S GD&T THANH HA

Trng THPT Hu lc I

KIM TRA CHT LNG DY HC BI DNG LN I NM HC 2009-2010

Mn: Ha hc 12 (Thi gian lm bi 90 pht)

H tn hc sinh: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . S bo danh. . . . . . . . .Phng thi . . . . . . .. . ____________________________________________________________________________ ( Cho C=12, H=1, O=16, N=14, Na=23, Cu=64, S=32, Ba=137, Be=9, Mg=24, Ca=40, Sr=87 Al=27, Fe=56, Br=80, Cl=35,5, P=31, Ag=108 , K=39 ). M : 147 I- PHN CHUNG CHO TT C THI SINH: (40 cu, t cu 1 n cu 40) Fe + H2SO4 long (1) Fe +HNO3 1. Cho cc phn ng: Fe + Cl2 (3) Fe + S Fe3O4 + HCl (5) dd Fe2+ + MnO4- + H+ 2+ Fe + dd Cu (7) dd Fe2+ + dd Ag+ 3+ Nhng phn ng to ra mui Fe l: A. 2, 3, 5, 6, 8. B. 2, 3, 5, 6, 7. C. 1, 3, 5, 6, 8. D. 2, 3, 4, 6, 8 0 (2) H2NCH2COOH + HNO2 2. Cho cc phn ng sau (1) Cu(NO3)2 t (3) NH3 + CuO
t0
0

(2) (4) (6) (8)

(4) NH4NO2

t0
0

(5) C6H5NH2 + HNO2 HCl(0 5 ) (6) (NH4)2CO3 t Cc phn ng thu c N2 l: A. 1, 2, 3. B. 3, 4, 5. C. 2, 3, 4. D. 4, 5, 6. 3. Chia hn hp gm Mg v MgO thnh 2 phn bng nhau: - Phn 1: Cho tc dng ht vi dung dch HCl thu c 3,136 lt H2(ktc), dung dch sau phn ng cha 14,25gam mui - Phn 2: Cho tc dng ht vi dung dch HNO3 thu dc 0,448 lt kh X nguyn cht (ktc). C cn cn thn v lm kh dung dch sau phn ng thu c 23,40 gam mui. Cng thc phn t ca kh X l: A. N2O B. NO2 C. N2 D. NO 4. Khi cho Cu vo dung dch ca cht X hoc dung dch ca cht Y u khng c phn ng xy ra. Nhng khi cho Cu vo dung dch hn hp ca X v Y th Cu li tan. X v Y l: A. KNO3 v NaHSO4 B. KNO3 v NaHCO3 C. NaCl v NaHSO4 D. NaCl v H2SO4 long 5. Tch nc mt ancol n chc X trong iu kin thch hp thu c hp cht hu c Y. Bit t khi hi ca Y so vi X bng 1,4375. Cng thc cu to ca X l: A. C3H5OH B. C2H5OH C. C3H7OH D. CH3OH 6. Ha tan cc cht sau vo nc: y no sau y cc cht c sp xp theo chiu tng dn tnh baz ?
A. B. C. D. 7. Trong cc phn ng di y phn ng no gi nguyn mch polime ? 300 0 C t0 A. Polistiren B. Cao su Buna + HCl C. Nilon-6,6 + dd NaOH
t0

D. Rezol

150 0 C

8. Cho 7,2 gam hn hp hai mui CO32- ca hai kim loi k tip nhau trong nhm IIA. Ho tan ht hn hp

hai mui trong dung dch HCl thu c kh B. B c hp th hon ton bi 450ml dung dch Ba(OH)2 0,2M thy xut hin 15,76 gam kt ta. hai kim loi l: hoc A. B. hoc C. D. 9. Cho 1 lt cc dung dch c cng nng mol/lt sau: Ba(OH)2; HNO3; H2O; NaOH v H2SO4. Dy no trong cc dy sau c sp xp theo th t gim dn pH ? A. NaOH; Ba(OH)2; H2O; HNO3; H2SO4 B. NaOH; Ba(OH)2; H2O; H2SO4; HNO3 C. Ba(OH)2; NaOH; H2O; HNO3; H2SO4 D. Ba(OH)2; NaOH; H2O; H2SO4; HNO3 (1) CH3COOCH=CH-CH3 + NaOH (2) 10. Cho cc phn ng sau: 2,2-iclo propan + NaOH Cumen + O2 ( H2SO4 20%) (3) Propin + H2O (4) + 2,3-imetyl but-2-en + KMnO4 (H ) (5) Etin + H2O (6)

1,1-iclo propan + NaOH (7) CH3-CH=CHBr + NaOH (8) Bit rng c cc iu kin, xc tc cn thit cc phn ng u xy ra. Nhng phn ng no sau y u khng thu c axeton (CH3-CO-CH3 ) ? A. 3, 5, 6, 7 B. 2, 6, 7, 8 C. 1, 2, 4, 6 D. 1, 2, 5, 8 t0 NaHSO4 + HX ( X l anion gc axit). Phn ng trn 11. Cho s phn ng: KXrn + H2SO4 c dng iu ch: A. HF, HCl, HBr B. HNO3, HCl, HBr C. HCl, HBr, HI D. HNO3, HF, HCl 12. C hai bnh in phn mc ni tip: Bnh (1) cha 100ml dung dch CuSO4 0,1M; Bnh (2) cha 100ml dung dch NaCl 0,1M tin hnh in phn c mng ngn cho ti khi bnh hai to ra dung dch c pH=13 th ngng in phn. Gi s th tch dung dch hai bnh khng i. Nng mol ca Cu2+ trong dung dch bnh (1) sau in phn l: A. 0,04M B. 0,10M C. 0,05M D. 0,08M 13. Trn 300 ml HCl 0,05M vi 200 ml dung dch Ba(OH)2 c nng a mol/l c 500 ml dung dch c pH =12. Gi tr ca a l: A. 0,125M B. 0,375M C. 0,05M D. 0,015M 14. Ho tan hn hp X gm Na2O, Al2O3 v FeO vo nc d thu c dung dch Y v cht rn Z. Cho kh H2 d i qua Z nung nng thu c rn D. D b ho tan mt phn trong dung dch NaOH d. Bit cc phn ng xy ra hon ton. Thnh phn ca cc cht trong dung dch Y v rn Z l: A. Y l NaOH; Z l FeO B. Y l NaOH v Na[Al(OH)4] ; Z l Al2O3 d v FeO C. Y l Na[Al(OH)4]; Z l Al2O3 d v FeO D. Y l NaOH; Z l Al2O3 d v FeO 15. Mt th tch hi anehit X mch h cng hp ti a hai th tch H2 thu c sn phm Y. Cho Y tc dng ht vi Na thu c th tch H2 ng bng th tch hi anehit ban u. Bit cc th tch kh v hi o cng iu kin nhit v p sut. X thuc loi an hit no sau y ? A. n chc, cha no c mt ni i B. Cha no, hai chc C. No, n chc D. No, hai chc Dy no sau y c sp xp theo chiu tng dn bn knh ca nguyn t v ion ? ( Bit 16.
A. C. B. D.

17. t chy hon ton x mol P trong kh O2 d thu c rn X. Cho X vo dung dch cha x mol NaOH th dung dch sau phn ng cha mui no sau y ? A. NaH2PO4 v Na2HPO4 B. NaH2PO4 C. Na3PO4 v Na2HPO4 D. Na2HPO4 18. ng vi cng thc C7H8O c bao nhiu ng phn cha vng bezen va phn ng vi Na, va phn ng vi NaOH ? A. 2 ng phn B. 5 ng phn C. 3 ng phn D. 4 ng phn 19. Nh t t dung dch Na2CO3 vo dung dch Al(NO3)3 ta quan st c: A. Kt ta v c kh bay ra B. Ch c kh bay ra C. Ch c kt ta xut hin D. Khng c hin tng g 20. Thc hin x phng ha 0,5 mol cht bo (C17H33COO)3C3H5 cn va V ml dung dch NaOH 0,75M, thu c m gam Glixerol. V v m c gi tr l: A. 1500 ml; 36 gam B. 2000 ml; 46 gam C. 3000 ml; 60 gam D. 2500 ml; 56 gam 21. Cho 3,38 gam hn hp gm axit axetic, axit acrylic v axit propionic tc dng va vi Na, thu c 672 ml kh (ktc) v dung dch X. C cn dung dch X thu c khi lng cht rn khan l: A. 4,04 gam B. 3,71 gam C. 4,40 gam D. 4,70 gam 22. Cho 56 ml CO2 (ktc) hp th ht vo 1 lt dung dch cha NaOH 0,02M v Ba(OH)2 0,02M. Khi lng kt ta thu c l: A. 0,4925 gam B. 0,2145 gam C. 1,970 gam D. 3,94 gam 23. Dng nc clo oxi ho va 8 gam Br2 thu c dung dch X. Th tch KOH 1,5M cn trung ho va dung dich X l: A. 400 ml. B. 333,33 ml C. 133,33 ml D. 600 ml 24. T 1 tn qung A ngi ta iu ch c 420 kg Fe. T 1 tn qung B ngi ta iu ch c 504 kg Fe. Phi trn 2 qung A v B vi t l khi lng l bao nhiu dc 1 tn qung hn hp m t 1 tn qung hn hp iu ch c 468 kg Fe ?

3 3 1 2 B. C. D. 4 5 2 5 25. Cho hn hp Cu v Fe vo dung dch HNO3 c nng cho n khi cc phn ng kt thc thy cn d li mt t Cu. Nu b qua s thy phn ca cc ion th trong dung dch sau phn ng c cha cc ion no sau y: A. Cu2+, Fe3+ v NO3B. Cu2+, Fe2+ v NO3- C. Cu2+, Fe3+, Fe2+ v NO3D. Fe3+ v NO326. Oxi ha hon ton 14,3 gam hn hp bt cc kim loi Mg, Al, Zn bng O2 thu c 22,3 gam hn hp cc oxit. Cho lng oxit tc dng ht vi dung dch HCl th khi lng mui to ra l: A. 38,6 gam B. 49,8 gam C. 32,05 gam D. 36,6 gam 27. Dn 1 mol ancol etylic i qua ng ng CuO nung nng. Sau phn ng cn li ng ng CuO thy khi lng gim i 8 gam. Khi lng anehit to thnh l : A. 22 gam B. 4,6 gam C. 23 gam D. 11 gam un 18 gam hn hp Glucoz v Fructoz ( t l s mol tng ng 2:3) vi Cu(OH)2 va trong mi 28. trng kim, un nng thu c khi lng kt ta l: A. 5,76g B. 8,64g C. 1,44g D. 14,4g 29. Cho 1,35 gam hn hp gm Cu, Mg v Al tc dng ht vi dung dch HNO3 thu c 1,12 lit hn hp kh X (ktc) gm NO v NO2 , t khi hi ca X so vi H2 bng 21,4. Tnh khi lng mui nitrat thu c trong dung dch sau phn ng ? A. 4,41 gam B. 5,69 gam C. 4,56 gam D. 6,14 gam 30. X, Y, Z l cc nguyn t thuc cng mt chu k trong bng tun hon.Bit: - Oxit ca X tan trong nc to thnh dung dch lm giy qu tm. - Y tan ngay trong nc to thnh dung dch lm xanh giy qu tm. - xit ca Z phn ng c c vi dung dch HCl v dung dch NaOH Dy no sau y c sp xp tho chiu tng dn s hiu nguyn t ca X, Y v Z ? A. X, Z, Y B. X, Y, Z C. Z, Y, X. D. Y, Z, X 31. Dn V lt kh NH3 (ktc) vo 200 ml dung dch ZnCl2 0,25M thy xut hin 2,97 gam kt ta. Th tch NH3 (ktc) ti a c th dng l: A. 0,896 lit B. 1,344lit C. 1,176 lit D. 4,032 lt 32. Caroten( cht mu vng da cam c trong c c rt) c cng thc phn t C40H56 c chc lin kt i v c vng. Khi hiro ho hon ton caroten thu c mt hirocacbon no c cng thc phn t C40H78. S lin kt i v s vng trong phn t caroten l: A. 1 vng v 11 ni i B. 1 vng v 13 ni i C. 2 vng v 11 ni i D. 2 vng v 13 ni i 33. Este X khng no, mach h, c t khi hi so vi oxi bng 3,125. Khi cho X phn ng vi NaOH nung nng th thu c mt andehit v mt mui ca axit cacboxylic. S cng thc cu to ph hp vi X l ? A. 3 B. 4 C. 2 D. 5 34. Cho cc phn ng sau: a. FeO + H2SO4 c nng b. FeS + H2SO4 c nng c. Al2O3 + HNO3 d. Cu + Fe2(SO4)3 Ni ,t 0 e. RCHO + H2 f. Glucoz + AgNO3 + NH3 + H2O g. Etilen + Br2 h. Glixerol + Cu(OH)2 Dy gm cc phn ng u thuc loi phn ng oxi ho- kh l ? A. a, b, d, e, f, g B. a, b, d, e, f, h C. a, b, c, d, e, g D. a, b, c, d, e, h 35. Gi thit rng khi lu ho cao su, S thay th hon ton cc nguyn t H ca nhm metylen (- CH2-) trong mch cao su. Bit rng cao su lu ho c cha 2% S v khi lng. Hi c bao nhiu mt xch isopren th c mt cu ni isunfua (-S-S-) ? A. 25 B. 12 C. 46 D. 18 36. Cho cc ng nghim mt nhn cha ring bit cc cht: Glucoz, anbumin (lng trng trng), Glixerol, H tinh bt. Ho cht no sau y c th nhn bit c mi cht (cc dng c coi nh c ) ? A. Dung dch I2 B. Cu(OH)2/ OHC. Dung dch Br2 D. AgNO3/ dd NH3 37. Thm m gam K vo 300ml dung dch cha NaOH 0,1M v Ba(OH)2 0,1M thu c dung dch X.Cho t t dung dch X vo 200ml dung dch Al2(SO4)3 0,1M thu c kt ta Y. lng ta Y ln nht th gi tr ca m l: A. 1,17 gam B. 1,59 gam C. 1,67 gam D. 1,71 gam 38. Cho hai hp cht hu c ng phn c cng thc phn t C2H7O2N tc dng vi dung dch NaOH va , un nh, thu c 1,12 lit hn hp X(ktc) gm hai kh u c kh nng l xanh giy qu tm m. T
A.

khi hi ca X so vi kh H2 l 12. Nu c cn cn thn dung dch sau phn ng th thu c bao nhiu gam cht rn khan ? A. 3,68g B. 3,75g C. 4,76g D. 5,38g 39. Mt loi xng ch cha hn hp pentan v hexan c t khi hi so vi H2 bng 38,8. Hi t chy va hn hp hi xng th cn trn hi xng v khng kh vi t l th tch l bao nhiu ? (O2 chim 20% th tch khng kh) 1 2 1 3 A. B. C. D. 37 86 34 43 40. Thu phn hon ton 1 mol peptit X thu c cc aminoaxit A, B, C, D v E mi loi mt mol. Thu phn tng phn X trong iu kin thch hp thu c cc i peptit v tri peptit AD, CB, DC, BE, DCB. Cu to ca X l: A. A-D-E-B-C B. A-B-C-D-E C. B-D-C-E-A D. A-D-C-B-E
II. PHN RING. ( Th sinh ch c chn lm mt trong 2 phn A hoc B) A- Theo chng trnh SGK c bn. ( 10 cu, t cu 41 n cu 50 ) 41. Cho dung dch X cha cc ion Mg2+, SO42-, NH4+ v Cl-. Nu dng dung dch NaOH th c th nhn bit

ti a bao nhiu ion ? A. 4 B. 3 C. 2 D. 1 42. Cho mt lung kh CO d i qua hn hp cc oxit CuO, Fe2O3, ZnO, CaO nung nng nhit cao. Sau khi cc phn ng xy ra hon ton ta thu c cht rn gm: A. Cu, FeO, ZnO, CaO B. Cu, Fe, Zn, CaO C. Cu, Fe, ZnO, CaO D. Cu, Fe, Zn, Ca 43. Mt l Fe c chia lm hai phn bng nhau: Phn 1 cho tc dng vi Cl2 d (th nghim 1). Phn hai cho tc dng vi dung dch HCl d (th nghim 2). Khi cc phn ng kt thc th khi lng mui thu c th nghim 1 v th nghim 2 ln lt l: A. 32,5 gam FeCl3 v 32,5 gam FeCl2 B. 25,4 gam FeCl3 v 35,4 gam FeCl2 C. 25,4 gam FeCl3 v 25,4 gam FeCl2 D. 32,5 gam FeCl3 v 25,4 gam FeCl2 44. Cho 0,94 gam hn hp hai anehit n chc no, k tip nhau trong dy ng ng tc dng ht vi dung dich AgNO3/ NH3 thu c 3,24g Ag. Hai anehit ln lt l: A. CH3CHO v C2H5CHO B. C3H7CHO v C4H9CHO C. C2H5CHO v C3H7CHO D. CH3CHO v HCHO 45. Tin hnh crckinh V lt C4H10 thu c 35 ml hn hp A gm 7 cht kh. Cho hn hp A li t t qua bnh ng dung dch brm d phn ng hon ton th thy kh i ra khi bnh c th tch l 20 ml. Hiu sut ca phn ng crckinh l: A. 85% B. 75% C. 80% D. 50% 46. Cho cc cht ring bit : axit fomic, anehit axetic, ancol etylic, axit axetic. Th t cc ho cht dng lm thuc th phn bit cc cht trn thuc dy no ? A. Qu tm, dung dch NaHCO3 B. Dung dch AgNO3/NH3 , dung dch NaOH C. Qu tm, dung dch NaOH D. Qu tm, dung dch AgNO3/NH3 47. Cho 6,05 gam hn hp 3 kim loi Zn, Fe v Mg tc dng va vi x gam dung dch HCl 10%. C cn dung dch sau phn ng thu c 13,15 gam mui khan. Gi tr ca x l ? A. 58,5 gam B. 79 gam C. 73 gam D. 36,5 gam 48. p sut khng lm nh hng n cn bng ho hc no sau y ? 2SO3(kh) A. N2(kh) + 3H2(kh) 2NH3(kh) B. 2SO2(kh) + O2(kh) N2O4(kh) 2HI(kh) C. 2NO2(kh) D. H2(kh) + I2(kh) 49. Cho 3,1 gam ankylamin X tc dng vi dung dch MgCl2 d thu c 2,9 gam ta. Cng thc ca X l: A. CH3NH2 B. C3H7NH2 C. C4H9NH2 D. C2H5NH2 50. Khi ln men a gam Glucoz cha trong nc qu nho sau khi ln men cho 100 lt ru vang 100, bit hiu sut ln men l 95%, khi lng ring ca ru nguyn cht l 0,8 gam/ml. Gi tr ca a l: A. 16,476 gam B. 15,625 gam C. 32,952 gam D. 29,739 gam
B- Theo chng trnh SGK nng cao. ( 10 cu, t cu 51 n cu 60 ) 51. Cho mt l Cu c khi lng 5 gam vo 125 gam dung dch AgNO3 4%. Sau mt thi gian khi ly l

Cu ra, thy khi lng AgNO3 trong dung dch gim 17%. Khi lng l Cu sau phn ng l: A. 3,58 gam B. 2,38 gam C. 5,28 gam D. 5,38 gam

52. Khi tch nc t mt ancol c cng thc phn t C4H10O to thnh 3 anken l ng phn ca nhau. Cng thc cu to thu gn ca X l: A. CH3-CH(CH3)-CH2-OH B. CH3 -CH(OH)-CH2-CH3 C. (CH3)3C-OH D. CH3-CH2-CH2-CH2-OH 53. Cht hu c mch h X c cng thc phn t C3H5Br3 c tc dng vi NaOH d, sau c cn dung dch ri nung nng mnh vi vi ti xt thy c kh bay ra. Tn gi ca X l A. 1,2,2-Tribom propan B. 1,2,3-Tribom propan 1,1,3-Tribom propan C. D. 1,1,1- Tribom propan 54. Len men a gam Glucoz vi hiu sut 90%, lng CO2 sinh ra c hp thu ht bi dung dch nc vi trong thu c 10 gam ta v khi lng dung dch nc vi trong sau phn ng gim 3,4 gam. Gi tr ca a l: A. 15 gam B. 21,5 gam C. 20 gam D. 13,5 gam 55. Ha tan hon ton m gam hn hp 3 kim loi cha r ha tr bng dung dch HNO3 thu c V lt hn hp kh A (ktc) gm NO2 v NO (khng sinh ra mui NH4NO3). T khi hi ca A so vi H2 bng 18,2. Tng s gam mui khan to thnh theo m v V l: A. m+6,0893V B. m+ 3,2147 C. m+2,3147V D. m+6,1875V C(kh) + D(kh) . Bt u th nghim ngi ta trn 4 cht A, 56. Cho cn bng ho hc sau: A(kh) + B(kh) B, C v D mi cht 1 mol vo mt bnh kn c dung tch khng i. Khi cn bng c thit lp thy lng cht C trong bnh l 1,5 mol. Hng s cn bng ca phn ng trn l : A. 4 B. 9 C. 10 D. 25 57. Cho cc loi hp cht: aminoaxit (X), Mui amoni ca axit cacboxilic (Y), amin (Z), este ca aminoaxit (T). dy gm cc loi hp cht u tc dng vi dung dch NaOH v u tc dng vi dung dch HCl l: A. X, Y, Z. B. Y, T, Z. C. X, Y, Z, T. D. X, Y, T. 58. C 7 cht bt ring bit : NaCl, BaCO3, Na2SO4, Na2S, BaSO4, MgCO3, Na2SiO3. Ch dng thm mt dung dch no cho di y c th phn bit c cc mui trn ? A. BaCl2 B. NaOH C. HCl D. AgNO3 59. Ha tan cc cht sau y vo nc c 500 ml dung dch A: 0,05 mol NaCl; 0,1 mol HCl; 0,05 mol NaHCO3; 0,05 mol H2SO4; v 0,1 mol (NH4)2SO4. 300 ml dung dch B cha KOH 0,5M v Ba(OH)2 1M. Trn dung dch A vi dung dch B thu c 800 ml dung dch C. Hi khi lng dung dch C so vi tng khi lng hai dung dch A v B gim bao nhiu gam ? A. 35,25 gam B. 36,55 gam C. 32,65 gam D. 38,35 gam 2+ 2+ 60. Cho th t cc cp oxi ho -kh chun ca cc kim loi sau: Zn /Zn , Fe /Fe , Cu2+/Cu v Fe3+/Fe2+. Phn ng ho hc no sau y khng xy ra ? A. Fe + Zn2+ B. Cu + Fe3+ C. Fe + Fe3+ D. Zn + Cu2+

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