2012 1224

()

()

50 cm 5 cm

()
5

50 cm

pH, BOD, COD, SS, T-N1

1
6

()
50 cm 5 cm

50cm

()

()
()

()

()

BOD

CODSS

BODCOD

0.3 mg/L (

0.01 mg/L

0.01 mg/L

0 01 mg/L
0.01

0.1 mg/L

g
0.01 mg/L

0.1 mg/L

10

11

4813 2412

0.5 5 mm

50 g

(10)

7
5

6
200 , 45 cm

0.3
0.3
1.5

0.3
0.005

0 3
0.3

12
11
12
111
112
13

1
1
0.003
0.3
0.1
0.2
0.02
120.04
110.2
120.4
1113
1120.06
130.02
0.06

0.03

0.2
0.1
3

1()

#
#

H3
46

H15
18

S48
13

0.01
0.003
0.05
0.01
0.0005

0.01
0.8
1

0.01
0.01**
0.05
0.01***
0.0005

0.01
0.8
1

0.01
0.01
0.05
0.01
0.0005

0.01
0.8
1

0.1
0.1
0.5
0.1
0.005

0.1
10 (230)
(
)
8 (15)

0.3
0.3
1.5
0.3
0.005

0.3
-

*
**
***
$
$$

1 mg/kg-
g/ g
15 mg/kg-

15

16

17

18

(1

19

(2

20

21

22

?2

1000 kg

7 kg

10 kg

22 kg
g

61 kg

2 kg

3 kg
2 kg

7 kg

76 kg

10 kg
23

(2010)

21

24

(3

No 1
No.1

No 2
No.2

25

? 3

1000 kg

14 kg

No 1
No.1

No 2
No.2

12 kg

7 kg

14 kg

50 kg

8 kg

7 kg

50 kg
A

29 kg
26

?
100.0

3 7

8 12 12 12 13 13 14 14 14
14 14 14 15 15 15 16 17 17 17 18 19 20

90.0

20 22 22 25 26
27 29 33
34

80.0
70.0

41 46
50 50 53 55
57

67

60.0
50.0
40.0
30.0

19

83 85
97 93 92
88 88 88 87 87 86 86 86 86 86 86 85 85 85 84 83 83 83
82 81 80 80 80 78 78
75 74 73 71
67 66

20.0

81
59 54
50 50 47 45
43

33

10.0

17 15

100.0

18

9
12

22

80.0

37

77
92

92
92

88

99 100

74 70

72 71 69

92
28

60 58 57
40 36

63

95 94 97 99 100100100100100100 99 99 99 98
98 98

90 88

Bi

51 54

72

Cd

Sb

Se

83

30.0

As

Cs

42
60 63

79 79 78

Ag

Rb

Zn

30
12 11

Na

Pb

Mo

Li

Ta

Ga

Mg

Ti

Sr

Au

Cr

Ca

Ge

Pd

Al

24 30

50.0

47
37
28

23

17
3

V
B
Mn

Pd
Pt
Mo
Cu
Co
As
In
Ni
Ge
Au
Fe
Nb
W
Cr

0.0

18
8

7
1

K
Rb
Cs
Bi
Zn
Pb
Cd
Sb
Ga

Y
Ca
Sr
Li
Se
Na

10.0

11

60.0

20.0

16

70.0

40.0

Ba

Nd

Zr

Si

Eu

Ce

Sc

Mn

La

Sn

Co

Zr
Ti
Al
Sc
Ce
Si
Nd
La
Mg
Eu
Ba

()

90.0

Nb

Fe

Ni

Cu

0.0

(2010)

:%

%
Others

Others,37.7

Ca,26.7

72.6

Si,13.0

Zn,0.6 ,0.0
Ti,0.6 S,2.3

, 00.0
,0.0
0 Al,8.8
Al 8 8

Ti,1.2
Mg,1.8
Na,1.6 Fe,1.9
K,0.8 Cl,1.0

Al, 1.9
Al,1.9

Cl,21.9

Na,4.5

Ca,22.8

90.0 Si,17.0

27.4 Si,6.8

Mg,0.9 K,6.2

P,1.0
Al,5.6
Ti,1.3
K,2.0
Fe,4.2
Mg,1.5
Na,2.2Cl,2.9

Others,
41.5

Ca,24.5
,

Others 27 7
Others,27.7

Others,19.4 Ca,13.7
Pb,1.3

Si,1.0

,0.0
,0.0

Zn,6.5
7.7 Cl,29.1
S,2.5
0
K,14.0
Na,10.6

Fe,1.0

Al

Ca

Cl

Cu

Fe

Mg

Na

Pb

Si

Ti

Zn

Si,4.0
Cr,0.9
Ni,0.9 Others,
Rb,0.0
Br,0.0
7.4
,Y,0.0
F,0.0

Cu,8.3
S,0.0
P,6.9
Cl,0.0

2.3
Fe,
70.2
28


: 1 100111 ((=0.01 1%

2.7
5.0
0.39
122
0.80
3.4
60.0
353
0.89
2200
<0.05
19.6
934
8.2
12.1
382
781
0.38
<0.05
41.0
0.71
365
<0.25
62.8
2640

Ag
As
Au
B
Bi
Cd
Co
Cr
Cs
Cu
In
Li
Mn
Mo
Nd
Ni
Pb
Pd
Pt
Sb
Se
Sn
Tl
V
Zn

8.2
16.0
<0.25
65 7
65.7
9.8
49.2
22.3
214
2.4
411
<0.05
18.3
393
9.0
5.8
26.2
1010
0.20
0.05
225
2.5
151
0.50
28.1
4800

1.8
0.80
<0.25
179
<0.5
<0.05
9.7
595
0.100
329
<0.05
28.0
1260
2.4
19.5
99.5
8.4
<0.05
<0.05
1.5
1.5
16 8
16.8
<0.25
46.9
456

16.2
12.6
<0.25
15 5
15.5
67.3
344
3.9
20.3
12.7
2740
0.3
41.5
379
4.3
0.81
10.0
12600
<0.05
<0.05
611
5.6
2540
4.3
2.9
69300

57.2
192
14.6
299
<1
<0.1
1390
9180
<0.1
82600
7.7
<5
1680
400
0.28
9090
271
19.0
14.7
1940
<1
2270
<0.5
386
1740

320%

(2010)

29

As

Cd

13
23

Cr

Cu

Hg

Pb

<0.05 1100

4700 0.22 2780

900
3210
950
1500

B7
B8
B9
B10

B11
B12
B13
B14
B15
B
15

6.0

4.0

1.4

8 400

385

14
1200

B21
B22
B23
B24
B25

6.0
2.0
3.0

3.48
3.7

2.0

16)
16)
25)
26)

5100
1326
1900
1100

0.14 3300
469
0.12 720
410
0.03 510

27)
28)
29)
30)
31)

43

8
3
6

500 3100
1000
400 2800

230

890
950
0.14 1000
0.01 300

37)
38)
38)
39)
40)

13
14
18
16

19
9
400 2550
517 2941
374 2025

24
7
0.12 890
0.09 1227
0.09 1179

F1
F2
F3
F4
F5

As

D
S

W
S

SD
S
S
D

S
D

F6
F7
F8
F8
F9
F10

S
S
S
S
F

D
W
W
D

F11
F 12
F12
F13
F14
F15

S
S
S
S
S

D
D
W
D
W

F26
F27
F28
F29

S
F
S

W
D
W
D

Cd

Cr

Cu

180 300 1800

180 400 1700
120 300 1100
80

200

Hg
1.5
4.2
40

Pb
5800
8700
7800
186
990

41)
41)
41)
42)
24)

400

1800

760

2 245 275
684 7700

0.2 1200 24)

19900 24)
3.6
3 6 4600 24)
0.5 1450 21)
4100 43)

400

600

1490
4660
88 494 512
304 149 1940

900 26)
0.3 1500 28)
12600 25)
4.1 1480 44)
3.4 8330 44)

0.6

200 200
5.1 12800 50)
1.3
9 280 3800 1.7 1000 51)
40.0 220

14.0 6300 52)

6.0 69 200

1000 39)
5 16 14 26
6.0 180 290 880
12.6 458 353 1577
16.4 1129 207 1793

13
3.6
6.6
11

2000
19931998 -
S:F:: D:, SD:W:, :

28
2545
5100
5279
30

No 1
No.1

No 2
No.2

31

(2010)

32

33

34


1
1
1

1000
1000
1000

1000

1 m3

ppm 1
1 000 000 mg/kg 1 000 000 ppm = 100%
10 000 mg/kg
10 000 ppm = 1%
1 mg/L 1 ppm

1 1
35

100

13

10

5.5
3.4

2.55

2.2

01
0.1

0.01

0.15

0.145

0.15

1kkg

0.315

0.1
0.06

0.01

10

0.08

0.1

0.09

0 05
0.05

1.9

10

10

100

100

0.1

1kg

1kkg

1000

1kg

0.1

0 01
0.01

0 01
0.01

0 01
0.01

0.013

0.013

0.001

http:// www.union.tokyo23-seisou.lg.jp/thermal/kentouiinkai/sixth/13.pdf (H18-H21)

0 01
0.01

36

1) 4

11)

ND

ND

ND

0.026

0.026

ND

ND

0.000

ND

ND

ND

ND

ND

ND

0.006

0.003

0.001

0.000

0.002

0.000

0.001

0.006

0.001

0.007

ND

ND

0.001

ND

0.026

0.007

ND

ND

ND

ND

0.001

0.001

0.034

0.003

0.036

0.002

0.002

0.000

ND

0.084

ND

ND

ND

ND

ND

ND

ND

ND

ND

0.008

ND

ND

ND

ND

0.008

ND

ND = Not Detected =

2), 3)

150ppm

1.0ppm

20mg/g

4%0.05mg/L

1) 14 http://www.eikanken-okinawa.jp/shokuG/osenbutu/osenbutu.htm
2) http://www.shokusan.or.jp/haccp/hazardous/2_8_ziyukin.html , 3) http://wwwhourei.mhlw.go.jp/hourei/index.html

38

39

1
1.
2.
3.
4.
5.

1. ()
2. ?
40

81
2

1
3
200712
41
37

R
R

S
N

Pb

C
S

R
C

N
R

42

43

44

45

R
R

S
N

Pb

C
S

R
C

N
R

A
B

C
46


48 13

0.5 5 mm

50 g

(10)

7
5

6
200 , 45 cm

0.3

0.3
1.5
0 3
0.3
0.005

0.3
3

12
11
1
1
12
111
112
13

1
1
0.003
0

0.3
3
0.1
0.2
0.02
120.04
110

1 1 0.2
2
120.4
1113
1120.06
130.02
0.06

0.06
0.03
0.2
0.1
3

100

10

1
0

0.1
0.01

-500

0 001
0.001

05
0.5

10
1.0

-1000
15
1.5

1kg

1 kg

2002

49

50

?
(mg/L)

0 m 1
0 m 2
1 m 1

1 m 2

2 m 1
3 m 1
4 m 1
5 m 1

Pb
81
< 0.001
0.002
0.028
0.007
0 009
0.009
0.009
0.006
0.016
0.031
0 031
0.3
< 0.02
0.1

Cd
0.001
< 0.001
< 0.001
< 0.001
< 0.001
< 0.001
0 001
< 0.001
< 0.001
< 0.001
< 0.001
0 001
0.3
< 0.001
0.1

Cu
0.017
0.008
< 0.001
< 0.001
< 0.001
< 0.001
0 001
< 0.001
< 0.001
< 0.001
< 0.001
0 001
-

Zn
4.2
0.15
0.001
0.022
0.015
0 018
0.018
0.009
0.004
0.008
0.015
0 015
-

pH
H
12.6
12.5
8.8
11.3
11.3
11 3
11.3
11.3
11.1
11.1
11.1
11 1
6.7
59

51

200 g

100 mL

9 3 3
H, K, S
pH H,
H K
K, S
H, K, S
7 2 L
L

52

1000

100
Pb
(mg/L
L)

H pH
H
K

Pb
IC = 0.5 mg/L
IC = 5.0 mg/L

10

0.1

0.01
0

10

12

14

pH

pH Pb
53

()

()

Air-Drying

40

51

N2-Drying

40

26

Air Purge
Air-Purge

37

68

O2-Wet

37

68

N2-Wet

37

68

, N2

, O2,
N2

54

100

Pb
(mg/L
L)

J
10

N2-Drying

Air-Drying
y g
N2-Drying

O2-Wet
1

Air-Purge

Air-Drying

O2-Wet
Air-Purge

0.1

N2-Wet

N2 Wet
N2-Wet
0.01

20

40
(d)

60

80 0

20

40
(d)

60

80

Pb

( pH 12 )
55

56

0.3 mg/L (

0.01 mg/L

0.01 mg/L

0 01 mg/L
0.01

0.1 mg/L

g
0.01 mg/L

0.1 mg/L

57

3
1. pH(13.5)

2. (
)
3
3.

58

59

60

 (2007.03 )

61

20073

200712

23

1
2
14

23

23

17

11

1
0
13

11

14

23

0
0
0
0
0

24
25
14
0
63

()

32

32

0
1
0
1
2

33
12
13
1
59
62


200712

(%)

30

n
16 000
16,000

20
10

(%))

0
0
40

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

30

n45
9,200

20
10
0
0
40

(%)

40

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

30

n29
32,000

20

n26
2,500

10
0
0
40

(%)

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

30

n21
51,000
,

20

n17
14,000
,

10
0

5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 85 90 95 100

()

63

30%

64

65

66

67

No 1
No.1

No 2
No.2

(2010)

68

No 1
No.1

No 2
No.2

69

(2010)

(
)

()

()

70

2
2
2

71