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QC
S GIO DC & O TO H NI

K THI CHN HC SINH GII THNH PH LP 12 Nm hoc 2012 - 2013 Ngy thi: 15 -10 -2012 Thi gian lm bi: 180 pht ____(e th gm 2 trang) ____

CHNH THC

Cu I ( 2,0 im). 1/ Hp cht M to bi cation x+ v anion Y3', c hai ion u do 5 nguyn t ca hai nguyn t to nn. Trong ion x+ cha nguyn t A c s oxi ha l -a, B l mt nguyn t c s oxi ha cao nht trong ion Y3'. Trong cc hp cht, cc nguyn t A v B u c s
oxi ha cao nht l +(a+2). Phn t khi ca M bng 149, trong Mr' > 5 Hy tm
M\

cng thc phn t ca hp cht M. 2/ Tin hnh phn ng thun nghch trong bnh kn dung tch 1 lt CO(k) + Cl2(k) COCl2(k) nhit khng i, nng cn bng ca cc cht l: [CO] = 0.02 mol/1; [Cb]=0,01 mol/1; [COC2]=0,02 mol/1. Bm thm vo bnh 0,03 mol C2 v gi nhit khng i, sau mt thi gian, phn ng t trng thi cn bng mi. Tnh nng cc cht trng thi cn bng mi. Cu n (3,5 im): 1/ Cho s phn ng:
KCIO3 (Xi) clorua vi CaCCb KX2) Ca(N3)2

(X3) (Yi) lu hunh

.(Y2)> (YI) -KY3)-*Na2S04 -KY4)-^ (Ys) - PbS

(Y) (Y2) (Y3)( Y1) K2 s O4 (Y 7) Pb s Bit cc cht Xi,X2,X3 c phn t khi tha mn X1+X2+X3 = 214;

cc cht Yi, Y2, Y3, Y4, Y5, Y, Y7 l cc hp cht khc nhau ca lu hunh v c phn t khi tha mn cc iu kin: Yi+Y7=174; Y2+Y5=112; Y3+Y4=154; Y5+Y6=166; mi mi tn tng ng vi mt phng trnh ha hc. Vit cc phng trnh ha hc theo s phn ng. 2/ Supephotphat n c iu ch t mt loi bt qung c cha 73% Ca3(P4)2, 26% CaCCb v 1% S1O2. Supephotphat n thu c gm nhng cht no? Tnh t l % P2O5 trong loi supephotphat n trn. Cu m (3,25 im) 1/ Dung dch X gm cc mui NaCl, FeC3, AICI3, NH4CI v C11CI2 ( nng mi cht xp x 0,1M). a)Dung dch X c mi trng axit, baz hay trung tnh? Ti sao? b)Cho H2S li chm qua dung dch X cho n d, lc tch kt ta thu c dung dch Y. Hy cho bit thnh phn cc cht trong kt ta v trong dung dch Y. c)Thm t t n d dung dch KOH vo dung dch Y trong iu kin khng c oxi, thu c cht kt ta. Xc nh thnh phn cht kt ta. d)Thm t t n d dung dch NH3 vo dung dch X. Vit phng trnh ha hc xy ta dng ion.

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2/ Chia 1,6 lt dung dch X cha NaOH nng a mol/lt v Ba(OH )2 0,3M lm 2 phn bng nhau: Phn 1 em tc dng vi 200ml dung dch Y cha H2SO4 0,375M v A1C3

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