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THI TH I HC NM 2012-2013 MN: HA HC LN I NGY 04/11/2012 M : 001 Thi gian lm bi: 90 pht khng k thi gian pht

chnh thc ( thi gm 8 trang)

H, tn th sinh:...................................................................... S bo danh:........................................................................... Cho bit nguyn t khi ca cc nguyn t: H=1; C=12; N=14; O=16; Na=23; Mg=24; Al=27; S=32; Cl=35,5; K=39; Ca=40; Cr=52; Mn=55; Fe=56; Cu=64; Zn=65; Br=80; Ag=108; Sn=119; I=127; Ba=137. I. PHN CHUNG CHO TT C CC TH SINH (40 cu, t cu 1 n cu 40)

Cu 1: Cho 5,61(g) andehit A tc dng vi AgNO3/NH3 d. Sau khi phn ng xy ra hon ton em ton b lng kt ta tc dng vi HNO3 d thu c 1,91 (l) NO (o 34C; 1,121atm). A l: A. HCHO B. CH3CHO C. C2H5OH D. C3H7OH Cu 2: Hn hp kim loi no sau y c kh nng xy ra phn ng hon ton vi HCl c, ngui ly d: A. Fe, Al B. Fe, Cu C. Au, Pt D. Al, Pt Cu 3: Cho m gam Cu tc dng vi dung dch cha Fe(NO3)3 v HCl, sau phn ng thu c dung dch X cha 2 cht tan v 20,16 lt NO ( ktc ). Ga tr ln nht ca m l: A. 86,4 B. 105,56 C. 96,0 D. 172,8

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Cu 4: Cho m(g) hn hp 2 amin n chc k tip nhau trong dy ng ng tc dng vi HCl d thu c 18,975(g) mui. Mt khc t chy hon ton m(g) hn hp trn thu c 2,8(l) N2 (ktc). Gi tr ca m l: A. 12,52(g) l: A. 31 A. Fe B. 28 B. Al C. 34 C. Cu D.26 D.Ba Cu 6: Dng thuc th no sau y c th phn bit c cc dung dch: HCl, H2SO4, HNO3 (u long): Cu 7: Cho cc cht sau: C2H5OH, NH2-CH2-COOH, NO2-CH2-COOH, C6H5OH tnh axit tng dn l: A. NO2-CH2-COOH < C6H5OH < NH2-CH2-COOH < C2H5OH B. C6H5OH < C2H5OH < NH2-CH2-COOH < NO2-CH2-COOH C. NO2-CH2-COOH < C6H5OH < C2H5OH < NH2-CH2-COOH D. C2H5OH < C6H5OH < NH2-CH2-COOH < NO2-CH2-COOH Cu 8: to ra 250kg nha bakelit cn dng bao nhiu kg phenol ( C6H5OH ).Bit hiu sut phn ng t 70% : A. 297,63kg B. 316,71kg C. 309,52kg D. 311,53kg Cu 9: Pht biu no sau y ng v kim loi kim th: A. Nhit si ca cc kim loi kim th tng dn theo chiu tng dn in tch ht nhn. B. lm mm nc cng vnh cu ngi ta c th dng NaOH hoc Ca(OH)2. C. Cho mt t NaCl vo nc cng tam thi ta c nc cng ton phn. D. Thnh phn ch yu ca qung olomit l MgCO3.BaCO3. Cu 10: Nung nng m(g) Fe ngoi khng kh sau mt thi gian thu c 7,52(g) hn hp A gm FeO,Fe3O4,Fe2O3. Ha tan hon ton A cn t nht 160ml dung dch HNO3 2M thu c V(l) NO duy nht (ktc). Gi tr m v V ln lt l: A. 5,04(g) ; 0,56(l) C. 6,16(g) ; 0,784(l) A. Cu, Al, Fe C. Ag, Fe, Zn % khi lng Al, Na trong A ln lt l: A. [23,13% v 76,87%] hoc [15,06% v 84,94%] B. [14,33% v 85,67%] hoc [28,79% v 71,21%] C. [13,90% v 86,10%] hoc [33,47% v 66,53%] D. [14,82% v 85,18%] hoc [30,12% v 69,88%] Cu 13: Pht biu no sau y l ng khi ni v nhm Cacbon ? A. Trong phn t CO2, cacbon trng thi lai ha sp2. B. Cacbon tc dng vi HNO3(long) to ra sn phm l cc oxt. C. Natri cacbonat (Na2CO3) dng to kh gas cho cc loi thc ung. B. 5,6(g) ; 0,448(l) D. 6,72(g) ; 0,672(l) B. Zn, Fe, Cu C. Mg, Zn, Cu B. 9,85(g) C. 11,37(g) D. 10,08(g) Cu 5: Cho phn ng: FeSO4+K2Cr2O7 +H2SO4 Tng h s ti gin sau khi cn bng phng trnh

Cu 11: Nhng kim loi no sau y c iu ch bng cch dng Cacbon kh oxit tng ng:

Cu 12: Cho 24,2(g) hn hp A gm Al v Na vo 300ml dung dch Al(NO3)3 1M thu c 26,3(g) cht rn.

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D. T lnh dng lu s c mi hi, c th cho vo t lnh mt t cc than g (xp) kh mi hi l do than hp th cc kh c mi. Cu 14: Kh hon ton 25,6(g) 1 oxit kim loi bng CO thu c 3,854 (l) kh CO2 (ktc) em ton b lng kin loi tc dng vi HCl d thu c 7,168 (l) kh H2 (ktc) .Oxit kim loi l: A. FeO B. Fe2O3 C. Fe3O4 D. MnO Cu 15: Cho 0,94 gam hn hp hai anehit n chc, no l ng ng lin tip tc dng ht vi dung dch AgNO3/NH3 thu c 3,24 gam Ag. Cng thc phn t ca 2 anehit l: A. CH3CHO v HCHO C. C2H5CHO v C3H7CHO B. CH3CHO v C3H5CHO D. C3H7CHO v C4H9CHO

Cu 16: Cho hn hp X gm (1) CH2=CH-O-CH3 ; (2) CH2=CH-CH2OH v (3) CH3-CH2-CHO (s mol mi cht u bng nhau) phn ng vi lng d dung dch AgNO3 trong NH3, kt thc phn ng thu c 5,4 gam Ag.Nu cho X tc dng vi dd Br2/H2O th s gam Br2 phn ng l: A. 8 gam B. 12 gam C. 4 gam D. 6 gam Cu 17: Cho 200ml dung dch NaOH c ph=13 tc dng hon ton vi 100ml dung dch Cu(NO3)2 1M. Dung dch thu c sau phn ng l (gi s th tch dung dch khng i): A. 4 B. 5 C. 6 D. 7 Cu 18: Trn m gam Fe v p gam S un nng (khng c khng kh) thu hh A. Cho A vo dd HCl d thu 0,8g cht rn B, dd C v hn hp kh D (t khi ca D so vi H2 l 9).Cho lng kh D vo dd CuCl2 d thu 9,6g kt ta.Gi tr ca m v p l: A. 11,2 v 3,84 B. 8,4 v 4 C. 11,2 v 4 D. 22,4 v 4 Cu 19: cho phn ng: H2 + I2 2HI (H>0)Khi thay i yu t no sau th tc phn ng thun thay i: (1) nhit , (2)nng HI, (3) xc tc, (4) p sut. A. (1)(3)(4) B. (1),(2)(4) C. (1),(2),(3) D. (1),(2),(3),(4) Cu 20: Thu phn m(g) mantozo trong mi trng axit vi hiu sut 80% thu c hn hp A. Khi cho A tc dng vi dd AgNO3/NH3 d thu c 388,8g kt ta. Gi tr ca m l: A. 342 B. 348,75 C. 651,6 D. 513 Cu 21: Ha tan 19,9g hh gm Ba v hai kim loi kim thuc 2 chu k lin tip vo nc c dd A v 4,48(l) H2 (ktc).Cho dd A vo dd Na2SO4 d thu c 23,3g kt ta. Mt khc trung ho dd A cn 200ml dd HCl 1M.Hai kim loi kim l: A. Li, Na B. Na, K C. K, Rb D. Li, K Cu 22: Hn hp X gm 0,1 mol propyl bromua, 0,1 mol anlyl clorua; 0,3 mol etyl clorua; 0,15 mol phenyl bromua,. un si X vi nc n khi phn ng xy ra hon ton, chit ly phn nc lc, ri cho tc dng vi dung dch AgNO3 d thu c m gam kt ta. Gi tr ca m l: A. 57,4 B. 14,35 C. 70,75 D. 28,7 Cu 23: Ha tan hn hp X gm Al v Sn vo axit HNO3 long d, thu c 57,75 gam mui v 4,48 ltkh NO (sn phm kh duy nht).Th tch kh O2 ( ktc) cn phn ng hon ton vi X l: A. 5,04 lt B. 3,36 lt C. 6,72 lt D. 4,48 lt Cu24: Dung dch phenol ( C6H5OH ) trong nc phn ng c vi bao nhiu cht trong s cc cht sau: NaOH, HCl, Br2/H2O, (CH3CO)2O, CH3COOH, Na, NaHCO3:

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A. 4 B. 6 C. 5 D. 7

Cu 25: Crackinh 11,6 gam butan vi xc tc thch hp thu c hn hp X gm 5 hirocacbon. Tch ring hn hp X thnh 2 phn: hn hp Y gm cc anken v hn hp Z gm cc ankan. t hn hp Y cn 14,112 lt O2 (ktc). t hn hp Z (metan chim 50% th tch) cn V lt O2 (ktc). Gi tr ca V v hiu sut phn ngl : A. 15,232 v 60% C. 15,008 v 60% nhiu cht trong s trn ha tan c bt nhm ? A. 2 A. 2 B. 3 B. 3 C. 4 C. 6 D. 5 D. 4 Cu 27: Glyxin v axit glutamic to c bao nhiu ipeptit (mch h) cha c hai loi amino axit ny ? Cu 28: Cho phenylclorua tc dng vi dung dch NaOH c d ( nhit , p sut cao ) thu c dung dch X. Thnh phn cht tan c trong dung dch X l: A. Phenol, NaCl C. Natriphenolat, NaCl, NaOH B. Phenol, NaCl, NaOH D. Natriphenolat, NaOH B. 15,008 v 80% D. 15,232 v 80%

Cu 26: Cho cc dung dch sau: Na2CO3, KHSO4, NaOH, Fe(NO3)3, H2SO4 c ngui v Brom lng, C bao

Cu 29: Lin kt kim loi l lin kt sinh ra do : A. Lc ht tnh in gia cc ion dng v ion m. B. C s dng chung cc cp e. C. Cc e t do gn kt vi cc ion dng kim loi vi nhau. D. C lc ht Van-dec-van gia cc nguyn t kim loi. Cu 30: Ho tan hon ton 24 gam hn hp gm 2 axit cacboxylic no n chc vo nc. Chia dung dch thnh 2 phn bng nhau. Cho phn th nht phn ng vi bc oxit (ly d) trong dung dch amoniac, thu c 21,6 gam bc kim loi. Phn th 2 c trung ho hon ton bi 200 ml dung dch NaOH 1M. Vy cng thc ca 2 axit trong hn hp l: A. HCOOH, CH3COOH C. HCOOH, C4H9COOH B. HCOOH, C2H5COOH D. HCOOH, C2H7COOH

Cu 31: : Ha tan hon ton 150g CuSO4.5H2O vo 600ml dung dch HCl 0,6M thu c dung dch A. Tin hnh in phn 1/3 dung dch A vi cng dng in I=1,34A trong 4 gi. Khi lng kim loi bm vo catot v th tch kh thot ra anot ( ktc ) ln lt l : A. 3,2g v 17,92 lt C. 6,4g v 0,896 lt B. 6,4g v 1,792 lt D. 3,2g v 0,448 lt

Cu 32: Cho m1 gam hn hp gm Mg, Al vo m2 gam dung dch HNO3 24%. Sau khi cc kim loi tan ht c 8,96 lt hn hp kh X gm NO, N2O, N2 bay ra ( ktc) v dung dch A. Thm mt lng va O2 vo X, sau phn ng thu c hn hp kh Y. Dn Y t t qua dung dch NaOH d c 4,48 lt hn hp kh Z i ra ( ktc). T khi ca Z i vi H2 bng 20. Nu cho dung dch NaOH vo A c lng kt ta ln nht th thu c 62,2 gam kt ta.Ga tr ca m1, m2 ln lt l ? (Bit lng HNO3 ly d 20% so vi lng cn thit.) A. 23,1 v 913,5 B. 22,8 v 931,5

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C. 23,1 v 535,5 A. Dung dch AgNO3. C. Phenolphtalein. D. 22,8 v 535,5 B. Dung dch NaOH. D. Dung dch H2SO4 long.

Cu 33: phn bit cc dung dch: NaCl, MgCl2, AlCl3, FeCl2 ch cn dng mt thuc th l:

Cu 34: Chia m gam hn hp M gm hai ancol n chc k tip trong dy ng ng thnh 2 phn bng nhau. Cho phn mt tc dng vi Na (d), c 3,36 lt kh hiro (ktc). Cho phn hai phn ng hon ton vi CuO nhit cao, c hn hp M1 cha hai anehit (ancol ch bin thnh anehit). Ton b lng M1 phn ng ht vi AgNO3 trong NH3, thu c 86,4 gam Ag. Gi tr ca m l: A. 24,8 gam B. 30,4 gam C. 15,2 gam D. 45,6 gam Cu 35: C bao nhiu cht c th phn ng vi dung dch axit fomic trong s cc cht sau: KOH, NH3, CaO, Mg, Cu, Na2CO3, Na2SO4, CH3OH, C6H5OH, AgNO3/NH3 ? A. 8 B. 9 C. 7 D. 6 Cu 36: t chy hon ton 0,1 mol hn hp hai axit cacboxylic l ng ng k tip thu c 3,36 lt CO2 (ktc) v 2,7 gam H2O. S mol ca mi axit ln lt l: A. 0,05 mol v 0,05 mol. C. 0,04 mol v 0,06 mol. A. 9 B. 7 B. 0,045 mol v 0,055 mol. D. 0,06 mol v 0,04 mol. C. 8 D. 6

Cu 37: Trung ha 28 gam mt cht bo cn dng 20 ml dung dch NaOH 0,175M. Ch s axit ca cht bo l: Cu 38: Cho cc pht biu sau: 1. Nitrophotka l hn hp ca (NH4)2HPO4 v KNO3. 2. Kh CO2 tc dng vi dung dch nc Gia-ven thu c axit clor. 3. Axit H2S l mt axit yu nn khng th y c axit mnh ra khi mui. 4. SiO2 ch tan c trong dung dch axit HF to sn phm kh. 5. Trong cac phan ng hoa hoc, khi H2 lun la mt cht kh. 6. Tnh phi kim tng dn theo th t: N < P < O < F. 7. Trong cc pht biu trn, c bao nhiu pht biu ng ? A. 2 B. 3 C. 4 D. 5 Cu 39: Ha tan hon ton 4,59g BaO vo nc thu c dung dch A. Cho 3,68g hn hp gm MgCO3 v CaCO3 tan hon ton trong dung dch HCl thu c kh B. Cho dung dch A hp th ht kh B thu c dung dch C.( Cc th nghim trn thc hin trong cng iu kin ) Nhn xt no sau y l ng ? A. Dung dch C c cha 2 mui ca Ba2+. B. Dung dch C ch cha mui Ba(HCO3)2. C. Khi lng mui trong dung dch C l 5,91g. D. Th tch kh B thu c nh nht l 672ml ( ktc ). Cu 40: Nhng ngi thiu Vitamin A thng phi n cc qu chn, c c mu nh c rt, qu c chua, qu gc v trong c cha : A.Vitamin A. B. Caroten (thy phn cho ra Vitamin A). D.Cc enzim tng hp nn Vitamin A. C.Hp cht este ca Vitamin A

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II. PHN RING: Th sinh ch c lm mt trong hai phn ring ( Phn A hoc phn B ) A. Theo chng trnh Chun (10 cu, t cu 41 n 50) Cu 41: Mt hh A gm Al2O3, K2O, CuO: - Nu thm vo hn hp A mt lng nc d th cn li 15g cht rn. - Nu thm vo hn hp A 50% lng Al2O3 ban u ri ha tan vo nc d th cn li 21g cht rn. - Nu thm vo hn hp A 75% lng Al2O3 ban u ri lm th nghim nh trn th cn li 25g cht rn.( Cc phn ng xy ra hon ton ) Khi lng K2O trong hn hp A l: A. 32,9g B. 17,16g C. 28,2g D. 16,58g Cu 42: Cho cc dung dch sau: KHCO3, Ca(OH)2, NH4Cl, NaAlO2, phenylamoniclorua, HClO, Glixin, anilin, natri phenolat, natri hipocloro. S dung dch lm qu tm ha xanh l: A.4 B.6 C.5 D.7 Cu 43:Dn kh CO d qua hn hp rn cha FeO, ZnO, PbO, CuO n phn ng hon ton c cht rn A. Ho tan A bng dung dch HNO3 va thu c dung dch B. Nho t t dung dich Na2S cho ti d vo dung dch B c kt ta X. Kt ta X cha bao nhiu cht ? A. 2 B. 3 C. 4 D. 5 Cu 44: Cho 17,8(g) hn hp Al, Al2O3, Fe, Fe3O4, Mg vo dung dch HNO3 long d, thu c dung dch A v 6,72 l NO (ktc). Cho A tc dng ht vi NaOH, lc kt ta em nung nng ngoi khng kh ti khi lng khng i th thu c m(g) cht rn. Tm m? A. 21,7(g) B. 28,3(g) C. 25(g) D. 31,2(g) Cu 45: Cho cc phn ng ha hc sau: a) O3 + Ag2S c) Al4C3 + H2O e) MnO2 + H2SO4 (c, t0) g) H2O2 + KI (dd) S phn ng sinh ra n cht l : A.4 B.5 C.6 D.7 b) NH3 (k) + Cl2 (k) d) Cl2 + H2S (dd) f) Cu2O + Cu2S (t0) h) CaOCl2 + HCl (dd)

Cu 46: Dung dch X c cha: 0,07 mol K+, 0,02 mol SO42- v x mol OH-. Dung dch Y c cha ClO4-, NO3v y mol H+; tng s mol ClO4 -v NO3- l 0,04. trn X v Y thu c 100ml dung dch Z. Dung dch Z c pH (b qua s in li nc) l: A. 1 B. 2 C. 12 D. 13 Cu 47: Trong cc loi t sau: t visco, t xenluloz axetat, t nitron, t lapsan, nilon-6,6. S loi t c iu ch bng phng php trng ngng l A. 1 B. 2 C. 3 D. 4 Cu 48: un nng 34,2 gam matoz trong dung dch axit sunfuric long. Trung ha dung dch thu c sau phn ng bng dung dch NaOH ri cho tc dng hon ton vi dung dch AgNO3/NH3 d, un nng thu c 37,8 gam Ag. Hiu sut phn ng thy phn mantoz l: A. 87,5% B. 69,27% C. 62,5% D. 75% Cu 49: t chy hon ton hn hp X gm amoniac, metylamin, imetyl amin, etylmatyl amin bng mt

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lng khng kh va sau dn ton b sn phm chy qua bnh ng P2O5 d th thy khi lng bnh tng 11,52 gam v thot ra 75,264 lt kh (ktc). Nu ly ton b X trn tc dng vi dung dch H2SO4 d th khi lng mui to thnh l A. 50g B. 60g C. 16,16g D. 24g Cu 50: Cho cc cht: bc axetilua, metan, 1,2-iclo etan, canxicacbua, propan, etylclorua, etanol, nhm cacbua. S cht iu ch ra etanal bng 2 phn ng ha hc l: A. 5 B. 6 C. 7 D. 8 B. Theo chng trnh Nng Cao (10 cu, t cu 51 n 60) Cu 51: Nn 3 mol N2 v 8mol H2 vo bnh kn c th tch 2 lit(cha sn cht xc tc vi th tch ko ng k)v gi cho nhit ko i.Khi phn ng trong bnh t ti trng thi cn bng.p sut cc kh trong bnh bng 0,6 ln p sut lc u(khi mi cho vo bnh,cha xy ra phn ng).Nng ca kh NH3 ti thi im cn bng l gi tr no trong s cc gi tr sau? A. 2,2M l: A. 2 B. 3 C. 4 D. 5 Cu 53: X l hexapeptit Ala-Gly-Ala-Val-Gly-Val, Y l tetrapeptit Gly-Ala-Gly-Glu. Khi thy phn m gam X v Y trong mi trng axit thu c 4 loi aminoaxit trong c 30 gam glyxin v 28,48 gam alanin. Gi tr m l A. 87,4 B. 73,4 C. 77,6 D. 83,2 Cu 54: Cho cc s phn ng sau: MnO2 + HCl ( kh X) Na2SO3 + HCl ( kh Y) KClO3 ( kh Z) cc kh X,Y,Z,T,E,F l: A. Cl2, HCl, H2S, SO2, O2,H2 C. Cl2, SO3, O2, H2S, HCl, H2 B. 4M C. 4,4M D. 4,2M Cu 52: Cho cc cht sau: axit glutamic; valin; lysin; alanin; trimetylamin; anlin. S cht lm qu tm i mu

FeS + HCl ( kh T) NaCl tinh th + H2SO4 c ( kh E) Zn + H2SO4 long ( Kh F) B. Cl2,SO2, O2, H2S, HCl, H2 D. H2, SO2, O2, H2S, HCl, Cl2

Cu 55: Cho hn hp X gm HCOOH; CH3COOH (t l mol 1:1) v hn hp Y gm CH3OH, C2H5OH (t l mol 2:3). 16,96 gam hn hp X tc dng vi 8,08 gam Y (c xc tc H2SO4 c) thu c m gam este (hiu sut cc phn ng este ha l 80%). Gi tr ca m l A. 12,064 y la ung v R, X v Y A. C X v Y u l kim loi, R l kh him B. X la phi kim va Y la kim loai , R la khi him C. X la kim loai va Y la phi kim, R la khi him D. X,Y ,R cung thuc 1 chu ky Cu 57: Cho cac phat biu: a) thc Cht xc tc l cht lm thay tc phn ng,nhng khi lng khng thay i sau khi phn ng kt B. 19,3024 C. 15,08 D. 24,128 Cu 56: Cu hnh electron lp ngoi cng ca nguyn t R v ion X2- , Y+ u l 4s24p6. Nhn xet nao sau

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b) c) d) e) f) Tai thi im cn bng, cn bng hoa hoc la cn bng ng Khi thay i nng cc cht,s lm thay i hng s cn bng Cht xc tc l cht thng lm tng tc phn ng Khi nhit tng th tc phn ng tng Hng s cn bng t l nghch vi nhit S ap an ung la: A. 2 B. 4 C. 6 D. 5 Cu 58: Cho phn ng xy ra trong pin in ha nh sau: Fe (r) + 2Ag+ (dd) Fe2+ (dd) + 2Ag (r). Bit E0(Fe2+/Fe) = -0,44V ; E0(Ag+/Ag) = +0,8V. Sc in ng ca pin in ha ny l: A.2,04V B.1,24V C.0,84V D.2,14V Cu 59: Cho cc pht biu sau: 1.Cc ht cu to nn hu ht cc nguyn t l proton v ntron 2.Nhng nguyn t c cng in tch ht nhn th cng mt nguyn t nhng tnh cht ha hc c th khng ging nhau. 3.K hiu nguyn t biu th y c trng cho nguyn t ca mt nguyn t ha hc v n cho bit s khi A v s n v in tch ht nhn. 4.S hiu nguyn t ca nguyn t cho bit s electron trong nguyn t ca nguyn t . 5.cc ng v ca mt nguyn t ha hc l nhng nguyn t c cng s proton v s khi A, nhng khc nhau v s Ntron. Cc pht biu sai l: A. 1, 2 v 4. C. 1, 2 v 5 B. 2, 3, v 4. D. 1 v 2.

Cu 60: Sp xp theo th t lc axit tng dn: C6H5COOH(1), m-O2N-C6H4-COOH (2), p-CH3-C6H4COOH(3), p-H2N-C6H5-COOH(4) (cc cht u c vng benzen) A. 4<3<2<1 B. 2<1<3<4 B. 4<3<1<2 D. 1<2<3<4

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