Bin son : Nguyn nh Hnh- THCS Chu Vn An, k P, Gia Lai

MT S BI TON NHIT NHM

1) C m(g) hn hp X gm Fe2O3 v Al. Nung X ( khng c kk) n phn ng hon ton thu c rn Y. Chia Y lm 2 phn bng nhau. -Phn 1: Ha tan trong V lt dung dch NaOH 2M va th thy c 3,36 lt kh H2 ( ktc). -Phn 2: Ha tan ht trong dung dch HCl thu c dung dch Z v thot ra 4,48 lt H2 ( ktc). a) Tnh m v V. b) Cho NaOH d vo dung dch Z, sc kh O2 lin tc n khi kt ta khng thay i thu c m gam kt ta. Tnh m. { S: m = 40,1 gam ; V = 0,075 lt} 2) C 40,1 gam hn hp X gm Fe2O3 v Al. Nung X ( khng c kk) n phn ng hon ton thu c rn Y. Chia Y lm 2 phn bng nhau. -Phn 1: Ha tan trong dung dch NaOH d th thy c kh H2 sinh ra. -Phn 2: Ha tan ht trong dung dch HCl thu c dung dch Z v thot ra 4,48 lt H2 ( ktc). Tnh % khi lng mi cht trong X. { S: %mAl (X) = 20,2% ; %mFe2O3 (X) = 79,8% } 3) C mt hn hp B gm nhm v oxit st t. Ly 32,22 g hn hp B em nung nng phn ng nhit nhm xy ra hon ton. Chia hn hp sau phn ng thnh 2 phn. - Phn 1: tc dng ht vi dd NaOH d, thu c 2,016 lt H2 (ktc). - Phn 2: Ha tan ht vo lng d axit HCl to ra 8,064 lt H2 (ktc). a) Vit phng trnh phn ng xy ra. b) Tnh s gam oxit st t c trong 32,22 g hn hp B. { S: 20,88 gam } 4) Hn hp X gm 0,3 mol Al vo 0,2 mol Fe2O3. Nung nng hn hp sau mt thi gan thu c hn hp rn Y ( gi s Al kh Fe2O3 ch to sn phm Fe ). Cho Y vo dung dch HCl d thu c 8,064 lt kh H 2 Tnh hiu sut phn ng nhit nhm. Bit cc th tch kh o ( ktc). {S: H% = 60% } 5) Thc hin phn ng nhit nhm (trong chn khng) hn hp bt A gm nhm v mt oxit st thu c 5,09 gam cht rn B. Ha tan B vo NaOH d un nng thu c 1,008 lt kh (ktc), phn cht rn C cn li cho tan ht vo dung dch HNO3 long gii phng 0,896 lt kh (ktc) khng mu ha nu trong khng kh. a) Vit phng trnh phn ng. Tnh khi lng Al2O3 to thnh sau phn ng nhit nhm. b) Xc nh cng thc ha hc ca oxit st. Bit cc phn ng xy ra hon ton. m { S: Al2O3 =2,04 (g) ; Fe2O3 } 6) Trn 16,2 gam bt Al vi Fe3O4 thu c hn hp X. Thc hin phn ng nhit nhm hn hp X trong chn khng thu c hn hp Y. Cho Y tc dng vi dung dch HCl d thu c 17,64 lt H2 ( ktc). Tnh hiu sut ca phn ng nhit nhm. Bit rng lng Fe3O4 dng > 52,2 gam. { S: H% = 50% } 7) Tin hnh phn ng nhit nhm m gam hn hp X gm bt Al v mt oxit st (khng c khng kh) th thu c hn hp rn Y. Nghin nh hn hp Y v trn u ri chia thnh 2 phn: -Phn 1: c khi lng 14,49g c ho tan ht trong dd HNO3 un nng, thu c dung dch C v 0,165 mol NO(sp kh duy nht). -Phn 2: tc dng vi dung dch NaOH nng, d thy c 0,015mol kh H2 thot ra v cn li 2,52g cht rn. Xc nh m v CTHH ca oxit st. Bit rng cc phn ng xy ra hon ton. { S: m = 19,32 gam ; Fe3O4 } 8) Ly 26,8 g hn hp gm v Fe2O3 thc hin hon ton phn ng nhit nhm, thu c cht rn , cho cht rn ny ha tan hon ton trong dd HCl d thy thot ra 11,2 lt kh H 2(o ktc).Hy xc nh thnh phn % cc cht trong hn hp ban u. { S: 40,3% ; 59,7% } 9) Ly hn hp X gm Fe3O4 v Al nung trong mi trng khng c khng kh. Sau khi phn ng xy ra hon ton thu c 93,9 (g) hn hp Y. Chia Y lm hai phn khng bng nhau: -Phn 1: Cho tc dng vi NaOH d thu c 0,672 lt kh H2(ktc).

Bin son : Nguyn nh Hnh- THCS Chu Vn An, k P, Gia Lai

-Phn 2: Cho tc dng vi dung dch HCl d thu c 18,816 lt kh H2(ktc). Tnh % khi lng cc cht trong hn hp X, bit cc phn ng u c hiu sut100% { S: 74,12% ; 25,88% } 10) Hn hp A gm Al v oxit st t. Nung nng A trong chn khng phn ng xy ra hon ton thu c hn hp rn B. Nghin nh bt B trn u.Chia hn hp lm hai phn: - phn 1(t hn): cho tc dng vi NaOH d thu c 1,176 lt kh (ktc).Tch ring cht khng tan em ho tan trong dung dch HCl d thu c 1,008 lt (ktc). - phn 2(nhiu hn): cho tc dng vi HCl d thu c 6,552 lt kh (ktc) a) Vit phng trnh phn ng ho hc. b) Tnh khi lng hn hp A v thnh phn phn trm ca cc cht c trong hn hp A. { S: % m Al = 36,78% ; % m Fe3O4 = 63,22% } 11) Cho hn hp A khi lng m gam bt Al v FenOm. Tin hnh phn ng nhit nhm hn hp A trong iu kin khng c oxi c hn hp B .Nghin nh v trn u ri chia lm hai phn . - Phn 1: c khi lng 5,67 gam c ho tan ht trong dung dch HNO 3 un nng c dung dch C v 4,704 lt kh NO2 duy nht(ktc) . - Phn 2: cho tc dng vi lng d dung dch NaOH un nng thy thot ra 1,344 lt kh (ktc) v cn li 13,44 gam cht rn khng tan .cc phn ng xy ra hon ton a) Vit phng trnh ho hc ca cc phn ng xy ra. b) Xc nh cng thc ca oxit st . {S: FeO} 12) Sau khi thc hin phn ng nhit nhm hn hp A gm Al v FexOy thu c 92,35 gam cht rn B. Ho tan B bng NaOH d thy c 8,4 lt kh bay ra ktc v cn li phn khng tan C .Nu ho tan ht C cn ng 240 gam dung dch H2SO4 98% phn ng ch to thnh mui Fe(III) v kh SO2 duy nht. Cc phn ng u t hiu sut 100% . Tnh khi lng Al2O3 to thnh v xc nh cng thc ca oxit Fe. m Al O = 40,8 gam ; Fe2O3 } { S: 2 3 13) Hn hp A nng m(g) gm Fe2O3 v Al. Nung A n hon ton thu c rn B, cho B tc dng H 2SO4 long thu c 2240ml kh ( ktc). Mt khc nu cho B tc dng vi dung dch NaOH d th thy cn li 13,6 gam cht rn khng tan. a) Xc nh khi lng cc cht trong A v B. b) Tnh th tch dung dch HCl 0,5M ha tan ht 13,6 gam cht rn trn. { S: B: m Fe2O3 ( d) = 8 gam ; m Al2O 3 = 5,1 gam ; m Fe = 5,6 gam A: m Fe2O 3 = 16 gam ; m Al = 2,7 gam ; V = 1 lt 14) Tin hnh phn ng nhit nhm hn hp gm Al v Fe2O3 trong iu kin khng c khng kh. Hn hp thu c em trn u v chia 2 phn. Phn 2 c khi lng nhiu hn phn 1 l 134 gam. - Phn 1: Tc dng vi dung dch NaOH d thy c 16,8 lt H2 bay ra. - Phn 2: Tc dng vi dung dch HCl d thy c 84 lt H2 bay ra . ( Cc phn ng u xy ra hon ton, cc th tch kh o iu kin tiu chun) a) Vit cc phng trnh phn ng. b) Tnh khi lng Fe to thnh trong phn ng nhit nhm. { S: 112 gam } 15) C 11,98 gam hn hp X gm Al v Fe3O4. Thc hin phn ng nhit nhm sau mt thi gian thu c rn Y. Ha tan Y vo dung dch NaOH d thu c dung dch Z v nay ra 2,016 lt kh ( ktc). Sc kh CO2 n d vo dung dch Z thu c 7,8 gam kt ta. a) Tnh khi lng mi cht trong X v Y. b) Tnh hiu sut phn ng nhit nhm. { S: X : m Al = 2,7 gam ; m Fe3O 4 = 9,28 gam Y: m Al = 1,62 gam ; m Al2O3 = 2,04 gam ; m Fe = 2,52 gam ; m Fe2O3 = 5,8 gam } 16) Hn hp X gm a mol Al v b mol Fe2O3; hn hp Y gm b mol Al v a mol Fe2O3. Tin hnh phn ng nhit nhm tng hn hp n khi kt thc thu c 16,86 gam hn hp X v hn hp Y tng ng. Nu x l X bng dung dch NaOH d thu c 1,008 lt H2, khi x l Y bng dung dch HCl 2,31M th cn th tch ti thiu l V lt. Tnh V. Th tch kh o iu kin tiu chun. { S: V = 0,5 lt }

Bin son : Nguyn nh Hnh- THCS Chu Vn An, k P, Gia Lai

19) Tin hnh phn ng nhit nhm hn hp gm Al v mt oxit st thu c rn X. Cho X tc dng vi dung dch NaOH d thu c dd Y, phn khng tan Z v 0,672 lt kh (ktc). Cho dung dch HCl vo dung dch Y n khi thu c lng kt ta ln nht, lc ly kt ta, nung n khi lng khng i thu c 5,1 gam cht rn. Cho Z tc dng vi dd H2SO4 c nng, sau p thu c dung dch E ch cha mt loi mui st sunfat v thot ra 2,688 lt kh SO2(ktc). Cc phn ng u xy ra hon ton. Tm cng thc phn t ca oxit st. { S: Fe2O3 hoc FeO } 20) Tin hnh nung nng hn hp A gm Al v FeO n khi phn ng hon ton thu c 34,2 gam rn B. Nghin nh v trn u rn B ri em chia 2 phn. -Phn 1: Cho vo dung dch NaOH d th khi lng cht rn gim 2,55 gam, khng c kh sinh ra. -Phn 2: Ngm vo V lt dung dch HCl 2M ( d 25% ) thy c 5,04 lt H2. ( cc phn ng u xy ra hon ton, cc th tch kh o ktc). Xc nh khi lng mi cht trong A v tnh V. { S: m Al (A) = 5,4 gam ; m FeO = 28,8 gam ; V = 0,7 lt } 21) Cho 22,3 gam hn hp Al v Fe2O3 vo trong bnh kn ( khng c khng kh ). Nung nng bnh n khi phn ng hon ton th thu c hn hp rn X. Ho tan rn X trong HCl d th thu c 5,6 lt kh ( ktc). a) Xc nh khi lng mi cht trong hn hp u. 1 b) Cho X + V lt dd NaOH M va . Tnh V. 6 m Fe O = 16 gam ; m = 6,3 gam ; V = 1,4 lt } { S: Al 2 3 22) Hn hp A gm Fe3O4 v Al. Nung hn hp A n nhit thch hp ri ngui thu c hn hp B. Chia B lm 2 phn bng nhau. - Phn 1: Ha tan trong dung dch H2SO4 long d c kh C v dung dch D. Cho D tc dng vi NaOH d thu kt ta E em phi ngoi khng kh chuyn ht thnh rn F. Bit E khc F l 8,5 gam. - Phn 2: Tc dng vi potat (KOH) d c mt dung dch, rn G v kh 1,68 lt kh C ( ktc). Bit lng G t hn lng B dng trong phn ng ny l 11,55 gam. a) Vit cc phng trnh phn ng xy ra. b) Tnh th tch kh C sinh ra th nghim phn 1 (ktc). c) Cho 35,18 gam hn hp A tc dng va vi dung dch HCl 3,65% ( D=1,02 g/ml) thu c dung dch Z. Tnh nng mol ca cc cht trong dung dch Z. { S: VH2 ( phn 1) = 6,72 lt } 23) Tin hnh phn ng nhit nhm hn hp Al v Fe2O3 khng c khng kh .Chia hn hp sau phn ng trn u thnh hai phn khng bng nhau. - Phn I: tc dng vi NaOH d thu c 1,68 lt kh ktc . - Phn II: tc dng va vi 1,95 lt dung dch HCl 1M thot ra 11,76 lt kh ktc. Hiu sut cc phn ng 100% .Tnh khi lng Fe to thnh trong phn ng nhit nhm. { S: 22,4 gam } 24) Trn 5,4 gam bt Al vi 17,4 gam bt Fe3O4 ri tin hnh phn ng nhit nhm (trong iu kin khng c khng kh). Gi s ch xy ra phn ng kh Fe3O4 thnh Fe. Ha tan hon ton cht rn sau phn ng bng dung dch H2SO4 long (d) thu c 5,376 lt kh H2 ( ktc). Tnh hiu sut phn ng nhit nhm v s mol H2SO4 phn ng. { S: H% = 80% ; 0,54 mol } 25) Hn hp A gm Al v FexOy .Thc hin phn ng nhit nhm hon ton thu c 92,35 g cht rn B. Ha tan B trong dung dch NaOH ly d thy thot ra 8,4 lit kh (ktc) v cht D khng tan .Cho D tan ht trong dung dch HCl ly d thu c 17,92 lt H2 (KC) .Tm CTHH ca FexOy ; tnh khi lng mi cht trong A. { S: Fe2O3 ; mFe2O3 = 64 gam ; mAl = 28,35 gam 26) Thc hin phn ng nhit nhm hn hp m (gam) kim loi Al v 4,56 gam Cr2O3 trong iu kin khng c khng kh sau khi phn ng kt thc thu c hn hp X. Cho ton b X vo mt lng d dung dch HCl long nng, sau khi phn ng xy ra hon ton thu c 2,016 lt kh H2 ( ktc). Cho ton b X vo V( lt) dung dch NaOH 4M ( d 20% ) un nng sau khi cc p kt thc. Tnh V. { S: V = 0,025 lt } 27) Hn hp A gm 0,56gam Fe v 16gam Fe2O3 v x mol Al. Nung nng A trong iu kin khng c khng kh (Fe2O3 ch b kh thnh Fe) th thu c hn hp rn B. Xc nh gi tr ca x, bit:

Bin son : Nguyn nh Hnh- THCS Chu Vn An, k P, Gia Lai

- Nu cho B tan trong H2SO4 long d c V (lt) kh.

- Nu cho B tc dng vi NaOH d th thu c 0,25V lt kh. { S: 0,0022 mol < x 0,2467 mol } 28) Trn 10,8g Al vi 34,8g Fe3O4 ri thc hin phn ng nhit nhm c hn hp A (chi xay ra kh Fe3O4 thanh Fe). Ha tan ht A bng HCl c 10,752 lt H2 (ktc). Tnh hiu sut phn ng nhit nhm v th tch dung dch HCl 2M ti thiu cn dng. ( p s: 80% v 1,08 lt) 29) Khi cho 41,4 gam X gm Fe2O3, Cr2O3 v Al2O3 tc dng vi dung dch NaOH c (d), sau phn ng c 16 gam cht rn. kh hon ton 41,4 gam X bng phn ng nhit nhm, phi dng 10,8 gam Al. Tnh % theo khi lng ca Cr2O3 trong X l (Bit H= 100% ) ( S: 36,71%) 30) Cho hn hp X khi lng m1 gam gm bt Al v mt oxit ca st FexOy. Tin hnh phn ng nhit nhm vi X trong iu kin khng c khng kh. Sau khi kt thc phn ng em nghin nh v trn u hn hp thu c ri chia thnh hai phn. - Phn 1 (c khi lng 7,245 g): tc dng vi dung dch NaOH d, nng thy c 0,504 lt kh ( kc) thot ra v cn li 3,78g cht rn khng tan. - Phn 2: Cho tc dng vi mt dung dch HNO3 nng, thy bay ra 5,544 lt kh duy nht NO ( ktc). Cc phn ng u xy ra hon ton. a) Vit cc phng trnh phn ng xy ra. c) Tnh m1 v xc nh cng thc ca oxit st. ( S: Fe3O4 ; m1= 28,98 gam ) ------------Ht------------Email: n.dhanhcs@gmail.com hoc n.dhanh@yahoo.com.vn