H O

H C

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TIU LUN V HA HC XANH

PHNG PHP S DNG CO2 SIU TI HN

GVHD: Thy Phan Thanh Sn Nam Nhm:1

Trng Khc Ph Cng

Phm S Nguyn

Nguyn Vn Hin

ng t n i c nh th a ai g Ph t Kh n th ch ng l Tng m ch CO i p h quan v 2 s t c p CO2 siuh si d ht Th no l lu cht u ti hsiu ti hn ng n n t i Ha hc xanh l g

Ni Dung

Tiu lun v Ha Hc Xanh

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1.Ha hc xanh l g

Tiu lun v Ha Hc Xanh

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2.Th no l lu cht siu ti hn

Th no l lu cht siu ti hn
im ti hn ca CO2(304,1oK,73,75atm)

Tiu lun v Ha Hc Xanh

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3.Tng quan v CO2 siu ti hn

Tng quan v CO2 siu ti hn

Ci nhn chung di gc ha hc xanh u im ca CO2 siu ti hn K thut tin hnh phn ng

Ci nhn chung
Tc cht phn ng Thay th dung mi Ci tin hiu sut

Gc ha hc xanh

uim

u im so vi cc phng php truyn thng Tnh cht ha l u im so vi cc dung mi khc

So vi phng php truyn thng

Cht lng cao

Khng cn dung mi d

Tch c hm lng cao

Khng nhim

Cng ngh cao v an ton

Tnh cht ha l
Sc cng b mt thp nht thp Kh nng ha tan tt
linh ng cao T trng xp x cht lng Kh nng khuych tn cao

So snh vi dung mi khc

K thut tin hnh phn ng

CO2 (K)

p, toC

CO2 (scf) X p

Nguyn liu CO2 (scf) + tinh du Tch (1)

X l

CO2 (K)

Tch (2)

Tinh du

Tiu lun v Ha Hc Xanh

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3.Chit polyphe nol t l ch xanh

CHIT POLYPHENOL T L CH XANH DNG CO2 SIU TI HN

I. Gii thiu chung v cy Ch xanh

Cy Ch thuc h Ch (Theaceae) c ngun gc t Trung Quc.

Hin nay cy Ch c trng nhiu cc vng nhit i v cn nhit i

II. Thnh phn ha hc ca Ch

khong 70% l nc

protein, khong, x, lignan v pectin

L CH TI

2 - 3,5% cafein

20% tanin

III. Chit Polyphenol t Ch xanh

Hin nay ch yu chit s dng dung mi hu c nh ethanol, methanol v hoc hn hp ca chng vi nc. Nhc im: Tn ti mt lng ln cc cht khng mong mun b chit cng Polyphenol, cc glycosid b thy phn khi s dng dung mi chit l dd nc acid.

Chit Polyphenol t Ch xanh bng CO2 siu ti hn

chn lc cao, loi b c cafein t sm

Chit bng dung mi hu c

Chit bng CO2 siu ti hn

Chu trnh trng thi ca CO2 trong qu trnh chit

IV. Cc yu t nh hng Tnh trng mu Thng s trng thi Co-solvent Thi gian chit T l SCO2 v nguyn liu

Xanh ch no ?
Nguyn tc 1: Ngn nga v Tnh kinh t Nguyn tc 2: Tnh kinh t Nguyn tc 5: Dung mi v cc cht ph tr an ton hn. Nguyn tc 7: S dng nguyn liu c th ti sinh

Tiu lun v Ha Hc Xanh

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5.Khai thc nng lng a Nhit

Khai thc nng lng a Nhit

Nng lng a nhit l g

Phng php khai thc nng lng a nhit truyn thng

S dng CO2 siu ti hn trong khi thc nng lng a nhit

1.Nng lng a nhit l g? Nng lng nhit m Tri t c c thng qua cc phn ng ht nhn m trong lng.

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a nhit c th l ngun nng lng sn xut cng nghip quy m va, trong cc lnh vc nh: - Nh my in a nhit - Si m a nhit

Hnh: Nh my in a nhit Iceland

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2.Cc phng php khai thc truyn thng

- S trc tip s dng hi nng kh - S gin tip s dng hi nc - S hn hp (hai chu trnh)

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Khai thc in a nhit bng CO2 siu ti hn

u im
Chy d dng qua cc khe nt

Gim CO2

Tit kim lng ln nc sch

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K T L U N
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Ti liu tham kho

[1]. Phan Thanh Sn Nam, Ha hc xanh trong tng hp hu c Tp 1: Xc tc xanh & Dung mi xanh , Nh xut bn i hc Quc gia TpHCM, 2008, 485tr. [2]. Lu Hong Ngc, Nghin cu cng ngh chit tch mt s ch phm thin nhin c gi tr kinh t cao bng CO2 lng trng thi siu ti hn, Vin Ha hc Cng nghip, B Cng nghip, 2007, 137tr. [3]. Chng trnh mc tiu quc gia v s dng nng lng tit kim v hiu qu b cng thng- VNEEP [4]. Bn tin cng ngh mi- nng lng a nhit trung tm tit kim nng lng tp HCM (Energy conservation center of HCM city) http://www.ecchcm.gov.vn [5]. Bn tin khoa hc-cng ngh khai thc a nhit bng CO2 siu ti hn http://tietkiemnangluong.com.vn [6]. Kerton F. M, Alternative solvent in green chemistry, RSC publishing, 2009, 226tr.

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