CU HI V BI TP TRC NGHIM IN PHN Cu 1: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l: ( Trch TSH

A 2009) A. Fe, Cu, Ag. B. Mg, Zn, Cu. C. Al, Fe, Cr. D. Ba, Ag, Au. Cu 2: in phn dung dch cha a mol CuSO4 v b mol NaCl (vi in cc tr, c mng ngn xp). dung dch sau in phn lm phenolphtalein chuyn sang mu hng th iu kin ca a v b l: A. 2b = a. B. b < 2a. C. b = 2a. D. b > 2a. Cu 3: Trong cng nghip, natri hiroxit c sn xut bng phng php: A. in phn dung dch NaCl, khng c mng ngn in cc. B. in phn dung dch NaCl, c mng ngn in cc. C. in phn dung dch NaNO3 , khng c mn ngn in cc. D. in phn NaCl nng chy. Cu 4: Cho cc ion: Na+, Al3+, Ca2+, Cl-, SO42-, NO3-. Cc ion khng b in phn khi trng thi dung dch l: A. Na+, Al3=, SO42- NO3- B. Na+,B. Na+, Al3=, SO42- , Cl-. C. Na+, Al3=, SO42- , Cl-, NO3-. D. Cu2+, Al3=, Cl-, NO3. Cu 5: in phn ( in cc tr, c mng ngn xp) mt dung dch c cha cc cation: Fe2+, Fe3+, Cu2+. Th t xy ra s kh catot l: A. Fe2+, Cu2+, Fe3+. B. Fe3+, Cu2+, Fe2+. C. Fe3+, Fe2+, Cu2+. D. Fe2+, Fe3+,Cu2+. Cu 6: in phn ( in cc tr, c mng ngn xp) mt dung dch c cha cc anion: S2-, SO2-. Th t xy ra s oxi ha anot l: A. S2-, OH-, SO42-. B. S2-, SO42- OH-. C. OH-, S2-, SO42D. OH-, SO42-. S2--. Cu 7: Cho cc dung dch ring bit sau: KCl, NaCl, CaCl2, Na2SO4, ZnSO4, H2SO4, KNO3, AgNO3, NaOH. Dung dch khi in phn thc cht ch l in phn nc l: A. NaOH, NaCl, ZnSO4, KNO3, AgNO3. B. NaOH, Na2SO4, H2SO4, KNO3, CaCl2. C. NaOH, Na2SO4, H2SO4, , KNO3. D. Na2SO4,, KNO3, KCl. Cu 8: Khi in phn dung dch NaCl ( in cc tr, khng c mng ngn xp) th sn phm thu c gm: A. H2, Cl2, NaOH. B. H2, Cl2, nc Javen. C. H2, nc Javen. D. H2,Cl2, NaOH, nc Javen. Cu 9: Cho cc dung dch: KCl, NaCl, CaCl2, Na2SO4, , ZnSO4, H2SO4,, KNO3, AgNO3, NaOH. Sau khi in phn, cc dung dch cho mi trng baz l: A. KCl, KNO3, NaCl, Na2SO4, . B. KCl, NaCl, CaCl2, NaOH. C. NaCl, CaCl2, NaOH, H2SO4, D. NaCl, NaOH, ZnSO4, AgNO3. Cu 10: Pht biu no sau y khng ng? A. Khi in phn cc cht nng chy th catot cc cation kim loi nhn electron. B. Khi in phn cc cht nng chy th anot cc anion nhng electron. C. Khi in phn th trn cc b mt in cc xy ra qu trnh oxi ha kh D. Khi in phn cc dung dch mui trong nc th cc dng b n mn. Cu 11: in phn 200ml dung dch CuSO4 nng x M (in cc tr). Sau mt thi gian th thy khi lng dung dch gim 8 gam v lm kt ta ht ion Cu2+cn d trong dung dch cn dng 100ml dung dch NaOH 0,5 M. Gi tr ca x l: A. 0,5. B. 1,0. C. 1,5. D. Kt qu khc. Cu 12: in phn dung dch cha NaOH 0,01M v dung dch Na2SO4,0,01M. Th tch dung dch trong qu trnh in phn thay i khng ng k. pH ca dung dch sau in phn l: A. 2. B. 8. C. 10. D. 12. Cu 13: in phn 400ml dung dch AgNO3 0,2M v Cu(NO3)2 0,1M ( h= 100%, in cc Pt) vi cng dng in I = 10A. Sau thi gian t giy th ngng in phn, khi lng Cu thot ra bm vo catot l 1,28 gam. Gi tr ca t l: A. 1158. B. 2316. C. 9650. D. 4825. Cu 14: in phn dung dch NaOH vi cng dng in l I = 10A trong thi gian 268 giy. Sau khi in phn cn li 100 gam dung dch NaOH 24%. Nng % ca dung dch NaOH trc khi in phn l: A. 20. B. 25. C. 16. D. Kt qu khc. Cu 15: in phn 500ml dung dch AgNO3 0,1M v Cu(NO3)2 0,2M ( in cc platin) vi cng dng in I = 10 A.Dung dch sau in phn c [H+] = 0,16M.Gi s hiu sut in phn l 100% v th tch dung dch khng thay i. Nng mol ca mui nitrat trong dung dch sau in phn l: A. 0,2M. B. 0,3M. C. 0,1M. D. 0,17M. D.

PIN IN V IN PHN TRONG H & C L THUYT Cu 1: Dy gm cc kim loi c iu ch trong cng nghip bng phng php in phn hp cht nng chy ca chng, l : A. Na, Ca, Al B. Na, Ca, Zn C. Na, Cu, Al D. Fe, Ca, Al Cu 2: Trong pin in ha Zn-Cu, qu trnh kh trong pin l A. Zn Zn2+ + 2e. B. Cu Cu2++ 2e. C. Zn2++ 2e Zn. D. Cu2+ + 2e Cu. Cu 3: Cho cc cp kim loi nguyn cht tip xc trc tip vi nhau: Fe v Pb; Fe v Zn; Fe v Sn; Fe v Ni. Khi nhng cc cp kim loi trn vo dung dch axit, s cp kim lai trong Fe b ph hy trc l: A. 4. B. 1. C. 2 . D. 3. Cu 4: Trong cng nghip, natri hiroxit c sn xut bng phng php A. in phn dung dch NaCl, khng c mng ngn in cc. B. in phn dung dch NaNO3, khng c mng ngn in cc. C. in phn dung dch NaCl, c mng ngn in cc. D. in phn NaCl nng chy. Cu 5: Cho sut in ng chun Eo ca cc pin in ho: Eo(Cu-X) = 0,46V; Eo(Y-Cu) = 1,1V; Eo(Z-Cu) = 0,47V (X, Y, Z l ba kim loi). Dy cc kim loi xp theo chiu tng dn tnh kh t tri sang phi l A. Z, Y, Cu, X. B. X, Cu, Z, Y. C. Y, Z, Cu, X. D. X, Cu, Y, Z. Cu 6(:2008 ) Cho phn ng ha hc: Fe + CuSO4 FeSO4 + Cu. Trong phn ng trn xy ra A. s kh Fe2+ v s oxi ha Cu. B. s kh Fe2+ v s kh Cu2+. C. s oxi ha Fe v s oxi ha Cu. D. s oxi ha Fe v s kh Cu2+. Cu 7: Hai kim loi c th c iu ch bng phng php in phn dung dch l A. Al v Mg. B. Na v Fe. C. Cu v Ag. D. Mg v Zn. Cu 8: Cho bit phn ng oxi ho - kh xy ra trong pin in ho Fe Cu l: Fe + Cu2+ Fe2+ + Cu E0 (Fe2+/Fe) = 0,44 V, E0 (Cu2+/Cu) = + 0,34 V. Sut in ng chun ca pin in ho Fe - Cu l A. 1,66 V. B. 0,10 V . C. 0,78 V. D. 0,92 V. Cu 9: Khi in phn NaCl nng chy (in cc tr), ti catt xy ra A. s kh ion Na+. B. s oxi ho ion Cl-. C. s oxi ho ion Na+. D. s kh ion Cl-. Cu 10: Bit rng ion Pb2+ trong dung dch oxi ha c Sn. Khi nhng hai thanh kim loi Pb v Sn c ni vi nhau bng dy dn in vo mt dung dch cht in li th A. ch c Sn b n mn in ho. B. ch c Pb b n mn in ho. C. c Pb v Sn u khng b n mn in ho. D. c Pb v Sn u b n mn in ho. Cu 11: Tin hnh bn th nghim sau: - Th nghim 1: Nhng thanh Fe vo dung dch FeCl3; - Th nghim 2: Nhng thanh Fe vo dung dch CuSO4; - Th nghim 3: Nhng thanh Cu vo dung dch FeCl3; - Th nghim 4: Cho thanh Fe tip xc vi thanh Cu ri nhng vo dung dch HCl. S trng hp xut hin n mn in ho l A. 1. B. 2. C. 4. D. 3. Cu 12: Cho hn hp bt Al, Fe vo dung dch cha Cu(NO3)2 v AgNO3. Sau khi cc phn ng xy ra hon ton, thu c hn hp rn gm ba kim loi l: A. Fe, Cu, Ag. B. Al, Cu, Ag. C. Al, Fe, Cu. D. Al, Fe, Ag. Cu 13: Cho cc hp kim sau: Cu-Fe (I); Zn Fe (II); Fe-C (III); Sn-Fe (IV). Khi tip xc vi dung dch cht in li th cc hp kim m trong Fe u b n mn trc l: A. I, II v III. B. I, II v IV. C. I, III v IV. D. II, III v IV. Cu 14:(( 2009 - 2010 ) Cho hn hp gm Fe v Zn vo dung dch AgNO3 n khi cc phn ng xy ra hon ton, thu c dung dch X gm hai mui v cht rn Y gm hai kim loi. Hai mui trong X l A. Fe(NO3)2 v AgNO3. B. AgNO3 v Zn(NO3)2. C. Zn(NO3)2 v Fe(NO3)2. D. Fe(NO3)3 v Zn(NO3)2. Cu 16: Dy cc kim loi u c th c iu ch bng phng php in phn dung dch mui ca chng l:A. Ba, Ag, Au. B. Fe, Cu, Ag. C. Al, Fe, Cr. D. Mg, Zn, Cu. Cu 15: C 4 dung dic h ring bi : CuSO4, ZnCl2, FeCl3, AgNO3. Nhng vo mi dung dch mt thanh Ni. S trng hp xut hi n mn i ho l A. 1 B. 4 C. 3 D. 2 Cu 16: Phn ng in phn dung dch CuCl2 (vi in cc tr) v phn ng n mn in ha xy ra khi nhng hp kim Zn-Cu vo dung dch HCl c c im l: A. Phn ng xy ra lun km theo s pht sinh dng in. B. u sinh ra Cu cc m. C. Phn ng cc m c s tham gia ca kim loi hoc ion kim loi. D. Phn ng cc dng u l s oxi ha Cl-. Cu 17: in phn (vi in cc tr) mt dung dch gm NaCl v CuSO4 c cng s mol, n khi catot xut hin bt kh th dng in phn. Trong c qu trnh in phn trn, sn phm thu c anot l

A. kh Cl2 v O2. B. kh H2 v O2. C. ch c kh Cl2. D. kh Cl2 v H2. Cu 18: Cho 29,8 gam hn hp bt gm Zn v Fe vo 600 ml dung dch CuSO4 0,5M. Sau khi cc phn ng xy ra hon ton, thu c dung dch X v 30,4 gam hn hp kim loi. Phn trm v khi lng ca Fe trong hn hp ban u l A. 56,37% B. 37,58% C. 64,42% D. 43,62% Cu 19: in phn dung dch CuSO4 vi anot bng ng (anot tan) v in phn dung dch CuSO4 vi anot bng graphit (in cc tr) u c c im chung l A. catot xy ra s oxi ha: 2H2O +2e 2OH+H2 B. anot xy ra s kh: 2H2O O2 + 4H++4e C. anot xy ra s oxi ha: Cu Cu2+ +2e D. catot xy ra s kh: Cu2++ 2e Cu Cu 20: Khi in phn dung dch NaCl (cc m bng st, cc dng bng than ch, c mng ngn xp) th: A. cc dng xy ra qu trinh oxi ha ion Na+ v cc m xy ra qu trnh kh ion Cl-. B. cc m xy ra qu trnh kh H2O v cc dng xy ra qu trnh oxi ha Cl-. C. cc m xy ra qu trnh oxi ha H2O v cc dng x ra qu trnh kh ion Cl-. D. cc m xy ra qu trnh kh ion Na+ v cc dng xy ra qu trnh oxi ha ion Cl-. Cu 21: Trong qu trnh hot ng ca pin in ha Zn Cu th A. khi lng ca in cc Zn tng. B. nng ca ion Cu2+ trong dung dch tng. C. nng ca ion Zn2+ trong dung dch tng. D. khi lng ca in cc Cu gim. Cu 21: Tin hnh hai th nghim sau: - TN 1: Cho m gam bt Fe (d) vo V1 lt dung dch Cu(NO3)2 1M; - TN 2: Cho m gam bt Fe (d) vo V2 lt dung dch AgNO3 0,1M. Sau khi cc phn ng xy ra hon ton, khi lng cht rn thu c hai th nghim u bng nhau. Gi tr ca V1 so vi V2 l A. V1 = V2. B. V1 = 10V2. C. V1 = 5V2. D. V1 = 2V2. Cu 22: Cho mt lng bt Zn vo dung dch X gm FeCl2 v CuCl2. Khi lng cht rn sau khi cc phn ng xy ra hon ton nh hn khi lng bt Zn ban u l 0,5 gam. C cn phn dung dch sau phn ng thu c 13,6 gam mui khan. Tng khi lng cc mui trong X l A. 13,1 gam. B. 17,0 gam. C. 19,5 gam. D. 14,1 gam.--------------------Cu 23: Cho hn hp gm 1,2 mol Mg v x mol Zn vo dung dch cha 2 mol Cu2+ v 1 mol Ag+ n khi cc phn ng xy ra hon ton, thu c mt dung dch cha 3 ion kim loi. Trong cc gi tr sau y, gi tr no ca x tha mn trng hp trn? A. 1,5 B. 1,8 C. 2,0 D. 1,2 Cu 24: in phn c mng ngn 500 ml dung dch cha hn hp gm CuCl2 0,1M v NaCl 0,5M (in cc tr, hiu sut in phn 100%) vi cng dng in 5A trong 3860 giy. Dung dch thu c sau in phn c kh nng ho tan m gam Al. Gi tr ln nht ca m l A. 4,05 B. 2,70 C. 1,35 D. 5,40 Cu 25: in phn nng chy Al2O3 vi anot than ch (hiu sut in phn 100%) thu c m kg Al catot v 67,2 m3 ( ktc) hn hp kh X c t khi so vi hiro bng 16. Ly 2,24 lt ( ktc) hn hp kh X sc vo dung dch nc vi trong (d) thu c 2 gam kt ta. Gi tr ca m l A. 54,0 B. 75,6 C. 67,5 D. 108,0 Cu 26: Nhng mt thanh st nng 100 gram vo 100 ml dung dch hn hp gm Cu(NO3)2 0,2M v AgNO3 0,2M. Sau mt thi gian ly thanh kim loi ra, ra sch lm kh cn c 101,72 gam (gi thit cc kimloi to thnh u bm ht vo thanh st). Khi lng st phn ng l A. 2,16 gam B. 0,84 gam C. 1,72 gam D. 1,40 gam Cu 27: Cho 19,3 gam hn hp b t Zn v Cu c t l mol tng ng l 1 : 2 vo dung dch cha 0,2 mol Fe2(SO4)3. Sau khi cc phn ng xy ra hon toa, nthu c m gam kim loa.i Gi tr ca m l A. 6,40 B. 16,53 C. 12,00 D. 12,80
Cu 28: i n phn (vi i n cc tr ) 200 ml dung di ch CuSO 4 nng x mol l, sau m t thi gian thu c dung di ch vn cn mu xanh , c khi lng gim 8g so vi dung d ch ban u . Cho 16,8g b t Fe vo , sau khi cc phn ng xy ra hon ton, thu c12,4g kim lo i. Gi tr ca x l A. 2,25 B. 1,5 C. 1,25 D. 3,25

Cu 29: Cho bit cc phn ng xy ra sau: 2FeBr2 + Br2 2FeBr3 2NaBr + Cl2 2NaCl + Br2 Pht biu ng l: A. Tnh kh ca Cl - mnh hn ca Br -. B. Tnh oxi ha ca Br2 mnh hn ca Cl2. C. Tnh kh ca Br - mnh hn ca Fe2+. D. Tnh oxi ha ca Cl2 mnh hn ca Fe3+. H V C NM 2011 Cu 30 Ha tan 13,68 gam mui MSO4 vo nc c dung dch X. in phn X (vi in cc tr, cng dng in khng i) trong thi gian t giy, c y gam kim loi M duy nht catot v 0,035 mol kh anot. Cn nu thi gian in phn l 2t giy th tng s mol kh thu c c hai in cc l 0,1245 mol. Gi tr ca y l A. 4,480. B. 3,920. C. 1,680. D. 4,788. Cu 31: in phn dung dch gm 7,45 gam KCl v 28,2 gam Cu(NO3)2(in cc tr, mng ngn xp) n kh khi lng dung dch gim i 10,75 gam th ngng in phn (gi thit lng nc bay hi khng ng k). Tt c cc cht tan trong dung dch sau in phn l A. KNO3 v KOH. B. KNO3, KCl v KOH. C. KNO3 v Cu(NO3)2. D. KNO3, HNO3 v Cu(NO3)2. Cu 32: Cho 2,7 gam hn hp bt X gm Fe v Zn tc dng vi dung dch CuSO4. Sau mt thi gian, thu c dung dch Y v 2,84 gam cht rn Z. Cho ton b Z vo dung dch H2SO4 (long, d). Sau khi cc phn ng kt thc th khi lng cht rn gim 0,28 gam v dung dch thu c ch cha mt mui duy nht. Phn trm khi lng ca Fe trong X l: A. 58,52% B. 51,85% C. 48,15% D. 41,48% Cu 33: Cho m gam bt Cu vo 400 ml dung dch AgNO3 0,2M, sau mt thi gian phn ng thu c 7,76 gam hn hp cht rn X v dung dch Y. Lc tch X, ri thm 5,85 gam bt Zn vo Y, sau khi phn ng xy ra hon ton thu c 10,53 gam cht rn Z. Gi tr ca m l A. 3,84 B. 6,40 C. 5,12 D. 5,76 Cu 34: in phn 500 ml dung dch CuSO4 0,2M (in cc tr) cho n khi catot thu c 3,2 gam kim loi th th tch kh (ktc) thu c anot l: A. 3,36 lt B. 1,12 lt C. 0,56 lt D. 2,24 l Cu 34: Trong qu trnh hot ng ca pin in ha Zn Cu th A. khi lng ca in cc Zn tng B. nng ca ion Cu2+ trong dung dch tng 2+ C. nng ca ion Zn trong dung dch tng D. khi lng ca in cc Cu gim Cu 35(A-2012): Cho cc cp oxi ho - kh c sp xp theo chiu tng dn tnh oxi ho ca dng oxi ha nh sau: Fe /Fe, Cu /Cu, Fe /Fe . Pht biu no sau y l ng? A. Fe oxi ha c Cu thnh Cu
3+ 2+ 2+ 2+ 2+ 2+ 3+ 2+

. B. Cu oxi ho c Fe thnh Fe .
3+

2+

2+

3+

C. Fe oxi ha c Cu thnh Cu . D. Cu kh c Fe thnh Fe. Cu 36: in phn mui clorua kim loi kim nng chy th thu c 0,896 lt kh (ktc) anot v 3,12 gam kim loi catot. Cng thc mui clorua l A. KCl. B. NaCl. C. LiCl. D. RbCl. Cu 37: Trong hin tng n mn in ha th xy ra A s oxi ha cc m B. s kh cc m C. . s oxi ha cc dng D. s oxi ha kh u cc dng Cu 38 in phn 2 lt dung dch CuSO4 (vi in cc tr) n khi kh thot ra c 2 in cc u l 0,02 mol th dng li. Coi th tich dung dch khng ii Gi tr pH ca dung dch sau in phn l A. 2,0. B. 1,7. C. 1,4. D. 1,2 Cu139: in phn dung dch AgNO3 (vi in cc tr). Nu dung dch sau khi in phn c pH = 1, hiu sut in phn l 80 %, th tch ca dung dch c coi nh khng i (100ml) th nng AgNO3 trong dung dch ban u l A. 0,08. B. 0,1. C. 0,325. D. 0,125. Cu 40. Tin hnh in phn 200ml dung dch gm HCl 0,6M v CuSO4 1M vi cng dng in 1,34 A trong thi gian 4 gi. Bit hiu sut in phn l 100%. Th tch kh (ktc) thot ra trn anot l A. 1,344 lt. B. 1,568 lt. C. 1,792 lt. D. 2,016 lt. Cu 41P: Tin hnh in phn (in cc tr, mng ngn xp) 1 dung dch cha m gam hn hp CuSO4 v NaCl cho ti khi nc bt u b in phn c 2 in cc th dng li, thu c 0,448 lt kh (ktc). Dung dch sau in phn c mi trng axit v c th ho tan ti a 0,68 gam Al2O3. Gi tr ca m l A. 4,955 gam. B. 5,385. C. 4,370. D. 5,970 gam.