. a + 2b = 2x + 3y + z + t S : D VD 2: t chy hon ton 0,1 mol mt axit cacboxylic n chc, cn va V lt O 2 ktc thu c 0,3 mol CO2 v 0,2 mol H2O. Gi tr ca V l: A.8,96 B.13,44 C.6,72 D.4,48 S : C Cu 1: kh hon ton 3,04 gam hn hp X gm FeO, Fe3O4, Fe2O3 cn 0,05 mol H2. Mt khc ha tan hon ton 3,04 gam hn hp X trong dung dch H 2SO4 c thu c th tch SO2 l sn phm kh duy nht ktc l. A. 448 ml B. 112 ml C. 224 ml D. 336 ml Cu 2: Nhit phn m gam NH3 thu c hn hp X c th tch bng 134,4 lt ktc. Cho X i qua dung dch H2SO4 d cn li hn hp kh Y c th tch bng 89,6 lt ktc. Gi tr ca m l: A. 34 B. 68 C. 17 D. 51 Cu 3: t chy hon ton 4,04 gam mt hn hp bt kim loi gm Al, Fe, Cu thu c 5,96 gam hn hp 3 oxit. Tnh th tch dung dch HCl 2M cn dng ha tan ht hn hp 3 oxit . A. 0,06 lt B. 0,12 lt C. 0,24 lt D. 0,48 lt Cu 4: Thi t t V lt hn hp kh X ktc gm CO, H2 i qua ng ng 16,8 gam hn hp 3 oxit gm CuO, Fe3O4, Al2O3 nung nng. Sauk hi phn ng hon ton thu c m gam cht rn v mt hn hp kh Y nng hn khi lng ca X l 0,32 gam. Ga tr ca V v m l : A. 0,448 lt v 16,48 gam B. 0,448 lt v 18,46 gam C. 0,224 lt v 16,48 gam D. 0,224 lt v 18,46 gam Cu 5: Thi rt chm 2,24 lt ktc hn hp X gm CO v H2 i qua ng s ng 24 gam hn hp Al2O3, CuO, Fe2O3 v Fe3O4 ly d ang c un nng. Sau khi kt thc phn ng, khi lng cht rn cn li trong ng s l : A. 22,4 gam B. 11,2 gam C. 20,8 gam D. 44,8 gam Cu 6: Cho m gam mt ancol no n chc X qua bnh ng CuO d, un nng. Sau khi phn ng hon ton, khi lng cht rn trong bnh gim 0,32 gam. Hn hp hi thu c c t khi i vi H2 l 15,5. Gi tr ca m l? A. 0,46 B. 0,32 C. 0,64 D. 0,92 Cu 7: Ha tan hon ton 9,65 gam hn hp gm Al, Fe trong HCl d. Dung dch thu c cho tc dng vi dung dch NaOH d, lc kt ta, nung trong khng kh n khi lng khng i cn li 8 gam cht rn. Phn trm khi lng ca Fe trong hn hp ban u l : A. 58,03% B. 41,97% C. 53,08% D. 46,92% Cu 8: 11,2 gam bt Fe ngoi khng kh, sau mt thi gian, thu c cht rn X. Ha tan hon ton X trong H2SO4 c nng d thu c dung dch Y v kh SO2 duy nht. Khi lng mui khan trong dung dch Y l. A.20 gam B.40 gam C.80 gam D.120 gam

Cu 9: t chy hon ton 0,1 mol mi cht FeS2 v CuS bng lng O2 d , kh sinh ra cho hp th ht vo dung dch KMnO4 1M . Th tch dung dch KMnO4 dng l A.600 ml B.300 ml C.120 ml D.240 ml Cu 10: Ha tan hn hp gm 0,2 mol Fe v 0,1 mol Fe2O3 vo dung dch HNO3 long d thu c dung dch A. Cho dung dch A tc dng vi dung dch NaOH d thu c kt ta, lc kt ta, ra sch, sy kh, nung trong khng kh n khi lng khng i thu c m gam cht rn. Tnh m. A.32 gam B.16 gam C.42 gam D.24 gam Cu 11: Cho 4,16 gam Cu tc dng vi 120 ml dung dch HNO 3 thu c 2,464 lt ktc hn hp 2 kh NO v NO2. Tnh nng mol ca HNO3? A.1 M B.0,1M C.2M D.0,5M Cu 12: Ha tan hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit HNO3 va thu c dung dch X ch cha hai mui sunfat v kh duy nht NO. Ga tr ca a l: A.0,12 mol B.0,04 mol C.0,075 mol D.0,06 mol Cu 13: tc dng va 7,68 gam hn hp gm FeO, Fe 3O4, Fe2O3 cn dng 260 ml dung dch HCl 1M. Dung dch thu c cho tc dng vi NaOH d, lc kt ta nung trong khng kh n khi lng khng i nhn c m gam cht rn. Gi tr ca m l? A.6 B.7 C.8 D.9 Cu 14: Cho hn hp A gm 3 kim loi X, Y, Z c ha tr 3, 2, 1 v t l mol tng ng 1 : 2 : 3 trong s mol X bng x mol. Ha tan hon ton A bng dung dch cha y gam HNO3 ly d 25%. Sau phn ng thu c dung dch B khng cha NH4NO3 v V lt hn hp kh G gm NO2 v NO ktc. Quan h x, y, V l? A. y = 78,75(10x + V/22,4) B.y = 78,75(10x + V/44,8) C. y = 87,75(10x + V/22,4 ) D.87,75(10x + V/44,8)

DNG 3: PHNG PHP BO TON ELECTRON

Cu 1: Ho tan hon ton 12 gam hn hp Fe, Cu t l mol 1:1 bng axit HNO 3 thu uc V lt (ktc) hn hp kh X gm NO v NO2 v dung dch Y ch cha hai mui v axit d. T khi ca X i vi H2 bng 19 . Gi tr ca V l bao nhiu? Cu 2: Cho 0,01 mol hp cht ca st tc dng ht vi H2SO4 c nng d thot ra 0,112 lt kh SO2 ktc l sn phm kh duy nht. Cng thc ca hp cht Fe l g trong: FeO, FeCO3, FeS, FeS2 Cu 3: Cho 12 gam hn hp Fe V Cu tc dng ht vi dung dch H2SO4 c nng d. Sau khi phn ng xy ra hon ton thu c 5,6 lt kh SO2 ktc v dung dch X . Khi lng ca Fe trong 12 gam hn hp u l bao nhiu? Cu 4: Hn hp X gm Cu v Fe c t l khi lng tng ng l 7:3. Ly m gam X cho phn ng xy ra hon ton vi dung dch cha 44,1 gam HNO3 sau phn ng cn li 0,75m gam cht rn v c 0,56 lt kh Y gm NO v NO2 ktc. Gi tr ca m l? S: m = 50,4 gam Cu 5: Trn 0,54 gam bt Al vi bt CuO v Fe2O3 ri tin hnh phn ng nhit nhm trong iu kin khng c khng kh. Ho tan hn hp thu c vo dung dch HNO3 d th c hn hp kh NO v NO2 vi t l mol tng ng l 1:3. Th tch 2 kh thu c l?S: 0,896 lt Cu 6: m gam phi bo st ngoi khng kh, sau mt thi gian bin thnh hn hp X c khi lng 12 gam gm Fe, FeO, Fe3O4, Fe2O3 . Cho X tc dng hon ton vi dung dch HNO3 thy gii phng ra 2,24 lt kh NO duy nht. Ga tr ca m l? S: 10.08 gam Cu 7: Trn 0,81 gam bt Al vi bt Fe2O3 v CuO ri t nng tin hnh phn ng nhit nhm thu c hn hp X. Ho tan hon ton X trong dung dch HNO 3 un nng thu c V lt kh NO iu kin tiu chun. Tnh V? S: 0,672 lit

Cu 8: Ho tan hon ton 6,4 gam Cu trong dung dch HNO3 long d thu c hn hp kh X gm 0,04 mol NO v 0,01 mol NxOy. Cng thc ca NxOy l? S: N2O Cu 9: Cho V lt hn hp kh Cl2, O2 ktc tc dng va ht vi 2,7 gam Al v 3,6 gam Mg thu c 22,1 gam sn phm. V c gi tr bng? Cu 10: Hn hp X gm hai kim loi A ,B ng trc H trong dy hat ng ho hc v c ho tr khng i trong cc hp cht . Chia m gam X thnh hai phn bng nhau . Phn I : ho tan hon ton trong dung dch cha axit HCl v H2SO4 long to ra 3,36 lt kh . Phn II : tc dng hon ton vi dung dch HNO3 thu c V lt kh NO sn phm kh duy nht Bit cc th tch kh o ktc. Tnh V? Cu 12: Trn 0,54 g bt Al vi bt Fe2O3 v CuO ri tin hnh phn ng nhit nhm thu c hn hp A. Ho tan hon ton A trong dung dch HNO3 c hn hp kh gm NO v NO2 c t l s mol tng ng l 1:3. Th tch (ktc) kh NO v NO2 ln lt l? Cu 13: Cho hn hp gm FeO, CuO, Fe3O4 c s mol ba cht u bng nhau tc dng ht vi dung dch HNO3 thu c hn hp kh gm 0,09 mol NO2 v 0,05 mol NO. S mol ca mi cht l: A. 0,12 mol. B. 0,24 mol. C. 0,21 mol. D. 0,36 mol. Cu 14: Cho a gam Al tc dng ht vi dung dch HNO3 long th thu c 0,896 lt hn hp kh X, gm N2O v NO ktc, t khi ca X so vi hiro bng 18,5. Tm gi tr ca a? A. 1,98 gam. B. 1,89 gam. C. 18,9 gam. D. 19,8 gam Cu 15: Cho tan hon ton 3,76 gam hn hp X dng bt gm S, FeS, FeS2 trong dung dch HNO3 thu c 0,48 mol NO2 v dung dch D. Cho dung dch D tc dng vi dung dch Ba(OH)2 d lc v nung kt ta n khi lng khng i thu c m gam hn hp cht rn. Tnh gi tr ca m. A.11,65 g B.12,815 g C.13,98 g D.15,145 g THM Cu 1: Cho 1,35 gam hn hp gm Cu, Mg, Al tc dng ht vi dung dch HNO3 d thu c hn hp kh gm 0,01 mol NO v 0,04 mol NO2. a.Tnh khi lng mui to ra trong dung dch : A.5,69 B.6,59 C.9,56 D.5,96 b.Tnh s mol HNO3 phn ng: A.0,05 B.0,07 C.0,12 D.0,24 Cu 2: Oxi ha hon ton 2,184 gam bt Fe thu c 3,048 gam hn hp A gm cc oxit st. Chia hn hp A thnh 3 phn bng nhau: a) Kh hon ton phn 1 cn V lt kh H2 ktc. Tnh V A.0,4032 B.0,2304 C.0,3204 D.0,4023 b) Ha tan phn th 2 bng dd HNO3 long d thu c V1 lt NO duy nht ktc. Tnh gi tr V1 A.0,0336 B.0,0448 C.0,0672 D.0,0224 c) Phn th 3 em trn vi 5,4 gam bt Al d ri tin hnh phn ng nhit nhm H = 100%. Ha tan hn hp thu c sau phn ng bng dung dch HCl d thu c V2 lt H2 . Tnh V2. A.4,608 B.5,608 C.6,608 D.7,608 Cu 3: Ha tan 19,2 gam kim loi M trong dung dch HNO3 d thu c 8,96 lt kh ktc hn hp gm NO2 v NO c t l th tch 3:1. Xc nh kim loi M v tnh khi lng HNO3 phn ng. A. Mg, 63 gam B. Zn, 63 gam C. Cu, 63 gam D. Fe, 6,3 gam Cu 4: Ha tan hon ton 11,2 gam Fe vo HNO3 d thu c dung dch A v 6,72 lt hn hp kh X gm NO v mt kh A c t l th tch 1:1. X l A.N2O B.N2O4 C.N2 D.NO2

Cu 5: m gam phoi bo st A ngoi khng kh sau mt thi gian bin thnh hn hp B c khi lng 12 gam gm Fe v cc oxit FeO, Fe2O3, Fe3O4. Cho tc dng hon ton vi axit Nitric d gii phng ra 2,24 lt kh duy nht NO. Tnh m A. 10,08 B. 5,04 C. 12,02 D. 10,08 Cu 6: Cho hn hp bt gm 2,7 gam Al v 5,6 gam Fe vo 550 ml dung dch AgNO 3 1M. Sau cc phn ng xy ra hon ton thu c m gam cht rn. Gi tr ca m l bao nhiu? A. 64,8 gam B. 54 gam C. 59,4 gam D. 32,4 gam Cu 7 : Ha tan hon ton m gam Al vo dd HNO 3 long d thu c 1,344 lt kh ktc N2 v dung dch X. Thm NaOH d vo dung dch X v un si th thu c 1,344 lt kh NH3. Gi tr ca m l? A.4,86 gam B.1,62 gam C.7,02 gam D.9,72 gam

DNG 4 : PHNG PHP GII TON ION

Phng trnh ion: iu kin c Phn ng gia cc ion: Mt trong 3 iu kin sau: + L phn ng ca Axt v Baz + Sn phm sau phn ng c kt ta. + Sn phm sau phn ng c kh Bi tp: Phn I : Vit cc phng trnh phn ng di dng ion trong cc trng hp sau: 1. Trn dung dch gm NaOH, Ba(OH)2, KOH vi dung dch gm HCl, HNO3. 2. Trn dung dch gm NaOH, Ba(OH)2, KOH vi dung dch gm HCl, H2SO4 3. Ho tan hn hp kim loi gm Na, Ba vo dung dch gm NaCl, Na2SO4 4. Ho tan hn hp kim loi gm Na, Ba vo dung dch gm HCl, H2SO4 5. Ho tan hn hp kim loi gm Na, Ba vo dung dch cha NH4NO3 6. Ho tan hn hp kim loi gm K, Ca vo dung dch cha (NH4)2CO3 7. Ho tan hn hp K, Ca vo dung dch hn hp cha NH4HCO3 8. Ho tan K, Na, Al vo nc 9. Ho tan hn hp gm Al, Fe vo dung dch hn hp gm HCl, H2SO4. 10. Trn NaOH, KOH vi NaHCO3 v Ca(HCO3)2 11. Trn dung dch gm Na2CO3, K2CO3 vi dung dch cha CaCl2, MgCl2, Ba(NO3)2 Phn II: Bi tp Cu 1: Trn 200 ml dung dch hn hp NaOH 1M, Ba(OH)2 0,5M vo 300 ml dd hn hp HCl 0,5M, H2SO4 1M Tnh nng ca cc ion cn li sau phn ng v Khi lng kt ta to thnh. Cu 2: Trn 200 ml dung dch NaHSO4 0,2M v Ba(HSO4)2 0,15M vi V lit dung dch hn hp NaOH 1M v Ba(OH)2 1M thu c dung dch c PH = 7. Tnh V v khi lng kt ta to thnh. Cu 3: Thm m gam K vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t 200 ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu uc lng kt ta Y ln nht th gi tr ca m l A.1,17 B.1,71 C.1,95 D.1,59 2+ + Cu 4: Trn dung dch Ba , OH : 0,06 mol v Na : 0,02 mol vi dung dch cha HCO3 : 0,04 mol; 2 CO3 : 0,04 mol v Na+. Khi lng (g)kt ta thu c sau phn ng l? Cu 5: Cho m gam hn hp Mg, Al vo 250 ml dung dch X cha hn hp axit HCl 1M v axit H2SO4 0,5M thu c 5,32 lt kh H2 ktc v dung dch Y. Tnh pH ca dung dch Y (Coi dung dch c th tch nh ban u).

s: pH = 1 Cu 6: Cho hn hp X cha Na2O, NH4Cl, NaHCO3 v BaCl2 c s mol mi cht u bng nhau. Cho hn hp X vo H2O d un nng dung dch thu c cha. A. NaCl B.NaCl, NaOH C.NaCl, NaOH, BaCl2 D.NaCl, NaHCO3, NH4Cl, BaCl2 Cu 7: Trn 100 ml dung dch gm Ba(OH)2 0,1M v NaOH 0,1M vi 400 ml dung dch gm H2SO4 0,0375M v HCl 0,0125M thu c dung dch X. Tnh pH ca dung dch X. Cu 8: Cho dung dch cha a mol Ca(HCO3)2 vo dung dch cha a mol Ca(HSO4)2. Hin tng quan st c l: A. Si bt kh B. vn c C. Si bt kh v vn c D. Vn c, sau trong sut tr li. Cu 10: Trn V1 ml dung dch gm NaOH 0,1M, v Ba(OH)2 0,2 M vi V2 ml gm H2SO4 0,1 M v HCl 0,2M thu oc dung dch X c gi tr pH = 13. Tnh t s V1:V2 A.4/5 B.5/4 C.3/4 D.4/3 Cu 12: Mt dd cha a mol NaHCO3 v b mol Na2CO3. Khi thm (a+b)mol CaCl2 hoc (a+b)mol Ca(OH)2 vo dd th lng kt ta thu c trong hai trng hp c bng nhau khng? A. Lng kt ta trong hai trng hp c bng nhau. B. Lng kt ta trong trng hp 2 gp i vi trng hp 1. C. Trng hp 1 c b mol kt ta, trng hp 2 c (a+b) mol kt ta. D. Trng ,hp 1 c a mol kt ta, trng hp 2 c (a+b) mol kt ta. Cu 13: in phn dung dch NaCl vi in cc tr mng ngn xp thu c dung dich c phn ng va vi Ca(HCO3)2 to ra 1 gam kt ta. Kh Cl2 thu c dn qua bnh ng KOH 1M 100oC. Tnh V KOH dng: A.100 ml B.20 ml C.10 ml D.40 ml Cu 14: Thc hin hai th nghim sau : 1. Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt kh NO . 2. Cho 3,84 gam Cu phn ng vi 80 ml dung dch cha HNO 3 1M v H2SO4 0,5M thot ra V2 lt kh NO. So snh V1 v V2 Cu 15: Cho 0,2 mol Na vo 100 ml dung dch cha CuSO4 0,1M v H2SO4 2M. Hin tng quan st c l: A.C kh bay ln B.C kh bay ln v c kt ta xanh C.C kt ta D. C kh bay ln v c kt ta mu xanh sau kt ta li tan. Cu 16 :Dung dch X c cc ion Mg2+, Ba2+, Ca2+ v 0,1 mol Cl , 0,2 mol NO3 . Thm dn V lt dung dch K2CO3 1M vo dung dch X n khi c lng kt ta ln nht. Ga tr ca V l? THM Bi ton 1: Trn 100 ml dung dch X gm KHCO3 1M v K2CO3 1M vi 100 ml dung dch Y gm NaHCO3 1M v Na2CO3 1M thu c dung dch Z. Nh t t 100 ml dung dch A gm H 2SO4 2M v HCl 1M vo dung dch Z thu c V lt kh CO2 ktc. Ga tr V l. S: 6,72 lt Bi ton 2: Cho 27,4 gam Ba vo 500 g dd hn hp gm (NH4)2SO4 1,32% v dd CuSO4 2%. Sau khi kt thc tt c cc phn ng un nh loi b ht kh ta thu c kh A, kt ta B, dd C.Tnh th tch kh A S : 6,72 lt Bi ton 3: Hn hp X gm Fe, FeO, Fe3O4, Fe2O3 vi s mol mi cht l 0,1 mol. Ha tan ht X vo dung dch Y gm HCl, H2SO4 long d thu c dung dch Z. Nh t t dung dch Cu(NO3)2 vo dung dch Z cho ti khi ngng kh NO thot ra. Tnh th tch Cu(NO3)2 dng.

S : 50 ml Bi ton 4: Cho 12,15 gam Al vo 112,5 ml dung dch NaNO3 1M v NaOH 3M khuy u cho n khi ngng thot kh ra th dng li. Tnh th tch kh thu c ktc S : 7,56 lt Bi ton 5: Nh t t dung dch HCl 1M vo 100 ml dung dch gm NaOH 1M v NaAlO 2 1,5M. Sau mt thi gian thu c 7,8 gam kt ta. Tnh th tch HCl 1M dng. S : 200 ml ; 400 ml Bi ton 6: Mt dung dch X cha 0,1 mol Ca2+, 0,5 mol Na+, 0,1 mol Mg2+, 0,3 mol Cl-, x mol HCO3 . un nng dung dch thu c bao nhiu gam mui. Bi ton 7: Mt dung dch X cha cc ion : Mg2+ , SO 2 , NH + ,. Chia thnh hai phn bng nhau . 4 4 Phn 1 : Tc dng vi NaOH d, un nng, thu c 0,58 gam kt ta v 0,672 lt kh ktc Phn 2 : tc dng vi dung dch BaCl2 d thu c 4,66 gam kt ta. Tng khi lng cc cht tan trong dung dch l: S : 6,11 Bi ton 8: t chy ht 4,04 gam mt hn hp kim loi gm Al, Fe, Cu thu c 5,96 gam hn hp 3 oxit. Ha tan ht hn hp 3 oxit bng dung dch H2SO4 long 2M th cn bao nhiu lt. S: 0,06 mol Bi ton 9: Ha tan 2,29 gam hn hp hai kim loi Ba, Na vo nc thu c dung dch A v 672 lt kh ktc. Nh t t dung dch FeCl3 vo dung dch A cho n d, lc b kt ta ra sch, sy kh v nung n khi lng khng i thu c m gam cht rn.Tnh m S: 1,6 gam

DNG 5: BI TON V NHM

V d 1: Cho t t 100 ml dung dch NaOH 5M vo 200 ml dung dch Al(NO3)3 1M Tnh nng mol ca cc ion sau phn ng. Luyn tp: Cu 1: Thm m gam K vo 300 ml dung dch cha Ba(OH)2 0,1M v NaOH 0,1M thu c dung dch X. Cho t t 200 ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. thu uc lng kt ta Y ln nht th gi tr ca m l . A.1,17 B.1,71 C.1,95 D.1,59 Cu 2: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,1M. Lung kt ta thu c l 15,6 gam. Tnh gi tr ln nht ca V? Cu 3: Th tch dung dch NaOH 2M l bao nhiu khi cho tc dng vi 200 ml dung dch X (HCl 1M AlCl3 0,5M) th thu uc kt ta ln nht? s: 250 ml Cu 4: Cho V lt dung dch hn hp 2 mui MgCl2 1M v AlCl3 1M tc dng vi 1 lt NaOH 0,5M th thu c kt ta ln nht . Tnh V. S: V = 100 ml. Cu 5: Cho V lt dung dch hn hp 2 mui MgCl2 1M v AlCl3 1M tc dng vi 1,1 lt NaOH 0,5M thu c 9,7 gam kt ta. Tnh V ln nht. S: 100 ml . Cu 6: Cho V lt dung dch NaOH 0,2M vo dung dch cha 0,15 mol AlCl3 thu c 9,86 gam kt ta. Tnh V. Cu 7: Cho 1 lt dung dch HCl vo dung dch cha 0,2 mol NaAlO2 lc ,nung kt ta n khi lng khng i c 7,65 gam cht rn. Tnh nng ca dung dch.

Cu 8: Hn hp X gm Na v Al. Cho m gam X vo lng d nc th thot ra 1 lt kh .Nu cng cho m gam X vo dung dch d th c 1,75 lt kh .Tnh thnh phn phn trm khi lng ca cc cht trong hn hp X (bit cc kh o iu kin tiu chun ). Cu 9: Chia m gam hn hp A gm Ba , Al thnh 2 phn bng nhau: -Phn 1: Tan trong nc d thu c 1,344 lt kh H2 (ktc) v dung dch B. -Phn 2: Tan trong dung dch Ba(OH)2 d c 10,416 lt kh H2 (ktc) a/ Tnh khi lng kim loi trong hn hp ban u . b/ Cho 50ml dung dch HCl vo B. Sau phn ng thu c 7,8 gam kt ta.Tnh nng mol ca dung dch HCl. Cu 10: Thm 240 ml dung dch NaOH vo cc ng 100 ml dung dch AlCl 3 nng a mol, khuy u ti phn ng hon ton thy trong cc c 0,08 mol kt ta. Thm vo cc 100 ml dung dch NaOH 1M khuy u thy phn ng xy ra hon ton thu oc 0,06 mol kt ta. Tnh nng a A.2M B.1,5M C.1M D.1,5M Cu 12: Hn hp X gm cc kim loi Al, Fe, Ba. Chia X thnh 3 phn bng nhau: Phn I tc dng vi nc d, thu c 0,896 lt kh H2 Phn II tc dng vi 500 ml dung dch NaOH 1M d thu c 1,568 lt kh H2 Phn III tc dng vi HCl d thu uc 2,24 lt kh H2 1. Tnh phn trm khi lng cc kim loi trong hn hp X 2. Sau phn ng phn II, lc c dung dch Y. Tnh th tch dung dch HCl 1M cn thm vo dung dch Y : a. Thu c lng kt ta nhiu nht. b. Thu c 1,56 g kt ta Bi thm v nhm: Cu 1: Hn hp X gm Na, Al. Cho m gam X vo mt lung nuc d thy thot ra V lt kh. Nu cho m gam X vo dung dch NaOH d th thu uc 1,75V lt kh. Thnh phn khi lung ca Na trong X l bao nhiu? S: 29,78 Cu 2: Cho 10,5 gam hn hp K v Al tan ht trong nuc uc dung dch X. Nh t t dung dch HCl 1M vo X, khi th tch dung dch HCl thm vo dng 100 ml th bt u c kt ta. T s mol K v Al trong hn hp l bao nhiu. S: 2 : 1 Cu 3: Cho a gam hn hp X gm Na, Fe, Al tc dng vi H2O d uc V1 lt kh v cht rn Y . Cho a gam X phn ng vi dd NaOH d c V2. Th tch kh o cng iu kin v V2 > V1. Kt lun no sau y ng. A. Cht rn Y l Fe B. Cht rn Y l Fe v Al C. Dung dch sau phn ng vi nuc cha Natri Aluminat v NaOH D. Dung dch sau phn ng vi nc ch cha NaOH Cu 4: Hn hp X gm kim loi kim M v Al. Ly 3,72 gam hn hp X cho vo H2O d thy gii phng ra 0,16 gam kh, cn li 1,08 gam cht rn khng tan. M l kim loi no. S : K Cu 5: Ha tan han ton hn hp X (Na, Mg, Al) vo nuc, c 8,96 lt kh ktc 5,1 gam cht rn khng tan Y v dung dch Z. Cho ton b Y vo dung dch HCl d thu oc 0,25 mol kh. Tnh khi lung ca Al trong X. S: 4,5 gam

Cu 6: Trn 6,48 gam Al vi 16 gam Fe2O3. Thc hin phn ng nhit nhm thu c cht rn A. Khi cho A tc dng vi dung dch NaOH d c 1,344 lt kh H 2 ktc thot ra. Hiu sut phn ng nhit nhm l S : 100% Cu 7: Dung dch A l dung dch NaOH C%. Ly 36 gam dung dch A trn vi 400 ml dung dch AlCl3 0,1M th lng kt ta bng khi ly 148 gam dung dch A trn vi 400 ml dung dch AlCl3 0,1M. Gi tr ca C l bao nhiu S : 4% Cu 8: Dung dch X gm NaAlO2 0,16 mol ; Na2SO4 0,56 mol ; NaOH 0,66 mol . Th tch dung dch HCl 2M cn cho vo dung dch X thu c 0,1 mol kt ta l bao nhiu . S : 0,38 lt v 0,5 lt Cu 9: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M , lng kt ta thu c l 15,6 gam . Tnh gi tr ln nht ca V. S : 2M Cu 10: Cho 200 ml dung dch Al2(SO4)3 0,5M tc dng vi 200 gam dung dch NaOH thu c 11,7 gam kt ta trng. Nng dung dch NaOH dung l bao nhiu? S : 9% hoc 13% Cu 11: X l dung dch Al2(SO4)3, Y l dung dch Ba(OH)2. Trn 200 ml dung dch X vi 300 ml dung dch Y c 8,55 gam kt ta. Trn 200 ml dung dch X vi 500 ml dung dch Y c 12,045 gam kt ta. Nng mol ca dung dch X v Y ln lt l bao nhiu. S : 0,075 M v 0,1M Cu 12: Cho a gam hn hp kim loi Zn, Cu vo 500 ml dung dch NaOH x M thu c 0,448 lt kh ktc v cn li b gam kim loi khng tan. xi ha han ton lung kim loi khng tan thu c 1,248b gam xit. Tnh x? S : 0,08M THM Bi ton tm iu kin c kt ta ln nht 1: Ha tan 28,1 gam hn hp X gm MgCO3 a% v khi lng v BaCO3 vo dung dch HCl d thu c kh A. Cho A hp th ht vo 100 ml dung dch Ca(OH)2 2M thu c kt ta B. 1. Tm a khi lng kt ta B nh nht? S : 30% 2. Tm a khi lng kt ta B nh nht? S : 100 % Bi ton tm iu kin c kt ta ln nht 2: Chia hn hp X gm 3 kim loi Al, Mg, Ba thnh 2 phn bng nhau: Phn 1 tc dng vi H2O d thu c 0,896 lt kh H2 ktc Phn 2 cho tc dng vi 50 ml dung dch NaOH 1M d thu c dd Y 1,568 lt kh H2 Tnh th tch dung dch HCl 1M cn thm vo dd Y thu c lng kt ta cc i. S: 70 ml Bi ton tm iu kin c kt ta ln nht 3: Cho 200 ml dung dch A gm MgCl2 0,3M, AlCl3 0,45M, HCl 0,55M. Thm t t V lt dung dch X gm NaOH 0,02M v Ba(OH)2 0,01 M vo dung dch A thu c kt ta Y. 1. Tm V kt ta thu c l ln nht? S: 12,5 lt 2. Tm V kt ta Y khng i? S: 14,75 lt Bi ton tm iu kin c kt ta ln nht 4: Cho 2,24 gam bt Fe vo 200 ml dd hn hp gm AgNO3 0,1M, Cu(NO3)2 0,5M, khuy u cho ti khi phn ng hon ton thu c dd A. Thm t t V ml dd NH3 2M vo dd A thu c kt ta B . 1. Tnh V lng kt ta B ln nht? S: 110 2. Ga tr V ti thiu lng kt ta B khng i l? S: 250

Bi ton tm iu kin c kt ta ln nht 5: Ha tan 9,5 gam hn hp (Al2O3, Al, Fe) vo 900 ml dd HNO3 thu c dd A v 3,36 lt kh NO duy nht ktc. Cho t t dd KOH 1M vo dung dch A cho n khi lng kt ta khng i na th dng ht 850 ml, lc kt ta thu c, nung n khi lng khng i nhn c 8 gam cht rn. Nu mun thu c lng kt ta ln nht cn bao nhiu ml dd KOH 1M vo dd A? S: 750 ml Bi ton tm iu kin c kt ta ln nht 6: Cho t t 75 ml dung dch Ba(OH)2 a M vo 25 ml dung dch Al2(SO4)3 b M va c lng kt ta ln nht bng 17,1 gam. Gi tr a, b ln lt l? S: 0,8 v 0,8 Bi ton tm iu kin c kt ta ln nht 7: 2 2 Dung dch A cha cc ion Na+ a mol, HCO3 b mol, CO3 c mol v SO 4 d mol. to ra lng kt ta ln nht th ngi ta cho dung dch A tc dng vi 100 ml dung dch Ba(OH)2 nng x M. Gi tr ca x l? S: (a+b)/2 BI TON NHIT NHM Cu 1: Nung m gam hn hp A gm Al, Fe2O3 trong iu kin khng c oxi thu c hn hp B, bit phn ng xy ra hon ton. Chia B thnh hai phn bng nhau: Ha tan phn I trong H2SO4 long d, thu c 1,12 lt kh ktc. Ha tan phn II trong dung dch NaOH d th khi lng cht khng tan l 4,4 gam. Tnh gi tr ca m. s: 13,9 gam Cu 2: Nhit nhm hon ton 26,8 gam Al v Fe2O3 thu c cht rn A. Ha tan hon ton A trong dung dch HCl d thu c 11,2 lt kh H2 ktc. Khi lng Fe 2O3 trong hn hp u l bao nhiu. S: 16 gam

DNG 6: BI TON IN PHN

Cu 1: in phn 100ml dung dch cha AgNO3 0,1M v Cu(NO3)2 0,1M vi cng dng in I l 1,93A. Tnh thi gian in phn (vi hiu xut l 100%). 1) kt ta ht Ag (t1) 2) kt ta ht Ag v Cu (t2) A. t1 = 500s, t2 = 1000s B. t1 = 1000s, t2 = 1500s C. t1 = 500s, t2 = 1200s D. t1 = 500s, t2 = 1500s Cu 2: in phn 100ml dung dch CuSO4 0,2M vi cng I = 9,65 A.Tnh khi lng Cu bm bn catot khi thi gian in phn t1 = 200s v t2 = 500s (vi hiu sut l 100%). A. 0,32g ; 0,64g B. 0,64g ; 1,28g C. 0,64g ; 1,32g D. 0,32g ; 1,28g Cu 3: in phn 100ml dung dch CuSO4 0,1M cho n khi va bt u si bt bn catot th ngng in phn. Tnh pH dung dch ngay khi y vi hiu sut l 100%. Th tch dung dch c xem nh khng i. Ly lg2 = 0,30. A. pH = 0,1 B. pH = 0,7 C. pH = 2,0 D. pH = 1,3 Cu 4: in phn 100ml dung dch cha NaCl vi in cc tr, c mng ngn, cng dng in I l 1.93A. Tnh thi gian in phn c dung dch pH = 12, th tch dung dch c xem nh khng thay i, hiu sut in phn l 100%. A. 100s B. 50s C. 150s D. 200s Cu 5: in phn 100 ml dd CuSO4 0,2M v AgNO3 0,1M vi cng dng in I = 3,86A. Tnh thi gian in phn c mt khi lng kim loi bm bn catot l 1,72g. A. 250s B. 1000s C. 500s D. 750s

Cu 6: in phn 100ml dung dch CuCl2 0,08M. Cho dung dch thu c sau khi in phn tc dng vi dung dch AgNO3 d th thu c 0,861g kt ta. Tnh khi lng Cu bm bn catot v th tch kh thu c bn anot. A. 0,16g Cu; 0,056 l Cl2 B. 0,64g Cu; 0,112 l Cl2 C. 0,32g Cu; 0,112 l Cl2 D. 0,64g Cu; 0,224 l Cl2 Cu 7: in phn 100ml dung dch CuSO4 0,1M vi cng I = 9065A. Tnh th tch kh thu c bn catot v bn anot lc t1 = 200s v t2 = 300s. A. catot: 0;112ml; anot: 112;168ml C. catot: 0;112ml; anot: 56;112ml B. catot: 112;168ml; anot: 56;84ml D. catot: 56;112ml; anot: 28;56ml Cu 8: in phn 100ml dung dch AgNO3 0,2M. Tnh cng I bit rng phi in phn trong thi gian 1000s th bt u si bt bn catot v tnh pH ca dung dch ngay khi y. Th tch dung dch c xem nh khng thay i trong qu trnh in phn. Ly lg2 = 0,30. A. I = 1.93A,pH = 1.0 B. I = 2.86A,pH = 2.0 C. I = 1.93A,pH = 1.3 D. I = 2.86A,pH = 1.7 Cu 9: in phn 200ml dung dch CuSO4 0,1M v MgSO4 cho n khi bt u si bt bn catot th ngng in phn. Tnh khi lng kim loi bm bn catot v th tch (ktc) thot ra bn anot. A. 1.28g; 2.24 lt B. 0.64; 1.12lt C. 1.28g; 1.12 lt D. 0.64; 2.24 lt Cu 11: in phn 100 ml hn hp dd gm FeCl 3 1M, FeCl2 2M, CuCl2 1M v HCl 2M vi in cc tr c mng ngn xp cng dng in l 5A trong 2 gi 40 pht 50 giy catot thu c A.5,6 g Fe B.2,8 g Fe C.6,4 g Cu D.4,6 g Cu Cu 12: in phn hon ton dung dch hn hp gm a mol Cu(NO 3)2 v b mol NaCl vi in cc tr, mng ngn xp. dung dch thu c sau khi in phn c kh nng phn ng vi Al2O3 th A. b = 2a B.b > 2a C.b < 2a D.b < 2a hoc b > 2a Cu 13: in phn 500 ml dung dch A FeSO4 v KCl vi in cc tr, gia cc in cc c mng ngn xp ngn cch. Sau khi in phn xong anot thu c 4,48 lt kh B ktc. ca tt thu c kh C v bnh in phn thu c dung dch D. Dung dch D ha tan ti a 15,3 gam Al2O3. 1. Tnh nng mol/l cc cht trong A 2. Tnh th tch kh C thot ra catot 3. Sau khi in phn khi lng dung dch A gim i bao nhiu gam? Cu 14: in phn 200 ml dung dch hn hp gm HCl 0,1M v CuSO 4 0,5M bng in cc tr. Khi catot c 3,2 gam Cu th th tch kh thot ra Anot l A.0,56 lt B.0,84 lt C.0,672 lt D.0,448 lt

DNG 7 : BI TON CO2

Cu 1: Cho 1,568 lt CO2 ktc li chm qua dung dch c ha tan 3,2 gam NaOH. Hyxc nh khi lng mui sinh ra? Cu 4 : Cho 8 lt hn hp kh CO v CO 2 trong CO2 chim 39,2 % i qua dung dch c cha 7,4 gam Ca(OH)2. Hy xc nh s gam kt ta thu c sau phn ng? Cu 5: Cho m gam tinh bt ln men thnh ancol etylc vi hiu sut 81%.Ton b lng CO 2 vo dung dch Ca(OH)2 thu c 550 gam kt ta v dung dch X. un k dung dch X thu thm c 550 gam kt ta. Ga tr ca m l? Cu 6 : Hp th hon ton 2,688 lt kh CO2 ktc vo 2,5 lt dung dch Ba(OH)2 nng a mol/l, thu c 15,76 gam kt ta. Gi tr ca a l? Cu 7: Cho 3,36 lt kh CO2 ktc vo 200 ml dung dch cha NaOH 1M v Ba(OH) 2 0,5M. Khi lng kt ta thu c sau phn ng l?

Cu 8: Dn 5,6 lt CO2 hp th hon ton vo 500 ml dung dch Ca(OH)2 nng a M th thu c 15 gam kt ta. Gi tr ca a l? Cu 9: Dn 112 ml CO2 ktc hp th han ton vo 200 ml dung dch Ca(OH) 2 thu c 0,1 gam kt ta. Nng mol ca nc vi trong l? Cu 10: Dn 5,6 lt CO2 hp th hon ton vo 200 ml dung dch NaOH nng a M thu c dung dch c kh nng tc dng ti a 100 ml dung dch KOH 1M.Tnh a? Cu 11: Kh hon ton 4,06 gam mt xit kim loi bng CO nhit cao thnh kim loi. Dn ton b khi ssinh ra vo bnh ng dung dch Ca(OH)2 d, thy to thnh 7 gam kt ta. Nu ly lng kim loi sinh ra ha tan ht vo dung dch HCl d th thu c 1,176 lt kh H2 ktc. 1. Xc nh cng thc oxit kim loi 2. Cho 4,06 gam oxit kim loi trn tc dng hon ton vi 500 ml dung dch X v c kh SO2 bay ra. Hy xc nh nng mol/l ca mui trong dung dch X.

DNG 8 : TRUNG HA IN TCH

L THUYT Mt dung dch tn ti cc ion: Aa+ (m mol), Bb+ (n mol) v cc aninon Cc- (x mol), Dd- (y mol) Ta c phng trnh trung ho in:

A .m + b.n x.c y.d = 0

Cc v d n gin : 2 VD 1: Dung dch tn ti cc ion sau: Al3+ 0,5 mol; Fe3+ 0,5 mol; NO3 0,5 mol; SO 4 x mol. Tnh x? VD 2: Dung dch A c cha cc ion Ba2+, Ca2+, NO3 0,2 mol, Cl 0,2 mol. Tnh th tch ca MgSO4 2M va to kt ta ht vi cc ion c trong dung dch. S: V = 100 ml VD 3: Dung dch A c cha cc ion : Ca2+ 0.2 mol, Na+ 0.2 mol v Cl a mol v NO3 b mol. Khi c cn thu c 36,55 gam. Tnh a, b? S: a = 0,5; b = 0,1 BI TP Cu 1: Mt dung dch tn ti 3 ion: Al3+, Cu2+, SO 2 tc dng va vi 800 ml dung dch Ba(OH)2 4 0,5M . Thu c kt ta, nung kt ta trong khng kh n khi lng khng i thu c 111,4 gam. Tnh khi lng mui ban u? S: 50,2 gam Cu 2: Mt dung dch cha cc ion Fe2+, Cu2+, Cl , cho 1 lng 600 ml dung dch AgNO3 1M phn ng va vi dung dch trn thu c 82,55 gam cht rn. Tnh khi lng mui ban u. Cu 3: Dung dch A cha cc ion Mg2+, Ca2+, HCO3 tc dng va vi 400 ml dung dch Ca(OH)2 1M. Sau phn ng ch thu c kt ta v H2O.Tnh khi lng mui ban u. Cu 4: Dung dch Xc cha cc ion Ca2+, Al3+, Cl . lm kt ta ht ion Cl trong 10 ml dung dch phi dng ht 70 ml AgNO3 1M. Khi c cn dung dch X thu c 35,55 gam mui khan. Tnh nng mol/l ca Ca2+ trong X. 2 Cu 5: Dung dch Ba2+; OH 0,06 v Na+ 0,02 mol vi dung dch cha HCO3 0,04 mol; CO3 0,04 mol v Na+. Khi lng kt ta thu c sau phn ng l? Cu 6: Dung dch X gm c cc ion: Mg2+, Ba2+, Ca2+ v 0,1 mol Cl , 0,2 mol NO3 . Thm dn V lt dung dch K2CO3 1M vo dung dch X n khi c lng kt ta ln nht. Ga tr ca V(ml) l?

Cu 7: Dung dch cha 0,02 mol Cu2+, 0,03 mol K+, x mol Cl , y mol SO 2 . Tng khi lng cc 4 mui tan c trong dung dch l 5,345 gam. Ga tr ca x v y l?

DNG 9 : CU TO NGUYN T
Cu 1: Cho hai nguyn t c cu hnh electron nguyn t l: + Nguyn t X: 1s22s22p63s2 + Nguyn t Y: 1s22s22p63s23p63d34s2 - X v Y c thuc cng mt nhm nguyn t khng? Gii thch - Hai nguyn t ny cch nhau bao nhiu nguyn t ho hc? C cng chu k khng? Cu 2: Nguyn t X chu k 3, nhm VA ca bng tun hon. a) Vit cu hnh electron ca X. b) Vit cu hnh electron ca nguyn t nguyn t cng nhm thuc hai chu k k tip (trn v di) Gii thch ti sao li vit c nh vy. Cu 3: Cho nguyn t X c Z = 30 a) Vit cu hnh electron nguyn t X b) Vit cu hnh electron ca nguyn t nguyn t cng chu k,thuc hai nhm lin tip (trc v sau) vi nguyn t X v hy gii thch v sao li vit c nh vy. Cu 4: Cho hai nguyn t X v Y hai lin tip nhau trong mt chu k ca bng HTTH v c tng s proton bng 27. Hy vit cu hnh electron nguyn t v xc nh v tr ca chng trong bng HTTH. Cu 5: Cho hai nguyn t A, B ng k tip nhau trong bng HTTH v c tng s n v in tch ht nhn l 37. a) C th khng nh A, B thuc cng mt chu k khng? Xc nh ZA, ZB. b) Xc nh v tr ca A, B trong bng TH. Cho bit A, B l kim loi, phi kim, hay kh him? Cu 6: Cho 1,2 gam mt kim loi thuc nhm IIA trong bng HTTH tc dng vi HCl thu c 0,672 lt kh (ktc). Tm kim loi , vit cu hnh electron nguyn t, nu r v tr trong bng HTTH. Cu 7: Cho 0,78 gam mt kim loi nhm IA tc dng vi HCl thu c 0,224 lt kh thot ra (ktc). nh tn kim loi . Cu 8: Khi cho 5,4 gam mt kim loi M tc dng vi oxi khng kh thu c 10,2 gam 1 oxit M 2O3. Tm tn kim loi M. Cu 9: A l nguyn t chu k 3. Hp cht ca A vi cacbon cha 25% cacbon v khi lng,v khi lng phn t ca hp cht l 144 u. nh tn nguyn t A,cng thc phn t ca hp cht. Cu 10: Mt nguyn t B to thnh 2 loi oxit c cng thc AOx v AOy ln lt cha 50% v 60% oxi v khi lng. Xc nh nguyn t B v cng thc phn t hai oxit. Cu 11: Cho 8,8 gam hn hp 2 kim loi thuc hai chu k lin tip nhau v thuc nhm IIIA, tc dng vi HCl d th thu c 6,72 lt kh hiro (ktc). Da vo bng tun hon cho bit tn hai kim loi . Cu 12: X, Y l 2 halogen (thuc nhm VIIA) 2 chu k lin tip. Ha tan 16,15 gam hn hp NaX v NaY vo nc sau cho tc dng vi dung dch AgNO3 d thu c 33,15 gam kt ta. Xc nh tn ca X, Y v phn trm khi lng mi mui trong hn hp u. Cu 13: C hp cht MX3 trong : Tng s proton, ntron, elctron l 196. S ht mang in nhiu hn s ht khng mang in l 60. S khi ca M nh hn s khi ca X l 8. Tng s proton, ntron, elctron trong X nhiu hn trong ion M3+ l 16. Xc nh v tr ca M v X trong bng tun hon

DNG 10: BI TON KH N2, NO2, Cl2

KH NIT Dng I: Hiu sut phn ng Cu 1: Mt hn hp A gm hai kh N2 v H2 theo t l mol 1 : 3 cho chng phn ng vi nhau to NH3. Sau phn ng thu c hn hp kh B. T khi hi ca A i vi B l 0,6. Tnh hiu sut phn ng tng hp NH3. Cu 2: Mt hn hp kh gm N2 v H2 c t khi i vi H2 bng 3,6. Sau khi un nng mt thi gian h t ti trng thi cn bng th t khi ca hn hp sau phn ng i vi H2 bng 4,5. a) Xc nh %V hn hp trc v sau phn ng. b) Tnh H%. KH CLO Cu 1: Dn hon ton 0,112 lt kh Cl2 vo 200 ml dung dch NaOH nhit thng. Sau phn ng, nng NaOH cn li l 0,05 M gi thit th tch dung dch khng thay i. Nng ban u ca dung dch NaOH l. A.0,2 M B.0,15 M C.0,05 M D.0,1 M Cu 2: Khi cho 10,5 gam NaI vo 50 ml dung dch Br2 0,5M, khi lng NaBr thu c l: A.10,5 g B.4,67 g C.5,15 g D.2,575 g Cu 3: Ho tan hon ton 104,25 gam hn hp X gm NaCl, NaI vo nc c dung dch. Sc kh Cl2 d vo dung dch A. Kt thc th nghim, c cn dung dch thu c 58,5 gam mui khan. Khi lng NaCl c trong hn hp X l: A.29,25 gam B.58,5 g C.17,55 g D.23,4 g Cu 4: Dn hai lung kh Cl2 i qua 2 dung dch KOH, dung dch (I) long ngui, dung dch (II) m c, nng. Nu lng mui KCl sinh ra trong hai dung dch bng nhau th t l th tch kh Cl 2 i qua 2 dung dch KOH (I) v (II) l? A.5/6 B.6/3 C.10/3 D.5/3 Cu 5: Cho 13,44 lt kh Cl2 ktc i qua 2,5 lt dung dch KOH 100 oC. Sau phn ng xy ra hon ton, thu c 37,25 gam KCl. Dung dch KOH trn c nng l. A.0,24 M B.0,2 M C.0,48 M D.0,4 M Cu 6: Hn hp A gm hai mui NaX v NaY (X , Y l hai halogen k tip nhau). kt ta hon ton 2,2 gam hn hp A cn 150 ml dung dch AgNO3 0,2M A.Cl v Br B.Br v Cl C.Br v I D.I v Br Cu 7: Cho 356 gam hn hp X gm NaBr v NaI tc dng vi 0,4 mol Cl2 thu c cht rn A (sau khi c cn dung dch) c khi lng l 282,8 gam. Tnh s mol mi cht trong hn hp X gi s lng Clo ti thiu cho cht rn A ch cha mui l 35,5 gam Cl2. A.2 mol NaBr v 1 mol NaI B.1 mol NaBr v 2 mol NaI C.2 mol NaBr v 3 mol NaI D.3 mol NaBr v 1 mol NaI Cu 8: Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t ZX < ZY) vo dung dch AgNO3 (d), thu c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l A. 58,2%. B. 52,8%. C. 41,8%. D. 47,2%.

DNG 11: CC BI TP ST
Cu 1: Cho 16,8 gam bt st vo 800 ml dung dch HNO3 0,5 M thu c kh NO duy nht. Tnh: Th tch kh thu c Tnh khi lng kim loi cn d. Khi lng mui thu c S: V = 2.24 lt, m kim loi d = 8.4 g, m Fe(NO3)2 = 27 g Cu 2: Cho 16,8 gam bt st vo V lt dung dch HNO3 0,5 M thu c 8,4 gam kim loi d. Tnh th tch kh thu c. S : V = 2.24 l Cu 3: Cho 16,8 gam bt Fe vo 400 ml dung dch HNO3 1M, thu c kh NO duy nht, lng mui thu c cho vo dung dch NaOH d thu c kt ta. Nung nng kt ta thu c m gam cht rn. Tnh m? S: mFeO = 10,.8 gam Cu 4: Cho m gam Fe vo 400 ml dung dch HNO3 1M thu c V lt kh NO duy nht v 14 gam kim loi. Tnh m? V? S: m = 22.4 gam , V = 2,24 lt Cu 5: Cho m gam Fe vo 800 ml dung dch HNO3 1M thu c V lt kh NO v dung dch A. Cho dung dch A tc dng vi dung dch NaOH d thu c kt ta B. em nung B trong khng kh thu c 18,8 gam cht rn. Tnh V? m? S: m = 14 gam , V = 2.24 lt Cu 6: Cho 5,6 gam bt Fe tc dng vi 500 ml dung dch AgNO 3 0,5 M. Tnh khi lng mui thu c, khi lng kim loi thu c. S : m mui = 21.1 gam , m Ag = 27 gam Cu 7: Cho 18,5 gam hn hp Z gm Fe, Fe3O4 tc dng vi 200 ml dung dch HNO3 long un nng v khuy u. Sau phn ng xy ra han ton thu c 2,24 lt kh NO duy nht ktc, dung dch Z1 v cn li 1,46 gam kim loi. 1. Vit phng trnh phn ng ha hc xy ra 2. Tnh nng mol/lit ca dung dch HNO3 3. Tnh khi lng mui trong dung dch Z1 Cu 9: Kh 4,8 gam mt oxit ca kim loi trong dy in ha nhit cao cn 2,016 lt kh H 2 ktc. Kim loi thu c em ha tan trong dung dch HCl thu c 1,344 lt kh H2 ktc. Hy xc nh cng thc ha hc ca oxit dng. Cu 10: Mt dung dch c ha tan 1,58 gam KMnO4 tc dng vi dung dch hn hp c ha tan 9,12 gam FeSO4 v 9,8 gam H2SO4. Hy tnh s gam cc cht c trong dung dch sau phn ng. Cu 11: Hn hp X gm Cu v Fe c t l khi lng tng ng l 7:3. Ly m gam X cho phn ng xy ra hon ton vi dung dch cha 44,1 gam HNO3 sau phn ng cn li 0,75m gam cht rn v c 0,56 lt kh Y gm NO v NO2 ktc. Gi tr ca m l? S : m = 50,4 gam Bi tp v FexOy :

Cu 1: Dng CO kh han ton m gam FexOy, dn ton b kh sinh ra qua 1 lt dung dch Ba(OH)2 0,1M thu c 0,05 mol kt ta. Mt khc ha tan m gam Fe xOy bng dung dch HCl d ri c cn th thu c 16,25 gam mui khan. Gi tr ca m l bao nhiu. S: 8 gam Cu 2: Ha tan han ton a gam mt oxit st bng dung dch H2SO4 c nng va , c cha 0,075 mol H2SO4 thu c b gam mt mui khan v c 168 ml kh SO2 ktc duy nht thot ra. Gi tr ca b l bao nhiu? S: 9 gam Cu 3: Cho 44,08 gam mt oxit st FexOy c ha tan ht bng dung dch HNO3 long thu c dung dch X. Cho dung dch NaOH d vo dung dch X thu c kt ta. em nung lng kt ta ny nhit cao cho n khi lung khng i thu uc mt oxit kim loi. Dng H 2 kh ht lng oxit ny th thu c 31,92 gam cht rn l mt kim loi. Tm oxit FexOy. S : Fe3O4 Cu 4: Ha tan han ton oxit FexOy bng dung dch H2SO4 c nng va thu c 2,24 lt kh SO2 ktc . C cn dung dch sau phn ng thu uc 120 gam mui khan . Cng thc ca oxit Fe xOy l g. S : Fe3O4 Cu 5: Cho 6,94 gam hn hp FexOy v Al ha tan trong 100 ml dung dch H2SO4 1,8M, sinh ra 0,672 lt H2 ktc. Bit lng axit ly d 20% so vi lng cn thit phn ng. Tm cng thc ca xit st S : Fe2O3 Cu 6: Cho 4,48 lt kh CO ktc t t qua ng s nung nng ng 8 gam mt oxit st n khi phn ng xy ra hon ton. Kh thu c sau phn ng c t khi so vi H2 bng 20. Cng thc ca oxit st v phn trm th tch ca kh CO2 trong hn hp sau phn ng l bao nhiu. S : Fe2O3; 75% Bi tp thm v mui Fe III Cu 1: Cho 5,8 gam FeCO3 tc dng va vi dung dch HNO3 oc hn hp kh CO2, NO v dung dch X. Khi thm H2SO4 d vo X th dung dch thu uc ha tan ti a bao nhiu gam Cu, bit rng ch c kh NO bay ra. S: 16 gam Cu 2: Ha tan 1,52 gam hn hp Fe, Cu vo 200 ml dung dch HNO3, sau khi phn ng xy ra han ton thu oc dung dch A v 224 ml kh NO duy nht ktc v cn 0,64 gam kim loi d khng b ha tan. Nng mol ca dung dch HNO3 ban u l bao nhiu. S: 0,2M Cu 3: Hn hp X gm Fe, Cu vi t l khi lung l 4 : 6. Ha tan m gam X bng dung dich HNO 3 thu c 0,448 lt kh NO sn phm kh duy nht, ktc, dung dch Y v c 0,65m gam cht rn khng tan. Khi lung mui khan trong dung dch Y l bao nhiu? S: 5,4 gam Cu 4: Ha tan 30 gam hn hp A gm Mg v Fe2O3 bng dung dch H2SO4 long d thy thot ra V lt kh H2 ktc v thu uc dung dch B. Thm t t NaOH cho n d vo dung dch B. Kt thc th nghim, lc ly kt ta em nung ngoi khng kh n khi lng khng i thu c 42 gam cht rn. Tnh V. S: 15,12 Cu 5: Cho 8,64 gam hn hp gm Fe v Fe3O4 tc dng va vi 200 ml dung dch HNO3 long, nng. Sau khi phn ng xy ra hon ton thu c 0,896 lt kh NO duy nht. Tnh nng ca HNO3 dung. S: 2M Cu 6: Hn hp A gm 16,8 gam Fe, 6,4 gam Cu v 2,7 gam Al. Cho A tc dng vi dung dch HNO3, ch thot ra kh N2 duy nht, trong dung dch thu c khng c ion NH + . Tnh th tch dung 4 dch HNO3 2M ti thiu ha tan hon ton hn hp A. S: 660 ml Cu 7: Cho m gam Fe vo 0,2 lt dung dch X cha HNO3 0,1M v H2SO4 0,2M sau phn ng cn 0,2m gam loi cha tan ht, thu c dung dch Y v hn hp NO, H2. Tnh m. Cu 8: Cho m gam Fe phn ng vi va ht vi H 2SO4 c kh A, sn phm kh duy nht khng phn ng c vi CuSO4. Bit s mol Fe phn ng bng 37,5 % s mol H2SO4. Tm m. Cu 9: Ha tan hon ton m gam Fe trong dung dch H2SO4 c nng c dung dch HCl c, chia X lm hai phn bng nhau:

- Phn I: Cho phn ng vi 700 dung dch KMnO 4 0,1M thm tip dung dch HCl c vo dung dch sau phn ng thy c 0,56 lt kh thot ra - Phn II: em c cn th thu c 65,6 gam mui. Tnh m.

DNG 12: BI TP V HNO3 V MUI NITRAT

Cu 1: Nung nng hn hp 27,3 gam hn hp NaNO 3, Cu(NO3)2. Hn hp kh thot ra c dn vo 89,2 ml nc th cn d 1,12 lt kh ktc khng b hp th. Tnh khi lng ca mi mui trong hn hp u Cu 2: Cho bt Cu d vo V1 lt dung dch HNO3 4M v vo V2 lt dung dch HNO3 3M v H2SO4 1M. NO l kh duy nht thot ra. Xc nh mi quan h gia V1 v V2 bit rng kh thot ra hai th nghim l nh nhau. Cu 3: Thc hin hai th nghim: 1) Cho 3,84 gam Cu phn ng vi 80 ml dung dch HNO3 1M thot ra V1 lt NO. 2) Cho 3,84 gam Cu phn ng vi 80 ml dd cha HNO3 1M v H2SO4 0,5 M thot ra V2 lt NO. Bit NO l sn phm kh duy nht, cc th tch kh o cng iu kin. Quan h gia V1, V2 A. V2 = V1. B. V2 = 2V1. C. V2 = 2,5V1. D. V2 = 1,5V1. Cu 4: Cho 200 ml gm HNO3 0,5M v H2SO4 0,25M tc dng vi Cu d c V lit NO (ktc) c cn dung dch sau phn ng c m gam mui khan. V v m c gi tr ln lt l: A. 2,24; 12,7 B.1,12 ; 10,8 C.1,12 ; 12,4 D.1,12 ; 12,7 Cu 5: Cho 0,96 gam Cu vo 100ml dung dch cha ng thi KNO 3 0,08M v H2SO4 0,2M sinh ra V (lit) mt cht kh c t khi so vi H2 l 15 v dung dch A. V c gi tr l: A. 0,1702 lit B. 0,3584 lit C. 0,448 lit D. 0,336 lit

DNG 13: CHUYN DCH CN BNG VN TC PHN NG

1. Cch tnh hiu ng nhit: Tnh theo lin kt E Q = Tng E sn phm Tng E ban u Tnh theo sinh nhit: Q = Tng Sn Sn phm Tng Sn ban u Sinh nhit ca n cht bng 0 2. Vn tc tc thi ca phn ng l Xt phn ng : m A + n B p C + q D Vn tc ca phn ng l : V = k.[A]m.[B]n Trong K l hng s tc phn ng, ch ph thuc vo nhit , [] l nng mol/l ca cc cht. A, B l cc cht kh hay dung dch 3. Vn tc trung bnh ca phn ng: v =
1 A 2 A1 1 C 2 C1 . = . m t 2 t1 p t 2 t1
2 1

4. S ph thuc ca vn tc vo nhit phn ng . Vt = Vt . 10 Trong l h s nhit ca phn ng. l s ln tng ca vn tc phn ng khi tng ln 10oC. 5. Phn ng thun nghch v cn bng ha hc Xt phn ng thun nghch : m A + n B p C + q D Vt = Kt.[A]m.[B]n

(t 2 t1 )

Vn = Kn.[C]p.[D]q

K [ C ] .[ D ] T ta c hng s cn bng ca phn ng: K cb = t = K n [ A ] m . [ B] n

p q

Cu 1: Phn ng gia hai cht kh A, B c biu din bng phng trnh sau A + B = 2C Tc phn ng l V = K.[A].[B]. Thc hin phn ng ny vi s khc nhau v nng ban u mi cht Trng hp 1: Nng mi cht l 0,01 mol/l Trng hp 2: Nng mi cht l 0,04 mol /l Trng hp 3: Nng ca cht A l 0,04 mol/l ca cht B l 0,01 mol/l. Tnh tc ph ng ca mi trng hp. So snh Cu 2: Tc phn ng ha hc c biu din theo phng trnh v = K.[A]x.[B]y . Gi nng B khng i, tng A ln hai ln th tc phn ng tng 2 ln Gi nng A khng i, tng B ln hai ln th tc phn ng tng 4 ln. Hy tnh x, y Cu 3: Cho phn ng ca cc cht kh sau: Ak + 2Bk Ck + Dk Hi tc phn ng tng hay gim bao nhiu ln i vi mi trng hp sau [A] = 2[A] v [B] = 2[B] [A] = [A] v [B] = 2[B] b. Nu nng ca A, B ban u khng i th tc phn ng (1) tng bao nhiu ln nu nhit tng ln 40oC . Bit rng c tng ln nhit thm 10oC th phn ng tng 2 ln. Cu 4: Xt phn ng: m A + n B p C + q D TN1: [A] = 0,5M, [B] = 0,5 M, v1 = 62,5.10-4 mol/l.S TN2: [A] = 0,5M, [B] = 0,8 M, v2 = 16.10-3 mol/l.S TN3: [A] = 0,8M, [B] = 0,8 M, v3 = 2,56.10-2 mol/l.S a. Da vo cc gi tr trn hy xc nh m, n b. Tnh hng s tc phn ng. Cu 5 : Nng ban u ca SO2 v O2 trong h l SO2 + O2 = SO3 trng ng l 4 mol/l v 2 mol/l A. Tnh hng s cn bng ca phn ng bit rng khi t cn bng c 80% SO2 phn ng B. cn bng c 90% SO2 phn ng th lng oxi lc u ly vo l bao nhiu C. Nu tng p sut ln hai ln th cn bng chuyn dch theo chiu no.

DNG 13: BI TON TNG GIM KHI LNG

Cu 1: Cho 1,12 gam bt Fe v 0,24 gam bt Mg tc dng vi 250 ml dung dch CuSO 4 khuy nh cho n khi mu xanh mt i. Nhn thy khi lng kim loi sau phn ng l 1,88 gam. Nng mol/l ca dung dch CuSO4 l bao nhiu. A.0,15M B.0,05M C.0,1M D.0,12M Cu 2: Hai thanh kim loi ging nhau u cng ngun t R v ha tr II v c cng khi lng. Cho thanh th nht vo dung dch Cu(NO3)2 v thanh th hai vo dung dch Pb(NO3)2. Sau mt thi gian khi s mol 2 mui bng nhau, ly 2 thanh kim loi ra khi dung dch thy khi lng thanh th nht gim 0,2% cn khi lng thanh th hai tng 28,4%. Nguyn t R l nguyn t no di y. A. Mg B. Cu C. Fe D. Zn

Cu 3: Hai thanh kim loi cng cht c khi lng bng nhau. Mt c ngm trong dung dch CuCl2, mt c ngm trong dung dch CdCl2. Sau mt thi gian phn ng, ngi ta nhn thy khi lng l kim loi ngm trong dung dch CuCl2 tng 1,2 % v khi lng l kim loi kia tng 8,4%. Bit s mol CuCl2 v CdCl2 trong hai dung dch gim nh nhau v kim loi b oxi ha thnh ion kim loi c in tch +2. Tm kim loi dung? Cu 4: Ngm mt l Zn kim loi vo dung dch c cha 8,32 gam CdSO 4, sau khi phn ng dung dch khng cn Cd2+ th thy thanh kim loi tng 2,35% so vi ban u. Khi lng Zn ban u l. A.81g B.8 g C.13 g D.80 g

DNG 14: BI TON NNG C% - CM

Cu 1: Ha tan hon ton 10,2 gam oxit kim loi kim loi ha tr III cn 331,8 gam dung dch H2SO4 th va . Dung dch sau phn ng c nng 10%. Cng thc phn t ca oxit kim loi l: A.Fe2O3 B.Al2O3 C.Cr2O3 D.Mn2O3 Cu 2: Ha tan mt kim loi M ha tr II vo dung dch HCl 14,6% c dung dch mui c nng 18,19%. Tm M? Cu 3: Ha tan va mt hidroxit ca kim loi M c ha tr II trong dung dch H2SO4 20% thu c dung dch mui c nng 27,21%. Tm M Cu 4: Cho mt l ng c khi lng 10 gam vo 250 gam dung dch AgNO3 4%. Khi ly l ng ra th khi lng mui AgNO3 trong dd gim 17%. Khi lng l ng sau phn ng l bao nhiu Cu 5: Ha tan 20 gam mui K2SO4 vo 150 gam nc c dung dch A, in phn dung dch A vi in cc tr cho n khi c dung dch c nng phn trm l 14,925%. Th tch kh sinh ra anot (20oC, 1atm) l bao nhiu . Cu 6: Ho tan hon ton hn hp X gm Fe, Mg bng mt lng va dung dch HCl 20%, thu c dung dch Y. Nng ca FeCl2 trong dung dch Y l 15,76 %. Nng % ca MgCl2 trong dung dch Y l? A.11,79% B.24,24% C.28,21% D.15,76%

THM
Bi ton 1: Ha tan 92 gam ancol etylic vo nc thu c 250 ml dung dch X. Gi thit khng c s hao ht v th tch cc cht khi pha trn v khi lng ring ca C 2H5OH l 0,8 g/ml. Tnh C% ca X. S : 40% Bi ton 2: Cho dung dch X gm RCOOH x mol/l v RCOOM y M . Ly 50 ml X tc dng vi 120 ml Ba(OH)2 0,125M thu c dung dch Y. Trung ha Ba(OH)2 d trong Y cn 3,75 gam dung dch HCl 14,6%. Mt khc, nu ly 50 ml dung dch X cho phn ng vi H 2SO4 long d sau chng ct thu c 784 ml hi RCOOH ktc. Tnh x, y . S: 0,3M v 0,5=4M Bi ton 3: Cho 104 gam dung dch BaCl2 10% v 200 gam dung dch H2SO4. Lc b kt ta , trung ha dung dich nc lc cn dng 250 ml dung dch NaOH 25% ( d = 1,28 g/ml ). Tnh % H2SO4 S : 51,45% Bi ton 4: Cho hidroxit mt kim loi nhm IIA tc dng va vi dung dch H 2SO4 20% th thu c mt mui c nng 24,1%. Tm hidroxit ? S : Ca(OH)2 Bi ton 5: Mt hn hp X gm Fe, Zn v mt dung dch Y l dung dch HCl. Ly 2,98 gam X cho vo 400 ml dung dch Y, sau phn ng hon ton ta c cn trong iu kin khng c oxi th thu c 6,53 gam cht rn . Nu ly 2,98 gam X cho vo 200 ml dung dch Y, sau phn ng li c cn nh trn th thu c 5,82 gam cht rn . Tnh nng mol HCl. S : 0,4M

Bi ton 6: Cho 1,12 gam bt Fe v 0,24 gam bt Mg tc dng vi 250 ml dung dch CuSO 4 khuy nh n khi dung dch ht mu xanh , nhn c khi lng ca kim loi sau phn ng l 1,88 gam . Tnh CM ca CuSO4 .S : 0,1M Bi ton 7: Cho 50 gam dung dch MX ( M l kim loi kim, X l halogen ) 35,6 % tc dng vi 10 gam AgNO3 thu c kt ta. Lc b kt ta c dung dch nc lc. Bit nng ca MX sau th nghim gim 1,2 ln so vi nng ban u. Tm MX? S: LiCl

DNG 15 : KIM LOI + MUI

Cu 1: Cho 40 gam hn hp Mg v Fe vo 2,4 lit dung dch AgNO 3 0,5 khi phn ng xong thu c 126,4 gam hn hp 2 kim loi. Vy Fe chim: A. 58,34% B.70 % C.79,2% D.Kt qu khc Cu 2: Cho m gam hn hp Mg v Fe vo 0,8 lit dung dch AgNO 3 0,5 M khi phn ng xong thu c 78.4 gam hn hp 3 kim loi. Gi tr ca m l: A. 40 B.41.66 C.72 D.Kt qu khc Cu 3: Hn hp X gm 0,03 mol Al v 0,05 mol Fe tc dng vi 100 ml dung dch Y cha Cu(NO3)2 a mol/l; AgNO3 b mol /l. Sau phn ng thu c dung dch Z v 8,12 gam cht rn Q gm 3 kim loi. Cho cht rn Q tc dng vi dd HCl d thu c 0,672 lt kh H2 ktc. Tnh a, b? A.0,02 v 0,03 B.0,03 v 0,05 C.0,5 v 0,3 D.0,05 v 0,03

THM
Bi tp 1: Ha tan ht 4 gam hn hp Fe v mt kim loi M ha tr II v dung dch HCl thu c 2,24 lt kh H2 ktc. Nu ha tan 2,4 gam M vo 500 ml dung dch HCl 1M th thu c dung dch vn cn d HCl. Tm M? S : Mg Bi tp 2: Ha tan hon ton 10,5 gam hn hp X gm K, Al vo nc thu c dung dch X thm t t cho n ht 100 ml HCl 1M vo dung dch X th trong dung dch X bt u xut hin kt ta. Phn trm Khi lng K, Al trong X l? S : 74% v 26% Bi tp 3: Ha tan 21,6 gam hn hp A gm Na, Al, Fe vo nc d thu c 0,448 lt kh ktc v cn li cht rn B. Cho B tc dng ht vi 60 ml dung dch CuSO4 1M thu c 3,2 gam Cu v dung dch C. Cho dung dch C tc dng vi lng va dung dch NH 3 thu c lng kt ta ln nht. Nu nung kt ta trong khng kh n khi lng khng i thu c bao nhiu cht rn E? S : 3,42 gam Bi tp 4: Cho 8,3 gam hn hp X gm Al, Fe vo 1 lt dung dch Y cha AgNO3 v Cu(NO3)2 thu c 23,6 gam cht rn Z v dung dch Q mu xanh nht. Thm NaOH d vo dung dch Q c kt ta , Nung kt ta n khi lng khng i nhn c 24 gam cht rn E. Nng ca AgNO 3 v Cu(NO3)2 l? S : 0,1M v 0,4M Bi tp 5: Cho 8,3 gam hn hp X gm Fe, Al vo 1 lit dung dch Y cha AgNO 3 0,1M v Cu(NO3)2 0,2M. Sau khi phn ng kt thc thu c cht rn B v dung dch C mt mu hon ton. B khng tan trong dung dch HCl. Khi lng ca B l? S : 23,6 gam . Bi tp 6: Ha tan 10 gam hn hp X (Mg, Zn, Fe) vo 100 ml dung dch ng H 2SO4 0,8M v HCl 1,2M. Dn lng kh sinh ra qua ng ng CuO nung nng cho n khi phn ng xy ra hon ton thu c 14,08gam cht rn Y. Ha tan cht rn Y trong dung dch AgNO3 d thu c cht rn Z trong Ag chim 25,23% khi lng. Gi tr ca m l? S : 15,2 gam Bi tp 7: Cho hn hp X gm 0,15 mol Mg v 0,1 mol Fe vo 1 lt dung dch Y cha AgNO3 0,1M v Cu(NO3)2 0,15M thu c cht rn v dung dch Z. Thm NaOH d vo dung dch Z, lc

b kt ta, nung nng trong khng kh n khi lng khng i nhn c m gam cht rn Q. Gi tr ca m l? S: 10 gam Bi tp 8: Cho hn hp X gm 0,15 mol Mg v 0,1 mol Fe vo 1 lt dung dch Y cha AgNO3 v Cu(NO3)2 thu c dung dch Z khng mu v 20 gam cht rn Q. Thm NaOH d vo dung dch Z c kt ta E gm 2 hidroxit. Nung E trong khng kh n khi lng khng i thu c 8, 4 gam cht rn F. Tnh nng mol ca cc cht AgNO3, Cu(NO3)2. S : 0,06M v 0,15M .

Dng 16 : BI TP CO, H2 TC DNG VI OXIT KIM LOI

Cu 1: Cho kh CO i qua ng s nung nng cha 16 gam Fe2O3 ung nng, sau phn ng thu c hn hp cht rn X gm Fe, FeO, Fe3O4, Fe2O3. Ha tan han ton X bng H2SO4 c nng thu c dung dch Y. C cn dung dch Y, lng mui khan thu c l bao nhiu. S: 40 gam Cu 2: Trong bnh kn cha 0,5 mol kh CO v m gam Fe3O4. un nng cho ti khi phn ng xy ra han tan, th kh trong bnh c t khi so vi kh CO ban u l 1,457. Gi tr ca m l bao nhiu. S : 16,8 gam Cu 3: Cho dng kh CO i qua ng s ng 0,12 mol hn hp gm FeO v Fe2O3 nung nng, phn ng to ra 0,138 mol CO2. Hn hp cht rn cn li trong ng nng 14,352 g gm bn cht. Ha tan ht bn cht ny trong dung dch HNO3 d th thu c V lt kh NO duy nht. Tnh gi tr ca V? s : 2,2848 lt Cu 4: Dn t t hn hp kh gm CO v H2 qua ng s ng 55,4 gam hn hp bt gm CuO, MgO, ZnO, Fe3O4 un nng. Sau phn ng xy ra hon ton thu c 10,08 lt kh kct hn hp kh v hi ch cha CO2 v H2O, trong ng s cn li mt lng cht rn c khi lng l? S : 48,2 Cu 5: Thi rt chm 2,24 lt ktc hn hp kh gm CO, H 2 qua mt ng s ng hn hp bt Al2O3, CuO, Fe3O4, Fe2O3 c khi lng 24 gam nung nng. Hn hp kh v hi thot ra khi ng s c hp th han ton bi dung dch Ca(OH)2 d, thu c 5 gam cht kt ta trng. Khi lng cht rn trong ng s l bao nhiu? S : 22,4 gam Cu 6: Cho 4,48 lt kh CO ktc tc dng vi FeO nhit cao. Sau phn ng thu c cht rn A c khi lng b hn 1,6 gam so vi khi lng FeO ban u. Khi lng Fe thu c v % th tch CO2 trong hn hp sau phn ng ln lt l g? S : 5,6g ; 50% Cu 7: Hn hp X gm Al, Al2O3, ZnO, Fe3O4, Cu c chia lm hai phn bng nhau. Phn 1: Cho H2 nng d qua X n phn ng han tan ri cho dung dch NH3 d vo Phn 2: Cho tc dng vi dung dch HCl d ri cho dung dch NH3 d vo. S phn ng xy ra trong cc th nghim trn l bao nhiu. Cu 8: Dng CO kh han ton 2,8 gam hn hp X gm FeO, Fe, Fe 2O3 thu c 2,24 gam cht rn. Mt khc ha tan 2,88 gam X cn dung va vi 100 ml dung dch HCl. Kt thc th nghim thu c 224 ml kh ktc. Nng mol ca dung dch HCl l bao nhiu? S: 1M Cu 9: t chy 12,27 gam hn hp X gm Al, Fe, Cu trong khng kh. Sau phn ng thu uc 16,51 gam hn hp A gm cc xit. Cho A tc dng vi xt thy cn dung ti a 100 ml dung dch NaOH 1M. Th tch hn hp kh Y gm H2 v CO o ktc cn dung kh ht vi hn hp A l bao nhiu? S : 2,576 lt

Cu 10: Thi t t lung kh H2 d i qua ng s cha hn hp gm m gam MgO v m gam CuO nung nng n phn ng han ton. Kt thc th nghim th nghim, hn hp cht rn thu c c khi lng l bao nhiu? S : 1,8m Cu 11: Cho lung kh CO i qua ng s ng m gam Fe 2O3 nung nng. Sau mt thi gian thu c 13,92 gam hn hp X gm Fe, FeO, Fe3O4, Fe2O3. Ha tan ht X bng HNO3, c nng thu c 5,824 lt NO2 ktc. Tnh m S : 16 gam Cu 12: Hn hp A c khi lng 17,86 gam gm CuO, Al2O3, FeO. Cho H2 d qua A nung nng sau khi phn ng xong thu c 3,6 gam H2O. Ha tan hon ton A bng dung dch HCl d, c dung dch B. C cn dung dch B thu c 33,81 gam mui khan. Khi lng Al2O3 trong hn hp A l bao nhiu? S : 3,06 gam

Dng 17: Bi tp v

HCO3

Cu 1: Cho dung dch cha a mol Ca(HCO3)2 vo dung dch cha a mol Ca(HSO4)2. Hin tng quan st c l A. Si bt kh B. Vn c C. Si bt kh c vn c D. C vn c sau trong tr li Cu 2: C 3 dung dch b mt nhn l Ba(NO3)2, Ca(HCO3)2, MgSO4. Khng dung thuc th no sau y nhn bit c c 3 dung dch trn A. Ba(OH)2 B. H2SO4 C. NaOH D. Na2CO3 Cu 3: Cho a mol Ba(OH)2 vo dung dch cha b mol NaHCO3 ( bit a < b < 2a ). Sau khi kt thc tt c cc phn ng thu uc kt ta X v dung dch Y. S cht tan trong Y l bao nhiu Cu 4: Cho dung dch X gm Na2CO3, K2CO3, NaHCO3. Chia X thnh 2 phn bng nhau: Phn 1: Tc dng vi nuc vi trong d thu oc 20 gam kt ta Phn 2: Tc dng vi HCl d thu oc V lt CO2 ktc. Gi tr ca V l bao nhiu S : 4,48 lt Cu 5: Cp cht no sau y khng cng tn ti trong mt dung dch A.Ca(HCO3)2 v NaHSO4 B.NaHSO4 , NaHCO3 C.NaHCO3, BaCl2 D.AgNO3 , Fe(NO3)2 2+ Cu 6: Trn dung dch cha Ba , OH 0,06 mol; Na+ 0,02 mol; dung dch cha HCO3 0,04 mol, 2 CO3 0,03 mol v Na+. Khi lng kt ta sau khi trn l? Cu 7: Trn dung dch NaHCO3 vi dung dch NaHSO4 theo t l 1:1 ri un nng. Sau phn ng thu c dung dch pH c gi tr no so vi 7 Cu 8: Dung dch Y cha Ca2+ 0,1 mol; Mg2+ 0,3 mol; Cl 0,4 mol; HCO3 y mol. C cn dung dch c bao nhiu gam mui khan. S : 49,8 gam Cu 9: Nung nng 100 gam hn hp gm Na2CO3 v NaHCO3 cho n khi lung hn hp khng i thu uc 69 gam cht rn. Phn trm khi long ca mi cht trong hn hp l. S: 16% v 84% Cu 10: Thi t t CO2 vo dung dch NaOH n d thu oc dung dch X, sau nh t t dung dch Ca(OH)2 n d vo dung dch X. S phng trnh phn ng xy ra l bao nhiu

Cu 11: 250 ml dung dch A cha Na2CO3 v NaHCO3 khi tc dng vi H2SO4 d cho ra 2,24 lt kh CO2 ktc. 500 ml dung dch A tc dng vi CaCl2 d cho ra 16 gam kt ta. Tnh nng mol ca 2 mui trong dung dch A. S : 0,32M v 0,08M Cu 12: Hp th han ton 3,36 lt kh CO2 ktc vo 500 ml dung dch NaOH x mol/l oc dung dch X. Dung dch X c kh nng hp th ti a 2,24 lt kh CO2 ktc. Gi tr ca x l bao nhiu. S : 0,5M Cu 13: Dn 5,6 lt CO2 ktc vo bnh cha 200 ml dung dch NaOH x mol/l, dung dch thu oc c kh nng tc dng ti a vi 100 ml dung dch KOH 1M. Gi tr ca x l bao nhiu. S : 1,5M Cu 14: Sc 1,568 lt kh CO2 ktc vo 500 ml dung dch NaOH 0,16M. Sau th nghim c dung dch A. Rt 250 ml dung dch B gm BaCl2 0,16M v Ba(OH)2 x M vo dung dch A thu oc 3,94 gam kt ta v dung dch C. Nng x ca Ba(OH)2 l? S : 0,02M

DNG 18 : BI TON LIN QUAN N HIU SUT

A + B Sn phm a. Nu H = 100% Th hoc A v B va ht, hoc A ht B d, hoc A d B ht Thng thng n gin nhiu phn ng ha hc u c gi thit H = 100% b. Nu H < 100% phn ng xy ra khng hon ton, phn ng thun nghch khi c A v B u d, ngha l A v B c mt trong sn phm. Trong thc t y l trng hp ph bin. 2. C hai cc tnh hiu sut 2.1. Tnh theo lng cht thiu tham gia phn ng: H = lng thc t p: lng ban u .100% + Lng thc t phn ng < hoc = lng ban u + Lng thc t phn ng thng cho trong bi hoc c tnh qua phng trnh phn ng theo lng sn phm bit + Lng thc t phn ng v lng ban u u c ly cng mt cht nn phi cng mt n v o. + Cht thiu s l cht ht trc khi gi thit hiu sut H = 100% Tnh hiu sut theo cht 2.2. Tnh theo lng sn phm: H = lng sn phm thc t to thnh: Lng sn phm tnh theo l thuyt .100% + Lng sn phm thc t thu c thng c cho trong bi + Lng sn phm tnh theo l thuyt c tnh theo phng trnh phn ng theo cht thiu tham gia phn ng (khi H = 100%) + Lng sn phm thc t v lng sn phm l thuyt phi c cng n v 3. Nu phn ng l mt chui qu trnh a% b% c% d% A B C D E Th hiu sut chung ca c qu trnh s l : H = a%.b%.c%.d%.100% VD 1: Cho 0,5 mol H2 tc dng vi 0,45 mol Cl2 thu c 0,6 mol HCl. Tnh hiu sut phn ng? A.60% B.66,7% C.33,4% D.40% VD2: Nung 1 kg vi cha 80% CaCO3 thu c 112 lt kh ktc. Tnh hiu sut phn ng phn hy vi? A.50% B.38,5% C.62,5% D.66,7%

VD3: Hn hp X gm axit HCOOH v CH3COOH c s mol bng nhau. Ly 5,3 gam hn hp X cho tc dng vi 5,75 gam C2H5OH (c H2SO4 c lm xc tc) thu c m gam hn hp este (hiu sut ph ng este ha l 80%). Tnh m A.7,04 B.6,48 C.8,1 D.8,8 BI TP Cu 1: Ngi ta iu ch kh N2 bng phn ng nhit phn mui (NH4)2Cr2O7. Bit khi nhit phn 32 gam mui ny th thu c 20 gam cht rn. hiu sut ca phn ng ny l A.80% B.85% C.90% D.Kt qu khc Cu 2: Nung m gam Cu(NO3)2 cho n khi phn ng kt thc, lm ngui thy khi lng cht rn gim 0,54 gam (H = 80%). Tnh m A.0,94 B.1,48 C.1,175 D.0,752 Cu 3: Hn hp A gm N2 v H2 theo t l th tch 1 : 3. Tin hnh phn ng tng hp ammoniac, sau phn ng thu c hn hp B. Bit t khi ca A so vi B bng 0,7. Hiu sut phn ng tng hp ammoniac l A.60% B.80% C.85% D.75% Cu 4: Nhit phn 66,2 g Pb(NO3)2 thu c 55,4 gam cht rn. Hiu sut phn ng nhit phn l: A.60% B.70% C.80% D.50% Cu 5: T m kg qu nho chn c cha 40% ng nho (glucozo), ngi ta tin hnh ln men thnh ancol (H1= 80%). Sau oxi ha ancol thnh andehit (H2 = 75%) thu c 2 kg dung dch CH3CHO 30%. Gi tr ca m l A.5,144 B.3,410 C.10,22 D.6,82 Cu 6: Oxi ha nh 3,2 gam ancol metylic thu c hn hp sn phm gm andehit, axit, ancol d, v nc. Trong s mol andehit gp 3 ln s mol axit. em thc hin phn ng trng bc hon ton hn hp sn phm ny thu c 15,12 gam Ag. Hiu sut phn ng oxi ha ancol l bao nhiu? A.40% B.10% C.70% D.30% Cu 7: Bit khi lng ring ca ancol etylic l 0,8 g/ml. Khi ln men m kg glucozo thu c 200 lit dung dch ancol etylic 30o (H = 96%). Tnh m A.90,16 B.45,08 C.97,83 D.152,86 Cu 8: Trng hp 5,6 lt C2H4 ktc th khi lng polime thu c bao nhiu nu hiu sut phn ng l 90% . A.5,3 B.7,3 C.4,3 D.6,3 Cu 10: Chia hn hp 7,8 gam hn 2 ancol etylic v ng ng ca n thnh hai phn bng nhau. Phn 1 cho tc dng vi Na d thu c 1,12 lt H 2 ktc . Phn 2 tc dng vi 30 gam CH 3COOH (c mt H2SO4 c). Tnh khi lng este thu c, bit hiu sut phn ng este ha l? A.6,48 B.8,1 C.8,8 D.Kt qu khc . Cu 11: Trn 19,2 gam Fe2O3 v 5,4 gam Al ri tin hnh phn ng nhit nhm (khng c khng kh). Ha tan hn hp sau phn ng bng dung dch NaOH d thy bay ra 1,68 lt kh H 2 ktc. Hiu sut phn ng nhit nhm l A.57,5% B.60% C.62,5% D.75% Cu 12: Mt bnh kn dung tch 112 lt cha N2 v H2 theo t l th tch 1:4 0oC v p sut 200 atm, c sn mt t cht xc tc. Nung nng bnh mt thi gian, sau a nhit v 0oC thy p sut trong bnh gim 10% so vi p sut ban u. Hiu sut phn ng tng hp amoniac l A.70% B.25% C.60% D.45% Cu 13: Tin hnh thy phn m gam bt go cha 80% tinh bt, ri ly ton b dung dch thu dc thc hin phn ng trng bc th thu c 5,4 gam kim loi bc. Bit hiu sut ton b qu trnh l 50%. Tnh m?

A.1,62 B.2,531 B.10,125 D.5,062 Cu 14: Ly 11,55 gam mui CH3COONH4 cho vo 300 ml dung dch NaOH 1M. un nng cho n khi phn ng hon ton, c cn thu c mt cht rn. Nung nng cht rn c kh X bay ra. Nung kh X nhit d 1500oC, sau lm lnh nhanh thu c hn hp Y gm 3 kh c th tch 5,6 lt ktc. Tnh % X b nhit phn? A.33,33% B.66,67% C.75% D.80% o Cu 15: un nng 57,5 gam Etanol vi H2SO4 c 170 C. Dn sn phm kh v hi ln lt qua cc bnh cha mi cht CuSO4 khan, NaOH c, dung dch Br2 d trong CCl4. Sau th nghim khi lng bnh ng dung dch Br2 tng 21 gam. Hiu sut phn ng hidrat ha etanol l. A.55% B.59% C.60% D.70% Cu 16: Cho bt st un nng vo bnh cha 5 mol kh clo thu c hn hp rn X. Cho X phn ng vi HCl d thy to ra 2,24 lt kh H2 ktc. Nu cho X phn ng vi dung dch NaOH d thu c 0,03 mol kt ta nu . Hiu sut ca phn ng st chy trong kh Clo l. A.30% B.46% C.23% D.70% Cu 17: Kh CO2 sinh ra khi ln men mt lng glucozo c dn vo dung dch Ca(OH) 2 d thu dc 40 gam kt ta . Nu hiu sut phn ng ln men l 80% th khi lng ancol etylic thu c l bao nhiu gam. A.16,4 B.18,4 C.14,72 D.14,27 Cu 18: Nung m gam hn hp X gm Fe, S trong bnh kn khng c oxi. Sn phm thu c em cho tc dng vi HCl d thu c 3,8 gam cht rn A khng tan, dung dch B, v 4,48 lt kh Y ktc. Dn kh Y qua dung dch Cu(NO3)2 d thu c 9,6 gam kt ta. Tnh hiu sut phn ng nung nng hn X? A.30% B.45,7% C.50% D.54,3% Cu 19: Nung nng hn hp X gm Zn v S trong bnh kn khng c oxi thu c cht rn A. Ha tan A vo dung dch HCl d thu c 8,96 lt kh B ktc v 1,6 gam cht rn D khng tan. Bit t khi ca B so vi H2 bng 7. Tnh hiu sut phn ng nung X thnh A. A.85% B.37,5% C.63,5% D.75% Cu 20: T t n cha 90% CaC2 ngi ta iu ch c anilin theo s sau, vi hiu sut cc giai on l 95% 80% 85% 80% CaC2 C 2 H2 C6H6 C6H5-NO2 C6H5NH2 Tnh khi lng t n cn dng iu ch 50 kg anilin c nguyn cht 98%? A.101,16 B.217,49 C.72,49 D.202,32 Cu 21: Mt hn hp X gm 100 ml N2 v H2 theo t l 1 : 3. p sut ban u l 300 atm, p sut sau khi phn ng to ammoniac gim cn 285 atm. Nhit phn ng khng i. Hiu sut phn ng l. A.15% B.14% C.40% D.10% Cu 22: Nha PVC c iu ch t kh thin nhin theo s sau : CH4 C2H2 CH2=CHCl PVC Nu hiu sut ton b qu trnh iu ch l 20% th th tch kh thin nhin ktc cn ly iu ch 1 tn PVC l? (Xem kh thin nhin cha 100% metan v th tch). A.1792 m3 B.2915 m3 C.3584 m3 D.896 m3 Cu 23: Ngi ta iu ch tinh bt theo s sau: Tinh bt Glucozo Ancol etylic Buta-1,3-dien Cao su buna T 10 tn khoai cha 80% tinh bt iu ch c bao nhiu tn cao su buna? Bit hiu sut ca c qu trnh l 60%. A.3 tn B.2 tn C.2,5 tn D.1,6 tn

Cu 24: em trng hp 10,8 gam buta-1,3-dien thu c sn phm gm cao su buna v buta-1,3dien d. Ly sn phm tc dng vi dung dch Br2 d thy c 10,2 gam Br2 phn ng. Hiu sut phn ng l. A.40% B.80% C.60% D.79% Cu 25: Mt hn hp kh A gm 2 ankin c th tch V A = 17,92 lt kh ktc. Thm H2 vo c hn hp kh X c th tch Vx = 62,72 lt ktc. Nung X vi xc tc Ni thu c hn hp Y c th tch gim 4/7 so vi th tch ca X. Hiu sut ca phn ng cng H2 l. A.100% B.75% C.80% D.65% Cu 26: T nguyn liu l v bo, mn ca (cha 50% khi lng l xenlulozo) ngi ta iu ch c ancol etylic vi hiu sut 75%. Tnh khi lng nguyn liu cn thit iu ch c 1000 lt cn 90o. Bit khi lng ring ca etylic l 0,8g/ml. A.2000 kg B.3381 kg C.1818 kg D.3000 kg Cu 27: Crackinh C4H10 thu c hn hp ch gm 5 hidrocacbon c phn t khi trung bnh M = 36,52 g/mol. Hiu sut phn ng crackinh l : A.62,5% B.80% C.60% D.65,2% Cu 28: C mt loi qung pirit cha 96% FeS 2, nu mi ngy nh my sn xut ra 100 tn H 2SO4 98% v hiu sut iu ch H2SO4 l 90% th lng qung pirit cn dng l: A.69,44% B.66,67% C.67,44% D.60 tn

DNG 19: PHNG PHP GII BI TP V PHI KIM

V d 1: Cho 13,5 gam hn hp kh Cl2 v Br2 c t s mol 5 : 2 vo mt dung dch cha m gam NaI. C cn dung dch sau phn ng thu c 15,82 gam cht rn A. Gi tr m l A.15 B.30 C.36 D.42 V d 2: Cho 1,5 mol H2S tc dng vi dd cha a mol NaOH thu c hn hp 2 mui. Gi tr a l? A.1,5 B.3 C.4,5 D.2,0 V d 3: Hp th 4,48 lt kh SO2 ktc vo 500 ml dung dch hn hp gm NaOH 0,1M; Ba(OH) 2 0,2M . Sinh ra m gam kt ta. Gi tr ca m l: A.9,85 B.11,82 C.17,73 D.10,08 V d 4: Cho hn hp X gm Zn v S vo bnh kn khng c khng kh. Nung cho phn ng xy ra hon ton thu c cht rn Y. Ha tan Y vo dung dch HCl d thu c 6 gam cht rn Z khng tan v 4,48 lt kh Q ktc c t khi so vi H2 l 17. Tnh khi lng hn hp X. A.12,4 B.19 C.21 D.25,4 V d 5: un nng 5,6 gam bt Fe vi 1,6 gam bt S. Sau phn ng thu c m gam cht rn. Cho m gam cht rn ny tc dng vi HCl thu c hn hp kh A % th tch kh H2S trong A l bao nhiu bit cc phn ng xy ra hon ton. A.100% B.50% C.75% D.25% V d 6: Nung 37,6 gam mui nitrat ca kim loi M n khi lng khng i thu c 16 gam cht rn v hn hp kh X c t khi so vi hidro bng 21,6. Cng thc ca mui nitrat l A.Mg(NO3)2 B.Zn(NO3)2 C.Cu(NO3)2 D.AgNO3 V d 7: Cho CO d i qua hn hp A gm MgO, Fe3O4 nung nng, sau khi phn ng kt thc cho ton b kh thu c hp th vo dung dch nc vi trong d thy to thnh 6 gam kt ta. Mt khc ha tan A cn ht 170 ml dung dch HNO3 2M v thu c V lt kh NO duy nht ktc. Tnh gi tr ca V. A.0,224 B.0,112 C.0,336 D.0,448

V d 8: Cho 22,4 lt hn hp A gm hai kh CO, CO 2 i qua than nng (khng c mt khng kh) thu c kh B c th tch hn th tch ca A l 5,6 lt (th tch kh o ktc). Dn B i qua dung dch Ca(OH)2 va th thu c dung dch ch c cha 20,25 gam Ca(HCO 3)2. Thnh phn % ca mi kh trong hn hp A l A.25% v 75% B.37,5% v 62,5% C.40% v 60% D.50% v 50% V d 9: Hn hp A gm hai mui NaX v NaY (X, Y l hai halogen k tip nhau). kt ta hon ton 2,2 gam hn hp A cn 150 ml dung dch AgNO3 0,2M. A.Cl v Br B.Br v Cl C.Br v I D.I v Br V d 10: Cho 356 gam hn hp X gm NaBr v NaI tc dng vi 0,4 mol Cl 2 thu c cht rn A (sau khi c cn dung dch) c khi lng l 282,8 gam. Tnh s mol mi cht trong hn hp X gi s lng Clo ti thiu cho cho cht rn A ch cha mui l 35,5 gam Cl2. A.2 mol NaBr v 1 mol NaI B.1 mol NaBr v 2 mol NaI C.2 mol NaBr v 3 mol NaI D.3 mol NaBr v 1 mol NaI