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Trng THPT Dn tc ni tr tnh

THI TH I HC NM HC 2009 - 2010

MN HO HC - ln 1
Thi gian lm bi: 90 ph(khng k thi gian giao )
M thi 165

H, tn th sinh:..........................................................................
S bo danh:...............................................................................
Cu 1: Hy sp xp cc cp oxi ha kh sau y theo th t tng dn tnh oxi ha
ca cc ion kim loi: (1): Fe2+/Fe; (2): Pb2+/Pb; (3): 2H+/H2; (4): Ag+/Ag;
(5): Na+/Na; (6): Fe3+/Fe2+; (7): Cu2+/Cu.
A. (5) < (1) < (6) < (2) < (3) < (4) < (7). B. (4) < (6) < (7) < (3) < (2) < (1) < (5).
C. (5) < (1) < (2) < (3) < (7) < (6) < (4). D. (5) < (1) < (2) < (6) < (3) < (7) < (4).
Cu 2: Hn hp X gm 0,02 mol HCOONa v a mol mui natri ca hai axit no n
chc l ng ng lin tip. t chy hn hp X v cho sn phm chy (CO2, hi
nc) ln lt qua bnh 1 ng H2SO4 c bnh 2 ng KOH thy khi lng bnh 2
tng nhiu hn bnh mt l 7,02 gam. Phn cht rn Y cn li sau khi t l Na2CO3
cn nng 5,30 gam. Xc nh cng thc phn t ca hai mui natri.
A. CH3COONa v C2H5COONa.
B. C3H7COONa v C4H9COONa.
C. C2H5COONa v C3H7COONa.
D. Kt qu khc.
Cu 3: C 5,668 gam cao su buna-s phn ng va ht vi 3,462 gam Br2 trong CCl4.
T l mt xch butadien v stiren trong cao su buna-s l:
A. 2/3.
B. 3/5.
C. 1/3.
D. 1/2.
Cu 4: Trong cc dung dch sau : Ca(OH)2, BaCl2, Br2, H2S. S dung dch dng
phn bit c 2 kh CO2 v SO2 l
A. 4
B. 2
C. 1
D. 3
Cu 5: Trong dy ng ng ru n chc no, khi mch cacbon tng, ni chung
A. si tng, kh nng tan trong nc tng.
B. si tng, kh nng tan trong nc gim
C. si gim, kh nng tan trong nc tng.
D. si gim, kh nng tan trong nc gim.
Cu 6: Cho s chuyn ha sau:
A + HCl B + D
B + Cl2 F
E + NaOH H + NaNO3 A + HNO3 E + NO + D
B + NaOH G + NaCl
G + I + D H
Cc cht A, G v H l
A. PbO, PbCl2 v Pb(OH)4.
B. Cu, Cu(OH)2 v CuOH.
C. CuO, CuOH v Cu(OH)2.
D. FeO, Fe(OH)2 v Fe(OH)3.
Cu 7: So snh tnh axit ca cc cht sau y : CH2ClCH2COOH (1), CH3COOH
(2), CH3CH2COOH (3), CH3CHClCOOH (4)
A. (3) > (2) > (1 ) > (4).
B. (4) > (1) > (3) > (2).
C. (1 ) > (4) > (3) > (2).
D. (4) > (1 ) > (2) > (3).
Cu 8: Khi lng K2Cr2O7 cn dng oxi ha ht 0,06 mol FeSO4 trong mi
trng H2SO4 long d l
A. 2,94g
B. 5,92g
C. 2,49g
D. 2,96g
Cu 9: Cht no khng phn ng c vi Cu(OH)2?
A. HOCH2CH2OH.
B. CH3CH=O.
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C. CH3COOH.
D. HOCH2CH2CH2OH.
Cu 10: Trong s cc loi polime sau:
(1) [-NH-(CH2)6-NH-CO-(CH2)4-CO-]n
(2) [-NH-(CH2)5-CO-]n
(3) [-NH-CH2 -CO-]n
(4) [C6H7O2(O-CO-CH3)3]n .
polime no cha lin kt peptit ?
A. (1) v (3)
B. (1) ; (2) v (3) C. (1) ; (2) v (4) D. (3) v (4)
Cu 11: C 2 hp cht hu c (X), (Y) cha cc nguyn t C, H, O, khi lng phn
t u bng 74. Bit (X) tc dng c vi Na, c (X), (Y) u tc dng c vi
dung dch NaOH v dung dch AgNO3 trong NH3. Vy X, Y c th l
A. CH3COOCH3 v HOC2H4CHO.
B. C4H9OH v HCOOC2H5.
C. OHCCOOH v C2H5COOH.
D. OHCCOOH v HCOOC2H5.
Cu 12: A, B l cc kim loi hot ng ha tr II, thuc 2 chu k lin tip trong bng
tun hon. Ha tan hn hp gm 23,5 gam cacbonat ca A v 8,4 gam mui cacbonat
ca B bng dung dch HCl d c cn v in phn nng chy hon ton cc mui
th thu c 11,8 gam hn hp kim loi catot v V lt khi anot. Hai kim loi A v
B l
A. Sr v Ba.
B. Mg v Ca.
C. Ba v Ra.
D. Be v Mg.
Cu 13: Gi s c cc hn hp bt kim loi ring bit gm: Al v Ag (1) ; Zn v Ag
(2); Mg v Fe (3); Al v Zn (4). Ch dng cp dung dch no sau y c th nhn ra
c tt c cc hn hp trn ?
A. HNO3 long v NaCl
B. HCl v NH3
C. HCl v HNO3 long
D. HCl v NaOH
Cu 14: Cho 250 ml hn hp A gm cc kh Cl2, HCl v H2 (ktc) vo lng d
dung dch KI (trong bng ti), c 1,27 gam I2 to ra. Phn kh thot ra khi dung dch
KI c th tch 80 ml (ktc). Phn trm th tch HCl trong hn hp A l:
A. 44,8%
B. 32%
C. 25%
D. 23,2%
Cu 15: Cho 2,24 lt CO2 ktc vo 20 lt dung dch Ca(OH)2, thu c 6 gam kt ta.
Nng ca dung dch Ca(OH)2 dng l
A. 0,0035M.
B. 0,004M.
C. 0,003M.
D. 0,003M hoc 0,004M.
Cu 16: Cho 11,6 gam mui FeCO3 tc dng vi dung dch HNO3, thu c hn hp
kh CO2, NO v dung dch X. Thm vo dung dch X mt lng HCl (d) th thu
c dung dch ho tan ti a bao nhiu gam bt ng, bit rng kh bay ra la NO.
A. 3,2 gam
B. 32 gam
C. 28,8 gam
D. 14,4 gam
Cu 17: Sp xp cc hiroxit theo chiu tng dn tnh baz:
A. Be(OH)2, Mg(OH)2, NaOH, KOH.
B. Mg(OH)2, NaOH, KOH, Be(OH)2.
C. Mg(OH)2, Be(OH)2, KOH, NaOH.
D. NaOH, KOH, Mg(OH)2, Be(OH)2.
Cu 18: Tng s ht ca phn t XY l 45; Tng s ht ca phn t XY2 l 69.
Trong cc nguyn t X, Y u c s ht proton bng s ht ntron. Hy chn gi tr
ng nht vi s khi ca X, Y.
A. AX = 14; AY = 16
B. AX = 21; AY = 24
C. AX = 22; AY = 23
D. AX = 12; AY = 16
Cu 19: Trn 3 dung dch H2SO4 0.1M; HCl 0,2M; HNO3 0,3M vi th tch bng
nhau c dung dch A. Cho 300 ml dung dch A tc dng vi V ml dung dch B
cha NaOH 0,2M v Ba(OH)20,1M c dung dch C c pH = 1. Gi tr ca V l
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A. 0,24 lt. B. 0,32 lt.

C. 0,08 lt.
D. 0,16 lt.
Cu 20: Hy sp xp cc cht sau y theo trt t tng dn tnh baz: NH3, CH3NH2,
C6H5NH2; (CH3)2NH v (C6H5)2NH
A. (C6H5)2NH < C6H5NH2 < NH3 < CH3NH2 < (CH3)2NH.
B. (CH3)2NH < CH3NH2 < NH3 < C6H5NH2 < (C6H5)2NH.
C. (C6H5)2NH < NH3 < C6H5NH2 < (CH3)2NH < CH3NH.
D. (CH3)2NH > CH3NH2 > NH3 < C6H5NH2 > (C6H5)2NH.
Cu 21: Xt cc loi hp cht hu c mch h sau: Ru n chc, no (A); anehit
n chc, no (B); ru n chc, khng no 1 ni i (C); anehit n chc, khng
no 1 ni i (D). ng vi cng thc tng qut CnH2nO ch c 2 cht sau:
A. A, D.
B. B, C
C. C, D
D. A, B
Cu 22: Cho cc bt trng K2O, MgO, Al2O3, Al4C3. phn bit cc cht trn ch
cn dng thm
A. dung dch NaOH.
B. dung dch H2SO4.
C. H2O.
D. dung dch HCl.
Cu 23: Cho dung dch cha cc ion sau (Na+, Ca2+, Mg2+, Ba2+, H+, Cl). Mun tch
c nhiu cation ra khi dung dch m khng a ion l vo dung dch, ta c th cho
dung dch tc dng vi cht no trong cc cht sau?
A. Dung dch KHCO3 va .
B. Dung ch NaOH va .
C. Dung dch Na2CO3 va .
D. Dung dch Na2SO4 va .
Cu 24: Theo nh ngha mi v axit-baz, nhm phn t no sau y c xc nh
ng?
A. Nhm phn t HCO3, Cl, K+ c tnh trung tnh.
B. Nhm phn t HCO3, S2, Al3+ c tnh baz.
C. Nhm phn t HCO3, H2O, HS, Al(OH)3 c tnh lng tnh.
D. Nhm phn t NH4+, SO42, NO3 c tnh axit.
Cu 25: Nguyn t ca nguyn t X c cu hnh eletron ho tr: (n-1)d5 ns1 (n 4).
V tr ca nguyn t X trong bng tun hon l:
A. Chu k n, nhm IA
B. Chu k n, nhmVI B
C. Chu k n, nhm VI A
D. Chu k n, nhm IB
Cu 26: Sp xp cc cht sau y theo trnh t gim dn nhit si: CH3COOH (1),
HCOOCH3 (2), CH3CH2COOH (3), CH3COOCH3 (4), CH3CH2CH2OH (5)
A. (3) > (1) > (4) > (5) > (2).
B. (3) > (5) > (1 ) > (2) > (4).
C. (1 ) > (3) > (4) > (5) > (2).
D. (3) > (1) > (5) > (4) > (2).
Cu 27: Ho tan hon ton 2,175 gam hn hp 3 kim loi Zn, Mg, Fe vo dung dch
HCl d thy thot ra 1,344 lt H2 (ktc). Khi c cn dung dch ta thu c bao nhiu
gam mui khan? Chn p s ng.
A. 4,365.
B. 6,555.
C. 6,435.
D. 4,305.
Cu 28: Cho s chuyn ho sau:
1). C3H4O2 + NaOH (A) + (B)
2). (A) + H2SO4 long (C) + (D)
3). (C) + AgNO3 + NH3 + H2O (E) + Ag + NH4NO3
4). (B) + AgNO3 + NH3 + H2O (F) + Ag + NH4NO3
Cc cht B v C (theo th t) c th l
A. CH3CHO v HCOOH.
B. HCHO v CH3CHO.
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C. CH3CHO v HCOONa.
D. HCHO v HCOOH.
Cu 29: Thy phn este X trong mi trng axit thu c hai cht hu c Y v Z.
Oxi ha Y to sn phm l cht Z. Cht X khng th l :
A. isopropyl propionat
B. etilenglicol oxalat
C. etyl axetat
D. vinyl axetat
Cu 30: Trong mt cc nc cha a mol Ca2+, b mol Mg2+, c mol Cl v d mol
HCO3. Nu ch dng nc vi trong nng p mol/l lm gim cng trong
cc, th ngi ta thy khi cho V lt nc vi trong vo, cng ca nc trong bnh
l b nht, bit c = d. Biu thc lin h gia a, b v p l
A. V = (2a + b)/p.
B. V = (2b + a)/p.
C. V = (3a + 2b)/2p.
D. V = (b + a)/2p.
Cu 31: Cho 13,6 gam mt cht hu c X (C, H, O) tc dng va vi 300 ml
dung dch AgNO3 2M trong NH4OH thu c 43,2 gam bc. Bit t khi hi ca X
i vi oxi bng 2,125. Xc nh cng thc cu to ca X.
A. HCCCH2CHO.
B. HCCCHO.
C. CH2=CHCH2CHO.
D. CH3CH2CHO.
Cu 32: Trong qu trnh in phn, cc ion m di chuyn v
A. cc dng v b in cc kh.
B. Cc m v b in cc oxi ho.
C. cc m v b in cc kh.
D. cc dng v b in cc oxi ho.
Cu 33: Mt loi mn ca cha 60% xenluloz c dng lm nguyn liu iu
ch ancol etylic. Bit hiu sut ca qu trnh l 70%. Khi lng ring ca ancol
etylic nguyn cht l 0,8 g/ml. T 1 tn mn ca trn iu ch c th tch cn 70o
l:
A. 306,5 lt
B. 305,7 lt
C. 425,9 lt
D. 310,6 lt
Cu 34: Thy phn este E c cng thc phn t C4H8O2 vi xc tc axit v c long,
thu c hai sn phm hu c X, Y (ch cha cc nguyn t C, H, O). T X c th
iu ch trc tip ra Y bng mt phn ng duy nht. Cht X l
A. ru etylic.
B. axit axetic.
C. axit fomic.
D. etyl axetat.
Cu 35: Khi cho 17,4 gam hp kim Y gm st, ng, nhm phn ng ht vi H2SO4
long d ta c dung dch A; 6,4 gam cht rn; 9,856 lt kh B 27,3oC v 1atm.
Phn trm khi lng mi kim loi trong hp kim Y l
A. Al: 30%; Fe: 50% v Cu: 20%.
B. Al: 31,03%; Fe: 32,18% v Cu: 36,78%.
C. Al: 30%; Fe: 32% v Cu: 38%
D. Al: 25%; Fe: 50% v Cu: 25%.
Cu 36: Cho mt phn ng n gin xy ra trong bnh kn:
2NO(k) + O2(k) 2NO2 (k).
Khi th tch bnh phn ng gim i 3 ln th tc ca phn ng tng ln
A. 16 ln
B. 81 ln
C. 27 ln
D. 64 ln
Cu 37: Nhit phn 1,88 gam Cu(NO3)2 ri hp th ton b lng kh sinh ra bng
H2O c 2 lt dung dch A. pH ca dung dch A l
A. 7.
B. 2
C. 3.
D. 2,2.
Cu 38: t chy mt hn hp cc cht thuc dy ng ng anehit ta thu c s
mol CO2 = s mol H2O th l dy ng ng
A. Anehit khng no n chc cha 1 lin kt i.
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B. anehit non chc mch h.

C. anehit vng no.
D. anehit hai chc no.
Cu 39: Cho cc cht: etyl axetat, anilin, ancol etylic, axit acrylic, phenol,
phenylamoni clorua, ancol benzylic, p-crezol. Trong cc cht ny, s cht tc dng
c vi dung dch NaOH l:
A. 4
B. 5
C. 6
D. 3
Cu 40: A l este to bi mt ankanol v mt axit khng no mch h, n chc, ch
cha mt lin kt i. Cng thc phn t tng qut ca A phi l
A. CxH2x4O2 (x4).
B. CxH2x2O2 (x4).
C. CxH2xO2 (x4).
D. CxH2x4O2 (x3).
Cu 41: trung ho 200 ml dung dch aminoaxit X nng 0,5M cn 100 gam
dung dch NaOH 8%, c cn dung dch sau phn ng c 16,3 gam mui khan. X
c cng thc cu to:
A. H2NCH(COOH)2.
B. H2NCH2CH(COOH)2.
C. (H2N)2CHCOOH.
D. H2NCH2COOH.
Cu 42: Ho hi 2,28 gam hn hp 2 andehit c th tch ng bng th tch ca 1,6
gam oxi cng iu kin, mt khc cho 2,28 gam hn hp 2 andehit trn tc dng
vi AgNO3 trong NH3 d thu c 15,12 gam Ag. Cng thc phn t 2 andehit l
A. C2H4O v C2H2O2
B. CH2O v C3H4O
C. CH2O v C2H2O2
D. CH2O v C2H4O
Cu 43: Crckinh 5,8 gam C4H10 thu c hn hp sn phm X gm H2 v 6
hirocacbon. t chy 1/2 hn hp X th lng H2O thu c l
A. 4,5 gam.
B. 13,5 gam.
C. 9 gam.
D. 6,3 gam.
Cu 44: C7H6O2 cha nhn thm v tham gia phn ng trng gng. S cng thc
cu to ph hp ca C7H6O2 l
A. 1
B. 4
C. 3
D. 5
Cu 45: Trn 18 gam axit axetic vi 23 gam ancol etylic ri un nng mt thi gian.
Sau khi ngui hn hp v tch ring ht este th c hn hp lng X. Cho ton
b X tc dng ht vi Na thu c 6,72 lit H2 (ktc). Vy s gam este to ra l
A. 8,8 gam.
B. 17,6 gam.
C. 26,4 gam.
D. 44
Cu 46: Cho 1,365 gam mt kim loi kim X tan hon ton vo nc thu c mt
dung dch ln hn khi lng nc ban u l 1,33 gam. Kim loi M dng l
A. Na.
B. Rb.
C. Cs.
D. K.
Cu 47: ha tan hon ton 10 gam bt hn hp Fe, Mg, Zn cn 100 ml dung dch
hn hp 2 axit H2SO4 v HCl c nng tng ng l 0,8M v 1,2M. Sau khi phn
ng xong, ly 1/2 lng kh sinh ra cho i qua ng s ng a gam CuO nung nng.
Sau khi phn ng kt thc trong ng cn li 14,08 gam cht rn. Khi lng a l
A. 25,20 gam.
B. 15,20 gam.
C. 14,20 gam.
D. 15,36 gam.
Cu 48: Xenluloz trinitrat c iu ch t xenluloz v axit nitric c c xc tc
axit sunfuric c, nng. c 118,8 kg xenluloz trinitrat, cn dng dung dch cha
m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l :
A. 60
B. 84
C. 42
D. 30
Cu 49: Hp cht hu c C4H7O2Cl khi thy phn trong mi trng kim c cc
sn phm trong c hai cht c kh nng trng gng. Cng thc cu to ng l
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A. C2H5COOCHClCH3.
B. HCOOCH2CHClCH3.
C. CH3COOCH2Cl.
D. HCOOCHClCH2CH3.
Cu 50: Cho hn hp Y gm 2,8 gam Fe v 0,81 gam Al vo 200ml dung dch C
cha AgNO3 v Cu(NO3)2. Khi phn ng kt thc, thu c dung dch D v 8,12 gam
cht rn E gm 3 kim loi. Cho cht rn E tc dng vi dung dch HCl d th thu
c 0,672 lt kh H2 (ktc). Nng mol ca AgNO3 v Cu(NO3)2 trong dung dch
C l
A. 0,2M v 0,6M.
B. 0,075M v 0,0125M.
C. 0,3M v 0,5M.
D. 0,15M v 0,25M.
(Bit : H = 1; Li = 7; C = 12; N = 14; O = 16; Na = 23; Mg = 24; Al = 27;
P = 31; S = 32; Cl = 35,5; K = 39; Ca = 40; Fe = 56; Cu = 64;
Zn = 65; Cr = 52 ; Br = 80; Rb = 85,5; Ag = 108; Ba = 137)------------------------- HT ----------

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