thi th i hc Cao ng ln 1 S GD&T H TNH Trng THPT Hng Kh ( thi c 6 trang)

Trng THPT Hng Kh

- THI TH I HC, CAO NG LN I NM HC 2009 - 2010 Mn thi: HO HC - KHI A, B Thi gian lm bi: 90 pht

H v tn th sinh: ................................................................................... S bo danh: ..............................................................................................

I. Phn chung cho tt c cc th sinh (40 cu, t cu 1 n cu 40).

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(Cho bit nguyn t khi ca cc nguyn t C = 12; H = 1; O = 16; N = 14; Al = 27; Fe = 56; Cu = 64; Ag = 108). Cu 1: X phng ha este C5H10O2 thu c mt ancol. un nng ancol ny vi H2SO4 c 1700C c hn hp cc anken. Este l: A. CH3COOCH2CH2CH3 B. CH3COOCH(CH3)2 C. HCOOCH(CH3)C2H5 D. HCOO(CH2)3CH3 Cu 2: Hp th V lt CO2 (ktc) vo 200 ml dd NaOH 1M thu c dd X. Khi cho CaCl2 d vo dung dch X c kt ta v dung dch Y, un nng li thy c kt ta xut hin. Gi tr ca V l: A. V 1,12 B. 2,24 < V < 4,48 C. 1,12 < V < 2,24 D. 4,48 V Cu 3: C 4 hp cht hu c cng thc phn t ln lt l: CH2O, CH2O2, C2H2O3, C3H4O3. S cht va tc dng vi dung dch NaOH va tc dng vi Na, va c phn ng trng gng l: A. 1 B. 2 C. 3 D. 4 Cu 4: Ha tan hn hp gm Mg v Al vo dung dch HNO3 va thu c dung dch X khng cha mui amoni v 0,336 lt N2O (ktc) thot ra duy nht. Nu cho t t dung dch NaOH 1M vo dung dch X n khi khi lng kt ta t gi tr 2,52 gam th th tch dung dch NaOH ti thiu dng l 90 ml (gi s Mg(OH)2 kt ta ht trc khi Al(OH)3 bt u kt ta trong dung dch kim). Vy % khi lng ca Mg trong hn hp u l: A. 42,86% B. 57,14% C. 36% D. 69,23% Cu 5: Hp cht X khng no mch h c cng thc phn t C5H8O2 khi tham gia phn ng x phng ha thu c mt anehit v 1 mui ca axit hu c. C bao nhiu cng thc cu to ph hp vi X (khng k ng phn CiS, tran S)? A. 2 B. 3 C. 4 D. 5 Cu 6: Dy gm cc cht u tc dng vi dung dch AgNO3 trong NH3 l: A. Anehit axetic, but -1 -in, etilen B. Anehit axetic, axetilen, bt - 2 -in. C. Axit fomic, vinylaxetilen, propin D. Anehit fomic, axetilen, etilen Cu 7: Cho lung kh H2 (d) qua hn hp cc oxit CuO, Fe2O3; ZnO, MgO nung nhit cao. Sau phn ng hn hp rn cn li l: A. Cu, Fe, Zn, MgO B. Cu, Fe, ZnO, MgO C. Cu, Fe, Zn, Mg Cu 8: Cho cn bng ha hc sau: SO2 + H2O D. Cu, FeO, ZnO, MgO H+ + HSO3-

Khi thm vo dung dch mt t mui NaHSO4 (khng lm thay i th tch) th cn bng trn s: A. Chuyn dch theo chiu nghch B. Chuyn dch theo chiu thun C. Khng xc nh D. Khng chuyn dch theo chiu no

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Cu 9: Trong hp cht ion XY (X l kim loi, Y l phi kim), s electron ca cation bng s electron ca anion v tng s electron trong XY l 20. Bit trong mi hp cht, Y ch c mt mc oxi ha duy nht. Cng thc XY l: A. AlN B. MgO C. LiF D. NaF Cu 10: Nguyn t ca nguyn t X c phn lp electron ngoi cng l 3p. Nguyen t ca nguyn t Y c phn lp electron ngoi cng l 3s. Tng s electron 2 phn lp ngoi cng ca X v Y l 7. Bit rng X v Y d dng phn ng vi nhau. S hiu nguyn t ca X v Y tng ng l: A. 18 v 11 B. 13 v 15 C. 12 v 16 D. 17 v 12 Cu 11: Trong s cc kim loi Al, Fe, Cr, Cu th kim loi khng phn ng vi dung dch HNO3 c ngui l: A. Cu B. Al v Fe C. Al, Fe v Cr D. Al, Fe, Cr v Cu. Cu 12: Khng nh no sau y l ng: A. Xenluloz, tinh bt, mantoz u l polime t nhin. B. Xenluloz, tinh bt, nha bakelit u c mch nhnh. C. T nilon -6,6 v t nilon -7 u c lin kt amit. D. Cc polime u b thy phn trong mi trng axit khi un nng. Cu 13: t chy hon ton 5,6 lt (ktc) hn hp hai este no, mch h, n chc l ng ng lin tip thu c 19,712 lt CO2 (ktc). X phng ha cng lng este trn bng dung dch NaOH to ra 17 gam mt mui duy nht. Cng thc ca hai este trn l: A. HCOOC2H5 v HCOOC3H7 B. CH3COOCH3 v CH3COOC2H5 C. HCOOC3H7 v HCOOC4H9 D. CH3COOC2H5 v CH3COOC3H7 Cu 14: t chy hon ton 8,96 lt hn hp (ktc) hai anken kh l ng ng lin tip thu c m gam H2O v (m+39) gam CO2. Hai anken l: A. C4H8 v C5H10 B. C2H4 v C3H6 C. C4H8 v C3H6 D. C5H10 v C6H12 Cu 15: Ha tan 20 gam K2SO4 v 150 gam nc, thu c dung dch A. Tin hnh in phn dung dch A mt thi gian. Sau khi in phn khi lng K2SO4 trong dung dch chim 15% khi lng ca dung dch. Bit lng nc bay hi khng ng k. Th tch kh thot ra mi in cc o ktc l: A. 22,815 lt v 11,4 lt B. 40 lt v 22 lt C. 45,63 lt v 22,8 lt D. 44,4 lt v 22,2 lt Cu 16: Xenlulozo trinitrat c iu ch t xenlulozo v axit nitric c c xc tc axit sunfuric c, nng. c 29,7kg xenlulozo trinitrat cn dng dung dch cha m kg axit nitric (hiu sut phn ng t 90%). Gi tr ca m l: A. 42 kg B. 10 kg C. 30 kg D. 21 kg Cu 17: Cho 200 ml dung dch AlCl3 1,5M tc dng vi V lt dung dch NaOH 0,5M, lng kt ta thu c l 15,6 gam. Gi tr ln nht ca V l: A. 1,2 B. 1,8 C. 2,4 D. 2 Cu 18: Cho 2,46 gam hn hp gm HCOOH, CH3COOH, C6H5OH tc dng va vi 40 ml dung dch NaOH 1M. Tng khi lng mui khan thu c sau khi phn ng l: A. 3,52 gam B. 6,45 gam C. 8,42 gam
2+

D. 3,34 gam

Cu 19: Trong cc cht v ion sau: Zn, S, Cl2, SO2, FeO, Fe2O3, Fe , Cu2+, Cl- c bao nhiu cht v ion ng vai tr va l oxi ha, va kh. A. 4 B. 5 C. 6 D. 7

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Cu 20: Thy phn hon ton 89 gam cht bo bng dung dch NaOH iu ch x phng, thu c 9,2 gam glixerol. Bit mui ca axit bo chim 60% khi lng x phng. Khi lng x phng thu c l: A. 91,8gam B. 58,92 gam C. 55,08 gam D. 153 gam Cu 21: Cho cc dung dch sau: Na2CO3, NaCl, CH3COONa, NH4Cl, NaHSO4, K2S, NaHCO3 v C6H5ONa. S dung dch c pH > 7 l: A. 6 B. 3 C. 5 D. 4 Cu 22: C 6 dung dch ring bit ng trong 6 l mt nhn: NH4Cl, (NH4)2SO4, Na2SO4 NaOH, FeCl3, AlCl3. Nu ch dng mt thuc th nhn bit 6 dung dch trn, ta c th dng dung dch no sau y: A. Dung dch AgNO3 B. Dung dch KCl C. Dung dch Ba(OH)2 D. Dung dch Na2CO3 + Cu 23: Nng mol/l ca ion H trong dung dch HCl nng 0,5.10-7 mol/l l: A. 0,5 . 10-7 B. 1,5.10-7 C. 1,28.10-7 D. 1,25.10-7 Cu 24: Cho hn hp X gm hai cht hu c c cng cng thc phn t C2H7NO2 tc dng va vi dung dch NaOH v un nng, thu c dung dch Y v 4,48 lt hn hp Z ( ktc) gm hai kh (u lm xanh giy qu m). T khi hi ca Z i vi H2 bng 13,75. C cn dung dch Y thu c khi lng mui khan l: A. 16,5gam B. 14,3 gam C. 8,9 gam D. 15,7 gam. 2+ + Cu 25: Mt dung dch cha 0,02 mol Cu ; 0,03 mol K , x mol Cl v y mol SO42-. Tng khi lng cc mui tan c trong dung dch l 5,435 gam. Gi tr ca x v y ln lt l: A. 0,03 v 0,02 B. 0,05 v 0,01 C. 0,01 v 0,03 D. 0,02 v 0,05 Cu 26: Trn ln 200ml dung dch Al2(SO4)3 0,1M vi 100ml dung dch HCl nng a mol/l c dung dch A. Cho 0,12 mol Ba vo dung dch A, lc ly kt ta nung n khi lng khng i c 15 gam cht rn. Gi tr a l: A. 1,8 M v 1M B. 1,6 M v 0,8 M C. 1,4M v 0,9 M D. 2,2 M v 1,5 M. Cu 27: A l mt - amino axit no, ch cha mt nhm -NH2 v mt nhm - COOH. Cho 8,9 gam A tc dng vi dung dch HCl d thu c 12,55 gam mui. Cng thc cu to ca A l: A. CH3 - CH - COOH B. CH3 - CH2 - CH - COOH
| |

NH2 C. H2N - CH2 - CH2 - COOH

NH2 D. CH3 - CH - CH2 - COOH

|

NH2 Cu 28: Ha tan hon ton 17,4 gam hn hp ba kim loi Al, Fe, Mg trong dung dch HCl thy thot ra 13,44 lt kh. Nu cho 8,7 gam hn hp tc dng vi dung dch NaOH d thu c 3,36 lt kh. Vy nu cho 34,8 gam hn hp trn tc dng vi dung dch CuSO4 d, lc ly ton b cht rn thu c sau phn ng tc dng vi dung dch HNO3 c nng, d th thu c V lt kh NO2. Cc th tch kh u o ktc. Th tch kh NO2 thu c l: A. 53,76 lt B. 44,8 lt C. 13,44 lt D. 26,88 lt

Cu 29: Trng hp 65,0 gam Stiren bng cch un nng cht ny vi mt lng nh cht xc tc benzoyl peoxit. Cho ton b hn hp sau phn ng ( loi ht benzoyl peoxit) vo 1,0 lt dung dch brom 0,15M, sau cho thm KI (d) thy sinh ra 6,35 g It. Hiu sut ca phn ng trng hp Stiren l: A. 70% B. 80% C. 60% D. 85%

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Cu 30: Cho dy cc cht: Ca(HCO3)2 , NH4Cl , (NH4)2CO3, ZnSO4, Al(OH)3, Zn(OH)2. S cht trong dy c tnh cht lng tnh l: A. 3 B. 5 C. 2 D. 4 Cu 31: Cho dung dch metylamin d ln lt vo tng dung dch sau: FeCl3, AgNO3, NaCl, Cu(NO3)2. S kt ta thu c l: A. 1 B. 2 C. 3 D. 4 Cu 32: Trong s cc cht phenol, anilin, glucoz, mantoz, axitacrilic. S lng cht phn ng c vi dung dch nc brom l: A. 2 cht B. 3 cht C. 4 cht D. 5 cht. Cu 33: Cho bit s hiu nguyn t ca Cu l 29. Pht biu no sau y khng ng: A. Cu thuc chu k 4 B. Cu thuc nhm IIB + C. Ion Cu c lp electron ngoi cng bo ha D. Cu hnh electron ca Cu l cu hnh vi bo ha Cu 34: Chn mt thuc th cho di y nhn bit cc dung dch ring bit: HCl, KI, ZnBr2, Mg(NO3)2? A. Dung dch AgNO3 B. Dung dch NaOH C. Giy qu tm D. Dung dch NH3 Cu 35: Thnh phn chnh ca amophot, mt loi phn bn phc hp l: A. Ca(H2PO4)2 B. NH4H2PO4 v Ca(H2PO4)2 C. NH4H2PO4 v (NH4)2HPO4 D. (NH4)2HPO4 v Ca(H2PO4)2 Cu 36: Cho 2 gam hn hp A gm Mg, Al, Fe, Zn tc dng vi HCl d gii phng 0,1 gam kh; 2 gam A tc dng vi Cl2 d thu c 5,763 gam hn hp mui. Phn trm khi lng Fe trong A l: A. 22,4% B. 19.2% C. 16,8% D. 14% Cu 37: Mt anehit no c cng thc n gin nht l C2H3O. C bao nhiu cng thc cu to ng vi cng thc phn t ? A. 2 B. 1 C. 3 D. 4 Cu 38: t chy ht a gam hn hp A gm 2 ancol n chc, ng ng k tip thu c 22 gam CO2 v 12,6 gam H2O. Mt khc cho a gam hn hp A tc dng hon ton vi CuO, nung nng thu c hn hp B. Cho B tc dng ht vi lng d AgNO3/NH3 (hay Ag2O/NH3) thu c 21,6 gam Ag. Hai ancol l: A. Etanol v Propan -1-ol C. Metanol v etanol B. Metanol v Propan -1-ol D. Etanol v Propan -2-ol

Cu 39: t chy hon ton hn hp M gm 2 ru (ancol) X v Y ng ng k tip nhau, thu c 0,3mol CO2 v 0,425 mol H2O. Mt khc, cho 0,25 mol hn hp M tc dng vi Na (d), thu c cha n 0,15 mol H2. Cng thc phn t ca X, Y l: A. C2H6O v C3H8O B. C2H6O v CH4O C. C2H6O2 v C3H8O2 D. C3H6O v C4H8O Cu 40: t chy hon ton 0,1 mol hn hp gm CH4, C2H4, C4H10 thu c 0,14 mol CO2 v 0,23 mol H2O. S mol ca ankan v anken trong hn hp ln lt l: A. 0,09 v 0,01 B. 0,08 v 0,02 C. 0,02 v 0,08 D. 0,01 v 0,09

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II. PHN RING. Th sinh ch c lm mt trong hai phn (phn A hoc phn B). A. Theo chng trnh chun (10 cu, t cu 41 n cu 50). Cu 41: Phn bit 3 dung dch: H2N - CH2 - COOH, CH3COOH v C2H5NH2 ch cn dng mt thuc th l: A. Natri kim loi B. Dung dch HCl C. Qu tm D. Dung dch NaOH Cu 42: Ha tan hon ton 14,8 gam hn hp kim loi Fe v Cu vo lng d dung dch hn hp HNO3 v H2SO4 m c, nng. Sau phn ng thu c 10,08 lt kh NO2 v 2,24 lt SO2 (ktc). Khi lng Fe trong hn hp ban u l: A. 5,6 gam B. 8,4 gam C. 18 gam D. 18,2 gam. Cu 43: Trn hn hp ancol metylic v ancol etylic, ri tin hnh un nng c mt axit H2SO4 m c, thu c ti a s sn phm hu c l: A. 4 B. 5 C. 7 D. 6 Cu 44: Trung ha 6,72 gam axit cacboxylic X cn 16,95 ml dung dch NaOH 22,4% (d = 1,18 g/ml). Cng thc cu to ca X l: A. C2H5COOH D. CH3 - CH - COOH CH3 Cu 45: A l dung dch HNO3 c pH = 1. Pha long A 40 ln c dung dch B. pH ca dung dch B l: A. 2,602 B. 3,204 C. 4,806 D. 1,206 Cu 46: Ha tan hon ton 28 gam Fe vo dung dch AgNO3 d th khi lng cht rn thu c l: A. 108 gam B. 162 gam C. 216 gam D. 154 gam Cu 47: Cho 22,72 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 phn ng ht vi dung dch HNO3 long d thu c V lt kh NO (duy nht ktc) v dung dch X. C cn dung dch X thu c 77,44 gam mui khan. Gi tr ca V l: A. 2,688 B. 2,24 C. 4,48 D. 5,6 Cu 48: Dy gm cc kim loi u tc dng c vi dung dch FeCl3 l: A. Fe, Mg, Cu, Ag, Al B. Fe, Zn, Cu, Al, Mg C. Cu, Ag, Au, Mg, Fe D. Au, Cu, Al, Mg, Zn Cu 49: Trong cng nghip, sn xut gng soi v rut phch nc, ngi ta s dng phn ng? A. Dung dch Glucoz tc dng vi dung dch AgNO3 trong NH3. B. Axetilen tc dng vi dung dch AgNO3 trong NH3. C. Anehit fomic tc dng vi dung dch AgNO3 trong NH3. D. Dung dch Sacaroz tc dng vi dung dch AgNO3 trong NH3. Cu 50: Hai cht CH3 - CHO v CH3 - CO - CH3 u tc dng c vi: A. H2 (xc tc Ni) B. Nc brom C. Dung dch AgNO3/NH3 B. CH3COOH C. CH3 - CH2 - CH2COOH

D. Cu(OH)2

B. Theo chng trnh nng cao (10 cu, t cu 51 n cu 60). Cu 51: T 3 -aminoaxit X, Y, Z c th to thnh my tripeptit trong c c X, Y, Z? A. 2 B. 3 C. 4 D. 6 Cu 52: Hn hp X gm hai axit no: A1 v A2. t chy hon ton 0,3 mol X thu c 11,2 lt kh CO2 (ktc). trung ha 0,3 mol X cn 500 ml dung dch NaOH 1M. Cng thc cu to ph hp ca hai axit l: A. CH3COOH v C2H5COOH C. HCOOH v HOOC - COOH A. +1; +2; +3 B. +2, +3, +6 B. HCOOH v C2H5COOH D. CH3COOH v HOOC - CH2 - COOH C. +2, +4, +6 D. +1, +3, +5

Cu 53: Trong cc hp cht, nguyn t Crom c cc s oxi ha ph bin l:

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Cu 54: Cho Eo Ni2+/Ni = -0,26V; Eo Ag+/Ag = + 0,80V. Sut in ng chun ca pin in ha l: A. 0,54 V B. 1,43 V C. 1,86V D. 1,06V Cu 55: Hiro ha 3 gam hn hp X gm 2 anehit no, n chc k tip nhau trong dy ng ng thu c 3,16 gam, hn hp Y gm 2 ancol v 2 anehit d. Hai anehit l: A. HCHO v CH3CHO B. CH3CHO v C2H5CHO C. C2H5CHO v C3H7CHO D. C3H7CHO v C4H9CHO Cu 56: Nhn nh no sau y khng ng? A. Gi tr Ka ca mt axit ph thuc vo nhit . B. Gi tr Ka ca mt axit ph thuc vo bn cht axit. C. Gi tr Ka ca mt axit ph thuc vo nng axit. D. Gi tr Ka ca mt axit cng ln th lc axit cng mnh. Cu 57: Trong phn t amiloz cc mt xch glucoz lin kt vi nhau bng cc lin kt no sau y? A. -1,6 - glicozit B. -1,4-glicozit C. -1,6-glicozit D. -1,4-glicozit Cu 58: Ly 1,66 gam hn hp A gm hai cht X v Y k tip nhau trong dy ng ng ankanol, cho tc dng ht vi natri. Sau phn ng thu c hn hp B c khi lng tng 0,66 gam so vi hn hp A ban u. Mt khc khi em oxi ha X, Y bng CuO un nng th Y cho sn phm khng c phn ng trng gng. Cng thc cu to ca X v Y ln lt l: A. CH3CH2OH , CH3CH2CH2OH B. CH3CH2OH, CH3CH(OH)CH3 C. CH3CH(OH)CH3 , CH3CH2CH(OH)CH3 D. CH3CH2CH2OH , CH3CH2CH(OH)CH3 Cu 59: Cho kim loi M tc dng vi Cl2 c mui X, cho kim loi M tc dng vi dung dch HCl c mui Y. Nu cho kim loi M tc dng vi dung dch mui X ta cng c mui Y. Kim loi M c th l: A. Mg B. Zn C. Al D. Fe Cu 60: Ha tan hon ton hn hp gm 0,12 mol FeS2 v a mol Cu2S vo axit nitric (va ) thu c dung dch X (ch cha hai mui sunfat) v kh duy nht NO. Gi tr ca a l: A. 0,04 B. 0,075 C. 0,12 D. 0,06.

(Th sinh khng c s dng bng tun hon, gim th khng gii thch g thm). ------------------- Ht -------------------

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TRNG THPT HNG KH- H TNH.

P N THI TH I HC - CAO NG LN 1 NM HC 2009 - 2010 - MN HA HC M 142 C 31 C 32 C 33 B 34 A 35 A 36 A 37 A 38 B 39 D 40

1 2 3 4 5 6 7 8 9 10

C B C B C C A A D D

11 12 13 14 15 16 17 18 19 20

C C A C C D D D B D

21 22 23 24 25 26 27 28 29 30

A D B A C C A D A A

41 42 43 44 45 46 47 48 49 50

C B A B A B A B A A

51 52 53 54 55 56 57 58 59 60

D C B D A C B B D D

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