BI TP ANKYLBENZEN

Bi tp l thuyt.
- CTTQ, ng phn, danh
Cu 1/ Trong phn t benzen:
a. 6 nguyn t H v 6 C u nm trn 1 mt phng.
b. 6 nguyn t H nm trn cng 1 mt phng khc vi mp ca 6 C
c. Ch c 6 C nm trong cng 1 mt phng.*
d. Ch c 6 H nm trong cng 1 mt phng.
Cu 2/ Cho cc CT :
H

(1)
(2)
(3)
Cu to no l ca benzen:
a.(1) v (2)
c.(2) v (3)
b.(1) v (3)
d.(1) ; (2) v (3)*
Cu 3/ Dy ng ng ca benzen c cng thc chung l:
a.CnH2n+6 ; n6
c. CnH2n-6 ; n6
b. CnH2n-6 ; n3
d. CnH2n-6 ; n6*
Cu 4/ Cho cc cht C6H5CH3 (1) p-CH3C6H4C2H5 (2)
C6H5C2H3 (3) o-CH3C6H4CH3 (4)
Dy gm cc cht l ng ng ca benzen l:
a.(1);(2) v (3)
c.(1);(3) v (4)*
b.(2);(3) v (4)
d.(1);(2) v (4)
Cu 5/ Cho cu to sau:C tn gi g sau y:
CH3

CH3

a.o-xilen
c.p-xilen
b.m-xilen*
d.1,5-imetylbenzen
Cu 6/ CH3C6H2C2H5 c tn gi l:
a.etyl,metylbenzen
c.p-etyl,metylbenzen*
b. metyl,etylbenzen
d.p-metyl,etylbenzen
Cu 7/ (CH3)2CHC6H5 c tn gi l:
a.propylbenzen
c.i-propylbenzen*
b.n-propylbenzen
d.imetylbenzen
Cu 8/ Ankylbenzen l HC c cha :
a.vng benzen
c.gc ankyl v 1 benzen
b.gc ankyl v vng benzen
d.gc ankyl v 1 vng benzen
Cu 9/ iu no sau u khng ng kh ni v 2 v tr trn 1 vng benzen:
a. v tr 1,2 gi l ortho
c. 1,3-meta
b. 1,4-para
d. 1,5-ortho*
Cu 10/ Mt ankylbenzen A (C12H18)cu to c tnh i xng cao.A l:
a.1,3,5-tri etylbenzen
c. 1,2,3-tri metylbenzen
b. 1,2,4-tri etylbenzen
d. 1,2,3,4,5,6-hexametylbenzen*
Cu 11. C7H8 c s ng phn thm l:
a.1*
b.2
c.3
d.4
Cu 12. A l ng ng ca benzen c cng thc nguyn l: (C3H4)n. Cng thc phn t ca A l:
a.C3H4
b.C6H8
c.C9H12*
d.C12H16
Cu 13. ng vi cng thc C9H12 c bao nhiu ng phn c cu to cha vng benzen?
a.6
b.7
c.8*
d.9

Cu 14/ Cht no sau y c th cha vng benzen:

a.C10H16
b. C9H14BrCl
Cu 15/ Cu to ca 4-cloetylbenzen l:

c. C8H6Cl2*

d. C7H12

C2H5

C2H5

C2H5

C2H5
Cl

Cl
a.
b.
c.
d.
Cu 16/ ng vi cng thc phn t C8H10 c bao nhiu cu to cha vng benzen?
a.2
b.3*
c.4
d.5
Cu 17/ Cht no sau y khng th cha vng benzen
a.C8H10
b. C6H8*
c. C8H10
d. C9H12
Cu 18/ Gc C6H5-CH2- c tn gi l:
a.Phenyl
b.Vinyl
c.anlyl
d.benzyl*
Cu 19/ Cho cc cht (1)benzen ; (2) toluen; (3)xiclohexan;(4)hex-5-trien; (5)xilen;(6) Cumen
Dy gm cc HC thm l:
a.(1);(2);(3);(4)
c. (2);(3);(5) ;(6)
b. (1);(2);(5;(6)*
d. (1);(5);(6);(4)
Cu 20/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi stiren ,gi tr ca n v a ln lt l:
a. 8 v 5
b.5 v 8
c.8 v 4
d.4 v 8
Cu 21/ Cng thc tng qut ca hirocacbon CnH2n+2-2a.i vi naptalen ,gi tr ca n v a ln lt l:
a.10 v 5
b.10 v 6
c.10 v 7*
d.10 v 8
Cl

Cl

- Tnh cht vt l
Cu 22. Tnh cht no sau y khng phi ca ankyl benzen
a.Khng mu sc
c.Khng tan trong nc
b.Khng mi v*
d.Tan nhiu trong cc dung mi hu c
Cu 23. Hot tnh sinh hc ca benzen, toluen l:
a.Gy hi cho sc khe*
c.Gy nh hng tt cho sc khe
b.Khng gy hi cho sc khe
d.C th gy hi hoc khng gy hi
- Tnh cht ho hc
Cu 24. Tnh cht no khng phi ca benzen?
a.Tc dng vi dung dch Br2 (Fe)
c.Tc dng vi dung dch KMnO4*
b.Tc dng vi HNO3 /H2SO4()
d.Tc dng vi Cl2 (as)
Cu 25. Tnh cht no khng phi ca toluen?
a.Tc dng vi dung dch Br2 (Fe)
c.Tc dng vi dung dch KMnO4, t0
b.Tc dng vi Cl2 (as)
d.Tc dng vi dung dch Br2 *
Cu 26. Toluen + Cl2 (as) xy ra phn ng:
a.Cng vo vng benzen
c.Th nhnh, kh khn hn CH4
b.Th vo vng benzen, d dng hn
d.Th nhnh, d dng hn CH4*
Cu 27. Tin hnh th nghim cho nitro benzen tc dng vi HNO3/H2SO4 (), nng ta thy:
a.Khng c phn ng xy ra
b.Phn ng d hn benzen, u tin v tr meta
c.Phn ng kh hn benzen, u tin v tr meta*
d. Phn ng kh hn benzen, u tin v tr ortho
Cu 28. Dy cc nhm th lm cho phn ng th vo vng benzen d dng hn v u tin v tr o- v p- l:
a.-CnH2n+1, -OH, -NH2, *
c.CH3, -NH2, -COOH
b.OCH3, -NH2, -NO2
d.NO2, -COOH, -SO3H
Cu 29. Dy gm cc nhm th lm cho phn ng th vo vng benzen u tin v tr m- l:
a.-CnH2n+1, -OH, -NH2
c.CH3, -NH2, -COOH
b.OCH3, -NH2, -NO2
d.NO2, -COOH, -SO3H*
Cu 30. A l dn xut benzen c cng thc nguyn (CH)n. 1 mol A cng ti a 4 mol H2 hoc 1 mol Br2(dd).
Vy A l:

a.etyl benzen
c.vinyl benzen*
b.metyl benzen
d.ankyl benzen
Cu 31. Tnh cht no khng phi ca benzen?
a.D th
c.Bn vi cht oxi ha
b.Kh cng
d.Km bn vi cc cht oxi ha
xt ,t o
Cu 32. A
toluen + 4H2. Vy A l:
a.metyl xiclo hexan
c.n-hexan
b.metyl xiclo hexen
d.n-heptan
Cu 33. Benzen + X etyl benzen. Vy X l
a.axetilen
b.etilen
c.etyl clorua
d.etan
xt ,t o
Cu 34. C6H6 + Y
etyl benzen + 4 HCl. Vy Y l:
a.CH2ClCH2Cl
c.CH3CH2Cl
b.CH2=CHCl
d.CH2=CH-CH2Cl
Cu 35/ Phn ng chng minh tnh cht no;khng no ca benzen ln lt l:
a.th,cng*
c.chy,cng
b.cng,nitro ho
d.cng,brom ho
Cu 36/ phn bit c cc cht Hex-1-in,Toluen,Benzen ta dng 1 thuc th duy nht l:
a. dd AgNO3/NH3
b.dd Brom
c.dd KMnO4*
d.dd HCl
Cu 37/ D phn bit d dng Hex-1-in,Hex-1-en,benzen ta ch dng 1 thuc th duy nht l:
a. dd Brom *
c.dd [Ag(NH3)2]OH
b. dd AgNO3/NH3
d.dd HCl
Cu 38/ Phn ng Benzen tc dng vi clo to C6H6Cl6 xy ra trong iu kin:
a. c bt Fe xc tc
b.c nh snh khuych tn*
c.c dung mi nc
d.c dung mi CCl4

as
Cu 39/ 1 mol Toluen + 1 mol Cl2 A . A l:
a.C6H5CH2Cl*
c. o-ClC6H4CH3
b. p-ClC6H4CH3
d.B v C u ng
H 2 SO4 d

Cu 40/ 1 mol nitrobenzen + 1 mol HNO3

B + H2O. B l:
to
a.m-initrobenzen
c. p-initrobenzen
b. o-initrobenzen
d.B v C u ng.

Cu 44/ C2H2 A B m-brombenzen .A v B ln lt l:

a.benzen ; nitrobenzen*
c. nitrobenzen ; benzen
b.benzen,brombenzen
d. nitrobenzen; brombenzen
Cu 45/ Phn ng ng trng hp gia stiren v buta-1,3-ien to ra sn phm l:
a.cao su buna
c.cao su buna-S*
b.cao su buna-N
d.cao su isopren
- ng dng, iu ch.
Cu 46. ng dng no benzen khng c:
a.Lm dung mi
c.Lm nhin liu
b.Tng hp monome
d.Dng trc tip lm dc phm
Cu 47. Thuc n TNT c iu ch trc tip t
a.benzen
b.metyl benzen
c.vinyl benzen
d.p-xilen
Cu 48/ Phn ng no sau y khng dng iu ch Benzen:
a.tam hp axetilen
c.kh H2,ng vng n-hexan
b.kh H2 ca xiclohexan
d.tam hp etilen*
Cu 49/ Phn ng no khng iu ch c Toluen?
AlCl3 ;t o
c.kh H2 metylxiclohexan
a.C6H6 + CH3Cl
d.tam hp propin*
b. kh H2,ng vng benzen
Bi tp tnh ton.
Cu 50/ Cho m g HC (A) chy thu c 0,396 g CO2 v 0,108 g H2O.Trng hp 3 phn t A thu c cht B l
ng ng ca benzen.A v B thuc dy no sau?
a.A,B u l ankin
c.A:ankylbenzen;B:ankin
b.A,B u l ankylbenben
d. A:ankin ; B:ankylbenzen*
Cu 51/ A(CxHy) l cht lng iu kin thng c dA/kk l 2,7. A chy mCO2 : mH2O = 4,9 : 1.Cng thc
phn t ca A l:
a. C7H8
b. C6H6*
c. C10H14
d. C9H12
Cu 52/ t chy hon ton m (g) A (CxHy) m g H2O; 150 < MA < 170. Cng thc phn t ca A l:
a.C4H6
b.C8H12
c.C16H24
d.C12H18*
Cu 53/ t chy hon ton a (g) hp cht hu c A ch thu c CO2 v H2O.Trong khi lng H2O bng
a g.Cng thc nguyn ca A l:
a.(CH)n
b.(C2H3)n*
c.(C3H4)n
d.(C4H7)n
Cu 54/ t chy 16,2 g 1 cht hu c (A) thu c 1,2 mol CO2 ; 0,9 mol H2O. 150 < MA < 170.Cng thc
phn t ca A l:
a.C8H10
b.C9H12
c.C10H14
d.C12H18*
Cu 55. t chy hon ton 10,8g mt ankyl benzen A thu c 39,6g CO2. Cng thc phn t ca A l:

a.C6H6
b.C8H8
c.C8H10
d.C9H12
Cu 56. t chy 10,8g A (CxHy) 10,8g H2O. A c cha 1 vng benzen. Cng thc phn t ca A l:
a.C3H4
b.C6H8
c.C9H12
d.C12H16
Cu 57/ Cho benzen vo 1 l ng Cl2 d ri a ra asng .Sau khi phn ng xy ra hon ton thu c 5,82 kg
benzen.Tn ca sn phm v khi lng benzen tham gia phn ng l:
a.clobenzen;1,56kg
c.hexacloran;1,56kg*
b.hexacloxiclohexan;1,65kg
d.hexaclobenzen;6,15kg
Cu 58/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H2O v V (l) CO2 (ktc).Gi tr ca V
l:
a.15,654
b.15,465
c.15,546
d.15,456*
Cu 59/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c 8,1 g H2O v CO2.Dn ton b lng CO2
vo 100ml dd NaOH 1M thu c m g mui.Gi tr ca m v thnh phn ca mui:
a.64,78 g (2 mui)*
c.31,92g(NaHCO3)
b.64,78g (Na2CO3)
d.10,6g (Na2CO3)
Cu 60/ t chy ht 9,18 g 2 ng ng ca benzen A,B thu c H2O v 30,36 g CO2 .Cng thc phn t
ca A v B ln lt l:
a.C8H10 ; C9H14
c. C8H12 ; C9H14
b. C8H10 ; C9H12*
d. C8H14 ; C9H16
Cu 61/ t chy hon ton 12 g cht hu c A , ng ng ca benzen thu c 20,16 lt CO2 (ktc)
Cng thc phn t ca A l:
a. C9H12*
b. C8H10
c. C7H8
d. C10H14
Cu 62/ t chy hon ton m g A ng ng ca benzen thu c 20,16 lt CO2 (ktc) v 10,8 ml H2O
(lng).Cng thc ca A l:
a. C7H8
b. C8H10
c. C9H12*
d. C10H14
Cu 63/ t chy hon ton 0,1 mol CxHy thu c 20,16 lt CO2 (ktc) v 10,8 g H2O (lng).Cng thc ca
CxHy l:
a. C7H8
b. C8H10
c. C10H14
d. C9H12*
Cu 64/ Hiro ho etylbenzen ta c stiren;trng hp stiren ta c polistiren vi hiu sut chung
80%.Khi lng etylbenzen cn dng sn xut 10,4 tn polisitren l:
a.13,52 tn
c.13,25 tn*
b.10,6 tn
d.8,48 tn
Cu 65/ t chy hon ton hi A(CxHy) thu c 8 lt CO2 v cn dng 10,5 lt oxi.Cng thc phn t ca A
l:
a. C7H8
b. C8H10*
c. C10H14
d. C9H12
Cu 66/ t chy hon ton 1,3 g A(CxHy) 0,9 g H2O .Cng thc nguyn ca A l:
a.(CH)n*
b.(C2H3)n
c.(C3H4)n
d.(C4H7)n
Cu 67/ A t 1 hp cht vng c to thnh t s trng hp axetilen,dA/kk l 3,59.C.thc phn t A l:
a. C8H8*
b. C6H6
c. C10H14
d. C4H4
Cu 68/ A c cng thc phn t l C8H8 ,tc dng vi dd KMnO4 nhit thng to ra ancol 2 chc.
1 mol A tc dng ti a vi:
a.4 mol H2; 1 mol brom*
c.3 mol H2; 3 mol brom
b. 3 mol H2; 1 mol brom
d. 4 mol H2; 4 mol brom
Cu 69/ 5,2 g stiren b trng hp 1 phn tc dng va vi dd cha 0,0125 mol brom.Lng stiren cha b
trng hp l:
a.25%
b.50%
c.52%
d.75%*
Cu 70/ 1 ankylbenzen A(C9H12),tc dng vi HNO3 c (c xt H2SO4 ) theo t l mol 1:1 to ra 1 dn xut
mononitro duy nht . Vy A l:
a. n-propylbenzen
c.i-propylbenzen
b.p-etyl,metylbenzen
d.1,3,5-trimetylbenzen*
Cu 71/ Cho A(CxHy) l 1 cht kh kthng .t chy hon ton 1 lng cht A thu c 1 sn phm cha
76,52% CO2 v khi lng.Cng thc phn t ca A l:
a. C2H6
b. C3H6
c. C4H6*
d. C6H6

Cu 72/a.ACl
cht
C3H
kh
c. Clt
* A ktc tc dng va
d. C
0,4 mol
2H1
6 HC mch h , b.
6 iu kin thng .4,48
4H6kh
6Hvi
6
Cu 73/Brom
Cho ato
g cht
ra sn
A(C
phm
chy
chathu
85,562%
c 13,2
brom
g CO
v 2khi
v 3,6
lng.
g H2Cng
O.Tamthc
hpphn
A thu
tc
ca AB,mt
l: ng ng
xHy)B
ca ankyn benzen.Cng thc phn t ca A v B ln lt l:
a.C3H6 v C9H8
b. C2H2 v C6H6
c. C3H4 v C9H12*
d. C9H12 v C3H4
Cu 74/ Mt cht hu c A c mC:mH:mCl = 1,2 : 0.1 : 3,55.Phn t c vng 6 cnh.Vy A l:
a.hexacolran
c.hexaclobenzen
b.hexacloxiclohexan
d.a,b,c u ng
Cu 75/ t 0,13 g mi cht A v B u cng thu c 0,01 mol CO2 v 0,09 g H2O.d A/B l 3; d B/C2H4 l
0,5.Cng thc ca A v B ln lt l:
a.C2H2 v C6H6
b. C6H6 v C2H2*
c. C2H2 v C4H4
d. C6H6 v C8H8
Cu 76/ 1,3 g cht hu c A chy hon ton thu c 4,4 g CO2 v 0,9 g H2O.T khi hi ca A i vi oxi(d)
tho mn iu kin 3<d<3,5.Cng thc phn t ca A l:
a.C2H2
b.C8H8*
c.C4H4
d.C6H6
Cu 77/ Cho 120 t n khng nguyn cht tc dng hon ton vi H2O thu c kh A.Chuyn kh A thnh
benzen vi hiu sut 60%,thu c 26 ml benzen(d=0,9 g/ml)% khi lng tp cht trong t n l:
a.10%
b.20%*
c.30%
d.40%