THI CHN HC SINH GII MN: HA HC - KHI: 11 NM HC: 2011 - 2012 Thi gian lm bi 150 pht Cho: H = 1; Be = 9; C = 12;

N = 14; O = 16; Na = 23; Mg = 24; Al = 27; P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64; Zn = 65; Br = 80; Ag = 108; Ba = 137. Cu I (5 im): 1. Dung dch X gm HF 0,1M v NaF 0,1M. -4 a. Tnh pH ca dung dch X, bit hng s axit ca HF l Ka = 6,8.10 . b. Tnh pH ca dung dch thu c khi thm 0,01 mol HCl vo dung dch X, coi th tch dung dch thay i khng ng k. 2. t chy hon ton a g hirocacbon X cn b lt khng kh (ktc), dn ton b sn phm chy qua bnh (1) cha H2SO4 c ri bnh (2) cha KOH c d, thy bnh (1) tng c gam v bnh (2) tng d gam. Bit rng cc phn ng xy ra hon ton, oxi chim 20% th tch khng kh. Tnh a, b theo c, d. Cu II (5 im): 1. Hon thnh s chuyn ho sau: ddNaOH NaN ddHCl NH4HCO3 CuO (C) O (B)
2

S GD T BNH NH TRNG THPT V GI

(A)

(1 : 1

(B)

2. Ha tan hon ton 1,62 gam nhm trong 280 ml dung dch HNO3 1M c dung dch A v kh NO (sn phm kh duy nht). Mt khc, cho 7,35 gam hai kim loi kim thuc hai chu k lin tip vo 500ml dung dch HCl, c dung dch B v 2,8 lt kh H2 (ktc). Khi trn dung dch A vo dung dch B thy to thnh 1,56 gam kt ta. a. Xc nh tn 2 kim loi kim. b. Tnh nng mol/lt ca dung dch HCl dng. Cu III (5 im): 1. Vit cc phng trnh phn ng xy ra khi: a. Cho dung dch FeCl3 vo dung dch Na2CO3. b. Trn dung dch NaOH vi dung dch Ba(HCO3)2. c. Trn dung dch Ba(HCO3)2 vi dung dch NaHSO4 d. Cho FeS2 vo axit H2SO4 c nng, d. 2. Ho tan hon ton u mol ZnSO4 vo nc c dung dch X. Nu cho 15,6 gam K vo dung dch X th thu c 2a mol kt ta. Mt khc, nu cho 39 gam K vo X th thu c a mol kt ta. Tm u, a. Cu IV (5 im): 1. Cho 3 nguyn t A, B, C: Nguyn t A c electron cui cng ng vi 4 s lng t: n = 3, l = 1, m = 0 ms = + -1/2. Hai nguyn t B, C to thnh cation X c 5 nguyn t. Tng s ht mang in l 21. Vit cu hnh electron v xc nh tn, v tr ca A, B, C trong bng tun hon. 2. Dung dch X cha hn hp gm Na2CO3 1,5 M v KHCO3 1M; dung dch Y cha hn hp NaOH 0,6M v Ba(OH)2 1,2M. Nh t t tng git n ht 400 mL dung dch HCl 1M vo 200

mL dung dch X, ton b kh thot ra c hp th vo 50 mL dung dch Y thu c m gam kt ta. Tnh m. ---------- Ht ----------