TRNG THPT QUNG XNG 3

THI TH I HC, CAO NG LN 1 NM HC 2009-2010 Mn thi: HO HC

Thi gian lm bi: 90 pht ( thi c 4 trang) M thi: 657 Cho bit: H=1; C=12; N=14; O=16; Na=23; Mg=24; Al=27; S=32; Cl=35,5; K=39; Ca=40; Cu=64; Br=80; Ag=108; Ba=137 PHN CHUNG CHO TT C TH SINH (40 cu, t cu 1 n cu 40) 1. Cho m gam oleum H2SO4.3SO3 tan trong 200 gam H2O c dung dch H2SO4 15%. Tnh m? A. 29,71 B. 31,1 C. 19,36 D. 28,2 2+ 2. Cho dy cht v ion: Al, Cl2, P, Fe3O4, S, SO2, HCl, Fe . S cht v ion va c tnh kh, va c tnh oxi ho l: A. 6 B. 5 C. 7 D. 8 3. Ho tan hon ton mt oxt kim loi M ho tr II khng i bng lng va dung dch H2SO4 24,5% thu c dung dch mui tng ng c nng 33,47%. Kim loi M l: A. Ni B. Ca C. Mg D. Zn 4. Thu phn hon ton 44,5 gam triglixerit X bng lng va 100 ml dung dch KOH 1,5M. Tnh khi lng x phng thu c? A. 48,3 gam B. 52,9 gam C. 38,6 gam D. 39,1 gam 5. Trn 100 ml dung dch gm HCl 0,1M v H2SO4 xM vi 100 ml dung dch hn hp gm KOH 0,1M v Ba(OH)2 0,2M c dung dch X c pH=1. Gi tr ca x l: A. 0,3 B. 0,1 C. 0,2 D. 0,5 6. T glucoz vi cc cht v c, xc tc, thit b c , qua 2 phng trnh phn ng c th iu ch c nhng cht no sau y? A. CH3CHO, C2H4, CH2=CH-CH=CH2 B. CH3CHO, CH3COOH, CH2=CH-CH3 C. CH3COOC2H5, CH3COOH, C2H4 D. CH3COOH, CH2=CH-CH=CH2, (CH3)2O 7. Sn phm ca phn ng este ho gia anhirit axetic v phenol c tn l: A. phenyl axetat B. phenyl fomat C. benzyl fomat D. benzyl axetat 8. Hy cho bit polime no sau y c to ra t phn ng trng hp? A. t tm B. t nilon-6,6 C. t Lapsan D. t capron 9. Este X c cng thc phn t C5H10O2. un nng X vi dung dch NaOH thu c mui Y v ancol Z, trong MY<MZ. X c bao nhiu cng thc cu to ph hp? A. 3 B. 4 C. 6 D. 5 10. Ho tan hon ton a gam hn hp gm K v Ba c s mol bng nhau vo nc thu c 900 ml dung dch Y c pH = 13. Cho dung dch Y tc dng vi 125 ml dung dch AlCl3 0,2M sau phn ng thu c b gam kt ta. Gi tr ca a v b tng ng l: A. 5,28 v 0,975 B. 7,2 v 0,78 C. 5,28 v 0,78 D. 8 v 0,975 11. S so snh no sau y ng vi chiu tng dn tnh baz ca cc amin? A. etyl amin<imetyl amin< etyl metyl amin B. imetyl amin<etyl amin< etyl metyl amin C. etyl metyl amin< etyl amin<imetyl amin D. imetyl amin< etyl metyl amin<etyl amin 12. Khng nh no sau y ng: (1) ng c th tan trong dung dch HCl c mt oxi (2) hn hp Cu v Fe2O3 c s mol bng nhau s tan ht c trong dung dch HCl (3) dung dch AgNO3 khng tc dng vi Fe(NO3)2 A. (2) v (3) B. ch c (2) C. (1) v (3) D. (1) v (2) 13. Mt axit hu c n chc X phn ng va vi 91,2 gam dung dch NaHCO3, sau phn ng thu c 2,24 lt kh CO2 (ktc) v dung dch mui c nng 10%. Tm cng thc ca X? A. CH2=CH-COOH B. HCOOH C. CH3COOH D. CH2=C(CH3)-COOH 14. Cho cc cht sau: axetilen, etilen, benzen, buta-1,3-ien, vinyl benzen. C my cht trong s trn tc dng c vi dung dch nc brom? 1 Hoa 657 10/17/2005

A. 2 B. 4 C. 3 D. 5 15. Khng nh no sau y khng ng: A. dung dch lng trng trng phn ng vi Cu(OH)2 cho sn phm mu tm c trng. B. dung dch lng trng trng to kt ta vng khi phn ng vi HNO3 c. C. ipeptit phn ng vi Cu(OH)2 cho sn phm mu tm c trng. D. anilin to kt ta trng khi phn ng vi dung dch nc brom 16. Cho cu hnh electron ca mt s nguyn t l: [Ar]4s1(1), [Ar]3d104s1 (2), [Ar]3d54s1 (3), [Ar]3d104s2 (4). Nguyn t s l: A. (1), (2) v (3) B. (1) v (2) C. (1), (2), (3) v (4) D. (1) 17. un nng cht hu c X n chc mch h trong dung dch NaOH thu c 1 mui v 1 anehit. t chy hon ton cht X c CO2 v H2O theo t l mol tng ng l 4:3. Hi X c bao nhiu ng phn cu to ph hp? A. 2 B. 4 C. 1 D. 3 18. Cht X khng tc dng vi Na, khi thu phn X thu c axit aipic v ancol metylic. Hi t chy hon ton 1 mol X cn dng bao nhiu mol O2? A. 8,5 B. 9,5 C. 9,0 D. 10,5 19. Cho cc cht sau: CH3NH3Cl, CH3CH(NH2)COOH, HOOC-CH2-CH2-CH(NH2)-COOH, CH3CH(NH2)COONa, CH3CH(NH3Cl)COOH. C my cht trong s trn m dung dch ca chng c pH<7? A. 4 B. 2 C. 5 D. 3 20. Ho tan hon ton 4,2 gam Mg bng dung dch HNO3 long (va ) thu c dung dch X v 0,896 lt hn hp kh Y (ktc) gm 2 kh NO v N2O c t khi so vi H2 l 20,25. Lm bay hi dung dch sau phn ng thu c m gam mui khan. Tnh m? A. 13,35 B. 26,7 C. 27,6 D. 25,9 21. Hn hp X gm 2 cht hu c n chc. Cho X phn ng va vi 400 ml dung dch KOH 1M thu c hn hp gm 2 mui ca 2 axit cacboxylic v 1 ancol. Cho ton b lng ancol tc dng vi Na d sinh ra 2,24 lit kh H2 (ktc). Vy hn hp X gm: A. 1 este v 1 ancol B. 1 axit v 1 este C. 1 axit v 1 ancol D. 2 este 22. Thu phn hon ton m gam hn hp gm saccaroz v mantoz trong mi trng axit un nng, trung ho axit sau cho tc dng vi lng d dung dch AgNO3/NH3 thu c 43,2 gam Ag. Tnh m? A. 18,0 B. 36,0 C. 17,1 D. 34,2 23. Cho phn t cc cht: O3, C2H2, N2, SO3. Theo thuyt bt t, cht c lin kt ba trong phn t l: A. N2, O3, SO3 B. N2, C2H2 C. N2, C2H2, SO3 D. N2, C2H2, O3 24. Mt dung dch cha cc ion: a mol K+; 0,9 mol NH4+; 0,5 mol CO32-; 0,3 mol HCO3-. Cho 0,6 mol Ba(OH)2 vo dung dch X v un nng nh, sau phn ng hon ton thu c dung dch Y, kt ta Z v kh T. S mol cht tan trong dung dch Y l: A. 0,3 mol KOH B. 0,2 mol K2CO3 C. 0,4 mol KOH D. 0,3 mol KHCO3 25. Cho cht hu c X c cng thc phn t C4H6O4 tc dng vi dung dch NaOH un nng theo phn ng: C4H6O4 + 2NaOH 2Z + Y. oxi ho ht a mol Y cn 2a mol CuO (t0) thu c cht T(Z, Y, T l cc cht hu c). Phn t khi ca T l: A. 62 B. 44 C. 58 D. 82 26. Cho 21,6 gam hn hp gm Fe, FeO, Fe2O3 v Fe3O4 tan hon ton trong dung dch HNO3 long d thu c dung dch A v 2,24 lt kh NO l sn phm kh duy nht (ktc). Dung dch A ho tan c ti a 16,8 gam Fe (sn phm kh vn l NO). S mol HNO3 c trong dung dch ban u l: A. 1,0 B. 1,3 C. 0,9 D. 1,4 27. Cho cc cht v ion sau: HCO3-, HSO3-, Al2O3, ZnO, SO2, Fe2+, (NH4)2CO3, Al. S cht v ion lng tnh l: A. 8 B. 6 C. 7 D. 5 28. Cho cc cht sau: anilin(1), metyl phenyl amin (2), benzyl amin (3), p-metylanilin(4). Nhng cht tc dng vi dung dch Br2 to ra kt ta trng l: A. (1), (3), (4) B. (2), (3), (4) C. (1), (2), (4) D. (1), (2), (3) 29. Cho kh Cl2 tc dng vi dung dch NaOH un nng, sn phm thu c l: A. NaCl, NaClO, H2O B. NaCl, NaClO2, H2O C. NaClO2, NaClO3, H2O D. NaCl, NaClO3, H2O 2 Hoa 657 10/17/2005

30. Cho dung dch cc cht khng mu, ng trong cc l ng ring bit mt nhn gm: K2CO3, KHCO3, NaOH, BaCl2, H2SO4, Na2SO4. nhn ra cc dung dch trn m ch dng thm 1 thuc th, ta dng: A. dd BaCl2 B. dd Ba(OH)2 C. qu tm D. dd HCl 31. Ho tan hon ton 13,92 gam mt oxt st bng dung dch HNO3 long thu c dung dch X v 0,448 lt kh NO duy nht (ktc). Khi lng mui st trong dung dch X l: A. 43,56 gam B. 130,68 gam C. 21,78 gam D. 14,52 gam 32. Ho tan ht 23,2 gam Fe3O4 bng dung dch H2SO4 long d thu c dung dch A. Dung dch A phn ng va vi dung dch c x mol KMnO4. Tnh x? A. 0,02 B. 0,01 C. 0,03 D. 0,04 t0 33. Cho phn ng: CuS + H2SO4 CuSO4 + SO2 + H2O. T l s mol H2SO4 to mui v H2SO4 to kh l: A. 4:1 B. 1:5 C. 1:4 D. 1:3
Cl 2 , 500 C NaOH 34. Cho s phn ng: X ancol anlylic. Hi X l cht no sau y? Y A. propan B. xiclopropan C. propin D. propen 35. Cho x gam hn hp cc ng phn ankin ca C4H6 qua dung dch AgNO3/NH3 d, sau phn ng c 3,36 lt mt cht kh thot ra (ktc) v thu c 16,1 gam kt ta. Tnh x? A. 28 B. 14 C. 13,5 D. 27 36. Cho cc kim loi: Fe, Ni, Cu, Ag v cc dung dch HCl, FeCl2, FeCl3, CuCl2. S phn ng xy ra khi cho tng kim loi vo tng dung dch l: A. 7 B. 6 C. 5 D. 8 37. Cho dung dch cc cht sau: glucoz, axit fomic, fructoz, glixerol, natrifomat. C my dung dch trong s trn tham gia phn ng trng gng? A. 3 B. 4 C. 2 D. 5 38. Cho m gam bt Al vo 500 ml dung dch Fe2(SO4)3 0,3M v CuSO4 0,6M. Sau phn ng hon ton thu c 27,6 gam hn hp 2 kim loi. Tnh m? A. 5,4 B. 8,1 C. 10,8 D. 9,45 39. Khi in phn dung dch CuSO4. Ti catot xy ra: A. s kh cc ion Cu2+ B. s kh cc phn t H2O C. s oxi ho cc phn t H2O D. s oxi ho cc ion Cu2+ 40. Trong cc trng hp sau: a. l nung c lm bng gang, lun nung nhit cao b. hp kim Fe-C trong khng kh m c. cho ming Fe kim loi vo dung dch CuCl2 d. hp kim Fe-Cu c nhng trong dunng dch H2SO4 long. S trng hp xy ra s n mn in ho v ho hc tng ng l: A. 3 v 1 B. 1 v 3 C. 2 v 1 D. 2 v 2
0

PHN RING (10 cu): Th sinh ch c lm 1 trong 2 phn: phn I hoc phn II Phn I. Theo chng trnh NNG CAO 41. Ho tan ht 7,68 gam Cu v 9,6 gam CuO cn ti thiu th tch dung dch hn hp HCl 1M v NaNO3 0,1M (vi sn phm kh duy nht l kh NO) l: A. 80 ml B. 56 ml C. 800 ml D. 560 ml 42. Kh SO2 c, trnh kh SO2 thot ra ngoi khng kh (khi lm th nghim Cu tc dng vi H2SO4 c, nng) ta nt ng nghim bng bng tm dung dch no sau y? A. H2SO4 B. HCl C. NaOH D. Br2 43. Dy no sau y c xp theo chiu gim dn tnh oxi ho: A. Fe3+>Cl2>Cu2+>Fe2+ B. Cl2>Fe3+>Cu2+>Fe2+ C. Cl2>Cu2+>Fe2+>Fe3+ D. Cu2+>Fe2+>Cl2>Fe3+ 44. Dy gm cc cht tan trong nc, dung dch c pH>7 l: A. NaOH, KOH, NH3, NaCl, BaCl2 B. NaOH, K2CO3, K[Al(OH)4 ], Na2SO4 C. NaHCO3, K[Al(OH)4 ], NH3, Na2S, Na3PO4 D. KOH, NaOH, Ba(OH)2, CuCl2, Na2CO3 45. Cht no sau y khi thu phn trong dung dch NaOH un nng cho sn phm l anehit? A. CH3-CCl2-CH3 B. CH2=CH-CH2Cl C. CH3-CHCl-CH2Cl D. CH3CH2CHCl2 3 Hoa 657 10/17/2005

46. Cho 0,1 mol alanin phn ng vi 100 ml dung dch HCl 1,5M thu c dung dch A. Cho A tc dng va vi dung dch NaOH thu c dung dch B, lm bay hi dung dch B thu c bao nhiu gam cht rn khan? A. 14,025 gam B. 19,875 gam C. 11,10 gam D. 8,775 gam 47. Ho tan hon ton m gam hn hp bt cc kim loi gm Al, Fe, Cu, Ag trong dung dch HNO3 d thu c dung dch X. Cho t t dung dch NH3 n d vo dung dch X thu c kt ta Y, nung Y trong khng kh ri cho cht rn tc dng vi kh CO d, sau phn ng hon ton thu c hn hp Z, Z gm: A. Al, Fe, Cu, Ag B. Al, Fe C. Al2O3, Fe D. Al2O3, FeO 48. Cc dung dch sau: glucoz, mantoz, saccaroz, fructoz c tnh cht chung no sau y? A. thu phn hon ton cho sn phm l glucoz B. un nng vi Cu(OH)2 cho kt ta mu gch C. un nng vi AgNO3/NH3 cho kt ta bc D. ho tan Cu(OH)2 cho dung dch mu xanh lam 49. Oxi ho ancol metylic vi hiu sut H% bng CuO thu hn hp A gm H2O, ancol d v anehit. Chia A lm 2 phn bng nhau. Phn 1 tc dng vi Na d thu c 0,224 lt kh (ktc), phn 2 tc dng vi AgNO3 d/NH3 thu c 6,912 gam Ag. Tnh H? A. 60 B. 70 C. 80 D. 75 50. 7,2 gam mt axit cacboxylic X phn ng va vi 160 ml dung dch KOH 1M. Tn ca X l: A. axit oxalic B. axit propanioic C. axit axetic D. axit fomic Phn II. Theo chng trnh CHUN 41. Bit th in cc chun ca Cu2+/Cu l 0,34V, sut in ng chun ca pin Cr-Cu l 1,08V. Tnh th in cc chun ca Cr3+/Cr? A. -1,42V B. 1,42V C. -0,74V D. 0,74V HCl 42. Cho s phn ng: Glixin A NaOHdu B . Cht B l: A. CH2(NH3Cl)-COONa B. H2N-CH(CH3)-COOH C. H2N-CH2-COONa D. H2N-CH(CH3)-COONa 43. Mt loi nc thi cha cc ion kim loi nng Cu2+, Pb2+. tch b cc ion kim loi nng trn ra khi nc thi ta dng: A. dung dch Na2SO4 B. dung dch nc vi C. dung dch H2SO4 D. dung dch HCl 44. Trng hp no sau y este b thu phn to ra 2 sn phm u c phn ng trng gng? A. HCOOC(CH3)=CH2 B. CH3COOCH=CH2 C. HCOOCH=CH-CH3 D. HCOOCH2-CH=CH2 45. Cho 16,6 gam hn hp 2 axit n chc tc dng va vi 200 ml dung dch hn hp gm NaOH 0,5M v Ba(OH)2 0,5M. C cn dung dch sau phn ng thu c bao nhiu gam mui khan? A. 36,85 gam B. 23,2 gam C. 37,7 gam D. 32,3 gam 46. Cho 6 gam hn hp gm axit axetic v ancol propylic tc dng vi Na d thu c V lt kh H2 (ktc), tnh V? A. 3,36 lit B. 1,12 lit C. 2,24 lit D. 0,56 lit 47. Cho hn hp dng bt gm 16 gam Fe2O3 v 6,4 gam Cu tan trong dung dch HCl va thu c dung dch X. Cho AgNO3 d vo dung dch X thu c m gam kt ta. Tnh m? A. 21,6 gam B. 86,1 gam C. 107,7 gam D. 129,6 gam 48. Ho tan hon ton 2,28 gam hn hp gm Fe, Cu, Ag c s mol bng nhau bng lng d dung dch HNO3 thu c dung dch A. Sc kh NH3 n d vo dung dch A thu c m gam kt ta. Tnh m? A. 4,10 gam B. 2,05 gam C. 2,14 gam D. 1,07 gam 49. Ln men 162 gam tinh bt vi hiu sut cc qu trnh ln men ln lt l 80% v 90%. Tnh th tch dung dch ru 400 thu c? Bit khi lng ring ca C2H5OH nguyn cht l 0,8 g/ml A. 230ml B. 115 ml C. 207 ml D. 82,8 ml 50. Trng hp no sau y cc ion tn ti ng thi trong cng mt dung dch? A. Al3+, Cl-, SO42-, Mg2+ B. Ba2+, HSO4-, Ca2+, HCO32+ + C. HCO3 , OH , Ba , K D. HCO3-, HSO4-, Na+, Cl------------------------------------------ The end -------------------------------------------------

4 Hoa 657 10/17/2005

O STT M thi 655 p n ng (Cu 1 n 40):C D C C D A C D B D B D A A A B D B A A D B D A B D A A A D C D B A D BACAA (Cu 41 n 50 nng cao):B A A C C B D B B A (Cu 41 n 50 chun):B A A C C B D B B A (Cu 1 n 40):D A A A B D C C A C B B C A A A D A D D A D D C B A C B B D B C B C A BBADA (Cu 41 n 50 nng cao):D B C A D C C C C D (Cu 41 n 50 chun):D B C A D C C C C D (Cu 1 n 40):A C D A A A A D B C A D A B C D A B D B B D B B C D D C D C A A D D C ABCAA (Cu 41 n 50 nng cao):C C B C D B C D C A (Cu 41 n 50 chun):C C B C D B C D C A (Cu 1 n 40):A B A D A B D B A C B A C B D C B D B B B D D A D B D C C B B C B D C ABACD (Cu 41 n 50 nng cao):C D D D D D A D D D (Cu 41 n 50 chun):C D D D D D A D D D

656

657

658

5 Hoa 657 10/17/2005