2012 Box Ha hc

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TUYN TP CC BI TP HA HC HAY
V LI GII CA DIN N BOXMATH
PHN BI TP
Phn bi tp ch l tp nh km cho tuyn tp chnh thc c li gii y .
Cc bn c th ti xung tuyn tp chnh thc min ph ti www.boxmath.vn.

BoxMath, thng 1 2012

PHN 1. CC BI TON V C
Bi 1. _________________________________________________________________________________
Hn hp A gm mui sunfit, hidrosunfit v sunfat ca cng mt kim loi kim M. Cho 17,775 gam hn hp
A vo dung dch Ba(OH ) 2 d, to thnh 24,5275 gam hn hp kt ta. Lc kt ta, ra sch v cho kt ta
tc dng vi dung dch HCl d, thy cn 2,33 g cht rn. Kim loi kim M l
A. Li
B. K
C. Rb
D. Na
Bi 2. ______________________________________________________________________________
Cho mt hp cht ca st tc dng vi H 2 SO4 c nng, to ra SO2 (sn phm kh duy nht). Nu t l

H 2 SO4 em dng v SO2 to ra l nH 2 SO4 : nSO2 4 :1 th cng thc phn t ca X l:

A. Fe
B. FeS
C. FeO
D. Fe3O4
Bi 3. _____________________________________________________________________________
Cho t t a gam st vo V ml dung dch HNO3 1M khuy u cho n khi tan ht thy thot ra 0,448 lt kh
NO (ktc) ng thi thu c dung dch A . Dung dch A c kh nng lm my mu hon ton 10 ml dung
dch KMnO4 0,3M trong mi trng axit. Gi tr ca a v V l:
A. a =1,4 gam; V = 80 ml
B. a = 1,12 gam; V = 80 ml
C. a = 0,56 gam; V = 56 ml
D. a = 0,84 gam; V = 60 ml
Bi 4. _____________________________________________________________________________
Hn hp X gm c Al , Fex Oy . Tin hnh nhit nhm hon ton m( g ) hn hp X trong iu kin khng c
khng kh thu c hn hp Y. Chia Y thnh hai phn.
Phn 1. Cho tc dng vi NaOH d thu c 1,008 lt H 2 (ktc) v cn li 5,04 gam cht rn khng tan.
Phn 2 c khi lng 29,79 gam, cho tc dng vi dung dch HNO3 long d thu c 8,064 lt NO (ktc,
l sn phm kh duy nht).
Gi tr ca m v cng thc ca oxit st l
A. 39,72 gam & FeO
B. 39,72 gam & Fe3O4
C. 38,91 gam & FeO
D. 36,48 gam & Fe3O4
Bi 5. ______________________________________________________________________________
in phn in cc tr dung dch cha 0,2 mol AgNO3 vi cng dng in 2,68 A, trong thi gian t
(gi) thu c dung dch X (hiu sut ca qu trnh in phn l 100%). Cho 16,8 gam bt Fe vo X thy
thot ra kh NO (sn phm kh duy nht) v sau cc phn ng hon ton thu c 22,7 gam cht rn. Gi tr
ca t l:
A. 2,00
B. 1,00
C. 0,50
D. 0,25
Bi 6. _______________________________________________________________________________
Cho 8,64 gam Al vo dung dch X (X c to thnh bng 74,7 gam hn hp Y gm CuCl2 v FeCl3 vo
nc). Kt thc phn ng thu c 17,76 gam cht rn gm hai kim loi. T l mol ca FeCl3 : CuCl2 trong
hn hp Y l:
A. 2:1
B. 3:2
C. 3:1
D. 5:3
Bi 7. _______________________________________________________________________________
Cho 240 ml dung dch Ba(OH ) 2 1M vo 200 ml dung dch hn hp AlCl3 a mol/lt v Al2 ( SO4 )3 2a mol/lt
thu c 51,3 gam kt ta. Gi tr ca a l:
A. 0,12
B. 0,15
C. 0,16
D. 0,2
Bi 8. ______________________________________________________________________________
un nng hn hp gm Fe v S c t l mol 1:2 trong bnh kn cha khng kh thu c hn hp X. Cho
hn hp X tc dng vi dung dch HCl d n khi phn ng hon ton thy khi lng cht rn gim 60%.
Hiu sut ca phn ng l:
A. 50%
B. 25%
C. 33,33%
D. 66,67%
Bi 9. ______________________________________________________________________________
Cho a mol kim loi M (ha tr n khng i) tan va ht trong dung dch cha 54 a mol H 2 SO4 c 19,32
gam mui v kh B. Lng kh B c hp th hon ton bi 250ml dung dch NaOH 0,2M to thnh 2,12
gam mui. Xc nh kim loi.
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A. Na
B. Cu
C. Zn
D. Al
Bi 10. _____________________________________________________________________________
Cho 9,6 gam kim loi R tc dng vi 500ml dung dch HNO3 c mol/lt va , thu c 2,24 lt kh A (l
kh duy nht, ktc) v dung dch B. C cn dung dch B thu c 59,2 gam mui khan. A khng th l kh
no sau y?
A. N2O
B. N 2
C. NO
D. NO2
Bi 11. _____________________________________________________________________________
Cho 13,32 mol hn hp Zn v ZnO tan hon ton trong dung dch cha 0,38 mol H 2 SO4 thu c mt sn
phm duy nht v dung dch ch cha mui sunfat. S mol sn phm kh thu c l:
A. 0,19
B. 0,18
C. 0,16
D. 0,20
Cu 12. _____________________________________________________________________________
X l hn hp ca hai kim loi gm kim loi kim M v kim loi kim th R. Ly 28,8 gam X ha tan vo
nc thu c 6,72 lt kh H 2 (ktc). em 2,8 gam Li luyn thm vo 28,8 gam X th phn trm khi lng
Li trong hp kim va luyn c l 13,29%. Kim loi kim th R trong X l?
A. Mg
B. Ca
C. Ba
D. Sr
Cu 13. _____________________________________________________________________________
t hn hp gm 0,4 mol Fe v 0,2 mol Cu trong bnh ng kh O2 , sau mt thi gian thu c m gam
cht rn. em cht rn ny tc dng vi HCl d, sau phn ng hon ton c 3,36 lt kh thot ra ( ktc) v
6,4 gam kim loi khng tan. Gi tr ca m c th l:
A. 44,8
B. 41,6
C. 40,8
D. 38,4
Bi 14.______________________________________________________________________________
Cho 12,4 gam hn hp gm mt kim loi kim v oxit ca n tc dng vi dung dch HCl d th thu c
27,75 gam mui khan. Kim loi kim th l
A. Ba
B. Mg
C. Ca
D. Sr
Bi 15. ____________________________________________________________________________
Cho 11,36 gam hn hp gm Fe, FeO, Fe2O3 , Fe3O4 phn ng ht vi dung dch HNO3 long d thu c
1,344 lt kh NO (sn phm kh duy nht, kc) v dung dch X. Dung dch X c th ho tan ti a 12,88
gam Fe (to kh NO duy nht). S mol HNO3 c trong dung dch u l?
A.0,88mol
B.1,04mol
C.0,64mol
D.0,94mol
Bi 16. _____________________________________________________________________________
Ha tan hn hp X nng m gam gm Fe, FeCl2 , FeCl3 trong HNO3 c nng c 8,96 lt NO2 (sn phm
kh duy nht ktc) v dung dch Y. Thm NaOH d vo Y c 32,1 gam kt ta. Gi tr m l:
A. 16,8
B. 25,675
C. 34,55
D. 17,75
Bi 17.______________________________________________________________________________
Cho m gam KOH vo 2 lt KHCO3 a (M) c 2 lt X. Ly 1 lt X tc dng vi BaCl2 d thu c kt ta
15,76 g kt ta. Mt khc cho 1 lt X tc dng CaCl2 d ri un nng, sau cc phn ng xy ra hon ton
thu c 10 g kt ta. Gi tr ca m v a ln lt l:
A. 5,6 g; 0,04 M
B. 8,96 g; 0,12 M
C. 4,48 g; 0,06 M
D. 5,04 g; 0,07 M
Bi 18. ____________________________________________________________________________
Lc 13,14 gam Cu vi 250ml AgNO3 0,6M mt thi gian thu c 22,56 cht rn A v dung dch B. nhng
kim loi M nng 15, 45 gam vo dung dch B khuy u n khi phn ng hon ton thu c dung dch ch
cha 1 mui duy nht v 17,355 g cht rn Z. Xc nh M.
Cu 19. ___________________________________________________________________________
Ha tan 3 gam hn hp kim loi R ha tr I, M ha tr II vo dung dch hn hp HNO3 , H 2 SO4 . Sau phn
ng thu c dung dch A v 1,344 lt hn hp B gm NO2 v kh C , khi lng hn hp B l 2,94 gam.
Nu ly 1 t dung dch A cho tc dng lng d Cu v H 2 SO4 long th khng c kh thot ra. Tnh khi
lng mui khan trong dung dch A ?
Bi 20. ____________________________________________________________________________

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Dung dch X gm FeCl2 , MgCl2 , AlCl3 . Cho 200ml dung dch X tc dng vi NaOH long d thu c
20,6 g kt ta. Nu cho 200 ml dung dch X tc dng vi lng d Na2CO3 ta thu c 44 g kt ta. Nu
cho 200 ml dung dch X tc dng vi lng d NH 3 . Lc kt ta nung n khi lng khng i trong
khng kh thu c 26,2 g cht rn. Tnh nng mol ca cc cht trong X ?
Bi 21.______________________________________________________________________________
Cho 8,96 lt hn hp 2 kh H 2 v CO (ktc) i qua ng s ng 0,2 mol Al2O3 v 0,3 mol CuO nung nng
n phn ng hon ton thu c cht rn X. X phn ng va trong 0,5 lt dung dch HNO3 c nng
a M (sn phm kh l kh NO duy nht). Gi tr ca a l:
A. 3,67
B. 2,80
C. 4,00
D. 2,00
Bi 22. _____________________________________________________________________________
Nung nng m gam hn hp Al v Fe2O3 (trong mi trng khng c khng kh) n khi phn ng xy ra
hon ton, thu c hn hp rn Y . Chia Y thnh hai phn bng nhau:
Phn 1 tc dng vi dung dch H 2 SO4 long (d), sinh ra 3, 08 lt kh H 2 ( ktc);
Phn 2 tc dng vi dung dch NaOH (d), sinh ra 0,84 lt kh H 2 ( ktc).
Gi tr ca m l
A. 22, 75
B. 21, 40
C. 29, 40
D. 29, 43
Cu 23. ____________________________________________________________________________
Hn hp X gm Na v Al . Cho m gam X vo 1 lng nc(d) th thot ra V lt kh. Nu cng cho m gam
X vo dung dch NaOH d th thu c 1, 75V lt kh. Thnh phn % theo khi lng ca Na trong X l
bao nhiu? (bit cc th tch o cng iu kin)
Bi 24._____________________________________________________________________________
Cho dung dch cha 6,03 gam hn hp gm hai mui NaX v NaY (X, Y l hai nguyn t c trong t
nhin, hai chu k lin tip thuc nhm VIIA, s hiu nguyn t Z X ZY ) vo dung dch AgNO3 (d), thu
c 8,61 gam kt ta. Phn trm khi lng ca NaX trong hn hp ban u l
A. 58,2%.
B. 41,8%.
C. 52,8%.
D. 47,2%.
Bi 25. ______________________________________________________________________________________
Nung mt hn hp rn gm a mol FeCO3 v b mol FeS2 trong bnh kn cha khng kh (d). Sau khi cc
phn ng Xy ra hon ton, a bnh v nhit ban u, thu c cht rn duy nht l Fe2O3 v hn hp
kh. Bit p sut kh trong bnh trc v sau phn ng bng nhau, mi lin h gia a v b l (bit sau cc
phn ng, lu hunh mc oxi ho +4, th tch cc cht rn l khng ng k)
A. a = 0,5b.
B. a = b.
C. a = 4b.
D. a = 2b.
Bi 26. ______________________________________________________________________________________
Ha tan hn hp gm m gam Cu v 116 gam Fe3O4 vo dung dch H 2 SO4 long d sau khi cc phn ng
kt thc ch thu c dung dch X . X lm mt mu va 300 ml dung dch KMnO4 0, 4M . Gi tr ca m
l?
Bi 27. ____________________________________________________________________________
Nung m gam hn hp X gm FeS v FeS2 trong mt bnh kn cha khng kh (gm 20% th tch O2 v
80% th tch N 2 ) n khi cc phn ng xy ra hon ton thu c mt rn duy nht v hn hp kh Y c
thnh phn th tch 84,8% N 2 , 14% SO2 , cn li l O2 . Phn trm khi lng FeS trong hn hp X l:
A. 42,31%
B. 59,46%
C. 19,64%
D. 26,83%.
Bi 28. ______________________________________________________________________________
Ha tan hon ton m gam hn hp X gm FeS2 v Cu2 S trong H 2 SO4 c nng d thu c 4,48 lt kh

SO2 . Nu ha tan m gam hn hp X ni trn vo HNO3 c nng d th thu c dung dch Y . Ly 1/2
dung dch Y cho tc dng vi BaCl2 d thu c 5,825 gam kt ta. Gi tr m l:
A. 4g
B. 2,8g
C. 5,2g
D. 4,4g
Bi 29. _____________________________________________________________________________________
Thm V (lt) dung dch Ba(OH ) 2 0,1M vo 100 ml KAl ( SO4 )2 0,1M c 2,1375 gam kt ta. Tnh V?
A. 0,05
B. 0,075
C. 0,08
D. 0,01
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Bi 30. ______________________________________________________________________________________
Nung 18,96 gam hn hp X gm Cu , Cu ( NO3 )2 trong bnh kn khng cha khng kh n khi phn ng
hon ton thu c m gam rn Y. ha tan ht Y cn dng 400 ml dung dch HNO3 1M, thu c a mol
kh NO (sn phm kh duy nht). Gi tr m v a ln lt l
A. 12,48 v 0,08
B. 13,44 v 0.04
C. 12,48 v 0,04
D. 13,44 v 0,08
Bi 31. ____________________________________________________________________________
Cho m gam hn hp X gm Al , Fe3O4 , FeO, Fe2O3 tc dng vi dung dch HCl d thu c dung dch
Y , trong khi lng ca FeCl2 l 31,75 gam v 8,064 lt H 2 (ktc). C cn dung dch Y thu c

151,54 gam cht rn khan. Nu cho m gam hn hp X tc dng vi dung dch HNO3 long d thu c
dung dch Z v kh NO (sn phm kh duy nht). C cn dung dch Z thu c bao nhiu gam mui
khan?
A. 242,3
B. 268,4
C. 189,6
D. 254,9
Bi 32. ______________________________________________________________________________
Ha tan hon ton hn hp X gm 0,11 mol Al v 0,15 mol Cu vo dung dch HNO3 th thu c 1,568 lt
(ktc) hn hp Y gm 2 kh (trong c mt kh khng mu ha nu ngoi khng kh) v dung dch Z cha
2 mui. Xc nh s mol HNO3 tham gia phn ng.
A. 0,63
B. 0,7
C. 0,77
D. 0,76
Bi 33. ______________________________________________________________________________
Cho x mol Fe tan hon ton trong dung dch cha y mol HNO3 ( x : y 16 : 61 ) thu c mt sn phm kh
duy nht v dung dch ch cha mui nitrat. S mol e do lng st trn nhng l khi b ha tan l:
A. y
B. 3x
C. 2x
D. 0,75y
Bi 34. _____________________________________________________________________________
Ha tan ht 6,08 gam hn hp gm Cu v Fe bng dung dich HNO3 thu c dung dch X v 1,792 lt NO
(dktc). Thm t t 2,88 gam bt Mg vo dung dch X n khi phn ng hon ton thu c 0,448 lt NO
(ktc), dung dch Y v m gam cht rn khng tan. Gi tr ca m l:
A. 4,96 gam
B. 3,84 gam
C. 6,4 gam
D. 4,4 gam
Bi 35. ____________________________________________________________________________
Ly m(g) K cho tc dung 500ml dung dch HNO3 thu c dung dch M v thot ra 0,336(l) hn hp N
(ktc) gm 2 kh X v Y. Cho thm vo M vo dung dch KOH d th thot ra 0,224 (l) Y. Bit qu trnh
kh HNO3 ch to ra 1 sn phm kh duy nht. m c gi tr l
A. 3,12
B. 7,8
C. 12,48
D. 6,63
Bi 36. _____________________________________________________________________________
ha tan ht mt ming km trong dung dch axit HCl 20o C cn 27 pht. Nu thc hin th nghim
40o C th thi gian phn ng l 3 pht. Nu thc hin th nghim 55o C th thi gian phn ng l :
A.34,64s.
B.64,43s
C.44.36s
D.43.64s
Bi 37. _____________________________________________________________________________
Ly 32 g FexO y nung nng ri dn kh CO vo, sau mt thi gian ta thu c m gam cht rn gm nhiu
cht v V (l) kh B. Dn V1 (l) kh B ( V1 < V ) vo dung dch Ca(OH ) 2 d th thu 56 gam kt ta. Tm cng
thc ca FexO y . Bit cc th tch o cng iu kin nhit , p sut.
A.FeO
B. Fe2O3
C. Fe3O4
D. Cha d kin xc nh
Bi 38. _____________________________________________________________________________
Dung dch X cha 14,6 g HCl v 22,56g Cu ( NO3 )2 . Thm m( g ) Fe vo dung dch X sau khi phn ng
xy ra hon ton thu c hn hp kim loi c khi lng 0,5m v ch to NO (sn phm kh duy nht). Gi
tr ca m l
A. 1,92 g
B. 20,48g
C. 14,88
D. Khng tn ti m tha mn
Bi 39. _____________________________________________________________________________

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Cho 11,15 gam hn hp gm hai kim loi Al v kim loi kim M vo trong nc. Sau phn ng thu ch
c dung dch B v V lt kh (ktc). Cho t t n 400 ml dung dch HCl 1M vo dung dch B. Trong qu
trnh thu c lng kt ta ln nht l 15,6 gam, sau kt ta tan mt phn. Kim loi kim l:
A. Ba
B. Na
C. K
D. Khng d kin
Bi 40. _____________________________________________________________________________
Dung dch A gm NaOH 1M v Ba(OH ) 2 0,5M. Dung dch B gm AlCl3 1M v Al2 ( SO4 )3 0,5M. Cho V1
lt dung dch A vo V2 lt dung dch B thu c 427,5V2 (gam) kt ta. T s V1 : V2 l:
A. 2,537
B. 3,5
C. 3
D. A hoc B.
Bi 41. _____________________________________________________________________________
Phn ng no sau y sai.
A. 2HI + Cu CuI2 + H2
B. 2HBr + 2FeCl3 2FeCl2 + Br2 + 2HCl
C. H2O2 + KNO2 H2O + KNO3
V2O5 , t o

2SO3
D. 2SO2 + O2

Bi 42. _____________________________________________________________________________
Chn pht biu ng nht
A. Trong kh than kh, hm lng CO nhiu hn kh than t
B. Trong phng thi nghim, CO c iu ch bng cch thi CO2 qua C nung nng trn ngn la
n cn
C. CO c thu bng cch y khng kh (p ngc bnh)
D. CO c dng lm nhin liu kh
Bi 43. _____________________________________________________________________________
(1) Ngi ta khng dng CO2 dp tt cc m chy c Al, Mg do Al, Mg c th chy trong CO2
to hp cht cacbua
(2) Trong cng nghip, kh CO2 c thu hi trong qu trnh ln men ru t glucz
(3) CO km bn nhit, d tc dng vi oxi to CO2
(4) Trong t nhin, Cacbon ch yu tn ti trong cc khong vt: canxit, magiezit, dolomit,...
C bao nhiu pht biu ng trong cc pht biu trn?
A. 1
B. 2
C. 3
D. 4
Cu 44. ____________________________________________________________________________
Ha tan m gam hn hp X gm Cu, Al vo dung dch HCl d thy c 2 gam cht rn khng tan. Nu trn
thm 4 gam Mg vo 0,5m gam X th c hn hp Y. Hm lng % theo khi lng ca Al trong Y nh
hn trong X l 33,33%. Khi cho Y tc dng vi dung dch NaOH th th tch H 2 thu c ktc nhiu hn
2 lt. Thnh phn phn trm theo khi lng ca Cu trong X l:
A.40%
B.16.67%
C.18.64%
D.30%
Bi 45. ____________________________________________________________________________
Nung 10 gam hn hp gm MgCO3 , CaCO3 , BaCO3 thu c kh A. Dn kh A vo dung dch nc vi
trong d thu c 5 gam kt ta v dung dch B. un nng B hon ton th thu c thm 3 gam kt ta
na. Hi % khi lng MgCO3 trong hn hp ban u nm khong no?
A. 52,5% n 86,69%
C. 52,5% n 60,64%
B. 60,64% n 86,69%
D. 86,69% n 90,45%
Bi 46. _____________________________________________________________________________
Ha tan hon ton m gam hn hp gm FeS2 v Cu2 S trong dung dch HNO3 sau cc phn ng xy ra
hon ton thu c dung dch X ch c hai cht tan khi lng cc cht tan l 72. Gi tr ca m l
A. 20
B. 40
C. 60
D. 80
Bi 47. _____________________________________________________________________________
Hin tng g xy ra khi cho H 2 S li qua dung dch FeCl3 (mu vng)?
A. Khng c hin tng g.
B. Mu vng mt dn v c kt ta en xut hin.
C. Mu vng mt dn v c kt ta mu vng xut hin.
D. Mu vng mt dn v c kt ta mu nu xut hin.
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PHN 2. CC BI TON HU C
Bi 1. _____________________________________________________________________________
Oxi ha 9,2 gam ru etylic bng CuO un nng, c 13,2 gam hn hp (andehit, axit, nc v ru cha
phn ng). Hn hp ny tc dng vi Na to ra 3,36 lt H 2 (ktc). Phn trm khi lng ru b oxi ha l:
A. 75%
B. 25%
C. 66,67%
D. 33,33%
Bi 2. _____________________________________________________________________________
Thy phn hon ton 60 gam hn hp hai ipeptit thu c 63,6 gam hn hp X gm cc amino axit (ch c
1
1 nhm amin v 1 nhm cacboxyl). Nu cho
hn hp X tc dng vi HCl (d), c cn cn thn dung
10
dch, th lng mui khan thu c l:
A. 7,82
B. 16,3
C. 7,09
D. 8,15
Bi 3. _____________________________________________________________________________
Hn hp X gm Cn H 2n 1CHO,Cn H 2 n1COOH ,Cn H 2n 1CH 2OH (u mch h, n nguyn dng). Cho 2,8
gam X phn ng va vi 8,8 gam brom trong nc. Mt khc cho ton b lng X trn phn ng vi
lng d dung dch AgNO3 trong NH 3 , kt thc phn ng thu c 2,16 gam Ag . Phn trm khi lng
ca Cn H 2 n1CHO trong X l:
A. 26,63%
B. 22,22%
C. 20,00%
D. 16,42%
Bi 4. ____________________________________________________________________________
Cho cc cht lng khng mu: dung dch NaHCO3 , dung dch NaAlO2 , dung dch C6 H 5ONa, C6 H 5OH ,

C6 H 5 NH 2 , CH 3COOC2 H 5 , C2 H 5OH , C3 H 7OH . Ch dng thm HCl c th nhn ra s lng cht lng l?
A. 5
B. 7
C. 8
D. 6
Bi 5. ______________________________________________________________________________
Oxi ha 9,2 gam ru etylic bng CuO un nng, c 13,2 gam andehit, axit, ru cha phn ng v nc.
Hn hp ny tc dng vi Na d sinh ra 3,36 lt H 2 (ktc). Phn trm khi lng ru b oxi ha l bao
nhiu?
Bi 6. ______________________________________________________________________________
Hn hp A gm CH 4 v H 2 . Cho A i qua ng ng bt Ni nung nng thu c hn hp B ch gm 3
hidrocacbon c t khi so vi H 2 l 21,5. T khi ca A so vi H 2 l:
A. 10,4
B. 9,2
C. 7,2
D. 8,6
Bi 7. ______________________________________________________________________________
Hp cht X cha C, H, O c khi lng mol phn t l 74 gam. X phn ng c vi NaOH . S cht tha
mn X l:
A. 3
B. 4
C. 5
D. 6
Bi 8. ______________________________________________________________________________
Hn hp M gm anken X v hai amin no, n chc, mch h Y, Z ( M Y M Z ). t chy hon ton mt
lng M cn dng 21 lt O2 , sinh ra 11,2 lt CO2 . Cng thc ca Y l
A. CH 3CH 2CH 2 NH 2

C. C2 H 5 NH 2

B. CH 3CH 2 NHCH 3
D. CH3 NH 2
Bi 9. ______________________________________________________________________________
Cho anilin tc dng vi cc cht sau: dung dch Br2 , H 2 , CH 3 I , dung dch HCl , dung dch NaOH , HNO2 .
S phn ng xy ra l:
A. 5
B. 3
C. 4
D. 6
Bi 10._____________________________________________________________________________
Cho hn hp 3,88 gam X gm 2 axit cacboxylic no, n chc, mch h. X tc dng vi NaOH to ra 5,2
gam mui. t chy hon ton 3,88 gam X cn bao nhiu lt O2 ?
A. 2,24
B. 3,36
C. 1,12
D. 5,6
Bi 11. _____________________________________________________________________________
t chy hon ton mt hidrocacbon mch h X (X l cht kh iu kin thng, X nng hn khng kh)
thu c 14,08 gam CO2 . Sc m gam hidrocacbon ny vo nc brom d n phn ng hon ton thy c
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51,2 gam brom tham gia phn ng. Gi tr ca m l:

A. 2
B. 4
C. 4,053
D. 4 hoc 4,053
Bi 12. ____________________________________________________________________________
t chy hon ton 29,6 gam hn hp X gm CH 3COOH , C x H y COOH , (COOH )2 thu c 0,8 mol nc
v m gam CO2 . Cng 29,6 gam X tc dng vi NaHCO3 d thu c 0,5 mol CO2 . Gi tr ca m l:
A. 11
B.22
C.44
D.33
Bi 13. ____________________________________________________________________________
Cho hn hp X gm ancol metylic v 2 axt k tip nhau trong dy ng ng ca axt axetic tc dng ht
vi Na gii phng 6,72 lt H 2 . Nu un nng hn hp X c H 2 SO4 c xc tc th cc cht trong hn hp
phn ng va vi nhau to thnh 25 gam este. t chy hon ton hn hp X ri dn sn phm qua bnh
H 2 SO4 c th khi lng ca bnh tng bao nhiu gam?
A.25,2
B. 23,3
C. 24,6
D. 15,2
Bi 14. _____________________________________________________________________________
a mol cht bo X c th cng hp ti a vi 4 a mol Br2 . t chy hon ton a mol X thu c b mol H 2O
v V lt kh CO2 . Biu thc lin h gia V vi a,b l:
A. V 22.4(b 7 a )
B. V 22.4(4a b)
C. V 22.4(b 3a)
D. V 22.4(b 6 a)
Bi 15. _____________________________________________________________________________
Cho hai hidrocacbon X v Y ng ng ca nhau, phn t khi ca X gp i Y. Cng thc tng qut ca
hai hidrocacbon l:
A.Cn H 2n 2
B.Cn H 2n 2
C.Cn H 2 n6
D.Cn H 2n
Bi 16. ____________________________________________________________________________
t chy hon ton 2,76 gam hn hp X gm: C x H y COOH ; C x H y COOCH 3 v CH 3OH thu c 2,688 lt

CO2 (ktc) v 1,8 gam H 2O . Mt khc, cho 2,76 gam hn hp X phn ng va vi 30ml dung dch
NaOH 1M, thu c 0,96 gam CH 3OH . Ly lng C x H y COOH c trong X cho tc dng hon ton vi hn
hp cha 0,04 mol CH 3OH v 0,06 mol C2 H 5OH , xc tc H 2 SO4 c, un nng. Gi s 2 ancol phn ng
vi kh nng nh nhau th khi lung este ho to thnh l:
A.0,88 gam
B.0,944 gam
C.1,62 gam
D.8,6 gam
Bi 17. _____________________________________________________________________________
Hn hp X gm vinyl axetat, metyl axetat , etyl fomat. t chy hon ton 3,08 gam X, thu c 2,16 gam
H 2O . Phn trm s mol ca vinyl axetat trong X l:
A.25%
B.27,92%
C.72,08%
D.75%
Bi 18. ____________________________________________________________________________
Cho X l hn hp gm H 2 v hi ca hai anehit (no, n chc, mch h, phn t u c s nguyn t C
nh hn 4), c t khi so vi heli l 4,7. un nng 2 mol X (xc tc Ni), c hn hp Y c t khi hi so
vi heli l 9,4. Thu ly ton b cc ancol trong Y ri cho tc dng vi Na (d), c V lt H 2 (ktc). Gi tr
ln nht ca V l:
A. 22,4
B. 5,6
C. 11,2
D. 13,44
Bi 19. ____________________________________________________________________________
Hn hp X gm O2 v O3 c t khi so vi H 2 l 22. Hn hp kh Y gm metylamin v etylamin c t khi
107
so vi H 2 l
. t chy hon ton V1 lt Y cn va V2 lt X (bit sn phm chy gm CO2 , H 2O
6
v N 2 , cc cht kh khi o cng iu kin nhit , p sut). T l V1 : V2 l:
A. 3 : 5
B. 5 : 3
C. 2 : 1
D. 1 : 2
Bi 20. _____________________________________________________________________________
Hn hp X gm 2 axit hu c no (mi axit cha khng qu 2 nhm COOH ) c khi lng 16g tng
ng vi 0,175 mol. t chy hon ton hn hp X ri cho sn phn qua nc vi trong d thu c 47,5 g

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kt ta. Mt khc, nu cho hn hp X tc dng va vi dung dch Na2CO3 thu c 22, 6g mui. Cng
thc cu to ca cc axit trong hn hp X l:
A. HCOOH , (COOH )2
B. CH 3COOH , (COOH )2

C. C2 H 5COOH , HOOC CH 2 COOH

D. CH 3COOH , HOOC CH 2 COOH
Bi 21. _____________________________________________________________________________
Cho hp cht thm X: C6 H8 N 2O3 . Cho 28,08g X tc dng 200ml KOH 2M. Sau phn ng thu c dung
dch Y. C cn Y c m gam cht rn khan. Gi tr ca m l?
A. 21,5g
B. 30,5g
C. 18,1g
D. 38,8g
Bi 22.____________________________________________________________________________
Cho hn hp X HCOOH , CH 3COOH (t l mol 1:1) v hn hp Y ch CH 3OH , C2 H 5OH (t l mol l
2:3). 16,96 gam hn hp X tc dng vi 8,08 g Y (c xc tc H 2 SO4 c) thu c m gam este (Hiu sut
cc phn ng este ha bng 80%). Gi tr ca m l?
Bi 23. ____________________________________________________________________________
t chy m gam hn hp X gm 2 ancol n. Cho ton b sn phm chy qua bnh 1 ng H 3 PO4 c sau
cho qua bnh 2 ng nc vi trong d. Sau th nghim thy bnh 1 tng 1,98 gam, bnh 2 c 8 gam kt
ta. Mt khc, cho m gam hn hp X tc dng vi CuO un nng c sn phm ha c Y. Cho Y tc dng
vi lng d AgNO3 trong NH 3 thu c 2,16 gam Ag . Xc nh CTCT 2 ancol.
Bi 24. ____________________________________________________________________________
Kh hon ton este n chc no X bng LiAlH 4 , thu c hn hp hai ancol Y ng ng k tip. Oxi ho
ht Y bng CuO, nhit thu c 7,65 gam hn hp cc cht hu c Z. Cho Z phn ng vi lng d
dung dch AgNO3 / NH 3 thy sinh ra 16,2 gam Ag kt ta. Xc nh CTCT X, bit M X 120 .
A. CH3COOCH 2CH 2CH 3

B. HCOOCH 2CH 3

C. C2 H 3COOCH 2CH 2C2 H 3

D. C A v B

Bi 25.______________________________________________________________________________________
t chy hon ton mt este n chc, mch h X (phn t c s lin kt nh hn 3), thu c th tch
6
kh CO2 bng th tch kh O2 phn ng (cc th tch kh o cng iu kin). Cho m gam X tc dng
7
hon ton vi 200 ml dung dch KOH 0, 7 M thu c dung dch Y . C cn Y thu c 12,88 gam cht rn
khan. Gi tr ca m l bao nhiu?
Bi 26. ______________________________________________________________________________________
Cho m gam tinh bt ln men thnh ancol (ru) etylic vi hiu sut 81% . Ton b lng CO2 hp th hon
ton vo dung dch nuc vi trong, thu c 550 g kt ta v dung dich Y . un k dung dch Y thu thm
100 gam kt ta. Khi lng m l bao nhiu ?
Bi 27.______________________________________________________________________________________
Cho 200 gam mt loi cht bo c ch s axit bng 7 tc dng va vi mt lng NaOH, thu c 207,55
gam hn hp mui khan. Khi lng NaOH tham gia phn ng l:
A. 31 gam
B. 32,36 gam
C. 30 gam
D. 31,45 gam
Bi 28. ______________________________________________________________________________________
Khi thu phn kim 265,2 g cht bo to bi mt axitcacboxylic thu uc 288 gam mui kali. Cht bo ny
c tn gi l:
A. glixerol tristearat
B. glixerol trioleat
C. glixerol trilinoleat
D. glixerol tripanmitat
Bi 29. _____________________________________________________________________________________
A l mt hn hp gm hai cht thuc dy ng ng ca stiren c khi lng phn t hn km nhau 14
vC. t chy hon ton m gam A bng O2 d. Cho sn phm chy hp th vo 300ml dung dch NaOH
2M. Khi lng bnh ng dung dch tng 22,44 gam v thu c dung dch D. Cho BaCl2 d vo dung
dch D thu c 35,46 gam kt ta. cc phn ng Xy ra hon ton. Tm CTPT ca 2 hidrocacbon trong A.
Bi 30. _____________________________________________________________________________________

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Hp cht X mch h c CTPT l C4 H 9 NO2 . Cho 10,3 g X phn ng va vi dung dch NaOH sinh ra 1
cht kh Y v dung dch Z. Kh Y nng hn khng kh, lm qu tm m chuyn mu Xanh. dung dch Z c
kh nng lm mt mu nc brom. C cn dung dch Z thu c m g mui khan. Gi tr m?
Bi 31. ____________________________________________________________________________
Aminoaxit Y cng thc c dng NC x H y COOH m . Ly mt lng axit aminoaxetic ( X ) v 3,104 gam Y.
Bit X v Y c cng s mol. t chy hon ton lng X v Y trn, th tch O2 cn dng t chy Y
nhiu hn X l 1,344l (ktc). CTCT thu gn ca Y l:
A. CH 3 NHCH 2COOH
B. H 2 NCH 2CH 2COOH
C. N CH 3COOH 3

D. NC4 H 8 COOH 2

Bi 32. _____________________________________________________________________________
Cho 0,02 mol mt este X phn ng va ht vi 200 ml dung dch NaOH 0,2M, sn phm to ra ch 1 mui
v mt ancol u c s mol bng s mol este, u c cu to mch thng. Mt khc khi x phng ho hon
ton 2,58 gam este bng 20 ml dung dch KOH 1,5M va thu c 3,33 gam mui. Vy X l:
A. etilenglicol oxalat
B. etilenglicol adipat
C. imetyl adipat
D. ietyl oxalat
Bi 33. ____________________________________________________________________________
Mt este A ( khng cha chc khc) c to nn t 1 axit hu c B v 1 ancol C. Ly m gam A cho tc
dng vi KOH d thu c m1 gam mui. Ly m gam A cho tc dng vi Ca(OH ) 2 d thu c m2 gam
mui. Bit m2 m m1 . CT thu gn ca C l:
A. C2 H 5OH

B. CH 3OH

C. C3 H 7OH
D. C4 H8OH
Bi 34. _____________________________________________________________________________
Thc hin phn ng este ho 1 mol HCOOH v 1 mol C2 H 5OH nhit ko i, (xc tc H 2 SO4 c),
khi h cn bng thu 0,6 mol este. cng iu kin trn este ho 1mol C2 H 5OH v x mol HCOOH , khi h
cn bng thu 0,75 mol este. Gi tr ca x l:
A. 1,25 mol
B. 0,75mol
C. 2mol
D. 1mol
Bi 35. ____________________________________________________________________________
un 0,4 mol hn hp 2 ancol no, n chc, mch h k tip trong dy ng ng bng dung dch H 2 SO4

140o C thu c 7,704 g hn hp 3 ete. Tham gia phn ngs ete ho c 50% s mol ancol c khi lng
phn t ln v 40% ancol c khi lng phn t nh. Xc nh cng thc hai ancol.
A.Metylic v etylic
B. etylic v n-propylic
C. n-propylic v n-butylic
D. propan-2-ol v butan-2-ol
Bi 36. _____________________________________________________________________________
t hon ton 1,6 g este n chc E thu c 3,52 g kh cacbonic v 1,152 g hi nc. Mt khc, khi cho
10 g E tc dng vi lng NaOH va thu c 14 gam G. G tc dng axit long thu c G1 khng phn
nhnh. Pht biu no sau y sai:
A. E c to thnh t axit tp chc
B. Thu phn E cho 1 sn phm duy nht
C. Nung G vi vi ti xt thu c pentan
D. t G thu s mol CO2 bng s mol H 2O .
Bi 37. _____________________________________________________________________________
Cho hn hp X gm 2 cht hu c c cng cng thc phn t C2 H 7 NO2 tc dng va vi dung dch
NaOH v un nng thu c dung dch Y v 4, 48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy
qu m). T khi hi ca Z i vi H 2 bng 13, 75 . C cn dung dch Y thu c khi lng mui khan
l:
A.16,5 gam
B.14,3 gam
C.8,9 gam
D.15,7 gam
Bi 38. _____________________________________________________________________________________
C bao nhiu cht hu c c CTPT C2 H 2On tc dng vi AgNO3 / NH 3 thu c kt ta?
A. 2
B. 3
C. 4
D. 5
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Bi 39. _____________________________________________________________________________________
Cho 3,6 gam axit cacboxylic no n chc X tc dng hon ton vi 500ml dung dch KOH 0,12M v
NaOH 0,12M . C cn dung dch thu c 8,28 gam hn hp rn khan. Cng thc phn t ca X l g?
Bi 40. ____________________________________________________________________________
Hn hp A gm X , Y ( M X M Y ) l hai este n chc c chung gc axit. un nng m (g) A vi 400 ml
dung dch KOH 1M d thu c dung dch B v (m 12,6) gam hn hp gm hai andehit no, n chc,
ng ng k tip c t khi hi so vi H 2 l 26,2. C cn dung dch B thu c (m + 6,68) gam cht rn
khan. Phn trm khi lng ca X trong A l:
A. 54,66%
B. 45,55%
C. 36,44%
D. 30,37%
Bi 41. _____________________________________________________________________________
t chy hon ton mt lng hn hp kh X gm mt ankan v mt anken cn dng va 0,7 mol O2 ,
thu c 0,4 mol CO2 . Cng thc ca ankan l:
A. C4 H10
B. C3 H8
C. C2 H 6
D. CH 4
Bi 42. _____________________________________________________________________________
t chy hon ton 0,25 mol hn hp X gm H 2 N R (COOH ) x , Cn H 2n 1COOH thu c 0,6 mol

CO2 v 0,675 mol H 2O . Mt khc 0,2 mol hn hp X phn ng va vi dung dch cha a mol HCl .
Tnh a.
Bi 43. _____________________________________________________________________________
Cho hn hp gm 2 este mch h l ng phn ca nhau. Ly 0,2 mol X cho phn ng hon ton vi 300 ml
dung dch NaOH 1M, ri tin hnh chng ct c 8,5 gam hn hp hai ancol ng ng k tip nhau. C
cn phn dung dch cn li sau chng ct c cht rn A. Nung A trong oxi d n phn ng hon ton
c 22 gam CO2 v 7,2 gam H 2 O cng 1 lng Na2CO3 . Cng thc phn t ca hai este l:
A. C2 H 3COOC2 H 5 & C3 H 5COOCH 3
B. C2 H 5COOC2 H 5 & C3 H 7COOCH3
C. C2 H 3COOC3 H 7 & C3 H 5COOC2 H 5
D. C3 H 5COOC3 H 7 & C4 H 6COOC2 H 5
Bi 44. _____________________________________________________________________________
Ly 15,66g amin n chc, mch h X ( X c khng qu 4 lin kt ) trn vi 168 lt khng kh (ktc).
Bt tia la in t chy hon ton X , hn hp sau phn ng c a v 0 C, 1atm ngng t ht
hi nc th c th tch l 156,912 lt. Xc nh s ng phn ca X.
A.2
B.17
C.16
D.8
Bi 45. _____________________________________________________________________________
Oxi ha 38 gam hn hp propanal, ancol A no n chc bc 1 v este B (to bi mt axit ng ng ca axit
acrylic v ancol A) c hn hp X gm axit v este. Mt khc, cho lng X phn ng vi 0,5 lt dung
dch NaOH 1,5M th sau phn ng trung ha ht NaOH d cn 0,15 mol HCl c dung dch D. C cn D
c hi cht hu c E, cn li 62,775 gam hn hp mui. Cho E tch nc 140o C ( H 2 SO4 c xc tc)
c F c t khi vi E l 1,61. A v B ln lt l:
A. C2 H 5OH v C3 H 5COOC2 H 5
C. CH 3OH v C4 H 7COOCH 3
B. CH 3OH v C3 H 5COOCH 3
D. C2 H 5OH v C4 H 7COOC2 H 5
Bi 46. _____________________________________________________________________________
Hn hp X gm mt s hidrocacbon l ng ng k tip c tng khi lng phn t l 204, trong khi
lng phn t ca hidrocacbon nng nht c khi lng phn t nng gp 2,4 ln khi lng ca
hidrocacbon nh nht. Cng thc ca hidrocacbon nh nht l:
A. C2 H 2
B. C3 H 6
C. C2 H 6
D. C4 H 8
Bi 47. _____________________________________________________________________________
Hn hp X gm 2 este n chc l ng ng k tip c t l khi lng tng tng ng l 0,7396 : 1 v
hiu s mol ca chng l cc i. X phng ho hon ton 86,96 gam X bng dung dch KOH d thu c
mt mui duy nht (khng c kh nng tham gia phn ng trng Ag) c khi lng m1 gam v 2 ru n

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chc. Ly ton b ru qua CuO nung nng ri dn sn phm qua dung dch Br2 d th thy c a (mol) Br2
phn ng. Gi tr ca m1 v a l:
A. 76,26g v 1,36 mol
B. 87,42g v 1,36 mol
C. 87,41g v 0,93mol
D. 76,26g v 0,93 mol
Bi 48. _____________________________________________________________________________
Cho 0,1 mol CH 3COOH vo cc cha 30 ml dung dch ROH 20% (d = 1,2 g/ml, R l mt kim loi nhm
IA). C cn dung dch sau phn ng, ri t chy hon ton cht rn khan cn li. Sau khi t chy th cn
li 9,54 gam cht rn v m gam hn hp CO2 , hi nc bay ra. Gi tr ca m l:
A. 7,54
B. 8,26
C. 9,3
D. 10,02
Bi 49. _____________________________________________________________________________
un nng hn hp 1mol HCOOH v 1 mol CH 3COOH v 2 mol C2 H 5OH t oC ( trong bnh kn dung
tch khng i ) n trng thi cn bng th thu 0,6 mol HCOOC2 H 5 v 0,4 mol CH 3COOC2 H 5 . Nu un
nng hn hp gm 1 mol HCOOH , 3 mol CH 3COOH v a mol C2 H 5OH iu kin nh trn n trng
thi cn bng th thu c 0,8 mol HCOOC2 H 5 . Gi tr ca a l:
A.12,88
B.9,97
C.5,6
D.6,64
Bi 50. ____________________________________________________________________________
Phn ng no sau y to ra sn phm sai?
A. Glucozo Cu OH 2 NaOH Axit Gluconic
o

Ni ,t
B. Glucozo H 2
X (X c CTPT l C6 H16O6 )
HCl khan
C. Glucozo CH 3OH
Metyl glucozit

D. C6 H12O6 Cu OH 2 C6 H 11O6 2 Cu
Bi 51. _____________________________________________________________________________
Chn nhn nh ng.
A. Amin bc 1 tc dng vi HNO2 nhit thng lun cho ancol v gii phng N2 .
B. Anilin tc dng vi HNO2 nhit cao cho mui iazoni.
C. Do nguyn t nit cn hai electron c thn c th to lin kt cho nhn vi ion H nn amin th
hin tnh cht baz.
D. ra l ng anilin, ngi ta ch cn dng nc.
Cu 52. ____________________________________________________________________________
Chn pht biu ng.
A. Cht nhit rn khc cht nhit do ch kh nng chy.
B. Hu ht cc polime khng tan trong dung mi thng thng m ch tan trong mt s dung mi thch
hp.
C. PE khng phn ng vi dung dch brom do monome ca n khng c lin kt i.
D. Theo cch tng hp, ngi ta chia polime thnh 3 loi: thin nhin, nhn to v tng hp.
Bi 53. _____________________________________________________________________________
Dy no sau y cha cht khng to lin kt hidro vi nc?
A. Etanol, axeton, axit axetic
B. Etanol, metyl amin, p-xilen
C. Metyl amin, etanol, metanal
D. Etanol, metanol, axit axetic
Bi 54. _____________________________________________________________________________
Hn hp X gm imetyl amin v hai hidrocacbon ng ng lin tip. t chy hon ton 100 ml hn hp
X bng lng oxi va , thu c 550 ml hn hp kh v hi nc. Nu cho Y i qua dung dch axit
sunfuric c, d th cn li 250 ml kh (Cc th tch kh v hi o cng iu kin). Cng thc phn t ca
hai hidrocacbon l?
A. CH 4 v C2 H 6
C. C2 H 6 v C3 H8
B. C2 H 4 v C3 H 6

D. C3 H 6 v C4 H 8
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