Trang 1/5 - M thi 132

S GD&T THANH HA
TRNG THPT HONG L KHA
THI TH I HC LN 1 NM 2010
MN: HA HC
Thi gian lm bi:90 pht


M thi 132


H, tn th sinh:..........................................................................
S bo danh:...............................................................................

Cu 1: Khi pin in ha CrCu phng in, xy ra phn ng :
2Cr + 3Cu
2+
2Cr
3+
+ 3Cu
Bit
+ +
= =
3 2
0 0
Cr Cu
Cr Cu
E 0,74 V; E + 0,34 V , sut in ng ca pin in ha (
0
pi n
E ) l
A. 1,08V. B. 2,5V. C. 1,40V. D. 1,25V.
Cu 2: Cho cc cu hnh electron ca cc nguyn t sau
(1). 1s
2
2s
1
(5). 1s
2
2s
2
2p
6
3s
1
(9). 1s
2
2s
2
2p
3

(2). 1s
2
2s
2
2p
6
3s
2
3p
2
(6). 1s
2
2s
2
2p
4
(10). 1s
2
2s
2
2p
6
3s
2
3p
6
4s
1

(3). 1s
2
2s
2
2p
6
3s
2
3p
1
(7). 1s
2
(11). 1s
2
2s
2
2p
6
3s
2
3p
5

(4). 1s
2
2s
2
2p
6
3s
2
3p
6
3d
5
4s
1
(8). 1s
2
2s
2
2p
6
3s
2
3p
6
3d
5
4s
2
(12). 1s
2
2s
2
2p
6
3s
2
3p
6
3d
10
4s
2
4p
5

C cc nhn nh sau: Trong cc nguyn t cho trn:
1. C 6 nguyn t l kim loi
2. C 5 nguyn t l phi kim
3. Khng c nguyn t no l kh him
4. Ch c 5 nguyn t thuc nguyn t khi p
5. C 3 nguyn t thuc nguyn t khi d
6. C 2 nguyn t c s electron c thn l 2, c 6 nguyn t c s electron c thn l 1.S nhn
nh ng l:
A. 3. B. 4 C. 2 D. 5
Cu 3: Cho 9,25 gam hn hp X gm Fe, Fe
3
O
4
tc dng vi 200ml dung dch HNO
3
long, un
nng v khuy u. Sau khi phn ng xy ra hon ton thu c 1,12 lt kh NO duy nht (ktc),
dung dch Y v cn li 0,73 gam kim loi. Khi lng mui trong Y v nng mol ca dung dch
HNO
3
l
A. 65,34 gam ; 2,7M. B. 24,3 gam ; 1,6M. C. 24,3 gam ; 3,2M. D. 34,2 gam ; 3,2M.
Cu 4: X phng ha hon ton mgam mt cht bo (khng c axit bo t do) cn dng va dung
dch c cha 0,03mol NaOH v 0,06 mol KOH c cn dung dch sau phn ng thu c 27,66gam x
phng. Gi tr ca m l:
A. 26,78 B. 25,86 C. 24,78 D. 27,32
Cu 5: X l hn hp kim loi Ba v Al. Ha tan m gam X vo lng d nc thu c 4,48 lt H
2

(ktc). Cng ho tan m gam X vo dung dch NaOH d th thu c 6,16 lt kh H
2
(ktc). Gi tr ca
m l
A. 6,85. B. 29,25. C. 10,90. D. 25,75.
Cu 6: Quy lut bin thin nhit si ca CH
3
OH, H
2
O, C
2
H
5
OH, CH
3
OCH
3
nh sau:
A. H
2
O > C
2
H
5
OH > CH
3
OH > CH
3
OCH
3
B. H
2
O > C
2
H
5
OH > CH
3
OCH
3
> CH
3
OH
C. C
2
H
5
OH >H
2
O > CH
3
OCH
3
> CH
3
OH D. C
2
H
5
OH >H
2
O > CH
3
OH> CH
3
OCH
3

Cu 7: Cho t t tng git dung dch cha 0,05 mol HCl vo dung dch cha 0,06 mol Na
2
CO
3
. Th
tch kh CO
2
(ktc) thot ra l
A. 1,120 lt. B. 0,00 lt. C. 1,344 lt. D. 0,56 lt.
Cu 8: Cacbon phn ng c vi nhm cht no sau y
A. Fe
2
O
3
, Ca, CO
2
, H
2
, HNO
3
c, H
2
SO
4
c B. Fe
2
O
3,
CO
2
, MgO, HNO
3
c, H
2
SO
4
c
C. CO
2
, H
2
O, CaO, HNO
3
c, H
2
SO
4
c D. CO
2
, Al
2
O
3
, Ca, CaO, HNO
3
c, H
2
SO
4
c
Cu 9: Thm 250 ml dung dch NaOH 2M vo 200 ml dung dch H
3
PO
4
1,5M. Mui to
Trang 2/5 - M thi 132
thnh l
A. NaH
2
PO
4
; Na
2
HPO
4
. B. Na
2
HPO
4
; Na
3
PO
4
.
C. NaH
2
PO4 ; NaHPO
4
. D. NaH
2
PO
4
; Na
3
PO
4

Cu 10: Hp cht hu c X c iu ch t etyl benzen theo s sau
Etyl benzen
+
+
0
4
, / t H KMnO
X
+ dac SO H dac HNO
4 2 3
/
Y
+
0
4 2 5 2
, / t dac SO H OH H C
Z.
Vy Z c cng thc cu to l:
A. ng phn m- ca O
2
N-C
6
H
4
-COOC
2
H
5

B. ng phn o- ca O
2
N-C
6
H
4
-COOC
2
H
5

C. Hn hp ng phn o- v p- ca O
2
N-C
6
H
4
-COOC
2
H
5

D. ng phn p- ca O
2
N-C
6
H
4
-COOC
2
H
5

Cu 11: Cho tt c cc ng phn mch h ca hp cht c CTPT C
2
H
4
O
2
ln lt tc dng vi: Na;
NaOH; NaHCO
3
. S phn ng ha hc xy ra l:
A. 5 B. 6 C. 4 D. 3
Cu 12: X l Mt aren c cng thc n gin nht l C
4
H
5
. Khi X tham gia phn ng brom ha c
mt nh sng hoc xc tc st nung nng, mi trng hp ch thu c mt dn xut mono brom duy
nht. Tn gi ca X l:
A. vinyl benzen B. m- xilen C. p-xilen D. o-xilen
Cu 13: Theo Bronsted th cc ion sau: Na
+
, NH
4
+
, S
2-
, Cl
-
, CO
3
2-
, HS
-
, CH
3
COO
-
, HSO
4
-
, HCO
3
-
,
K
+
, Cu
2+
. S ion l axit, baz, lng tnh ln lt l :
A. 3, 3, 2 B. 1, 0, 3 C. 2, 3, 3 D. 1, 3, 3
Cu 14: C
5
H
10
O (X) l hp cht hu c mch h c kh nng cng H
2
/ Ni, t
0
to thnh 2-metylbutan-
1-ol. S CTCT ca X l:
A. 2 B. 3 C. 4 D. 5
Cu 15: Cho hn hp gm { Fe v Cu } d vo dung dch HNO
3
long. Sau khi phn ng kt thc
thu c dung dch X. Cht tan trong dung dch X l
A. Fe(NO
3
)
2
. B. Fe(NO
3
)
3
.
C. Fe(NO
3
)
3
v Cu(NO
3
)
2
. D. Fe(NO
3
)
2
v Cu(NO
3
)
2
.
Cu 16: Cho 14 gam bt Fe vo 400ml dung dch X gm : AgNO
3
0,5M v Cu(NO
3
)
2
xM. Khuy
nh cho ti khi phn ng kt thc thu c dung dch Y v 30,4 gam cht rn Z. Gi tr ca x l
A. 0,15. B. 0,125. C. 0,2. D. 0,1.
Cu 17: Cho m gam hn hp X gm Zn, Fe v Mg vo dung dch HCl d thu c dung dch Y.
Thm tip KNO
3
d vo dung dch Y th thu c 0,672 lit kh NO duy nht (ktc). Vy khi lng
st c trong m gam hn hp X ban u l :
A. 3,36gam B. 6,72gam C. 1,68gam D. 5,04gam
Cu 18: Cho hn hp X gm Fe
3
O
4
, Al, Al
2
O
3
, Fe. Cho X tan trong dung dch NaOH d c hn
hp cht rn A
1
, dung dch B
1
, kh C
1
. Kh C
1
(ly d) cho tc dng vi X nung nng c hn hp
cht rn A
2
. Dung dch B
1
tc dng vi dung dch H
2
SO
4
long, d c dung dch B
2
. Cht rn A
2

cho tc dng vi H
2
SO
4
c, nng c dung dch B
3
v kh C
2
. Cho B
3
tc dng vi bt Fe c
dung dch B
4
. S phn ng oxi ha kh xy ra l
A. 7. B. 4. C. 5. D. 6.
Cu 19: Dung dch A: HCl 0,5M v H
2
SO
4
0,15M, dung dch B: KOH 0,3M v Ba(OH)
2
0,1M.
Trung ho 400 ml dung dch A cn V ml dung dch B v thu c p gam kt ta. Gi tr ca V v p
l
A. 640ml v 14,912g B. 320ml v 6,99 g C. 640ml v 13,98 g. D. 400ml v 7,456g
Cu 20: Hin tng no di dy c m t khng ng?
A. Thm Cu vo dd Fe(NO
3
)
3
thy dd chuyn t mu vng nu sang mu xanh.
B. Thm mt t bt Fe vo lng d dd AgNO
3
thy xut hin dd mu vng nht.
C. Thm Fe(OH)
2
mu nu vo dd H
2
SO
4
thy hnh thnh dd mu vng nu.
D. Thm NaOH vo dd FeCl
3
mu vng nu thy xut hin kt ta nu .
Cu 21: un nng cht H
2
N-CH
2
-CONH-CH(CH
3
)-CONH-CH
2
COOH trong dung dch HCl d, sau
khi phn ng kt thc thu c sn phm l:
Trang 3/5 - M thi 132
A. H
2
NCH
2
COOH; H
2
N-CH(CH
3
)

COOH
B. H
2
NCH
2
COOH; H
2
N CH
2
CH
2
COOH
C. H
3
N
+
-CH
2
COOHCl
-
; H
3
N
+
-CH(CH
3
)

COOHCl
-

D. H
3
N
+
-CH
2
COOHCl
-
; H
3
N
+
-CH
2
CH2COOHCl
-

Cu 22: Mt hn hp gm hai bt kim loi Mg v Al c chia thnh hai phn bng nhau:
- Phn 1: cho tc dng vi HCl d thu c 3,36 lt H
2
.
- Phn 2: ho tan ht trong HNO
3
long d thu c V lt mt kh khng mu, ho nu trong
khng kh (cc th tch kh u o ktc). Gi tr ca V l
A. 4,48 lt. B. 3,36 lt. C. 2,24 lt. D. 5,6 lt.
Cu 23: Hp cht hu c X c CTPT C
4
H
7
O
2
Cl khi thy phn trong mi trng axit c cc sn
phm trong c 2 hp cht c kh nng tham gia phn ng trng gng. CTCT ca X l:
A. CH
3
COO-CHCl-CH
3
B. HCOO-CH
2
-CHCl-CH
3

C. C
2
H
5
COOCH
2
Cl D. HCOO-CHCl-CH
2
CH
3

Cu 24: Cho phn ng: A + B C + D. Nng ban u : C
A
= C
B
= 0,1 mol/lt. Sau mt thi
gian, nng ca A, B cn li 0,04 mol/l. `Tc p/ thi im ny gim bao nhiu ln sao vi
thi im ban u?
A. 5,25 ln B. 6,25 ln C. 2,5 ln D. 0,4 ln
Cu 25: X,Y l hai hidrocacbon c CTPT ln lt l C
5
H
12
v C
6
H
14
. Khi thc hin phn ng clo ha
mi cht th X to thnh 4 dn xut mono clo, cn Y to tnh 2 dn xut mono clo. Tn gi ca X, Y
ln lt l:
A. isopentan v 2,3-imetylbutan B. isopentan v n-hexan
C. neopentan v 2,3-imetylbutan D. n-pentan v neohexan
Cu 26: Nhit phn hon ton hn hp BaCO
3
,MgCO
3
,Al
2
O
3
c rn X v kh Y.Ho tan rn X vo
nc thu c kt ta E v dd Z.Sc kh Y d vo dd Z thy xut hin kt ta F,ho tan E vo dd
NaOH d thy tan mt phn c dd G. Kt lun no sau y l ng
A. Dung dch Z cha Ba(AlO
2
)
2
, Dung dch G cha NaOH v NaAlO
2

B. Dung dch Z cha Ba(AlO
2
)
2
, Dung dch G cha NaAlO
2

C. Dung dch Z cha Ba(OH)
2
v Ba(AlO
2
)
2
, Dung dch G cha NaOH v NaAlO
2

D. Dung dch Z cha Ba(OH)
2
, Dung dch G cha NaOH v Ba(OH)
2

Cu 27: Ha tan ht m gam hn hp X gm FeO, Fe
2
O
3
, Fe
3
O
4
bng HNO
3
c nng thu c 4,48
lt kh NO
2
(ktc). C cn dung dch sau phn ng thu c 145,2 gam mui khan gi tr ca m l
A. 15,8 gam. B. 77,7 gam. C. 35,7 gam. D. 46,4 gam.
Cu 28: X l ancol bc II c CTPT C
6
H
14
O. un X vi H
2
SO
4
c 170
0
C ch to c mt anken
duy nht. Tn ca X l g?
A. 2,2-imetylbutan-3-ol B. 3,3-imetylbutan-2-ol
C. 2,3-imetylbutan-3-ol D. 1,2,3-trimetylpropan-1-ol
Cu 29: in phn 400ml dung dch gm : AgNO
3
0,2M v Cu(NO
3
)
2
0,1M vi cng dng in
I=12A, anot tr. Sau t giy, ngt dng in sy kh catot ri cn li thy khi lng catot tng thm
m gam, trong c 1,28 gam Cu. Gi tr ca m v t l
A. 1,28 ; 1930. B. 9,92 ; 965. C. 9,92 ; 1930. D. 2,28 ; 965.
Cu 30: C 4 dung dch mui ring bit : CuCl
2
, ZnCl
2
, FeCl
3
, AlCl
3
. Nu thm dung dch KOH d
ri thm tip dung dch NH
3
d vo 4 dung dch trn th s cht kt ta thu c l
A. 2. B. 4. C. 3. D. 1.
Cu 31: Trong cng nghip, anehit fomic c iu ch trc tip
A. ch t metan B. ch t axit fomic
C. ch t ru metylic D. t metan hoc t ru metylic
Cu 32: Ha tan hon ton 2,84 gam hn hp hai mui cacbonat ca hai kim loi phn nhm II
A
v
thuc hai chu k lin tip trong bng tun hon bng dung dch HCl ta thu c dung dch X v 672
ml CO
2
( ktc). C cn dd X thu c m gam mui khan
Cc kim loi, v gi tr ca m l
A. Mg; Ca; m = 3,17 B. Mg; Ca; m = 2,54 C. Be; Mg; m = 3,17 D. Ca; Sr; m = 2,95
Trang 4/5 - M thi 132
Cu 33: Este X khng no mch h c t khi hi so vi oxi bng 3,125 v khi tham gia phn ng x
phng ha to ra mt anehit v mt mui ca axit hu c. C bao nhiu CTCT ph hp vi X
A. 5 B. 4 C. 3 D. 2
Cu 34: Xenluloz khng phn ng c vi tc nhn no di y
A. [Cu(NH
3
)
4
](OH)
2
B. HNO
3
c/H
2
SO
4
c, t
0

C. (CS
2
+ NaOH) D. H
2
/Ni
Cu 35: Cho cc phn ng xy ra sau y:
(1) AgNO
3
+ Fe(NO
3
)
2
Fe(NO
3
)
3
+ Ag+
(2) Mn + 2HCl MnCl
2
+ H
2 |
Dy cc ion c sp xp theo chiu tng dn tnh oxi ho l
A. Mn
2+
, H
+
, Ag
+
, Fe
3+
B. Ag
+
, Mn
2+
, H
+
, Fe
3+

C. Ag
+
, Fe
3+
, H
+
, Mn
2+
D. Mn
2+
, H
+
, Fe
3+
, Ag
+

Cu 36: Cho mgam hp cht hu c x (C
3
H
9
O
2
N) tc dng vi 200ml dung dch NaOH 1M. Sau cc
phn ng hon ton thu c dung dch A v 2,24 lit kh B duy nht(ktc). B c t khi hi so vi
hidro l 15,5 v c kh nng lm qu tm m ha xanh. C cn dung dch A th thu c bao nhiu
gam cht rn.
A. 12,2gam B. 8,2gam C. 13,6gam D. 16,4gam
Cu 37: X phng ha hon ton 66,6gam hn hp 2 este HCOOC
2
H
5
v CH
3
COOCH
3
bng dung
dch NaOH; thu c hn hp X gm 2 ancol. un nng X vi H
2
SO
4
c 140
0
C sau khi phn ng
hon ton thu c m gam nc. Gi tr ca m l:
A. 18,00 B. 8,10 C. 16,20 D. 4,05
Cu 38: Pht biu no sau y khng ng ?
A. glucoz v fructoz l ng phn cu to ca nhau
B. C th phn bit glucoz v fructoz bng phn ng trng bc
C. Trong dung dch glucoz tn ti dng mch vng u tin hn dng mch h
D. metyl- - glicozit khng th chuyn sang dng mch h
Cu 39: Cho s phn ng : X PVA (poli (vinylaxetat)
Pht biu khng ng v X l:
A. X c 4 ng phn cu to mch h l hp cht hu c cng chc
B. X cng dy ng ng vi etyl acrylat
C. Thy phn X trong mi trng axit to ra sn phm c kh nng tham gia phn ng trng
gng
D. X c kh nng lm mt mu dung dch Brom
Cu 40: Poli (metyl metacrylat) v nilon 6c to thnh t cc monome tng ng l:
A. CH
3
COOCH=CH
2
; H
2
N(CH
2
)
5
COOH B. CH
2
=C(CH
3
)-COOCH
3
; H
2
N(CH
2
)
6
COOH
C. CH
2
=C(CH
3
)-COOCH
3
; H
2
N(CH
2
)
5
COOH D. CH
2
=CH-COOCH
3
; H
2
N(CH
2
)
6
COOH
Cu 41: in phn dung dch X cha hn hp cc mui sau : NaCl, CuCl
2
, FeCl
3
, ZnCl
2
. Kim loi
u tin thot ra catot l:
A. Fe. B. Zn. C. Na. D. Cu.
Cu 42: oxi ha mgam ancol CH
3
OH bng O
2
vi xc tc thch hp thu c hn hp hi Y(gm
H
2
O, anehit, axitcacboxylic tng ng v ancol d). Chia Y thnh 3 phn bng nhau. trung ha
ht phn 1 cn 40ml dung dch NaOH 1M. Cho phn 2 tc dng vi lng d dung dch AgNO
3
/NH
3

un nng, sau phn ng hon ton thu c 34,56gam Ag. Cho phn 3 tc dng ht vi Na d thu
c 2,016lit H
2
(ktc). Gi tr ca m l
A. 17,28 B. 23,04 C. 24,96 D. 13,44
Cu 43: Lin kt hidro bn nht trong hn hp metanol nc theo t l mol 1:1 l lin kt no:
A. ... O H ... O H ... B. ... O H ... O H ...

H CH
3
CH
3
H
C. ... O H ... O H ... D. ... O H ... O H ...

CH
3
CH
3
H

H
Trang 5/5 - M thi 132
Cu 44: Dy gm cc cht u phn ng vi phenol l:
A. nc brom, anehit axetic, dd NaOH B. nc brom, axit axetic, dd NaOH
C. dd NaCl, dd NaOH, kim loi Na D. nc brom, anhiritaxetic, dd NaOH
Cu 45: t chy hon ton 0,1mol hn hp X gm 1 anehit A v mt axit hu c B( A hn B mt
nguyn t Cacbon) thu c 3,36lit CO
2
(ktc) v 2,7gam nc. Vy khi cho 0,2mol X tham gia phn
ng trng gng hon ton vi dd AgNO
3
/NH
3
d th khi lng Ag thu c l:
A. 21,6gam B. 32,4gam C. 43,2gam D. 64,8gam
Cu 46: X (c cha nhm NH
2
) v Y l 2 ng phn c cng thc phn t l C
3
H
7
O
2
N tham gia 2
phn ng
1. X + NaOH C
2
H
4
O
2
N Na + CH
4
O
2. Y + NaOH C
3
H
3
O
2
Na + Z + H
2
O
Pht biu khng ng l:
A. Z l cht kh tan tt trong nc v kh c CuO nung nng thnh Cu
B. X l este (ca amino axit) c CTCT l CH
3
OOCCH
2
NH
2

C. Y l mui amoni ca axit acrylic
D. Z c tnh kh mnh v l sn phm cui cng ca qu trnh nhit phn NH
4
NO
3

Cu 47: Cho cc phn ng
HBr + C
2
H
5
OH
0
t

C
2
H
4
+ Br
2

C
2
H
4
+ HBr
C
2
H
6
+ Br
2

) ( 1 : 1 , mol askt

S phn ng to ra C
2
H
5
Br l
A. 4 B. 3 C. 2 D. 1
Cu 48: Cho hn hp gm 0,15 mol CuFeS
2
v 0,09 mol Cu
2
FeS
2
tc dng vi dung dch HNO
3
d
thu c dung dch X v hn hp kh Y gm NO v NO
2.
Thm BaCl
2
d vo dung dch X thu c
m gam kt ta. Mt khc, nu thm Ba(OH)
2
d vo dung dch X, ly kt ta nung trong khng kh
n khi lng khng i thu c a gam cht rn. Gi tr ca m v a l:
A. 111,84g v 157,44g B. 112,84g v 157,44g
C. 112,84g v 167,44g D. 111,84g v 167,44g
Cu 49: Nung 13,5 gam hn hp 2 mui cacbonat ca 2 kim loi ho tr 2, thu c 6,9 gam cht rn
v kh X. Lng kh X sinh ra cho hp th vo 75ml dung dch NaOH 1M. Khi lng mui khan thu
c sau phn ng l
A. 4,2 gam. B. 5,8 gam. C. 6,3 gam. D. 6,5 gam.
Cu 50: trung ha 5,48gam hn hp gm axit axetic, phenol v axit benzoic cn dng 600ml dd
NaOH 0,1M. C cn dd sau phn ng thu c hn hp cht rn khan c khi lng l:
A. 8,64gam B. 6,84gam C. 4,90gam D. 6,80gam

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