Cv ada hubungannya Q

Cp = Cv + R
Cp = Cv + 1.99 (BTU/lb mole F)
Cp/Cv = K sangat sering digunakan
pada Adiabatic Process
Untuk ideal gas = PV
K
= constant

Type of Ideal Gas


Cp Cv
Monoatomic 5/2 R 3/2 R
Biatomic 7/2 R 5/2 R
Triatomic 9/2 R 7/2 R
Incompressible Liquid :
dH = Cp dT
dV = Cv dT
Effect Pressure In Specific Heat and
Entalphy
Cp @ P > 1 atm
Cp (P,T) = Cp (14.7 psia, T) + Cp(Pr,Tr)




V = spesific volume (ft
3
/ lb mole)
PV = zRT
P
T
v
T V
p
h
T
|
.
|

\
|
c
c
=
|
|
.
|

\
|
c
c


Jadi :

P P
T
z
P
RT
P
zR
T
V
|
.
|

\
|
c
c
+ =
|
.
|

\
|
c
c
P
2
T
2
T
P T
T
z
P
RT
P
h
P
T
z
P
RT
P
zRT
P
zRT
P
h
T
z
P
RT
P
zR
T
P
zRT
P
h
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
(

|
.
|

\
|
c
c
+ =
|
.
|

\
|
c
c
Bila dirubah Pr dan Tr

( )
( )
( )
Pr
2
Tr
Pr
2
Pr
2
T
Tr
z
Pr
TcTr
986 . 1
Pr
h
Tr
z
Pr
TcTr
2 . 778
144 732 . 10
Tr Tc
z
Pr Pc
TcTr R
Pr Pr
h
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
=
|
.
|

\
|
c
c
Dimana:

| |
( )
( ) BTU / lbf f t 2 . 778
Pc / Psia Pr
Pr mole lb / BTU
Pr
h

c
c
Entrophy (S)
heat in change q : ana dim
T
q
S S S
T
q
S
1 2
= c
|
.
|

\
|
c
= =
|
.
|

\
|
c
=
A A
Hukum Thermodinamika II


Dimana :
S
E
S
B
= entrophy change E B
S
I
= entrophy with all stream the
system
So = entrophy ass with all stream
leaving the system
( ) Sc Sp Tb / Q S S S S
O I B E
+ + =

Tb = temp. @ boundary system
Sp = entrophy production of system
Sc = entrophy change due to
atomic transformation
Q = transfer to or from the system